阅读说明：本技术 连续玄武岩纤维生产原料的优化配方设计方法 (Optimized formula design method of continuous basalt fiber production raw materials ) 是由 苗世顶 司集文 左传潇 李静瑶 于 2021-10-20 设计创作，主要内容包括：本发明公开了连续玄武岩纤维生产原料的优化配方设计方法。其特征在于优化配方不仅可用于玄武岩单一原料的原岩筛选,也可以用于调整多种玄武岩与外加添加剂的比例,形成CBF原料的复合配料。基于酸度偏离系数,粘度偏离系数,铁偏离系数,硅碱比,铝钛比等准则,并通过实验证明该配方为优化配方。所述优化配方化学成分的质量百分比如下：SiO-(2)含量在48.0-56.0％,SiO-(2)+Al-(2)O-(3)＝60.0-72.0％,Fe-(2)O-(3)/FeO＝0.75-1.25,硅碱比1.0-7.0,粘度系数2.0-2.5,酸度系数4.0-7.0。优化实验表明上述原料玄武岩粉在1390-1550℃能获得优质熔料,通过Pt-Rh漏板实现连续拉丝。在无外界物理条件干扰下,断丝频率几乎为零。该配方能做到规模化生产,解决当前玄武岩纤维生产企业的频繁断丝问题。(The invention discloses an optimized formula design method of continuous basalt fiber production raw materials. The method is characterized in that the optimized formula not only can be used for raw rock screening of a single basalt raw material, but also can be used for adjusting the proportion of various basalt and an external additive to form a composite ingredient of the CBF raw material. Based on the criteria of acidity deviation coefficient, viscosity deviation coefficient, iron deviation coefficient, silica-soda ratio, aluminum-titanium ratio and the like, the formula is proved to be an optimized formula through experiments. The optimized formula comprises the following chemical components in percentage by mass: SiO 2 2 48.0-56.0% of SiO 2 +Al 2 O 3 ＝60.0‑72.0％，Fe 2 O 3 0.75-1.25 percent of/FeO, 1.0-7.0 percent of silica-alkali ratio, 2.0-2.5 of viscosity coefficient and 4.0-7.0 of acidity coefficient. Optimization experiments show that the raw material basalt powder can obtain high-quality molten materials at 1390-. The yarn is broken under the condition of no external physical condition interferenceThe frequency is almost zero. The formula can realize large-scale production and solve the problem of frequent filament breakage of current basalt fiber production enterprises.)

1. The method for designing the optimized formula of the raw materials for producing the continuous basalt fibers is characterized in that the formula is SiO₂48.0-56.0% of SiO₂+Al₂O₃＝60.0-72.0％，Fe₂O₃0.75-1.25 percent of/FeO, 1.0-7.0 percent of silica-soda ratio, 2.0-2.5 of viscosity coefficient and 4.0-7.0 of acidity coefficient;

the formula optimization implementation comprises the following main steps:

(1) determining basalt components, selecting basalt raw rock in different regions, performing chemical analysis, and determining its main oxide content, including SiO₂、Al₂O₃、Fe₂O₃、FeO、CaO、MgO、TiO₂、K₂O、Na₂O、P₂O₅MnO and Loss On Ignition (LOI), the sum of the main contents of the 12 items is 99-101%, and the data is valid;

(2) if the single raw material can not meet the formula requirements, compounding to form a composite raw material to meet the component requirements; the ingredients can be basalt samples with other components (regions), and also can be oxide additives such as soda-lime glass, sodium silicate, quicklime, calcium carbonate, soda ash, caustic soda and the like;

(3) grinding the basalt raw material which meets the component requirements to below 50 meshes, and fully mixing; and (3) putting the material powder into a tank furnace, heating, and carrying out wire drawing operation after homogenization to obtain a continuous basalt fiber product.

2. The method for designing the optimized formulation of the raw material for producing the continuous basalt fiber according to claim 1, wherein the determination of the FeO content in the step (1) requires a chemical titration method to give an exact value; values determined instrumentally or by calculation are not available.

3. The method of claim 1, wherein the formulation has a silica-soda ratio (SiO)₂)/(K₂O+Na₂O), acidity coefficient ═ SiO₂+Al₂O₃) (CaO + MgO), the above are mass percentages; viscosity coefficient ═ SiO₂+₂Al2O₃)/(FeO+2Fe₂O₃+CaO+MgO+K₂O+Na₂O)，The formula is the molar ratio.

4. The method for designing an optimized formula of a continuous basalt fiber production raw material according to claim 1, wherein the added ingredients are of such a quality that the final composite ingredients satisfy the range of the ingredients of the optimized formula; and in the step (2) and the step (3), different ingredients need to be ground and fully mixed.

5. The method for designing the optimized formula of the raw materials for producing the continuous basalt fibers according to the claim 1, wherein the furnace temperature is set to 1350-.

Technical Field

The invention relates to an optimized formula design of a continuous basalt fiber production raw material.

Background

Continuous Basalt Fiber (CBF) is an inorganic non-metallic fiber produced by utilizing basalt ore, and is another high-technology fiber after carbon fiber, aramid fiber and polyethylene fiber with ultrahigh relative molecular mass. Besides high mechanical properties, CBF also has a series of special properties such as good insulating properties, excellent thermal stability, good chemical stability and the like. The production process of the CBF has less waste, and the waste products can be directly transferred into a roadbed or a protective project, so the CBF is a real environment-friendly material. Although the production cost of basalt fiber is relatively low, the production yield is low at present due to the fact that the raw material of basalt is not suitable for producing CBF, the broken filament rate in fiber production is high and the like, so that the market development and the application range of basalt fiber are limited [ chendeli 2014; zhao Zheng xing 2014 ].

The patent provides an optimized formula aiming at the technical bottleneck existing in the large-scale industrial production of the CBF at present, namely, the basalt components in various places are not uniform, the wire is frequently broken in the wire drawing process, the yield is low, the continuous operation is blocked, and the production capacity of continuous basalt enterprises is small. Factors affecting the wire drawing efficiency are many, including ore composition, drawing rate, furnace body temperature gradient, discharge spout temperature, etc., for example: yan Quanying et al found that basalt feedstock particles having an average particle size of 2.5 to 3.5mm are suitable [ Yan Quanying 2000 ]]. The ore composition is the most important, and directly determines the viscosity and filamentation characteristics at high temperature. The earlier research shows that SiO₂The chemical stability and melt viscosity of the fiber are improved, and the elasticity of the fiber is enhanced; al (Al)₂O₃The use temperature of the fiber is favorably improved; FeO + Fe₂O₃The color and luster of the fiber are influenced, and the important influence is exerted on the filamentation temperature and the viscosity; CaO has an important influence on the extraction of the filaments and influences the durability, chemical stability and thermal stability of CBF; TiO 2₂Is favorable for improving the surface tension, viscosity and chemical stability of the melt and forming fibers. But the melting process cannot have a reducing atmosphere, e.g. FeO + Fe₂O₃After being reduced to Fe, Pt/Fe alloy is easily formed with Pt, and the bushing is damaged.

Patent CN1884164B thoughVarious oxides are added to reduce the filament breakage frequency of the basalt fiber, but specific standards and ranges for the addition of the oxides are not given. Patent CN107609331A discloses an optimized design method for continuous basalt fiber formula, but the target value acidity coefficient>3，FeO/Fe₂O₃Not less than 0.5, viscosity coefficient not less than 1.5, no upper limit given, not strong operability, and prediction results far from experiments, such as: the rhyolitic rock with high FeO content can completely reach the indexes, but the basalt fiber drawn by the rhyolitic rock is only reported, and the preparation of CBF by the ore is not feasible in experiments. However, patent CN106242305B proposes to improve the production capacity of basalt fiber by mixing two kinds of basalt raw materials, but limits the selection range of basalt, and cannot realize the utilization of most basalt.

The patent provides a raw material optimization formula for continuous basalt fiber production, which comprises the criteria of main oxide content, acidity deviation coefficient, viscosity deviation coefficient, iron deviation coefficient, silica-soda ratio, aluminum-titanium ratio and the like in the raw materials, and optimization experiments show that the basalt powder of the raw materials can obtain high-quality molten materials at 1390-. The filament breakage frequency of the formula is almost zero without the interference of external physical conditions. The formula can realize large-scale production and solve the problem of frequent filament breakage of current basalt fiber production enterprises.

Disclosure of Invention

The technical problem to be solved is as follows:

1. the invention mainly provides a feasible optimized formula, and aims to solve the problem of frequent yarn breakage in the CBF production process.

2. The invention mainly provides a feasible optimized formula, and aims to further expand the range of basalt raw materials suitable for producing CBF.

3. The invention mainly provides a feasible optimized formula, which is used for utilizing the basalt with high FeO content.

4. The invention further provides a method for realizing component optimization by using a plurality of basalt raw materials and a small amount of low-price additives, such as sodium silicate, quicklime, calcium carbonate and the like in a compounding way.

The technical scheme is as follows:

in order to solve the technical problems, the invention provides an optimized formula design method, which can improve the application range of basalt raw materials and solve the problem of filament breakage in the fiber production process and the like. The method is realized by the following technical scheme:

1. the optimized formula design of the raw materials for producing the continuous basalt fibers is characterized in that the formula is SiO₂48.0-56.0% of SiO₂+Al₂O₃＝60.0-72.0％，Fe2O₃0.75-1.25 percent of/FeO, 1.0-7.0 percent of silica-alkali ratio, 2.0-2.5 of viscosity coefficient and 4.0-7.0 of acidity coefficient.

The formula optimization implementation comprises the following main steps:

(1) determining basalt components, selecting basalt raw rock in different regions, performing chemical analysis, and determining the content of main oxides including SiO₂、Al₂O₃、Fe₂O₃、FeO、CaO、MgO、TiO₂、K₂O、Na2O、P₂O₅MnO and Loss On Ignition (LOI), the sum of the main contents of the 12 items is 99-101%, and the data is valid.

(2) If the single raw material can not meet the formula requirements, the components need to be mixed to form a composite raw material to meet the component requirements. The ingredients can be basalt samples with other components (regions), and also can be oxide additives such as soda-lime glass, sodium silicate, quicklime, calcium carbonate, soda ash, caustic soda and the like.

(3) Grinding the basalt raw material which meets the component requirements to below 50 meshes, and fully mixing. And (3) putting the material powder into a tank furnace, heating, and carrying out wire drawing operation after homogenization to obtain a continuous basalt fiber product.

2. Preferably, the optimized formula design of the raw materials for producing the continuous basalt fibers is characterized in that the FeO content determination in the step (1) needs a chemical titration method to give an exact value. Values determined instrumentally or by calculation are not available.

3. Preferably, the optimized formula design of the raw materials for producing the continuous basalt fibers is characterized in that the formulaMedium silica-to-soda ratio (SiO)₂)/(K₂O+Na₂O), acidity coefficient ═ SiO₂+Al₂O₃) (CaO + MgO), the above are mass percentages; viscosity coefficient ═ SiO₂+2Al₂O₃)/(FeO+2Fe₂O₃+CaO+MgO+K2O+Na₂O), the formula is a molar ratio.

4. Preferably, the optimized formula design of the continuous basalt fiber production raw material is characterized in that the quality of the added ingredients is such that the final compound ingredient meets the component range of the optimized formula. And in the step (2) and the step (3), different ingredients need to be ground and fully mixed.

5. Preferably, the optimized formula design of the raw materials for producing the continuous basalt fibers is characterized in that the furnace temperature is set to 1350-.

The invention has the following positive effects:

the preparation method mainly adopts Laban basalt, Anshan basalt and super basic basalt as raw material main bodies, realizes the utilization of most basalt ores by adding other kinds of basalt or trace oxides, can realize continuous wire drawing of zero wire breaking frequency by a small amount of ingredients under the condition of not changing any basalt production equipment and process, and can also realize continuous wire drawing at higher roller rotating speed, thereby providing a feasible and universal basalt fiber production optimization formula, and having the positive effects that:

1. the formula of the invention has wide applicability and can realize the utilization of most basalt ore resources.

2. The invention solves the problem that the basalt with high FeO content is used for producing CBF worldwide.

3. The basalt with different components in different regions can be compositely utilized as the material is used as much as possible.

4. The additive with low price can be used as a material to realize component optimization.

5. Realizing the continuous operation of zero broken wire.

Drawings

FIG. 1 is a schematic structural view of a drawing experimental apparatus of the present invention, the upper part of which is a tank furnace; the middle part is a buncher which can also be used as a device for applying impregnating compound; the lower part is a high-speed rotor used for recovering CBF products;

FIG. 2 is a photograph of a CBF of the present invention.

Detailed Description

The specific implementation mode is as follows:

the present invention is further illustrated by the following examples, which do not limit the present invention in any way, and any modifications or changes that can be easily made by a person skilled in the art to the present invention will fall within the scope of the claims of the present invention without departing from the technical solution of the present invention.

Example 1

Weighing basalt A1, which comprises the following main components: SiO 2₂：49.09；Al₂O₃：13.46；Fe₂O₃：8.75；FeO：2.67；CaO：8.48；MgO：6.09；K₂O：1.70；Na₂O：2.79；TiO₂：2.18；MnO：0.11；P₂O₅: 0.53; LIO: 3.58. through experiments, the raw materials are singly used for drawing, and the wire forming rate is extremely low and is about 20%. Most of the melt passes through the bushing plate to form melt flows with different thicknesses. According to the calculation: SiO 2₂+Al₂O₃62.55 (falling within the evaluation interval); iron ratio Fe₂O₃: FeO 3.28 (iron deviation factor 173.10%); CaO + MgO was 14.57, and the silica-soda ratio was 10.93 (not falling within the evaluation interval); the viscosity coefficient is 1.85 (not falling into the evaluation interval, but is negative), the lower limit deviation coefficient of the viscosity coefficient is-7.50%, and the upper limit deviation coefficient of the viscosity coefficient is-26.00%; the acidity coefficient is not 4.29 (falling into the evaluation interval, but is negative), the lower limit deviation coefficient of the acidity coefficient is 7.25%, the upper limit deviation coefficient of the acidity coefficient is-38.67%, and the mineral aggregate is evaluated to be singly used and cannot be used as a whole.

Basalt B1 is also taken, and the main components are as follows: SiO 2₂：56.79，Al₂O₃：16.45；Fe₂O₃：3.83；FeO：5.15；CaO：3.46；MgO：0.85；K₂O：5.00；Na₂O：5.23；TiO₂：0.89；MnO：0.19；P₂O₅：0.48；LIO：1.50。SiO₂+Al₂O₃73.24 (not falling within the evaluation range); iron ratio Fe₂O₃: FeO 0.74 (iron deviation factor-38.02%); CaO + MgO was 4.32, and the silica-soda ratio was 5.55 (falling within the evaluation range); the viscosity coefficient is 3.26 (not falling into the evaluation range, being more positive), the lower limit deviation coefficient of the viscosity coefficient is 63.00%, and the upper limit deviation coefficient of the viscosity coefficient is 30.40%; the acidity coefficient is not 16.97 (not falling into the evaluation range, being biased to be positive), the lower limit deviation coefficient of the acidity coefficient is 324.17%, the upper limit deviation coefficient of the acidity coefficient is 142.38%, and the mineral aggregate is evaluated to be singly used and not usable as a whole.

Taking 1 part of sample A and 3 parts of sample B to form a composite ingredient, wherein the components are as follows: SiO 2₂：54.87；Al₂O₃：15.70；Fe₂O₃：5.06；FeO：4.53；CaO：4.72；MgO：2.16；K₂O：4.18；Na₂O：4.62；TiO₂：1.21；MnO：0.18；P₂O₅：0.46；LIO：2.02。SiO₂+Al₂O₃70.57 (falling within the evaluation range); iron ratio Fe₂O₃: FeO 1.12 (falling within the evaluation range); CaO + MgO was 6.88, silica-soda ratio was 6.90 (falling within the evaluation range); viscosity coefficient 2.46 (falling within the evaluation range); the acidity index was not 6.88 (falling within the evaluation range), and as a result of the evaluation, the composite material was usable.

Example 2

Weighing basalt A2, which comprises the following main components: SiO 2₂：49.54；Al₂O₃：14.76；Fe₂O₃：10.19；FeO：2.71；CaO：7.12；MgO：4.90；K₂O：1.63；Na₂O：3.11；TiO₂：2.13；MnO：0.14；P₂O₅: 0.47; LIO: 3.04. through experiments, the raw materials are singly used for drawing, the wire forming rate is extremely low, continuous drawing is difficult, and most of melt cannot form melt flow through a bushing. According to the calculation: SiO 2₂+Al₂O₃64.30 (falling within the evaluation interval); iron ratio Fe₂O₃：FeO＝3.76 (iron deviation factor 213.36%); CaO + MgO was 12.02, and the silica-soda ratio was 10.45 (not falling within the evaluation interval); the viscosity coefficient is 2.83 (not falling into the evaluation interval, being more positive), the lower limit deviation coefficient of the viscosity coefficient is 34.76%, and the upper limit deviation coefficient of the viscosity coefficient is 13.20%; the acidity coefficient is not 5.35 (falling into the evaluation interval), the lower limit deviation coefficient of the acidity coefficient is 33.74%, the upper limit deviation coefficient of the acidity coefficient is-23.53%, and the mineral aggregate is evaluated to be singly used and cannot be used as a whole.

Basalt B2 is also taken, and the main components are as follows: SiO 2₂：56.58，Al₂O₃：16.69；Fe₂O₃：3.05；FeO：5.55；CaO：3.61；MgO：10.5；K₂O：4.19；Na₂O：5.20；TiO₂：0.99；MnO：0.20；P₂O₅：0.54；LIO：1.33。SiO₂+Al₂O₃73.27 (not falling within the evaluation range); iron ratio Fe₂O₃: FeO 0.55 (iron deviation factor-54.20%); CaO + MgO was 4.66, silica-soda ratio was 5.60 (falling within the evaluation range); the viscosity coefficient is 3.24 (not falling into the evaluation range, being more positive), the lower limit deviation coefficient of the viscosity coefficient is 62.00%, and the upper limit deviation coefficient of the viscosity coefficient is 29.60%; the acidity coefficient is not 15.72 (not falling into the evaluation range, being biased to be positive), the lower limit deviation coefficient of the acidity coefficient is 293.08%, the upper limit deviation coefficient of the acidity coefficient is 124.62%, and the mineral aggregate is evaluated to be singly used and not usable as a whole.

Basalt of C1 is also taken, and the main components are as follows: SiO 2₂：49.62，Al₂O₃：16.58；Fe₂O₃：3.58；FeO：7.01；CaO：6.70；MgO：6.77；K₂O：2.17；Na₂O：4.18；TiO₂：1.84；MnO：0.14；P₂O₅：0.60；LIO：0.57。SiO₂+Al₂O₃66.20 (falling within the evaluation range); iron ratio Fe₂O₃: FeO 0.51 (iron deviation factor-57.40%); CaO + MgO was 13.47, silica-soda ratio was 7.81 (not falling within the evaluation range); the viscosity coefficient is 1.70 (not falling into the evaluation range, is negative), the lower limit deviation coefficient of the viscosity coefficient is-1.20%, and the upper limit deviation coefficient of the viscosity coefficient is-32.00%; the acidity index was not 4.92 (falling within the evaluation range), the lower limit of the acidity index deviated by a factor of 22.88%, and the acidityThe upper limit of the coefficient deviates from the coefficient of 29.78%, and the mineral aggregate is evaluated to be singly used and cannot be used as a whole.

Taking 2 parts of sample A, 5.5 parts of sample B and 2.5 parts of sample C, and simultaneously adding 3.0% of quicklime by mass ratio for regulation to form a composite ingredient, wherein the components are as follows: SiO 2₂：51.99；Al₂O₃：15.67；Fe₂O₃：4.89；FeO：4.98；CaO：8.07；MgO：3.05；K₂O：3.51；Na₂O：4.41；TiO₂：1.33；MnO：0.17；P₂O₅：0.49；LIO：1.24。

SiO₂+Al₂O₃67.66 (falling within the evaluation range); iron ratio Fe₂O₃: FeO is 0.98 (falling within the evaluation range); CaO + MgO was 11.12, and the silica-soda ratio was 6.89 (falling within the evaluation range); viscosity index 2.24 (falling within the evaluation range); the acidity index was not 6.09 (falling within the evaluation range), and as a result of the evaluation, the composite material was usable.

Example 3

Weighing basalt A3, which comprises the following main components: SiO 2₂：56.42；Al₂O₃：16.47；Fe₂O₃：3.69；FeO：5.77；CaO：4.65；MgO：2.13；K₂O：3.97；Na₂O：4.84；TiO₂：1.00；MnO：0.22；P₂O₅: 0.42; LIO: 0.16. through the experiment, the raw materials are singly used for wire drawing, the continuous wire drawing is difficult under the condition of higher rotating speed of the roller, and the melt cannot form uniform and stable melt flow through the bushing plate. According to the calculation: SiO 2₂+Al₂O₃72.88 (not falling into the evaluation interval); iron ratio Fe₂O₃: FeO 0.64 (iron deviation factor-46.67%); CaO + MgO was 6.78, silica-soda ratio was 6.40 (falling within the evaluation interval); the viscosity coefficient is 2.88 (not falling into the evaluation interval, being more positive), the lower limit deviation coefficient of the viscosity coefficient is 44.00%, and the upper limit deviation coefficient of the viscosity coefficient is 15.20%; the acidity coefficient was not 10.75 (not within the evaluation interval, but was more positive), the lower limit deviation coefficient of acidity was 168.79%, and the upper limit deviation coefficient of acidity was 53.60%, and the mineral aggregate was evaluated as a whole and was not usable alone.

Taking basalt of B3, which mainly comprisesThe method comprises the following steps: SiO 2₂：50.95，Al₂O₃：13.32；Fe₂O₃：5.30；FeO：4.68；CaO：7.49；MgO：8.54；K₂O：1.31；Na₂O：2.94；TiO₂：1.69；MnO：0.13；P₂O₅：0.31；LIO：2.86。SiO₂+Al₂O₃64.27 (falling within the evaluation range); iron ratio Fe₂O₃: FeO 1.13 (iron deviation factor-5.57%); CaO + MgO was 16.04, and the silica-soda ratio was 12.01 (not falling within the evaluation range); the viscosity coefficient is 0.81 (not falling into the evaluation range, is negative), the lower limit deviation coefficient of the viscosity coefficient is-9.50%, and the upper limit deviation coefficient of the viscosity coefficient is-27.60%; the acidity coefficient is not 4.01 (falling into the evaluation range), the lower limit of the acidity coefficient deviates from the coefficient by 0.19%, the upper limit of the acidity coefficient deviates from the coefficient by-42.75%, and the mineral aggregate is evaluated to be singly used and not to be used as a whole.

Mixing the A3 and B3 samples in a mass ratio of 9:11 to form a compound ingredient, wherein the ingredients are as follows: SiO 2₂：53.41；Al₂O₃：14.74；Fe₂O₃：4.58；FeO：5.17；CaO：6.21；MgO：5.66；K₂O：2.51；Na₂O：3.97；TiO₂：1.38；MnO：0.17；P₂O₅：0.36；LIO：1.59。SiO₂+Al₂O₃68.15 (falling within the evaluation range); iron ratio Fe₂O₃: FeO is 0.89 (falling within the evaluation range); CaO + MgO was 11.87, and the silica-soda ratio was 6.45 (falling within the evaluation range); viscosity coefficient 2.21 (falling within the evaluation range); the acidity index was not 5.74 (falling within the evaluation range), and as a result of the evaluation, the composite was usable.

Example 4

Weighing basalt A4, which comprises the following main components: SiO 2₂：56.77；Al₂O₃：16.00；Fe₂O₃：5.30；FeO：4.68；CaO：3.31；MgO：0.74；K₂O：5.03；Na₂O：5.54；TiO₂：0.79；MnO：0.22；P₂O₅: 0.41; LIO: 1.70. through experiments, the raw materials are singly used for wire drawing, and the continuous wire drawing is difficult and the wire breaking condition is easy to occur under the condition of higher rotating speed of the roller. According toAnd (3) calculating: SiO 2₂+Al₂O₃72.77 (no evaluation interval was fallen); iron ratio Fe₂O₃: FeO 0.51 (iron deviation factor-57.65%); CaO + MgO was 4.04, silica-soda ratio was 5.37 (falling within the evaluation interval); the viscosity coefficient is 3.22 (not falling into the evaluation interval, being more positive), the lower limit deviation coefficient of the viscosity coefficient is 61.00%, and the upper limit deviation coefficient of the viscosity coefficient is 28.80%; the acidity coefficient is not 18.01 (not falling into the evaluation interval, being more positive), the lower limit deviation coefficient of the acidity coefficient is 350.31%, the upper limit deviation coefficient of the acidity coefficient is 157.32%, and the mineral aggregate is evaluated to be singly used and not to be used as a whole.

Basalt B4 is also taken, and the main components are as follows: SiO 2₂：49.09，Al₂O₃：13.46；Fe₂O₃：8.75；FeO：2.67；CaO：8.48；MgO：6.09；K₂O：1.70；Na₂O：2.79；TiO₂：2.18；MnO：0.11；P₂O₅：0.53；LIO：3.58。SiO₂+Al₂O₃62.55 (falling within the evaluation range); iron ratio Fe₂O₃: FeO 3.28 (iron deviation factor 173.10%); CaO + MgO was 14.57, and the silica-soda ratio was 10.93 (not falling within the evaluation range); the viscosity coefficient is 1.85 (not falling into the evaluation range, is negative), the lower limit deviation coefficient of the viscosity coefficient is-7.50%, and the upper limit deviation coefficient of the viscosity coefficient is-26.00%; the acidity coefficient was not 4.29 (falling within the evaluation range), the lower limit of the acidity coefficient deviated by a coefficient of 7.33%, the upper limit of the acidity coefficient deviated by a coefficient of-38.67%, and the mineral aggregate was evaluated as a whole to be used singly and not.

Basalt of C2 is also taken, and the main components are as follows: SiO 2₂：57.40，Al₂O₃：16.33；Fe₂O₃：3.46；FeO：6.03；CaO：3.68；MgO：1.02；K₂O：4.88；Na₂O：5.19；TiO₂：0.89；MnO：0.25；P₂O₅：0.22；LIO：0.26。SiO₂+Al₂O₃73.74 (not falling within the evaluation range); iron ratio Fe₂O₃: FeO 0.57 (iron deviation factor-52.28%); CaO + MgO was 4.70, and the silica-soda ratio was 5.70 (falling within the evaluation range); viscosity coefficient 3.16 (not falling into the evaluation range, biased positive), viscosity coefficient lower limit deviation coefficient 58.00%The viscosity coefficient deviates from the upper limit by 26.40%; the acidity coefficient is not 15.69 (not falling into the evaluation range, being biased), the lower limit deviation coefficient of the acidity coefficient is 292.19%, the upper limit deviation coefficient of the acidity coefficient is 124.11%, and the mineral aggregate is evaluated to be singly used and not capable of being used.

Mixing A4, B4 and C2 samples in a mass ratio of 5:7:8, and additionally adding quicklime in a mass ratio of 3.8% to form a composite batch, wherein the components are as follows: SiO 2₂：52.35；Al₂O₃：14.69；Fe₂O₃：5.02；FeO：4.69；CaO：8.73；MgO：2.63；K₂O：3.67；Na₂O：4.28；TiO₂：1.27；MnO：0.19；P₂O₅：0.45；LIO：1.59。

SiO₂+Al₂O₃67.03 (falling within the evaluation range); iron ratio Fe₂O₃: FeO 1.07 (falling within the evaluation range); CaO + MgO was 11.36, silica-soda ratio was 6.59 (falling within the evaluation range); viscosity coefficient 2.22 (falling within the evaluation range); the acidity index was not 5.90 (falling within the evaluation range), and as a result of the evaluation, the composite material was usable.

Test example:

performing a performance test experiment on the basalt fibers prepared in the embodiments 1 to 4, and detecting a tensile strength experiment according to national standards GB/T38111-2019 and GB/T7690.3-2013; and carrying out continuous wire drawing operation at a wire drawing rate of 21.3m/s, and counting the wire breakage frequency at 8 h.

Table 1 ingredients and physicochemical properties (wt%) of the basalt optimized formulation of each example