阅读说明：本技术 一种胶黏剂复合耐磨超疏水涂层及其制备方法 (Adhesive composite wear-resistant super-hydrophobic coating and preparation method thereof ) 是由 王艳艳 徐志勇 唐兴杰 彭长四 于 2021-10-28 设计创作，主要内容包括：本发明公开了一种胶黏剂复合耐磨超疏水涂层及其制备方法,将胶黏剂涂在刚性基底上,再压入纳米二氧化硅,得到胶黏剂复合耐磨超疏水涂层,刚性基底为玻璃；胶黏剂为硅橡胶、水性漆、水性不干胶、502胶水、环氧树脂AB胶中的一种或几种。现有技术普遍存在环境污染、工艺复杂、成本高昂等问题,无法实现大规模制备,大多只能局限在实验室理想的研究环境下。本发明以HMDS为改性剂,无氟制备超疏水SiO-(2)粒子,引入胶黏剂为辅助涂层,制备出高机械强度的复合超疏水涂层,并对胶黏剂、制备工艺及耐磨性增强机理进行了分析研究。(The invention discloses an adhesive composite wear-resistant super-hydrophobic coating and a preparation method thereof, wherein the adhesive is coated on a rigid substrate, and then nano silicon dioxide is pressed into the rigid substrate to obtain the adhesive composite wear-resistant super-hydrophobic coating, wherein the rigid substrate is glass; the adhesive is one or more of silicone rubber, water-based paint, water-based non-setting adhesive, 502 glue and epoxy resin AB glue. The prior art generally has the problems of environmental pollution, complex process, high cost and the like, can not realize large-scale preparation, and is mostly limited to the ideal research environment of a laboratory. The invention takes HMDS as a modifier to prepare the super-hydrophobic SiO in a fluorine-free way 2 The particles are prepared by introducing an adhesive as an auxiliary coating, and the adhesive, the preparation process and the wear resistance enhancing mechanism are analyzed and researched.)

1. The adhesive composite wear-resistant super-hydrophobic coating comprises a rigid substrate, an adhesive and nano silicon dioxide, and is characterized in that the adhesive is positioned on the surface of the rigid substrate, and the nano silicon dioxide is positioned in the adhesive.

2. The adhesive composite wear-resistant super-hydrophobic coating of claim 1, wherein the rigid substrate is glass; the adhesive is one or more of silicone rubber, water-based paint, water-based non-setting adhesive, 502 glue and epoxy resin AB glue.

3. The adhesive composite wear-resistant super-hydrophobic coating as claimed in claim 1, wherein nano-silica is prepared from tetraethyl orthosilicate, ammonia water and hexamethyldisilazane.

4. The preparation method of the adhesive composite wear-resistant super-hydrophobic coating of claim 1, which comprises the following steps of coating an adhesive on a rigid substrate, and pressing nano silica to obtain the adhesive composite wear-resistant super-hydrophobic coating.

5. The preparation method of the adhesive composite wear-resistant super-hydrophobic coating according to claim 4, wherein the nano-silica is obtained by preparing sol from tetraethyl orthosilicate, ammonia water and hexamethyldisilazane and drying and grinding the sol.

6. The preparation method of the adhesive composite wear-resistant super-hydrophobic coating according to claim 4, wherein the adhesive is one or more of silicone rubber, water-based paint, water-based adhesive sticker, 502 glue and epoxy resin AB glue.

7. The adhesive and the application of the nano silicon dioxide in preparing the rigid super-hydrophobic wear-resistant material.

8. The application of claim 7, wherein the adhesive is one or more of silicone rubber, water-based paint, water-based adhesive sticker, 502 glue and epoxy resin AB glue.

9. The adhesive composite wear-resistant super-hydrophobic coating of claim 1 is used for preparing a rigid super-hydrophobic wear-resistant material.

10. Use according to claim 7 or 9, wherein the rigid superhydrophobic wear resistant material has a self-cleaning function.

Technical Field

The invention belongs to the preparation of hydrophobic materials, and particularly relates to an adhesive composite wear-resistant super-hydrophobic coating and a preparation method thereof.

Background

Judging whether the wetting process can be carried out spontaneously or not, wherein the surface free energy of a solid and a solid-liquid interface is required, and three wetting types can only occur spontaneously when the change of the free energy of the system is a negative value, wherein the wetting is the easiest, the wetting is the second, and the spreading is the hardest. The wetting performance of the solid can be evaluated by observing the shape of the liquid on the surface of the solid, the liquid on the surface which is easy to wet can be always thoroughly spread, and the liquid on the surface which is difficult to wet is only partially spread into a hemispherical shape or even a sphere-like shape. To accurately represent the degree of wetting of a solid surface, one introduces contact and rolling angles as wettability evaluation parameters.

The research on the superhydrophobic property has been focused on the hydrophobic mechanism and the preparation method, the technology for preparing the superhydrophobic surface has become mature with the increasingly deep research, and in recent years, scholars begin to pay more attention to the specific application and specific properties of the superhydrophobic surface. The preparation of the super-hydrophobic surface is mainly realized by controlling the microstructure and the surface free energy of the surface, and different materials and microstructures can enable the super-hydrophobic surface to have more functional characteristics. Currently, the main application studies of superhydrophobic surfaces include: oil-water separation, frost prevention and freeze resistance, metal corrosion prevention, water vapor collection and the like, and other common reports such as energy conservation and drag reduction, pollution prevention and dust prevention, wood mildew prevention, biological adhesion prevention and the like are also reported. In many application fields of super-hydrophobic materials, the improvement of the transparency and the durability of a hydrophobic surface is the most critical. How to prepare the super-hydrophobic surface with excellent performance by a simpler, safer and more efficient method is the key and difficult point of current research.

The biggest obstacle currently faced by the application of the transparent super-hydrophobic surface is the problem of the mechanical strength of a film layer, particularly, the adhesion between a rough structure formed by assembling nano particles and a substrate is poor, the rough structure is easy to damage by external force and wear so as to lose hydrophobicity, the contradiction which is difficult to reconcile exists between transparency and wear resistance, and the improvement of the wear resistance of the transparent super-hydrophobic surface is a great challenge in the super-hydrophobic field. The application field of the super-hydrophobic surface determines that the super-hydrophobic material is exposed to a severe natural environment for a long time, most of reported preparation methods cannot prepare long-acting super-hydrophobic surfaces, and the problems of chemical stability, thermal stability, corrosion resistance, ultraviolet radiation resistance and particularly mechanical stability of the hydrophobic layer are mainly overcome when the service life of the hydrophobic layer is prolonged. The improvement of the wear resistance of the hydrophobic layer greatly promotes the development of the super-hydrophobic application field.

Disclosure of Invention

The preparation of the super-hydrophobic surface of animals and plants with far-exceeding performance in the nature is basically realized in the prior art, however, a longer distance needs to be spanned for really realizing the industrial production of the super-hydrophobic material, because the methods generally have the problems of environmental pollution, complex process, high cost and the like, the large-scale preparation cannot be realized, and most of the methods can only be limited in the ideal research environment of a laboratory. The invention takes HMDS as a modifier to prepare the super-hydrophobic SiO in a fluorine-free way₂The particles are prepared by introducing an adhesive as an auxiliary coating, and the adhesive, the preparation process and the wear resistance enhancing mechanism are analyzed and researched. Compared with a micro-nano hierarchical structure and a self-repairing material, the hydrophobic nano particles and the substrate can be firmly attached together under the strong bonding action of the adhesive, so that the wear resistance of the coating is improved.

The invention adopts the following technical scheme:

the adhesive composite wear-resistant super-hydrophobic coating comprises a rigid substrate, an adhesive and nano silicon dioxide, wherein the adhesive is positioned on the surface of the rigid substrate, and the nano silicon dioxide is positioned in the adhesive.

The invention discloses a preparation method of the adhesive composite wear-resistant super-hydrophobic coating, which comprises the following steps of coating an adhesive on a rigid substrate, and pressing nano silicon dioxide to obtain the adhesive composite wear-resistant super-hydrophobic coating.

In the present invention, the rigid substrate is glass; the adhesive is one or more of silicone rubber, water-based paint, water-based non-setting adhesive, 502 glue and epoxy resin AB glue.

In the invention, tetraethyl orthosilicate, ammonia water and hexamethyldisilazane are used as raw materials to prepare nano silicon dioxide; specifically, tetraethyl orthosilicate, ammonia water and hexamethyldisilazane are used as raw materials to prepare sol, and then the sol is dried and ground to obtain the nano silicon dioxide.

According to the invention, the adhesive composite wear-resistant super-hydrophobic coating is positioned on the rigid substrate and forms a super-hydrophobic wear-resistant material with the rigid substrate.

The invention discloses an application of an adhesive and nano silicon dioxide in preparation of a rigid super-hydrophobic wear-resistant material; or the adhesive is compounded with the wear-resistant super-hydrophobic coating and is applied to the preparation of the rigid super-hydrophobic wear-resistant material. The rigid super-hydrophobic wear-resistant material has a self-cleaning function.

The application field of the super-hydrophobic coating determines that the hydrophobic layer is exposed to severe natural environments for a long time, such as ice and snow coverage in severe cold winter, water flow impact in heavy rain weather, wind blowing and sun drying in dry weather, scraping and squeezing in various forms and the like, and if the mechanical strength and the material stability of the super-hydrophobic coating cannot be effectively improved so as to prolong the service life of the super-hydrophobic coating, the super-hydrophobic coating is inevitably prevented from playing a role in practical application. Meanwhile, the preparation of the hydrophobic coating involves the use of various chemical reagents such as fluorine-containing compounds, organic solvents and the like, so that the cost is high, and once the loss and the loss are caused, the environmental and life safety are easily threatened. The abrasion resistance of the coating is improved, and the optimization of the preparation process is a key problem which needs to be solved in the field of super-hydrophobicity. According to the invention, Hexamethyldisilazane (HMDS) is introduced in the hydrolytic polycondensation reaction process, and a low-surface-energy methyl group is grafted onto SiO2 particles, so that a large amount of super-hydrophobic coating can be prepared, however, the super-hydrophobic coating formed by inorganic particles is low in mechanical strength and difficult to apply. The invention relates to a method for preparing a high-temperature-resistant ceramic material. The adhesive is used as an auxiliary coating, the adhesive force and the structural stability of the hydrophobic material and the substrate can be effectively improved by bonding the hydrophobic SiO2 and the substrate material, the operation is simple, the device condition is not limited, the adhesive is a very common chemical product, the preparation and production technology is already complete, the adhesive does not contain organic solvent, is safe and environment-friendly, has controllable curing speed and certain adhesive force, and has mature process, low cost, wide application and no pollution or toxic effect.

Drawings

FIG. 1 is a schematic diagram of an experimental flow for preparing the abrasion resistance of an adhesive composite coating;

fig. 2 is a physical representation and SEM image of hydrophobic coatings (comparative) prepared with different adhesives: (a, g) a sol; (b, h) glue 502; (c, i) a water-based paint; (d, j) adhesive sticker; (e, k) epoxy AB glue; (f, l) PDMS;

FIG. 3 shows mechanical strength (a) sandpaper abrasion of different adhesive composite coatings (comparative examples); (b) tearing and sticking the adhesive tape;

fig. 4 is a picture of a polished object and a corresponding SEM image of different adhesive coatings (comparative examples): (a, a 1) glue 502; (b, b 1) water-based paint; (c, c 1) self-adhesive sticker; (d, d 1) epoxy AB glue; (e, e 1) 184 silicone rubber;

fig. 5 is a drawing of a taped object of different adhesive coatings (comparative examples) and the corresponding SEM images: (f, f 1) glue 502; (g, g 1) water-based paint; (h, h 1) self-adhesive sticker; (i, i 1) epoxy AB glue; (j, j 1) 184 silicone rubber;

fig. 6 shows the mechanical strength of different adhesive composite coatings: (a) abrasive paper is worn; (b) tearing and sticking the adhesive tape;

FIG. 7 is a diagram of a composite coating with improved wear resistance: (a) water paint; (b) adhesive sticker; (c) epoxy resin AB glue; (d) 184 silicon rubber;

FIG. 8 is a diagram of different composite coatings after sanding (a-g) and tearing and adhering (b-h) with sand paper: (a, b) a water-based paint; (c, d) adhesive sticker; (e, f) epoxy AB glue; (g, h) 184 silicone rubber;

fig. 9 is a diagram of (a) a water-based paint composite coating sandpaper after being polished 50 (last) times and 60 (next) times; (b) SEM image of water paint composite coating; (c) SEM images of the composite coating of the epoxy resin AB glue and the 502 glue;

FIG. 10 shows the contact angle (a) of the composite coating after heat treatment and the actual graph: (b) AB glue; (c) PDMS; (d) sol; (e) 502 glue; (f) adhesive sticker; (g) water paint;

FIG. 11 shows the change in hydrophobicity of the adhesive composite coating in an acid-base solution immersion test;

FIG. 12 is a self-cleaning process of a water-based paint composite super-hydrophobic coating;

FIG. 13 is a process of freezing water drops on the surface of the water paint composite coating;

FIG. 14 is the change in hydrophobicity in the coating icing-deicing test: a contact angle curve is arranged above the contact angle curve; the lower part is a rolling angle curve.

Detailed Description

The raw materials involved in the invention are all existing products. 184 silicon rubber (PDMS) is Dow Corning (SYLGARD 184), a two-component kit product consisting of liquid components comprises basic components and a curing agent, wherein the basic components and the curing agent are completely mixed according to a ratio of 10:1 when in use; the water paint is a Libang Baodeli water mixed paint; waterborne Stickers (SINWE) are from Shenzhen Xinwei electronic materials, Inc.; 502 glue (7144) from force group; epoxy AB glue (JL 510) from polyester industry available in eastern guan; the desktop spin coater is KW-4A/5; lance RG-3L Atnst rock field machinery (Shanghai) Co., Ltd.

Sample testing characterization methods:

and (3) wettability testing: the method comprises the following steps of (1) representing the wetting performance of a sample by adopting a JCY-4 type contact angle measuring instrument, wherein the wetting performance comprises a dynamic contact angle and a static contact angle, the testing environment is room temperature, and the amount of water drops dripped each time is 4 mu L;

and (3) surface topography test: the surface morphology of the sample was observed using a Sigma 300 scanning electron microscope of zeiss, germany, with a test acceleration voltage of 3 KV. And carrying out gold spraying treatment on the surface of the sample before testing. The current of each sample during the gold spraying treatment is 20 mA, and the gold spraying time is 40 s;

and (3) transmittance test: measuring the transmittance of a sample by adopting a UV-3600 ultraviolet-visible light photometer of Shimadzu corporation, wherein the test wavelength range is 300-800 nm;

and (3) testing mechanical stability: and respectively adopting modes of abrasive paper abrasion and adhesive tape tearing and adhering to test and analyze the mechanical stability of the sample. When the abrasion test of the sand paper is carried out, the super-hydrophobic surface is tightly pressed on the sand paper by weights with different masses and is slowly pushed for 10cm at the speed of 1cm/s, the grinding is carried out in one cycle, and the sample is rotated for 90 degrees clockwise every 10 times of grinding and then the test is carried out. In the tape peel adhesion test, a special test tape of 3M company was used to stick it on a superhydrophobic surface, then pressed with a 500 g weight for 5 min to ensure sufficient adhesive strength of the tape, and the tape was slowly peeled off the surface of the sample. And observing and recording the change conditions of the contact angle and the rolling angle of the sample in the test process to represent the strength of the super-hydrophobic surface structure and the adhesion of the super-hydrophobic surface structure to the substrate. If the contact angle of the sample is reduced to 150 degrees or the rolling angle is increased to 8 degrees or the coating is completely worn, stopping the experiment and recording the times;

and (3) testing thermal stability: placing the sample in a tube furnace to be baked at different temperatures for 100 min, observing the change of the macro morphology and the hydrophobicity of the baked sample, wherein the initial temperature is 100 ℃, the temperature interval is 100 ℃, and the test temperature range is 100-500 ℃;

and (3) testing chemical stability: preparing a solution with the pH value of 1-14, completely immersing a sample in the solution, recording the contact angle of the sample every 24 hours, observing the change of the microstructure of the sample, and representing the corrosion resistance of the sample to an acid-base solution;

self-cleaning performance test: uniformly mixing soil, lime and gravel according to the mass ratio of 1:1:1 to serve as a pollution source for testing, spreading pollutants on the surface of a sample, and slowly injecting water drops by using an injector to enable the water drops to take away the pollutants on the surface of the sample;

and (3) frost resistance test: placing the sample in a freezing chamber, setting the temperature to be-15 ℃, dripping about 500 mu L of water drops, observing the appearance change of the water drops in different time periods in the icing process, beating the appearance of the water drops every 200 s, and testing the icing delaying performance of the sample. Dropping a plurality of water drops on the surface of the sample, putting the sample into a freezing chamber, wherein the water content of the water drops is about 50 mu L, taking out the sample after the water drops are completely frozen, directly removing the water drops, and measuring the change of the hydrophobicity of the sample so as to represent the mechanical stability of the icing-deicing process of the sample.

Synthesis example

Adding 40 ml of ethanol, 1 ml of deionized water and 5ml of tetraethyl orthosilicate into a beaker, continuously stirring, adding 1 ml of ammonia water (27%) after 30 min, continuously stirring for 30 min, finally adding 3 ml of hexamethyldisilazane, continuously stirring for 4h, aging for one week to obtain stable silica sol, and carrying out the whole process at room temperature; and then, conventionally drying and grinding the silica sol to obtain the nano silica.

The following experimental samples all use soda-lime glass substrates as substrates, before use, the glass is cut into 2.5cm × 2.5cm size, and is respectively treated with acetone, ethanol and deionized water by ultrasonic treatment and dried by nitrogen blow-drying to be cleaned.

Examples

Coating a layer of adhesive on a glass substrate at room temperature, coating nano silicon dioxide (5 mL of sol dried) on the adhesive, covering a glass sheet, putting a 1Kg weight, and pressurizing and curing to obtain the adhesive composite wear-resistant super-hydrophobic coating, wherein the contact angle is 161 degrees, and the rolling angle is less than 3 degrees. The preparation process is schematically shown in figure 1, and the curing time is set according to the specification of the adhesive.

The conditions for effectively improving the wear resistance of the invention are as follows: 1. the adhesive has strong adhesive effect on the material; 2. the adhesive material has high abrasion resistance by combining with the nano silicon dioxide; 3. the adhesive can be mixed with the nano particles to act as a skeleton.

Comparative example

Taking 5ml of silica sol, adjusting the spraying distance (25 cm) and the spraying pressure (0.4 MPa), directly spraying the silica sol on a glass substrate (without an adhesive), standing at room temperature, and obtaining a coating after a sample is completely cured, wherein the contact angle is 165 degrees and the rolling angle is less than 3 degrees.

Comparative example

Coating a layer of adhesive on a glass substrate, then taking 5ml of silica sol, adjusting the spraying distance (25 cm) and the spraying pressure (0.4 MPa), directly spraying the sol on the adhesive on the substrate, standing at room temperature, and obtaining a coating when a sample is completely cured, wherein the contact angle is 160 degrees and the rolling angle is less than 5 degrees.

As shown in fig. 2, the microscopic morphology of the sample is further tested and analyzed by a scanning electron microscope, and it can be seen that the surface morphologies of the composite superhydrophobic coatings prepared from different adhesives are similar, and the hydrophobically modified nanoparticles completely cover the surface of the adhesive coating. Due to different materials of different adhesives, the change response of the surface microstructure in the process of compounding with the nanoparticles has a certain difference, which is mainly reflected in that micron-scale pits exist on the surface of the water paint or the 502 glue (fig. 2 (h, i)), the evenness of the surface of the original sol coating is lost, and in comparison, the surface appearance of the epoxy resin AB glue and PDMS composite coating is closer to that of the original sol coating (a comparison example) (fig. 2 (k, l)). Although the selected adhesives are completely transparent, the thickness of the composite coating is increased, the nano particles are embedded into the coating, the scattering is intensified, and the transparency is reduced in different degrees.

Common characterization means of the wear resistance of the super-hydrophobic coating include water flow impact, gravel impact, finger polishing, abrasive paper abrasion and the like. Experiments show that the slight abrasion has no obvious influence on the hydrophobicity of the coating, the abrasion strength is increased (the weight is 500 g), the coating is torn and stuck by an adhesive tape, and the damage degree of the coating is gradually serious. The original sol coating (comparative example) is not wear-resistant, and obvious nanoparticle shedding can occur after three times of polishing or gluing; as can be seen from fig. 3, 4 and 5, the semitransparent superhydrophobic coating prepared by the sol direct spraying method (comparative example) cannot effectively withstand the high-strength external force damage (500 g weight polishing), and the improvement of the mechanical strength of the coating is limited.

The mechanical stability can be effectively improved by adopting the pressure curing of the silicon dioxide powder, as shown in fig. 6, 7 and 8, and the most part of the coating still presents white color by combining the appearance graph of the coating after the abrasion test, which shows that SiO is₂The particles and the adhesive are effectively bonded and mixed, so that the coating can maintain certain hydrophobicity before being completely ground. Different adhesives have certain difference in the aspect of improving the wear resistance of the coating, after the nano particles and the adhesives are fully mixed, the original hydrophobicity of the coating can be well maintained before the coating completely falls off in the wear process, and after the PDMS composite coating is subjected to a peeling test for 50 times, although part of the area is seriously damaged, the surface can still enable water drops to easily roll down, and the rolling angle is formed<8 degrees. It is observed in the abrasion process that the hydrophobicity of the water-based paint composite coating is not obviously changed, although the coating is inevitably damaged to a certain degree, the remained coating always has better hydrophobic capability until the coating is completely worn out, and as can be seen in (b) (c) of figure 9, the surface of the water-based paint coating has a concave structure,the nano particles are filled and gathered in the coating in a large amount, the adhesive nano particles which are easy to cure and hard in material are easy to expose and accumulate on the outer surface of the coating, the water-based paint is easy to combine with the nano particles, and the film formed after curing has balanced flexibility and hardness. When the hydrophobic nano particles are fully embedded into the water-based paint film layer, the coating is in a fully hydrophobic state from the surface to the inside, so that the wear resistance is stably and effectively improved.

As shown in fig. 10, after different composite coatings are heated in an environment of 500 ℃ for 100 min, the hydrophobicity of the different composite coatings is affected to different degrees, wherein the coatings made of the non-setting adhesive, the water-based paint and the 502 glue are less affected, the contact angle is about 155 degrees, and the coatings show higher thermal stability, while the coatings made of the sol (a control group, i.e. containing no adhesive), the epoxy AB glue and the PDMS are greatly affected by high temperature, and particularly the PDMS coatings completely lose the superhydrophobicity. It is worth noting that the hydrophobic layer prepared by reducing the surface energy by the method of dip coating or depositing the HMDS after the micro-nano rough structure is prepared, cannot bear the high temperature of 500 ℃, and the contact angle of the hydrophobic coating formed by the sol prepared by the HMDS modification is reduced to 145 ℃ after the hydrophobic coating is subjected to heat treatment. FIG. 11 is a graph for analyzing the change of contact angle of the coating in the process of soaking in acid-base solution, and the adhesive with relatively stable component property in hydrophobic SiO₂The composite coating layer is accumulated on the surface layer to block the influence of full contact of corrosive liquid and colloid, and the formed composite coating layer has stronger corrosion resistance.

The composite super-hydrophobic coating prepared by other adhesives has similarity in self-cleaning performance. Taking a water paint coating as an example, the self-cleaning performance of the composite coating is analyzed. As shown in fig. 12, it can be seen that the water paint composite coating not only has good self-cleaning property, but also has high cleaning efficiency, and only a small amount of water drops are needed to take away dust pollutants accumulated on the surface of the coating, so that compared with the fire-baked PDMS super-hydrophobic coating in the previous application, the water paint composite coating has better self-cleaning property. This is because the self-cleaning property of the coating depends not only on the hydrophobicity of the surface, but also on the adhesion of dust to the surface, and experiments show that the modified SiO₂The formed super-hydrophobic surface is more difficult to be adhered by dust, and is easier to fall off the surface of the substrate along with water beads,the self-cleaning performance is stronger.

Fig. 13 and 14 show that the composite coating has icing delaying performance and freezing damage resistance in a low-temperature environment, and each adhesive composite coating has certain icing delaying capacity, so that the effective icing delaying time is about 600 s. In the icing-deicing test, coatings prepared from different adhesives show certain differences. During the first 30 cycles of the test, there was only a slight change in the hydrophobicity of the coating due to the SiO of the coating surface₂The distribution is concentrated, the influence of a small amount of nano particles taken away after the water drops are frozen on the roughness of the coating is very limited, and the higher roughness of the surface of the coating can effectively reduce the adhesive force between the ice drops and the coating. However, with the increase of the cycle number, the hydrophobicity of the self-adhesive coating is relatively fast to decrease, and other adhesives such as epoxy resin, PDMS and the like show good stability due to strong bonding effect and a large amount of hydrophobic nano particles embedded in the surface layer part.

Research shows that the 502 glue and the nano particles form a hard brittle film after being mixed, the hard brittle film has extremely poor toughness and is easy to break, the film layer directly falls off from a substrate due to the poor adhesion of the 502 glue and glass, the wear resistance and the adhesive tape tearing resistance are poor, the damage force generated when ice beads are separated from the substrate cannot be borne completely, and the coating is rapidly cracked. The adhesive sticker can form a soft film, the preparation is simpler and more convenient, and even the hydrophobic silicon dioxide powder can be directly coated on the adhesive sticker to realize the preparation of the super-hydrophobic coating at any time and any place, but the surface of a hydrophobic layer formed by mixing the nano particles and the nano particles is large in macroscopic roughness and extremely uneven. The film formed by the water paint is more uniform and flat. In the experiment, the water paint, the epoxy resin AB glue and the PDMS are easy to crack on the surface of the coating in the process of compounding with the nano particles, which is probably caused by the fact that SiO is attached to the surface layer part of the coating₂And then the hardened plate is quickly solidified, so that the system is uneven in tension. Generally speaking, the curing speed of the water paint, the epoxy resin AB glue and the PDMS rubber is proper, the bonding range is wide, the material flexibility is strong, and the composite super-hydrophobic coating is more suitable for preparing.

In the examples and comparative examples, as a general knowledge, the glue properties were different and the method of coating on glass was also different, generally speaking, for 502 liquid glue, two drops of the glue were applied on glass, for non-drying glue and epoxy AB glue, a bench spin coater was used to spin coat at 5000 rpm for 30 s, for water paint at 2500 rpm for 15 s, for 184 silicone rubber (PDMS) after adding curing agent, the glue was first spun at 3000 rpm for 30 s and then left to stand for 24h to cure it slightly. This is a conventional technique.

Currently, there are three main approaches to improving the abrasion resistance of super-hydrophobic coatings: the micro-nano hierarchical structure is constructed by adopting a self-repairing material, introducing an auxiliary reagent and designing. The self-repairing material generally repairs chemical compositions through migration movement of low-surface-energy substances embedded in a coating, or completes repair and even reconstruction of a micro-nano structure through expansion and flowing processes of materials near a damaged area. Due to the high preparation requirements of self-repairing materials, the dependence of the repairing process on specific conditions and the limited repairing efficiency and performance, improvements are still continuously sought. Compared with the prior art, the method for introducing the auxiliary reagent and preparing the micro-nano hierarchical structure is more effective. The auxiliary agent is generally a silane coupling agent or a resin adhesive, and the agent can consolidate the structure of the nano particles, improve the adhesive force between the super-hydrophobic material and the substrate and effectively enhance the wear resistance of the coating. The rough structure with the micro-nano hierarchical scale is prepared on the substrate, the hydrophobic nano particles can be effectively protected from being worn by external force by the high-strength micro-scale structure, but the design and preparation of the complex microstructure have a larger technical bottleneck and certain damage to the substrate. The invention relates to hydrophobic SiO modified by HMDS₂The nano particles and the adhesive are directly bonded and compounded to prepare the wear-resistant super-hydrophobic composite coating, and research and analysis show that the product has strong bonding force and high material flexibility, and can effectively improve SiO₂The wear resistance of the super-hydrophobic coating is effectively improved, the super-hydrophobic coating has high chemical stability, self-cleaning property and frost resistance, is simple to operate, safe and environment-friendly, and is expected to be applied to daily life.