阅读说明：本技术 一种防臭袜的制备工艺 (Preparation process of deodorant socks ) 是由 李仲贵 于 2021-02-07 设计创作，主要内容包括：本申请涉及袜子领域,更具体地说,它涉及一种防臭袜的制备工艺。一种防臭袜的制备工艺,具体包括以下步骤：S1：纱线的选择；S2：染色防臭处理,将制成的纱线经过防臭剂处理,所述防臭剂包括以下重量份的原料制成：木犀草素10-12份；交联剂70-90份；分散剂10-20份；β-环糊精80-100份；壳聚糖3-5份；甲基纤维素4-6份；S3：染色,将经过染色的纱线进行染色；S4：袜子织造；S5：缝头处理；S6：定型处理,将经过步骤S5处理的袜子通过整理剂定型处理；S7：配对包装。本申请的袜子制备工艺可减少香味与臭气混合后出现更加难闻的味道的情况发生。(The application relates to the field of socks, in particular to a preparation process of deodorant socks. A preparation process of deodorant socks specifically comprises the following steps: s1: selecting yarns; s2: dyeing and deodorizing, namely treating the prepared yarn by using an odor inhibitor, wherein the odor inhibitor is prepared from the following raw materials in parts by weight: 10-12 parts of luteolin; 70-90 parts of a cross-linking agent; 10-20 parts of a dispersing agent; 80-100 parts of beta-cyclodextrin; 3-5 parts of chitosan; 4-6 parts of methyl cellulose; s3: dyeing, namely dyeing the dyed yarns; s4: weaving socks; s5: sewing the head; s6: shaping, namely shaping the socks processed in the step S5 by using a finishing agent; s7: and (6) matching and packaging. The sock preparation process can reduce the occurrence of more unpleasant smell after the fragrance and the odor are mixed.)

1. The preparation process of the deodorant socks is characterized by comprising the following steps:

s1: selecting yarns;

s2: dyeing and deodorizing, namely treating the prepared yarn by using an odor inhibitor, wherein the odor inhibitor is prepared from the following raw materials in parts by weight:

s3: dyeing, namely dyeing the dyed yarns;

s4: weaving socks;

s5: sewing the head;

s6: shaping, namely shaping the socks processed in the step S5 by using a finishing agent;

s7: and (6) matching and packaging.

2. The preparation process of the deodorant sock according to claim 1, characterized in that: the cross-linking agent is prepared from the following raw materials in percentage by weight:

5-7% of tannic acid;

24-35% of butane tetracarboxylic acid;

60-70% of citric acid.

3. The preparation process of the deodorant sock according to claim 2, characterized in that: the dispersing agent is prepared from the following raw materials in percentage by weight:

4. the preparation process of the deodorant sock according to claim 3, wherein the preparation process comprises the following steps: the deodorant is prepared by the following steps:

step A: stirring luteolin, beta-cyclodextrin, chitosan, methyl cellulose, sodium hypophosphite, sodium bicarbonate and sodium carbonate for 5-10min under the condition that the rotating speed is 800-;

and B: stirring tannic acid, butanetetracarboxylic acid and citric acid for 5-10min under the condition that the rotation speed is 100-200r/min to obtain a deodorization agent B;

and C: acetic acid is stored separately as deodorant C agent.

5. The preparation process of the deodorant sock according to claim 1, characterized in that: the yarn in the step S1 is coffee fiber.

6. The preparation process of the deodorant sock according to claim 1, characterized in that: the finishing agent used in the step S6 comprises a finishing agent A, and the finishing agent A comprises the following raw materials in parts by weight:

7. the manufacturing process of the deodorant sock according to claim 6, characterized in that: the finishing agent A is prepared from the following raw materials in parts by weight:

5-8 parts of isomeric tridecyl alcohol ether;

1-2 parts of ethylene glycol monobutyl ether.

8. The manufacturing process of the deodorant sock according to claim 6, characterized in that: the finishing agent A is prepared by the following steps:

step a: stirring amino modified silicone oil 4703, dodecyl trimethyl ammonium chloride, isomeric tridecyl alcohol and ethylene glycol monobutyl ether for 10-15min under the condition that the rotation speed is 10000-20000r/min to obtain a mixture a;

step b: adding the amino modified silicone oil 4708 and the amino modified silicone oil RC into the mixture a, and stirring for 10-15min under the condition that the rotation speed is 10000-20000r/min to obtain a mixture b, namely the finishing agent A.

9. The preparation process of the deodorant sock according to claim 1, characterized in that: the finishing agent used in the step S6 further comprises a finishing agent B, and the finishing agent B comprises the following raw materials in parts by weight:

10. the preparation process of the deodorant sock according to claim 1, characterized in that: and in the step S3, dispersing the dye into water to obtain a dye solution, wherein the mass fraction of the dye is 2-3% (omf), the bath ratio is 1: (50-70); adding glacial acetic acid 0.3-0.5g/L and anhydrous sodium sulfate 2.5-4g/L, and dyeing at 55-65 deg.C for 30-50 min.

Technical Field

The application relates to the field of socks, in particular to a preparation process of deodorant socks.

Background

The sock is a dress article worn on the foot and used for protecting the foot. In an extreme environment, socks can not be replaced in time, and when the same pair of socks are worn for a long time, feet and the socks can generate odor, the root cause of the odor and the odor is that organic matters in body fluid are decomposed in the reproduction process of anaerobic bacteria, the anaerobic bacteria take the organic matters in the body fluid as a nutrient source and reproduce a large number of the organic matters under the anaerobic condition to decompose the organic matters into organic amine, aldehyde and sulfide with odor.

The Chinese patent with application publication number CN101314915A discloses a fabric deodorization treating fluid and application thereof, wherein each 1 liter of the fabric deodorization treating fluid comprises the following components: nano TiO 2₂Or 0.5-20 g of tourmaline; 1-5 g of sodium dodecyl sulfate; 0.5-3 g of wetting agent JFC; 50-70 g of polyacrylate microemulsion with the solid content of 20-40%; 1-20 g of essence microcapsule suspension with solid content of 10-30%; make up to 1L of deionized water.

With respect to the related art in the above, the inventors consider that: the essence microcapsule suspension is used in the sock treatment process, and in the sock specific use process, the odor and the fragrance are mixed easily, so that more unpleasant taste can be generated.

Disclosure of Invention

In order to reduce the occurrence of more unpleasant smell after the fragrance and the odor are mixed, the application provides a preparation process of the deodorant socks.

The preparation process of the deodorant socks adopts the following technical scheme:

a preparation process of deodorant socks specifically comprises the following steps:

s1: selecting yarns;

s2: dyeing and deodorizing, namely treating the prepared yarn by using an odor inhibitor, wherein the odor inhibitor is prepared from the following raw materials in parts by weight:

s3: dyeing, namely dyeing the dyed yarns;

s4: weaving socks;

s5: sewing the head;

s6: shaping, namely shaping the socks processed in the step S5 by using a finishing agent;

s7: and (6) matching and packaging.

By adopting the technical scheme, when the sock is subjected to deodorization treatment, the essence microcapsule suspension is not used any more, and the sock is subjected to deodorization treatment, so that unnecessary essence smell does not exist on the sock any more, the occurrence of the condition of more unpleasant smell after the mixture of the fragrance and the odor is reduced, the odor and the odor on the sock are reduced by adsorbing the odor and the odor by using the beta-cyclodextrin, and the stability of the deodorant in the deodorization treatment process can be improved to a certain extent by the beta-cyclodextrin, so that the yarn can be uniformly contacted with the deodorant.

Luteolin has a good antibacterial effect, most of peculiar smells on socks are from decomposition of protein and fat in sweat by microorganisms, so that the luteolin reduces the peculiar smells on the socks to a certain extent, and the luteolin, yarn fibers and beta-cyclodextrin have good connection strength, so that the sock has good washing fastness.

The chitosan has a good antibacterial effect, can reduce the generation of peculiar smell on the socks to a certain extent, and has a good connection effect with the beta-cyclodextrin.

The methyl cellulose has a certain antibacterial effect, can reduce the generation of peculiar smell on the socks to a certain extent, and can enhance the connection strength of the deodorant and the yarns to a certain extent, so that the sock has better washing fastness.

Preferably, the cross-linking agent is prepared from the following raw materials in percentage by weight:

5-7% of tannic acid;

24-35% of butane tetracarboxylic acid;

60-70% of citric acid.

By adopting the technical scheme, the tannin, the butanetetracarboxylic acid and the citric acid can enable the beta-cyclodextrin, the chitosan and the methylcellulose to be well crosslinked on the yarns, and the washability of the deodorant can be enhanced to a certain degree. Butane tetracarboxylic acid, citric acid and tannic acid act together, so that the yarn has good flexibility, and the yarn can be prevented from being dried and hardened to a certain extent.

Preferably, the dispersing agent is prepared from the following raw materials in percentage by weight:

by adopting the technical scheme, the acetic acid can enhance the connection strength between the beta-cyclodextrin, the chitosan and the methyl cellulose and the yarns to a certain degree, and can react with the sodium bicarbonate and the sodium carbonate to generate carbon dioxide, and the carbon dioxide escapes from the water, so that the deodorant can be more quickly and better dispersed in the water. Sodium hypophosphite is used as a dispersant to help the deodorant disperse well in water.

And the sodium acetate generated by the reaction of the acetic acid, the sodium bicarbonate and the sodium carbonate is a better mordant and has a certain color fixing effect. Meanwhile, sodium acetate can alleviate bad smell to a certain extent. And after the sodium acetate, the methylcellulose and the sodium hypophosphite act together, the growth of microorganisms can be inhibited to a certain degree.

Sodium carbonate also acts as a desiccant during storage, reducing the effect of moisture on the deodorant.

Preferably, the deodorant is prepared by the following steps:

step A: stirring luteolin, beta-cyclodextrin, chitosan, methyl cellulose, sodium hypophosphite, sodium bicarbonate and sodium carbonate for 5-10min under the condition that the rotating speed is 800-;

and B: stirring tannic acid, butanetetracarboxylic acid and citric acid for 5-10min under the condition that the rotation speed is 100-200r/min to obtain a deodorization agent B;

and C: acetic acid is stored separately as deodorant C agent.

By adopting the technical scheme, the odor-resistant A agent is obtained by mixing sodium carbonate, luteolin, beta-cyclodextrin, chitosan, methylcellulose and sodium bicarbonate, the sodium carbonate plays a role of a drying agent, and the influence of moisture on the beta-cyclodextrin, the chitosan, the luteolin and the methylcellulose is reduced in the storage process.

Preferably, the yarn in step S1 is coffee fiber.

By adopting the technical scheme, the yarns used in the step S1 are the coffee fibers, the coffee fibers have certain adsorption effect on odor and peculiar smell, the coffee fibers have certain antibacterial effect, and meanwhile, the coffee fibers and the deodorant have good connection strength, so that the washability of the coffee fibers subjected to deodorization treatment is enhanced to a certain extent.

Preferably, the finishing agent used in step S6 includes a finishing agent a, and the finishing agent a includes the following raw materials in parts by weight:

by adopting the technical scheme, the three amino modified silicone oils are matched for use, so that the used raw materials are fewer, and a better soft finishing effect can be achieved. The dodecyl trimethyl ammonium chloride has good dispersing effect and certain sterilizing and antistatic effects.

Preferably, the finishing agent A is prepared from the following raw materials in parts by weight:

5-8 parts of isomeric tridecyl alcohol ether;

1-2 parts of ethylene glycol monobutyl ether.

By adopting the technical scheme, the dodecyl trimethyl ammonium chloride, the isomeric alcohol tridecyl fatty alcohol and the ethylene glycol monobutyl ether have good synergistic effect, and the three kinds of amino modified silicone oil can be well dispersed in water.

Preferably, the finishing agent A is prepared by the following steps:

step a: stirring amino modified silicone oil 4703, dodecyl trimethyl ammonium chloride, isomeric tridecyl alcohol and ethylene glycol monobutyl ether for 10-15min under the condition that the rotation speed is 10000-20000r/min to obtain a mixture a;

step b: adding the amino modified silicone oil 4708 and the amino modified silicone oil RC into the mixture a, and stirring for 10-15min under the condition that the rotation speed is 10000-20000r/min to obtain a mixture b, namely the finishing agent A.

By adopting the technical scheme, firstly, amino modified silicone oil is mixed with dodecyl trimethyl ammonium chloride, isomeric tridecyl alcohol ether and ethylene glycol monobutyl ether at a high rotating speed, then, amino modified silicone oil 4708 and amino modified silicone oil RC are added into the mixture a, so that the three amino modified silicone oils are better dispersed in isomeric tridecyl alcohol ether, ethylene glycol monobutyl ether and dodecyl trimethyl ammonium chloride, and when the finishing agent A is added into water, the three amino modified silicone oils are better dispersed in water under the action of isomeric tridecyl alcohol ether, ethylene glycol monobutyl ether and dodecyl trimethyl ammonium chloride.

Preferably, the finishing agent used in step S6 further includes a finishing agent B, and the finishing agent B is prepared from the following raw materials in parts by weight:

by adopting the technical scheme, the chitosan quaternary ammonium salt and the chitosan have better antibacterial and antistatic effects under the combined action, and the chitosan quaternary ammonium salt and the sock yarns have better connection strength.

The methylcellulose also has good connection strength with the sock yarns, and the methylcellulose, the chitosan quaternary ammonium salt and the chitosan act together to enable the sock to have a good anti-wrinkle effect.

The dodecyl trimethyl ammonium bromide and the dodecyl trimethyl ammonium chloride have better antistatic and antibacterial effects on the socks together.

The hexadecyl trimethyl ammonium bromide and the nonylphenol polyoxyethylene ether can enable the chitosan quaternary ammonium salt to be well connected to the sock fibers, and enable the chitosan quaternary ammonium salt and the methyl cellulose to be well dispersed in water, so that the sock is uniformly contacted with the chitosan quaternary ammonium salt and the methyl cellulose.

Preferably, in the step S3, the dye is dispersed in water to obtain a dye solution, wherein the mass fraction of the dye is 2-3% (omf), and the bath ratio is 1: (50-70); adding glacial acetic acid 0.3-0.5g/L and anhydrous sodium sulfate 2.5-4g/L, and dyeing at 55-65 deg.C for 30-50 min.

By adopting the technical scheme, the dyeing is carried out in an acid environment, wherein glacial acetic acid can better connect the dye to the limit position of the sock.

In summary, the present application has the following beneficial effects:

1. when the sock is subjected to deodorization treatment, the suspension of the essence microcapsules is not used, only the sock is subjected to deodorization treatment, so that unnecessary essence smell is not existed on the sock, the beta-cyclodextrin is used for adsorbing peculiar smell and odor, the peculiar smell and the odor on the sock are reduced, the stability of the deodorant in the deodorization treatment process can be improved to a certain extent by the beta-cyclodextrin, and yarns can be uniformly contacted with the deodorant. Luteolin has a good antibacterial effect, most of peculiar smells on socks are from decomposition of protein and fat in sweat by microorganisms, so that the luteolin reduces the peculiar smells on the socks to a certain extent, and the luteolin, yarn fibers and beta-cyclodextrin have good connection strength, so that the sock has good washing fastness. The chitosan has a good antibacterial effect, can reduce the generation of peculiar smell on the socks to a certain extent, and has a good connection effect with the beta-cyclodextrin. The methyl cellulose has a certain antibacterial effect, can reduce the generation of peculiar smell on the socks to a certain extent, and can enhance the connection strength of the deodorant and the yarns to a certain extent, so that the sock has better washing fastness.

2. Tannin, butanetetracarboxylic acid and citric acid can enable beta-cyclodextrin, chitosan and methyl cellulose to be well crosslinked on yarns, and the washfastness of the deodorant can be enhanced to a certain extent. Butane tetracarboxylic acid, citric acid and tannic acid act together, so that the yarn has good flexibility, and the yarn can be prevented from being dried and hardened to a certain extent.

3. The acetic acid can enhance the connection strength between the beta-cyclodextrin, the chitosan and the methyl cellulose and the yarn to a certain degree, and can react with the sodium bicarbonate and the sodium carbonate to generate carbon dioxide, and the carbon dioxide escapes from the water, so that the deodorant can be dispersed in the water more quickly and better. Sodium hypophosphite is used as a dispersant to help the deodorant disperse well in water. And the sodium acetate generated by the reaction of the acetic acid, the sodium bicarbonate and the sodium carbonate is a better mordant and has a certain color fixing effect. Meanwhile, sodium acetate can alleviate bad smell to a certain extent. And after the sodium acetate, the methylcellulose and the sodium hypophosphite act together, the growth of microorganisms can be inhibited to a certain degree.

Detailed Description

Source of raw materials

The present application will be described in further detail with reference to examples.

Preparation example of deodorant

Preparation examples 1 to 3

The deodorant is prepared by the following steps:

step A: the odor-resistant agent A is prepared by stirring luteolin, beta-cyclodextrin, chitosan, methylcellulose, dispersant (sodium hypophosphite) and cross-linking agent (butanetetracarboxylic acid) at 900r/min for 10 min.

Wherein the added parts by weight of the luteolin, the beta-cyclodextrin, the chitosan, the methyl cellulose, the dispersant and the cross-linking agent are shown in the following table 1:

TABLE 1

Preparation examples 4 to 6

Preparation examples 4 to 6 differ from preparation example 3 in that: the crosslinking agents used in preparation examples 4 to 6 were different from the crosslinking agent used in preparation example 3.

The deodorant is prepared by the following steps:

step A: stirring luteolin, beta-cyclodextrin, chitosan, methylcellulose and dispersant (sodium hypophosphite) at 900r/min for 10min to obtain deodorant A;

and B: stirring tannic acid, butanetetracarboxylic acid and citric acid at the rotation speed of 200r/min for 10min to obtain deodorizing B agent; the deodorant A and the deodorant B jointly form the deodorant.

Wherein, the weight percentages of the tannic acid, the butane tetracarboxylic acid and the citric acid are shown in the following table 2:

TABLE 2

Preparation examples 7 to 9

Preparation examples 7 to 9 differ from preparation example 6 in that: the dispersants used in preparation examples 7 to 9 were different from the dispersant used in preparation example 6.

The deodorant is prepared by the following steps:

step A: stirring luteolin, beta-cyclodextrin, chitosan, methyl cellulose, sodium hypophosphite, sodium bicarbonate and sodium carbonate at the rotation speed of 900r/min for 10min to obtain deodorant A;

and B: stirring tannic acid, butanetetracarboxylic acid and citric acid at the rotation speed of 200r/min for 10min to obtain deodorizing B agent;

and C: storing acetic acid as deodorant C agent; deodorant A, deodorant B and deodorant C together constitute deodorant.

Wherein, the weight percentages of the sodium hypophosphite, the sodium bicarbonate, the sodium carbonate and the acetic acid are shown in the table 3:

TABLE 3

Preparation example 10

Preparation 10 differs from preparation 9 in that: acetic acid was not added in preparation example 10.

Preparation example 11

Preparation 11 differs from preparation 9 in that: in preparation example 11, butane tetracarboxylic acid and tannic acid were replaced with citric acid in equal parts by weight.

Preparation example 12

Preparation 12 differs from preparation 9 in that: in preparation example 12, butanetetracarboxylic acid and citric acid were replaced with equal amounts of tannic acid.

Preparation example 13

Preparation 13 differs from preparation 9 in that: luteolin was not added in preparation example 13.

Preparation example 14

Preparation 14 differs from preparation 9 in that: in preparation example 14, chitosan was replaced with an equal weight part of β -cyclodextrin.

Preparation example 15

Preparation 15 differs from preparation 9 in that: in preparation example 15 methylcellulose was replaced with an equal amount of beta-cyclodextrin.

Preparation of finishing agent

Preparation examples 1 to 3

The finishing agent is prepared by the following steps:

step a: stirring amino modified silicone oil 4703 and dodecyl trimethyl ammonium chloride at rotation speed of 20000r/min for 10min to obtain mixture a;

step b: adding the amino modified silicone oil 4708 and the amino modified silicone oil RC into the mixture a, and stirring 10 at the rotation speed of 20000r/min to obtain a mixture b, namely a finishing agent A, which is the finishing agent.

Wherein, the added parts by weight of the amino modified silicone oil 4703, the amino modified silicone oil 4708, the amino modified silicone oil RC and the dodecyl trimethyl ammonium chloride are shown in the following table 4:

TABLE 4

Preparation examples 4 to 6

Preparation examples 4 to 6 differ from preparation example 3 in that: preparation examples 4 to 6 added isomeric tridecyl alcohol ethers and ethylene glycol monobutyl ether.

The finishing agent is prepared by the following steps:

step a: stirring amino modified silicone oil 4703, dodecyl trimethyl ammonium chloride, isomeric tridecyl alcohol and ethylene glycol monobutyl ether for 10min at the rotation speed of 20000r/min to obtain a mixture a;

step b: adding the amino modified silicone oil 4708 and the amino modified silicone oil RC into the mixture a, and stirring for 10min at the rotation speed of 20000r/min to obtain a mixture b, namely a finishing agent A, and the obtained finishing agent A is the finishing agent.

Wherein, the addition parts by weight of the isomeric tridecyl alcohol ether and the ethylene glycol monobutyl ether are shown in the table 5:

TABLE 5

Preparation examples 7 to 9

Preparation examples 7 to 9 differ from preparation example 6 in that: preparation examples 7 to 9 added chitosan quaternary ammonium salt, methyl cellulose, cetyltrimethyl ammonium bromide and nonylphenol polyoxyethylene ether.

The finishing agent is prepared by the following steps:

step a: stirring amino modified silicone oil 4703, dodecyl trimethyl ammonium chloride, isomeric tridecyl alcohol and ethylene glycol monobutyl ether for 10min at the rotation speed of 20000r/min to obtain a mixture a;

step b: adding the amino modified silicone oil 4708 and the amino modified silicone oil RC into the mixture a, and stirring for 10min at the rotation speed of 20000r/min to obtain a mixture b, namely a finishing agent A, and obtaining a finishing agent A;

step c: stirring chitosan sodium salt, methyl cellulose, cetyl trimethyl ammonium bromide and nonylphenol polyoxyethylene ether for 10min at the rotating speed of 800r/min to obtain a finishing agent B; the finishing agent A and the finishing agent B form the finishing agent.

Wherein, the added parts by weight of the chitosan quaternary ammonium salt, the methyl cellulose, the hexadecyl trimethyl ammonium bromide and the nonylphenol polyoxyethylene ether are shown in the following table 6:

TABLE 6

Preparation example 10:

preparation 10 differs from preparation 9 in that: in preparation example 10, amino-modified silicone oil 4703 and amino-modified silicone oil 4708 were replaced with an equal part by weight of amino-modified silicone oil RC.

Preparation example 11:

preparation 11 differs from preparation 9 in that: in preparation example 11, amino-modified silicone oil 4703 and amino-modified silicone oil RC were replaced with an equal part by weight of amino-modified silicone oil 4708.

Preparation example 12:

preparation 12 differs from preparation 9 in that: in preparation example 12, amino-modified silicone oil 4708 and amino-modified silicone oil RC were replaced with an equal part by weight of amino-modified silicone oil 4703.

Preparation example 13:

preparation 13 differs from preparation 9 in that: in preparation example 13, the isomeric tridecyl alcohol ether was replaced with an equal part by weight of ethylene glycol monobutyl ether.

Preparation example 14:

preparation 14 differs from preparation 9 in that: in preparation example 14, ethylene glycol monobutyl ether was replaced with an equal part by weight of the isomeric tridecyl alcohol ether.

Preparation example 15:

preparation 15 differs from preparation 9 in that: in preparation example 15, the quaternary ammonium salt of chitosan was replaced with chitosan in an equal weight part.

Preparation example 16:

preparation 16 differs from preparation 9 in that: in preparation example 16, methylcellulose was replaced with an equal part by weight of chitosan quaternary ammonium salt.

Preparation example 17:

preparation 17 differs from preparation 9 in that: in preparation example 17 cetyltrimethylammonium bromide was replaced with an equal part by weight of nonylphenol polyoxyethylene ether.

Preparation example 18:

preparation 18 differs from preparation 9 in that: preparation example 18 nonylphenol polyoxyethylene ether was replaced with an equivalent weight part of cetyltrimethylammonium bromide.

Examples

Examples 1 to 31

S1: selecting yarns, purchasing coffee fibers as raw materials for weaving socks.

S2: dyeing and deodorizing, the yarn was treated with an odor preventive agent, and the odor preventive agent used was as shown in table 7.

When the deodorant used was preparation examples 1 to 3, 5g/L of the deodorant was added directly to water; when the deodorizing agent used was preparation examples 4 to 6, a total of 5g/L of the deodorizing agent was added to water, wherein deodorizing agent A was added first and deodorizing agent B was added; when the deodorizing agents used were preparation examples 7 to 15, a total of 5g/L of the deodorizing agents were added to water, wherein deodorizing agent A was added first, deodorizing agent C was added, and deodorizing agent B was added.

S3: and dyeing, namely dyeing the dyed yarns, and dispersing the dye in water to obtain a dye solution, wherein the dye mass fraction is 3% (omf), and the bath ratio is 1: 70; then 0.5g/L glacial acetic acid and 4g/L anhydrous sodium sulphate are added into the dye solution, and dyeing is carried out for 30min at the dyeing temperature of 65 ℃.

S4: and (5) weaving the socks.

S5: and (4) performing head sewing treatment, namely performing head sewing treatment on the socks.

S6: shaping, namely shaping the socks processed in the step S5 by using a finishing agent, and adding 10g/L of finishing agent into water when the used finishing agent is the preparation examples 1-6; when the finishing agents used are preparation examples 7 to 18, after water is added into one water tank, 10g/L of finishing agent A is added into the water, water is added into the other water tank, and 8g/L of finishing agent B is added into the water; after being treated by the agent A, the socks are washed once, then treated by the agent B, and finally shaped by a shaping machine.

S7: and (6) matching and packaging.

TABLE 7

Examples	Preparation example of deodorant	FinishingPreparation examples of the agent
			Example 1	Preparation example 1	Preparation example 9
Example 2	Preparation example 2	Preparation example 9
			Example 3	Preparation example 3	Preparation example 9
Example 4	Preparation example 4	Preparation example 9
			Example 5	Preparation example 5	Preparation example 9
Example 6	Preparation example 6	Preparation example 9
			Example 7	Preparation example 7	Preparation example 9
Example 8	Preparation example 8	Preparation example 9
			Example 9	Preparation example 9	Preparation example 9
Example 10	Preparation example 10	Preparation example 9
			Example 11	Preparation example 11	Preparation example 9
Example 12	Preparation example 12	Preparation example 9
			Example 13	Preparation example 9	Preparation example 1
Example 14	Preparation example 9	Preparation example 2
			Example 15	Preparation example 9	Preparation example 3
Example 16	Preparation example 9	Preparation example 4
			Example 17	Preparation example 9	Preparation example 5
Example 18	Preparation example 9	Preparation example 6
			Example 19	Preparation example 9	Preparation example 7
Example 20	Preparation example 9	Preparation example 8
			Example 21	Preparation example 9	Preparation example 9
Example 22	Preparation example 9	Preparation example 10
			Example 23	Preparation example 9	Preparation example 11
Example 24	Preparation example 9	Preparation example 12
			Example 25	Preparation example 9	Preparation example 13
Example 26	Preparation example 9	Preparation example 14
			Example 27	Preparation example 9	Preparation example 15
Example 28	Preparation example 9	Preparation example 16
			Example 29	Preparation example 9	Preparation example 17
Example 30	Preparation example 9	Preparation example 18

Example 31

The yarn used in example 31 was a polyester yarn.

Comparative example

Comparative example 1

Comparative example 1 differs from example 9 in that: the example of production of the deodorant used in comparative example 1 is example 13.

Comparative example 2

Comparative example 2 differs from example 9 in that: the deodorant agent preparation used in comparative example 2 was preparation 14.

Comparative example 3

Comparative example 3 differs from example 9 in that: the example of production of the deodorant used in comparative example 3 is production example 15.

Performance test

First, testing of deodorizing Performance

A specified amount of gas to be detected was put into a plurality of specified closed containers (5L), a test fabric (10 cm. times.10 cm) was put in, and after sealing and storage for 2 hours, the residual gas concentration was measured with an instrument (ammonia gas was measured with a detector tube). The measurement was repeated three times, and the average value was taken, and the deodorization ratio was calculated according to the formula (1).

A＝[(P_b-P_c)÷P_b]×100％

In the formula (I), the compound is shown in the specification,

a-deodorization Rate/%

P_b-initially detecting the concentration of the gas

P_c-detecting the concentration of the gas after deodorizing

A normal program of an AATCC135 (shrinkage performance test) standard washing machine is selected, the washing temperature is (41 +/-3) DEG C, GB/T8629-2017 standard detergents of household washing and drying programs for textile tests are adopted as the detergents, and the deodorization rate of the fabric after washing for different times is tested to evaluate the washing resistance of the fabric.

Second, test of antibacterial Properties

Reference is made to FZ/T73023-2006 appendix d.8 "antimicrobial fabric test method: and testing by an oscillation method, and calculating the bacteriostatic ratio Y of the fabric.

Third, hand feeling test

The hand touch evaluation is performed by multiple persons, and is represented by numbers 1-5. 1 is the worst hand feeling, hard and rough; 5 is best hand feeling, soft and slippery.

TABLE 8

Discussion of ammonia odor elimination Rate and washability

As can be seen by combining examples 1-12, example 31 and comparative examples 1-3 with Table 8, acetic acid, tannic acid, citric acid and butanetetracarboxylic acid have a superior effect of enhancing the washfastness of the socks.

The chitosan and the beta-cyclodextrin have a good synergistic effect, and the washability can be enhanced to a certain extent. The methylcellulose and the beta-cyclodextrin have a good synergistic effect, and the washability can be enhanced to a certain degree.

Melissic acid has a certain antibacterial effect and can enhance the washability to a certain extent.

Discussion of bacteriostatic Effect

As can be seen by combining examples 13-30 and Table 8, the quaternary ammonium salt of chitosan and cetyltrimethylammonium bromide have better bacteriostatic effects. The sodium acetate, the methyl cellulose and the sodium hypophosphite have good antibacterial effect.

The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.