Preparation process of cryolite ceramic tile and cryolite ceramic tile
阅读说明：本技术 一种冰晶石瓷砖的制备工艺及冰晶石瓷砖 (Preparation process of cryolite ceramic tile and cryolite ceramic tile ) 是由 梁桐灿 曾凡平 丁英美 梁耀龙 宋树刚 冯勇 刘海光 蔡三良 于 2021-03-23 设计创作，主要内容包括：本申请公开一种冰晶石瓷砖的制备工艺及冰晶石瓷砖,包括以下步骤：依次对闪光原料进行破碎、酸洗、除铁和筛选后得到闪光颗粒；将面釉原料和抛釉原料分别球磨、过筛除铁后得到面釉和抛釉；将闪光颗粒、辅助添加剂加入至抛釉中得到闪光釉料；在坯体表面施加面釉后进行喷墨打印,然后在坯体表面第一次施加闪光釉料,再第二次施加干粒；经干燥、烧成和抛光后即得到所述冰晶石瓷砖。通过以上方法制备得到的冰晶石瓷砖表面较为平滑,光泽度更高,较于市面上的闪光瓷砖具有更好的闪光效果。(The application discloses preparation technology and cryolite ceramic tile of cryolite ceramic tile, including following step: sequentially crushing, pickling, deironing and screening the flash raw materials to obtain flash particles; respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing; adding the flash particles and the auxiliary additive into the polished glaze to obtain flash glaze; applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles; and drying, sintering and polishing to obtain the cryolite ceramic tile. The cryolite ceramic tile prepared by the method has a smooth surface and higher glossiness, and has a better flashing effect compared with the flashing ceramic tiles on the market.)
1. A preparation process of a cryolite ceramic tile is characterized by comprising the following steps:
sequentially crushing, pickling, deironing and screening the flash raw materials to obtain flash particles;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing;
adding the flash particles and the auxiliary additive into the polished glaze to obtain flash glaze;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles;
and drying, sintering and polishing to obtain the cryolite ceramic tile.
2. The process for preparing a cryolite tile according to claim 1, wherein in the step of "pretreating the glittering raw material to obtain glittering particles", the glittering raw material is zircon, the zircon has a tetragonal crystal form, and the refractive index is 1.93-2.01;
the mass ratio of the polished glaze to the zircon is 10 (1-2).
3. The process for producing a cryolite tile according to claim 2, wherein the cryolite tile has a gloss of 95 to 100 °.
4. The process for preparing a cryolite tile according to claim 2, wherein 30-40 mesh of the glitter particles is 48-57%, 40-60 mesh of the glitter particles is 40-50%, and less than 100 mesh is 3.0%.
5. The process for preparing a cryolite tile according to claim 1, wherein the first application of the glittering glaze has a specific gravity of 1.90-2.1g/ml, and an application amount of 300-400g/m2；
When the dry particles are applied for the second time, the specific gravity of the dry particles is 1.30-1.45g/ml, and the application amount is 400-2。
6. The process for preparing a cryolite tile according to claim 1, wherein the glaze polishing raw material comprises the following components in percentage by weight: SiO 22:48.5-55.8％，Al2O3：12.9-17％，Fe2O3：0-0.45％，CaO：9-15％，MgO：3-7％，Na2O：2.8-6％，K2O：0.3-2.0％，ZnO：1.5-6％，B2O3：0.3-1.6％，BaO：4.2-8％。
7. The process for producing a cryolite tile according to claim 6, wherein B2O3：CaO：BaO＝1：(12-12.8)：(5-6)。
8. The process for preparing a cryolite tile according to claim 1, wherein the supplementary additive comprises the following components in parts by weight: 90-110 parts of water, 3-7 parts of sodium carboxymethylcellulose, 12-18 parts of ethylene glycol, 0.1-0.2 part of sodium tripolyphosphate and 0.1-0.15 part of preservative.
9. The process for preparing a cryolite tile according to claim 1, wherein the firing temperature is 1220-1250 ℃ and the firing period is 68-70 min.
10. A cryolite tile produced by the process for the preparation of a cryolite tile according to any one of claims 1 to 9.
Technical Field
The application relates to the technical field of cryolite ceramic tile preparation, in particular to a preparation process of a cryolite ceramic tile and the cryolite ceramic tile.
Background
The ceramic tile has the characteristics of long service life, easy cleaning and good decorative effect, and is widely used in modern decoration. According to the ceramic tile characteristic difference, the ceramic tile is divided into a plurality of kinds, including ancient brick, entire body brick, glazed tile etc. and the ceramic tile that flashes is as a special ceramic tile kind, because its inside scintillation granule can outwards refract out the light of multichannel difference under the shining of light for ceramic tile surface is bright and dazzlingly, therefore many commercial decoration occasions are used more.
However, the existing flashing ceramic tile is only glazed once, and in the subsequent polishing process, the flashing particles are mostly various stone materials with high hardness and capable of refracting light, so that when the surface of the ceramic tile with the flashing particles is directly polished, due to the fact that the hardness of the flashing particles is high, when the area of the flashing particles is polished in the polishing process, a plurality of pits can appear, the smoothness degree of the surface of the ceramic tile is affected, the glossiness of the ceramic tile is low, the corresponding flashing effect is correspondingly reduced, the abrasion to an abrasive material is high during polishing, and the production cost is correspondingly increased.
Disclosure of Invention
The application mainly aims to provide a preparation process of a cryolite ceramic tile and the cryolite ceramic tile, and aims to solve the technical problems that the existing ceramic tile with flashing has a rough surface and a poor flashing effect.
In order to achieve the above purpose, the present application provides a process for preparing a cryolite tile, comprising the following steps:
sequentially crushing, pickling, deironing and screening the flash raw materials to obtain flash particles;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing;
adding the flash particles and the auxiliary additive into the polished glaze to obtain flash glaze;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles;
and drying, sintering and polishing to obtain the cryolite ceramic tile.
Preferably, in the step of pretreating the flash raw material to obtain flash particles, the flash raw material is zircon, the crystal form of the zircon is a tetragonal system, the refractive index is 1.93-2.01, and the mass ratio of the glaze polishing to the zircon is 10 (1-2).
Preferably, the cryolite tile has a gloss of 95 to 100 °.
Preferably, 30-40 meshes account for 48-57%, 40-60 meshes account for 40-50%, and less than or equal to 3.0% below 100 meshes in the glittering granules.
Preferably, the first application of the glittering glaze has a specific gravity of 1.90-2.1g/ml and an application amount of 300-400g/m2(ii) a When the dry particles are applied for the second time, the specific gravity of the dry particles is 1.30-1.45g/ml, and the application amount is 400-2。
Preferably, the glaze polishing raw material comprises the following components in percentage by weight: SiO 22:48.5-55.8％，Al2O3：12.9-17％，Fe2O3：0-0.45％，CaO：9-15％，MgO：3-7％，Na2O：2.8-6％，K2O：0.3-2.0％，ZnO：1.5-6％，B2O3：0.3-1.6％，BaO：4.2-8％。
Preferably, B2O3：CaO：BaO＝(1-1.7)：(12-12.8)：(5-6)。
Preferably, the auxiliary additive comprises the following components in parts by weight: 90-110 parts of water, 3-7 parts of sodium carboxymethylcellulose, 12-18 parts of ethylene glycol, 0.1-0.2 part of sodium tripolyphosphate and 0.1-0.15 part of preservative.
Preferably, the firing temperature is 1220-1250 ℃ and the firing period is 68-70 min.
The application also provides a cryolite ceramic tile, which is prepared by the preparation process of the cryolite ceramic tile.
The technical scheme of this application provides a preparation technology and cryolite ceramic tile of cryolite ceramic tile, in order to obtain the cryolite ceramic tile that has excellent flash of light effect, this scheme has carried out joint adjustment to the component of whole preparation technology and each raw materials and has applyed the parameter, make each preparation technology and raw materials proportion, the glaze is applyed the parameter and is mutually supported, in order to reach the optimal flash of light effect, and the flash of light ceramic tile that the preparation obtained has better glossiness, specific glossiness is in 95-100 within range, cooperation zircon flash of light granule makes flash of light effect reach the best, the ceramic tile mechanical properties that the production obtained is also comparatively excellent.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present application, and for those skilled in the art, other related drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic representation of the surface effect of cryolite tile example 13 provided herein;
fig. 2 is a schematic representation of the surface effect of the cryolite tile comparative example 1 provided herein.
In the drawings: zircon glittering particles 1 and pits 2.
The implementation, functional features and advantages of the objectives of the present application will be further explained with reference to the accompanying drawings.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions of the embodiments of the present application will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
In the embodiment of the application, the preparation process of the cryolite ceramic tile comprises the following steps:
sequentially crushing, pickling, deironing and screening the flash raw materials to obtain flash particles;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing;
adding the flash particles and the auxiliary additive into the polished glaze to obtain flash glaze;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles;
and drying, sintering and polishing to obtain the cryolite ceramic tile.
The technical scheme of this application is through adopting the method that the secondary glazed, and what adopt when glazing for the back time is the dry grain that does not add the flash of light granule, make the ceramic tile after the polishing have better flash of light effect, because the inlayer contains the glaze layer wearing and tearing volume of the flash of light granule can not worn and torn even less, consequently the ceramic tile surface after the polishing is polished still has more flash of light granule, guarantee that it has better flash of light effect, and because not adding the flash of light granule in the top layer glaze, when can not having the great flash of light granule of hardness of polishing, the condition of more pit 2 appears in the ceramic tile surface, the ceramic tile surface is more level and smooth, glossiness is higher. Before actual application, the flash particles need to be crushed, acid-washed, deironized and screened, so that impurities in the flash particles can be removed to the greatest extent, and the glaze polishing in the scheme is a glaze component matched with the flash particles, so that the flash particles have a better flash effect; the auxiliary additives are also added to promote fusion between the glazing and glitter particle mixing systems and comprise various suspending agents, stabilizing agents, preservatives and the like.
In an embodiment of the application, in the step of "pretreating the glittering raw material to obtain glittering particles", the glittering raw material is zircon, a crystal form of the zircon is a tetragonal system, a refractive index is 1.93-2.01, and a mass ratio of glaze polishing to zircon is 10 (1-2). The glittering particles in the embodiments of the present application are specifically zircon, which has a high refractive index for light, and thus has a good glittering effect on the surface of the ceramic. The zircon crystal form that selects for use in this scheme is the tetragonal system, and the refracting index is 1.93-2.01, and in this scope, the zircon is at the surperficial flash of light effect best of ceramic tile to the zircon still has characteristics such as high temperature resistant, stand wear and tear and covering power is strong, consequently uses and can also make the ceramic tile obtain better mechanical properties in the ceramic tile.
In an embodiment of the present application, the cryolite tile has a gloss of 95 to 100 °. Through the preparation process and the limitation of each parameter, the glossiness of the obtained ceramic tile is 95-100 degrees, which is different from the glossiness requirement of the glittering ceramic tile on the market at present, and the glossiness of the cryolite ceramic tile is 95-100 degrees, so that the ceramic tile has a good decorative effect, and the glittering effect of the glittering particles on the surface of the ceramic tile is further improved.
In one embodiment of the present application, the specific gravity of the glittering glaze is 1.90-2.1g/ml and the application amount is 300-400g/m2(ii) a When the dry particles are applied for the second time, the specific gravity of the dry particles is 1.30-1.45g/ml, and the application amount is 400-2. The embodiment of this application adopts above proportion and application volume, can guarantee the specific thickness on each glaze layer to make each layer raw materials distribute more even, further guarantee the planarization on cryolite ceramic tile surface, make the ceramic tile obtain better flash effect.
In an embodiment of the application, the glaze polishing raw material comprises the following components in percentage by weight: SiO 22:48.5-55.8％，Al2O3：12.9-17％，Fe2O3：0-0.45％，CaO：9-15％，MgO：3-7％，Na2O：2.8-6％，K2O：0.3-2.0％，ZnO：1.5-6％，B2O3: 0.3-1.6%, BaO: 4.2 to 8 percent. In the glaze polishing raw material, SiO is calculated according to weight percentage2Can be any value between 48.5%, 49%, 50%, 51%, 52%, 53%, 54%, 55%, 55.8% and 48.5-55.8%; al (Al)2O3Can be 12.9%, 13%, 14%, 16%, 17% and any value between 12.9-17%; fe2O3Can be any value between 0%, 0.1%, 0.2%, 0.3%, 0.4%, 0.45% and 0-0.45%; the content of CaO may be any value between 9%, 10%, 11%, 12%, 13%, 14%, 15% and 9-15%; the content of MgO may be any value between 3%, 4%, 5%, 6%, 7% and 3-7%; na (Na)2The content of O can be any value between 2.8%, 3%, 4%, 5%, 6% and 2.8-6%; k2The content of O may be any value between 0.3%, 0.5%, 0.7%, 0.9%, 1.1%, 1.3%, 1.5%, 1.7%, 1.9%, 2%, and 0.3-2%; b is2O3The content of (b) may be any value between 0.3%, 0.5%, 0.7%, 0.9%, 1.1%, 1.3%, 1.5%, 1.6% and 0.3-1.6%; the content of BaO may be any value between 4.2%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, and 4.2 to 8%. The preferred proportion of each raw material is SiO2:50.6％，Al2O3：15.7％，Fe2O3：0.15％，CaO：13.4％，MgO：5.05％，Na2O：4.3％，K2O：1.2％，ZnO：3％，B2O3: 1.1%, BaO: 5.5 percent, when all the glaze polishing raw materials are in the proportion, the composite effect of the glaze polishing raw materials and the zirconite is the best, and the corresponding flash performance is the best.
In an embodiment of the present application, B2O3：CaO：BaO＝1：(12-12.8)：(5-6)。
In an embodiment of the present application, the auxiliary additive comprises the following components in parts by weight: 90-110 parts of water, 3-7 parts of sodium carboxymethylcellulose, 12-18 parts of ethylene glycol, 0.1-0.2 part of sodium tripolyphosphate and 0.1-0.15 part of preservative.
In one embodiment of the present application, the firing temperature is 1220-1250 ℃, and the firing period is 68-70 min.
This application still provides a cryolite ceramic tile, the cryolite ceramic tile is obtained by the preparation technology preparation of any kind of cryolite ceramic tile of the aforesaid, the preparation technology of cryolite ceramic tile refers to above-mentioned embodiment, because the cryolite ceramic tile has adopted the whole technical scheme of above-mentioned all embodiments, consequently has all effects that the technical scheme of above-mentioned embodiment brought at least, no longer gives unnecessary details one by one here.
The technical solutions of the present application are further described in detail with reference to the following specific examples, which should be understood as merely illustrative and not limitative.
Example 1
A preparation process of a cryolite ceramic tile comprises the following steps:
sequentially crushing, pickling, deironing and screening a zirconite raw material to obtain zirconite flash particles 1, wherein the particle size of the screened zirconite flash particles 1 is 40-60 meshes, and common zirconite is adopted;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing;
the overglaze and the polishing glaze adopt conventional components, and the specific components and the proportion are shown in the following table:
adding the zircon flash particles 1 and an auxiliary additive into the polished glaze to obtain the flash glaze, wherein the mass ratio of the polished glaze to the zircon flash particles 1 is 10:1.3, and the auxiliary additive comprises: 105 parts of water, 4 parts of sodium carboxymethylcellulose, 16 parts of ethylene glycol, 0.1 part of sodium tripolyphosphate and 0.12 part of preservative;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry granules, wherein the components and the proportion of the dry granules are shown in the following table:
name (R)
SiO2
Al2O3
Fe2O3
TiO2
CaO
MgO
K2O
Na2O
Others
Composition of
61.54
8.76
0.15
0.05
10.54
1.48
2.53
8.65
0.20
The first application of flashing glaze had a specific gravity of 1.95g/ml and an application rate of 460g/m2(ii) a When the dry pellets were applied for the second time, the specific gravity of the dry pellets was 1.35g/ml, and the application amount was 550g/m2；
The cryolite ceramic tile is obtained after drying, sintering and polishing, wherein the specific sintering temperature is 1235 ℃, and the sintering period is 68 min.
Example 2
A preparation process of a cryolite ceramic tile comprises the following steps:
sequentially crushing, pickling, deironing and screening a zirconite raw material to obtain zirconite flash particles 1, wherein the particle size of the screened zirconite flash particles 1 is 40-60 meshes, and common zirconite is adopted;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing; the overglaze and glaze employed the composition described in example 1.
Adding the zircon flash particles 1 and an auxiliary additive into the polished glaze to obtain the flash glaze, wherein the mass ratio of the polished glaze to the zircon flash particles 1 is 10:2, and the auxiliary additive comprises: 98 parts of water, 6 parts of sodium carboxymethylcellulose, 15 parts of ethylene glycol, 0.2 part of sodium tripolyphosphate and 0.15 part of preservative;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles, wherein the components and the proportion of the dry particles are consistent with those of the embodiment 1, when the flashing glaze is applied for the first time, the specific gravity of the flashing glaze is 2.1g/ml, and the application amount is 450g/m2(ii) a When the dry pellets were applied for the second time, the specific gravity of the dry pellets was 1.40g/ml, and the application amount was 520g/m2；
The cryolite ceramic tile is obtained after drying, sintering and polishing, wherein the specific sintering temperature is 1225 ℃, and the sintering period is 70 min.
Example 3
A preparation process of a cryolite ceramic tile comprises the following steps:
sequentially crushing, pickling, deironing and screening a zirconite raw material to obtain zirconite flash particles 1, wherein the particle size of the screened zirconite flash particles 1 is 40-60 meshes;
respectively ball-milling the overglaze raw material and the glaze polishing raw material, and sieving to remove iron to obtain overglaze and glaze polishing; the overglaze and glaze employed the composition described in example 1.
Adding the zircon flash particles 1 and an auxiliary additive into the polished glaze to obtain the flash glaze, wherein the mass ratio of the polished glaze to the zircon flash particles 1 is 10:1, and the auxiliary additive comprises: 90 parts of water, 3 parts of sodium carboxymethylcellulose, 12 parts of ethylene glycol, 0.15 part of sodium tripolyphosphate and 0.1 part of preservative;
applying overglaze on the surface of the blank, then carrying out ink-jet printing, firstly applying flashing glaze on the surface of the blank, and secondly applying dry particles, wherein the components and the proportion of the dry particles are consistent with those of the embodiment 1, when the flashing glaze is applied for the first time, the specific gravity of the flashing glaze is 1.90g/ml, and the application amount is 420g/m2(ii) a When the dry pellets were applied for the second time, the specific gravity of the dry pellets was 1.45g/ml, and the application amount was 515g/m2；
The cryolite ceramic tile is obtained after drying, sintering and polishing, wherein the specific sintering temperature is 1240 ℃, and the sintering period is 70 min.
The performance of the tile is tested in examples 1-3, the specific test results are shown in the following table, wherein the flashing effect of each tile is observed by the same observer with naked eyes, each 2 rock crystal tile samples are compared separately and then compared with each other, the comparison data are collected, evaluation is carried out according to the visual flashing effect of the tile, and the final obtained result is as follows: flash effect of example 3> flash effect of example 1> flash effect of example 2.
/
Gloss degree/° C
Example 1
96
Example 2
95
Example 3
97
As can be seen from the table above, the cryolite ceramic tile obtained by the preparation process has a good flashing effect because the surface is smooth, the glossiness of the whole ceramic tile is good, and the specific glossiness is over 95 degrees.
Comparative example 1
The conditions in this example are the same as in example 3, except that: this comparative example did not have a secondary application of dry particles (only glitter glaze applied) to the tile surface, followed directly by the drying, firing and polishing steps.
The performance of comparative example 1 was tested, and the evaluation results of the flashing effect were: example 3> example 1> example 2 > comparative example 1, and this comparative example 1 (glitter particles worn away during sanding and more pits present on the surface) was significantly less glitter and also less glossy than the first 3 examples after visual inspection, as shown in the following table:
it can be seen from the above table that because the secondary drying is not carried out, the surface of the ceramic tile is covered with more flash particles, when the ceramic tile is polished in the subsequent process, the grinding tool directly contacts with the flash particles, namely zircon, so that part of the flash particles can be worn away, and because the hardness of the flash particles is higher, part of cracks and pits can be caused to appear on the surface of the ceramic tile, and the surface of the ceramic tile is uneven, so that the glossiness of the surface of the ceramic tile is synchronously reduced and is far lower than the flash effect of the cryolite ceramic tile in the scheme.
Example 4
The conditions in this example are the same as in example 3, except that: the zircon grain composition used in this example was: the content of 30-40 meshes is 52.5%, the content of 40-60 meshes is 46%, and the content of less than 100 meshes is 1.5%.
Example 5
The conditions in this example are the same as in example 3, except that: the zircon grain composition used in this example was: 98 percent of 30-40 meshes and 2 percent below 100 meshes.
Example 6
The conditions in this example are the same as in example 3, except that: the zircon grain composition used in this example was: 52.5 percent of 30-40 meshes, 26 percent of 40-60 meshes, 20 percent of 60-80 meshes and 1.5 percent below 100 meshes.
The results of practical observation of examples 4-6 were: example 4 > example 6> example 5> example 3> example 1> example 2 > comparative example 1. As the particles were formulated in this set of examples, the corresponding cryolite tiles also varied in sparkle effect. Correspondingly, the grain composition of the ceramic tile (zircon) is 30-40 meshes accounting for 52.5%, 40-60 meshes accounting for 46%, and 1.5% below 100 meshes has the best glittering effect, and is far larger than that of other embodiments; then, after the particle grading is increased to 4 types of particles with the particle sizes-example 6, the glittering effect is not increased or decreased, so that the preferable particle grading of the scheme is that the particle grading is 48-57% of 30-40 meshes, 40-50% of 40-60 meshes and less than or equal to 3.0% of 100 meshes; similarly, when the (zircon) grain composition is reduced to 2 post-examples 5, the corresponding sparkle effect is worse than that of example 6.
Example 7
The conditions in this example are the same as in example 3, except that: the specific gravity of the glittering glaze used in the present example was 1.92g/ml, application amount is 348g/m2(ii) a The dry pellets had a specific gravity of 1.35g/ml and an application amount of 470g/m2。
Example 8
The conditions in this example are the same as in example 3, except that: the glitter glaze used in this example had a specific gravity of 2.5g/ml and was applied in an amount of 465g/m2(ii) a The dry granules had a specific gravity of 1.8g/ml and an application amount of 588g/m2。
Example 9
The conditions in this example are the same as in example 3, except that: the glitter glaze used in this example had a specific gravity of 1.3g/ml and was applied in an amount of 275g/m2(ii) a The dry granules had a specific gravity of 1.1g/ml and an application amount of 370g/m2。
The performance tests of examples 7 to 9 were carried out, and the evaluation results of the glitter effect were: example 7>Example 4 > example 6>Example 8>Example 5>Example 3>Example 1>Example 2>Example 9 "comparative example 1. In order to further improve the flash effect of the cryolite ceramic tile, the application also verifies the influence of glazing parameters on the flash effect, and finally obtains that the specific gravity of the flash glaze is 1.90-2.1g/ml and the application amount is 400g/m for 300-one materials when the flash glaze is applied for the first time2(ii) a When the dry particles are applied for the second time, the specific gravity of the dry particles is 1.30-1.45g/ml, and the application amount is 400-2The flashing effect of the tile is best in this range. Overall, the volume of applying of flash of light frit and dry grain is all comparatively moderate, and the setting of above parameter can guarantee basically that the dry grain layer on surface is worn and torn off when the polishing, and the inside flash of light frit surface has to grind to a very shallow part, and zircon is thrown to the regional quilt of only top small range because the main part is all thrown glaze raw materials parcel, and consequently, can not cause the pit phenomenon, and slightly polish to that zircon layer flash of light effect is better. The results of the corresponding tests of examples 7-9 can verify that when the application amount and specific gravity are large (example 8), the flashing effect is not even as good as that of example 6; when the application amount and the specific gravity were small (example 9), the glittering effect was greatly reduced because of the small application amount.
Example 10
This exampleThe conditions in (1) were the same as in example 7 except that: the glaze polishing component is SiO2:50.6％，Al2O3：15.7％，Fe2O3：0.15％，CaO：13.4％，MgO：5.05％，Na2O：4.3％，K2O：1.2％，ZnO：3％，B2O3: 1.1%, BaO: 5.5% of, wherein B2O3：CaO：BaO＝1.1：13.4：5.5。
Example 11
The conditions in this example were the same as in example 7, except that: the glaze polishing component is SiO2:53.6％，Al2O3：14.5％，Fe2O3：0.3％，CaO：12.1％，MgO：3.9％，Na2O：5％，K2O：1.5％，ZnO：3％，B2O3: 1%, BaO: 5.1% of, wherein B2O3：CaO：BaO＝1：12.1：5.1。
Example 12
The conditions in this example were the same as in example 7, except that: the glaze polishing component is SiO2:50.5％，Al2O3：13.9％，Fe2O3：0.2％，CaO：11.5％，MgO：6.3％，Na2O：5.5％，K2O：1％，ZnO：4.1％，B2O3: 0.8%, BaO: 6.2% of them, wherein B2O3：CaO：BaO＝0.8：11.5：6.2。
The performance tests of examples 10 to 12 were carried out, and the evaluation results of the glitter effect were: EXAMPLE 10 EXAMPLE 11>Example 12>Example 7>EXAMPLE 4 EXAMPLE 6>Example 8>Example 5>Example 3>Example 1>Example 2>Example 9 "comparative example 1. From the above detection results, the chemical composition of the glaze polishing of the present invention needs to be limited to SiO2:48.5-55.8％，Al2O3：12.9-17％，Fe2O3：0-0.45％，CaO：9-15％，MgO：3-7％，Na2O：2.8-6％，K2O：0.3-2.0％，ZnO：1.5-6％，B2O3: 0.3-1.6%, BaO: in the range of 4.2-8%, otherwise preparedThe obtained polished tiles have relatively poor glittering effect, just as the glaze polishing compositions adopted in examples 1-9 and the glaze polishing compositions adopted in examples 10-12 have better glittering effect in examples 10-12, and the glittering effect of example 10 is obviously better than that of examples 11 and 12 as a preferred example; in addition, from the results of the tests in examples 10 to 12, it can be seen that B is the number B in this case2O3: CaO: the ratio of BaO to BaO is controlled to be 1: (12-12.8): (5-6), the glittering effect is better, and when the component proportion of the glittering particles, the glittering particles and the polishing glaze is controlled, the glittering particles are better fused in the polishing glaze, cannot be worn away during polishing, and the pits 2 are fewer.
As shown in fig. 1 to 2, the surface of the cryolite tile obtained in example 10 and comparative example 1 is observed, and as shown in fig. 1 to 2, the surface of the cryolite tile obtained in example 13 is not substantially provided with pits 2, the corresponding antifouling effect is also good, and the zircon glittering particles 1 are not substantially absent on the surface of the tile, so that the overall glittering effect is good, and as shown by the detection results of the above examples and comparative examples, the glittering effect of example 10 is higher than that of comparative example 1 by multiple grades, so that the cryolite tile with excellent glittering effect can be obtained by the above preparation process and parameters. As shown in fig. 2, the surface of comparative example 1 had many pits 2, relatively poor glossiness, and low glitter effect.
The above description is only a preferred embodiment of the present application, and not intended to limit the scope of the present application, and all modifications and equivalents of the technical solutions that can be directly or indirectly applied to other related fields without departing from the spirit of the present application are intended to be included in the scope of the present application.