阅读说明：本技术 一种复合纸及其制备方法 (Composite paper and preparation method thereof ) 是由 王忠良 于 2021-01-15 设计创作，主要内容包括：本发明公开了一种复合纸及其制备方法,复合纸原料由废弃物烟渣、茶渣、黑液、白水等组成。通过黑液制浆、打浆、成浆、废液混合后浓缩、涂敷施胶、表面再施胶、烘干、压光、卷取等步骤制成。本发明的复合纸用原料,充分利用了烟厂、茶厂和纸厂的废弃物,实现了废弃物循环合理利用,另外,本发明所用原料来源广泛、成本低、生产效率高、产品性能指标较好,同时减轻了环境负荷。(The invention discloses a composite paper and a preparation method thereof, wherein the raw material of the composite paper comprises waste cigarette residue, tea residue, black liquor, white water and the like. The method comprises the steps of pulping black liquor, pulping, mixing to obtain pulp, concentrating waste liquor after mixing, coating and gluing, surface re-gluing, drying, press polishing, reeling and the like. The raw material for the composite paper fully utilizes the wastes of a cigarette factory, a tea factory and a paper factory, realizes the recycling and reasonable utilization of the wastes, and has the advantages of wide source of the used raw materials, low cost, high production efficiency, good product performance index and environmental load reduction.)

1. The composite paper is characterized by being prepared from tobacco residue, tea residue, black liquor, white water, sodium hydrogen phosphate and diatomite.

2. The composite paper and the preparation method thereof as claimed in claim 1, wherein the black liquor is waste water produced by an alkaline pulping process of a paper mill, and the Baume degree is not less than 15Be degrees.

3. The composite paper as claimed in claim 1, wherein the white water is waste water from paper making section of paper mill, and contains fine fiber, filler, sizing agent, wet strength agent, and antiseptic.

4. The composite paper and the preparation method thereof as claimed in claim 1, wherein the tobacco residue is one or a mixture of several of offal and tobacco powder of a cigarette factory.

5. The composite paper and the preparation method thereof as claimed in claim 1, wherein the tea residue is one or a mixture of several of tea stem and tea dust which are leftovers of a tea factory.

6. The composite paper and the preparation method thereof as claimed in claim 1, wherein the preparation method of the composite paper comprises the following specific steps:

(1) mixing the raw materials of the tobacco residue and the tea residue, adding the mixture into black liquor according to a solid-to-liquid ratio of 1: 3-4, and soaking for 2-3 hours;

(2) directly cooking the raw material soaked in the step 1) by using black liquor, wherein the cooking temperature is 95-110 ℃, the cooking temperature rise time is 40-60 min, the heat preservation time is 120-180 min, and the cooking pressure is 0.4-0.6 MPa;

(3) pulping the raw materials cooked in the step 2), wherein the pulping degree is controlled to be 28-32 DEG SR;

(4) adding sodium hydrogen phosphate and diatomite into the pulped raw materials in the step 3) in a pulp storage tank, starting a propeller, and stirring for 15-30 min for later use;

(5) adding white water waste liquor into the black liquor after pulp squeezing in the step 2), mixing, and concentrating to the mass percent concentration of 30-50%;

(6) sizing the raw material subjected to the sizing in the step 4) through a head box, squeezing paper sheets, and coating the concentrated waste liquid obtained in the step 5) for primary sizing;

(7) the paper sheet after primary sizing in the step 6) is subjected to surface sizing after passing through a second group of drying cylinders;

(8) and (3) drying, press polishing and reeling the paper sheet subjected to secondary sizing in the step 7) to obtain the composite paper.

7. The method for preparing composite paper as claimed in claim 6, wherein the diatomite has a particle size greater than 1000 mesh in step (4).

8. A method for making a composite paper as claimed in claim 6, wherein in step (6) the dryness of the paper sheet after passing through the second set of drying cylinders is maintained at 20-30%.

9. The method for preparing a composite paper according to claim 6, wherein the surface sizing agent in the step (7) is formed by mixing modified hemicellulose and polyvinyl alcohol;

the preparation method of the surface sizing agent comprises the following process steps:

(1) dissolving: and (3) mixing hemicellulose according to the ratio of g to g solid to liquid of 1: 30, adding solvent water, and dissolving in a dissolving tank at the stirring speed of 100r/min at the temperature of 75 ℃ for 30min, wherein the solution is ready for use after dissolving;

(2) boiling glue: mixing polyvinyl alcohol according to the ratio of g to g solid-liquid of 1: 35 adding solvent water, boiling the glue in a glue boiling pot for 60min at the temperature of 55-75 ℃ and the stirring speed of 100r/min, and keeping the glue for later use after the glue is boiled;

(3) solution mixing: firstly, mixing the colloidal solution obtained in the step 1) and the step 2) in a stirring reaction tank, adding a certain amount of reactant, stirring and reacting at the temperature of 50-75 ℃, the reaction time of 40-60 min and the stirring rotation speed of 100r/min, and obtaining the papermaking surface sizing agent after the reaction is finished.

Technical Field

The invention relates to the technical field of pulping and papermaking, in particular to composite paper and a preparation method thereof.

Background

Tobacco production in China is all over the country, the tobacco yield per year is 400-500 ten thousand tons, the annual total amount of tobacco waste is 90-100 ten thousand tons, and the tobacco waste accounts for about 18-25% of the total yield. Only Yunnan province, the discarded tobacco leaf scraps produced each year can reach more than 20 ten thousand tons, so how to carry out harmless treatment on the tobacco leaf scraps and effectively utilize the tobacco leaf scraps meets the urgent requirements in production. In addition, the number of field fresh tobacco leaves discarded due to improper climate, pest and disease damage or improper management or unqualified field fresh tobacco leaves is also extremely large, so the comprehensive utilization of tobacco waste becomes one of important research directions in the domestic tobacco industry.

China is a big tea planting country, the yield of Chinese tea is 279.34 ten thousand tons in 2019, but tea leaves generated after drinking tea are rarely used and mostly directly discarded, so that not only is the waste of resources caused, but also the environment is polluted. The tea leaves added into the papermaking raw materials not only can realize the secondary utilization of the tea leaves, but also can make the paper more environment-friendly and reduce the production cost of the paper.

The black liquor produced in the paper-making and pulping process of the paper-making black liquor is a serious pollutant of a water source, COD (chemical oxygen demand, the same below) in the wastewater discharged by the paper-making industry accounts for more than 40% of the total COD discharge of the national industry, and the pollutant contained in the paper-making black liquor accounts for more than 90% of the total discharge of the paper-making industry, and the treatment difficulty is high, and the environmental hazard is serious, so that the treatment of the paper-making black liquor is the key of the wastewater treatment of the paper-making industry, and the black liquor is treated by using a special device as a method for recovering alkali in the black liquor at present, but the cost is high, the treatment effect is. The papermaking black liquor contains lignin, pigment and NaOH, Na2CO3, Na2SO4 and Na2S2O3 inorganic substances.

The paper industry uses a considerable amount of water and is one of the important pollution sources causing environmental pollution. The papermaking white water contains fiber and stuffing, and the stuffing is rosin, aluminum sulfate, strength agent, talcum powder, polyacrylamide, etc. The direct discharge of the white water not only seriously pollutes water sources, but also causes a great deal of resource waste. At present, the domestic papermaking white water of a papermaking factory mostly uses a closed circulation recycling method, and the fine fiber and the filler are recycled in the whole large system, so that the defects exist, the product quality is seriously influenced, and the great burden is caused by water supply treatment, and the specific problems are as follows: white water contains various dissolved organic matters, inorganic matters and microorganisms, when a white water system of a paper machine is closed, along with the great reduction of fresh water amount entering the system and waste water amount discharged, harmful substances accumulated in the system are greatly increased, water quality is reduced, foam is generated, rotten pulp is generated, the pH value is out of control, glue application is difficult, precipitation and dirt are generated, meshes and blankets are blocked, viscosity is increased, water filtration is difficult, and the like, so that the wet part of the paper machine and the paper forming performance are influenced.

The invention aims to provide composite paper and a preparation method thereof, which effectively utilize waste to change waste into valuable, eliminate the pollution of the waste to the environment and generate better economic benefit. Specifically, the invention aims to provide composite paper and a preparation method thereof, wherein raw materials for preparing the composite paper comprise waste cigarette residue, tea residue, black liquor, white water and the like.

In the patent application No.: CN112064414A discloses a tea residue-containing paper and a manufacturing method thereof, and the raw materials thereof comprise, by mass, 1-10% of tea residues, 80-90% of paper pulp fibers, 1-5% of an adsorbent, 3-10% of a charge balancing agent and 2-5% of a fixative.

Patent application No.: CN108125272A discloses a preparation method of paper-making reconstituted tobacco, which comprises the following steps: mixing and crushing tobacco stems, tea leaf residues and rhizoma atractylodis, soaking the mixture in water, extracting to obtain a solid and an extracting solution, grinding the solid into slurry to obtain slurry, adding glucose oxidase and pectinase into the slurry, fermenting for 12-72 hours, putting the slurry into a sheet-making machine to obtain a sheet base, adding propylene glycol and proline into the extracting solution, concentrating to obtain a coating liquid, coating the coating liquid on the sheet base, and drying to obtain the reconstituted tobacco leaves by a paper-making method.

Patent application No.: CN110144260A discloses a method for producing perfume by using waste residue of paper-making reconstituted tobacco, which is to take the waste residue of paper-making reconstituted tobacco as a raw material, directly add water into fermentation equipment for sterilization, add fermentation strain or/and biological enzyme, ferment for 10-30 hours at the temperature of 20-50 ℃ to form fermented mash; extracting the fermented mash with water-soluble solvent to obtain extractive solution, adding natural plant material solution into the extractive solution, soaking and extracting at 30-150 deg.C for 2-5 hr, precipitating with ethanol to remove a little precipitate, and concentrating to obtain pasty perfume product. Compared with the common fermented extract, the spice prepared by the invention has richer fragrance, is favorable for being used as a cigarette additive to increase the smoking quality of cigarettes, and can also be used as an additive of reconstituted tobacco to increase the sensory quality of the reconstituted tobacco, reduce the stimulation, improve the aftertaste and improve the product quality of the reconstituted tobacco.

The invention discloses a preparation method of a mixed auxiliary agent for papermaking, which belongs to the field of pulping and papermaking, aims at the pollution-free discharge and comprehensive cyclic utilization of pulping black liquor, and aims at the black liquor characteristic of papermaking raw materials, and further coats the black liquor on a paper surface through acidification or/and modification treatment so as to ensure that the black liquor is not discharged and is fully utilized; provides a method for treating and comprehensively utilizing pulping black liquor for the paper industry, provides an effective way for industrial clean pollution-free pulping and paper making, can improve the yield of finished paper of pulping and paper making by 60-80 percent on the original basis, and effectively improves the resource utilization rate.

In summary, the disadvantages of the above process and raw materials are: the addition amount of raw materials is large, the cost is high, and waste raw material resources are not fully utilized.

Disclosure of Invention

The invention is provided on the basis of overcoming the above-mentioned disadvantage, the purpose of the invention is to provide a composite paper and its preparation method, the raw materials for composite paper that the invention utilizes, fully utilize the waste of the cigarette factory, tea factory and paper factory, has realized the waste circulates and reasonably utilizes, in addition, the raw materials used in the invention are wide in source, with low costs, the production efficiency is high, the product performance index is higher, lighten the environmental load at the same time.

In order to achieve the purpose, the invention adopts the following technical scheme:

a composite paper is prepared from tobacco residue, tea residue, black liquor, white water, sodium hydrogen phosphate and diatomite.

The black liquor is waste water produced by an alkaline pulping process of a paper mill, and the Baume degree is more than or equal to 15Be degrees.

The white water is waste water of a paper making working section of a paper mill, and contains fine fibers, filler, sizing material, wet strength agent and preservative.

The tobacco residue is one or a mixture of a plurality of leftovers of tobacco stems and tobacco powder in a tobacco factory.

The tea residue is one or a mixture of a plurality of tea stems and tea dust which are leftovers of a tea factory.

The preparation method of the composite paper comprises the following specific steps:

(1) mixing the raw materials of the tobacco residue and the tea residue, adding the mixture into black liquor according to a solid-to-liquid ratio of 1: 3-4, and soaking for 2-3 hours;

(2) directly cooking the raw material soaked in the step 1) by using black liquor, wherein the cooking temperature is 95-110 ℃, the cooking temperature rise time is 40-60 min, the heat preservation time is 120-180 min, and the cooking pressure is 0.4-0.6 MPa;

(3) pulping the raw materials cooked in the step 2), wherein the pulping degree is controlled to be 28-32 DEG SR;

(4) adding sodium hydrogen phosphate and diatomite into the pulped raw materials in the step 3) in a pulp storage tank, starting a propeller, and stirring for 15-30 min for later use;

(5) adding white water waste liquor into the black liquor after pulp squeezing in the step 2), mixing, and concentrating to the mass percent concentration of 30-50%;

(6) sizing the raw material subjected to the sizing in the step 4) through a head box, squeezing paper sheets, and coating the concentrated waste liquid obtained in the step 5) for primary sizing;

(7) the paper sheet after primary sizing in the step 6) is subjected to surface sizing after passing through a second group of drying cylinders;

(8) and (3) drying, press polishing and reeling the paper sheet subjected to secondary sizing in the step 7) to obtain the composite paper.

The particle size of the diatomite in the step (4) is larger than 1000 meshes.

In the step (6), the dryness of the paper after passing through the second group of drying cylinders is kept between 20 and 30 percent.

The surface sizing agent in the step (7) is formed by mixing modified hemicellulose and polyvinyl alcohol;

the preparation method of the surface sizing agent comprises the following process steps:

(1) dissolving: and (3) mixing hemicellulose according to the ratio of g to g solid to liquid of 1: 30, adding solvent water, and dissolving in a dissolving tank at the stirring speed of 100r/min at the temperature of 75 ℃ for 30min, wherein the solution is ready for use after dissolving;

(2) boiling glue: mixing polyvinyl alcohol according to the ratio of g to g solid-liquid of 1: 35 adding solvent water, boiling the glue in a glue boiling pot for 60min at the temperature of 55-75 ℃ and the stirring speed of 100r/min, and keeping the glue for later use after the glue is boiled;

(3) solution mixing: firstly, mixing the colloidal solution obtained in the step 1) and the step 2) in a stirring reaction tank, adding a certain amount of reactant, stirring and reacting at the temperature of 50-75 ℃, the reaction time of 40-60 min and the stirring rotation speed of 100r/min, and obtaining the papermaking surface sizing agent after the reaction is finished.

Compared with the prior art, the invention has the following beneficial effects:

the method fully utilizes the wastes of a tobacco plant, a tea plant and a paper plant, realizes the recycling and reasonable utilization of the wastes, and lightens the environmental load, particularly the papermaking black liquor and the white water waste liquor;

secondly, the raw material source is regional and strong, the centralized treatment is easy, and the cost of the waste is low;

solving the problems that the proportion of the formula of the tobacco residue and the tea residue in the raw materials is unreasonable and the quality and the strength of the finished paper are low due to the problems of the raw materials such as short fiber, difficult pulping and the like;

adding sodium hydrogen phosphate and diatomite into the pulp storage tank, so that the pulp storage tank has the characteristics of easy adsorption of the filler and water absorption, and is convenient for retaining the fiber, the filler and other substances in water;

the preparation method adopts multiple sizing, thereby fully utilizing waste resources, not increasing additional processes and having high production efficiency;

sixthly, in the two sizing operations, waste liquid is utilized in the first sizing operation, and the sizing agent prepared from modified hemicellulose and polyvinyl alcohol is adopted in the second surface sizing operation, so that the paper surface is finished while the paper strength is ensured.

Detailed Description

In order to better understand the present invention, the following examples further illustrate the invention, the examples are only used for explaining the invention, not to constitute any limitation of the invention.

Example 1

A composite paper is prepared from tobacco residue 3 parts, tea residue 2 parts, black liquor 15 parts, white water 10 parts, sodium hydrogen phosphate 0.2 parts, and diatomaceous earth 0.2 parts;

a preparation method of composite paper comprises the following specific steps:

(1) mixing the raw materials of the tobacco residue and the tea residue in proportion, and adding black liquor according to the solid-to-liquid ratio of 1:3 for soaking for 3 hours;

(2) directly cooking the raw material soaked in the step 1) by using black liquor, wherein the cooking temperature is 95 ℃, the cooking temperature rise time is 40 min, the heat preservation time is 180 min, and the cooking pressure is 0.4 MPa;

(3) pulping the raw materials steamed in the step 2), and controlling the pulping degree to be 28-degree SR;

(4) adding sodium hydrogen phosphate and diatomite into the raw material pulp storage tank after pulping in the step 3), starting a propeller, and stirring for 15min for later use;

(5) adding white water waste liquor into the black liquor after pulp squeezing in the step 2), mixing and concentrating to the mass percent concentration of 30%;

(6) sizing the raw material pulped in the step 4) through a head box, squeezing paper sheets, and then coating the concentrated waste liquid obtained in the step 5) for primary sizing;

(7) the paper sheet after the primary sizing in the step 6) passes through a second group of drying cylinders and then is subjected to surface sizing by using a sizing agent;

(8) and (3) drying, calendering and reeling the paper sheet subjected to secondary sizing in the step 7) to obtain the high-performance composite paper.

The physical properties of the paper obtained in example 1 were determined to be: tensile index of 46.35 N.m/g, tear index of 5.84 mN.m 2/g, burst index of 3.39 kPa.m 2/g, and folding endurance of 891 times.

Example 2

A composite paper is prepared from tobacco residue 5 parts, tea residue 5 parts, black liquid 35 parts, white water 25 parts, sodium hydrogen phosphate 1.0 part, and diatomaceous earth 1.0 part;

a preparation method of composite paper comprises the following specific steps:

(1) mixing the raw materials of the tobacco residue and the tea residue in proportion, and adding black liquor according to the solid-to-liquid ratio of 1:4 for soaking for 2 hours;

(2) directly cooking the raw material soaked in the step 1) by using black liquor, wherein the cooking temperature is 105 ℃, the cooking temperature rise time is 50 min, the heat preservation time is 150 min, and the cooking pressure is 0.5 MPa;

(3) pulping the raw materials steamed in the step 2), and controlling the pulping degree to be 30-degree SR;

(4) adding sodium hydrogen phosphate and diatomite into the raw material pulp storage tank after pulping in the step 3), starting a propeller, and stirring for 25min for later use;

(5) adding white water waste liquor into the black liquor after pulp squeezing in the step 2), mixing and concentrating to the mass percent concentration of 40%;

(6) sizing the raw material pulped in the step 4) through a head box, squeezing paper sheets, and then coating the concentrated waste liquid obtained in the step 5) for primary sizing;

(7) the paper sheet after the primary sizing in the step 6) passes through a second group of drying cylinders and then is subjected to surface sizing by using a sizing agent;

(8) and (3) drying, calendering and reeling the paper sheet subjected to secondary sizing in the step 7) to obtain the high-performance composite paper.

The physical properties of the paper obtained in example 2 were determined to be: the tensile index is 51.35 N.m/g, the tearing index is 7.06 mN.m 2/g, the burst index is 5.12 kPa.m 2/g, and the folding endurance is 1233 times.

Example 3

A composite paper is prepared from tobacco residue 8 parts, tea residue 12 parts, black liquor 60 parts, white water 40 parts, sodium hydrogen phosphate 1.2 parts, and diatomite 1.2 parts;

a preparation method of composite paper comprises the following specific steps:

(1) mixing the raw materials of the tobacco residue and the tea residue in proportion, and adding black liquor according to the solid-to-liquid ratio of 1:3 for soaking for 3 hours;

(2) directly cooking the raw material soaked in the step 1) by using black liquor, wherein the cooking temperature is 110 ℃, the cooking temperature rise time is 60min, the heat preservation time is 180 min, and the cooking pressure is 0.6 MPa;

(3) pulping the raw materials steamed in the step 2), and controlling the pulping degree to be 32-degree SR;

(4) adding sodium hydrogen phosphate and diatomite into the raw material pulp storage tank after pulping in the step 3), starting a propeller, and stirring for 30min for later use;

(5) adding white water waste liquor into the black liquor after pulp squeezing in the step 2), mixing and concentrating to the mass percent concentration of 50%;

(6) sizing the raw material pulped in the step 4) through a head box, squeezing paper sheets, and then coating the concentrated waste liquid obtained in the step 5) for primary sizing;

(7) the paper sheet after the primary sizing in the step 6) passes through a second group of drying cylinders and then is subjected to surface sizing by using a sizing agent;

(8) and (3) drying, calendering and reeling the paper sheet subjected to secondary sizing in the step 7) to obtain the high-performance composite paper.

The physical properties of the paper obtained in example 3 were determined to be: the tensile index is 56.78 N.m/g, the tearing index is 7.34 mN.m 2/g, the burst index is 5.86 kPa.m 2/g, and the folding endurance is 1235 times.