阅读说明：本技术 一种环保燃烧油及生产工艺 (Environment-friendly combustion oil and production process thereof ) 是由 聂志煌 于 2020-12-25 设计创作，主要内容包括：本发明公开了一种环保燃烧油,涉及燃油生产加工技术领域,包括以下按质量百分比计算的组分：甲醇5-10％、乙醇0.01-1％、1,2-丙二醇5-10％、乙二醇35-45％、1,3二氧杂烷-2-甲醇1-3％、1,2-丁二醇30-40％、1,2-己二醇0.01-1％、1,4-丁二醇0.01-1％、二乙二醇0.01-1％以及余量的水。其生产工艺包括：将乳化剂与表面活化剂均加入到燃烧油内按比例混合,得到混合燃烧油油；对混合燃烧油进行高速搅拌；对混合燃烧油进行对冲混合搅拌；将所述混合燃烧油与水按比例混合,得到乳化燃烧油。本发明选用甲醇与多种醇混合,使燃烧油更好的适应低温燃烧充分彻底,高效环保；本发明能够生产由燃烧油、乳化剂与水按比例配合的节能环保乳化燃烧油,形成油水油三重构造,生产效率高。(The invention discloses environment-friendly combustion oil, which relates to the technical field of fuel oil production and processing, and comprises the following components in percentage by mass: 5-10% of methanol, 0.01-1% of ethanol, 5-10% of 1, 2-propylene glycol, 35-45% of ethylene glycol, 1-3% of 1, 3-dioxane-2-methanol, 30-40% of 1, 2-butanediol, 0.01-1% of 1, 2-hexanediol, 0.01-1% of 1, 4-butanediol, 0.01-1% of diethylene glycol and the balance of water. The production process comprises the following steps: adding an emulsifier and a surfactant into the combustion oil and mixing in proportion to obtain mixed combustion oil; stirring the mixed combustion oil at a high speed; carrying out opposite-flushing mixing stirring on the mixed combustion oil; and mixing the mixed combustion oil and water in proportion to obtain the emulsified combustion oil. The invention selects and mixes methanol and various alcohols, so that the combustion oil is better suitable for low-temperature combustion, is full and thorough, and is efficient and environment-friendly; the invention can produce the energy-saving environment-friendly emulsified combustion oil which is prepared by proportionally mixing the combustion oil, the emulsifier and the water, forms an oil-water-oil triple structure and has high production efficiency.)

1. An environment-friendly combustion oil, which is characterized in that:

comprises the following components in percentage by mass: 5-10% of methanol, 0.01-1% of ethanol, 5-10% of 1, 2-propylene glycol, 35-45% of ethylene glycol, 1-3% of 1, 3-dioxane-2-methanol, 30-40% of 1, 2-butanediol, 0.01-1% of 1, 2-hexanediol, 0.01-1% of 1, 4-butanediol, 0.01-1% of diethylene glycol and the balance of water.

2. The environment-friendly combustion oil as claimed in claim 1, wherein:

comprises the following components in percentage by mass: 8.1% of methanol, 0.01% of ethanol, 6.41% of 1, 2-propanediol, 40.71% of ethylene glycol, 1.53% of 1, 3-dioxane-2-methanol, 38.83% of 1, 2-butanediol, 0.01% of 1, 2-hexanediol, 0.01% of 1, 4-butanediol, 0.01% of diethylene glycol and the balance of water.

3. The environment-friendly combustion oil as claimed in claim 1, wherein:

further comprises at least one of the following components: 0.01-1% of combustion improver, 0.01-1% of stabilizing agent, 0.01-1% of oxygen-increasing agent and 0.01-1% of corrosion inhibitor.

4. The environment-friendly combustion oil as claimed in claim 1, wherein:

the combustion improver consists of a ketone compound or an ester compound or an ether compound, glycerol, ferrocene and diesel, wherein the mass ratio of the ketone compound or the ester compound or the ether compound to the glycerol to the ferrocene to the diesel is 13-15: 18-20: 0.01-0.03: 1.

5. a process for producing an environmentally friendly combustion oil based on any one of claims 1 to 4, wherein: the method comprises the following steps:

a. adding an emulsifier and a surfactant into the combustion oil and mixing in proportion to obtain mixed combustion oil;

b. stirring the mixed combustion oil at a high speed for 5-10 minutes at a temperature of 10-90 ℃;

c. carrying out opposite-flushing mixing stirring on the mixed combustion oil for 5-10 minutes at the temperature of 10-90 ℃;

d. and mixing the mixed combustion oil and water in proportion, and stirring the mixed solution at a high speed for 5-10 minutes at the temperature of 10-90 degrees to obtain the emulsified combustion oil.

6. The environment-friendly combustion oil as claimed in claim 5, wherein:

the mixing ratio of the emulsifier to the combustion oil is 1: 1000.

7. The environment-friendly combustion oil as claimed in claim 5, wherein:

the mixing ratio of the surfactant to the combustion oil is 1: 1000.

8. The environment-friendly combustion oil as claimed in claim 5, wherein:

and pouring the emulsified combustion oil into a low-speed stirrer for storage for later use, wherein the rotating speed range of the emulsified combustion oil is 60-130 revolutions.

9. The environment-friendly combustion oil as claimed in claim 5, wherein:

the ratio of the mixed combustion oil to water is 1: 1.

10. The environment-friendly combustion oil as claimed in claim 5, wherein:

if the combustion oil is heavy oil, the temperature ranges of the high-speed stirring and the opposite impact stirring are both 70-90 degrees.

Technical Field

The invention relates to the technical field of fuel oil production and processing, in particular to environment-friendly combustion oil.

Background

The fuels such as diesel oil, liquefied petroleum gas and the like have the problems of large discharge amount of harmful substances, serious air pollution, easy occurrence of black smoke and carbon deposition during combustion, weak fuel firepower, low heat value, unstable combustion, non-renewable raw materials and the like. The alcohol-based fuel is used as a carrier of new energy and carbon cycle, the problem of high-efficiency storage and distribution of energy is solved, the dependence of human beings on coal and petroleum is reduced by various synthetic ways, even carbon dioxide in atmosphere and industrial waste can be recycled as raw materials for synthesis and repeated recycling, and the alcohol-based fuel has a medium and important contribution to relieving global warming. The alcohol-based fuel is generally liquid fuel which is mainly methanol and is mixed with other polyhydric alcohols and hydrocarbons, but the methanol has the characteristics of low calorific value, strong volatility and the like, and the problems of burner failure and the like caused by low thermal efficiency, easy layering, high density, unstable flame combustion and easy generation of black smoke carbon deposition exist due to more complex components for increasing the calorific value of the alcohol-based fuel, so that the application and development of the alcohol-based fuel are greatly limited; therefore, an energy-saving and environment-friendly combustion oil is needed to replace the existing energy sources.

Disclosure of Invention

In order to solve the problems of the prior art, the invention specifically adopts the following technical scheme:

the environment-friendly combustion oil comprises the following components in percentage by mass: 5-10% of methanol, 0.01-1% of ethanol, 5-10% of 1, 2-propylene glycol, 35-45% of ethylene glycol, 1-3% of 1, 3-dioxane-2-methanol, 30-40% of 1, 2-butanediol, 0.01-1% of 1, 2-hexanediol, 0.01-1% of 1, 4-butanediol, 0.01-1% of diethylene glycol and the balance of water.

The further scheme is that the composition comprises the following components in percentage by mass: 8.1% of methanol, 0.01% of ethanol, 6.41% of 1, 2-propanediol, 40.71% of ethylene glycol, 1.53% of 1, 3-dioxane-2-methanol, 38.83% of 1, 2-butanediol, 0.01% of 1, 2-hexanediol, 0.01% of 1, 4-butanediol, 0.01% of diethylene glycol and the balance of water.

The further scheme is that the paint also comprises at least one of the following components: 0.01-1% of combustion improver, 0.01-1% of stabilizing agent, 0.01-1% of oxygen-increasing agent and 0.01-1% of corrosion inhibitor.

The combustion improver comprises a ketone compound or an ester compound or an ether compound, glycerol, ferrocene and diesel oil, wherein the mass ratio of the ketone compound or the ester compound or the ether compound to the glycerol to the ferrocene to the diesel oil is 13-15: 18-20: 0.01-0.03: 1.

the production process of the environment-friendly combustion oil comprises the following steps:

a. adding an emulsifier and a surfactant into the combustion oil and mixing in proportion to obtain mixed combustion oil;

b. stirring the mixed combustion oil at a high speed for 5-10 minutes at a temperature of 10-90 ℃;

c. carrying out opposite-flushing mixing stirring on the mixed combustion oil for 5-10 minutes at the temperature of 10-90 ℃;

d. and mixing the mixed combustion oil and water in proportion, and stirring the mixed solution at a high speed for 5-10 minutes at the temperature of 10-90 degrees to obtain the emulsified combustion oil.

In a further scheme, the mixing ratio of the emulsifier to the combustion oil is 1: 1000.

In a further scheme, the mixing ratio of the surfactant to the combustion oil is 1: 1000.

The further proposal is that the emulsified combustion oil is poured into a low-speed stirrer for storage and standby application, and the rotating speed range is 60-130 revolutions.

In a further scheme, the ratio of the mixed combustion oil to water is 1: 1.

Further, if the combustion oil is heavy oil, the temperature ranges of the high-speed stirring and the opposite impact stirring are both 70-90 degrees.

The invention has the beneficial effects that:

the invention selects and mixes methanol and various alcohols, and the methanol can reduce the kinematic viscosity and the cold filter plugging point of oil products, so that the combustion oil is better suitable for low-temperature application; the calorific value of other alcohols such as 1, 2-propylene glycol, ethylene glycol, 1, 3-dioxane-2-methanol and the like is higher than that of methanol, and a plurality of alcohols are mixed, so that the calorific value and the oxygen content of combustion oil are improved, the thermal efficiency is high, the combustion is complete, the carbon deposition phenomenon is avoided after the combustion, the flame is stable, the combustion efficiency is high, the safety is good, and the high efficiency and the environmental protection are realized;

the invention can produce the energy-saving environment-friendly emulsified combustion oil which is prepared by proportionally mixing the combustion oil, the emulsifier and the water, and the three components are uniformly and fully mixed by stirring at high speed twice and stirring at opposite direction once to form an oil-water-oil triple structure, thereby having high production efficiency.

Detailed Description

The technical solutions in the embodiments of the present invention are clearly and completely described below.

One embodiment 1 of the invention discloses an environment-friendly combustion oil, which comprises the following components in percentage by mass: 5-10% of methanol, 0.01-1% of ethanol, 5-10% of 1, 2-propylene glycol, 35-45% of ethylene glycol, 1-3% of 1, 3-dioxane-2-methanol, 30-40% of 1, 2-butanediol, 0.01-1% of 1, 2-hexanediol, 0.01-1% of 1, 4-butanediol, 0.01-1% of diethylene glycol and the balance of water.

In this example 1, the following components are included by mass percent: 8.1% of methanol, 0.01% of ethanol, 6.41% of 1, 2-propanediol, 40.71% of ethylene glycol, 1.53% of 1, 3-dioxane-2-methanol, 38.83% of 1, 2-butanediol, 0.01% of 1, 2-hexanediol, 0.01% of 1, 4-butanediol, 0.01% of diethylene glycol and the balance of water.

In the embodiment 1, at least one of the following components is further included: 0.01-1% of combustion improver, 0.01-1% of stabilizing agent, 0.01-1% of oxygen-increasing agent and 0.01-1% of corrosion inhibitor.

In this embodiment 1, the combustion improver comprises a ketone compound or an ester compound or an ether compound, glycerol, ferrocene, and diesel oil, wherein the mass ratio of the ketone compound or the ester compound or the ether compound, the glycerol, the ferrocene, and the diesel oil is 13-15: 18-20: 0.01-0.03: 1. the glycerol in the combustion improver can prevent the combustion oil from solidifying at low temperature, and has the function of preventing swelling, so that the equipment can be effectively protected; ferrocene can play a role in supporting combustion, improve the heat value and the combustion efficiency of combustion oil, reduce the combustible temperature and reduce the occurrence of black smoke and carbon deposition during combustion; the diesel oil can improve the heat value of the fuel oil and the compatibility of each component in the combustion improver, and promote the full and thorough combustion. The combustion improver enables the fuel oil to be combusted more fully and thoroughly, effectively reduces the generation amount and the discharge amount of toxic and harmful gases during combustion, and is efficient and clean.

In this example 1, the ketone compound includes ketone and butanone. The addition of the ketone compound can properly reduce the flash point of the fuel oil and reduce the combustible temperature, thereby promoting the full combustion of the fuel oil.

In this example 1, the ester compound includes ethyl formate, isobutyl acetate, butyl acetate, pentyl propionate, fatty acid methyl ester, isooctyl nitrate, cyclic ethyl nitrate, isopropyl nitrate, n-octyl nitrate, dimethyl carbonate, diethyl carbonate.

In this example 1, the ether compound includes hexyl ether, methyl tert-butyl ether, ethyl tert-butyl ether, methyl isobutyl ether, dimethyl ether, diphenyl ether, petroleum ether. The ether organic matter can increase the heat value of the fuel oil, increase the compatibility among all components, reduce the melting point of the combustion oil and increase the fluidity.

In this example 1, the stabilizer is di-tert-butyl-p-cresol and isooctane in a mass ratio of 2-3: 3-5.

In this embodiment 1, the oxygenation agent includes hydrogen peroxide, potassium permanganate, and isopropyl hydroperoxide.

In this embodiment 1, the corrosion inhibitor is benzotriazole, imidazoline, or N-methylmorpholine, and has corrosion inhibiting and corrosion inhibiting effects.

The invention discloses an embodiment 2 based on embodiment 1, and discloses a production process of environment-friendly combustion oil, which comprises the following steps:

a. adding an emulsifier and a surfactant into the combustion oil and mixing in proportion to obtain mixed combustion oil;

b. stirring the mixed combustion oil at a high speed for 5-10 minutes at a temperature of 10-90 ℃;

c. carrying out opposite-flushing mixing stirring on the mixed combustion oil for 5-10 minutes at the temperature of 10-90 ℃;

d. and mixing the mixed combustion oil and water in proportion, and stirring the mixed solution at a high speed for 5-10 minutes at the temperature of 10-90 degrees to obtain the emulsified combustion oil.

In this example 2, the mixing ratio of the emulsifier to the combustion oil was 1: 1000.

In this example 2, the mixing ratio of the surfactant to the combustion oil was 1: 1000.

In this example 2, the emulsified combustion oil was poured into a low-speed blender and stored until use, at a speed in the range of 60-130 revolutions.

In this example 2, the mixed combustion oil to water ratio was 1: 1.

In this example 2, if the combustion oil is heavy oil, the temperature ranges of the high-speed stirring and the opposed stirring are both 70-90 °.

The invention selects and mixes methanol and various alcohols, and the methanol can reduce the kinematic viscosity and the cold filter plugging point of oil products, so that the combustion oil is better suitable for low-temperature application; the calorific value of other alcohols such as 1, 2-propylene glycol, ethylene glycol, 1, 3-dioxane-2-methanol and the like is higher than that of methanol, and a plurality of alcohols are mixed, so that the calorific value and the oxygen content of combustion oil are improved, the thermal efficiency is high, the combustion is complete, the carbon deposition phenomenon is avoided after the combustion, the flame is stable, the combustion efficiency is high, the safety is good, and the high efficiency and the environmental protection are realized;

the invention can produce the energy-saving environment-friendly emulsified combustion oil which is prepared by proportionally mixing the combustion oil, the emulsifier and the water, and the three components are uniformly and fully mixed by stirring at high speed twice and stirring at opposite direction once to form an oil-water-oil triple structure, thereby having high production efficiency.

Finally, only specific embodiments of the present invention have been described in detail above. The invention is not limited to the specific embodiments described above. Equivalent modifications and substitutions by those skilled in the art are also within the scope of the present invention. Accordingly, equivalent alterations and modifications are intended to be included within the scope of the invention, without departing from the spirit and scope of the invention.