阅读说明：本技术 一种轻质高强钢包永久层浇注料及其制备方法 (Light high-strength steel ladle permanent layer castable and preparation method thereof ) 是由 王团收 刘琳琳 刘丽 颜浩 刘靖轩 任林 崔志强 李健 张盛 于 2021-02-05 设计创作，主要内容包括：本发明提供一种轻质高强钢包永久层浇注料及其制备方法,轻质高强钢包永久层浇注料按照质量份数计算,其制备原料包括以下组分：废中包盖回收骨料20-100份、轻质莫来石骨料5-50份、废刚玉砖回收细粉1-30份、纯铝酸钙水泥1-30份、硅微粉1-15份、白刚玉除尘粉0.5-10份、α氧化铝微粉0.5-10份、钢纤维0.5-10份、有机纤维0.05-2份、减水剂0.05-2份、防爆剂0.001-0.2份。该轻质高强钢包永久层浇注料及其制备方法,该钢包永久层浇注料强度高、体积密度和导热系数小,大大提高了钢包的保温性能,且使用多种废弃料作为骨料,实现了回收原料的重复利用,节约了资源和成本。(The invention provides a light high-strength steel ladle permanent layer castable and a preparation method thereof, wherein the light high-strength steel ladle permanent layer castable comprises the following preparation raw materials in parts by mass: 20-100 parts of recycled aggregate of the waste tundish cover, 5-50 parts of light mullite aggregate, 1-30 parts of recycled fine powder of the waste corundum brick, 1-30 parts of pure calcium aluminate cement, 1-15 parts of silicon micropowder, 0.5-10 parts of white corundum dust removal powder, 0.5-10 parts of alpha alumina micropowder, 0.5-10 parts of steel fiber, 0.05-2 parts of organic fiber, 0.05-2 parts of water reducing agent and 0.001-0.2 part of explosion-proof agent. The castable for the permanent layer of the steel ladle has high strength, small volume density and heat conductivity coefficient, greatly improves the heat insulation performance of the steel ladle, uses various waste materials as aggregates, realizes the recycling of recycled raw materials, and saves resources and cost.)

1. The lightweight high-strength steel ladle permanent layer castable is characterized by comprising the following preparation raw materials in parts by mass:

20-100 parts of recycled aggregate of the waste tundish cover, 5-50 parts of light mullite aggregate, 1-30 parts of recycled fine powder of the waste corundum brick, 1-30 parts of pure calcium aluminate cement, 1-15 parts of silicon micropowder, 0.5-10 parts of white corundum dust removal powder, 0.5-10 parts of alpha alumina micropowder, 0.5-10 parts of steel fiber, 0.05-2 parts of organic fiber, 0.05-2 parts of water reducing agent and 0.001-0.2 part of explosion-proof agent.

2. The lightweight high-strength steel ladle permanent layer castable according to claim 1, wherein the preparation raw materials comprise the following components in parts by weight:

40-60 parts of recycled aggregate of the waste tundish cover, 10-25 parts of light mullite aggregate, 5-15 parts of recycled fine powder of the waste corundum brick, 5-10 parts of pure calcium aluminate cement, 3-8 parts of silicon micropowder, 1-5 parts of white corundum dusting powder, 1-5 parts of alpha alumina micropowder, 1-5 parts of steel fiber, 0.1-0.5 part of organic fiber, 0.1-0.5 part of water reducing agent and 0.01-0.05 part of explosion-proof agent.

3. The lightweight high-strength ladle permanent layer castable according to claim 2, wherein the waste tundish cover recycled aggregate comprises the following components in parts by weight:

15-25 parts of waste tundish recycled particles with the particle size of 3-5mm, 10-20 parts of waste tundish recycled particles with the particle size of 1-3mm and 10-20 parts of waste tundish recycled particles with the particle size of 0-1 mm;

recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%.

4. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

the grain diameter of the light mullite aggregate is 5-8 mm; al in the light mullite aggregate₂O₃The content is more than 65 wt%.

5. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

the particle size of the recovered fine powder of the waste corundum brick is 0.074-0.083 mm; recovering Al from fine powder of waste corundum bricks₂O₃The content of (A) is more than 85 wt%.

6. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

the grain diameter of the white corundum dust removal powder is 0.044-0.074 mm; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%.

7. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%.

8. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

the grain diameter of the alpha alumina micro powder is 1.5-2 μm; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%.

9. The lightweight high-strength ladle permanent layer castable according to claim 1, wherein:

the steel fiber is a nickel-chromium alloy element-containing heat-resistant steel fiber; the organic fiber is polyethylene fiber, and the melting point of the polyethylene fiber is 100-110 ℃; the water reducing agent is sodium hexametaphosphate, wherein P₂O₅The content of (A) is more than or equal to 68 wt%; the grain diameter of the explosion-proof agent is 0.074-0.083 mm; the explosion-proof agent is metal aluminum powder.

10. A method of preparing a lightweight high strength ladle permanent layer castable material as claimed in any one of claims 1 to 9, comprising the steps of:

and mixing the preparation raw materials of the light high-strength ladle permanent layer castable to obtain the light high-strength ladle permanent layer castable.

Technical Field

The invention belongs to the technical field of refractory materials, and particularly relates to a lightweight high-strength steel ladle permanent layer castable and a preparation method thereof.

Background

In the modern steel smelting process, the ladle is an important device for connecting a converter process and a continuous casting process, and plays a role of a refining furnace in external refining devices such as an LF furnace, an RH furnace and the like. At present, the steel works in China generally adopt an integral high-alumina castable as a working lining of a permanent layer of a steel ladle. However, the castable for the permanent layer of the refractory ladle takes alumina as a main raw material, and has high heat conductivity coefficient and volume density, so that the heat loss of molten steel is high, and the heat insulation performance of the ladle is seriously influenced. The heat preservation performance of the steel ladle directly influences the tapping temperature of the smelting furnace, the quality of casting blanks, the heat dissipation of the ladle wall and the service life of the lining of the steel ladle.

Therefore, in order to meet the requirements of steel mill production quality and energy conservation and emission reduction, the development of a lightweight high-strength ladle permanent layer castable with good heat insulation performance, high strength, long service life and low refractory material cost is urgently needed to replace a high-aluminum permanent layer castable commonly adopted by the steel mill at present.

Disclosure of Invention

The invention solves the technical problem of providing a light-weight high-strength ladle permanent layer castable and a preparation method thereof, the ladle permanent layer castable has high strength, small volume density and heat conductivity coefficient, greatly improves the heat preservation performance of a ladle, uses various waste materials as aggregates, realizes the recycling of recovered raw materials, and saves resources and cost.

In order to solve the above problems, one aspect of the present invention provides a lightweight high-strength steel ladle permanent layer castable, which comprises the following preparation raw materials, by mass:

20-100 parts of recycled aggregate of the waste tundish cover, 5-50 parts of light mullite aggregate, 1-30 parts of recycled fine powder of the waste corundum brick, 1-30 parts of pure calcium aluminate cement, 1-15 parts of silicon micropowder, 0.5-10 parts of white corundum dust removal powder, 0.5-10 parts of alpha alumina micropowder, 0.5-10 parts of steel fiber, 0.05-2 parts of organic fiber, 0.05-2 parts of water reducing agent and 0.001-0.2 part of explosion-proof agent.

Wherein, the recovered aggregate of the waste tundish cover refers to particles obtained by dismantling, removing impurities, crushing, baking and screening the recovered waste tundish cover material; the recovered fine powder of the waste corundum brick refers to fine powder obtained by removing impurities, crushing, baking, grinding and screening the recovered corundum brick; the white corundum dust removal powder refers to white corundum fine powder recovered by dust removal equipment in the process of producing the white corundum fine powder.

The lightweight high-strength ladle permanent layer castable disclosed by the invention introduces lightweight mullite aggregate with a porous structure and waste tundish cover recovery particles, so that the volume density and the heat conductivity coefficient of the ladle permanent layer castable can be greatly reduced, and the heat insulation performance of a ladle is improved; by adding pure calcium aluminate cement, silica micropowder and alpha alumina micropowder and introducing two coagulation hardening mechanisms of hydration combination and coagulation combination, the strength and durability of the ladle permanent lining castable can be obviously improved, and the service life of the ladle permanent layer castable is prolonged; the recycling of the recycled raw materials is realized by introducing the recycled particles of the waste tundish cover, the recycled fine powder of the waste corundum brick and the white corundum dust-removing powder, and the resources and the cost are saved.

Preferably, the preparation raw materials comprise the following components in parts by weight:

40-60 parts of recycled aggregate of the waste tundish cover, 10-25 parts of light mullite aggregate, 5-15 parts of recycled fine powder of the waste corundum brick, 5-10 parts of pure calcium aluminate cement, 3-8 parts of silicon micropowder, 1-5 parts of white corundum dusting powder, 1-5 parts of alpha alumina micropowder, 1-5 parts of steel fiber, 0.1-0.5 part of organic fiber, 0.1-0.5 part of water reducing agent and 0.01-0.05 part of explosion-proof agent.

A large number of experimental researches show that when the preparation raw material proportion is adopted, the obtained ladle permanent layer castable has the lowest cost under the conditions of optimal strength, volume density, heat conductivity coefficient and heat preservation performance.

Preferably, the reclaimed aggregate of the waste tundish cover is composed of the following components in parts by weight:

15-25 parts of waste tundish recycled particles with the particle size of 3-5mm, 10-20 parts of waste tundish recycled particles with the particle size of 1-3mm and 10-20 parts of waste tundish recycled particles with the particle size of 0-1 mm;

recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%.

Preferably, the grain diameter of the light mullite aggregate is 5-8 mm; al in the light mullite aggregate₂O₃The content is more than 65 wt%.

Preferably, the particle size of the recovered fine powder of the waste corundum bricks is 0.074-0.083 mm; recovering Al from fine powder of waste corundum bricks₂O₃The content of (A) is more than 85 wt%.

Preferably, the particle size of the white corundum dust removal powder is 0.044-0.074 mm; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%.

Preferably, Al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%.

Preferably, the particle size of the alpha alumina micro powder is 1.5-2 μm; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%.

Preferably, the steel fiber is a nickel-chromium alloy element-containing heat-resistant steel fiber; the organic fiber is polyethylene fiber, and the melting point of the polyethylene fiber is 100-110 ℃; the water reducing agent is sodium hexametaphosphate, wherein P₂O₅The content of (A) is more than or equal to 68 wt%; the grain diameter of the explosion-proof agent is 0.074-0.083 mm; the explosion-proof agent is metal aluminum powder.

In another aspect of the present invention, a method for preparing the light high-strength ladle permanent layer castable is provided, which comprises the following steps:

and mixing the preparation raw materials of the light high-strength ladle permanent layer castable to obtain the light high-strength ladle permanent layer castable.

Compared with the prior art, the invention has the following beneficial effects:

the lightweight high-strength ladle permanent layer castable disclosed by the invention introduces lightweight mullite aggregate with a porous structure and waste tundish cover recovery particles, so that the volume density and the heat conductivity coefficient of the ladle permanent layer castable can be greatly reduced, and the heat insulation performance of a ladle is improved; by adding pure calcium aluminate cement, silica micropowder and alpha alumina micropowder and introducing two coagulation hardening mechanisms of hydration combination and coagulation combination, the strength and durability of the ladle permanent lining castable can be obviously improved, and the service life of the ladle permanent layer castable is prolonged; the recycling of the recycled raw materials is realized by introducing the recycled particles of the waste tundish cover, the recycled fine powder of the waste corundum brick and the white corundum dust-removing powder, and the resources and the cost are saved.

Detailed Description

The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Example 1

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

20 parts of waste tundish recycled particles with the particle size of 3-5mm, 15 parts of waste tundish recycled particles with the particle size of 1-3mm, 15 parts of waste tundish recycled particles with the particle size of 0-1mm, 17.5 parts of light mullite aggregate with the particle size of 5-8mm, 13 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 6 parts of pure calcium aluminate cement, 6 parts of silicon micropowder, 2 parts of white corundum dusting powder with the particle size of 0.044-0.074mm, 3 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 2 parts of aluminum powder steel fiber containing nickel-chromium alloy elements, 0.25 part of polyethylene fiber, 0.2 part of sodium hexametaphosphate and 0.02 part of metal with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; said scrap steelRecovery of Al from fine powder of jade brick₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 2

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

15 parts of waste tundish recycled particles with the particle size of 3-5mm, 19 parts of waste tundish recycled particles with the particle size of 1-3mm, 18 parts of waste tundish recycled particles with the particle size of 0-1mm, 15 parts of light mullite aggregate with the particle size of 5-8mm, 14 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 10 parts of pure calcium aluminate cement, 4 parts of silicon micropowder, 4 parts of white corundum dust removal powder with the particle size of 0.044-0.074mm, 2 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 1.5 parts of aluminum powder steel fiber containing nickel-chromium alloy elements, 0.2 part of polyethylene fiber, 0.3 part of sodium hexametaphosphate and 0.01 part of metal with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; the above-mentionedAl in alpha alumina micropowder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 3

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

25 parts of waste tundish recycled particles with the particle size of 3-5mm, 10 parts of waste tundish recycled particles with the particle size of 1-3mm, 20 parts of waste tundish recycled particles with the particle size of 0-1mm, 12 parts of light mullite aggregate with the particle size of 5-8mm, 15 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 4 parts of pure calcium aluminate cement, 5 parts of silicon micropowder, 5 parts of white corundum dust removal powder with the particle size of 0.044-0.074mm, 2.5 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 2.5 parts of heat-resistant steel fibers containing nickel-chromium alloy elements, 0.3 part of polyethylene fibers, 0.4 part of sodium hexametaphosphate and 0.04 part of metal with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 4

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

17.5 parts of waste tundish recycled particles with the particle size of 3-5mm, 12.5 parts of waste tundish recycled particles with the particle size of 1-3mm, 12.5 parts of waste tundish recycled particles with the particle size of 0-1mm, 25 parts of light mullite aggregate with the particle size of 5-8mm, 12 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 8 parts of pure calcium aluminate cement, 7 parts of silicon micropowder, 3 parts of white dust-removing powder with the particle size of 0.044-0.074mm, 3.5 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 3 parts of nickel-chromium alloy element-containing heat-resistant steel fibers, 0.15 part of polyethylene fibers, 0.5 part of sodium hexametaphosphate and 0.03 part of metal aluminum powder with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 5

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

22.5 parts of waste tundish recycled particles with the particle size of 3-5mm, 17.5 parts of waste tundish recycled particles with the particle size of 1-3mm, 10 parts of waste tundish recycled particles with the particle size of 0-1mm, 20 parts of light mullite aggregate with the particle size of 5-8mm, 8 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 5 parts of pure calcium aluminate cement, 3 parts of silicon micropowder, 1 part of white corundum dust-removing powder with the particle size of 0.044-0.074mm, 5 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 3.5 parts of heat-resistant steel fibers containing nickel-chromium alloy elements, 0.35 part of polyethylene fibers, 0.1 part of sodium hexametaphosphate and 0.05 part of metal aluminum powder with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 6

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

20 parts of waste tundish recycled particles with the particle size of 3-5mm, 20 parts of waste tundish recycled particles with the particle size of 1-3mm, 20 parts of waste tundish recycled particles with the particle size of 0-1mm, 10 parts of light mullite aggregate with the particle size of 5-8mm, 5 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 7 parts of pure calcium aluminate cement, 8 parts of silicon micropowder, 2 parts of white corundum dust removal powder with the particle size of 0.044-0.074mm, 1 part of alpha alumina micropowder with the particle size of 1.5-2 mu m, 5 parts of heat-resistant steel fibers containing nickel-chromium alloy elements, 0.5 part of polyethylene fibers, 0.3 part of sodium hexametaphosphate and 0.02 part of metal aluminum powder with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 7

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

10 parts of waste tundish recycled particles with the particle size of 3-5mm, 5 parts of waste tundish recycled particles with the particle size of 1-3mm, 5 parts of waste tundish recycled particles with the particle size of 0-1mm, 50 parts of light mullite aggregate with the particle size of 5-8mm, 1 part of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 30 parts of pure calcium aluminate cement, 15 parts of silicon micropowder, 0.5 part of white corundum dust-removing powder with the particle size of 0.044-0.074mm, 0.5 part of alpha alumina micropowder with the particle size of 1.5-2 mu m, 10 parts of heat-resistant steel fibers containing nickel-chromium alloy elements, 2 parts of polyethylene fibers, 0.05 part of sodium hexametaphosphate and 0.2 part of metal with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Example 8

The lightweight high-strength steel ladle permanent layer castable provided by the embodiment is prepared from the following raw materials in parts by mass:

30 parts of waste tundish recycled particles with the particle size of 3-5mm, 30 parts of waste tundish recycled particles with the particle size of 1-3mm, 40 parts of waste tundish recycled particles with the particle size of 0-1mm, 5 parts of light mullite aggregate with the particle size of 5-8mm, 30 parts of waste corundum brick recycled fine powder with the particle size of 0.074-0.083mm, 1 part of pure calcium aluminate cement, 1 part of silicon micropowder, 10 parts of white corundum dust removal powder with the particle size of 0.044-0.074mm, 10 parts of alpha alumina micropowder with the particle size of 1.5-2 mu m, 0.5 part of heat-resistant steel fiber containing nickel-chromium alloy element, 0.05 part of polyethylene fiber, 2 parts of sodium hexametaphosphate and 0.001 part of metal aluminum powder with the particle size of 0.074-0.083 mm.

Al in the light mullite aggregate₂O₃The content is more than 65 wt%; recovering Al in the aggregate by the waste tundish cover₂O₃The content is more than 70 wt%; recovering Al from fine powder of waste corundum bricks₂O₃Is greater than 85 wt%; al in the pure calcium aluminate cement₂O₃The content of (B) is not less than 70 wt%; SiO in the silicon micro powder₂The content of (B) is not less than 94 wt%; al in the white corundum dust removal powder₂O₃The content of (B) is not less than 98.5 wt%; al in the alpha alumina micro powder₂O₃The content of (B) is not less than 99 wt%; p in sodium hexametaphosphate₂O₅The content of (B) is more than or equal to 68 wt%.

Mixing the above prepared raw materials according to the selected granularity and proportion, performing dry mixing for 3 minutes to obtain the lightweight high-strength ladle permanent layer castable, adding 6.5wt% of water, stirring for 5 minutes, performing vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, and performing natural curing for 24 hours and demolding to obtain the lightweight high-strength ladle permanent layer castable finished product detection sample block.

Performance test of light high-strength steel ladle permanent layer castable

And (3) placing the light high-strength steel ladle permanent layer castable finished product detection sample block into an oven, drying for 24 hours at the temperature of 110 +/-5 ℃, and sintering the standard strip sample at 1450 ℃, wherein the heat preservation time is 3 hours. The physicochemical indexes of the obtained product are shown in the following table 1, and the data in the following table show that the products prepared from the lightweight high-strength ladle permanent layer castable have good compressive strength and thermal conductivity, wherein examples 1-6 are preferred embodiments.

TABLE 1

It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.