阅读说明：本技术 一种防火蓄能发光涂料及其制备工艺 (Fireproof energy-storage luminous paint and preparation process thereof ) 是由 李伟东 于 2020-03-18 设计创作，主要内容包括：本发明公开了一种防火蓄能发光涂料,其原料按重量的配方如下：水280-320份、羟乙基纤维素1-3份、分散剂3-5份、水质稳定剂3-5份、消泡剂1-3份、杀菌剂1-3份、乙二醇1-3份、水质PH调节剂1-3份、苯丙乳液180-220份、弹性乳液40-60份、消泡剂0.3-0.7份、成膜助剂8-12份、阻燃包覆发光粉350-450份、增稠剂1-5份。本发明还提供了一种防火蓄能发光涂料的制备工艺。该发光材料通过使用苯丙乳液为胶黏剂,能够使得该涂料具有较强的耐水,耐湿热性,耐冻融性能。(The invention discloses a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 320 parts of water 280-containing material, 1-3 parts of hydroxyethyl cellulose, 3-5 parts of a dispersing agent, 3-5 parts of a water quality stabilizing agent, 1-3 parts of a defoaming agent, 1-3 parts of a bactericide, 1-3 parts of ethylene glycol, 1-3 parts of a water quality pH regulator, 220 parts of a styrene-acrylic emulsion 180-containing material, 40-60 parts of an elastic emulsion, 0.3-0.7 part of a defoaming agent, 8-12 parts of a film forming auxiliary agent, 450 parts of flame-retardant coating luminescent powder 350-containing material and 1-5 parts of a thickening agent. The invention also provides a preparation process of the fireproof energy-storage luminous paint. The styrene-acrylic emulsion is used as the adhesive, so that the coating has strong water resistance, humidity resistance and freeze-thaw resistance.)

1. The fireproof energy-storage luminous paint is characterized by comprising the following raw materials in parts by weight: 320 parts of water 280-containing material, 1-3 parts of hydroxyethyl cellulose, 3-5 parts of a dispersing agent, 3-5 parts of a water quality stabilizing agent, 1-3 parts of a defoaming agent, 1-3 parts of a bactericide, 1-3 parts of ethylene glycol, 1-3 parts of a water quality pH regulator, 220 parts of a styrene-acrylic emulsion 180-containing material, 40-60 parts of an elastic emulsion, 0.3-0.7 part of a defoaming agent, 8-12 parts of a film forming auxiliary agent, 450 parts of flame-retardant coating luminescent powder 350-containing material and 1-5 parts of a thickening agent.

2. The fireproof energy-storage luminous paint as claimed in claim 1, wherein the raw materials are as follows by weight:

310 parts of 290-part water-doped material, 1.5-2.5 parts of hydroxyethyl cellulose, 3.5-4.5 parts of dispersing agent, 3.5-4.5 parts of water quality stabilizer, 1.5-2.5 parts of defoaming agent, 1.5-2.5 parts of bactericide, 1.5-2.5 parts of ethylene glycol, 1.5-2.5 parts of water quality pH regulator, 210 parts of styrene-acrylic emulsion 190-doped material, 45-55 parts of elastic emulsion, 0.4-0.6 part of defoaming agent, 9-11 parts of film-forming assistant, 425 parts of flame-retardant coating luminescent powder 375-doped material and 2-4 parts of thickening agent.

3. A fireproof energy-storage luminous paint as claimed in claim 2, wherein the raw materials are as follows by weight: 300 parts of water, 2 parts of hydroxyethyl cellulose, 4 parts of a dispersing agent, 4 parts of a water quality stabilizing agent, 2 parts of a defoaming agent, 2 parts of a bactericide, 2 parts of ethylene glycol, 2 parts of a water quality pH regulator, 200 parts of styrene-acrylic emulsion, 50 parts of elastic emulsion, 0.5 part of a defoaming agent, 10 parts of a film-forming assistant, 400 parts of flame-retardant coating luminescent powder and 3 parts of a thickening agent.

4. A process for preparing a fire-proof energy-storing luminous paint according to claim 1, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Technical Field

The invention relates to the technical field of luminescent paint preparation, in particular to a fireproof energy-storage luminescent paint and a preparation process thereof.

Background

At present, the comprehensive performance of most products in the market is difficult to meet the variable environmental use requirements, particularly the weather resistance is poor, and the weather resistance determines the service life and the performance of the coating, so that the enhancement of the weather resistance is the key of the energy storage luminescent coating, and therefore, a fireproof energy storage luminescent coating is provided.

Disclosure of Invention

The invention provides a fireproof energy-storage luminous paint and a preparation process thereof, which aim to solve the problems in the background technology.

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 320 parts of water 280-containing material, 1-3 parts of hydroxyethyl cellulose, 3-5 parts of a dispersing agent, 3-5 parts of a water quality stabilizing agent, 1-3 parts of a defoaming agent, 1-3 parts of a bactericide, 1-3 parts of ethylene glycol, 1-3 parts of a water quality pH regulator, 220 parts of a styrene-acrylic emulsion 180-containing material, 40-60 parts of an elastic emulsion, 0.3-0.7 part of a defoaming agent, 8-12 parts of a film forming auxiliary agent, 450 parts of flame-retardant coating luminescent powder 350-containing material and 1-5 parts of a thickening agent.

Preferably, the formula of the raw materials by weight is as follows:

310 parts of 290-part water-doped material, 1.5-2.5 parts of hydroxyethyl cellulose, 3.5-4.5 parts of dispersing agent, 3.5-4.5 parts of water quality stabilizer, 1.5-2.5 parts of defoaming agent, 1.5-2.5 parts of bactericide, 1.5-2.5 parts of ethylene glycol, 1.5-2.5 parts of water quality pH regulator, 210 parts of styrene-acrylic emulsion 190-doped material, 45-55 parts of elastic emulsion, 0.4-0.6 part of defoaming agent, 9-11 parts of film-forming assistant, 425 parts of flame-retardant coating luminescent powder 375-doped material and 2-4 parts of thickening agent.

Preferably, the formula of the raw materials by weight is as follows: 300 parts of water, 2 parts of hydroxyethyl cellulose, 4 parts of a dispersing agent, 4 parts of a water quality stabilizing agent, 2 parts of a defoaming agent, 2 parts of a bactericide, 2 parts of ethylene glycol, 2 parts of a water quality pH regulator, 200 parts of styrene-acrylic emulsion, 50 parts of elastic emulsion, 0.5 part of a defoaming agent, 10 parts of a film-forming assistant, 400 parts of flame-retardant coating luminescent powder and 3 parts of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Compared with the prior art, the invention has the beneficial effects that:

1. the styrene-acrylic emulsion is used as the adhesive, so that the coating has strong water resistance, humidity and heat resistance and freeze-thaw resistance;

2. the luminescent material adopts large-particle-size coated luminescent particles, namely a water-resistant coating protective layer is coated on the surfaces of the particles by a physical method, so that the material has higher weather resistance;

3. the luminescent material can absorb and store energy after being irradiated by light, and when the power supply is cut off in an emergency, the part coated with the energy storage type luminescent coating can automatically emit light in the dark to guide the trapped people to safely evacuate, so that the coating can be used for indicating marks of safety channels, safety doors and the like in public places;

4. the luminescent material has the advantages of no toxicity, no harm, no radioactivity, good weather resistance and light resistance, environmental protection, strong adsorption capacity, no decolorization after long-term use and good luminescent effect, thereby being used as an interior and exterior wall coating.

Detailed Description

The invention is further illustrated by the following examples.

Example 1

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 280 parts of water, 1 part of hydroxyethyl cellulose, 3 parts of a dispersing agent, 3 parts of a water quality stabilizing agent, 1 part of a defoaming agent, 1 part of a bactericide, 1 part of ethylene glycol, 1 part of a water quality pH regulator, 180 parts of a styrene-acrylic emulsion, 40 parts of an elastic emulsion, 0.3 part of a defoaming agent, 8 parts of a film-forming assistant, 350 parts of flame-retardant coating luminescent powder and 1 part of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Example 2

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 290 parts of water, 1.5 parts of hydroxyethyl cellulose, 3.5 parts of a dispersing agent, 3.5 parts of a water quality stabilizing agent, 1.5 parts of a defoaming agent, 1.5 parts of a bactericide, 1.5 parts of ethylene glycol, 1.5 parts of a water quality pH regulator, 190 parts of styrene-acrylic emulsion, 45 parts of elastic emulsion, 0.4 part of a defoaming agent, 9 parts of a film-forming assistant, 375 parts of flame-retardant coating luminescent powder and 2 parts of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Example 3

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 300 parts of water, 2 parts of hydroxyethyl cellulose, 4 parts of a dispersing agent, 4 parts of a water quality stabilizing agent, 2 parts of a defoaming agent, 2 parts of a bactericide, 2 parts of ethylene glycol, 2 parts of a water quality pH regulator, 200 parts of styrene-acrylic emulsion, 50 parts of elastic emulsion, 0.5 part of a defoaming agent, 10 parts of a film-forming assistant, 400 parts of flame-retardant coating luminescent powder and 3 parts of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Example 4

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 310 parts of water, 2.5 parts of hydroxyethyl cellulose, 4.5 parts of a dispersing agent, 4.5 parts of a water quality stabilizing agent, 2.5 parts of a defoaming agent, 2.5 parts of a bactericide, 2.5 parts of ethylene glycol, 2.5 parts of a water quality pH regulator, 210 parts of styrene-acrylic emulsion, 55 parts of elastic emulsion, 0.6 part of a defoaming agent, 11 parts of a film-forming assistant, 425 parts of flame-retardant coating luminescent powder and 4 parts of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

Example 5

The invention provides a fireproof energy-storage luminous paint which comprises the following raw materials in parts by weight: 320 parts of water, 3 parts of hydroxyethyl cellulose, 5 parts of a dispersing agent, 5 parts of a water quality stabilizing agent, 3 parts of a defoaming agent, 3 parts of a bactericide, 3 parts of ethylene glycol, 3 parts of a water quality pH regulator, 220 parts of a styrene-acrylic emulsion, 60 parts of an elastic emulsion, 0.7 part of a defoaming agent, 12 parts of a film-forming assistant, 450 parts of flame-retardant coating luminescent powder and 5 parts of a thickening agent.

The invention also provides a preparation process of the fireproof energy-storage luminous paint, which comprises the following steps:

s1, selecting a stirrer as an auxiliary tool, sterilizing the stirrer at 80-100 ℃, and adding water into the stirrer after the sterilization is finished;

s2, slowly putting the hydroxyethyl cellulose into a stirrer according to the proportion, mixing and stirring in the adding process, and then continuing to disperse for 2 min;

s3, after S2 is finished, adding the dispersing agent, the water quality stabilizer, the defoaming agent, the bactericide, the ethylene glycol, the water quality pH regulator, the defoaming agent and the film forming aid into the stirrer again, mixing and stirring the materials in the adding process, and then continuing to disperse for 5 min;

s4, after the above steps are finished, continuing to add the styrene-acrylic emulsion and the elastic emulsion, and then adjusting the rotating speed to 1500r/min for dispersing for 1min

And S5, finally adding the flame retardant to coat the luminescent powder, adjusting the rotating speed to 500r/min, dispersing for 10min, adding the thickening agent again, stirring for 5min, filling and weighing to obtain the fireproof energy storage luminescent coating.

The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.