Laminate assembly, diaper comprising such an assembly and method for manufacturing such an assembly
阅读说明:本技术 层压组件、包括这种组件的尿布和用于制造这种组件的方法 (Laminate assembly, diaper comprising such an assembly and method for manufacturing such an assembly ) 是由 皮埃尔-伊夫·弗朗索瓦·让·利诺 于 2019-03-20 设计创作,主要内容包括:本发明涉及一种层压组件,该层压组件包括支撑层(32)和防滑条(34),防滑条(34)包括弹性体材料,支撑层(32)和防滑条(34)被层压在一起,防滑条(34)包括基部(34A)和从基部(34A)延伸的多个突出元件(34B),并且多个突出元件(34B)从层压组件(30)的表面(30A)突出。本发明还涉及一种包括这种层压组件(30)的尿布和一种用于制造层压组件(30)的方法。本发明还涉及一种包括这种组件的尿布和一种用于制造这种组件的方法。(The present invention relates to a laminate assembly comprising a support layer (32) and a cleat (34), the cleat (34) comprising an elastomeric material, the support layer (32) and the cleat (34) being laminated together, the cleat (34) comprising a base (34A) and a plurality of projecting elements (34B) extending from the base (34A), and the plurality of projecting elements (34B) projecting from a surface (30A) of the laminate assembly (30). The invention also relates to a diaper comprising such a laminate assembly (30) and to a method for manufacturing a laminate assembly (30). The invention also relates to a diaper comprising such an assembly and to a method for manufacturing such an assembly.)
1. A laminate assembly (30) comprising a support layer (32) and a cleat (34), the cleat (34) comprising an elastomeric material, the support layer (32) and the cleat (34) being laminated together, the cleat (34) comprising a base (34A) and a plurality of projecting elements (34B) extending from the base (34A), and the plurality of projecting elements (34B) projecting from a surface (30A) of the laminate assembly (30).
2. The laminate assembly (30) of claim 1 wherein the support layer (32) comprises a nonwoven web (36, 38).
3. The laminate assembly (30) of claim 1 or 2, wherein the support layer (32) comprises a thermoplastic film.
4. The laminate assembly (30) of claim 3, wherein the thermoplastic film is an elastomeric film (40).
5. The laminate assembly (30) of claim 4, wherein the base (34A) of the cleat (34) and the elastic film (40) each have a width, the width (L34A) of the base (34A) being less than the width (L40) of the elastic film (40), preferably the width of the base being greater than or equal to 10% and less than or equal to 60% of the width of the elastic film.
6. The laminate assembly (30) of claim 4 or 5, wherein the support layer (32) comprises a first nonwoven web (36), a second nonwoven web (38), and the elastic film (40), the elastic film (40) being laminated between the first nonwoven web (36) and the second nonwoven web (38).
7. Laminate assembly (30) according to any one of claims 1 to 6, wherein, in a rest state, in the region comprising the protruding elements (34B), the cleats (34) have a static coefficient of friction, measured according to the standard ASTM D1894, greater than or equal to 0.1, preferably greater than or equal to 0.5, even more preferably greater than or equal to 0.8, and less than or equal to 10, preferably less than or equal to 5, even more preferably less than or equal to 3, in the direction MD and/or in the direction CD.
8. Laminate assembly (30) according to any one of claims 1 to 7, wherein the cleats (34) have a static coefficient of friction measured according to the standard ASTM D1894, comprised between 50% and 150% of the static coefficient of friction in the rest condition when the cleats (34) are stretched to 15% of the rest value.
9. The laminate assembly (30) according to any one of claims 1 to 8, whereinA protruding element density of the plurality of protruding elements (34B) in a resting state being greater than or equal to per cm23 projecting elements, preferably greater than or equal to per cm210 projecting elements and less than or equal to per cm2400 projecting elements, preferably less than or equal to per cm2300 protruding elements.
10. The laminate assembly (30) according to any one of claims 1 to 9, wherein, in a resting state, the plurality of projecting elements (34B) have a pattern comprising a repeating cleat pattern (44).
11. The laminate assembly (30) according to any one of claims 1 to 10, wherein the sum of the areas defined on the base (34A) by orthogonal projection of the protruding elements (34B) on the base (34A) is greater than or equal to 1%, preferably greater than or equal to 5%, and less than or equal to 40%, preferably less than or equal to 35%, of the total area of the base of the cleat pattern (44).
12. The laminate assembly (30) according to any one of claims 1 to 11, wherein the base (34A) has a thickness (E34A) greater than or equal to 10 μ ι η, preferably greater than or equal to 15 μ ι η, and less than or equal to 200 μ ι η, preferably less than or equal to 150 μ ι η.
13. The lamination assembly (30) according to any one of claims 1 to 12, wherein the protruding elements (34A) are pins and/or studs and/or rods, each rod having a head disposed at an end of the rod opposite the base.
14. An absorbent article, such as a disposable diaper, comprising a laminate assembly according to any of the preceding claims.
15. A method for manufacturing a laminated assembly (30), the method comprising the steps of:
-forming a cleat (34) by dispensing elastomeric material in a forming device (100), the cleat comprising a base (34A) and a plurality of protruding elements (34B) extending from the base (34A);
-assembling the support layer (32) and the cleats (34) by laminating the support layer (32) and the cleats (34).
Technical Field
The present disclosure relates to laminate assemblies that may be used in the hygiene field, particularly absorbent articles, especially for making elastic ears for diapers.
Background
Disposable diapers are typically composed of an absorbent central portion including at each end a front waistband portion having two front ears and a back waistband portion having two back ears for attaching the diaper to the wearer of the disposable diaper. Each back ear is usually provided with a retaining means, for example with a hook, which cooperates with an application area arranged on the front belt. In the hygiene field, this application area is commonly referred to as the "landing area", or in french terms, as the "comfort zone".
However, due to movement of the diaper wearer, the diaper may sag at the ears and/or the front ears may move relative to the back ears. Such sagging and/or shifting can cause discomfort to the diaper wearer and/or cause undesirable leakage.
Disclosure of Invention
The present invention aims to remedy at least some of these disadvantages.
To this end, the invention relates to a laminate assembly comprising a support layer and a cleat, the cleat comprising an elastomeric material, the support layer and the cleat being laminated together, the cleat comprising a base and a plurality of projecting elements extending from the base, and the plurality of projecting elements projecting from a surface of the laminate assembly.
By means of the cleats, in particular the projecting elements, the displacement of the other surface relative to the cleats is reduced when the laminate assembly is in contact with the other surface. However, the projecting elements do not allow the cleat to engage and hook with the other surface. For example, cleats make it impossible to hang 1kg (kilogram) of weight for a period of 10 seconds. In some cases, the 180 ° peel force of the cleats is less than or equal to 0.02N, and in some cases equal to 0N.
The direction MD refers to the machine direction and to the direction of travel of the cleats in the machine during manufacture of the cleats, and the direction CD refers to the cross direction and to the direction perpendicular to the direction MD.
The "180 ° peel" method is a method for measuring the peel force, i.e., the force separating the laminate assembly from the application area. This method is described below.
Conditioning of samples-test samples were conditioned at 23 ℃ ± 2 ℃ and 50% ± 5% relative humidity for 2h (hours).
Preparation of cleats-cleats are typically used in the direction MD. The cleats are typically in the form of belts, the length of which is in the direction MD. Bonding a portion of the tape in the MD to 80g/cm2And applying or rotating a 2kg (kilogram) roller on the cleats in one direction, and then applying or rotating the roller in the other direction (back and forth) along the entire length of the belt portion at a speed of about 700mm/min (millimeters/minute). The paper and cleats were cut with scissors into strips 25.4mm (millimeters) wide in the direction MD. The length of each paper strip is 210mm, and the anti-slip strip is located in the center of the paper.
Preparation of application area-application area the sample has a width in the direction MD of 50mm and a maximum length of 200mm and is cut in half longitudinally.
Assembly-place the strip on the application area sample so that the cleats are centered on the application area sample. A 2kg (kilogram) roller was applied or rotated on the cleats in one direction and then applied or rotated in the other direction (back and forth) along the entire length of the belt at a speed of approximately 700 mm/min. The application area sample was placed in the clamp of the cradle, the cut side was placed in the clamp, and a 1kg weight was hung from the lower portion of the tape for 10 seconds (seconds). The weight was then removed. This step ensures that the cleats and application area samples are assembled.
Measure-then place the assembly in a tensile tester with 100N (newton) measuring cells. The strip is inserted into the upper (movable) jaw. The reading of the load cell is set to zero. The application area sample was inserted into the lower jaw (stationary) and slight tension was applied. The force must be between 0.02N and 0.05N. During insertion, the spacing of the jaws was 50 mm. The assembly is centered between the two jaws. The test was performed with a constant displacement at a speed of 305mm/min, the test stroke being 50 mm. The test stroke is adjusted according to the width of the holding device to be tested.
Since the cleats are made of an elastomeric material, the cleats are elastic. The elasticity of the cleats imparts elasticity to the laminate assembly. Thus, when a laminate assembly is used, the laminate assembly can be stretched while the cleats themselves are stretched. Stretching of the laminate assembly allows for example the application of a pressure when attaching the disposable diaper to a wearer that is greater than the pressure applied by the laminate assembly without stretching. This higher pressure also reduces the risk of the surface in contact with the cleats moving and/or shifting relative to the cleats.
Since the cleats are made of an elastomeric material, they are soft to the touch for both the wearer and the person handling the diaper and minimize the risk of skin irritation.
As non-limiting examples of elastomeric materials, mention may be made of: styrene/isoprene (SI), styrene/isoprene/Styrene (SIs), styrene/butadiene/styrene (SBS), styrene-ethylene/butylene-styrene (SEBS), styrene-ethylene/propylene-styrene (SEPS) or SIBS copolymers. Mixtures of these elastomers with each other or with non-elastomers may also be considered, so as to modify certain properties other than elasticity. For example, to modify certain properties of the substrate (elasticity, heat resistance, processability, uv resistance, coloration, etc.), up to 50% by weight (or mass%) but preferably less than 30% by weight (or mass%) of a polymer, such as polyethylene styrene, polystyrene or poly-alpha-methylstyrene, epoxy polyesters, polyolefins, such as polyethylene or certain ethylene/vinyl acetates, preferably of high molecular weight (higher molar mass) may be added.
The elastomeric material may in particular be styrene-isoprene-styrene, which may be available, for example, from KRATON Polymers under the name KRATON D (registered trademark), or from DEXCO Polymers LP under the name VECTOR SBC 4211 (registered trademark). Thermoplastic elastomer (TPE) materials, particularly thermoplastic polyurethane elastomers, including pellettane (registered trademark) 2102-75A from the dow chemical company may also be used. Styrene-butadiene-styrene may also be used, including KRATON D-2122 (registered trademark) from Kraton Polymers, or VECTOR SBC 4461 (registered trademark) from Dexco Polymers LP. Alternatively, styrene-ethylene/butylene, including KRATON G-2832 (registered trademark) from KRATON polymers, or styrene-ethylene-butylene-styrene (SEBS) block copolymers, including KRATON (registered trademark) G2703.
This list is not exhaustive and can be accomplished by using all of the following: hydrogenated polyisoprene polymers, such as styrene-ethylene-propylene-styrene (SEPS), styrene-ethylene-propylene-styrene-ethylene-propylene (sepsepsep); hydrogenated polybutadiene polymers, such as styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-butylene (sebsebsebseb), styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-isoprene-butadiene-styrene (SIBS); hydrogenated polyisoprene/butadiene polymers such as styrene-ethylene-propylene-styrene (SEEPS); and commercially available vinyl hydrogenated polyisoprene/polystyrene triblock polymers such as HYBRAR 7311(kuraray america, inc., Houston, Tex.), and combinations thereof.
Configurations of polymer blocks, such as diblock, triblock, multiblock, star, and radial, are also contemplated in this disclosure. In some cases, higher molecular weight (or molar mass) block copolymers may be desired. The block copolymer may be available from Kraton Polymers U.S. LLC of Houston, Tex, under the names of, for example, Kraton MD6716, Kraton D1102, Kraton SIBS 1102, Kraton D1184, Kraton FG1901 and Kraton FG1924, and from Septon Company of America, Pasadena, Tex, under the names of Septon 8007, Septon V9827 and Septon 9618. Dynasol from spain is another potential supplier of these polymers. In particular, kraton md6716 SEBS triblock polymers are particularly suitable for the present disclosure.
Copolymers of isooctyl acrylate and acrylic acid with a monomer ratio of 90/10, which are thermoplastics with physical crosslinking in the absence of crosslinking agents, can also be used. A polyamide polyester block copolymer PEBAX (registered trademark) 2533 from Arkema may also be used.
Other possible materials are polyolefin polymers with elastomeric properties, mainly copolymers of ethylene and/or propylene, especially from metallocene-catalyzed substances, such as VISTA AXX VM-1120 (registered trademark), available from Exxon Mobil Chemical, or rubber-filled polymers, such as EPDM-filled Santoprene.
Examples of polyolefin-based thermoplastic elastomers suitable for use in the elastomeric film layer include, inter alia, crystalline polyolefins, e.g., homopolymers or copolymers of alpha-olefins having from 1 to 20 carbon atoms and including from 1 to 12 carbon atoms.
The homopolymers and copolymers described below are examples of crystalline polyolefins.
(1) Ethylene homopolymers, ethylene homopolymers can be prepared by any low pressure and high pressure process.
(2) Copolymers of ethylene with up to 10 mole% of an alpha-olefin other than ethylene or vinyl monomers such as vinyl acetate and ethyl acrylate; for example, ethylene octene copolymers are available under the trade name Engage 8407 or Engage8842(Dow Chemical, Houston, Tex).
(3) A propylene homopolymer; examples include polypropylene impact copolymer PP7035E4 and polypropylene random copolymer PP9574E6(Exxon Mobil, Houston, Tex.).
(4) A random copolymer of propylene with not more than 10 mole% of an alpha-olefin other than propylene.
(5) A block copolymer of propylene with not more than 30 mole% of an alpha-olefin other than propylene.
(6) A homopolymer of butene-1-butene.
(7) A random copolymer of 1-butene with no more than 10 mole% of an alpha-olefin other than 1-butene.
8) 4-methyl-1-pentene homopolymer.
(9) A random copolymer of 4-methyl-1-pentene and not more than 20 mole% of an alpha-olefin other than 4-methyl-1-pentene.
The α -olefins include, for example, ethylene, propylene, 1-butene, 4-methyl-1-pentene, 1-hexene and 1-octene.
Commercially available polyolefin-based thermoplastic elastomers for the elastomeric film layer include VISTA MAX. TM. (propylene-based elastomers available from ExxonMobil Chemical, Houston, Tex.), INFUSE. TM. (olefin block copolymers available from Dow Chemical Company, Midland, Michigan), VERSIFY. TM. (propylene-ethylene copolymers), such as VERSIFY. TM.4200 and VERSIFY. TM.4300(Dow Chemical Company, Midland, Michigan), ENGAGE. TM. (ethylene octane copolymers available from Dow Chemical, Houston, Tex.), and NOTIO 0040 and NOTIO 3560 (available from Mitsui Chemical (USA), New York, N.Y.), Adflex X100G (available from Lyondelsilcell).
In particularly suitable embodiments, the polyolefin-based thermoplastic elastomer is VISTAMAXX. tm.6102fl or VISTAMAXX 7050FLX (available from ExxonMobil Chemical, Houston, Tex.). The symbol "TM" of the registered trademark name corresponds to "trademark".
In another case, the thermoplastic elastomer may be a thermoplastic ester/ether elastomer or a thermoplastic polyurethane.
Elastomeric material refers to a material that can be stretched without breaking under the application of a tensile force applied in a given direction, and can substantially recover its original shape and size after release of the tensile force. For example, the elastomeric material is a film that retains, after elongation and release, a residual SET or residual (reference) of less than or equal to 30%, preferably less than or equal to 20%, even more preferably less than or equal to 10% of its initial dimension (before elongation) for an elongation of 100% of its initial dimension at room temperature (23 ℃ -c.) (residual SET is also referred to as "permanent SET" or "SET"). The elastomeric material may be a thermoplastic elastomeric material, in particular a physically cross-linked thermoplastic elastomeric material such as those described in the present disclosure, or a chemically cross-linked thermoplastic elastomeric material.
In some embodiments, at room temperature (23 ℃ -degrees celsius), the cleats have a residual deformation of less than or equal to 30% of their initial dimension (prior to elongation), preferably less than or equal to 20%, even more preferably less than or equal to 15%, even more preferably less than or equal to 10%, for an elongation of 100% of their initial dimension.
In some embodiments, at room temperature (23 ℃ -degrees celsius), the cleats have a residual deformation of less than or equal to 30% of their initial dimension (prior to elongation), preferably less than or equal to 20%, even more preferably less than or equal to 15%, even more preferably less than or equal to 10%, for an elongation of 100% of their initial dimension.
In some embodiments, the support layer is comprised of a nonwoven web (nonwoven web).
By nonwoven web is meant a product obtained by forming a web of consolidated fibers and/or filaments. Consolidation may be mechanical, chemical, or thermal and involves the presence of bonds between fibers and/or filaments. Such consolidation may be direct, i.e. directly between the fibers and/or filaments by welding, or indirect, i.e. through intermediate layers between the fibers and/or filaments, such as adhesion layers or adhesive layers. The term nonwoven refers to a tape-like or net-like structure of fibers and/or filaments interwoven in a non-uniform, irregular, or random manner. The nonwoven may be made from a variety of synthetic and/or natural materials. Examples of natural materials are cellulosic fibers such as cotton, jute, flax, etc., and may also include reprocessed cellulosic fibers such as rayon or viscose. Natural fibers for nonwoven webs can be prepared using various methods such as carding. Examples of synthetic materials include, but are not limited to, synthetic plastic polymers, which are known to form fibers, including, but not limited to: polyolefins such as polyethylene, polypropylene, polybutylene, and the like; polyamides such as polyamide 6, polyamide 10, polyamide 12, and the like; polyesters such as polyethylene terephthalate, polybutylene terephthalate, polylactic acid, and the like; a polycarbonate; polystyrene; a thermoplastic elastomer; a vinyl polymer; a polyurethane; and blends and copolymers thereof.
In some embodiments, the support layer may have a single layer structure or a multi-layer structure. The support layer may also be combined with another material to form a laminate. For example, the nonwoven may be a spunbond, spunmelt, thermobonded carded type of nonwoven, and the support layer may be SMS, SMMS, SS, SSs, SSMMS, SSMMMS, through air, or others. These examples are given in a non-limiting manner.
Nonwoven webs are formed, for example, from webs of fibers and/or filaments produced by dry-laid (dry), wet-laid (wet) or spun-laid techniques (melt/extrusion) and consolidated by mechanical, chemical and/or adhesive bonding.
The nonwoven web may be a calendered carded nonwoven.
A calender carded nonwoven is a nonwoven comprising a fibrous web having web consolidation points that are substantially uniformly distributed on the web by thermal consolidation. Consolidation ensures a certain cohesion of the fibers, allowing them to be handled and transported, in particular to be wound into rolls and unwound. Activation of the calendered carded nonwoven web makes it possible to lengthen and/or destroy the fibers of the nonwoven web and/or deform the consolidation points of the web. Thus increasing the elongation capability of the nonwoven web.
The fibers of the calendered carded nonwoven web are comprised between 1dTex and 8dTex, preferably between 1.3dTex and 6.7dTex, more preferably between 1.6dTex and 5.5 dTex.
Tex is the SI unit of the fineness of the textile fiber. It represents the weight of a 1000m (meter) fiber length.
In some embodiments, the support layer may comprise a nonwoven web forming an acquisition veil, particularly an acquisition veil of an absorbent article.
In some embodiments, the carrier layer may comprise a thermoplastic film.
Thermoplastic film refers to a film of thermoplastic material, which may be an elastic material or a non-elastic material.
A thermoplastic film of an elastic material refers to a film that can be stretched without breaking under the action of a tensile force applied in a given direction and that can substantially recover its original shape and dimensions after release of the tensile force. For example, a thermoplastic film of an elastomeric material is a film that retains a residual SET or residual after elongation and release of less than or equal to 30%, preferably less than or equal to 20%, even more preferably less than or equal to 10% of its initial dimension (before elongation) for an elongation of 100% of its initial dimension at room temperature (23 ℃) (residual SET is also referred to as "permanent SET" or "SET").
A thermoplastic film of a non-elastic material refers to a film that does not fall within the definition of a thermoplastic film of an elastic material.
When the thermoplastic film is made of a non-elastic material, the elasticity of the laminate assembly is imparted by the elastomeric material of the cleats, for example by using a weight of less than 30g/m2(grams per square meter) of a nonwoven fabric.
As non-limiting examples of thermoplastic materials, mention may be made of polyolefins, polyethylene, Linear Low Density Polyethylene (LLDPE), Low Density Polyethylene (LDPE), metallocene polyethylene (m-PE), High Density Polyethylene (HDPE), EVA (ethylene vinyl acetate) and PP (polypropylene), which comprise a monomodal or multimodal (for example bimodal) molecular weight (molar mass) distribution, in particular a composition comprising LLDPE and plastomers, in particular polyethylene-based plastomers. Polyamides (PA), polylactic acids (PLA), Polyhydroxyalkanoates (PHA), PVOH, PBS, polyesters, polyvinyl chloride (PVC) or Acrylonitrile Butadiene Styrene (ABS) may also be used.
In some embodiments, the thermoplastic film is an elastomeric film.
As a non-limiting example of the elastomeric material used to form the elastic membrane, mention may be made of the same elastomeric materials cited as non-limiting examples of elastomeric materials used to make the cleats.
In some embodiments, the elastic film may be formed of an elastic adhesive.
In some embodiments, the elastic membrane may include more than one layer or be a "skin layer," i.e., an elastic membrane covered by skin.
In some embodiments, the elastic film may be formed of an elastic adhesive.
In some embodiments, the elastic adhesive film may be extruded onto the nonwoven web and then laminated to the nonwoven web.
In some embodiments, the support layer is comprised of a nonwoven web and an elastic film.
In some embodiments, the base of the cleat and the elastic film each have a width, the width of the base being less than the width of the elastic film, preferably the width of the base is greater than or equal to 10% and less than or equal to 60% of the width of the elastic film.
In some embodiments, the area of the protruding element of the cleat and the base of the cleat each have a width, the width of the area of the protruding element being less than the width of the base of the cleat, preferably less than or equal to 60% of the width of the base, even more preferably less than or equal to 45% of the width of the base.
In some embodiments, the support layer may include a first nonwoven web, a second nonwoven web, and an elastic film laminated between the first nonwoven web and the second nonwoven web.
In some embodiments, in the rest state, in the region comprising the protruding elements, the cleats have a static coefficient of friction, measured according to standard ASTM D1894, greater than or equal to 0.1, preferably greater than or equal to 0.5, even more preferably greater than or equal to 0.8, and less than or equal to 10, preferably less than or equal to 5, even more preferably less than or equal to 3, in direction MD and/or direction CD.
By "at rest" is meant that the laminated assembly is not subjected to external forces, such as stretching forces. In other words, for example, in the diaper field, "at rest" means that the laminate is tested before first use by the end user, immediately after packaging, i.e., before the diaper is placed on a person. The measurement of the static friction coefficient may be performed in the longitudinal direction and/or in a lateral direction, which is orthogonal to the longitudinal direction. The measurement of the static friction coefficient may be performed in the direction MD and/or the direction CD.
The direction MD refers to the machine direction and to the direction of travel of the cleats in the machine during manufacture of the cleats, and the direction CD refers to the cross direction and to the direction perpendicular to the direction MD.
In some embodiments, the cleats have a static coefficient of friction measured according to standard ASTM D1894, comprised between 50% and 150% of the static coefficient of friction in the state of rest when the cleats are stretched to 15% of the value of rest.
The measurement of the static friction coefficient may be performed in the longitudinal direction and/or in a lateral direction, which is orthogonal to the longitudinal direction. The measurement of the static friction coefficient may be performed in the direction MD and/or the direction CD.
The dimension of the cleats in the direction MD is greater than the dimension in the direction CD.
In some embodiments, the cleats have a grammage per unit area greater than or equal to 10g/m2(g/m), preferably greater than or equal to 20g/m2And is less than or equal to 250g/m2Preferably less than or equal to 200g/m2。
In some embodiments, the support layers are bonded by adhesive bonding.
The adhesive may be applied continuously in the longitudinal direction and discontinuously in the lateral direction. Thus, the adhesive forms a plurality of adhesive lines that are continuous, for example, in the longitudinal direction. Of course, the width of the adhesive lines and their lateral spacing may be varied.
To measure the properties of the elastomeric material, the support layer may be separated from the elastomeric material by using, for example, acetone and/or ethyl acetate.
The elastic film may be formed of an elastic adhesive.
The elastic adhesive film may then be extruded onto and then laminated to the nonwoven web. The activated zones may extend the entire length of the nonwoven web as measured in the machine direction.
In some embodiments, the support layers are assembled by ultrasonic welding.
In the manufacture of the laminate assembly, ultrasonic welding is performed by passing the support layer between two rollers, one of which is an ultrasonic generator. One of the two rollers is an ultrasonic generator and the two rollers apply a force to the support layer perpendicular to the general plane defined by the support layer such that the support layer is laminated during ultrasonic welding.
In some embodiments, the support layer is joined by two methods selected from the following list: ultrasonic welding, high frequency welding, gluing or direct lamination (also known as thermal lamination).
In some embodiments, the plurality of projecting elements has a projecting element density greater than or equal to per cm in the resting state23 projecting elements, preferably greater than or equal to per cm210 projecting elements and less than or equal to per cm2400 projecting elements, preferably less than or equal to per cm2300 protruding elements.
In some embodiments, in the resting state, the plurality of projecting elements have a pattern that includes a repeating cleat pattern that extends across the width of the cleat.
The dimension of the cleats in the direction MD is greater than the dimension in the direction CD.
In some embodiments, the sum of the areas defined on the base by orthogonal projections of the protruding elements on the base is greater than or equal to 1% of the total area of the base of the cleat pattern, preferably greater than or equal to 5% of the total area of the base of the cleat pattern, and less than or equal to 60% of the total area of the base of the cleat pattern, preferably less than or equal to 40% of the total area of the base of the cleat pattern, more preferably less than or equal to 35% of the total area of the base of the cleat pattern.
In some embodiments, the thickness of the base is greater than or equal to 10 μm, preferably greater than or equal to 15 μm, and less than or equal to 200 μm, preferably less than or equal to 150 μm.
In some embodiments, the thickness of the substrate is variable.
In some embodiments, the protruding elements have a variable width.
The width of the protruding element is measured in a plane parallel to the plane XY of the base. The width of the protruding element is measured at the point of the protruding element having the largest width.
In some embodiments, the protruding elements may comprise protruding elements having different heights and/or different widths measured in a plane parallel to the plane XY.
In some embodiments, the protruding elements are pins and/or studs and/or rods, each rod having a head at an end of the rod opposite the base.
The head is arranged at an end of the protruding element opposite the base, in particular at an upper surface of the base.
"Pin" refers to a shape having no head or overhang and a maximum height greater than or equal to a maximum width. "stud (stud)" means a shape having a maximum height less than a maximum width. The pin, stud or rod has a portion of constant cross-section or a portion of reduced cross-section, the reduction facing away from the base.
In some embodiments, the height of the protruding element in a direction perpendicular to the base is greater than or equal to 0.05mm (millimeter), preferably greater than or equal to 0.10mm, and less than or equal to 0.80mm, preferably less than or equal to 0.50 mm.
In some embodiments, the width of the cleats in the resting state is greater than or equal to 5%, preferably greater than or equal to 10%, and less than or equal to 45%, preferably less than or equal to 30% of the total width of the laminate assembly.
These values are suitable, for example, for infant or child diapers or adult incontinence diaper applications.
In some embodiments, in the rest condition, the width of the cleats is comprised between 25% and 75% of the total width of the laminate assembly.
These values are suitable, for example, for absorbent article applications, such as infant or child diapers or adult incontinence diapers or feminine hygiene articles. These values can be measured once the absorbent article is assembled.
In some embodiments, in the rest condition, the width of the cleats is comprised between 55% and 100% of the total width of the laminate assembly.
These values are for example suitable for absorbent article applications, such as feminine hygiene articles. These values can be measured once the absorbent article is assembled.
In some embodiments, the support layer penetrates at least partially into the base of the cleat, for example the support layer is bonded to the cleat by direct lamination.
In some embodiments, the cleats are bonded to the support layer.
In some embodiments, the cleats are welded to the support layer by ultrasonic welding.
In some embodiments, the cleats and the elastic membrane are made of the same elastomeric material.
In some embodiments, the cleats and the elastic membrane are made of different elastomeric materials.
In some embodiments, the nonwoven web is activated before and/or after being combined with the elastic film.
In some embodiments, the base of the cleat may include two edges along the longitudinal direction, one of the edges having a peak and a valley, wherein a maximum deviation between the peak and the valley along a lateral direction orthogonal to the longitudinal direction is less than 1mm compared to a length along the longitudinal direction corresponding to three consecutive peaks.
In some embodiments, the edge has a portion of circular shape when viewed in cross-section along the longitudinal direction.
In some embodiments, the maximum distance between a peak and a valley in a lateral direction orthogonal to the longitudinal direction and over the length in the longitudinal direction corresponding to three consecutive peaks is comprised between 0.001mm and 1mm, more particularly between 0.001mm and 0.5mm, even more particularly between 0.001mm and 0.1 mm.
In some embodiments, the three consecutive peaks are smaller than the distance corresponding to the 15 steps of the protruding element, preferably smaller than the distance of 25 mm.
In some embodiments, the width of the base is greater than or equal to 1mm, preferably greater than or equal to 3mm, even more preferably greater than or equal to 5mm, and less than or equal to 500mm, preferably less than or equal to 250mm, even more preferably less than or equal to 100 mm.
In some embodiments, the stem of the protruding element is rotationally symmetric about an axis perpendicular to the upper surface of the base.
In some embodiments, the protruding elements have an asymmetric geometry with respect to a direction transverse to the longitudinal direction of the base.
In some embodiments, the protruding element is symmetrical with respect to a plane extending in the longitudinal direction of the base and passing through the axis of the stem of the protruding element.
In some embodiments, the support layer is comprised of a first nonwoven web and a second nonwoven web.
In some embodiments, the first nonwoven web and the second nonwoven web have the same properties.
In some embodiments, the first nonwoven web and the second nonwoven web are different in nature.
In some embodiments, the first nonwoven web and the second nonwoven web each comprise an inactivated zone 3 and a zone that is activated prior to assembly.
The cleats may be bonded and/or ultrasonically welded to the upper surface of the support layer. The cleats may also be engaged by directly laminating the cleats to cause the support layer to penetrate at least partially into the base before fully curing the base of the cleats.
In case the support layer is a set of thermally consolidated fibers and/or filaments, the bonding to the base is also achieved by penetration into the base of some of the fibers and/or filaments of the support layer.
If the support layer is a nonwoven web, then even if a weight of less than 80g/m is used2(material mass of nonwoven, in grams per square meter) the protruding elements can also be easily removed from the mold. For example, the weight of the nonwoven may be included at 5g/m2And 120g/m2Or at 25g/m2And 100g/m2Or between 10g/m2And 70g/m2In the meantime.
A particular advantage of this method of joining the supporting layer to the base comprising the projecting elements is that it does not cause deformation of the base, thus advantageously making it possible to maintain the shape of the base obtained during the injection-moulding step, and in particular to maintain the straight edges obtainable by the method and apparatus described below.
The present disclosure also relates to an absorbent article, in particular a disposable diaper, comprising a laminate assembly as defined above.
In some embodiments, the cleats of the laminate assembly are disposed on elastic ears of the absorbent article and/or inelastic ears of the absorbent article, the inelastic ears comprising, for example, a nonwoven.
In some embodiments, the cleats of the laminate assembly are disposed on elastic portions (such as elastic ears) of the absorbent article such that the projecting elements of the cleats extend toward the absorbent portion of the absorbent article.
In some embodiments, the cleats of the laminate assembly are disposed on the inelastic portions (e.g., inelastic ears) of the absorbent article such that the projecting elements of the cleats extend away from the absorbent portion of the absorbent article.
The present disclosure also relates to a method for manufacturing a laminated assembly, the method comprising the steps of:
-forming a cleat by dispensing elastomeric material in a forming device, the cleat comprising a base and a plurality of projecting elements extending from the base;
-assembling the support layer and the cleats by laminating the support layer and the cleats.
Direction MD refers to the machine direction and to the direction of travel of the support layer in the machine during the manufacture of the laminate assembly, direction CD refers to the cross direction and to the direction perpendicular to direction MD.
In some embodiments, the forming means may comprise a forming strip, the thickness of which is comprised between 100 μm (micrometer) and 500 μm.
In some embodiments, the assembly of the support layer and the cleat is performed before the base of the cleat is fully cured, such that the support layer penetrates at least partially into the base.
In some embodiments, the support layer may comprise a nonwoven web, and dispensing the elastomeric material through the nonwoven web in the forming device is accomplished.
In some embodiments, the assembly of the support layer and the cleats is performed by gluing.
In some embodiments, the assembly of the support layer and the cleats is performed by ultrasonic welding.
In some embodiments, the support layer may comprise an elastic membrane formed by dispensing an elastomeric material in a molding apparatus.
In some embodiments, the support layer may include an elastic film and at least one nonwoven fabric, the cleats being joined to the support layer by at least one nonwoven fabric layer.
In some embodiments, the support layer may include a nonwoven web and an elastic film, the elastic film being woven by dispensing an elastomeric material in a forming device, and the assembly of the nonwoven web being performed prior to the elastic film being fully cured to cause the nonwoven web to at least partially penetrate into the elastic film.
In some embodiments, the elastomeric material of the resilient membrane is dispensed in a molding device after the elastomeric material of the cleats has been dispensed.
In some embodiments, the cleats and the elastic membrane are made of the same elastomeric material.
In some embodiments, the support layer may comprise a second nonwoven web, the assembly of the second nonwoven web being performed prior to the elastic film being fully cured to cause the second nonwoven web to at least partially penetrate into the elastic film.
In some embodiments, the support layer may comprise a second nonwoven web, the assembly of the second nonwoven web being achieved by bonding and/or ultrasonically welding the second nonwoven web to the elastic film.
In some embodiments, the forming device may include a forming bar on which the cleats are formed and a rotational drive device.
In some embodiments, the forming device may comprise a device for forming the heads of the protruding elements, including a drive roller and a forming roller.
In some embodiments, the drive roller and the forming roller rotate at different speeds such that the heads of the projecting elements are asymmetric.
In some embodiments, the ratio of the speed of the drive roller to the speed of the forming roller is greater than or equal to 0.4, preferably greater than or equal to 0.65, and less than or equal to 1.6, preferably less than or equal to 1.35.
In some embodiments, the ratio of the speed of the drive roller to the speed of the forming roller is greater than or equal to 0.4, preferably greater than or equal to 0.65, and strictly less than 1.
In some embodiments, the ratio of the speed of the drive roller to the speed of the forming roller is equal to 1.
In some embodiments, the drive roller and the forming roller rotate at equal speeds such that the heads of the protruding elements are symmetrical and flat.
Drawings
Further features and advantages of the subject matter of the present disclosure will become apparent from the following description of embodiments, given by way of non-limiting example, with reference to the accompanying drawings, in which:
figure 1 is a schematic view of a diaper;
figure 2A is a schematic cross-sectional view according to plane II-II of figure 1 of a laminate assembly according to a first embodiment;
figure 2B is a schematic cross-sectional exploded view of the support layer;
figures 3 to 5 are schematic cross-sectional views of a lamination assembly according to other embodiments;
fig. 6 is a schematic cross-sectional view of the cleat;
figure 7 is a partially schematic cross-sectional view of a laminate assembly according to other embodiments;
fig. 8A-8F are schematic cross-sectional and top views of different embodiments of the cleats;
figure 9 is a partial schematic view of the top of the forming bar;
figures 10 and 11 are schematic cross-sectional views of the shaped bar in figure 9;
FIG. 12 is an enlarged schematic view of the pattern of the area XII of the profiled strip in FIG. 9;
figure 13 is a schematic view of a pattern of elements of a profiled bar according to other embodiments;
FIG. 14 is a schematic cross-section according to plane XIV-XIV of the profiled bar in FIG. 13;
15-18 are schematic views of a pattern of shaped bars according to other embodiments;
figure 19 shows a partial schematic cross-section according to plane XIX-XIX of the shaped bar, to form the pattern of figure 18;
fig. 20 is a schematic view of an example of a device for manufacturing cleats;
figures 21 to 23 are schematic views of an example of a plant for manufacturing laminated assemblies;
figures 24A-24C are schematic views of a lamination assembly;
FIG. 25 is a schematic view of a test sample;
figure 26 is a schematic view of an apparatus for performing elongation at break and/or deformation measurements;
fig. 27 is a graph showing the elongation at break curves of a laminate assembly comprising cleats and a laminate assembly without such cleats;
fig. 28 is a schematic view of an example of an apparatus for manufacturing cleats comprising forming means;
fig. 29 is a top view of the cleat, showing the edge characteristics of the bar.
Common elements are identified by the same numerical reference numerals throughout the drawings.
Detailed Description
Fig. 1 is a highly schematic view of a diaper 10, such as a disposable diaper. The diaper 10 is comprised of an absorbent core 12, a front waistband 14 having two front ears 16 and a back waistband 18 having two
Fig. 2A shows a first embodiment of a
Hereinafter, the term laminate assembly will refer to both an uncut laminate assembly and a laminate assembly that is cut into the front ears 16 and/or
The
The
The
In the embodiment shown in fig. 2A, the
As shown in fig. 6, the
The projecting
The projecting
The plurality of projecting
The protruding
As shown in fig. 7, the
In fig. 20 to 23 are shown projecting elements comprising a stem surmounted by a head.
Fig. 2B is an exploded view of two
In the embodiment shown in fig. 2B, the
In the embodiment shown in fig. 2B, the first
In the embodiment shown in fig. 2B, the activated regions 36B, 38B are equal in size along the lateral direction Y. They may differ from one web to another and/or within the same web. The first
An adhesive 42 is applied to the first
The
The
Thus, the assembly formed by the forming
The illustrated example including two
The
The
Specifically, the
The
The
In the example shown, the
The portion of the
The portion of the
The portion of the
The portion of the
In the example shown in the figures, the portion of the
The
The forming
The
Where injection of molding material is performed while molding
The use of the
The use of profiled
Furthermore, the production of the profiled strip is greatly simplified compared to the production of a roll with profiled cavities. In fact, such rollers are generally made by stacking successive sheets, thus requiring a plurality of machining operations, and resulting in considerable constraints during assembly and each time the reference of the projecting element is changed, and are of high mass, requiring the rollers to be held by their two ends, thus complicating their replacement.
Where it is desired to form the projecting
The separation between the
In the example shown, the
The
In fig. 28 is shown a protruding element comprising a rod surmounted by a head. These protruded elements are obtained by calendering the protruded elements shown in fig. 20-23 with a forming apparatus 120 comprising a drive roll 122 and a forming roll 124.
When a symmetrical and
When forming the
An example of a
The
The apparatus and associated processes set forth above may also have means and steps for assembling the
In order to perform the assembly of the supporting
Fig. 21 and 22 schematically show examples of
The apparatus shown is similar to that previously described with reference to figure 20; therefore, common elements will not be described in detail herein.
As can be seen in fig. 21 and 22, the apparatus as shown comprises a
The
In the example shown in fig. 21 and 22, the
The drive means 112 of the
The
More precisely, the lower surface 34AB of the
Since this application is performed before the
For example, considering a
The
The bond between
Where the
If the
This method of joining the supporting
In the case where the
The
The
The embodiment of fig. 3 differs from the embodiment of fig. 2A in that the
In this embodiment, the
Since this application is performed before
The second
In the embodiment of fig. 4, the
Typically, the first and second
Since this application is performed before
The
The apparatus of fig. 23 includes a second material-dispensing device disposed downstream of the material-dispensing
In the embodiment of fig. 5, the second
In the embodiment of fig. 2 to 4, the cleats are arranged midway along the lateral direction Y of the supporting
As shown in fig. 24A-24B, the
The
Fig. 9-19 illustrate molding strips 102 for forming
Fig. 9 is a partial view of the
For example,the
Fig. 13 is a view of the
For example, the
Fig. 15 to 19 are views similar to those in fig. 12, showing other patterns formed by the
For example, the
For example, the
For example, the
For example, the
As shown in fig. 29, the
Two edges B are defined for the
The projecting elements are generally arranged close to the edge B, for example, at a distance D from the edge B comprised between 2 pitches P and 3 pitches P of the projecting elements, generally equal to 2 pitches P or 3 pitches P, the distance D being measured along a lateral direction Y relative to the longitudinal direction X. The pitch P between two protruding elements corresponds to the distance between two protruding elements that are consecutive in the longitudinal direction. In the example shown in fig. 29, the projecting elements are arranged in columns along the longitudinal direction X, these columns being repeated identically along the lateral direction Y. The protruding elements may be arranged in a staggered or "honeycomb" arrangement, for example by displacing the protruding elements in the longitudinal direction.
As shown in fig. 29, each edge B has a series of peaks and valleys extending in the longitudinal direction L and extending in a plane parallel to the plane formed by the
The valleys are understood to be the areas of the edge B projecting inwardly from the
Thus, the regularity of the edge B can be evaluated by means of these successive peaks and valleys.
The edge B has a portion of circular shape when viewed in cross-section transverse to the longitudinal direction. In particular, the circular shape is oriented laterally outward of the
The above-described apparatus and method make it possible to obtain the edge B of the
Such a definition also applies to lengths corresponding to three consecutive valleys; the maximum distance between the peaks and the valleys in the lateral direction Y is less than 3mm, or more precisely less than 2mm, or more precisely less than 1mm, or is comprised between 0.001mm and 1mm, more particularly between 0.001mm and 0.5mm, more particularly between 0.001mm and 0.1 mm.
The 3 consecutive peaks or valleys are typically smaller than the distance corresponding to the 15 steps P of the protruding element, more preferably smaller than the distance of 25 mm.
Obtaining a "straight" edge B is advantageous because it eliminates the need for a subsequent step of making the edge straight (e.g., a cutting step), as such a straight edge is perceived by the user as an indicator of product quality.
Furthermore, the apparatus and method used make it possible to obtain such straight edges without having an extra thickness at the edges of the strip, since such extra thickness is not functionally relevant.
As can be appreciated from the above description, a straight edge is obtained by injection molding material through the
In order to measure the static friction coefficient, the residual deformation and the elongation at break, measurement samples were prepared in a similar manner and according to the following method.
The laminate assembly was conditioned for 24 hours at a temperature of 23 ℃ ± 2 ℃ and a relative humidity of 50% ± 5% in a conventional atmosphere as defined in ASTM D5170.
The static friction coefficient was measured according to ASTM D1894 by moving a 200g (g) pad having an area of 63mm by 63mm on the surface of the cleat at a speed of 150mm/min (mm/min).
In the first part of the test, a sample of the laminated assembly was attached in an absolutely flat state to the rubbing stage of the test system using an adhesive tape. The types of belts that may be used to adhere the material sample to the friction table are well known to those of ordinary skill in the art and will not be described in further detail in this document.
In another part of the test, the front ear made from a spunbond nonwoven available from "TEXBOND nonwovens" under the brand ULTRATEX D1A 60X (60gsm PP (grams per square centimeter)) was located on the lower surface of the pad facing the upper surface of the laminate assembly sample, with the spunbond calendered surface facing the upper surface of the laminate assembly sample. The pad is translated over a length of at least 15mm over the sample to be tested, so that a value of the static friction coefficient can be obtained.
To measure the static coefficient of friction at 15% elongation, a sample of the
For a sample of laminate assembly without cleats, for example a laminate assembly sold under the name "
For a laminate assembly comprising a
For a laminate assembly comprising a
For a laminate assembly comprising a
For measuring the residual deformation and elongation at break, the measuring device is a dynamometer according to EN 10002, for example Synergy 200H,1column available from MTS Systems corp. together with the TESTWORKS 4.04B user software.
The
The
Each edge of the
The elongation at break test is performed at a constant speed of movement of the
The elongation at break test gives an elongation at break of 10N (newtons) expressed as a percentage of the initial dimension of the
The elongation at break test curve is shown in fig. 27. On the graph in fig. 27, the x-axis represents the elongation in percent of the original dimension of the
The residual deformation test was performed on the same equipment with the same type of sample as
The moving jaws have a constant speed of 508mm/min, the initial jaw distance is 40mm, and the sample is stretched until a force of 10N is reached. Once a force of 10N is reached, the movement of the movable jaw is stopped and the gap is maintained for 30 seconds. The jaws are then moved to their starting position at a constant speed and the
The result is a curve that gives the tensile force in N as a function of the elongation in% of the original sample size. The curve has hysteresis, and the residual deformation or SET deformation at the end of the cycle is determined as follows: SET-the intersection with the x-axis of the curve measured during the movement of the movable jaw when the movable jaw returns to its starting position (i.e. the jaw spacing is 40 mm).
While the present disclosure has been described with reference to specific example embodiments, it will be evident that various modifications and changes may be made to these examples without departing from the general scope of the invention as defined by the claims. Furthermore, individual features of the different embodiments mentioned may be combined in further embodiments. The specification and drawings are, accordingly, to be regarded in an illustrative rather than a restrictive sense. For example, the cleats may have a direction MD that is non-parallel to the direction MD of the support layer. As an alternative to the embodiments of fig. 2A to 8F, 20 to 25 and 28, it is possible to have studs and/or pins and/or rods covered on top with a head according to fig. 20 to 23 and/or rods covered on top with a head according to fig. 28.
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