阅读说明：本技术 包含3-芳基-6-三氟甲基哒嗪醇类化合物的除草组合物及其应用 (Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof ) 是由 彭学岗 赵德 刘娜 张景远 金涛 于 2019-04-22 设计创作，主要内容包括：本发明属于农药领域,具体涉及一种包含3-芳基-6-三氟甲基哒嗪醇类化合物的除草组合物及其应用。所述除草组合物包括除草有效量的活性成分A和活性成分B,其中,活性成分A选自通式Ⅰ所示化合物中的一种或两种以上：<Image he="231" wi="299" file="DDA0002326335440000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>X代表未取代或取代的芳基；优选地A为<Image he="265" wi="425" file="DDA0002326335440000012.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>活性成分B选自以下化合物及其盐/酯中的一种或多种：HPPD抑制剂、PDS抑制剂、DOXP抑制剂、ALS抑制剂、ACCase抑制剂、PPO抑制剂、PSII抑制剂、微管组装抑制剂等。该组合物能有效防除作物田中的藜、绿色狗尾草、宝盖草、野燕麦、反枝苋、稗草等杂草问题,具有扩大杀草谱、减少施用量、能够产生增效作用并解决抗性杂草等特点。(The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof. The weeding composition comprises an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is selected from one or more than two compounds shown in a general formula I: x represents an unsubstituted or substituted aryl group; preferably A is The active ingredient B is selected from one or more of the following compounds and salts/esters thereof: HPPD inhibitors, PDS inhibitors, DOXP inhibitors, ALS inhibitors, ACCase inhibitors, PPO inhibitors, PSII inhibitors, microtubule assembly inhibitors, and the like. The composition can effectively prevent and kill off the problems of weeds such as chenopodium quinoa, green setaria viridis, Japanese pennywort herb, wild oat, Amaranthus retroflexus, barnyard grass and the like in crop fields, and has the characteristics of expanding a weed control spectrum, reducing the application amount, generating a synergistic effect, solving resistant weeds and the like.)

1.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds, characterized by comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein,

the active ingredient A is selected from one or more than two compounds shown in a general formula I:x represents an unsubstituted or substituted aryl group;

the active ingredient B is selected from one or more of the following compounds and salts/esters thereof:

(1) HPPD inhibitors: sulcotrione, mesotrione, topramezone, tembotrione, fluroxypyr, mesotrione, bicyclosulfuron, topramezone, trazodone, triazophone, topramezone, pyrazote, pyraflutole, tolpyralate, fenquinotrione, isoxaflutole, pyraclonil, fenflurazone, topramezone,

(2) (ii) a PDS inhibitor: flurtamone, diflufenican, beflubutamid, fluroxypyr and fluridone;

(3) a DOXP inhibitor: clomazone, bixlazone;

(4) ALS inhibitors: tribenuron-methyl, thifensulfuron-methyl, bensulfuron-methyl, pyrazosulfuron-ethyl, thiencsulfuron-methyl, halosulfuron-methyl, propyrisulfuron-methyl, metrisulfuron-methyl, rimsulfuron-methyl, flucarbazone-methyl, mesosulfuron-methyl, nicosulfuron-methyl, foramsulfuron-methyl, flumetsulam-methyl, triasulfuron-methyl, fluazincarbazide-methyl, penoxsulam-methyl, cloransulam-methyl, pyroxsulam-methyl, imazamox, imazethapyr, imazapyr, pyriminobac-methyl, florasulam, pyribenzoxim-methyl, propbensulfuron-methyl, imazethapyr-methyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, amidosulfuron, triasulfuron-methyl, tribenuron-methyl, iodosulfuron-methyl sodium, flazasulfuron-methyl, flucetosulfuron, metsulfuron-methyl, triflusulfuron-methyl, sulfosulfuron-methyl, pyrazosulfuron-methyl;

(5) ACCase inhibitors: clodinafop-propargyl, pinoxaden, clethodim, sethoxydim, quizalofop-p-ethyl, tralkoxydim, fluazifop-p-butyl, haloxyfop-methyl, diclofop-methyl, fenoxaprop-p-ethyl, cyhalofop-butyl, clethodim, metamifop, oxadiargyl;

(6) PPO inhibitors: oxyfluorfen, fomesafen, oxadiazon, oxadiargyl, sulfentrazone, pyraclonil, flumioxazin, pentoxazone, tiafenacil, saflufenacil, pyraflufen, carfentrazone-ethyl, butafenacil, trifluoromethoxyfen, triflumimoxazin, metribuzin methyl ester;

(7) PSII inhibitors: atrazine, prometryn, simetryn, terbuthylazine, terbutryn, ametryn, ipratron, fenfluryn, diquat, simazine, metribuzin, ethiprole, amicarbazone, metamitron, cyanazine, chlortoluron, isoproturon, diuron, fluometuron, linuron, buthiuron, sumuron, gluron, bromuron, glufosinate, pyridazinol, hexazinone, isoethazine, prodazine, bromacil, lenacil, triclopyr, thiuron, isoxauron, metoxuron, subtilon, trifluoxazine, cycloprozoximate, propanil, pyridate, desmetryn, bromoxynil octanoate, bromoxynil, ioxynil;

(8) microtubule assembly inhibitors: trifluralin, butralin, pendimethalin, dithiopyr, butyfluing, oryzalin, sulfluralin, flumetsulam, fenthizamide, natremit, chlorthal and butafosinate;

(9) microtubule combination inhibitors: diacyl urea;

(10) VLCFA inhibitors: acetochlor, butachlor, pretilachlor, metolachlor, mefenacet, s-metolachlor, flufenacet, napropamide, pyroxafen, anilofos, dimethenamid, fentrazamide, triazolamide, cafenstrole, mephos, propisochlor, metazachlor, propyzamide, pethoxamid;

(11) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb, molinate, prosulfocarb, furbengal, ethofumesate, triallate, dichlormate, dichlorvos, penflufen and penflufen;

(12) synthesis of hormones: quinclorac, fluroxypyr-meptyl, triclopyr, clopyralid, picloram, aminopyralid, dicamba, fluroxypyr, 2-methyl-4-chlorophenoxyacetic acid, 2-methyl-4-chloro-phenothiolester, MCPB, 2-methyl-4-chlorophenoxypropionic acid, 2-methyl-4-sodium chlorophenoxyacetate, 2-methyl-4-isooctyl chlorophenoxyacetate, 2, 4-butyl dichlorophenoxyacetate, 2, 4-isooctyl dichlorophenoxyacetate, 2, 4-dichlorophenoxyacetate, chloroquinolinic acid, 2-methyl-4-chlorodimethylammonium salt, 2, 4-dichlorpropionic acid, 2, 4-dichlorbutyric acid, benazolin and cyprodinil;

(13) EPSPS inhibitors: glyphosate, phosphinothricin;

(14) a GS inhibitor: glufosinate, bialaphos, refined glufosinate;

(15) PSI inhibitor selected from paraquat, diquat;

(16) DHP inhibitors: asulam;

(17) cellulose synthesis inhibitors: triazinyl flufenacet, indexazine flufenacet;

(18) other herbicides: oxaziclomefone, cinmethylin, indanthrone, quinclomazone, cumyluron, tetflupyrlomet.

2.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 1, wherein X represents pyrazolyl which is unsubstituted or substituted by at least one group selected from C1-C6 alkyl, halo-substituted C1-C6 alkyl, cyano, halogen, C1-C6 alkoxy, C1-C6 alkylcarbonyl; preferably, X represents

3.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 1 or 2, wherein the weight ratio of A, B is 1:1000 to 200:1 and 1:600 to 150: 1; preferably 1: 500-100: 1 and 1: 400-80: 1; more preferably 1: 300-60: 1 and 1: 200-50: 1; further preferably 1: 100-30: 1 and 1: 50-20: 1; further preferred are 1:20 to 10:1, 1:10 to 5:1 and 1:5 to 1: 1.

4.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to any of the claims 1 to 3, wherein A, B represents 1 to 95% by weight of the total amount, preferably 10 to 80% by weight.

5.A herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compounds according to any one of claims 1 to 3, wherein conventional adjuvants are further included, preferably the conventional adjuvants include carriers, surfactants.

6. The herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to any one of claims 1 to 5, wherein the herbicidal composition further comprises at least one safener.

7.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 6, wherein the safener is selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet, gibberellic acid, furilazole, mecamifen.

8. The herbicidal composition containing the 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 7, wherein the formulation of the herbicidal composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.

9. Use of the herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 8 for controlling weeds.

10.A method for controlling unwanted plant growth, which comprises applying the herbicidal composition comprising a 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 8 to a plant, a plant part, a plant seed or an area where a plant is grown.

Technical Field

The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof.

Background

Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time. The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. For example, patent CN1543455A describes a herbicidal composition containing 3-phenoxy-4-pyridazinol derivatives, and there is still a need for the development of a herbicidal composition having high safety, broad herbicidal spectrum, synergistic effect and solving the problem of resistant weeds.

Disclosure of Invention

In order to solve the problems in the prior art, the invention provides a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof. The composition can effectively prevent and kill off the problems of weeds such as chenopodium quinoa, green setaria viridis, Japanese pennywort herb, wild oat, Amaranthus retroflexus, barnyard grass and the like in crop fields, and has the characteristics of expanding a weed control spectrum, reducing the application amount, generating a synergistic effect, solving resistant weeds and the like.

A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein,

the active ingredient A is selected from one or more than two compounds shown in a general formula I:x represents an unsubstituted or substituted aryl group;

the active ingredient B is selected from one or more of the following compounds and salts/esters thereof:

(1) HPPD inhibitors: sulcotrione (A)CAS number 99105-77-8), mesotrione (CAS number 104206-82-8), topramezone (CAS number 210631-68-8), tembotrione (CAS number 335104-84-2), flurtamone (CAS number 352010-68-5), benzoxaflutole (CAS number 473278-76-1), bicyclosulfatone (CAS number 156963-66-5), diconazole (CAS number 1622908-18-2), ciclopirox (CAS number 1855929-45-1), triazophorione (CAS number 1911613-97-2), topramezone (CAS number 1992017-55-6), fenpyrazazole (CAS number 365400-11-9), pyrazote (CAS number 58011-68-0), pyroxaflutole (CAS number 82692-44-2), tolpyrate (CAS number: 1101132-67-5), fenquinotrione (CAS number: 1342891-70-6), isoxaflutole (CAS number: 141112-29-0), penflufen (CAS number: 71561-11-0),

(2) (ii) a PDS inhibitor: flurtamone (CAS number: 61213-25-0), flurtamone (CAS number: 96525-23-4), diflufenican (CAS number: 83164-33-4), diflufenican (CAS number: 137641-05-5), beflubutamid (CAS number: 113614-08-7), norflurazon (CAS number: 27314-13-2), and fluridone (CAS number: 59756-60-4);

(3) a DOXP inhibitor: clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);

(4) ALS inhibitors: tribenuron-methyl (CAS number: 101200-48-0), thifensulfuron-methyl (CAS number: 79277-27-3), bensulfuron-methyl (CAS number: 83055-99-6), pyrazosulfuron-ethyl (CAS number: 93697-74-6), thiencarbazone-methyl (CAS number: 317815-83-1), halosulfuron-methyl (CAS number: 100784-20-1), propyrisulfuron (CAS number: 570415-88-2), metazosulfuron-methyl (CAS number: 868680-84-6), rimsulfuron-methyl (CAS number: 122931-48-0), ethoxysulfuron (CAS number: 126801-58-9), pyriminosulfuron-methyl (CAS number: 213464-77-8), flucarbazone-methyl (CAS number: 181274-17-9), mesosulfuron-methyl (CAS number: 208465-21-8), nicosulfuron (CAS number: 111991-09-4), Foramsulfuron (CAS number: 173159-57-4), flumetsulam (CAS number: 98967-40-9), triafamone (CAS number: 874195-61-6), penoxsulam (CAS number: 219714-96-2), cloransulam-methyl (CAS number: 147150-35-4), pyroxsulam (CAS number: 422556-08-9), imazamox (CAS number: 114311-32-9), imazapic (CAS number: 104098-48-8), imazethapyr (CAS number: 81385-77-5), imazapyr (CAS number: 81334-34-1), pyriminobac (CAS number: 147411-69-6), florasulam (CAS number: 145701-23-1), pyribenzoxim (CAS number: 135186-78-6), pyribenzoxim (CAS number: 168088-61-7), Tribenuron-methyl (CAS number: 145026-81-9), imazethapyr (CAS number: 81335-77-5), chlorsulfuron (CAS number: 64902-72-3), cinosulfuron (CAS number: 94593-91-6), cyclosulfamuron (CAS number: 136849-15-5), amidosulfuron (CAS number: 120923-37-7), triasulfuron (CAS number: 82097-50-5), iodosulfuron-methyl sodium salt (CAS number: 144550-36-7), flupyrsulfuron (CAS number: 144740-54-5), flucetosulfuron (CAS number: 412928-75-7), metsulfuron (CAS number: 74223-64-6), triflusulfuron (CAS number: 142469-14-5), sulfosulfuron (CAS number: 141776-32-1), pyrazosulfuron (CAS number: 122548-33-8), Bispyribac-sodium (CAS number: 125401-92-5), and sulfentrazone (CAS number: 139528-85-1);

(5) ACCase inhibitors: clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8), clethodim (CAS number: 99129-21-2), sethoxydim (CAS number: 74051-80-2), quizalofop-p-ethyl (CAS number: 100646-51-3), tralkoxydim (CAS number: 87820-88-0), fluazifop-p-butyl (CAS number: 69806-50-4), haloxyfop-R (CAS number: 72619-32-0), diclofop-p-methyl (CAS number: 51338-27-3), fenoxaprop-p-ethyl (CAS number: 113158-40-0), cyhalofop-butyl (CAS number: 122008-85-9), clethodim (CAS number: 139001-49-3), metamifop (CAS number: 256412-89-2), oxadiargyl (CAS number: 111479-05-1);

(6) PPO inhibitors: fluroxypyr ether (CAS number: 42874-03-3), fomesafen (CAS number: 72178-02-0), oxadiazon (CAS number: 19666-30-9), oxadiargyl (CAS number: 39807-15-3), sulfentrazone (CAS number: 122836-35-5), pyraclonil (CAS number: 158353-15-2), flumioxazin (CAS number: 103361-09-7), pentoxazone (CAS number: 110956-75-7), tiafenacil (CAS number: 1220411-29-9), saflufenacil (CAS number: 372137-35-4), pyraflufen (CAS number: 129630-19-9), carfentrazone (CAS number: 128621-72-7), butafenacil ester (CAS number: 134605-64-4), fluroxypyr ether ethyl ester (CAS number: 131086-42-5), Fluoroglycofen-ethyl (CAS No. 77501-60-1), fluoroglycofen-ethyl (CAS No. 50594-66-6), triflumimoxazin (CAS No. 1258836-72-4), and azinam-methyl (CAS No. 117337-19-6);

(7) PSII inhibitors: atrazine (CAS number: 1912-24-9), prometryn (CAS number: 7287-19-6), simetryn (CAS number: 1014-70-6), terbuthylazine (CAS number: 5915-41-3), terbutryn (CAS number: 886-50-0), ametryn (CAS number: 834-12-8), ipratropium (CAS number: 4147-51-7), fenflurazine (CAS number: 845-52-3), prometryn (CAS number: 1014-69-3), simazine (CAS number: 122-34-9), metribuzin (CAS number: 87-21064-9), ethiprole (CAS number: 64529-56-2), amicarbazone (CAS number: 129909-90-6), metribuzin (CAS number: 41394-05-2), cyanazine (CAS number: 21725-46-2), Chlortoluron (CAS number: 15545-48-9), isoproturon (CAS number: 34123-59-6), diuron (CAS number: 330-54-1), fluometuron (CAS number: 2164-17-2), linuron (CAS number: 330-55-2), buthiuron (CAS number: 34014-18-1), cypermethron (CAS number: 42609-52-9), chlortoluron (CAS number: 1746-81-2), bromuron (CAS number: 3060-89-7), endothel (CAS number: 555-37-3), pyridazinol (CAS number: 40020-01-7), hexazinone (CAS number: 51235-04-2), isoethazine (CAS number: 22936-75-0), prodrazine (CAS number: 1912-26-1), bromacil (CAS number: 314-40-9), Cyclinadine (CAS number: 2164-08-1), terbacil (CAS number: 5902-51-2), methabenzthiazuron (CAS number: 18691-97-9), cyclosulfamuron (CAS number: 1982-49-6), isoxaben (CAS number: 55861-78-4), metoxuron (CAS number: 19937-59-8), cumuron (CAS number: 1982-47-4), trifluoxazine (CAS number: 1258836-72-4), cyclopyromate (CAS number: 499231-24-2), propanil (CAS number: 709-98-8), pyridate (CAS number: 55512-33-9), betalain (CAS number: 13684-56-5), betanin (CAS number: 13684-63-4), bentazone (CAS number: 25057-89-0), bromoxynil octanoate (CAS number: 1689-99-2), Bromoxynil (CAS number: 1689-84-5), ioxynil (CAS number: 1689-83-4);

(8) microtubule assembly inhibitors: trifluralin (CAS number: 1582-09-8), butralin (CAS number: 33629-47-9), pendimethalin (CAS number: 40487-42-1), dithiopyr (CAS number: 97886-45-8), ethambucil (CAS number: 55283-68-6), oryzalin (CAS number: 19044-88-3), flumetsulam (CAS number: 1861-40-1), thiabendazole (CAS number: 117718-60-2), propaquilate (CAS number: 23950-58-5), dichlorvos (CAS number: 1861-32-1) and phorate (CAS number: 36335-67-8);

(9) microtubule combination inhibitors: diacyl-amine (CAS number: 16118-49-3);

(10) VLCFA inhibitors: acetochlor (CAS number: 34256-82-1), butachlor (CAS number: 23184-66-9), pretilachlor (CAS number: 51218-49-6), metolachlor (CAS number: 87392-12-9), mefenacet (CAS number: 73250-68-7), s-metolachlor (CAS number: 178961-20-1), flufenacet (CAS number: 142459-58-3), alachlor (CAS number: 15299-99-7), pyriflufen (CAS number: 447399-55-5), anilofol (CAS number: 64249-01-0), xylenol oxamine (CAS number: 87674-68-8), fentrazamide (CAS number: 158237-07-1), triafamone (CAS number: 212201-70-2), cafenstrole (CAS number: 125306-83-4), Mepiquat chloride (CAS number: 24151-93-7), propisochlor (CAS number: 86763-47-5), alachlor (CAS number: 15972-60-8), diflufenican (CAS number: 67129-08-2), propachlor (CAS number: 1918-16-7), dimethenamid (CAS number: 106700-29-2);

(11) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb (CAS number: 52888-80-9), molinate (CAS number: 2212-67-1), prosulfocarb (CAS number: 28249-77-6), benfuresate (CAS number: 68505-69-1), ethofumesate (CAS number: 26225-79-6), triallate (CAS number: 2303-17-5), dichlorfon (CAS number: 1929-77-7), butamolide (CAS number: 2008-41-5), dichlorfon (CAS number: 1134-23-2), pennisetum (CAS number: 61432-55-1) and penflun (CAS number: 85785-20-2);

(12) synthesis of hormones: quinclorac (CAS number: 84087-01-4), fluroxypyr (CAS number: 69377-81-7), fluroxypyr-meptyl (CAS number: 81406-37-3), fluroxypyr (CAS number: 943831-98-9), triclopyr (CAS number: 55335-06-3), clopyralid (CAS number: 1702-17-6), picloram (CAS number: 1918-02-1), aminopyralid (CAS number: 150114-71-9), dicamba (CAS number: 1918-00-9), fluroxypyr (CAS number: 1390661-72-9), 2-methyl-4-chlorophenoxyacetic acid (CAS number: 94-74-6), 2-methyl-4-chloro-phenothiolester (CAS number: 25319-90-8), MCPB (CAS number: 94-81-5), 2-methyl-4-chlorophenoxypropionic acid (CAS number: 93-65-2), sodium 2-methyl-4-chlorophenoxyacetate (CAS number: 3653-48-3), isooctyl 2-methyl-4-chlorophenoxyacetate (CAS number: 29450-45-1), butyl 2, 4-dichlorophenoxyacetate (CAS number: 94-80-4), isooctyl 2, 4-dichlorophenoxyacetate (CAS number: 25168-26-7), 2, 4-dichlorophenoxyacetic acid (CAS number: 94-75-7), chloroquinolinic acid (CAS number: 90717-03-6), 2-methyl-4 chlorodimethylammonium salt (CAS number: 2039-46-5), 2, 4-dichlorpropionic acid (CAS number: 120-36-5), 2, 4-D-butyric acid (CAS number: 94-82-6), benazolin (CAS number: 25059-80-7), aminocyclopyrachlor (CAS number: 858956-08-8);

(13) EPSPS inhibitors: glyphosate (CAS number: 1071-83-6), phosphinothricin (CAS number: 81591-81-3);

(14) a GS inhibitor: glufosinate-ammonium (CAS number: 77182-82-2), bialaphos (CAS number: 35597-43-4), and glufosinate-ammonium (CAS number: 35597-44-5);

(15) PSI inhibitors paraquat (CAS number: 1910-42-5), diquat (CAS number: 6385-62-2);

(16) DHP inhibitors: asulam (CAS number: 3337-71-1);

(17) cellulose synthesis inhibitors: triazinyl flumioxazin (CAS number: 131475-57-5), indexazin (CAS number: 950782-86-2);

(18) other herbicides: oxaziclomefone (CAS number: 153197-14-9), cinmethylin (CAS number: 87818-31-3), indanthrone (CAS number: 133220-30-1), quinclorac (CAS number: 130901-36-8), quintocet (CAS number: 1639426-14-4), prosulfuron (CAS number: 99485-76-4), imazalone (CAS number: 150-68-5), tetflupyrlomet (CAS number: 2053901-33-8).

Preferably, X represents phenyl or pyrazolyl, unsubstituted or substituted by at least one group selected from C1-C6 alkyl, halo C1-C6 alkyl, cyano, halogen, C1-C6 alkoxy, C1-C6 alkylcarbonyl.

More preferably, X representsNamely the active ingredient A is

In the context of the present specification, if the abbreviated forms of the common name of the active compounds are used, all customary derivatives, such as esters and salts, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are included in each case. If the generic name denotes esters or salts, all other customary derivatives, such as other esters and salts, free acids and neutral compounds, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are also included in each case. The chemical name given for a compound means at least one compound covered by the generic name, with compounds generally being preferred. In the case of sulfonamides, such as sulfonylureas, salts also include those formed by exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2 methyl 4 chloro sodium salt, potassium salt, dimethyl ammonium salt, isopropyl amine salt, etc., and 2 methyl 4 chloromethyl ester, ethyl ester, isooctyl ester, ethyl thioester, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolamine salt, isopropylamine salt, choline and the like, and 2,4-D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester and the like.

In the context of the present invention, the salts of the compounds are preferably in the form of the respective alkali metal, alkaline earth metal or ammonium salts, preferably in the form of the respective alkali metal salts, more preferably in the form of the respective sodium or potassium salts, most preferably in the form of the respective sodium salts.

A. The weight ratio of B is 1: 1000-200: 1 and 1: 600-150: 1; preferably 1: 500-100: 1 and 1: 400-80: 1; more preferably 1: 300-60: 1 and 1: 200-50: 1; further preferably 1: 100-30: 1 and 1: 50-20: 1; further preferred are 1:20 to 10:1, 1:10 to 5:1 and 1:5 to 1: 1.

The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.

The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.

The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.

Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.

The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.

In addition, the composition of the present invention can be mixed with the following active substances, for example, known substances in "the world Wide Specification of New agricultural chemical products", the Chinese agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, Terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolac, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron, sulfo, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, Betalain, asulam, tefurazol, avenacalin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, dichloropetalum, ethiofen, prosulfocarb, cloquintocet, prosulfocarb, dichloropetalum, dichloropetalate, dichloropetal, 2-methyl-4-chloropropionate, 2-methyl-4-chlorobutyric acid, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloroamine salt, dicamba, woollen boom, varparvax, cypress, triclosan, dichlorfenamic acid, metoclopramide, diclofop-p-ethyl, haloxyfop-methyl, haloxyfop-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, cyhalofop-butyl, fenoxaprop-p-ethyl, cloroph-ethyl, haloxyfop-ethyl, trifoliate-ethyl, clomazone, paraquat, dixyl, asulam, flutolon, isoproturon, chlorothalofop-ethyl, cyhalofop-p-ethyl, propafen-ethyl, butyfen-ethyl, fluroxypyr, metalaxyl, propafen, propaferin, propafen, glyphosate, anilofos, glufosinate, sulfosate, piperaphos, bialaphos, bensulide, imazapyr, mepyrazine, varroa, amifostine, glufosinate, imazethapyr ammonium salt, imazethapyr, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxyfen, triclopyr, thiazopyr, flurazinone, aminopyralid, flurazone, diflufenzopyr, butoxyethyl triclopyr, ciodinate, sethoxydim, clethodim, thiacet, sethoxydim, clethodim, carfenflurazone, buthiazole, metribuzin, carfenflurazone, metamitron, fenflurazone, fenpyr, benzone, iodoxynil, bromoxynil, isoflurazone, isofluroxypyr, bensulam, isofluroxypyr, clomazone, ioxynil, dichlobenil, tolfenacet, pyraclonil, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluralin, bispyribac, pyribenzoxim, pyriminobac-methyl, pyrithiobac-methyl, bicyclosulfuron, mesotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketoxydipradox, isoxaflutole, fenoxasulfolane, Methiozolin, isopyrafen, pyraflufen, pyraflutole, pyrazotocide, pyraclonil, pyraclofenacetone, flumetsulcotrione, flumetsulam, fenflurazole, fentrazachlor, amicarbazone, fentrazachlor, pyrazachlor, pyraclonil, flumicloram, flumioxazone, fenflurazole, flumicloram, bexapyroxadim, flumicloram, bexadim, flumicloram, benfluroram, flumicl, Phthalidyl ether, Flumezin, pentachlorophenol (sodium), dinol, terbenol, terbutal, pendimethalin, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop-p-ethyl, tetrazolyl amine, fluridazin, oxamyl, bromamine, dimethenamid, pyridaben, pyridate, pyrirfalol, quinclorac, bentazone, pyridate, oxaziclorac, benazolin, clomazone, clomeptyl, isoprox, iprodione, propamocarb, cumylfen, indoxacarb, sodium chlorate, dalton, dalapon, trichloroacetic acid, monochloroacetone, hexachloroacetone, tetrafluoropropionic acid, pasture, bromophenol oxime, triazoxide, fentrazol, furamethon, fursulam, ethon, benfurazolin, pyrimethanil, clorac, clodinafop, clorac, cumquat, cumarone, clorac, Thidiazuron, alantin, hydroxybenone, metophenone, saflufenacil, dichlorophosphoric, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphridam, Ipfancarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurflurazone, Tripropindan, Sulglycapin, Sumbelanoline, Campandichlor, Cytopyrimidic acid, thiocyananilide, clethodim, fenclorim, cloquintocet, mequintocet, oxaziclomex, oxabetrinil, pyroxaglim, furazolidone, imazaquin, isoxadifen, dichlormid, halauxin, halauxifen, DOWF, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.

The herbicidal composition further comprises at least one safener selected from the group consisting of:

a) dichlorophenyl pyrazoline-3-carboxylic acid (S1) compounds, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1 mefenpyr-diethyl, PM, p. 594-595), and related compounds described, for example, in WO91/07874 and PM (p. 594-595).

b) Dichlorophenyl pyrazole carboxylic acid derivatives, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2, 4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2, 4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylate (S1-4), ethyl 1- (2, 4-dichlorophenyl) -5-phenylpyrazole-3-carboxylate (S1-5), and related compounds as described in EP-A-333131 and EP-A-269806.

c) Triazole carboxylic acids (S1) and preferred compounds are, for example, fenchlorazole (fenchlorazole), i.e. ethyl 1- (2, 4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2, 4-triazole-3-carboxylate (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).

d) 5-benzyl-or 5-phenyl-2-isoxazoline-3-carboxylic acids or 5, 5-diphenyl-2-isoxazoline-3-carboxylic acids, preferred compounds being, for example, ethyl 5- (2, 4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds described in WO91/08202, or ethyl 5, 5-diphenyl-2-isoxazoline-3-carboxylate (S1-9, isoxadifen-ethyl)) or 5 described in the patent application (WO-A-95/07897), n-propyl 5-diphenyl-2-isoxazoline-3-carboxylate (S1-10) or ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylate (S1-11).

e) 8-Quinolinyloxyacetic acids (S2) of the class of compounds, preferably 1-methylhexan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-1, cloquintocet-mexyl), such as PM (p. 195-), (1, 3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinyloxy) acetate (S2-3), 1-allyloxypropan-2-yl (5-chloro-8-quinolinyloxy) acetate (S2-4), (ethyl 5-chloro-8-quinolinyloxy) acetate (S2-5), (methyl 5-chloro-8-quinolinyloxy) acetate (S2-6), allyl (5-chloro-8-quinolinyloxy) acetate (S2-7), 2- (2-propyleneiminoyloxy) -1-ethyl (5-chloro-8-quinolinyloxy) acetate (S2-8), 2-oxopropan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-9), and related compounds described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366.

f) (5-chloro-8-quinolinoxy) propanedioic acid-based compounds, preferred compounds are, for example, diethyl (5-chloro-8-quinolinoxy) malonate, (diallyl (5-chloro-8-quinolinoxy) malonate, (methylethyl (5-chloro-8-quinolinoxy) -malonate and related compounds described in EP-A-0582198.

g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acids, such as 2, 4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2-methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3, 6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).

h) Pyrimidines, such as fenclorim (PM, page 386-387) (═ 4, 6-dichloro-2-phenylpyrimidine),

i) dichloroacetamide-based active compounds, which are frequently used as pre-emergence safeners (soil-working safeners), for example "dichloroallylamine (dichlormid)" (PM, page 270-271) (═ N, N-diallyl-2, 2-dichloroacetamide), "AR-29148" (-3-dichloroacetyl-2, 2, 5-trimethyl-1, 3-oxazolidinone from Stauffer), "benoxacor" (PM, page 74-75) (-4-dichloroacetyl-3, 4-dihydro-3-methyl-2H-1, 4-benzoxazine), "APPG-1292" (-N-allyl-N [ (1, 3-dioxolan-2-yl) -methyl ] dichloroacetamide, from PPGIndustries), "ADK-24" (═ N-allyl-N- [ (allylaminocarbonyl) -methyl ] -dichloroacetamide, from Sagro-Chem), "AAD-67" or "AMON 4660" (═ 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane, from Nitrokemia or Monsanto), "diclonon" or "ABAS 145138" or "ala 145138" ((═ 3-dichloroacetyl-2, 5, 5-trimethyl-1, 3-diazabicyclo [4.3.0] nonane, from BASF), and "furilazol" or "AMON 13900" (see PM, 482 483) ((RS) -3-dichloroacetyl-5- (2-furyl) -2, 2-dimethyloxazolidone),

j) dichloroacetone derivative-based active compounds, for example, "AMG 191" (CAS registry No. 96420-72-3) (═ 2-dichloromethyl-2-methyl-1, 3-dioxolane, available from Nitrokemia),

k) oxyimino compounds as active compounds, which are referred to as seed dressing materials, for example "oxabetrinil" (PM, page 689) (═ Z) -1, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile), which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), "fluoroxyfen" (PM, page 467 468) (═ 1- (4-chlorophenyl) -2,2, 2-trifluoro-1-ethanone O- (1, 3-dioxolan-2-ylmethyl) -oxime, which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), and "cyanohydrin" or "a-CGA-43089" (PM, page 983) ((Z) -cyanomethoxyimino (phenyl) acetonitrile), which is called safener in seed dressing, to prevent the damage of metolachlor (metolachlor),

l) Thiazolecarboxylic acid ester active compounds, which are known as seed dressing materials, for example "flurazon" (PM, p. 450. 451), (-2-chloro-4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester), which are known as safeners in seed dressing to prevent damage to alachlor (alachlor) and metolachlor,

m) active compounds of the naphthalenedicarboxylic acid derivative class, which are known as seed dressings, for example "naphthalic anhydride" (PM, pp 1009-1010) (═ 1, 8-naphthalic anhydride), which are known as safeners in corn seed dressings to prevent damage to thiocarbamate herbicides,

n) chromanoic acid derivatives such as "ACL 304415" (CAS registry No. 31541-57-8) (═ 2-84-carboxychroman-4-yl) acetic acid available from american cyanamid),

o) active compounds which, in addition to herbicidal action on harmful plants, also have safener action on plants, for example "penetryn (dimerate)" or "AMY-93" (PM, p.302-303) (═ S-1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "diuron (daimuron)" or "ASK 23" (PM, p.247) (═ 1- (1-methyl-1-phenylethyl) -3-p-tolylureｃA), "cumyluron (cumyluron)", "jc-940" ((3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) ureｃA, see JP- ｃA-60087254), "benzophenone (methoxyphenon)" or "ANK 049" (═ 3,3' -dimethyl-4-methoxy-benzophenone), "CSB" (═ 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS registry No. 54091-06-4, available from Kumiai).

The safener is preferably one or more of isoxadifen (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), mefenpyr (CAS: 135590-91-9), cloquintocet (CAS: 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8) and metacamifen (CAS: 129531-12-0).

The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.

The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.

In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.

The invention also provides an application of the weeding composition in weed control; and to provide a method of controlling unwanted plant growth comprising applying the herbicidal composition to a plant, part of a plant, plant seed, or area where a plant is growing.

In addition, the compositions according to the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces infested or susceptible to infestation by weeds.

When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described, achieving reduced use and being more environmentally friendly.

The synergistic herbicidal composition of the invention also has the following advantages:

(1) the composition of the invention is environment-friendly and is easy to degrade in the environment.

(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.

Detailed Description

The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:

A) examples of the embodiments

Dispersible oil-suspendable agent A1+ sulcotrione (8+ 30: representing 8% A1+ 30% sulcotrione, the same applies hereinafter)

A1+ sulcotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ mesotrione (8+9)

A1+ mesotrione + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ topramezone (8+2)

A1+ topramezone + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ tembotrione (8+6)

A1+ tembotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ fluroxypyr (8+3) dispersible oil suspension

A1+ fluroxypyr, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

A1+ Furan sulcotrione (8+3) dispersible oil suspending agent

A1, Fusulcotrione, 6 percent calcium dodecyl benzene sulfonate, 7 percent fatty alcohol-polyoxyethylene ether, 5 percent castor oil-polyoxyethylene ether, 1.5 percent organic bentonite, 1.5 percent fumed silica, 5 percent 100# solvent oil and methyl oleate

7, A1+ benzobicyclon (8+10) dispersible oil suspending agent

A1+ benzobicyclon, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 5% 100# solvent oil and methyl oleate

8, A1+ topramezone (8+2) dispersible oil suspending agent

A1+ Metronidazole, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

Dispersible oil suspension agent of A1+ bicyclopyrone (8+9)

A1+ cyflufenac + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.2% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ triazasulamone (8+12)

A1+ triazophone + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

11, A1+ benzoxaflutole (8+6) dispersible oil suspending agent

A1+ benzoxaflutole + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ sulfonylopyrazole (8+2)

A1+ Sulfonyl pyrazole + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ pyrazolate (4+32)

A1+ pyrazolate + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + 5% 100# solvent oil + methyl oleate

14, A1+ pyroxadim (4+30) dispersible oil suspending agent

A1+ Bifencotrione + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organic bentonite + 5% 100# solvent oil + methyl oleate

A1+ tolpyralate (8+10) dispersible oil suspension

A1+ tolpyrate + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ fenquinotrione (8+10) dispersible oil suspension concentrate

A1+ fenquinotrione + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ isoxaflutole (8+6) dispersible oil suspending agent

A1+ isoxaflutole + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ benconazole (4+50) water dispersible granule

A1+ benzole + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

19.Dispersible oil suspension

Dispersible oil suspension concentrate of A1+ fluorochloridone (8+25)

A1, fluorochloridone, 5 percent calcium dodecyl benzene sulfonate, 6 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 0.5 percent organic bentonite, 0.5 percent fumed silica, 5 percent 100# solvent oil and methyl oleate

21, A1+ flurtamone (8+10) dispersible oil suspending agent

A1+ Fufuulone + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

22, A1+ diflufenican (8+10) dispersible oil suspending agent

A1+ diflufenican + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

23, A1+ fluopicolide (8+10) dispersible oil suspending agent

A1+ Fluopyramid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ beflubutamid (8+10) dispersible oil suspension

A1+ beflubutamid, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 5% 100# solvent oil and methyl oleate

25, A1+ norflurazon (4+36) water dispersible granule

A1+ norflurazon + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

26, A1+ fluazinone (4+70) wettable powder

A1+ fluazifop-butyl, 10% sodium lignosulfonate dispersant, 3% sodium dodecyl sulfate, 10% precipitated silica and kaolin

Dispersible oil suspension concentrate of A1+ clomazone (8+30)

A1+ clomazone + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 0.5% organobentonite + 5% 100# solvent oil + methyl oleate

A1+ bixlone (8+20) dispersible oil suspension

A1+ bixlone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate

29, A1+ tribenuron-methyl (8+2) dispersible oil suspending agent

A1+ tribenuron-methyl + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ thifensulfuron methyl (8+2)

A1+ thifensulfuron methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

31, A1+ bensulfuron methyl (8+2) dispersible oil suspending agent

A1+ bensulfuron methyl ++ 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

32, A1+ pyrazosulfuron-ethyl (8+2) dispersible oil suspending agent

A1+ pyrazosulfuron-ethyl, 5% calcium dodecylbenzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

Dispersible oil suspension agent of A1+ thiencarbazone-methyl (8+2)

A1+ Thiolosulfuron, 5% calcium dodecylbenzene sulfonate, 8% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

34, A1+ halosulfuron-methyl (8+2) dispersible oil suspending agent

A1+ halosulfuron-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

35, A1+ propyrisulfuron (8+4) dispersible oil suspending agent

A1+ propyrisulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

36, A1+ metazosulfuron (8+4) dispersible oil suspending agent

A1+ metazosulfuron-ethyl, 5% calcium dodecylbenzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

37, A1+ rimsulfuron (8+2) dispersible oil suspending agent

A1+ rimsulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

38, A1+ ethoxysulfuron (8+2) dispersible oil suspension

A1+ ethoxysulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ orthosulfamuron (8+5) dispersible oil suspending agent

A1+ sulfosulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-oxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

A1+ flucarbazone-sodium (8+2) dispersible oil suspending agent

A1+ Flucarbazone-sodium + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ mesosulfuron (8+1)

A1+ methylsulfonyl amine + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

42, A1+ nicosulfuron (8+4) dispersible oil suspending agent

A1+ nicosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

43, A1+ foramsulfuron (8+4) dispersible oil suspending agent

A1+ foramsulfuron + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ flumetsulam (8+3) dispersible oil suspending agent

A1+ flumetsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

45.A1+ fluocinolone acetonide (8+2) dispersible oil suspending agent

A1+ Fluoroketosulfometuron-amine + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

46, A1+ penoxsulam (8+2) dispersible oil suspending agent

A1+ penoxsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

47, A1+ cloransulam (8+2) dispersible oil suspending agent

A1+ cloransulam-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

48, A1+ pyroxsulam (8+1) dispersible oil suspending agent

A1+ pyroxsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

49, A1+ imazamox (8+2) dispersible oil suspending agent

A1+ metopimox, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

Dispersible oil suspension agent containing A1 and mebendazole nicotinic acid (8+3)

A1+ mebendazole nicotinic acid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

51, A1+ imazethapyr (8+5) dispersible oil suspending agent

A1+ imidazole acetic acid, 6% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organic bentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

A1+ imazapyr (8+50) water dispersible granules

A1+ Imazapyr + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + Kaolin to complement

53.A1+ pyriminobac-methyl (8+3) dispersible oil suspending agent

A1+ pyriminobac-methyl, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

54, A1+ florasulam (8+1) dispersible oil suspending agent

A1+ florasulam + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

Aqueous suspension of A1+ pyriftalid (8+20)

A1+ pyriftalid + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.05% xanthan gum + 0.5% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

56.A1+ pyribenzoxim (8+5) dispersible oil suspending agent

A1+ pyribenzoxim + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

57, A1+ propoxycarbazone (8+2) dispersible oil suspending agent

A1+ Tribensulfuron-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

58.A1+ imazethapyr (8+5) dispersible oil suspending agent

A1+ imazethapyr + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

59, A1+ chlorsulfuron (8+2) dispersible oil suspending agent

A1+ chlorsulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

60, A1+ cinosulfuron (8+2) dispersible oil suspending agent

A1+ cinosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

61.A1+ cyclosulfamuron (8+2) dispersible oil suspending agent

A1+ cyclosulfamuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

62, A1+ amidosulfuron (8+2) dispersible oil suspending agent

A1+ amidosulfuron, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

63.A1+ Ether tribenuron-methyl (8+2) dispersible oil suspending agent

A1+ Ether tribenuron-methyl + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

64, A1+ iodosulfuron-methyl sodium salt (8+1) dispersible oil suspending agent

A1+ iodosulfuron-methyl sodium salt + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

65.A1+ fluazisulfuron (8+2) dispersible oil suspending agent

A1+ flazasulfuron + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

66.A1+ Fluopyrsulfuron (8+2) dispersible oil suspending agent

A1+ Fluorosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

67, A1+ metsulfuron-methyl (8+1) dispersible oil suspending agent

A1+ metsulfuron-methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

68.A1+ triflusulfuron-methyl (8+1) dispersible oil suspending agent

A1+ Trifluoromethsulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

69, A1+ sulfonylsulfuron (8+2) dispersible oil suspension

A1+ sulfosulfuron, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

70, A1+ pyrazosulfuron-ethyl (8+1) dispersible oil suspending agent

A1+ pyrazosulfuron-ethyl, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

71.A1+ bispyribac-sodium (8+2) dispersible oil suspending agent

A1+ Bispyribac-sodium, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

72, A1+ metosulam (8+1) dispersible oil suspending agent

A1+ metosulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

73.A1+ clodinafop-propargyl (8+4) dispersible oil suspending agent

A1+ clodinafop-propargyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate

74, A1+ pinoxaden (8+4) dispersible oil suspending agent

A1+ pinoxaden + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

A1+ clethodim (8+6) dispersible oil suspending agent

A1+ clethodim + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate

76.A1+ sethoxydim (8+12) dispersible oil suspending agent

A1+ sethoxydim, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 6% 100# solvent oil + methyl oleate

77.A1+ quizalofop-p-ethyl (8+4) dispersible oil suspending agent

A1+ quizalofop-p-ethyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 6% 100# solvent oil + methyl oleate

78.A1+ clomazone (8+16) dispersible oil suspending agent

A1+ benzoximone + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 6% 100# solvent oil + methyl oleate

79.A1+ fluazifop-p-butyl (8+2) dispersible oil suspending agent

A1+ fluazifop-p-butyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 6% 100# solvent oil and methyl oleate

80.A1+ haloxyfop (8+2) dispersible oil suspending agent

A1+ haloxyfop-R-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-oxyethylene ether, 2% organobentonite, 1.5% fumed silica, 6% 100# solvent oil and methyl oleate

81, A1+ diclofop-p-ethyl (4+30) dispersible oil suspending agent

A1+ diclofop-p-ethyl + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organic bentonite + 6% 100# solvent oil + methyl oleate

82.A1+ fenoxaprop-p-ethyl (8+10) dispersible oil suspending agent

A1, fenoxaprop-p-ethyl, 6 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate

83, A1+ cyhalofop-butyl (8+10) dispersible oil suspending agent

A1+ cyhalofop-butyl, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica and methyl oleate

84, A1+ clethodim (8+4) dispersible oil suspending agent

A1+ clethodim + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate

85.A1+ metamifop (8+10) dispersible oil suspending agent

A1+ metamifop + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate

86.A1+ oxaoxalic acid (8+5) dispersible oil suspending agent

A1+ oxa oxalic acid + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organic bentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate

87, A1+ oxyfluorfen (8+12) dispersible oil suspending agent

A1+ oxyfluorfen + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.5% organobentonite + 2.5% fumed silica + 20% 100# solvent oil + methyl oleate

88.A1+ fomesafen (8+25) dispersible oil suspending agent

A1+ fomesafen + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate

89.A1+ oxadiazon (8+40) dispersible oil suspending agent

A1, oxadiazon, 5 percent calcium dodecyl benzene sulfonate, 5 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 0.5 percent organic bentonite, 5 percent 100# solvent oil and methyl oleate

90.A1+ oxadiargyl (8+6) dispersible oil suspending agent

A1, oxadiargyl, 5 percent calcium dodecyl benzene sulfonate, 6 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 1.5 percent organic bentonite, 1.5 percent fumed silica, 15 percent 100# solvent oil and methyl oleate

91, A1+ sulfentrazone (8+36) wettable powder

A1+ sulfentrazone + 12% calcium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin

92.A1+ pyraclonil (8+14) dispersible oil suspending agent

A1+ pyraclonil, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organobentonite, 5% 100# solvent oil and methyl oleate

93.A1+ flumioxazin (8+6) dispersible oil suspending agent

A1+ flumioxazin + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 15% 100# solvent oil + methyl oleate

94.A1+ pentoxazone (8+26) dispersible oil suspending agent

A1+ pentoxazone + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate

95.A1+ tiafenacil (8+2) dispersible oil suspending agent

A1+ tiafenacil + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate

96.A1+ saflufenacil (8+5) dispersible oil suspending agent

A1+ saflufenacil + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate

97, A1+ pyraflufen-ethyl (8+1) dispersible oil suspending agent

A1+ pyraflufen-ethyl, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 2.0% organobentonite, 1.5% fumed silica and methyl oleate

98.A1+ carfentrazone-ethyl (8+2) dispersible oil suspending agent

A1+ carfentrazone-ethyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organic bentonite + 1.5% fumed silica + methyl oleate

99.A1+ flupropyrim (8+1) dispersible oil suspending agent

A1+ Fluropyrim-fluroxypyr ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate

Dispersible oil suspension agent of A1+ Meclofenacet Ethyl ester (8+2)

A1+ Meclofenacet-ethyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

101, A1+ fluoroglycofen-ethyl (8+1) dispersible oil suspending agent

A1+ fluoroglycofen-ethyl + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate

102, A1+ acifluorfen (8+30) water dispersible granules

A1+ acifluorfen + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

A1+ triflumimoxazin (8+5) dispersible oil suspension concentrate

A1+ triflumimoxazin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate

Dispersible oil suspension agent containing A1+ oxazine methyl oxalate (8+1)

A1+ oxazine methyl oxalate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate

105, A1+ atrazine (4+30) aqueous suspension

A1+ atrazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

106, A1+ prometryn (8+30) aqueous suspension

A1+ prometryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

107, A1+ simetryn (8+30) aqueous suspension

A1+ simetryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

108, A1+ terbuthylazine (8+30) aqueous suspension

A1+ terbuthylazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ terbutryn (8+30)

A1+ terbutryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

110, A1+ ametryn (8+40) aqueous suspension

A1+ ametryn, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water

111, A1+ iprovalbumin (8+30) aqueous suspension

A1+ iprovalbumin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

112, A1+ Fengcao (8+40) water suspension

A1+ fenfluramine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

113, A1+ diquat (8+40) aqueous suspension

A1+ dimethomon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

114, A1+ simazine (8+40) aqueous suspension

A1+ simazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

115.A1+ metribuzin (8+10) aqueous suspension

A1+ metribuzin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

A1+ ethiprole (8+20) aqueous suspension

A1+ ethifluzone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ amicarbazone (8+10)

A1+ amicarbazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

A1+ metamitron (4+50) water dispersible granules

A1+ metamitron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

119, A1+ cyanazine (8+30) aqueous suspension

A1+ cyanazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

120, A1+ chlortoluron (8+50) water dispersible granule

A1+ chlortoluron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

Aqueous suspension of A1+ isoproturon (8+30)

A1+ isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

122, A1+ diuron (8+30) aqueous suspension

A1+ diuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

123, A1+ fluometuron (8+40) aqueous suspension

A1+ fluometuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ linuron (8+40)

A1+ linuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ buthiuron (8+40)

A1+ buthiuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

126, A1+ Saposlon (8+30) aqueous suspension

A1+ Saplon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

127, A1+ chlorsulfuron (8+50) wettable powder

A1+ Lu Gu Long + 12% calcium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and Kaolin for complement

128, A1+ bromogluron (8+30) aqueous suspension

A1+ bromogluron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ stephania (4+30)

A1+ Gerbazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ pyridazinol (8+20)

A1+ pyridazinol + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

131, A1+ hexazinone (8+40) aqueous suspension

A1+ hexazinone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

132, A1+ Isoprenyl (8+40) aqueous suspension

A1+ isoamyl ethyl, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water

133, A1+ Oxydazine (8+40) aqueous suspension

A1+ Oxazin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

134, A1+ Tribenidine (4+40) aqueous suspension

A1+ weedicide + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

135, A1+ lenacil (8+20) aqueous suspension

A1+ Cyclinum planiforme + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

136, A1+ terbacil (4+40) aqueous suspension

A1+ terbacil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

137, A1+ Methylphenethiol (8+6) aqueous suspension

A1+ methabenzthiazuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.5% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water

138, A1+ Cyclouron (4+40) aqueous suspension

A1+ cyhaloron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ Isooxan (8+30)

A1+ Isoxon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

Aqueous suspension of A1+ Methylon (4+40)

A1+ Methylon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

141, A1+ Subtilis-sodium (4+40) aqueous suspension

A1+ Kunlong + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

142, A1+ trifluoxazine (8+10) aqueous suspension

A1+ trifluoxazine + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

143, A1+ cycloprozoomate (8+8) aqueous suspension

A1+ cycloprominate + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

144, A1+ propanil (4+40) aqueous suspension

A1+ propanil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water

145, A1+ pyridate (8+30) aqueous suspension

A1+ pyridate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

146, A1+ Betam (4+30) aqueous suspension

A1+ Beetalol + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

147, A1+ betanin (4+30) aqueous suspension

A1+ betanin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

148, A1+ bentazone (8+40) aqueous suspension

A1+ bentazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

149, A1+ bromoxynil octanoate (8+12) aqueous suspension

A1+ bromoxynil octanoate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

150, A1+ bromoxynil (8+8) aqueous suspension

A1+ bromoxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

151, A1+ ioxynil (8+8) aqueous suspension

A1+ ioxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

152, A1+ trifluralin (8+20) dispersible oil suspending agent

A1+ trifluralin + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate

153, A1+ butralin (8+30) dispersible oil suspending agent

A1+ butralin + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organic bentonite + 0.5% fumed silica + methyl oleate

154, A1+ pendimethalin (8+30) dispersible oil suspension

A1+ pendimethalin + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate

155, A1+ dithiopyr (8+20) dispersible oil suspending agent

A1+ dithiopyr + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate

156, A1+ Flubenone (8+40) water dispersible granule

A1+ Fluoroxylen + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + Kaolin to complement

157, A1+ amisulpride (8+30) dispersible oil suspension

A1+ sulfamethoxazole + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate

158, A1+ flutolanil (acetopenyl) (8+30) dispersible oil suspending agent

A1+ flutolanil (benopentin), 6% calcium dodecylbenzenesulfonate, 7% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 10% 100# solvent oil and methyl oleate

159, A1+ fenthizamide (8+20) dispersible oil suspending agent

A1+ fenthizamide + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 10% 100# solvent oil + methyl oleate

160, A1+ propyzamide (8+20) dispersible oil suspending agent

A1+ Naxyfen (propyzamide), 5% calcium dodecylbenzenesulfonate, 9% fatty alcohol-polyoxyethylene ether, 6% castor oil-oxyethylene ether, 1% organobentonite, 0.5% fumed silica, 12% 100# solvent oil and methyl oleate

161, A1+ chlorthal (8+50) wettable powder

A1+ chlorthal + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin

162, A1+ glyphosate (8+50) wettable powder

A1+ P + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin

163, A1+ diacyl-chlor (8+30) dispersible oil suspending agent

A1+ diacyl-chlor, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organic bentonite, 0.5% fumed silica, 8% 100# solvent oil and methyl oleate

164, A1+ acetochlor (8+30) dispersible oil suspension

A1+ acetochlor, 6% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1% organobentonite, 1% fumed silica, 8% 100# solvent oil and methyl oleate

165, A1+ butachlor (8+30) dispersible oil suspending agent

A1+ butachlor + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.2% organobentonite + 1.5% fumed silica + methyl oleate

166, A1+ pretilachlor (8+30) dispersible oil suspending agent

A1+ pretilachlor + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + methyl oleate

167, A1+ metolachlor (8+30) dispersible oil suspension

A1+ metolachlor + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + methyl oleate

168, A1+ mefenacet (8+30) dispersible oil suspending agent

A1+ mefenacet + 6% calcium dodecylbenzene sulfonate + 4% fatty alcohol-polyoxyethylene ether + 7% castor oil-oxyethylene ether + 1.2% organobentonite + 1% fumed silica + methyl oleate

169, A1+ s-metolachlor (8+30) dispersible oil suspending agent

A1+ s-metolachlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate

170, A1+ flufenacet (8+10) dispersible oil suspending agent

A1+ flufenacet + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.0% fumed silica + 20% 100# solvent oil + methyl oleate

171, A1+ napropamide (8+30) dispersible oil suspending agent

A1+ napropamide + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.0% organic bentonite + 1.0% fumed silica + 20% 100# solvent oil + methyl oleate

172, A1+ sulfonepyrazoxazole (8+10) dispersible oil suspending agent

A1+ Sulfuron pyrazoxazole + 5% calcium dodecylbenzene sulfonate + 4% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organic bentonite + 10% 100# solvent oil + methyl oleate

173, A1+ anilofos (8+20) dispersible oil suspension concentrate

A1+ anilofos + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.0% organobentonite + 1.0% fumed silica + 12% 100# solvent oil + methyl oleate

174, A1+ dimethenamid (8+30) dispersible oil suspending agent

A1, dimethenamid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.2% organobentonite, 8% 100# solvent oil and methyl oleate

175, A1+ fentrazamide (8+10) dispersible oil suspension

A1+ tetrazolium amide + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate

176, A1+ Triazolecarboxamide (8+10) dispersible oil suspension

A1+ triazolyl oxamide + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate

177, A1+ cafenstrole (8+10) dispersible oil suspending agent

A1+ cafenstrole + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate

178, A1+ pipophos (8+30) dispersible oil suspension

A1+ piperalin P + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 1.6% organic bentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate

179, A1+ propisochlor (8+30) dispersible oil suspending agent

A1+ propisochlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 8% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ alachlor (8+30)

A1+ alachlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate

181, A1+ metazachlor (8+20) dispersible oil suspending agent

A1+ metazachlor, 6% calcium dodecyl benzene sulfonate, 4% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 8% 100# solvent oil and methyl oleate

182.A1+ propachlor (8+30) dispersible oil suspending agent

A1+ phenthoamine + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate

183, A1+ dimethenamid (8+30) dispersible oil suspension

A1+ dimethenamid, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 8% 100# solvent oil and methyl oleate

184, A1+ prosulfocarb (2+30) dispersible oil suspending agent

A1+ carbofuran + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate

185, A1+ molinate (8+50) water dispersible granules

A1+ molinate + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

186, A1+ thiobencarb (8+50) water dispersible granule

A1+ thiobencarb + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement

Dispersible oil suspension agent of A1+ furbenclamide (8+40)

A1+ Fulvhuang + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + methyl oleate

188, A1+ ethofumesate (8+40) dispersible oil suspending agent

A1+ ethofumesate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite + methyl oleate

189, A1+ triallate (8+40) dispersible oil suspension

A1+ Dicamba, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organobentonite, 0.5% fumed silica and methyl oleate

190, A1+ molinate (2+30) dispersible oil suspending agent

A1+ metalaxyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.2% organobentonite + 12% 100# solvent oil + methyl oleate

191, A1+ butachlor (8+10) dispersible oil suspending agent

A1+ butachlor, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate

192, A1+ Cytophilus (8+10) dispersible oil suspending agent

A1+ cyhalofop-butyl, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate

193, A1+ pipindone (8+30) dispersible oil suspension

A1+ pipindone + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 12% 100# solvent oil + methyl oleate

194, A1+ penflufen (4+30) dispersible oil suspension

A1+ penflufen + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 10% 100# solvent oil + methyl oleate

195, A1+ quinclorac (8+25) dispersible oil suspension

A1+ quinclorac + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 10% 100# solvent oil + methyl oleate

196, A1+ fluroxypyr (8+12) dispersible oil suspension

A1+ fluroxypyr + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate

197.A1+ fluroxypyr meptyl (8+12) dispersible oil suspension

A1+ fluroxypyr-meptyl ester + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate

198, A1+ Fluorochloropyridine ester (8+0.5) dispersible oil suspending agent

A1+ Fluorochloropyridine ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + methyl oleate

199, A1+ triclopyr (4+50) wettable powders

A1+ triclopyr + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin

Dispersible oil suspension of A1+ clopyralid (8+12)

A1+ clopyralid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ picloram (2+30)

A1+ amlodipine acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate

202, A1+ aminopyralid (4+30) dispersible oil suspending agent

A1+ amlodipine acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate

203, A1+ dicamba (8+14) dispersible oil suspension

A1+ Dicamba, 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate

204, A1+ Chlorofluoropyridine ester (8+2) dispersible oil suspension

A1+ fluroxypyridine ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

205, A1+ 2-methyl-4-chlorophenoxyacetic acid (4+30) dispersible oil suspending agent

A1+ 2-methyl-4-chlorophenoxyacetic acid + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate

Dispersible oil suspension of A1+ 2-methyl-4-chloro-phenol ethylthioester (4+30)

A1+ 2-methyl-4-chloro-phenol ethyl thioester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organic bentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate

207, A1+ MCPB (4+30) dispersible oil suspension

A1+ MCPB + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+ 2-methyl-4-chlorophenoxypropionic acid (4+30)

A1+ 2-methyl-4-chlorophenoxypropionic acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate

209, A1+ 2-methyl-4-sodium chlorophenoxyacetate (4+30) dispersible oil suspension agent

A1+ 2-methyl-4-sodium chlorophenoxy acetate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.2% organobentonite + 10% 100# solvent oil + methyl oleate

210, A1+ 2-methyl-4-chlorophenoxyacetic acid isooctyl ester (4+30) dispersible oil suspending agent

A1+ 2-methyl-4-chlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 10% 100# solvent oil + methyl oleate

211, A1+2, 4-dichlorphenoxyacetic acid butyl ester (8+35) dispersible oil suspending agent

A1+2, 4-dichlorophenoxyacetic acid butyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate

212, A1+2, 4-dichlorophenoxyacetic acid isooctyl ester (8+40) dispersible oil suspending agent

A1+2, 4-dichlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate

213, A1+2, 4-dichlorophenoxyacetic acid (8+30) dispersible oil suspension concentrate

A1+2, 4-dichlorophenoxyacetic acid + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate

214, A1+ chloromethylquinolinic acid (8+18) dispersible oil suspending agent

A1+ chloromethylquinolinic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + methyl oleate

215.A1+2 methyl 4 chlorodimethylammonium salt (8+15) dispersible oil suspension concentrate

A1+2 methyl-4-chlorodimethylammonium salt + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

Dispersible oil suspension agent of A1+2, 4-dichlorprop (4+30)

A1+2, 4-dichlorprop acid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 0.5% fumed silica, 20% 100# solvent oil and methyl oleate

217, A1+2,4-DB/2, 4-D butanoic acid (4+30) dispersible oil suspension

A1+2,4-DB/2, 4-D butyric acid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organobentonite, 0.5% fumed silica, 20% 100# solvent oil and methyl oleate

218, A1+ benazolin (8+20) dispersible oil suspending agent

A1+ benazolin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate

219, A1+ Cyclopropylpyrimidineoic acid (8+10) dispersible oil suspending agent

A1+ cyclopropane pyrimidinic acid + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

Aqueous suspension of A1+ glyphosate (8+40)

A1+ glyphosate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

221, A1+ phosphinothricin (4+30) aqueous suspension

A1+ phosphinothricin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

222, A1+ glufosinate-ammonium (8+40) aqueous suspension

A1+ glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

A1+ bialaphos (4+40) aqueous suspension

A1+ bialaphos + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

224, A1+ glufosinate-ammonium (8+30) aqueous suspension

A1+ glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

225, A1+ paraquat (8+40) aqueous suspension

A1+ paraquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

226, A1+ diquat (4+40) aqueous suspension

A1+ diquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

227, A1+ asulam (2+40) aqueous suspension

A1+ asulam + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water

228, A1+ triazine flumioxazin (8+0.5) dispersible oil suspending agent

A1+ triazine flumioxazin + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

229, A1+ indexazine flumioxazin (8+0.5) dispersible oil suspension

A1+ indenyloxazine-fluorchlor, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.8% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate

230, A1+ oxaziclomefone (8+2) dispersible oil suspending agent

A1+ oxaziclomefone + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

231, A1+ cinmethylin (8+1) dispersible oil suspending agent

A1+ cycloheptane ether + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

232, A1+ indanthrone (8+2) dispersible oil suspending agent

A1+ indene clomazone + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

233.A1+ quinclorac (8+20) dispersible oil suspending agent

A1+ Quinclorac, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 12% 100# solvent oil and methyl oleate

234, A1+ quintocet (8+4) dispersible oil suspending agent

A1+ quintocet-mefone + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

235, A1+ benzuron (8+20) dispersible oil suspending agent

A1+ benzuron + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

236, A1+ meturon (8+20) dispersible oil suspending agent

A1+ meturon-methyl + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 12% 100# solvent oil + methyl oleate

237, A1+ tetflupyrolimet (8+4) dispersible oil suspension concentrate

A1+ tetflupulolimet + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate

The processing equipment of the aqueous suspending agent comprises: mixing kettles, colloid mills, sand mills, shearing machines and the like.

The processing process of the aqueous suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.

The processing equipment of the dispersible oil suspending agent comprises the following steps: mixing kettles, colloid mills, sand mills, shearing machines and the like.

The processing process of the dispersible oil suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.

The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.

The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.

The processing equipment of the wettable powder comprises: mechanical disintegrators, jet mills, coulter mixers.

The processing process of the wettable powder comprises the following steps: all the materials enter a coulter type mixer, and then are mechanically crushed and airflow crushed to obtain a finished product.

B) Test of drug efficacy

Spraying treatment of stems and leaves after seedling:

1) test conditions

1.1) test target

Chenopodium quinoa is collected from Shaanxi Shaanyang, Setaria viridis is collected from Shandong Qingdao, Potentilla chinensis is collected from Chuzhou, Anhui, and Avena sativa is collected from Henan Staima shop. The weeds are cultured by a pot culture method, plastic nutrition bowls with the size of 180 х 140mm are placed in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which are just exposed to the white are uniformly placed on the surface of the soil, and then the enamel tray is covered with 0.5-1cm of soil according to the particle size of the seeds.

1.2) culture conditions

The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.

1.3), instrumentation

3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).

2) Design of experiments

2.1), reagents

The desired active ingredient a was obtained from patent CN201811035352.5 and the specific preparation process is as follows:

(1) preparation of intermediates

(1.1) dissolving the compound C-1 in dioxane solution, adding sodium methoxide solution (30% content, 1.5eq) and heating to 100 ℃ for reaction for 16-18 hours, and monitoring the completion of the reaction by a liquid phase. Cooling the reaction liquid to room temperature, removing the solvent by using concentrated acid, dissolving by using a 1M hydrochloric acid solution, extracting by using ethyl acetate until a water phase has no product, concentrating an organic phase to obtain a solid, and adding petroleum ether: and (3) pulping and purifying the ethyl acetate which is 10:1, and filtering to obtain the product C-2.

(1.2) Compound C-2 was dissolved in DCE, and phosphorus oxychloride (3eq) and DMF (2%) were added to react at 100 ℃ for 16 to 18 hours. And after the liquid phase monitoring reaction is finished, cooling the reaction liquid, concentrating, controlling the temperature of the obtained product, adding the obtained product into water, separating out a large amount of solids, continuously stirring for 30 minutes, and filtering the solids to obtain a product C.

(2) Preparation of Compound A1

(2.1) dissolving the intermediate C in dioxane solution, adding 10% by volume of water, then adding potassium carbonate (3eq) and a compound A1-1(1.05eq), replacing with nitrogen, adding a palladium catalyst (5%) under the protection of nitrogen, and heating the nitrogen protection system to 120 ℃ for reaction for 16-18 hours. After completion of the reaction, liquid phase monitoring was carried out, water was added to the reaction solution, extraction was carried out with ethyl acetate until the aqueous phase was free from the product, the organic phase was concentrated, and the sample was purified by column chromatography (petroleum ether: ethyl acetate 5: 1) to obtain product a 1-2.

(2.2) dissolving the compound A1-2 in DMSO, adding potassium acetate (5eq), heating the reaction system to 120 ℃, and reacting for 16-18 hours. And (3) after the liquid phase monitoring reaction is finished, cooling to room temperature, then pouring into water, extracting with DCM for three times, adjusting the pH value of the water phase to 4 by using 1M hydrochloric acid, separating out a large amount of solid, continuing stirring for 30 minutes, filtering, and drying a filter cake to obtain the product A1.

The active ingredients B required are diconazole, bicyclopyrone, topramezone and triazophone which are produced by the company, and others are purchased from a reagent company. The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.

2.2) test treatment

2.2.1), dose setting

When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.

2.2.2), test repetition

Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.

2.3) treatment method

2.3.1), treatment time and number of times

The test was performed 1 time in total. And (3) thinning when the weeds are in a 3-4 leaf period, keeping 15 weeds in each pot, keeping 45 weeds in each treatment, and then continuously culturing until the weeds are 4-5 leaves for treatment.

2.3.2), instruments and methods of use

Uniformly placing the cultured test material on a 0.5m area²Spraying stem and leaf by using a 3WP-2000 model walking spray tower on the platform, wherein the liquid spraying amount is 450 kg/hectare. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.

3) Test method

The potting method is adopted. The weed cultivation is shown in 1.1), and the method is carried out according to 'herbicide in pesticide indoor bioassay test guidelines'. The application method is shown in 2.3.2), and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture.

4) Data investigation and statistical analysis

4.1) investigation method

The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.

4.2), investigation time and number of surveys

The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.

4.3), statistical analysis of data

The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like. Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.

The statistical results are shown in tables 1-237 below.

TABLE 1 evaluation of the actual control and combination of Chenopodium album by compounding sulcotrione 1

TABLE 2A 1 evaluation of the actual control and combination of mesotrione compounded to Chenopodium album

TABLE 3A 1 evaluation of the actual control and Combined Effect of the Compound topramezone on Chenopodium quinoa

TABLE 4A 1 evaluation of the actual control and combination of the Ring Sulfonone on Chenopodium quinoa

TABLE 5A 1 evaluation of the actual control and Combined Effect of Fluoropyridone on Chenopodium quinoa

TABLE 6A 1 evaluation of the actual control and Combined Effect of Fusulcotrione on Chenopodium album

TABLE 7 evaluation of the actual control and combination of Chenopodium album by the combination of Dosulcotrione A1

TABLE 8A 1 evaluation of the actual control and Combined Effect of compounded Bixaflutole on Chenopodium album

TABLE 9A 1 evaluation of the actual control and Combined Effect of Cyclopyridoxal on Chenopodium album

TABLE 10A 1 evaluation of the actual control and combination of the Tribuli effects of the compounded triazophone

TABLE 11A 1 evaluation of the actual control and combination of the effect of the blended benzoxaflutole on Chenopodium quinoa

TABLE 12A 1 evaluation of the actual control and Combined action of the Mixed Sulfonylopyrazole on Chenopodium quinoa

TABLE 13A 1 evaluation of the actual control and combination of pyrazolate-compounded Tribuli

TABLE 14A 1 evaluation of the actual control and Combined Effect of blended pyridoxal on Chenopodium quinoa

TABLE 15A 1 evaluation of the actual control and combination of tolpyralate on Chenopodium quinoa

TABLE 16A 1 evaluation of the actual control and Combined action of the blended fenquinotrione on Chenopodium quinoa

TABLE 17 evaluation of the actual control and Combined Effect of isoxaflutole on Chenopodium quinoa by compounding with Isoxaflutole A1

TABLE 18A 1 evaluation of the actual control and combination of the blended benzonatazole on Chenopodium quinoa

TABLE 19A 1 compounding

Evaluation of actual control and combined action of Chenopodium quinoa

TABLE 20A 1 evaluation of the actual control and Combined Effect of the Compound fluorochloridone on Chenopodium quinoa

TABLE 21A 1 evaluation of the actual control and combination of Fuurodim versus Chenopodium quinoa

TABLE 22A 1 evaluation of actual control and Combined Effect of Bighua with Diflufenican

TABLE 23A 1 evaluation of actual control and Combined action of Fluopyramid on Chenopodium quinoa

TABLE 24A 1 evaluation of the actual control and combination of beflubutamid formulated for Chenopodium quinoa

TABLE 25A 1 evaluation of the actual control and Combined Effect of compounded norflurazon on Chenopodium quinoa

TABLE 26A 1 evaluation of the actual control and combination of fluazinone on Chenopodium quinoa

TABLE 27A 1 evaluation of the actual control and combination of clomazone on Chenopodium quinoa

TABLE 28A 1 evaluation of actual Bixlozone control and combination on Chenopodium quinoa

TABLE 29A 1 evaluation of the actual control and combination of tribenuron-methyl on Chenopodium quinoa

TABLE 30A 1 evaluation of the actual control and Combined Effect of Thifensulfuron methyl on Chenopodium quinoa

TABLE 31A 1 evaluation of the actual control and combination of bensulfuron methyl for Chenopodium quinoa

TABLE 32A 1 evaluation of the actual control and combination of pyrazosulfuron-ethyl on Chenopodium album

TABLE 33A 1 evaluation of the actual control and combination of the Thiolosulfuron

TABLE 34A 1 evaluation of the actual control and combination of halosulfuron-methyl on Chenopodium album

TABLE 35A 1 evaluation of the actual control and combination of the Tribuli effects of the blended propyrisulfuron

TABLE 36A 1 evaluation of the actual control and combination of the Ring-pyrazosulfuron-ethyl

TABLE 37A 1 evaluation of the actual control and combination of rimsulfuron with quinoa

TABLE 38A 1 evaluation of the actual control and combination of the Tribuli by the Ethoxysulfuron mixture

TABLE 39A 1 evaluation of the actual control and combination of Anilinosulfuron-P-Chenopodium

TABLE 40A 1 evaluation of the actual control and combination of Flucarbazone-sodium for Chenopodium quinoa

TABLE 41A 1 evaluation of the actual control and combination of Chenopodium album by compounding with mesosulfuron

TABLE 42A 1 evaluation of the actual control and combination of nicosulfuron on Chenopodium album

TABLE 43A 1 evaluation of the actual control and combination of foramsulfuron pairs of Chenopodium quinoa

TABLE 44A 1 evaluation of the actual control and combined action of mixed flumetsulam on Chenopodium quinoa

TABLE 45A 1 evaluation of the actual control and combination of Ottelia quinoa with Fluoroketofonamide

TABLE 46A 1 evaluation of the actual control and combination of penoxsulam on Chenopodium quinoa

TABLE 47A 1 evaluation of the actual control and combination of cloransulam-chloratum on Chenopodium quinoa

TABLE 48A 1 evaluation of the actual control and Combined action of mixed pyroxsulam on Chenopodium quinoa

TABLE 49A 1 evaluation of the actual control and Combined Effect of compounding imazamox on Chenopodium quinoa

TABLE 50A 1 evaluation of the actual control and combination of imazapic with compounding of Chenopodium album

TABLE 51A 1 evaluation of the actual control and combination of imazethapyr versus Chenopodium quinoa

TABLE 52A 1 evaluation of the actual control and combination of imazapyr on Chenopodium quinoa

TABLE 53 evaluation of the actual control and combination of pyriminobac-sodium for Chenopodium quinoa by compounding pyriminobac-methyl with 1

TABLE 54A 1 evaluation of the actual control and combination of florasulam on Chenopodium

TABLE 55A 1 evaluation of the actual control and combination of the Mixed pyriftalid on Chenopodium quinoa

TABLE 56A 1 evaluation of the actual control and combination of pyribenzoxim on Chenopodium quinoa

TABLE 57A 1 evaluation of the actual control and Combined Effect of Tribuli with Tribensulfuron mixture

TABLE 58A 1 evaluation of the actual control and combination of imazethapyr versus Chenopodium quinoa

TABLE 59A 1 evaluation of the actual control and combination of chlorsulfuron on Chenopodium quinoa

TABLE 60A 1 evaluation of the actual control and Combined Effect of Etosulfuron-methyl-compounded on Chenopodium quinoa

TABLE 61A 1 evaluation of the actual control and combination of cyclosulfamuron for Chenopodium quinoa

TABLE 62A 1 evaluation of the actual control and combination of amidosulfuron on Chenopodium album

TABLE 63A 1 evaluation of the actual control and Combined Effect of Tribuli's Mixed Ether tribenuron-methyl

TABLE 64A 1 evaluation of the actual control and combination of the sodium iodosulfuron for Chenopodium quinoa

TABLE 65A 1 evaluation of the actual control and combination of flazasulfuron on Chenopodium album

TABLE 66A 1 evaluation of the actual control and combination of Fluoropyrosulfuron on Chenopodium quinoa

TABLE 67A 1 evaluation of the actual control and Combined Effect of Tribuli with Tribena metsulfuron

TABLE 68A 1 evaluation of the actual control and Combined action of Tribuli with Tribenum Triben Tribute

TABLE 69 evaluation of the actual control and combination of the Sulfosulfuron-methyl-mixed to Chenopodium quinoa

TABLE 70A 1 evaluation of the actual control and combination of halosulfuron-methyl on Chenopodium album

TABLE 71A 1 evaluation of the actual control and combination of Bispyribac-sodium for Chenopodium quinoa

TABLE 72A 1 evaluation of the actual control and Combined action of Sulfocap-sodium on Chenopodium quinoa

TABLE 73A 1 evaluation of the actual control and combination of Clodinafop-propargyl for green grass

TABLE 74A 1 evaluation of the actual control and combination of pinoxaden with pinoxaden

TABLE 75A 1 evaluation of the actual control and combination of clethodim on green setaria

TABLE 76A 1 evaluation of the actual control and combination of sethoxydim for green setaria

TABLE 77A 1 evaluation of the actual control and combined action of quizalofop-p-ethyl on green setaria

TABLE 78A 1 evaluation of the actual control and combination of amiloride on green Setaria viridis

TABLE 79 evaluation of actual control and combination of fluazifop-p-butyl to green setaria viridis by A1 blending

TABLE 80A 1 evaluation of the actual control and joint action of haloxyfop-R-methyl on green setaria viridis

TABLE 81A 1 evaluation of the actual control and combination of diclofop-p-methyl on green setaria

TABLE 82A 1 evaluation of the actual control and joint action of fenoxaprop-p-ethyl on green setaria viridis

TABLE 83A 1 evaluation of actual control and combination of Cyhalofop-butyl for green setaria

TABLE 84A 1 evaluation of the actual control and combination of cycloxydim on green setaria

TABLE 85A 1 evaluation of the actual control and combination of metamifop to green bristlegrass

TABLE 86A 1 evaluation of the actual control and combination of green grass

TABLE 87A 1 evaluation of actual control and combination of oxyfluorfen in Chenopodium quinoa

TABLE 88A 1 evaluation of the actual control and combination of fomesafen versus Chenopodium quinoa

TABLE 89A 1 evaluation of the actual control and combination of oxadiazon on Chenopodium quinoa

TABLE 90A 1 evaluation of the actual control and Combined Effect of the Compound oxadiargyl on Chenopodium quinoa

TABLE 91A 1 evaluation of the actual control and combination of the grass-roots mixed with sulfentrazone

TABLE 92A 1 evaluation of the actual control and Combined action of Bixapyroxad on Chenopodium quinoa

TABLE 93A 1 evaluation of the actual control and combination of the quinoa with the compounded flumioxazin

TABLE 94 evaluation of the actual control and combination of the Effect of Cyclopentoxazone on Chenopodium quinoa by A1 compounding

TABLE 95A 1 evaluation of the actual control and Combined action of the Tiafenac blends on Chenopodium quinoa

TABLE 96A 1 evaluation of the actual control and combination of saflufenacil on Chenopodium quinoa

TABLE 97A 1 evaluation of the actual control and Combined Effect of Bighua with Bispyribac-sodium

TABLE 98A 1 evaluation of the actual control and Combined Effect of Mixed carfentrazone-ethyl on Chenopodium quinoa

TABLE 99A 1 evaluation of the actual control and combination of Flavering for Chenopodium quinoa

TABLE 100A 1 evaluation of the actual control and Combined Effect of the compounded ethoxyfen-ethyl on Chenopodium quinoa

TABLE 101A 1 evaluation of actual control and combination of haloxyfop-ethyl on Chenopodium quinoa

TABLE 102A 1 evaluation of actual control and combination of acifluorfen-sodium for Chenopodium quinoa

TABLE 103A 1 evaluation of the actual control and combination of triflumimoxazin against Chenopodium quinoa

TABLE 104A 1 evaluation of the actual control and combination of the methyl ester of mixed oxazine oxalate on Chenopodium quinoa

TABLE 105A 1 evaluation of actual prevention and Combined Effect of atrazine compounded on Chenopodium quinoa

TABLE 106A 1 evaluation of the actual control and combination of the Compound prometryn against Chenopodium quinoa

TABLE 107A 1 evaluation of actual control and combination of simetryn combinations on Chenopodium quinoa

TABLE 108A 1 evaluation of actual control and combination of Tribuli with terbuthylazine

TABLE 109A 1 evaluation of actual control and combination of Terbutyrn with Tribuli

TABLE 110A 1 evaluation of the actual control and Combined Effect of mixed ametryn on Chenopodium quinoa

TABLE 111A 1 evaluation of the actual control and combination of isoprotulin over Chenopodium quinoa

TABLE 112A 1 evaluation of the actual control and combination of phytocide on Chenopodium quinoa

TABLE 113A 1 evaluation of the actual control and Combined action of the Compound Dipterex on Chenopodium quinoa

TABLE 114A 1 evaluation of actual control and combination of Ximadzu in combination with Chenopodium quinoa

TABLE 115A 1 evaluation of the actual control and Combined Effect of Mixed metribuzin on Chenopodium quinoa

TABLE 116A 1 evaluation of the actual control and Combined Effect of compounding ethisterone on Chenopodium quinoa

TABLE 117A 1 evaluation of the actual control and Combined Effect of the compounded amicarbazone on Chenopodium quinoa

TABLE 118A 1 evaluation of the actual control and Combined Effect of Mixed metamitron on Chenopodium album

TABLE 119A 1 evaluation of actual control and combination of cyanazine on Chenopodium quinoa

TABLE 120A 1 evaluation of the actual control and combination of the Mixed Chloroton on Chenopodium quinoa

TABLE 121A 1 evaluation of the actual control and combination of Isoproton versus Chenopodium quinoa

TABLE 122A 1 evaluation of the actual control and combination of diuron versus Chenopodium quinoa blends

TABLE 123A 1 evaluation of the actual control and combination of the combination of fluazuron to Chenopodium quinoa

TABLE 124A 1 evaluation of the actual control and combination of Riguron compounded on Chenopodium quinoa

TABLE 125A 1 evaluation of the actual control and combination of the Tribuli effects of the Mixed Thidiazuron

TABLE 126A 1 evaluation of the actual control and Combined action of the blended Shapu' ron on Chenopodium quinoa

TABLE 127A 1 evaluation of the actual control and combination of Lugulong on Chenopodium quinoa

TABLE 128A 1 evaluation of the actual control and combination of bromuron on Chenopodium quinoa

TABLE 129A 1 evaluation of the actual control and combination of the herbal Robusta on Chenopodium quinoa

TABLE 130A 1 evaluation of the actual control and Combined Effect of the Mixed pyridazinols on Chenopodium quinoa

TABLE 131A 1 evaluation of the actual controlling effect and combined action of the hexazinone compound on Gelidium japonicum

TABLE 132A 1 evaluation of the actual control and combination of the Potentilla discolor with isoamyl ethrin

TABLE 133A 1 evaluation of actual control and joint action of Suzuojin mixed with grass

TABLE 134A 1 evaluation of actual control and combined action of blend herbicide on Baogeli grass

TABLE 135A 1 evaluation of the actual control and combination of lenacil to BAOGANCAO

TABLE 136A 1 evaluation of the actual control and combination of terbacil with gemini

TABLE 137A 1 evaluation of the actual control and combination of the Mesothiaron to Baoguo grass

TABLE 138A 1 evaluation of the actual control and combination of the Cymbopogon Citratus

TABLE 139A 1 evaluation of the actual control and combination of the active ingredients of Baogancao

TABLE 140A 1 evaluation of the actual control and combination of the Metronidazole mixture for the treatment of Gelidium japonicum

Table 141A 1 evaluation of actual control and joint action of Sulfuron mixed with Baoguo on Baoguo grass

TABLE 142A 1 evaluation of actual control and combination of trifluoxazine on Gelidium japonicum

TABLE 143A 1 evaluation of the actual control and combined action of the cyclopyromate on Geum japonicum

TABLE 144A 1 evaluation of the actual control and combination of propanil with BAOGANCAO

TABLE 145A 1 evaluation of the actual control and combination of pyridate mixed with Baoguo grass

TABLE 146A 1 evaluation of the actual control and combination of the use of betaine Ampelopsis Grossdentata

TABLE 147A 1 evaluation of the actual control and combination of Baogesi with betanin

TABLE 148A 1 evaluation of the actual control and combination of bentazon mixtures on Gelidium sp

TABLE 149A 1 evaluation of the actual control and combination of bromoxynil octanoate on Gelidium japonicum

TABLE 150A 1 evaluation of the actual control and combination of bromoxynil compounds on Gelidium sp

TABLE 151A 1 evaluation of the actual control and combination of ioxynil to Gelidium sp

TABLE 152A 1 evaluation of the actual control and combination of the trifluralin mixed with the BAOGANCAO

TABLE 153A 1 evaluation of the actual control and joint action of butralin mixed to Baogeicao

TABLE 154A 1 evaluation of the actual control and combination of pendimethalin in combination with Gelidium japonicum

TABLE 155A 1 evaluation of the actual control and combination of the Sulfothiadine mixture on the grass

TABLE 156A 1 evaluation of actual control and joint action of ETBUNFULING on BAOGICAO

TABLE 157A 1 evaluation of the actual control and joint action of the amisulpride mixture on Baoguo grass

TABLE 158A 1 evaluation of the actual control and combination of the fluroxypyr with acetopenetrol

TABLE 159A 1 evaluation of the actual control and Combined action of the Mixed Thiacloprid on Gelidium

TABLE 160A 1 evaluation of the actual control and combination of Panaxadiol on penoxsulam

TABLE 161A 1 evaluation of actual control and combination of chlorthal on BAOGAO

TABLE 162A 1 evaluation of the actual control and combination of Potentilla discolor with the incorporation of glyphosate inhibitor

TABLE 163A 1 evaluation of the actual control and Combined action of the mixed diacyl-ureas on Geum japonicum

TABLE 164A 1 evaluation of the actual control and combination of the acetochlor in the mixture for the grass

Table 165A 1 evaluation of actual control and combined action of butachlor in mixed form on Geiger grass

TABLE 166A 1 evaluation of the actual control and combination of pretilachlor on Geiger

Evaluation of actual control effect and combined effect of metolachlor compounded in Table 167A 1 on Boraginaceae

TABLE 168A 1 evaluation of the actual control and combination of penoxsulam

TABLE 169A 1 evaluation of the actual control and combined action of s-metolachlor mixed with gemini on pennisetum sp

TABLE 170A 1 evaluation of the actual control and combination of flufenacet in combination with Gelidium sp

TABLE 171A 1 evaluation of the actual control and combination of napropamide with a mixture of napropamide

TABLE 172A 1 evaluation of the actual control and combination of Sulfurpur Bifone for Gelidium

TABLE 173A 1 evaluation of the actual control and combination of anilofos when mixed with fenchox

TABLE 174A 1 evaluation of the actual control and combination of gemfibrozil with dimethenamid

TABLE 175A 1 evaluation of the actual control and combination of fenugreek with fentrazamide

TABLE 176A 1 evaluation of the actual control and combination of the objective Gelidium by compounding with triazolam

TABLE 177A 1 evaluation of the actual control and combination of the cafenstrole with penoxsulam

TABLE 178A 1 evaluation of the actual control and combination of the penfenphos mixture for Gelidium sp

TABLE 179A 1 evaluation of the actual control and combination of the action of propisochlor on the grass

TABLE 180A 1 evaluation of the actual control and combination of alachlor for Geum japonicum

TABLE 181A 1 evaluation of the actual control and combination of the synergistic effect of the mixed pyraflufen-ethyl on the grass of Geiger

TABLE 182A 1 evaluation of the actual control and combination of gemfibrozil with the combination of Convolvulus arvensis

TABLE 183A 1 evaluation of the actual control and combination of the penoxsulam on Geiger grass

TABLE 184A 1 evaluation of the actual control and combination of the mixed prosulfocarb on Avena sativa

TABLE 185A 1 evaluation of the actual control and Combined Effect of blended Dimethoate Avena sativa

TABLE 186A 1 evaluation of the actual control and combination of the mixed erysipelas to Avena sativa

TABLE 187A 1 evaluation of the actual control and combination of the Fulviao mixed with wild oat

TABLE 188A 1 evaluation of the actual control and combination of the mixed ethofumesate to Avena sativa

TABLE 189A 1 evaluation of the actual control and Combined action of Dicamba mixed with Avena sativa

TABLE 190A 1 evaluation of the actual control and Combined action of the Mixed Metronidazole oat

Evaluation of actual control effect and combined effect of Table 191A 1 mixed butantp on wild oat

TABLE 192A 1 evaluation of the actual control and Combined action of the mixed cycloprophoron and paraquat Avena sativa

TABLE 193A 1 evaluation of the actual control and Combined action of mixed piptanthus chinensis on Avena sativa

TABLE 194A 1 evaluation of actual control and combination of penflufen for Avena sativa

Evaluation of actual control and combined action of Quinclorac on Baoguo grass by compounding in Table 195A 1

TABLE 196A 1 evaluation of the actual control and Combined Effect of fluroxypyr-compounded on Geiger grass

TABLE 197A 1 evaluation of the actual control and Combined Effect of fluroxypyr-meptyl on Geiger

TABLE 198A 1 evaluation of the actual control and combination of Baogesi with fluroxypyridine

TABLE 199A 1 evaluation of actual control and combination of triclopyr on Gem

TABLE 200A 1 evaluation of actual control and combination of pennisetum hydridum with clopyralid

TABLE 201A 1 evaluation of the actual prevention and combination of Picloram to Gelidium japonicum

TABLE 202A 1 evaluation of the actual control and combination of Baogesi with aminopyralid

TABLE 203A 1 evaluation of the actual control and Combined action of dicamba on Gelidium

TABLE 204A 1 evaluation of the actual control and combination of fluroxypyr esters compounded for Geiger grass

TABLE 205A 1 evaluation of the actual control and combination of Baogeli with 2-methyl-4-chlorophenoxyacetic acid

TABLE 206A 1 evaluation of actual control and combination of Baogeli by blending 2-methyl-4-chloro-phenoxathion

TABLE 207A 1 evaluation of the actual control and combination of MCPB blended with Gelidium japonicum

TABLE 208A 1 evaluation of the actual control and combination of Baogeli with 2-methyl-4-chlorophenoxypropionic acid

TABLE 209 evaluation of the actual control and combination of Gelidium japonicum by compounding 2-methyl-4-sodium chlorophenoxylate with 1

TABLE 210A 1 evaluation of the actual control and combination of 2-methyl-4-chlorophenoxyacetic acid isooctyl ester on Geum japonicum

TABLE 211A 1 evaluation of the actual control and combination of butyl 2, 4-dichlorophenoxyacetate

TABLE 212 evaluation of the actual control and combination of the 2, 4-dichlorophenoxyacetic acid isooctyl ester blended with the grass of Geiger

TABLE 213A 1 evaluation of the actual control and combination of the 2, 4-dichlorophenoxyacetic acid with Geiger grass

Evaluation of actual prevention and combination of Table 214A 1 with chloromethylquinolinic acid for Gelidium japonicum

TABLE 215A 1 evaluation of the actual control and combination of Baogrash with 2-methyl-4-chlorodimethylammonium salt

TABLE 216 evaluation of actual control and joint action of 2, 4-Dipropionic acid mixed with Gelidium japonicum

TABLE 217A 1 evaluation of actual control and combination of Gelidium japonicum with 2,4-DB/2, 4-D-butyric acid

TABLE 218A 1 evaluation of the actual control and joint action of benazolin-compounded on BAOGICAO

TABLE 219 evaluation of the actual control and Combined action of Cytopyrimidic acid mixture of A1 on Gelidium japonicum

TABLE 220A 1 evaluation of actual control and Combined action of Glyphosate blends on Gelidium sp

TABLE 221A 1 evaluation of the actual control and combination of the grass-sulfur-phosphine compounds on the grass

TABLE 222A 1 evaluation of actual control and Combined action of glufosinate-ammonium compounded on Gelidium sp

TABLE 223A 1 evaluation of the actual control and Combined action of Bialanylphosphine blends on Geiger grass

TABLE 224A 1 evaluation of the actual control and combination of the Acronomum p-glufosinate on Geum japonicum

TABLE 225A 1 evaluation of the actual control and combination of paraquat on Gelidium sp

TABLE 226A 1 evaluation of the actual control and combination of the synergistic effect of diquat on Baoguo

TABLE 227A 1 evaluation of the actual control and combination of the Sulfocailin mixture to Baoguo grass

Table 228A 1 evaluation of the actual control and combination of triazineone-flumioxazin against Geiger grass

TABLE 229A 1 evaluation of the actual control and combination of the effects of the mixed indexazine flumioxazin on Geiger grass

Table 230A 1 evaluation of the actual control and combination of oxaziclomefone on Gelidium sp

TABLE 231A 1 evaluation of the actual control and combination of the grass

TABLE 232A 1 evaluation of the actual control and Combined action of the compounded indene-mefone on Gelidium

TABLE 233A 1 evaluation of the actual control and combination of quinoxydim on Boraginaceae

TABLE 234A 1 evaluation of the actual control and Combined action of the Compound Quinclorac on Gelidium

TABLE 235A 1 evaluation of the actual control and combination of the Bifenuron-blended compounds on the grass

TABLE 236A 1 evaluation of the actual control and combination of the Mesona Procumbens Hemsl

Evaluation of actual control and Combined action of Tetflubolimet mixed with Table 237A 1 on Geum japonicum

C) Demonstration of field

The herbicidal compositions prepared in examples 1 to 237 were used for field weed effect tests.

An exemplary popularization test was carried out in 2017 at the test point of Jiangsu Huai' an. The weeds in the field are mainly: amaranthus retroflexus, Chenopodium album, Setaria viridis, Echinochloa crusgalli, and the like.

The test method comprises the following steps:

treating stems and leaves, namely adding 30 kg of water per 667m by a manual sprayer when the weeds are in the 1-1.5 leaf stage²The stem and leaf are sprayed evenly.

The specific test agents and dosages are detailed in table 238, with a cell area of 50 square meters, repeated 4 times per treatment. The control effect 20 days after application is shown in Table 238.

Table 238 exemplary field Effect of the compounded compositions

Through a large number of tests and explorations, the composition is unexpectedly found to be used for preventing and removing weeds such as chenopodium quinoa, green setaria viridis, pagoda grass, wild oat, redroot amaranth, barnyard grass and the like, has a surprising and unexpected synergistic effect, is more remarkable in low-dosage performance, can reduce the dosage and the pollution to the environment, is reasonably compounded to reduce the agricultural cost, is efficient for ALS and ACCase inhibitor resistant weeds, and has a good application prospect. Meanwhile, the herbicide composition shows good selectivity and excellent synergistic effect in wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and other plants through tests, and can be developed into herbicide mixtures with wide market value.