阅读说明：本技术 一种抗菌洗衣液及其制备方法 (Antibacterial laundry detergent and preparation method thereof ) 是由 周旋峰 石荣莹 张培培 于 2020-06-05 设计创作，主要内容包括：本发明涉及洗衣液技术领域,具体涉及一种抗菌洗衣液及其制备方法。本发明提供的抗菌洗衣液,以质量百分比计,包括有机硅季铵盐5～15％,表面活性剂15～50％,助洗剂0.5～3％,功能添加剂0.1～5％,余量为水；所述有机硅季铵盐如式I所示。在本发明中,所述有机硅季铵盐中的硅基与衣物表面的氧原子结合固定于衣物表面,相较于传统的季铵盐或者其他类型杀菌剂,具有更加长久的抗菌效果；而且本发明使用的有机硅季铵盐为乙氧基体的季铵盐,在生产、使用过程中使用的是酒精,避免了甲醇的参与,能够大幅度提高安全性；本发明通过对各组分用量的控制,能够保证有机硅季铵盐对衣物的抗菌作用,协同配合提高洗衣液抗菌效果的时效。(The invention relates to the technical field of laundry detergents, and particularly relates to an antibacterial laundry detergent and a preparation method thereof. The antibacterial laundry detergent provided by the invention comprises, by mass, 5-15% of organic silicon quaternary ammonium salt, 15-50% of surfactant, 0.5-3% of builder, 0.1-5% of functional additive and the balance of water; the organosilicon quaternary ammonium salt is shown as a formula I. In the invention, the silicon base in the organosilicon quaternary ammonium salt is combined with the oxygen atoms on the surface of the clothes to be fixed on the surface of the clothes, and compared with the traditional quaternary ammonium salt or other bactericides, the organosilicon quaternary ammonium salt has longer antibacterial effect; the organosilicon quaternary ammonium salt used in the invention is the quaternary ammonium salt of the ethoxy matrix, and alcohol is used in the production and use processes, so that the participation of methanol is avoided, and the safety can be greatly improved; according to the invention, the antibacterial effect of the organosilicon quaternary ammonium salt on clothes can be ensured by controlling the use amount of each component, and the aging of the antibacterial effect of the laundry detergent is improved by synergistic cooperation.)

1. The antibacterial laundry detergent is characterized by comprising, by mass, 5-15% of organosilicon quaternary ammonium salt, 15-50% of surfactant, 0.5-3% of builder, 0.1-5% of functional additive and the balance of water; the organosilicon quaternary ammonium salt is shown as a formula I;

in the formula I, R1 is alkyl with 12-24 carbon atoms, R2 and R3 are independently alkyl with 1-6 carbon atoms, and X is halogen ion or organic carboxylic acid ion.

2. The antibacterial laundry detergent according to claim 1, characterized by comprising, by mass, 6-12% of a silicone quaternary ammonium salt, 16-30% of a surfactant, 1-2% of a builder, 0.2-0.5% of a functional additive, and the balance of water.

3. The antibacterial laundry detergent of claim 1 or 2, wherein the organosilicone quaternary ammonium salt is C12-C24 alkyl dimethyl triethoxy silyl propyl ammonium chloride.

4. The antibacterial laundry detergent of claim 3, wherein the quaternary ammonium organosilicate salt is octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, docosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride or tetracosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride.

5. The antimicrobial laundry detergent of claim 1 or 2, wherein the surfactant comprises at least one of fatty alcohol polyoxyethylene ether, fatty acid methyl ester ethoxylate, castor oil polyoxyethylene ether, hydrogenated castor oil polyoxyethylene ether, modified oil ethoxylate, coco glucoside, and isomeric alcohol polyoxyethylene ether.

6. The antibacterial laundry detergent of claim 1 or 2, characterized in that the builder comprises at least one of trisodium citrate, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, sodium methylglycinediacetate, and tetrasodium glutamate diacetate.

7. The antibacterial laundry detergent of claim 1 or 2, characterized in that the functional additive comprises at least one of a softener, an antistatic agent, a perfume, a pigment and an enzyme preparation.

8. The preparation method of the antibacterial laundry detergent as claimed in any one of claims 1 to 7, comprising the following steps:

carrying out first mixing on part of water and a surfactant to obtain a first solution;

secondly mixing the first solution with a builder, an organosilicon quaternary ammonium salt and a functional additive to obtain a second solution; the organosilicon quaternary ammonium salt is shown as a formula I;

and thirdly mixing the second solution and the residual water to obtain the antibacterial laundry detergent.

9. The preparation method according to claim 8, wherein the mass of the part of water accounts for 60-80% of the total water consumption.

10. The method according to claim 8, wherein the temperature of the first mixing is 40 to 60 ℃; the temperature of the second mixing is room temperature.

Technical Field

The invention relates to the technical field of laundry detergents, and particularly relates to an antibacterial laundry detergent and a preparation method thereof.

Background

With the improvement of the requirements of people on the sanitation of living environment, the antibacterial ability of fiber products is continuously concerned. It is desirable that everyday clothing, towels or other fibrous articles be rendered antibacterial and antiviral so as to reduce the risk of infection or secondary infection.

Although conventional antibacterial agents such as peroxide, hypochlorite, PCMX, silver ion, etc. have the ability to kill bacteria or viruses in a short time, their bactericidal ability is significantly reduced or disappeared after a certain period of time, and thus the demand for long-lasting antibacterial activity cannot be satisfied.

The other currently used methoxy quaternary ammonium salt, such as octadecyl dimethyl (3-trimethoxysilylpropyl) ammonium chloride, has a long-acting antibacterial effect, but cannot avoid the participation of methanol with high toxicity in the production, transportation and use processes, so that the safety of the quaternary ammonium salt cannot be guaranteed.

Disclosure of Invention

The invention aims to provide an antibacterial laundry detergent and a preparation method thereof, the antibacterial laundry detergent provided by the invention has excellent long-acting antibacterial and disinfecting capability, methanol can be avoided in the whole production, transportation and use processes, and the safety is obviously improved.

In order to achieve the above object, the present invention provides the following technical solutions:

the invention provides an antibacterial laundry detergent which comprises, by mass, 5-15% of organosilicon quaternary ammonium salt, 15-50% of surfactant, 0.5-3% of builder, 0.1-5% of functional additive and the balance of water; the organosilicon quaternary ammonium salt is shown as a formula I;

in the formula I, R1 is alkyl with 12-24 carbon atoms, R2 and R3 are independently alkyl with 1-6 carbon atoms, and X is halogen ion or organic carboxylic acid ion.

Preferably, the antibacterial laundry detergent comprises, by mass, 6-12% of organosilicon quaternary ammonium salt, 16-30% of surfactant, 1-2% of builder, 0.2-0.5% of functional additive, and the balance of water.

Preferably, the organosilicon quaternary ammonium salt is C12-C24 alkyl dimethyl triethoxy silyl propyl ammonium chloride.

Preferably, the quaternary ammonium salt of organosilicon is octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, docosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride or tetracosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride.

Preferably, the surfactant comprises at least one of fatty alcohol polyoxyethylene ether, fatty acid methyl ester ethoxylate, castor oil polyoxyethylene ether, hydrogenated castor oil polyoxyethylene ether, modified oil ethoxylate, coco glucoside and isomeric alcohol polyoxyethylene ether.

Preferably, the builder comprises at least one of trisodium citrate, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, sodium methylglycinediacetate, and tetrasodium glutamate diacetate.

Preferably, the functional additive comprises at least one of a softener, an antistatic agent, a perfume, a pigment and an enzyme preparation.

The invention provides a preparation method of the antibacterial laundry detergent, which comprises the following steps:

carrying out first mixing on part of water and a surfactant to obtain a first solution;

secondly mixing the first solution with a builder, an organosilicon quaternary ammonium salt and a functional additive to obtain a second solution; the organosilicon quaternary ammonium salt is shown as a formula I;

and thirdly mixing the second solution and the residual water to obtain the antibacterial laundry detergent.

Preferably, the mass of the part of water accounts for 60-80% of the total water consumption.

Preferably, the temperature of the first mixing is 40-60 ℃; the temperature of the second mixing is room temperature.

The invention provides an antibacterial laundry detergent which comprises, by mass, 5-15% of organosilicon quaternary ammonium salt, 15-50% of surfactant, 0.5-3% of builder, 0.1-5% of functional additive and the balance of water; the organosilicon quaternary ammonium salt is shown as a formula I. In the invention, silicon base in the organosilicon quaternary ammonium salt is combined and fixed with oxygen atoms on the surface of clothes, and compared with the traditional quaternary ammonium salt or other types of bactericides, the organosilicon quaternary ammonium salt has longer antibacterial effect; the organosilicon quaternary ammonium salt used in the invention is the quaternary ammonium salt of the ethoxy matrix, and alcohol is used in the production and use processes, so that the participation of methanol is avoided, and the safety can be greatly improved; according to the invention, the antibacterial effect of the organosilicon quaternary ammonium salt on clothes can be ensured by controlling the use amount of each component, and the aging of the antibacterial effect of the laundry detergent is improved by synergistic cooperation.

Detailed Description

The invention provides an antibacterial laundry detergent which comprises, by mass, 5-15% of organosilicon quaternary ammonium salt, 15-50% of surfactant, 0.5-3% of builder, 0.1-5% of functional additive and the balance of water; the organosilicon quaternary ammonium salt is shown as a formula I;

in the formula I, R1 is alkyl with 12-24 carbon atoms, R2 and R3 are independently alkyl with 1-6 carbon atoms, and X is halogen ion or organic carboxylic acid ion.

The antibacterial laundry detergent provided by the invention comprises 5-15% by mass of organosilicon quaternary ammonium salt, and preferably 6-12%. In the present invention, the quaternary ammonium organosilicon salt is preferably at least one of C12-C24 alkyldimethyltriethoxysilylpropylammonium chloride, more preferably octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, docosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride or tetracosyl dimethyl (3-triethoxysilylpropyl) ammonium chloride. In the invention, the silicon base in the organosilicon quaternary ammonium salt is combined with the oxygen atoms on the surface of the clothes to be fixed on the surface of the clothes, and compared with the traditional quaternary ammonium salt or other bactericides, the organosilicon quaternary ammonium salt has longer antibacterial effect; in addition, the organosilicon quaternary ammonium salt used in the invention is quaternary ammonium salt of an ethoxy matrix, and alcohol is used in the production and use processes, so that the participation of methanol is avoided, and the safety can be greatly improved.

The antibacterial laundry detergent provided by the invention comprises 15-50% by mass of a surfactant, and preferably 16-30%. In the invention, the surfactant preferably comprises at least one of fatty alcohol-polyoxyethylene ether, fatty acid methyl ester ethoxylate, castor oil polyoxyethylene ether, hydrogenated castor oil polyoxyethylene ether, modified oil ethoxylate, coco glucoside and isomeric alcohol polyoxyethylene ether, and the fatty alcohol-polyoxyethylene ether is preferably bio-based fatty alcohol polyoxyethylene ether. In a specific embodiment of the present invention, when the surfactant is coco glucoside, fatty alcohol polyoxyethylene ether and castor oil polyoxyethylene ether, the mass ratio of coco glucoside to fatty alcohol polyoxyethylene ether to castor oil polyoxyethylene ether is 6: 7: 4; when the surfactant is modified grease ethoxylate and fatty alcohol-polyoxyethylene ether, the mass ratio of the modified grease ethoxylate to the fatty alcohol-polyoxyethylene ether is 5: 4; when the surfactant is hydrogenated castor oil polyoxyethylene ether and fatty alcohol polyoxyethylene ether, the mass ratio of the hydrogenated castor oil polyoxyethylene ether to the fatty alcohol polyoxyethylene ether is 5: 12; when the surfactant is fatty acid methyl ester ethoxylate and fatty alcohol-polyoxyethylene ether, the mass ratio of the fatty acid methyl ester ethoxylate to the fatty alcohol-polyoxyethylene ether is 1: 1. in the present invention, the surfactant is capable of cleaning dirt of laundry.

The antibacterial laundry detergent provided by the invention comprises 0.5-3% by mass of a builder, and preferably 1-2%. In the present invention, the builder preferably includes at least one of trisodium citrate, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, sodium methylglycinediacetate, and tetrasodium glutamate diacetate. In the present invention, the builder functions to chelate calcium and magnesium ions in water.

The antibacterial laundry detergent provided by the invention comprises 0.1-5% of functional additive by mass percentage, and preferably 0.2-0.5%. In the present invention, the functional additive preferably includes at least one of a softener, an antistatic agent, a perfume, a pigment, and an enzyme preparation. In the invention, the softening agent preferably comprises one or more of hexadecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride and imidazoline ethyl sulfate; the antistatic agent preferably comprises one or more of polyvinylpyrrolidone hydrochloride, octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and pentaethoxy ammonium methyl sulfate; the enzyme preparation preferably comprises one or more of protease, amylase and lipase. In the present invention, the enzyme preparation functions to improve the cleaning ability of the laundry detergent. The invention has no special requirements on the specific components of the essence and the pigment, and the products which are well known in the field and sold on the market can be selected according to the product requirements.

The antibacterial laundry detergent provided by the invention comprises the balance of water, and the water is preferably deionized water.

The invention also provides a preparation method of the antibacterial laundry detergent, which comprises the following steps:

carrying out first mixing on part of water and a surfactant to obtain a first solution;

secondly mixing the first solution with a builder, an organosilicon quaternary ammonium salt and a functional additive to obtain a second solution; the organosilicon quaternary ammonium salt is shown as a formula I;

and thirdly mixing the second solution and the residual water to obtain the antibacterial laundry detergent.

According to the invention, part of water and a surfactant are subjected to first mixing to obtain a first solution. In the invention, the mass of the part of water is preferably 60-80% of the total water consumption. In the invention, the first mixing is preferably carried out under stirring, and the temperature of the first mixing is preferably 40-60 ℃, and more preferably 50 ℃; the stirring speed is preferably 400-500 rpm, and the stirring time is preferably 0.5-3 h. The invention can accelerate the dissolving speed by mixing the surfactant and the water in a heating mode.

After the first solution is obtained, the first solution, a builder, an organosilicon quaternary ammonium salt and a functional additive are subjected to second mixing to obtain a second solution; the organosilicon quaternary ammonium salt is shown as a formula I. In the present invention, the second mixing is preferably performed at room temperature, reducing energy consumption. In the present invention, the second mixing is preferably performed under a stirring condition, and the stirring rate is preferably 400 to 500 rpm. The stirring time of the invention has no special requirement, and all the components are preferably mixed uniformly. In the present invention, the order of addition of the raw materials in the second mixing is preferably: and sequentially adding a builder, a quaternary ammonium organosilicate and a functional additive into the first solution. The invention adopts the raw material adding sequence, which is beneficial to shortening the dissolving time of the system.

After the second solution is obtained, the second solution and the residual water are subjected to third mixing to obtain the antibacterial laundry detergent. The invention has no special requirements on the specific parameters of the third mixing, and the conventional mixing process in the field can be adopted.

In the preparation process of the antibacterial laundry detergent, the dissolution time is shortened according to the mixing sequence of the raw materials, and the production is facilitated. The preparation method provided by the invention is simple and easy to operate, and is suitable for industrial production.

The technical solution of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.