阅读说明：本技术 制备交联聚烯烃粒子的方法 (Process for preparing cross-linked polyolefin particles ) 是由 陈亮 R·S·莫利亚 C·A·克鲁兹 R·C·埃文 J·C·芒罗 J·M·柯吉恩 于 2018-11-29 设计创作，主要内容包括：提供了一种制备聚合组合物的方法,所述方法包含(a)提供初始聚烯烃粒子于水性介质中的分散液,其中所述初始聚烯烃粒子包含(i)一种或多种烃聚烯烃,(ii)一种或多种非烃聚烯烃,和(iii)一种或多种交联剂；(b)使所述初始聚烯烃粒子与过氧化物引发剂接触以形成交联聚烯烃粒子。(A process for preparing a polymeric composition is provided, the process comprising (a) providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise (i) one or more hydrocarbon polyolefins, (ii) one or more non-hydrocarbon polyolefins, and (iii) one or more crosslinking agents; (b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.)

1. A method of preparing a polymeric composition comprising

(a) Providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise

(i) One or more hydrocarbon polyolefins,

(ii) one or more non-hydrocarbon polyolefins, and

(iii) one or more cross-linking agents;

(b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.

2. The method of claim 1, wherein the hydrocarbon polyolefin comprises polymerized units of α -olefin having 4 or less carbon atoms and polymerized units of α -olefin having 5 or more carbon atoms.

3. The method of claim 1, wherein the initial polyolefin particles have a Tg of-30 ℃ or less.

4. The method of claim 1, wherein the non-hydrocarbon polyolefin comprises a reaction product of maleic anhydride grafted onto a hydrocarbon polyolefin.

5. The method of claim 1, wherein the peroxide initiator has structure R¹-O-O-R²Wherein R is¹And R²Each is hydrogen or alkyl, wherein R¹And R²Not all are hydrogen.

6. A dispersion of crosslinked polyolefin particles in an aqueous medium, prepared by the method of claim 1.