阅读说明：本技术 一种防滑防静电袜子的生产工艺 (Production process of anti-skid anti-static socks ) 是由 陈玉强 于 2019-12-06 设计创作，主要内容包括：本发明公开了一种防滑防静电袜子的生产工艺,包括如下步骤：(1)柠檬酸溶液浸泡处理；(2)物质称取备用；(3)浸渍液制备；(4)织物纤维处理；(5)成品袜子织造。本发明提供了一种袜子的生产工艺,其工艺步骤简单,便于推广应用,此方法适用于各种形状种类的袜子生产,制得的袜子具有良好的防滑防静电能力,且穿着舒适,抗菌吸汗特性强。(The invention discloses a production process of anti-slip and anti-static socks, which comprises the following steps: (1) soaking in citric acid solution; (2) weighing the materials for later use; (3) preparing an impregnation liquid; (4) treating fabric fibers; (5) and weaving the finished socks. The invention provides a production process of socks, which has simple process steps and is convenient to popularize and apply, the method is suitable for producing socks with various shapes, and the prepared socks have good anti-skid and anti-static capabilities, are comfortable to wear and have strong antibacterial and sweat-absorbing characteristics.)

1. The production process of the anti-slip anti-static socks is characterized by comprising the following steps:

(1) soaking the fabric fiber in a citric acid solution for 4-6 min, taking out and naturally airing for later use;

(2) weighing the following substances in parts by weight: 10-14 parts of dextrin fatty acid ester, 5-7 parts of glycerol, 2-4 parts of acrylic polymer, 3-6 parts of chitosan, 4-8 parts of reinforced montmorillonite, 2-5 parts of fatty alcohol-polyoxyethylene ether, 5-6 parts of sodium hexametaphosphate, 8-10 parts of polyvinyl alcohol and 260-280 parts of deionized water;

(3) putting all the substances weighed in the step (2) into a stirring tank together for high-speed stirring treatment, and taking out the substances after the high-speed stirring treatment to obtain a steeping liquor for later use;

(4) soaking the fabric fiber treated in the step (1) into the impregnation liquid prepared in the step (3), performing ultrasonic treatment for 40-45 min, taking out, washing with deionized water, then placing in a hot air drying oven for drying for 2-4 h, and taking out for later use;

(5) and (4) carrying out conventional weaving on the fabric fiber treated in the step (4) to prepare the finished product socks.

2. The production process of the anti-slip and anti-static socks according to claim 1, wherein the citric acid in the citric acid solution in the step (1) is 0.3-0.5% by mass; and heating to keep the temperature of the citric acid solution at 32-35 ℃ during soaking treatment.

3. The production process of the anti-slip and anti-static socks according to claim 1, wherein the preparation method of the reinforced montmorillonite in the step (2) comprises the following steps:

a. putting montmorillonite into a calcining furnace, heating to keep the temperature in the calcining furnace at 800-850 ℃, calcining for 1-2 h, and taking out;

b. then placing montmorillonite into a high-temperature reaction furnace, wherein the gas in the high-temperature reaction furnace consists of ethane, carbon monoxide and nitrogen, the corresponding volume ratio of the ethane, the carbon monoxide and the nitrogen is 10-12: 20-25: 80-85, then keeping the temperature in the high-temperature reaction furnace at 600-650 ℃, and taking the montmorillonite out for later use after heat preservation treatment for 3-5 hours;

c. and finally, immersing the montmorillonite into a silane coupling agent aqueous solution with the mass fraction of 6-8%, taking out after immersion treatment for 30-40 min, washing with deionized water once, and drying until the integral water content is not more than 5%.

4. The production process of the anti-slip and anti-static socks according to claim 1, wherein the high speed stirring treatment in the step (3) is carried out at a rotation speed of 1600-1800 rpm.

5. The production process of the anti-slip and anti-static socks according to claim 1, wherein the ultrasonic frequency is controlled to be 400-500 kHz during the ultrasonic treatment in the step (4).

6. The production process of the anti-slip and anti-static socks according to claim 1, wherein the temperature in the hot air drying oven is controlled to be 80-85 ℃ during the drying treatment in the step (4).

Technical Field

The invention belongs to the technical field of sock processing and manufacturing, and particularly relates to a production process of anti-slip and anti-static socks.

Background

Socks are indispensable articles for daily use in people's life, and no matter can all use when walking, motion or strolling, because the poor relation of partial socks gas permeability, the foot is often in humidity, airtight microenvironment, breeds the bacterium easily, produces harm feet such as beriberi, and general socks all are knitted moreover and form, and coefficient of friction is little and the grip is not high, and antiskid effect is poor. In addition, the conventional socks are not good in antistatic property, on one hand, the wearing comfort is affected by the generation of static electricity, and on the other hand, the existence of the static electricity in special occasions has great potential safety hazards. In order to improve the antistatic capacity of the socks, the application numbers are as follows: 201720867611.5 discloses an anti-slip and anti-static sock, which has good anti-slip and anti-static performance, but has complex overall structure, high manufacturing difficulty, high cost and poor wearing comfort.

Disclosure of Invention

The invention aims to provide a production process of anti-skid and anti-static socks aiming at the existing problems.

The invention is realized by the following technical scheme:

a production process of anti-slip and anti-static socks comprises the following steps:

(1) soaking the fabric fiber in a citric acid solution for 4-6 min, taking out and naturally airing for later use;

(2) weighing the following substances in parts by weight: 10-14 parts of dextrin fatty acid ester, 5-7 parts of glycerol, 2-4 parts of acrylic polymer, 3-6 parts of chitosan, 4-8 parts of reinforced montmorillonite, 2-5 parts of fatty alcohol-polyoxyethylene ether, 5-6 parts of sodium hexametaphosphate, 8-10 parts of polyvinyl alcohol and 260-280 parts of deionized water;

(3) putting all the substances weighed in the step (2) into a stirring tank together for high-speed stirring treatment, and taking out the substances after the high-speed stirring treatment to obtain a steeping liquor for later use;

(4) soaking the fabric fiber treated in the step (1) into the impregnation liquid prepared in the step (3), performing ultrasonic treatment for 40-45 min, taking out, washing with deionized water, then placing in a hot air drying oven for drying for 2-4 h, and taking out for later use;

(5) and (4) carrying out conventional weaving on the fabric fiber treated in the step (4) to prepare the finished product socks.

Further, the mass fraction of citric acid in the citric acid solution in the step (1) is 0.3-0.5%; and heating to keep the temperature of the citric acid solution at 32-35 ℃ during soaking treatment.

Further, the preparation method of the reinforced montmorillonite in the step (2) comprises the following steps:

a. putting montmorillonite into a calcining furnace, heating to keep the temperature in the calcining furnace at 800-850 ℃, calcining for 1-2 h, and taking out;

b. then placing montmorillonite into a high-temperature reaction furnace, wherein the gas in the high-temperature reaction furnace consists of ethane, carbon monoxide and nitrogen, the corresponding volume ratio of the ethane, the carbon monoxide and the nitrogen is 10-12: 20-25: 80-85, then keeping the temperature in the high-temperature reaction furnace at 600-650 ℃, and taking the montmorillonite out for later use after heat preservation treatment for 3-5 hours;

c. and finally, immersing the montmorillonite into a silane coupling agent aqueous solution with the mass fraction of 6-8%, taking out after immersion treatment for 30-40 min, washing with deionized water once, and drying until the integral water content is not more than 5%.

Further, the rotating speed of stirring is controlled to be 1600-1800 rpm during the high-speed stirring treatment in the step (3).

Further, the frequency of the ultrasonic wave is controlled to be 400-500 kHz during the ultrasonic treatment in the step (4).

Further, the temperature in the hot air drying oven is controlled to be 80-85 ℃ during the drying treatment in the step (4).

The invention improves the production process of the socks, simplifies the structure of the socks and ensures that the socks have good anti-slip and anti-static performances. The fabric fiber for sock production is mainly treated in production, the characteristics of socks are enhanced on the basis, wherein the fabric fiber is soaked by citric acid solution to activate the surface, which is beneficial to subsequent treatment, then impregnation liquid is prepared, a specially-made reinforced montmorillonite component is added in the impregnation liquid, montmorillonite is usually used as a filler and is also applied in the textile field, but in order to be better used in sock production, the reinforced modification treatment is carried out on the montmorillonite, the montmorillonite is subjected to high-temperature calcination treatment, the specific surface area and the adsorption capacity are improved by utilizing high temperature, then the montmorillonite is put into a high-temperature reaction furnace, under the high-temperature condition, the iron oxide component in the montmorillonite is reduced into atomic iron by hydrogen, the atomic iron can catalyze and promote the carbon chain fracture of ethane, so that a graphene layer can be deposited on the surface of the montmorillonite, the graphene layer and the montmorillonite are high in bonding strength, the surface characteristic of the montmorillonite is improved, the adsorption capacity of the montmorillonite is obviously improved, the reinforced montmorillonite is added into the impregnation liquid and then is adsorbed and fixed on the fabric fiber, the adsorption performance of the fabric fiber is obviously improved, the sweat absorption, deodorization and antibacterial performance of the sock are further improved, meanwhile, a conductive network structure is formed by the graphene layer through adsorption and filling of the montmorillonite, the antistatic performance of the sock is obviously enhanced, in addition, the reinforced montmorillonite can also play a role in filling dextrin fatty acid ester and acrylic polymer in the impregnation liquid and enhancing the bonding strength, the fixing strength of the whole on the fabric fiber is improved, the adhesion of the sock and the foot step can be improved through the addition of the dextrin fatty acid ester and the acrylic polymer, the sticky feeling is avoided at the same time, and the sweat absorption adsorption capacity of the reinforced montmorillonite is matched, ensuring the dry and comfortable comfort of the wearer, and finally weaving the treated textile fiber conventionally.

Compared with the prior art, the invention has the following advantages:

the invention provides a sock production process, which is simple in process steps and convenient to popularize and apply, and is suitable for producing socks in various shapes and types.

Detailed Description

A production process of anti-slip and anti-static socks comprises the following steps:

(1) soaking the fabric fiber in a citric acid solution for 4-6 min, taking out and naturally airing for later use;

(2) weighing the following substances in parts by weight: 10-14 parts of dextrin fatty acid ester, 5-7 parts of glycerol, 2-4 parts of acrylic polymer, 3-6 parts of chitosan, 4-8 parts of reinforced montmorillonite, 2-5 parts of fatty alcohol-polyoxyethylene ether, 5-6 parts of sodium hexametaphosphate, 8-10 parts of polyvinyl alcohol and 260-280 parts of deionized water;

(3) putting all the substances weighed in the step (2) into a stirring tank together for high-speed stirring treatment, and taking out the substances after the high-speed stirring treatment to obtain a steeping liquor for later use;

(4) soaking the fabric fiber treated in the step (1) into the impregnation liquid prepared in the step (3), performing ultrasonic treatment for 40-45 min, taking out, washing with deionized water, then placing in a hot air drying oven for drying for 2-4 h, and taking out for later use;

(5) and (4) carrying out conventional weaving on the fabric fiber treated in the step (4) to prepare the finished product socks.

Further, the mass fraction of citric acid in the citric acid solution in the step (1) is 0.3-0.5%; and heating to keep the temperature of the citric acid solution at 32-35 ℃ during soaking treatment.

Further, the preparation method of the reinforced montmorillonite in the step (2) comprises the following steps:

a. putting montmorillonite into a calcining furnace, heating to keep the temperature in the calcining furnace at 800-850 ℃, calcining for 1-2 h, and taking out;

b. then placing montmorillonite into a high-temperature reaction furnace, wherein the gas in the high-temperature reaction furnace consists of ethane, carbon monoxide and nitrogen, the corresponding volume ratio of the ethane, the carbon monoxide and the nitrogen is 10-12: 20-25: 80-85, then keeping the temperature in the high-temperature reaction furnace at 600-650 ℃, and taking the montmorillonite out for later use after heat preservation treatment for 3-5 hours;

c. and finally, immersing the montmorillonite into a silane coupling agent aqueous solution with the mass fraction of 6-8%, taking out after immersion treatment for 30-40 min, washing with deionized water once, and drying until the integral water content is not more than 5%.

Further, the rotating speed of stirring is controlled to be 1600-1800 rpm during the high-speed stirring treatment in the step (3).

Further, the frequency of the ultrasonic wave is controlled to be 400-500 kHz during the ultrasonic treatment in the step (4).

Further, the temperature in the hot air drying oven is controlled to be 80-85 ℃ during the drying treatment in the step (4).

The acrylic polymer is obtained by copolymerizing an acrylic alkyl ester having no functional group and an acrylic alkyl ester having a functional group or other monomer components other than the acrylic alkyl ester as main components. The acrylic alkyl ester having no functional group is an alkyl acrylate or an alkyl methacrylate in which the number of carbon atoms of an alkyl group is about 1 to 12, such as methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, pentyl (meth) acrylate, hexyl (meth) acrylate, heptyl (meth) acrylate, octyl (meth) acrylate, nonyl (meth) acrylate, decyl (meth) acrylate, undecyl (meth) acrylate, or dodecyl (meth) acrylate, and specifically 1 kind or 2 or more kinds may be used in combination. The acrylic alkyl ester having a functional group is a hydroxyl group-or epoxy group-containing acrylic alkyl ester such as 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate or glycidyl methacrylate. The other monomer than the acrylic alkyl ester is vinyl acetate, styrene, acrylonitrile, N-methylolacrylamide, N-dimethylacrylamide, or (meth) acrylamide.

The dextrin fatty acid ester is 1 or more selected from dextrin palmitate, dextrin caprylate, dextrin myristate, and dextrin ethylhexanoate.

The present invention will be further illustrated with reference to the following examples.