阅读说明：本技术 官能化氟化单体的制备方法、氟化单体及用于制备其的组合物 (Method for preparing functionalized fluorinated monomers, fluorinated monomers and compositions for preparing same ) 是由 M·P·格雷尔 于 2018-05-21 设计创作，主要内容包括：一种用于制造低聚物和聚合物的官能化氟化单体的制备方法,该低聚物和聚合物可用于改善聚合物衍生体系(例如涂料)的表面性能。制备官能化氟化单体的方法包括使至少一种氟化亲核反应物,例如氟化醇,与至少一种含有至少一个环氧基的化合物反应。其他方法包括氟化醇与环状羧酸酐的反应。在另一个实施方式中,一种方法包括使氟化甲磺酸酯、甲苯磺酸酯或三氟甲磺酸酯与胺、醇盐或酚盐反应。在其他实施方式中,该方法包括使氟化醇与卤代烷反应,或使氟化卤代烷与胺反应。官能化氟化单体可以用作中间体并反应以改性其上的官能团。此外,官能化氟化单体可以反应形成聚合物或低聚物,或与具有官能团的聚合物或低聚物反应以通过其上的官能团改性聚合物或低聚物。(A process for the preparation of functionalized fluorinated monomers useful for making oligomers and polymers useful for improving the surface properties of polymer derived systems, such as coatings. The method of preparing the functionalized fluorinated monomers includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxy group. Other methods include the reaction of fluorinated alcohols with cyclic carboxylic acid anhydrides. In another embodiment, a method comprises reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method comprises reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers can be used as intermediates and reacted to modify functional groups thereon. In addition, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or reacted with polymers or oligomers having functional groups to modify the polymers or oligomers with the functional groups thereon.)