作为润湿剂和分散剂的单环氧化物-单胺加合物

文档序号:1549065 发布日期:2020-01-17 浏览:30次 >En<

阅读说明:本技术 作为润湿剂和分散剂的单环氧化物-单胺加合物 (Monoepoxide-monoamine adducts as wetting agents and dispersants ) 是由 M·贝塞尔 M·梅彻斯内尔 C·纳格尔 M·桑切斯和索萨 C·比耶克尔 P·斯坦恩 于 2018-03-28 设计创作,主要内容包括:本发明涉及可如下获得的环氧化物-胺加合物:通过一种或多种通式(I)的伯胺(A)与一种或多种通式(II)的单环氧化物(B)反应,其中Q是基团R&lt;Sup&gt;t&lt;/Sup&gt;-[OEt]&lt;Sub&gt;n&lt;/Sub&gt;[OPr]&lt;Sub&gt;m&lt;/Sub&gt;[OBu]&lt;Sub&gt;s&lt;/Sub&gt;-,其中R&lt;Sup&gt;t&lt;/Sup&gt;是选自具有1至6个碳原子的烷基的基团,OEt是环氧乙烷基团,OPr是环氧丙烷基团且OBu是环氧丁烷基团,n是0至100的数,m是3至50的数且s是0至20的数且n+m+s=3至170,R是选自具有4至24个碳原子的脂族基团、具有6至18个碳原子的芳族基团和具有7至34个碳原子的芳脂族基团的有机基团,且p是0或1,其中(i)使伯胺(A)和单环氧化物(B)以1:2至1:1.35的当量比(A):(B)反应;和(ii)至少40摩尔%的基团R选自具有6至18个碳原子的芳族基团和具有7至24个碳原子的芳脂族基团;和任选随后所述反应产物的成盐和/或季铵化和/或改性。本发明还涉及包含或由所述环氧化物-胺加合物构成的润湿剂和分散剂,还涉及所述润湿剂和分散剂的生产,涉及所述环氧化物-胺加合物和所述润湿剂和分散剂用于生产分散体的用途。本发明还涉及包含所述环氧化物-胺加合物和润湿剂和分散剂的分散体和颗粒配制剂。Q-NH&lt;Sub&gt;2&lt;/Sub&gt;(I);&lt;Image he="182" wi="580" file="DDA0002299940780000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"&gt;&lt;/Image&gt;。(The present invention relates to epoxide-amine adducts obtainable as follows: by reacting one or more primary amines (A) of the formula (I) with one or more monoepoxides (B) of the formula (II) in which Q is a radical R t ‑[OEt] n [OPr] m [OBu] s -, wherein R t Is a group selected from alkyl groups having from 1 to 6 carbon atoms, OEt is an ethylene oxide group, OPr is a propylene oxide group and OBu is a butylene oxide group, n is a number from 0 to 100, m is a number from 3 to 50 and s is a number from 0 to 20 and n &#43; m &#43; s ═ 3 to 170, R is a group selected from aliphatic groups having from 4 to 24 carbon atoms, aromatic groups having from 6 to 18 carbon atoms and araliphatic groups having from 7 to 34 carbon atomsAn organic group, and p is 0 or 1, wherein (i) a primary amine (a) and a monoepoxide (B) are reacted in an equivalent ratio of (a) to (B) of 1:2 to 1: 1.35; and (ii) at least 40 mol% of the radicals R are selected from aromatic radicals having 6 to 18 carbon atoms and araliphatic radicals having 7 to 24 carbon atoms; and optionally subsequent salification and/or quaternization and/or modification of the reaction product. The invention also relates to wetting agents and dispersants comprising or consisting of the epoxide-amine adduct, to the production of the wetting agents and dispersants, and to the use of the epoxide-amine adduct and the wetting agents and dispersants for producing dispersions. The invention also relates to dispersions and particle formulations comprising the epoxide-amine adduct and wetting and dispersing agents. Q-NH 2 (I); 。)

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