Member for electricity storage device, method for producing same, and electricity storage device
阅读说明:本技术 蓄电装置用构件、其制造方法和蓄电装置 (Member for electricity storage device, method for producing same, and electricity storage device ) 是由 中林诚 阮红福 海田启司 奥村素宜 菊池卓郎 于 2018-03-20 设计创作,主要内容包括:本发明提供一种蓄电装置用构件。所述蓄电装置用构件包含主要由金属构成的基材和层叠在所述基材上的树脂层,其中所述树脂层含有交联含氟树脂。(The invention provides a member for an electric storage device. The member for an electricity storage device comprises a base material mainly composed of a metal and a resin layer laminated on the base material, wherein the resin layer contains a crosslinked fluorine-containing resin.)
1. A member for an electric storage device, comprising:
a base material mainly composed of a metal; and
a resin layer laminated on the substrate,
the resin layer contains a crosslinked fluorine-containing resin.
2. The member for a power storage device according to claim 1,
the fluorine-containing resin and the surface of the base material have a chemical bond therebetween.
3. The member for a power storage device according to claim 1 or 2,
the resin layer is a thermal adhesive layer.
4. The member for a power storage device according to claim 1, 2, or 3,
the resin layer contains a cloth or a filler, and
the resin layer has a linear thermal expansion coefficient of 1X 10-7/K~40×10-6/K。
5. The member for power storage devices according to any one of claims 1 to 4, further comprising a covering layer containing a fluorine-containing resin, wherein,
the cover layer is laminated on a surface of the resin layer opposite to the substrate,
the fluorine-containing resin contained in the cover layer is a non-crosslinked fluorine-containing resin or a fluorine-containing resin having a melting point lower than that of the crosslinked fluorine-containing resin.
6. The member for power storage devices according to any one of claims 1 to 5,
the cross-linked fluorine-containing resin is tetrafluoroethylene-hexafluoropropylene copolymer.
7. The member for a power storage device according to claim 5,
the fluorine-containing resin contained in the covering layer is tetrafluoroethylene-hexafluoropropylene copolymer.
8. The member for power storage devices according to any one of claims 1 to 7,
the peel strength between the resin layer and the base material is 0.1N/cm to 100N/cm.
9. The member for power storage devices according to any one of claims 1 to 8,
a ten-point average roughness (R) of the surface of the substrate in a region where the resin layers are laminatedZ) 0.001 to 10 μm.
10. The member for power storage devices according to any one of claims 1 to 9,
the component for the electric storage device is a tab lead or a case.
11. A method of manufacturing a member for a power storage device, the method comprising the steps of:
laminating a layer containing a fluorine-containing resin on a base material mainly composed of a metal, and
ionizing radiation is applied to the layer containing the fluorine-containing resin.
12. An electrical storage device, comprising:
a positive electrode;
a negative electrode;
an electrolyte;
a case that accommodates the positive electrode, the negative electrode, and the electrolyte; and
a lead wire of the pole ear is connected with the pole ear,
one end of the tab lead is exposed from the case and the other end is connected with the positive electrode or the negative electrode,
the case and the tab leads are thermally bonded to each other,
at least one of the case and the tab lead is the member for a power storage device according to any one of claims 1 to 9.
13. The power storage device according to claim 12, further comprising a thermoadhesive film interposed between the case and the tab lead, wherein,
the heat-adhesive film contains a non-crosslinked fluorine-containing resin or a fluorine-containing resin having a melting point lower than that of a crosslinked fluorine-containing resin.
Technical Field
The invention relates to a member for a power storage device, a method for manufacturing the same, and a power storage device. This application claims priority to japanese patent application No. 2017-110096, filed on 6/2 of 2017, the disclosure of which is incorporated herein by reference in its entirety.
Background
Lithium ion secondary batteries have been used as power sources for electronic devices. In addition to secondary batteries, other power storage devices such as electric double layer capacitors have been developed. For example, a secondary battery generally includes: a bag-like case made of an aluminum laminate film or the like; an electrode group including a positive electrode, a negative electrode, and the like, housed in the case; and a tab lead extending from the inside of the case to the outside (refer to patent document 1).
The tab lead is mainly composed of a metal base material responsible for transmitting electric power between the positive electrode or negative electrode of the electrode group and an external member. Typically, the pouch case further comprises a metal substrate in the form of a film. In order to electrically insulate the base material of the case from the base material of the tab lead, resin layers are respectively provided on the two base materials, and the two base materials are joined to each other with the resin layer interposed therebetween. The presence of these resin layers also makes it possible to seal the electrode group within the pouch-shaped case.
Typically, these resin layers are made of polyolefins such as polypropylene. These resin layers need to be sufficiently adhered to the metal substrate. However, for example, polyolefins have poor adhesion to metals. Therefore, in the tab lead or the like, when the base material and the polyolefin resin layer are laminated on each other, the acid-modified polyolefin is generally interposed between the base material and the polyolefin resin layer.
Disclosure of Invention
The present invention has been devised to solve the above problems. One aspect of the present invention is a member for an electricity storage device, comprising a base material mainly composed of a metal and a resin layer laminated on the base material, wherein the resin layer contains a crosslinked fluorine-containing resin.
Another aspect of the invention is a method of manufacturing a member for a power storage device, wherein the method includes the steps of: a layer containing a fluorine-containing resin is laminated on a base material mainly composed of a metal, and ionizing radiation is applied to the layer containing the fluorine-containing resin.
Another aspect of the invention is an electric storage device including a positive electrode; a negative electrode; an electrolyte; a case for accommodating the positive electrode, the negative electrode, and the electrolyte; and a tab lead having one end exposed from the case and the other end connected to the positive electrode or the negative electrode, wherein the case and the tab lead are thermally bonded to each other, and at least one of the case and the tab lead is the member for an electric storage device described above.
Drawings
Fig. 1 is a perspective view of a secondary battery according to a first embodiment of a power storage device of the present invention.
Fig. 2 is a partial sectional view of the secondary battery shown in fig. 1.
Fig. 3 is a partial cross-sectional view of a tab lead of a second embodiment of a member for an electricity storage device according to the present invention.
Fig. 4 is a partial sectional view of a secondary battery according to a third embodiment of the power storage device of the invention.
Detailed Description
[ problem to be solved by the present disclosure ]
The resin layer is required to have not only heat adhesiveness and adhesion to a substrate but also durability against an electrolytic solution, i.e., chemical resistance, heat resistance, flame retardancy, and strength, for example. When the chemical resistance or heat resistance of the resin layer is poor, adverse consequences may occur, including easy leakage of the electrolyte from, for example, a thermal bonding interface or an interface between the substrate and the resin layer. With the trend of applying a larger current and a higher voltage to an electric storage device such as an electric storage device for an electric vehicle, the demand for improvement in heat resistance and the like is also increasing.
The present invention has been devised in view of the above circumstances. The purpose of the present invention is to provide a member for an electrical storage device having good heat resistance and good flame retardancy, a method for manufacturing the member for an electrical storage device, and an electrical storage device including the member for an electrical storage device.
[ Effect of the present disclosure ]
The present invention can provide a member for an electric storage device including a resin layer having good heat resistance and good flame retardancy, a method of manufacturing the member for an electric storage device, and an electric storage device including the member for an electric storage device.
[ description of embodiments ]
A member for an electricity storage device according to one aspect of the present invention includes a base material mainly composed of a metal, and a resin layer laminated on the base material, wherein the resin layer contains a crosslinked fluorine-containing resin. The term "crosslinked" herein refers to a state in which a three-dimensional crosslinked structure is formed.
In a member for an electric storage device that includes a resin layer containing a crosslinked fluorine-containing resin and thus has good heat resistance and good chemical resistance, liquid leakage is reduced. In addition, the crosslinked fluorine-containing resin is excellent in flame retardancy. Therefore, the member for an electric storage device is excellent in, for example, heat resistance and flame retardancy of the resin layer, and is therefore suitable for an electric storage device intended to be used under high temperature and severe environment, such as an electric storage device for an electric vehicle. Further, the power storage device including the member for a power storage device is highly safe in an unpredictable abnormal situation such as heat generation. Here, the term "mainly composed of … (component)" means that the content of the component in all the components is the highest, preferably 50 mass% or more.
In the member for an electricity storage device, it is preferable that a chemical bond exists between the fluorine-containing resin and the surface of the base material. This configuration can improve the adhesion between the substrate and the resin layer, thereby making it possible to alleviate liquid leakage and ensure safety even in the case where an impact such as that caused by dropping is applied. Further, in manufacturing the member for a power storage device, neither roughening treatment of the base material nor use of an adhesive is required, so that productivity can be improved. "chemical bond" refers to any of covalent, ionic, and hydrogen bonds.
Preferably, the resin layer is a thermal adhesive layer. With this configuration, excellent thermal adhesiveness can be exhibited. The "thermal adhesive layer" herein refers to a layer bonded to another resin layer by a thermal bonding process. In the heat bonding treatment, the heat bonding layer, which is the resin layer of the member for the power storage device, can be softened to achieve heat bonding; or another resin layer to be bonded with the thermal bonding layer may be softened to achieve thermal bonding. In the latter case, the thermal adhesive layer of the member for an electrical storage device may remain substantially un-softened at the time of thermal bonding.
Preferably, the resin layer contains a cloth or a filler, and the resin layer has a linear thermal expansion coefficient of 1 × 10-7/K~40×10-6and/K. Such a configuration in which the resin layer contains the cloth or the filler can thereby lower the linear thermal expansion coefficient, thereby bringing the thermal expansion coefficient of the resin layer closer to that of the base material mainly composed of the metal. Thereby, for example, strain caused by a change in temperature is relieved, so that the peel strength, more specifically, the adhesion between layers can be further improved. When the substrate is temporarily adhered to the fluorine-containing resin layer by a technique such as pressing and then ionizing radiation is applied to the resultant to perform crosslinking, a very small gap may be formed, for example, between the substrate and the resin layer before the ionizing radiation is applied, due to a difference in linear thermal expansion coefficient. Thus, as described above, the resin layer contains the clothOr the filler and thus the resin layer has a coefficient of thermal expansion closer to that of the base material, the formation of a gap due to the difference in the linear thermal expansion coefficients can be alleviated. With the above-described configuration in which the resin layer contains cloth or filler, the tensile strength at break and the like can also be improved, whereby performance such as safety and durability can be improved. "coefficient of linear thermal expansion" herein refers to the length of an object that increases when the temperature increases by 1 ℃. Used herein is an average value of linear thermal expansion coefficients measured when the temperature is increased from 20 ℃ to 150 ℃. The "coefficient of linear thermal expansion" can be measured according to JIS-K-7197(2012) "test method for the coefficient of linear thermal expansion of plastics by thermal mechanical analysis".
Preferably, the member for an electricity storage device further includes a covering layer containing a fluorine-containing resin, the covering layer being laminated on a surface of the resin layer opposite to the substrate, and the fluorine-containing resin contained in the covering layer is a non-crosslinked fluorine-containing resin or a fluorine-containing resin having a melting point lower than that of the crosslinked fluorine-containing resin. With such a structure further including a coating layer containing a fluorine-containing resin, it is possible to maintain good heat resistance and good flame retardancy, and to improve heat adhesiveness.
Preferably, the crosslinked fluororesin is a tetrafluoroethylene-hexafluoropropylene copolymer (FEP). Compared with other fluorine-containing resins, FEP has a low melting point and has high fluidity at about 300 ℃. Therefore, the use of FEP in the resin layer can lower the heat bonding temperature and can shorten the duration of the heat bonding treatment.
Preferably, the fluorine-containing resin contained in the cover layer is FEP. As described above, FEP is preferable among the fluorine-containing resins from the viewpoint of heat adhesiveness. The use of FEP in the cover layer can lower the heat bonding temperature and shorten the duration of the heat bonding process.
Preferably, the peel strength of the resin layer from the substrate is 0.1N/cm to 100N/cm. The adhesion between the substrate and the resin layer can be further improved by setting the peel strength between the resin layer and the substrate to 0.1N/cm or more. Further, the peel strength is used as an index of the degree of crosslinking of the fluorine-containing resin in the resin layer. When the peel strength is 0.1N/cm or more, it is indicated that crosslinking is formed to an extent suitable for further improvement of heat resistance and chemical resistance. Further, when the peel strength between the resin layer and the substrate is 100N/cm or less, it indicates that crosslinking is formed to such an extent that moderate softening occurs upon heating to improve the heat adhesiveness. "peel strength" herein means "measurement of peel strength of adhesive-bonded assembly" according to JIS-K-6854-2(1999) "part 2: 180 ° peel "test method.
Preferably, in the region where the resin layers are laminated, the ten-point average roughness (R) of the surface of the base materialZ) In the range of 0.001 to 10 μm. When the smoothness of the surface of the substrate in the region where the resin layers are laminated is high, the thickness of the resin layer is uniform, so that insulation breakdown and migration can be reduced. In addition, the thermal adhesiveness and chemical resistance can be improved. Further, when the smoothness of the substrate surface is high, roughening treatment such as etching is not required, so that productivity can be improved. "Ten-point average roughness (Rz)" herein means a value obtained by measurement according to JIS-B-0601(2001) in which the cutoff wavelength (. lamda.c) is 2.5mm and the evaluation length (. lamda.c) is 12.5 mm.
Preferably, the member for the power storage device is a tab lead or a case. When the member for an electric storage device is used as a tab lead and/or a case, the advantages of the present invention including good heat resistance and good flame retardancy can be further effectively exhibited.
A method of manufacturing a member for a power storage device according to an aspect of the present invention includes the steps of: a layer containing a fluorine-containing resin is laminated on a base material mainly composed of a metal, and ionizing radiation is applied to the layer containing the fluorine-containing resin.
With the ionizing radiation, a cross-link may be formed in the fluorine-containing resin in the irradiated layer, and a chemical bond may also be formed between the fluorine-containing resin and the metal or the like in the base material. Therefore, a member for an electric storage device including a resin layer having good heat resistance, good flame retardancy, and excellent adhesion to a substrate can be obtained by using the production method.
An electrical storage device according to an aspect of the present invention includes: a positive electrode; a negative electrode; an electrolyte; a case for accommodating the positive electrode, the negative electrode, and the electrolyte; and a tab lead having one end exposed from the case and the other end connected to the positive electrode or the negative electrode, wherein the case and the tab lead are thermally bonded to each other, and at least one of the case and the tab lead is the member for an electric storage device described above.
In the power storage device in which at least one of the case and the tab lead is the above-described member for a power storage device, the resin layer has good heat resistance and good flame retardancy. Therefore, the power storage device can maintain its high quality even when used in a severe environment including a high-temperature environment or under a high voltage and a high current, for example.
Preferably, the power storage device further comprises a thermoadhesive film interposed between the case and the tab lead, wherein the thermoadhesive film contains a non-crosslinked fluorine-containing resin or a fluorine-containing resin having a melting point lower than that of the crosslinked fluorine-containing resin. In the electricity storage device in which a heat-adhesive film containing a non-crosslinked fluorine-containing resin or a fluorine-containing resin having a melting point lower than that of the crosslinked fluorine-containing resin is interposed between the case and the tab lead, heat adhesiveness can be improved.
[ details of embodiments of the present invention ]
< first embodiment:
Next, a secondary battery according to a first embodiment of the power storage device according to the present invention will be described in detail with reference to the appropriate drawings. A case and a tab lead of a secondary battery will also be described as embodiments of a member for an electric storage device according to the present invention.
The
A positive electrode and a negative electrode (not shown) are stacked on each other with a separator interposed therebetween, whereby they form a stacked electrode group. The stacked electrode groups and the electrolyte are housed in a
Typically, the positive electrode and the negative electrode are each a laminate composed of: a current collector such as a metal foil; an active material layer containing an active material is laminated on a surface of the current collector. The positive electrode and the negative electrode are each generally plate-shaped, but may be different in shape.
The separator is typically a porous sheet that is electrically insulating. The separator is impregnated with an electrolyte.
The electrolytic solution may be a nonaqueous solvent in which an electrolyte salt is dissolved. Alternatively, the solvent in the electrolyte may be water.
(case 11)
As shown in fig. 2, a
The
Preferably, the ten-point average roughness (R) in the inner side surface of the
The
The fluorine-containing resin refers to a resin in which at least one hydrogen atom bonded to a carbon atom in a main chain structural unit of a polymer chain is substituted with a fluorine atom or an organic group containing a fluorine atom (hereinafter, also referred to as a "fluorine atom-containing group"). The fluorine atom-containing group refers to a group in which at least one hydrogen atom in a linear, branched or cyclic organic group is substituted with a fluorine atom. Examples of the fluorine atom-containing group include fluoroalkyl groups, fluoroalkoxy groups and fluoropolyether groups.
"fluoroalkyl" refers to an alkyl group in which at least one hydrogen atom is replaced with a fluorine atom. Also included are "perfluoroalkyl groups". More specifically, "fluoroalkyl" comprises, for example, the following groups: an alkyl group in which all hydrogen atoms in the alkyl group are substituted with fluorine atoms, and an alkyl group in which all hydrogen atoms except one terminal hydrogen atom are substituted with fluorine atoms.
"fluoroalkoxy" refers to an alkoxy group in which at least one hydrogen atom is replaced by a fluorine atom. "Perfluoroalkoxy" is also included. More specifically, "fluoroalkoxy" includes, for example, the following groups: an alkoxy group in which all hydrogen atoms in the alkoxy group are substituted with fluorine atoms, and an alkoxy group in which all hydrogen atoms except one terminal hydrogen atom are substituted with fluorine atoms.
"fluoropolyether group" means a monovalent group having a plurality of oxyalkylene chains as a repeating unit and containing an alkyl group or a hydrogen atom at a terminal, wherein at least one hydrogen atom in the oxyalkylene chain and/or at least one hydrogen atom in the terminal alkyl group or the terminal hydrogen atom is substituted with a fluorine atom. The "fluoropolyether group" includes a "perfluoropolyether group" having a plurality of perfluoroalkoxyalkylene chains as a repeating unit.
The fluorine-containing resin is a polymer compound containing a fluorine atom in the molecule. Examples of the fluorine-containing resin include tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene- (perfluoroalkyl vinyl ether) copolymer (PFA), Polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluorodioxole copolymer (TFE/PDD), Polychlorotrifluoroethylene (PCTFE), chlorotrifluoroethylene-Ethylene Copolymer (ECTFE), polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), (vinylidene fluoride) -hexafluoropropylene copolymer (VDF-HFP copolymer), and (vinylidene fluoride) -hexafluoropropylene-tetrafluoroethylene copolymer (VDF-HFP-TFE copolymer). Among these fluorine-containing resins, tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene- (perfluoroalkylvinyl ether) copolymer (PFA), Polytetrafluoroethylene (PTFE), and tetrafluoroethylene-perfluorodioxole copolymer (TFE/PDD) are preferable, and FEP is more preferable. For example, the use of FEP can improve the heat adhesiveness as described above. One kind of these fluorine-containing resins may be used, or two or more kinds thereof may be used as a mixture.
The fluorine-containing resin in the
In the
For example, the presence of a chemical bond between the fluorine-containing resin and the base material can be confirmed by X-ray photoelectron spectroscopy (XPS), also referred to as Electron Spectroscopy for Chemical Analysis (ESCA). The X-ray photoelectron spectroscopy involves measuring the energy distribution of photoelectrons released from a sample upon X-ray irradiation, and then subtracting the obtained value from the energy value of the irradiated X-ray, thereby calculating the binding energy of electrons. The value of the binding energy of an electron is inherent to, for example, an element and its electronic state, and therefore the presence of an element and a chemical bond in a sample can be confirmed from the value. In particular, using hard X-rays such as Spring-8, it is possible to analyze a depth of about 20nm, and thus, it is possible to analyze chemical bonds at the interface.
The melting point of the crosslinked fluorine-containing resin in the
The formation of crosslinks in the fluorine-containing resin in the
The lower limit of the peel strength between the
The lower limit of the content of the fluorine-containing resin in the
Preferably, the
The percentage content of the cloth or filler in the
Examples of additional components that may be included in the
The upper limit of the linear thermal expansion coefficient of the
The average thickness of the
For example, the
(
As shown in fig. 2, the tab leads 12, 12' as one embodiment of the member for the power storage device according to the present invention include a
The
The size of the
Ten-point average roughness (R) in the central portion in the longitudinal direction of the
Both end portions of the
The
The crosslinked fluororesin contained in the
The average thickness of the
As described above, in the
(advantages)
In the
< method for manufacturing Member for Electrical storage device (
A method of manufacturing a member for a power storage device according to an embodiment of the present invention includes the steps of:
laminating a layer containing a fluorine-containing resin on a base material mainly composed of a metal; and
ionizing radiation is applied to the layer containing the fluorine-containing resin.
The ionizing radiation causes the fluorine-containing resin to crosslink to form a resin layer. In other words, this manufacturing method is suitable for manufacturing the
(laminating step)
The laminating step includes laminating a layer containing a fluorine-containing resin on the base material. The lamination can be performed, for example, by the following method: a method of forming a layer containing a substantially non-crosslinked fluorine-containing resin by melt extrusion while laminating the layer on a surface of a base material; or a method of laminating a layer containing a substantially non-crosslinked fluorine-containing resin and a substrate together. Alternatively, powder coating using a fluororesin-containing powder may be used to laminate the layers containing a fluororesin.
(irradiation step)
The irradiation step is performed by applying ionizing radiation to a laminate composed of a base material and a layer containing a fluorine-containing resin, more specifically, to the surface of the layer containing a fluorine-containing resin. As in the case of the
The laminate placed in an oxygen-free atmosphere, more specifically, an atmosphere having an oxygen concentration of 100ppm or less and the fluorine-containing resin in a molten state is subjected to the application of ionizing radiation. By this step, a crosslink is formed in the fluorine-containing resin, and a chemical bond is formed between the fluorine-containing resin and the base material.
More preferably, the oxygen-free atmosphere has an oxygen concentration of 10ppm or less. When the oxygen concentration is too high, the main chain of the fluorine-containing resin may be cut when ionizing radiation is applied. Preferably, the fluorine-containing resin is melted at a temperature higher than the melting point of the fluorine-containing resin, and the temperature difference is 0 ℃ or more and less than 30 ℃. When the fluorine-containing resin is heated to a temperature of 30 ℃ or more above the melting point, thermal degradation of the fluorine-containing resin may be promoted, thereby impairing the material properties. Examples of methods of reducing the oxygen concentration include using an inert gas such as nitrogen or creating a vacuum.
Examples of ionizing radiation that may be used include: gamma rays, electron beams, X-rays, neutron beams, and high energy ion beams. Preferably, the dose of ionizing radiation is from 0.01kGy to 2000kGy, more preferably from 1kGy to 500 kGy. When the dose of the radiation is less than the lower limit, the crosslinking reaction in the fluorine-containing resin may not sufficiently proceed. In contrast, when the dose of radiation is higher than the upper limit, the fluorine-containing resin may be easily degraded, and the crosslinking reaction may excessively proceed to impair the thermal adhesiveness.
The process of manufacturing the
< second embodiment: component for electric storage device (tab lead 22) >
The
On the substrate 28, a resin layer 29 and a
The resin layer 29 is directly laminated on the substrate 28. The resin layer 29 is a layer containing a crosslinked fluorine-containing resin. As the resin layer 29, the
The
The lower limit of the content of the fluorine-containing resin in the
For example, the
The
< third embodiment:
As shown in fig. 4, a
The
The heat-
< other embodiment >
It is to be understood that the embodiments disclosed herein are illustrative and not restrictive in all respects. The scope of the present invention is defined by the claims, not by the constitution of the above embodiments, and includes any modifications and variations within the meaning and scope equivalent to the claims.
For example, the description in the above embodiment has been made with the secondary battery as an exemplary power storage device, but the present invention may be applied to a power storage device other than a secondary battery. Examples of the power storage device other than the secondary battery include an electric double layer capacitor.
In the secondary battery according to the above embodiment, both the case and the tab lead are members for the power storage device according to the present invention. However, one of the case and the tab lead may be a conventional one. In other words, the resin layer of one of the case and the tab lead may not contain the crosslinked fluorine-containing resin. In this case, the resin layer may be made of a known thermoplastic resin, such as a non-crosslinked fluorine-containing resin, polyolefin, polyphenylene sulfide, and/or polyether ether ketone. As an alternative configuration, a cover layer may be laminated on the surface of the resin layer of the case. Further, the member for a power storage device according to the present invention may further include a layer other than any one of the base material, the resin layer, and the cover layer.
The member for the power storage device according to the present invention is not limited to the case and the tab lead. For example, the member for a power storage device according to the present invention may be used as a package of a power storage device.
- 上一篇:一种医用注射器针头装配设备
- 下一篇:可移除接头片以及具有其的电池组件