Resin polyacrylamide gel profile control agent

文档序号:1731151 发布日期:2019-12-20 浏览:44次 中文

阅读说明:本技术 一种树脂类聚丙烯酰胺凝胶调剖剂 (Resin polyacrylamide gel profile control agent ) 是由 于少君 李图雅 张作辉 张作民 王杰 于 2019-10-14 设计创作,主要内容包括:本发明一种树脂类聚丙烯酰胺凝胶调剖剂,涉及石油开采技术领域,是由下列物质按质量份数混合而成:聚丙烯酰胺5~8份、促溶剂0.2~0.6份、酚醛交联剂0.5~1.0份、引发剂0.1~0.3份和水90~98份。本发明的一种树脂类聚丙烯酰胺凝胶调剖剂,添加了促溶剂,加快了产品各组分之间的溶解速度,极大的减少了产品配置过程的配置时间,提高了现场工作的工作效率,同时也能有效降低现场工作的差错率;注入井下剖面改善效果好;同时能够利用温度控制呈胶时间,产品针对性强。(The invention relates to a resin polyacrylamide gel profile control agent, which relates to the technical field of oil exploitation and is prepared by mixing the following substances in parts by weight: 5-8 parts of polyacrylamide, 0.2-0.6 part of a dissolution promoter, 0.5-1.0 part of a phenolic crosslinking agent, 0.1-0.3 part of an initiator and 90-98 parts of water. According to the resin polyacrylamide gel profile control agent, the dissolution accelerator is added, so that the dissolution speed of each component of a product is accelerated, the configuration time of the product configuration process is greatly reduced, the working efficiency of field work is improved, and the error rate of the field work can be effectively reduced; the injection underground section has good improvement effect; meanwhile, the glue forming time can be controlled by using the temperature, and the product pertinence is strong.)

1. A resin polyacrylamide gel profile control agent is characterized by being prepared by mixing the following substances in parts by mass: 5-8 parts of polyacrylamide, 0.2-0.6 part of a dissolution promoter, 0.5-1.0 part of a phenolic crosslinking agent, 0.1-0.3 part of an initiator and 90-98 parts of water.

2. The resin-based polyacrylamide gel profile control agent of claim 1, wherein said dissolution promoter is acetone.

3. The resin-based polyacrylamide gel profile control agent of claim 1, wherein said phenol-formaldehyde cross-linking agent is a phenol-formaldehyde resin.

4. The resin-based polyacrylamide gel profile control agent according to claim 1, wherein the initiator is prepared by the following method: dissolving petroleum resin in acetone, and stirring at constant temperature of 120-150 ℃ until the mixture is uniform to obtain a wall material dispersion system, wherein the mass ratio of the petroleum resin to the acetone is 1: 75-90; adding ammonium persulfate and an auxiliary agent into the wall material dispersion system to obtain a core wall system, wherein the mass ratio of the wall material dispersion system to the core material to the auxiliary agent is (50-70: 2): 0.1 to 0.2; and mixing and homogenizing the core wall system and water, keeping the temperature of 120-150 ℃ for 2-4 hours, and finally filtering, washing and drying to obtain the initiator.

5. The resin polyacrylamide gel profile control agent according to claim 4, wherein the auxiliary agent comprises an auxiliary agent I and an auxiliary agent II, the mass ratio of the auxiliary agent I to the auxiliary agent II is 1-3: 1, wherein the auxiliary agent I is divinylbenzene, and the auxiliary agent II is acetone.

The technical field is as follows:

the invention relates to the technical field of oil exploitation, and particularly relates to a resin polyacrylamide gel profile control agent.

Background art:

with the continuous development of tertiary recovery and the gradual extension of the oil well exploitation limit, the increase of water yield is a main problem which prevents the oil from being continuously exploited. The most common method at present is to use a profile control agent to maximize the service life and the production life of the oil well.

The original profile control agent is only simple cement paste, then oil-based cement, lime cream, active thick oil and the like are successively developed, and in the seventy years of the last century, water-soluble polymers, gels and the like are applied to oil fields and achieve certain effects. At present, the plugging agent is mainly applied widely by technologies such as colloidal dispersion gel, expanded particles and flexible particles, but has certain defects, such as long pretreatment time, uncontrollable sol time and poor profile improvement effect.

The invention content is as follows:

the invention aims to overcome the defects of the prior art and provide a resin polyacrylamide gel profile control agent.

The invention relates to a resin polyacrylamide gel profile control agent, which is prepared by mixing the following substances in parts by weight: 5-8 parts of polyacrylamide, 0.2-0.6 part of a dissolution promoter, 0.5-1.0 part of a phenolic crosslinking agent, 0.1-0.3 part of an initiator and 90-98 parts of water.

As a further improvement of the invention, the cosolvent is acetone.

As a further improvement of the invention, the crosslinking agent is a phenol formaldehyde resin.

As a further improvement of the invention, the method for preparing the initiator is characterized in that: dissolving petroleum resin in acetone, and stirring at constant temperature of 120-150 ℃ until the mixture is uniform to obtain a wall material dispersion system, wherein the mass ratio of the petroleum resin to the acetone is 1: 75-90; adding ammonium persulfate and an auxiliary agent into the wall material dispersion system to obtain a core wall system, wherein the mass ratio of the wall material dispersion system to the core material to the auxiliary agent is (50-70: 2): 0.1 to 0.2; and mixing and homogenizing the core wall system and water, keeping the temperature of 120-150 ℃ for 2-4 hours, and finally filtering, washing and drying to obtain the initiator.

As a further improvement of the invention, the auxiliary agent consists of an auxiliary agent I and an auxiliary agent II, the mass ratio of the auxiliary agent I to the auxiliary agent II is 1-3: 1, wherein the auxiliary agent I is divinylbenzene, and the auxiliary agent II is acetone.

According to the resin polyacrylamide gel profile control agent, the dissolution accelerator is added, so that the dissolution speed of each component of a product is accelerated, the configuration time of the product configuration process is greatly reduced, the working efficiency of field work is improved, and the error rate of the field work can be effectively reduced; the injection underground section has good improvement effect; meanwhile, the glue forming time can be controlled by using the temperature, and the product pertinence is strong.

The specific implementation mode is as follows:

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