阅读说明：本技术 具有阴离子聚合物和阳离子聚合物的组合物 (Composition having an anionic polymer and a cationic polymer ) 是由 D·W·常 E·S·约翰逊 K·R·克罗格里昂 R·R·菲格罗亚 R·A·芬利 于 2018-04-25 设计创作，主要内容包括：一种毛发护理组合物,其包含约10％至约25％的一种或多种表面活性剂；约0.01％至10％的一种或多种表面活性剂可溶性去头皮屑剂；约0.1％至10％的一种或多种阴离子聚合物,约0.01％至5％的一种或多种阳离子聚合物；其中所述组合物具有大于1.2倍于对照组合物的沉积效率,其中所述对照组合物包含14％SLE1S、不具有聚合物组分、1％的表面活性剂可溶性去头皮屑剂,pH为约6。(A hair care composition comprising from about 10% to about 25% of one or more surfactants; from about 0.01% to 10% of one or more surfactant soluble anti-dandruff agents; from about 0.1% to 10% of one or more anionic polymers, from about 0.01% to 5% of one or more cationic polymers; wherein the composition has a deposition efficiency greater than 1.2 times that of a control composition comprising 14% SLE1S, no polymeric component, 1% surfactant soluble anti-dandruff agent, and a pH of about 6.)

1. a hair care composition comprising:

a) 10% to 25% of one or more surfactants;

b) From 0.01% to 10% of one or more surfactant soluble anti-dandruff agents;

c) 0.1% to 10% of one or more anionic polymers;

d) 0.01% to 5% of one or more cationic polymers; wherein the composition has a deposition efficiency greater than 1.2 times that of a control composition, wherein the control composition comprises 14% SLE1S, no polymeric component, 1% surfactant soluble anti-dandruff agent, pH 6, preferably wherein the composition has a deposition efficiency greater than or equal to 1.4 times that of a control composition, wherein the control composition comprises 14% SLE1S, 1% surfactant soluble anti-dandruff agent, pH 6.

2. The hair care composition according to any preceding claims, wherein the one or more cationic polymers are selected from cationic guar polymers, cationic non-guar galactomannan polymers, cationic tapioca polymers, cationic copolymers of acrylamide monomers and cationic monomers, synthetic non-crosslinked cationic polymers which may or may not form lyotropic liquid crystals when combined with detersive surfactants, cationic cellulose polymers, and mixtures thereof, preferably wherein the one or more cationic polymers are selected from the group consisting of guar hydroxypropyltrimonium chloride, salts of hydroxyethyl cellulose reacted with trimethylammonium substituted epoxide, cationic copolymers of acrylamide monomers and cationic monomers, synthetic non-crosslinked cationic polymers that may or may not form lyotropic liquid crystals when combined with detersive surfactants.

3. The hair care composition according to any preceding claims, wherein the one or more cationic polymers is from 0.08% to 3%, preferably from 0.1% to 2%, preferably from 0.2% to 1%.

4. The hair care composition according to any preceding claims, comprising from 0.25% to 8%, preferably from 0.5% to 5%, preferably from 1% to 2.5% of one or more anionic polymers selected from anionic polymers having anionic functional groups, anionic polymers being homopolymers of one monomer or copolymers of more than one type of monomer comprising one or more monomers having anionic functional groups and/or other monomers comprising non-anionic functional groups and mixtures thereof, preferably wherein the one or more anionic functional groups are selected from polyacrylates, polyacrylamide polymers being homopolymers based on acrylic acid, methacrylic acid or other related derivatives, alkali swellable and hydrophobically modified alkali swellable acrylic or methacrylate copolymers, Soluble crosslinked acrylic polymers, associative polymers, and mixtures thereof.

5. the hair care composition according to any preceding claims, wherein the composition further comprises one or more thickening polymers capable of increasing the viscosity of the composition to at least 3000cps at 2s "1, wherein a composition without a thickening polymer has a viscosity of less than 3000cps at 2 s" 1 and is incapable of thickening to above 3000cps at 2s "1 with a sodium chloride salt in the range of 0.1% to 3%, preferably wherein the composition without a thickening polymer is incapable of thickening to above 3000cps at 2 s" 1 with a sodium chloride salt in the range of 0.1% to 2%.

6. The hair care composition according to any preceding claims, wherein the thickening polymer is selected from homopolymers based on acrylic acid, methacrylic acid or other related derivatives, alkali swellable and hydrophobically modified alkali swellable acrylic or methacrylate copolymers, soluble cross-linked acrylic polymers, associative polymer thickeners and mixtures thereof, preferably wherein the one or more thickening polymers are selected from polyacrylates, polymethacrylates, polyethylacrylates and polyacrylamides, acrylic/acrylyl nitrogen copolymers, acrylate/steareth-20 itaconate copolymers, acrylate/cetyleth-20 itaconate copolymers, acrylate/aminoacrylate/C10-30 alkyl PEG-20 itaconate copolymers, acrylic acid/acrylyl nitrogen copolymers, acrylic acid/steareth-20 itaconate copolymers, acrylic acid/cetyl polyoxyethylene ether-20 itaconate copolymers, acrylic acid, Acrylate/aminoacrylate copolymer, acrylate/stearylpolyoxyethylene ether-20 methacrylate copolymer, acrylate/behenyl polyether-25 methacrylate copolymer, acrylate/stearylpolyoxyethylene ether-20 methacrylate cross-linked polymer, acrylate/behenyl polyether-25 methacrylate/HEMA cross-linked polymer, acrylate/neodecanoic acid vinyl ester cross-linked polymer, acrylate/vinyl isodecanoate crosspolymer, acrylate/palmitoleyl polyether-25 acrylate copolymer, acrylic acid/acrylamidomethylpropane sulfonic acid copolymer, and acrylate/C10-C30 alkyl acrylate crosspolymer, carbomer, hydrophobically modified polyacrylate; hydrophobically modified polyacrylic acid, hydrophobically modified polyacrylamide; hydrophobically modified polyethers, wherein these materials may have a hydrophobic moiety which may be selected from cetyl, stearyl, oleyl, and combinations thereof, acrylamide/ammonium acrylate copolymer (and) polyisobutylene (and) polysorbate 20; acrylamide/sodium acryloyldimethyl taurate copolymer/isohexadecane/polysorbate 80, ammonium acryloyldimethyl taurate/VP copolymer, sodium acrylate/sodium acryloyldimethyl taurate copolymer, acrylate crosspolymer-4, acrylate crosspolymer-3, acrylate/behenyl polyether-25 methacrylate copolymer, acrylate/acrylic acid C10-C30 alkyl ester crosspolymer, acrylate/stearyl polyoxyethylene ether-20 itaconate copolymer, ammonium polyacrylate/isohexadecane/PEG-40 castor oil; carbomer, sodium carbomer, cross-linked polyvinylpyrrolidone (PVP), polyacrylamide/C13-14 isoparaffin/laureth-7, polyacrylate 13/polyisobutylene/polysorbate 20, polyacrylate crosspolymer-6, polyamide-3, polyquaternium-37 (and) hydrogenated polydecene (and) trideceth-6, acrylamide/sodium acryloyldimethyl taurate/acrylic acid copolymer, sodium acrylate/sodium acryloyldimethyl taurate/dimethylacrylamide, cross-linked polymer (and) isohexadecane (and) polysorbate 60, sodium polyacrylate.

7. The hair care composition according to any preceding claims, wherein the surfactant is an anionic surfactant selected from anionic alkyl and alkyl ether sulfates having a linear or branched alkyl chain and mixtures thereof, preferably wherein the surfactant is an anionic surfactant selected from the group consisting of:

a)R O(CHCHRO) SOM；

b) CH3(CH2) z CHR 2CH 2O (CH2 CHR3O) y SO 3M; and

c) A mixture of these with a further component,

Wherein R1 represents CH3(CH2)10, R2 represents H or a hydrocarbon group comprising 1 to 4 carbon atoms such that the sum of carbon atoms in z and R2 is 8, R3 is H or CH3, y is 0 to 7, when y is not zero (0), the average value of y is 1, and M is a monovalent or divalent positively charged cation, preferably wherein the surfactant is a surfactant or combination of surfactants selected from the group consisting of: sodium lauryl sulphate, sodium laureth-n sulphate where n is between 0.5 and 3.5, where the alkyl chain may be linear or branched sodium C10-15 alkyl sulphate, where n is between 0.5 and 3.5 and the alkyl chain may be linear or branched sodium C10-15 alkanolpolyether-n sulphate, sodium decyl sulphate, sodium decylethoxylate-n sulphate where n is between 0.5 and 3.5, sodium undecylsulphate, sodium undecylethoxylate-n sulphate where n is between 0.5 and 3.5, sodium trideceth sulphate where n is between 0.5 and 3.5, anionic surfactants are selected from the group consisting of:

a)R1 O(CH2CHR3O)y SO3M；

b) CH3(CH2) z CHR 2CH 2O (CH2 CHR3O) y SO 3M; and

c) a mixture of these with a further component,

Wherein R1 represents CH3(CH2)10, R2 represents H or a hydrocarbon group containing 1 to 4 carbon atoms such that the sum of z and the carbon atoms in R2 is 8, R3 is H or CH3, y is 0 to 7, when y is not zero (0), the average value of y is 1, and M is a monovalent or divalent positively charged cation.

8. The hair care composition according to any preceding claims, wherein one or more surfactants is from 10% to 18%, preferably from 10% to 14%, preferably from 10% to 12%.

9. The hair care composition according to any preceding claims, further comprising from 0.25% to 15% of one or more amphoteric, nonionic or zwitterionic co-surfactants.

10. The hair care composition according to any preceding claims, wherein the pH of the composition is from 4 to 9, preferably from 4 to 6, preferably from 4 to 5.5, preferably from 4 to 5.

11. The hair care composition according to any preceding claims, wherein the surfactant soluble anti-dandruff agent is hydroxypyridine, preferably wherein the hydroxypyridone is piroctone olamine.

12. The hair care composition according to any preceding claims, wherein the surfactant soluble anti-dandruff agent is oxazole, preferably wherein the oxazole is climbazole.

13. The hair care composition according to any preceding claims, further comprising from 0.1% to 9%, preferably from 0.25% to 8, of one or more scalp health agents selected from the group consisting of: pyrithione salts, selenium sulfide, particulate sulfur, salicylic acid, menthol, menthyl lactate, and mixtures thereof, preferably wherein the one or more scalp health agents is a polyvalent metal salt of pyrithione, preferably wherein the one or more scalp health agents is zinc pyrithione.

14. The hair care composition according to any preceding claims, wherein the composition further comprises a conditioning agent, preferably wherein the conditioning agent is a silicone.

15. the hair care composition according to any preceding claims, wherein the hair care composition is dispensed in the form of a foam, preferably wherein the hair care composition is dispensed in the form of an aerosol foam, preferably wherein the hair care composition is dispensed in the form of a pumped foam.

Technical Field

The present invention relates to hair care compositions wherein the addition of certain anionic polymers in combination with one or more cationic polymers has been found to provide unexpected increases in coacervate formation as well as deposition benefits.

Background

For many years, anti-dandruff shampoos have been widely used to treat dandruff and to clean hair and scalp, but there remains a need for improved anti-dandruff shampoos. Generally, anti-dandruff shampoos are formulated from a combination of an anti-dandruff agent, a surfactant intended to deposit the anti-dandruff agent on the scalp, and an aqueous system. The anti-dandruff agent may be insoluble particles, for example zinc pyrithione and/or a surfactant soluble material such as galangin or octopirox. Many anti-dandruff shampoos use cationic polymers with anionic surfactants to form a coacervate that aids in the deposition of insoluble particulate agents. Generally, however, the coacervate does not affect the deposition of the soluble agent, as the soluble agent is not associated with the coacervate formed between the cationic polymer and the anionic surfactant. Indeed, it may prove difficult to deposit more than 1-2% of the soluble agent present in an anti-dandruff shampoo on the scalp, while the remaining 98-99% of the soluble agent in the formulation is rinsed away. Because many anti-dandruff agents can be relatively expensive, flushing > 97% of the soluble agent away equates to pouring money into the drain, and thus there remains a need for shampoos that can more effectively deposit soluble anti-dandruff agents. Furthermore, because consumers continue to desire shampoos that deliver superior anti-dandruff efficacy, and less agent deposition results in lower anti-dandruff efficacy, there remains a need for a shampoo that can deposit a higher percentage of the soluble agents present in anti-dandruff shampoos on the scalp.

The association of many classes of surfactants into micelle aggregates is a well-known phenomenon. Micelles are usually drawn as a static structure of spherical aggregates, but in practice the micelles are in dynamic equilibrium with individual surfactant molecules (monomers) that are constantly exchanged between the bulk and the micelle. In addition, the micelles themselves continue to disintegrate and reassemble. Two relaxation processes are involved in micellar solutions. The first is a fast relaxation process called τ 1, which is associated with a fast exchange of monomers between the micelle and the surrounding bulk phase. The second relaxation time τ 2 is due to the micelle formation and dissolution process (i.e., the lifetime of the micelle). Extensive experimental studies by Shah and colleagues on micellization kinetics (Patist, A., Jha, B.K., Oh, S.G., and Shah, D.O., J.surfactants Deterg.2, 317, (1999); James-Smith, M.A., Shekhawat, D.and Shah, D.O., Tenside surf.Det.44, 142(2007)) show a strong correlation of τ 2 with various detergent properties, including oil solubilization in micellar solutions and droplet size of emulsions, as well as surfactant properties such as dynamic surface tension and micellar stability. Their studies also show that τ 2 has a strong inverse correlation with other properties, such as foamability and concentration of sub-micellar aggregates. In particular, they show a maximum τ 2 and thus a maximum micelle stability corresponding to a maximum oil dissolution rate and a maximum amount of oil dissolution. Thus, it is logically suggested that cleaning compositions with longer τ 2, more stable micelles, and faster dissolution rates may be preferred, as such systems may better clean, solubilize greater amounts of oil or surfactant soluble materials more rapidly, and should be more stable. However, it has been shown that compositions with surfactant systems having shorter τ 2 and less stable micelles are preferred because the compositions are capable of depositing surfactant soluble anti-dandruff agents with significantly greater efficiency. Since the preferred compositions have less stable micelles, these compositions do not readily form elongated micelles, which are a key component in the formation of coacervates, because upon dilution, the elongated negatively charged micelles are required to associate with the cationic polymer to form the coacervate. Coacervates are known to provide wet conditioning and wet detangling from shampoos, which is a consumer desired benefit. Indeed, unlike what is observed in typical shampoos, hair care compositions comprising cationic polymers and surfactants that form less stable micelles form little or no coacervate upon dilution.

It has been surprisingly found that the addition of certain anionic polymers in combination with one or more cationic polymers provides unexpected increases in coacervate formation and deposition benefits.

Disclosure of Invention

a hair care composition comprising from about 10% to about 25% of one or more surfactants; from about 0.01% to 10% of one or more surfactant soluble anti-dandruff agents; from about 0.1% to 10% of one or more anionic polymers, from about 0.01% to 5% of one or more cationic polymers; wherein the composition has a deposition efficiency greater than 1.2 times that of a control composition comprising 14% SLE1S, no polymeric component, 1% surfactant soluble anti-dandruff agent, and a pH of about 6.

Detailed description of the preferred embodiments

All percentages and ratios used herein are by weight of the total composition, unless otherwise specified. Unless otherwise indicated, all measurements are understood to be made at ambient conditions, where "ambient conditions" refers to conditions at about 25 ℃, at about one atmosphere of pressure, and at about 50% relative humidity. All numerical ranges are narrower ranges including the endpoints; the upper and lower limits of the ranges described are combinable to form additional ranges not explicitly described.

the compositions of the present invention may comprise, consist essentially of, or consist of the essential components described herein, as well as optional ingredients. As used herein, "consisting essentially of means that the composition or component may include additional ingredients, so long as the additional ingredients do not materially alter the basic and novel characteristics of the claimed compositions or methods.

"applying" or "application" as used with respect to a composition refers to applying or spreading the composition of the present invention onto keratinous tissue, such as hair.

By "dermatologically acceptable" is meant that the composition or component is suitable for use in contact with human skin tissue without undue toxicity, incompatibility, instability, allergic response, and the like.

By "safe and effective amount" is meant an amount of a compound or composition sufficient to significantly induce a positive benefit.

while the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the present invention will be better understood from the following description.

As used herein, the term "fluid" includes liquids and gels.

As used herein, articles including "a" and "an" when used in a claim should be understood to mean one or more of what is claimed or described.

As used herein, "comprising" means that other steps and other ingredients that do not affect the end result can be added. The term encompasses the terms "consisting of … …" and "consisting essentially of … …".

as used herein, "mixture" is intended to include simple combinations of substances as well as any compounds that may result from their combination.

As used herein, "molecular weight" refers to weight average molecular weight unless otherwise specified. Molecular weight was measured using industry standard methods, gel permeation chromatography ("GPC").

In the case of the content ranges given, these are to be understood as the total amount of the stated ingredients in the composition, or in the case of more than one substance falling within the range defined by the ingredients, the total amount of all ingredients in the composition conforms to the stated definition.

For example, if the composition comprises 1% to 5% fatty alcohol, a composition comprising 2% stearyl alcohol and 1% cetyl alcohol and no other fatty alcohols would fall within this range.

The amount of each particular ingredient or mixture thereof described below may constitute up to 100% (or 100%) of the total amount of ingredients in the hair care composition.

As used herein, "personal care compositions" include liquid compositions such as shampoos, shower gels, liquid hand cleansers, hair colorants, facial cleansers, and other surfactant-based liquid compositions.

As used herein, the terms "comprising," "including," and "containing" are intended to be non-limiting and are understood to mean "having," "having," and "encompassing," respectively.

All percentages, parts and ratios are based on the total weight of the composition of the present invention, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level and, therefore, do not include carriers or by-products that may be included in commercially available materials.

unless otherwise indicated, all component or composition levels are in terms of the active portion of the component or composition and are exclusive of impurities, e.g., residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

it should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Soluble dandruff removing agent

The anti-dandruff agent may be one or a mixture selected from: azoles such as climbazole, ketoconazole, itraconazole, econazole and neoconazole; hydroxypyridinones such as piroctone olamine, ciclopirox, rilopirox, and MEA-hydroxyoctoxy pyridone; keratolytic agents, such as salicylic acid and other hydroxy acids; strobilurins such as azoxystrobin and metal chelators such as 1, 10-phenanthroline.

The azole antimicrobial may be an imidazole selected from the group consisting of: benzimidazole, benzothiazole, bifonazole, butoconazole nitrate, climbazole, clotrimazole, kruconazole, ebuconazole, econazole, neoconazole, fenticonazole, fluconazole, isoconazole, ketoconazole, lanoconazole, metronidazole, miconazole, naphthoconazole, omoconazole, oxiconazole nitrate, sertaconazole, sulconazole nitrate, tioconazole, thiazole, and mixtures thereof, or the azole antimicrobial agent is a triazole selected from the group consisting of: terconazole, itraconazole, and mixtures thereof. The azole antimicrobial agent can be ketoconazole. The only antimicrobial agent may be ketoconazole.

the soluble anti-dandruff agent may be present at a level of about 0.01% to 10%, about 0.1% to about 9%, about 0.25% to 8%, and about 0.5% to 6%. The soluble anti-dandruff agent may be surfactant soluble and may thus be a surfactant soluble anti-dandruff agent.

A. Detersive surfactant

The hair care composition may comprise greater than about 10% by weight of a surfactant system which provides cleansing performance to the composition; the composition may also comprise greater than 12% by weight of a surfactant system which provides cleaning performance to the composition. The surfactant system comprises an anionic surfactant and/or a combination of anionic surfactants and/or a combination of an anionic surfactant and a co-surfactant selected from the group consisting of amphoteric, zwitterionic, nonionic and mixtures thereof. Various examples and descriptions of detersive surfactants are shown in U.S. patent 8,440,605; U.S. patent application publication 2009/155383; and U.S. patent application publication 2009/0221463, which are incorporated herein by reference in their entirety.

The hair care composition may comprise from about 10% to about 25%, from about 10% to about 18%, from about 10% to about 14%, from about 10% to about 12%, from about 11% to about 20%, from about 12% to about 20%, and/or from about 12% to about 18% by weight of one or more surfactants.

suitable anionic surfactants for use in the composition are alkyl sulfates and alkyl ether sulfates. Other suitable anionic surfactants are the water-soluble salts of organic sulfuric acid reaction products. Other suitable anionic surfactants are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide. Other similar anionic surfactants are described in U.S. Pat. nos. 2,486,921; 2,486,922, respectively; and 2,396,278, which are incorporated herein by reference in their entirety.

Exemplary anionic surfactants for use in hair care compositions include ammonium lauryl sulfate, ammonium laureth sulfate, ammonium C10-15 alkanolsulfate, ammonium C10-15 alkyl sulfate, ammonium C11-15 alkyl sulfate, ammonium decyl sulfate, ammonium decylpolyoxyethylene sulfate, ammonium undecyl polyoxyethylene ether sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, sodium monolaurate sulfate, sodium lauryl sulfate, sodium laureth sulfate, C10-15 alkanoleth sulfate, sodium laureth sulfate, sodium lauryl sulfate, sodium laureth sulfate, ammonium decylethylene sulfate, ammonium undecyl polyoxyethylene ether sulfate, triethylamine lauryl sulfate, laureth sulfate, triethanolamine lauryl sulfate, monoethanolamine lauryl sulfate, Sodium C10-15 alkyl sulfate, sodium C11-15 alkyl sulfate, sodium decyl polyoxyethylene ether sulfate, sodium undecyl polyoxyethylene ether sulfate, potassium lauryl polyoxyethylene ether sulfate, potassium C10-15 alkanol polyether sulfate, potassium C10-15 alkyl sulfate, potassium C11-15 alkyl sulfate, potassium decyl polyoxyethylene ether sulfate, potassium undecyl polyoxyethylene ether sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosinate, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, triethanolamine cocoyl sulfate, monoethanolamine cocoyl sulfate, triethanolamine cocoyl sulfate, monoethanolamine cocoyl sulfate, and sodium lauryl sulfate, Monoethanolamine lauryl sulfate, sodium tridecylbenzene sulfonate, sodium dodecylbenzene sulfonate, sodium cocoyl isethionate, and combinations thereof. The anionic surfactant may be sodium lauryl sulfate or sodium laureth sulfate.

The composition of the invention may also comprise an anionic surfactant selected from:

a)R O(CHCHRO) SOM；

b) CH3(CH2) z CHR 2CH 2O (CH2 CHR3O) y SO 3M; and

c) A mixture of these with a further component,

Wherein R1 represents CH3(CH2)10, R2 represents H or a hydrocarbon group containing 1 to 4 carbon atoms such that the sum of z and the carbon atoms in R2 is 8, R3 is H or CH3, y is 0 to 7, when y is not zero (0), the average value of y is about 1, and M is a monovalent or divalent positively charged cation.

Suitable anionic alkyl sulfate and alkyl ether sulfate surfactants include, but are not limited to, those having branched alkyl chains synthesized from C8 to C18 branched alcohols that may be selected from: guerbet alcohols, aldol condensation derived alcohols, oxo alcohols, F-T oxo alcohols, and mixtures thereof. Non-limiting examples of 2-alkyl branched alcohols include: oxo alcohols such as 2-methyl-1-undecanol, 2-ethyl-1-decanol, 2-propyl-1-nonanol, 2-butyl-1-octanol, 2-methyl-1-dodecanol, 2-ethyl-1-undecanol, 2-propyl-1-decanol, 2-butyl-1-nonanol, 2-pentyl-1-octanol, 2-pentyl-1-heptanol, and those sold under the following trade names: (Sasol), and (Shell); and Guerbet and aldol condensation derived alcohols such as 2-ethyl-1-hexanol, 2-propyl-1-butanol, 2-butyl-1-octanol, 2-butyl-1-decanol, 2-pentyl-1-nonanol, 2-hexyl-1-octanol, 2-hexyl-1-decanol and those sold under the trade name (Sasol) or as alcohol ethoxylates and alkoxylates under the trade names lutensol (basf) and lutensol (basf).

anionic alkyl and alkyl ether sulfates may also include those synthesized from C8 to C18 branched alcohols derived from butylene or propylene, which are sold under the tradenames exxaltm (exxon) and (Sasol). This includes anionic surfactants of the subtype sodium trideceth-n sulfate (STnS), where n is between about 0.5 and about 3.5. Exemplary surfactants of this subclass are sodium trideceth-2 sulfate and sodium trideceth-3 sulfate. The compositions of the present invention may also comprise sodium tridecyl sulfate.

The compositions of the present invention may also include anionic alkyl and alkyl ether sulfosuccinates and/or dialkyl and dialkyl ether sulfosuccinates and mixtures thereof, which may be C6-15 straight or branched chain dialkyl or dialkyl ether sulfosuccinates. The alkyl moieties may be symmetrical (i.e., the same alkyl moiety) or asymmetrical (i.e., different alkyl moieties). Non-limiting examples include: disodium lauryl sulfosuccinate, disodium laureth sulfosuccinate, sodium ditridecyl sulfosuccinate, sodium dioctyl sulfosuccinate, sodium dihexyl sulfosuccinate, sodium dicyclohexyl sulfosuccinate, sodium diamyl sulfosuccinate, sodium diisobutyl sulfosuccinate, linear bis (tridecyl) sulfosuccinate, and mixtures thereof.

The hair care composition may comprise a co-surfactant. The co-surfactant may be selected from the group consisting of amphoteric surfactants, zwitterionic surfactants, nonionic surfactants, and mixtures thereof. The co-surfactant may include, but is not limited to, lauramidopropyl betaine, cocamidopropyl betaine, lauryl hydroxysultaine, sodium lauroamphoacetate, disodium cocoamphodiacetate, cocamide monoethanolamide, and mixtures thereof.

The hair care composition may further comprise from about 0.25% to about 15%, from about 1% to about 14%, from about 2% to about 13% by weight of one or more amphoteric, zwitterionic, nonionic co-surfactants, or mixtures thereof.

suitable amphoteric or zwitterionic surfactants for use in the hair care compositions herein include those known for use in shampoos or other hair care cleansing. Non-limiting examples of suitable zwitterionic or amphoteric surfactants are described in U.S. Pat. Nos. 5,104,646 and 5,106,609, which are incorporated herein by reference in their entirety.

Amphoteric co-surfactants suitable for use in the composition include those surfactants described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group, such as carboxy, sulfonate, sulfate, phosphate, or phosphonate. Suitable amphoteric surfactants include, but are not limited to, those selected from the group consisting of: sodium cocoyl aminopropionate, sodium cocoyl amphoacetate, sodium cocoyl amphodiacetate, sodium cocoyl amphohydroxypropyl sulfonate, sodium cocoyl amphopropionate, sodium corn oleoyl amphopropionate, sodium lauryl aminopropionate, sodium lauroyl amphoacetate, sodium lauroyl amphodiacetate, sodium lauroyl amphohydroxypropyl sulfonate, sodium lauroyl amphopropionate, sodium corn oleoyl amphopropionate, sodium lauryl iminodipropionate, ammonium cocoyl aminopropionate, ammonium cocoyl amphoacetate, ammonium cocoyl amphodiacetate, ammonium cocoyl amphohydroxypropyl sulfonate, ammonium cocoyl amphopropionate, ammonium corn oleoyl amphopropionate, ammonium lauryl aminopropionate, ammonium lauroyl amphoacetate, ammonium lauroyl amphodiacetate, ammonium lauroyl amphohydroxypropyl sulfonate, ammonium cocoyl hydroxypropylsulfonate, ammonium cocoyl amphopropionate, ammonium cocoyl amphoacetate, ammonium lauroyl amphodiacetate, ammonium lauroyl amphosulfate, ammonium cocoyl amphopropionate, ammonium cocoyl amphoacetate, ammonium cocoyl amphodiacetate, ammonium lauroyl amphopropionate, ammonium cocoyl hydroxypropylsulfonate, sodium cocoyl amphopropionate, sodium cocoyl amphoacetate, sodium cocoyl ampho, Ammonium lauroyl amphopropionate, ammonium corn oleoyl amphopropionate, ammonium laurimidodipropionate, triethanolamine cocoyl aminopropionate, triethanolamine cocoyl aminodipropionate, triethanolamine cocoyl amphoacetate, triethanolamine cocoyl amphohydroxypropyl sulfonate, triethanolamine cocoyl amphopropionate, triethanolamine corn oleoyl amphopropionate, triethanolamine lauryl aminopropionate, triethanolamine lauroyl amphoacetate, triethanolamine lauroyl amphohydroxypropyl sulfonate, triethanolamine lauroyl amphopropionate, triethanolamine corn oleoyl amphopropionate, triethanolamine lauryl iminodipropionate, disodium decanoyl amphodiacetate, disodium decanoyl amphodipropionate, disodium octanoyl amphodiacetate, disodium octanoyl amphodipropionate, disodium cocoyl amphocarboxylate, Disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium dicarboxyethyl-cocoamphopropane diamine, disodium laureth-5-carboxy amphodiacetate, disodium lauriminodipropionate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium oleylamphodipropionate, disodium PPG-2-isodecyl polyoxyethylene ether-7-carboxy amphodiacetate, lauryl aminopropionic acid, lauroamphodipropionic acid, lauryl aminopropylglycine, lauryl diethylenediaminoglycine, and mixtures thereof.

The composition can comprise a zwitterionic co-surfactant, wherein the zwitterionic surfactant is a derivative of an aliphatic quaternary ammonium, phosphonium, and sulfonium compound, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group, such as carboxy, sulfonate, sulfate, phosphate, or phosphonate. The zwitterionic surfactant may be selected from: cocamidoethyl betaine, cocamidopropyl amine oxide, cocamidopropyl betaine, cocamidopropyl dimethyl amidohydroxypropyl hydrolyzed collagen, cocamidopropyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, cocamidopropyl hydroxysultaine, cocamidobetaine amidoamphopropionate, cocoyl betaine, cocoyl hydroxysultaine, cocoyl/oleylamidopropyl betaine, cocoyl sultaine, lauramidopropyl betaine, lauryl hydroxysultaine, lauryl sultaine, and mixtures thereof.

nonionic surfactants suitable for use in the present invention include those described in "Detergents and Emulsifiers" north american edition of McCutcheion (1986, alternate Publishing Corp.) and "Functional Materials" north american edition of mccutcheon (1992). Nonionic surfactants suitable for use in the personal care compositions of the present invention include, but are not limited to, polyoxyethylated alkylphenols, polyoxyethylated alcohols, polyoxyethylated polyoxypropylene glycols, glyceryl alkanoates, polyglycerol alkanoates, propylene glycol alkanoates, sorbitol alkanoates, polyoxyethylene glycol alkanoates, polyoxyethylated alkanoic acids, alkanolamides, N-alkylpyrrolidones, alkyl glycosides, alkyl polyglucosides, alkylamine oxides, and polyoxyethylated silicones.

The co-surfactant may be a non-ionic surfactant selected from the group consisting of: cocamide, Cocamide methyl MEA, Cocamide DEA, Cocamide MEA, Cocamide MIPA, lauramide DEA, lauramide MEA, lauramide MIPA, myristamide DEA, myristamide MEA, PEG-20 Cocamide MEA, PEG-2 Cocamide, PEG-3 Cocamide, PEG-4 Cocamide, PEG-5 Cocamide, PEG-6 Cocamide, PEG-7 Cocamide, PEG-3 lauramide, PEG-5 lauramide, PEG-3 oleamide, PPG-2 Cocamide, PPG-2 hydroxyethyl isostearamide, and mixtures thereof.

Representative polyoxyethylene alcohols include those having an alkyl chain in the range of C9-C16 and from about 1 to about 110 alkoxy groups, including but not limited to, polyoxyethylene lauryl ether-3, polyoxyethylene lauryl ether-23, polyoxyethylene cetyl ether-10, polyoxyethylene stearyl ether-100, polyoxyethylene behenyl ether-10, and those commercially available under the trade names 91, 23, 25, 45, 135, 67, PC100, PC 200, PC 600 from Shell Chemicals (Houston, Texas), and mixtures thereof.

Also commercially available are polyoxyethylene fatty esters commercially available under the trade name Uniqema (Wilmington, Delaware), including but not limited to 30, 35, 52, 56, 58, 72, 76, 78, 93, 97, 98, 721, and mixtures thereof.

Suitable alkyl glycosides and alkyl polyglucosides can be represented by the formula (S) n-O-R, wherein S is a sugar moiety such as glucose, fructose, mannose, galactose, and the like; n is an integer from about 1 to about 1000, and R is a C8-C30 alkyl group. Examples of long chain alcohols from which the alkyl group may be derived include decyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, and the like. Examples of such surfactants include alkyl polyglucosides, wherein S is a glucose moiety, R is a C8-20 alkyl group, and n is an integer from about 1 to about 9. Commercially available examples of these surfactants include decyl polyglucoside and lauryl polyglucoside available from Cognis (Ambler, Pa) under the trade names 325CS, 600CS and 625 CS. Also useful herein are sucrose ester surfactants such as sucrose cocoate, and sucrose laurate, as well as alkyl polyglucosides available from The Dow Chemical Company (Houston, Tx) under The tradenames Triton BG-10 and Triton CG-110.

Other nonionic surfactants suitable for use herein are glyceryl esters and polyglyceryl esters, including, but not limited to, glyceryl monoesters of C12-22 saturated, unsaturated and branched fatty acids such as glyceryl oleate, glyceryl monostearate, glyceryl monopalmitate, glyceryl monobehenate, and mixtures thereof, and polyglyceryl esters of C12-22 saturated, unsaturated and branched fatty acids such as polyglyceryl-4 isostearate, polyglyceryl-3 oleate, polyglyceryl-2-sesquioleate, glyceryl diisostearate, diglyceryl monooleate, tetraglyceryl monooleate, and mixtures thereof.

Also useful as nonionic surfactants herein are sorbitan esters. Sorbitan esters of C12-22 saturated, unsaturated, and branched fatty acids may be used herein. These sorbitan esters typically comprise mixtures of mono-, di-, tri-esters, and the like. Representative examples of suitable sorbitan esters include sorbitan monolaurate (20), sorbitan monopalmitate (40), sorbitan monostearate (60), sorbitan tristearate (65), sorbitan monooleate (80), sorbitan trioleate (85), and sorbitan isostearate.

Also suitable for use herein are alkoxylated derivatives of sorbitan esters, including but not limited to polyoxyethylene (20) sorbitan monolaurate (20), polyoxyethylene (20) sorbitan monopalmitate (40), polyoxyethylene (20) sorbitan monostearate (60), polyoxyethylene (20) sorbitan monooleate (80), polyoxyethylene (4) sorbitan monolaurate (21), polyoxyethylene (4) sorbitan monostearate (61), polyoxyethylene (5) sorbitan monooleate (81), and mixtures thereof, all available from Uniqema.

also suitable for use herein are alkylphenol ethoxylates including, but not limited to, nonylphenol ethoxylates (tergitol NP-4, NP-6, NP-7, NP-8, NP-9, NP-10, NP-11, NP-12, NP-13, NP-15, NP-30, NP-40, NP-50, NP-55, NP-70, available from The Dow Chemical Company (Houston, Tx)) and octylphenol ethoxylates (Triton X-15, X-35, X-45, X-114, X-100, X-102, X-165, X-305, X-405, X-705 available from The Dow Chemical Company (Houston, Tx)).

Also suitable for use herein are tertiary alkylamine oxides, including lauryl amine oxide and coco amine oxide.

Non-limiting examples of other anionic, zwitterionic, amphoteric and nonionic additional surfactants suitable for use in hair care compositions are described in McCutcheon's Emulsifiers and Detergents (1989, by m.c. publishing Co.) publications and U.S. Pat. nos. 3,929,678, 2,658,072; 2,438, 091; 2,528,378, which are incorporated herein by reference in their entirety.

Suitable surfactant combinations comprise from about 0.5% to about 30%, alternatively from about 1% to about 25%, alternatively from about 2% to about 20%, by weight of the average weight of the alkyl branches. The surfactant combination may have a cumulative average weight% of C8 to C12 alkyl chain lengths of about 7.5% to about 25%, alternatively about 10% to about 22.5%, alternatively about 10% to about 20%. The surfactant combination may have an average C8-C12/C13-C18 alkyl chain ratio of from about 3 to about 200, alternatively from about 25 to about 175.5, alternatively from about 50 to about 150, alternatively from about 75 to about 125.

B. Cationic polymers

The hair care composition further comprises a cationic polymer. These cationic polymers may include at least one of the following: (a) a cationic guar polymer, (b) a cationic non-guar galactomannan polymer, (c) a cationic tapioca polymer, (d) a cationic copolymer of an acrylamide monomer and a cationic monomer, and/or (e) a synthetic non-crosslinked cationic polymer which may or may not form lyotropic liquid crystals upon combination with a detersive surfactant, (f) a cationic cellulose polymer. Additionally, the cationic polymer can be a mixture of cationic polymers.

The hair care composition may comprise a cationic guar polymer which is a cationically substituted galactomannan (guar) gum derivative. The guar used to prepare these guar derivatives is typically obtained as a naturally occurring material from the seed of the guar plant. The guar molecule itself is a linear mannan branched at regular intervals with single galactose units on alternating mannose units. The mannose units are linked to each other via a β (1-4) glycosidic linkage. Galactose branching occurs via the α (1-6) linkage. Cationic derivatives of guar are obtained by reaction between the hydroxyl groups of polygalactomannan and reactive quaternary ammonium compounds. The degree of substitution of the cationic groups onto the guar structure should be sufficient to provide the desired cationic charge density as described above.

the cationic polymer can include, but is not limited to, cationic guar polymers having a weight average molecular weight of less than 2,200,000g/mol, or from about 150,000g/mol to about 2,200,000g/mol, or from about 200,000g/mol to about 2,200,000g/mol, or from about 300,000g/mol to about 1,200,000g/mol, or from about 750,000,000g/mol to about 1,000,000 g/mol. The cationic guar polymer may have from about 0.2meq/g to about 2.2meq/g, or from about 0.3meq/g to about 2.0meq/g, or from about 0.4meq/g to about 1.8 meq/g; or a charge density of about 0.5meq/g to about 1.8 meq/g.

The cationic guar polymer may have a weight average molecular weight of less than about 1,500,000g/mol and a charge density of about 0.1meq/g to about 2.5 meq/g. The cationic guar polymer may have a weight average molecular weight of less than 900,000g/mol, or from about 150,000g/mol to about 800,000g/mol, or from about 200,000g/mol to about 700,000g/mol, or from about 300,000g/mol to about 700,000g/mol, or from about 400,000g/mol to about 600,000g/mol, from about 150,000g/mol to about 800,000g/mol, or from about 200,000g/mol to about 700,000g/mol, or from about 300,000g/mol to about 700,000g/mol, or from about 400,000g/mol to about 600,000 g/mol. The cationic guar polymer may have from about 0.2meq/g to about 2.2meq/g, or from about 0.3meq/g to about 2.0meq/g, or from about 0.4meq/g to about 1.8 meq/g; or a charge density of about 0.5meq/g to about 1.5 meq/g.

The cationic guar polymer may be formed from a quaternary ammonium compound. The quaternary ammonium compound used to form the cationic guar polymer may correspond to formula 1:

Wherein R3, R4 and R5 are methyl or ethyl groups; r6 is an epoxyalkyl group having the general formula 2:

or R6 is a halohydrin group having general formula 3:

Wherein R7 is C1 to C3 alkylene; x is chlorine or bromine, and Z is an anion, such as Cl-, Br-, I-or HSO 4-.

The cationic guar polymer may correspond to formula 4:

Wherein R8 is guar gum; and wherein R4, R5, R6 and R7 are as defined above; and wherein Z is halogen. The cationic guar polymer may conform to formula 5:

Suitable cationic guar polymers include cationic guar derivatives such as guar hydroxypropyltrimonium chloride. The cationic guar polymer may be guar hydroxypropyltrimonium chloride. Specific examples of guar hydroxypropyltrimonium chloride include the series commercially available from Solvay, such as C-500, commercially available from Solvay. C-500 has a charge density of 0.8meq/g and a molecular weight of 500,000 g/mol. Other suitable guar hydroxypropyltrimonium chlorides are: guar hydroxypropyltrimonium chloride having a charge density of about 1.3meq/g and a molecular weight of about 500,000g/mol and available from Solvay under the trade name Optima. Other suitable guar hydroxypropyltrimonium chlorides are: guar hydroxypropyltrimonium chloride having a charge density of about 0.7meq/g and a molecular weight of about 1,500,000g/mol and available from Solvay under the trade name Excel. Other suitable guar hydroxypropyltrimonium chlorides are: guar hydroxypropyltrimonium chloride having a charge density of about 1.1meq/g and a molecular weight of about 500,000g/mol and available from ASI, guar hydroxypropyltrimonium chloride having a charge density of about 1.5meq/g and a molecular weight of about 500,000g/mol and available from ASI.

Other suitable guar hydroxypropyltrimonium chlorides are: Hi-Care 1000, having a charge density of about 0.7meq/g and a molecular weight of about 600,000g/mol, and is available from Solvay; N-Hance 3269 and N-Hance 3270 having a charge density of about 0.7meq/g and a molecular weight of about 425,000g/mol, and are available from ASI; N-Hance 3196, which has a charge density of about 0.8meq/g and a molecular weight of about 1,100,000g/mol, and is available from ASI. AquaCat CG518 has a charge density of about 0.9meq/g, and a molecular weight of about 50,000g/mol, and is available from ASI. BF-13, which is a borate (boron) -free guar having a charge density of about 1.1meq/g and a molecular weight of about 800,000, and BF-17, which is a borate (boron) -free guar having a charge density of about 1.75 meq/g and an m.wt. of about 800,000, both from ASI.

The hair care composition of the present invention may comprise a galactomannan polymer derivative having a mannose to galactose ratio, on a monomer to monomer basis, of greater than 2:1, the galactomannan polymer derivative being selected from the group consisting of: cationic galactomannan polymer derivatives and amphoteric galactomannan polymer derivatives having a net positive charge. As used herein, the term "cationic galactomannan" refers to a galactomannan polymer to which cationic groups are added. The term "amphoteric galactomannan" refers to a galactomannan polymer to which cationic and anionic groups are added such that the polymer has a net positive charge.

The galactomannan polymer is present in the endosperm of leguminous seeds. Galactomannan polymers are composed of a combination of mannose monomers and galactose monomers. Galactomannan molecules are linear mannans branched at regular intervals with single galactose units on specific mannose units. The mannose units are linked to each other via a β (1-4) glycosidic linkage. Galactose branching occurs via the α (1-6) linkage. The ratio of mannose monomers to galactose monomers varies according to the species of the plant, and is also affected by the climate. The non-guar galactomannan polymer derivatives of the present invention have a mannose to galactose ratio of greater than 2:1, on a monomer to monomer basis. Suitable mannose to galactose ratios may be greater than about 3:1, and mannose to galactose ratios may be greater than about 4: 1. Analysis of mannose to galactose ratios is well known in the art and is generally based on the measurement of galactose content.

Gums for the preparation of non-guar galactomannan polymer derivatives are generally available in the form of naturally occurring substances, such as seeds or legume fruits from plants. Examples of various non-guar galactomannan polymers include, but are not limited to, tara gum (3 parts mannose per 1 part galactose), carob or carob gum (4 parts mannose per 1 part galactose), and cassia gum (5 parts mannose per 1 part galactose).

The non-guar galactomannan polymer derivative may have an m.wt. of from about 1,000 to about 10,000,000, and/or from about 5,000 to about 3,000,000.

The hair care composition of the present invention may further comprise a galactomannan polymer derivative having a cationic charge density of from about 0.5meq/g to about 7 meq/g. The galactomannan polymer derivative may have a cationic charge density of about 1meq/g to about 5 meq/g. The degree of substitution of the cationic groups on the galactomannan structure should be sufficient to provide the desired cationic charge density.

The galactomannan polymer derivative may be a cationic derivative of a non-guar galactomannan polymer obtained from the reaction between hydroxyl groups of the polygalactomannan polymer and a reactive quaternary ammonium compound. Suitable quaternary ammonium compounds for forming the cationic galactomannan polymer derivative include those conforming to the general formulae 1 to 5 as defined above.

The cationic non-guar galactomannan polymer derivatives formed from the above agents are represented by the general formula 6:

wherein R is a gum. The cationic galactomannan derivative may be a gum hydroxypropyltrimethylammonium chloride, which may be more specifically represented by formula 7:

alternatively, the galactomannan polymer derivative may be an amphoteric galactomannan polymer derivative having a net positive charge, which is obtained when the cationic galactomannan polymer derivative further comprises anionic groups.

The cationic non-guar galactomannan may have a mannose to galactose ratio of greater than about 4:1, a molecular weight of from about 1,000g/mol to about 10,000,000g/mol, and/or from about 50,000g/mol to about 1,000,000g/mol, and/or from about 100,000g/mol to about 900,000g/mol, and/or from about 150,000g/mol to about 400,000g/mol, and a cationic charge density of from about 1meq/g to about 5meq/g, and/or from 2meq/g to about 4meq/g, and may be derived from cinnamon plants.

the hair care composition may comprise a water-soluble cationically modified starch polymer. As used herein, the term "cationically modified starch" refers to a starch to which cationic groups have been added before the starch is degraded to have a smaller molecular weight, or to which cationic groups have been added after the starch has been modified to obtain a desired molecular weight. The term "cationically modified starch" is also defined to include amphiphilically modified starches. The term "amphiphilically modified starch" refers to a starch hydrolysate to which cationic and anionic groups have been added.

The cationically modified starch polymers disclosed herein have a bound nitrogen percentage of from about 0.5% to about 4%.

The cationically modified starch polymer used in the hair care composition may have a molecular weight of from about 850,000g/mol to about 1,500,000g/mol and/or from about 900,000g/mol to about 1,500,000 g/mol.

The hair care composition may comprise a cationically modified starch polymer having a charge density of from about 0.2meq/g to about 5meq/g, and/or from about 0.2meq/g to about 2 meq/g. Chemical modifications to achieve such charge densities include, but are not limited to, the addition of amino and/or ammonium groups to the starch molecule. Non-limiting examples of these ammonium groups may include substituents such as hydroxypropyl trimethyl ammonium chloride, trimethyl hydroxypropyl ammonium chloride, dimethyl stearyl hydroxypropyl ammonium chloride, and dimethyl dodecyl hydroxypropyl ammonium chloride. See Solarek, d.b., Cationic Starches in Modified starteches: properties and Uses (Wurzburg, O.B. ed., CRC Press, Inc., Boca Raton, Fla.1986, pp. 113-125). The cationic groups may be added to the starch before the starch is degraded to have a smaller molecular weight, or they may be added thereto after such modification.

The cationically modified starch polymers typically have a degree of substitution of cationic groups of from about 0.2 to about 2.5. As used herein, the "degree of substitution" of a cationically modified starch polymer is an average measure of the number of hydroxyl groups per anhydroglucose unit derived from the substituent. Since each anhydroglucose unit has three hydroxyl groups that can be substituted, the maximum possible degree of substitution is 3. The degree of substitution is expressed as moles of substituent per mole of anhydroglucose unit on a molar average basis. The degree of substitution can be determined using proton nuclear magnetic resonance spectroscopy (". sup.1h NMR") methods well known in the art. Suitable. sup.1H NMR techniques include those described in "bservation on NMR Spectra of Starches in Dimethyl Sulfoxide, Iodine-Complexing, and Solvating in Water-Dimethyl Sulfoxide", Qin-Ji Pen and Arthur S.Perlin, Carbohydrate Research, 160(1987), 57-72; and "An apparatus to the Structural Analysis of Oligosaccharides by NMR Spectroscopy", J.Howard Bradbury and J.Grant Collins, Carbohydrate Research, 71, (1979), 15-25.

The source of starch prior to chemical modification may be selected from a variety of sources such as tubers, legumes, cereals and foodstuffs. Non-limiting examples of such source starches may include corn starch, wheat starch, rice starch, waxy corn starch, oat starch, tapioca starch, waxy barley starch, waxy rice starch, glutinous rice starch, waxy corn starch, potato starch, tapioca starch, oat starch, sago starch, glutinous rice, or mixtures thereof.

The cationically modified starch polymer can be selected from the group consisting of degraded cationic corn starch, cationic tapioca, cationic potato starch, and mixtures thereof. Alternatively, the cationically modified starch polymer is cationic corn starch and cationic tapioca.

The starch may include one or more additional modifications before degrading to have a smaller molecular weight or after modifying to have a smaller molecular weight. For example, these modifications may include cross-linking, stabilization reactions, phosphorylation, and hydrolysis. The stabilization reactions may include alkylation and esterification.

the cationically modified starch polymer can be incorporated into the composition in the form of hydrolyzed starch (e.g., acid, enzymatic, or alkaline degradation), oxidized starch (e.g., peroxide, peracid, hypochlorite, alkali, or any other oxidizing agent), physically/mechanically degraded starch (e.g., via thermal mechanical energy input of the treatment device), or a combination thereof.

The best form of starch is one that readily dissolves in water and forms a substantially clear (about 80% transmission at 600 nm) solution in water. The transparency of the composition was determined by ultraviolet/visible (UV/VIS) spectrophotometry, which measures the absorption or transmission of UV/VIS light by a sample using a Gretag Macbeth Colorimeter Color i 5 according to the relevant instructions. It has been shown that a wavelength of light of 600nm is sufficient to characterize the transparency of a cosmetic composition.

suitable cationically modified starches for use in hair care compositions are available from known starch suppliers. Also suitable for use in the hair care composition are nonionic modified starches which may be further derivatized to cationic modified starches as is known in the art. Other suitable modified starch materials may be quaternized as is known in the art to produce cationic modified starch polymers suitable for use in hair care compositions.

and (3) starch degradation process: starch slurry can be made by mixing granular starch in water. The temperature was raised to about 35 ℃. An aqueous solution of potassium permanganate was then added at a concentration of about 50ppm, based on starch. The pH was raised to about 11.5 with sodium hydroxide and the slurry was stirred well to prevent the starch from settling. A solution of about 30% hydrogen peroxide diluted in water was then added to bring the peroxide level to about 1% based on starch. The pH was then restored to about 11.5 by the addition of additional sodium hydroxide. The reaction is completed over a period of about 1 to about 20 hours. The mixture was then neutralized with dilute hydrochloric acid. Degraded starch is recovered by filtration followed by washing and drying.

The hair care composition may comprise a cationic copolymer of an acrylamide monomer and a cationic monomer, wherein the copolymer has a charge density of from about 1.0meq/g to about 3.0 meq/g. The cationic copolymer can be a synthetic cationic copolymer of acrylamide monomers and cationic monomers.

The cationic copolymer may comprise:

(i) An acrylamide monomer having the formula AM:

Wherein R9 is H or C1-4 alkyl; and R10 and R11 are independently selected from H, C1-4 alkyl, CH2OCH3, CH2OCH2CH (CH3)2, and phenyl, or taken together are C3-6 cycloalkyl; and

(ii) Cationic monomers conforming to the formula CM:

Wherein k is 1, each of v, v', and v "is independently an integer from 1 to 6, w is zero or an integer from 1 to 10, and X" is an anion.

The cationic monomer may conform to formula CM, and wherein k ═ 1, v ═ 3, and w ═ 0, z ═ 1, and X — is Cl —, to form the following structure:

the above structure may be referred to as a diquaternary ammonium salt. Alternatively, the cationic monomer may conform to formula CM, and wherein v and v "are each 3, v' ═ 1, w ═ 1, y ═ 1, and X — is Cl-, such as:

The above structure may be referred to as a tri-quaternary ammonium salt.

Suitable acrylamide monomers include, but are not limited to, acrylamide or methacrylamide.

The cationic copolymer (b) may be AM: TRIQUAT, which is a copolymer of acrylamide and N- [2- [ [ [ dimethyl [3- [ (2-methyl-1-oxo-2-propenyl) amino ] propyl ] ammonium ] acetyl ] amino ] ethyl ] 2-hydroxy-N, N, N ', N ', N ' -pentamethyl 1, 3-propanediammonium trichloride. TRIQUAT is also known as polyquaternium 76(PQ 76). TRIQUAT may have a charge density of 1.6meq/g and a molecular weight of 1,100,000 g/mol.

The cationic copolymer can be an acrylamide monomer and a cationic monomer, wherein the cationic monomer is selected from the group consisting of: dimethylaminoethyl (meth) acrylate, dimethylaminopropyl (meth) acrylate, di-tert-butylaminoethyl (meth) acrylate, dimethylaminomethyl (meth) acrylamide, dimethylaminopropyl (meth) acrylamide; ethyleneimine, vinylamine, 2-vinylpyridine, 4-vinylpyridine; trimethyl ammonium chloride ethyl (meth) acrylate, trimethyl ammonium methyl sulfate ethyl (meth) acrylate, dimethyl benzyl ammonium chloride ethyl (meth) acrylate, 4-benzoylbenzyl dimethyl ammonium chloride ethyl acrylate, trimethyl ammonium chloride ethyl (meth) acrylamide, trimethyl ammonium chloride propyl (meth) acrylamide, vinyl benzyl trimethyl ammonium chloride, diallyl dimethyl ammonium chloride, and mixtures thereof.

The cationic copolymer may comprise a cationic monomer selected from the group consisting of: the cationic monomer comprises trimethyl ammonium chloride ethyl (meth) acrylate, trimethyl ammonium methyl sulfate ethyl (meth) acrylate, dimethyl benzyl ammonium chloride ethyl (meth) acrylate, 4-benzoyl benzyl dimethyl ammonium chloride ethyl acrylate, trimethyl ammonium chloride ethyl (meth) acrylamide, trimethyl ammonium chloride propyl (meth) acrylamide, vinyl benzyl trimethyl ammonium chloride, and mixtures thereof.

the cationic copolymer may be water soluble. The cationic copolymer is formed from: (1) a copolymer of (meth) acrylamide and a cationic (meth) acrylamide-based monomer and/or a hydrolysis-stable cationic monomer, (2) a terpolymer of (meth) acrylamide, a cationic (meth) acrylate-based monomer, and a (meth) acrylamide-based monomer, and/or a hydrolysis-stable cationic monomer. The cationic (meth) acrylate-based monomer may be a cationized ester of (meth) acrylic acid containing a quaternized N atom. The cationized ester of (meth) acrylic acid containing a quaternized N atom can be a quaternized dialkylaminoalkyl (meth) acrylate having C1 to C3 in the alkyl and alkylene groups. Suitable cationised esters of (meth) acrylic acid containing a quaternised N atom may be selected from: ammonium salts of dimethylaminomethyl (meth) acrylate, dimethylaminoethyl (meth) acrylate, dimethylaminopropyl (meth) acrylate, diethylaminomethyl (meth) acrylate, diethylaminoethyl (meth) acrylate quaternized with methyl chloride; and ammonium salts of diethylaminopropyl (meth) acrylate. The cationic ester of (meth) acrylic acid containing a quaternized N atom can be dimethylaminoethyl acrylate (ADAME-Quat) quaternized with an alkyl halide, or with methyl chloride, or benzyl chloride, or dimethyl sulfate. When based on (meth) acrylamide, the cationic monomer may be a quaternized dialkylaminoalkyl (meth) acrylamide having C1 to C3 in the alkyl and alkylene groups, or a dimethylaminopropyl acrylamide quaternized with an alkyl halide, or methyl chloride, or benzyl chloride, or dimethyl sulfate.

Suitable cationic (meth) acrylamide-based monomers include quaternized dialkylaminoalkyl (meth) acrylamides having C1 to C3 in the alkyl and alkylene groups. The (meth) acrylamide-based cationic monomer may be dimethylaminopropyl acrylamide, which is quaternized with an alkyl halide, especially methyl chloride, or benzyl chloride or dimethyl sulfate.

The cationic monomer can be a hydrolytically stable cationic monomer. The hydrolytically stable cationic monomer may be all monomers that can be considered stable by OECD hydrolysis testing, in addition to the dialkylaminoalkyl (meth) acrylamide. The cationic monomer can be hydrolytically stable, and the hydrolytically stable cationic monomer can be selected from the group consisting of: diallyl dimethyl ammonium chloride and a water-soluble cationic styrene derivative.

the cationic copolymer can be a terpolymer of acrylamide, 2-dimethylammonium ethyl (meth) acrylate quaternized with methyl chloride (ADAME-Q), and 3-dimethylammonium propyl (meth) acrylamide quaternized with methyl chloride (DIMAPA-Q). The cationic copolymer can be formed from acrylamide and acrylamidopropyltrimethylammonium chloride, wherein the acrylamidopropyltrimethylammonium chloride has a charge density of from about 1.0meq/g to about 3.0 meq/g.

The cationic copolymer may have a charge density of from about 1.1meq/g to about 2.5meq/g, or from about 1.1meq/g to about 2.3meq/g, or from about 1.2meq/g to about 2.2meq/g, or from about 1.2meq/g to about 2.1meq/g, or from about 1.3meq/g to about 2.0meq/g, or from about 1.3meq/g to about 1.9 meq/g.

the cationic copolymer can have a molecular weight of from about 100,000g/mol to about 1,500,000g/mol, or from about 300,000g/mol to about 1,500,000g/mol, or from about 500,000g/mol to about 1,500,000g/mol, or from about 700,000g/mol to about 1,000,000g/mol, or from about 900,000g/mol to about 1,200,000 g/mol.

The cationic copolymer can be a trimethylammonium propylmethacrylamide chloride-N-acrylamide copolymer, also known as AM MAPTAC. MAPTAC can have a charge density of about 1.3meq/g and a molecular weight of about 1,100,000 g/mol. The cationic copolymer may be AM: ATPAC. ATPAC may have a charge density of about 1.8meq/g and a molecular weight of about 1,100,000 g/mol.

(a) Cationic synthetic polymers

The hair care composition may comprise a cationic synthetic polymer which may be formed from

i) One or more cationic monomer units, and optionally

ii) one or more negatively charged monomer units, and/or

iii) a non-ionic monomer, wherein,

Wherein the subsequent charge of the copolymer is positive. The ratios of the three types of monomers are given as "m", "p" and "q", where "m" is the number of cationic monomers, "p" is the number of negatively charged monomers, and "q" is the number of nonionic monomers

The cationic polymer may be a water-soluble or water-dispersible non-crosslinked and synthetic cationic polymer having the structure:

Wherein a may be one or more of the following cationic moieties:

Wherein @ acylamino, alkylamido, ester, ether, alkyl, or alkylaryl;

Wherein Y is C1-C22 alkyl, alkoxy, alkylidene, alkyl, or aryloxy;

wherein ψ ═ C1-C22 alkyl, alkoxy, alkylaryl, or alkylaryloxy; .

wherein Z is C1-C22 alkyl, alkoxy, aryl, or aryloxy;

wherein R1 is H, C1-C4 straight or branched chain alkyl;

Wherein s is 0 or1, n is 0 or more than 1;

Wherein T and R7 ═ C1-C22 alkyl; and

Wherein X-is halogen, hydroxide, alkanol, sulfate or alkylsulfate.

Wherein the negatively charged monomer is defined by: r2' ═ H, C1-C4 straight or branched chain alkyl, and R3 is:

Wherein D is O, N, or S;

Wherein Q ═ NH2 or O;

Wherein u is 1 to 6;

Wherein t is 0 to 1; and

Wherein J ═ an oxygenated functional group containing the following element P, S, C.

Wherein the nonionic monomer is defined by: r2 ″ -H, C1-C4 straight or branched alkyl, R6 ═ straight or branched alkyl, alkylaryl, aryloxy, alkoxy, alkylaryloxy, and β is defined as

And is

Wherein G' and G "are independently from each other O, S or N-H, and L ═ 0 or 1.

Examples of the cationic monomer include aminoalkyl (meth) acrylates, (meth) aminoalkyl (meth) acrylamides; monomers comprising at least one secondary, tertiary or quaternary ammonium functional group, or a heterocyclic group containing a nitrogen atom, a vinylamine or an ethyleneimine; diallyldialkylammonium salts; mixtures thereof, salts thereof and macromers derived therefrom.

further examples of cationic monomers include dimethylaminoethyl (meth) acrylate, dimethylaminopropyl (meth) acrylate, di-tert-butylaminoethyl (meth) acrylate, dimethylaminomethyl (meth) acrylamide, dimethylaminopropyl (meth) acrylamide, ethyleneimine, vinylamine, 2-vinylpyridine, 4-vinylpyridine, trimethylammonium chloride ethyl (meth) acrylate, trimethylmethylammonium sulfate ethyl (meth) acrylate, dimethylbenzylammonium chloride ethyl (meth) acrylate, 4-benzoylbenzyldimethylammonium chloride ethyl acrylate, trimethylammonium chloride ethyl (meth) acrylamide, trimethylammonium chloride propyl (meth) acrylamide, vinylbenzyltrimethylammonium chloride, diallyldimethylammonium chloride.

Suitable cationic monomers include those comprising a quaternary ammonium group of formula-NR 3+, wherein R, which are identical or different, represent a hydrogen atom, an alkyl group comprising from 1 to 10 carbon atoms, or a benzyl group, optionally bearing a hydroxyl group, and include an anion (counterion). Examples of anions are halides (such as chloride, bromide), sulfate, hydrogen sulfate, alkyl sulfates (e.g., containing 1 to 6 carbon atoms), phosphate, citrate, formate, and acetate.

suitable cationic monomers include trimethyl ammonium chloride ethyl (meth) acrylate, trimethyl ammonium methyl sulfate ethyl (meth) acrylate, dimethyl benzyl ammonium chloride ethyl (meth) acrylate, 4-benzoylbenzyldimethyl ammonium chloride ethyl acrylate, trimethyl ammonium chloride ethyl (meth) acrylamide, trimethyl ammonium chloride propyl (meth) acrylamide, vinylbenzyltrimethyl ammonium chloride.

additional suitable cationic monomers include trimethyl ammonium chloride propyl (meth) acrylamide.

Examples of the monomer having a negative charge include α -ethylenically unsaturated monomers containing a phosphate group or a phosphonate group, α -ethylenically unsaturated monocarboxylic acids, monoalkyl esters of α -ethylenically unsaturated dicarboxylic acids, monoalkyl amides of α -ethylenically unsaturated dicarboxylic acids, α -ethylenically unsaturated compounds containing a sulfonic acid group, and salts of α -ethylenically unsaturated compounds containing a sulfonic acid group.

suitable monomers having a negative charge include acrylic acid, methacrylic acid, vinylsulfonic acid, salts of vinylsulfonic acid, vinylbenzenesulfonic acid, salts of vinylbenzenesulfonic acid, α -acrylamidomethylpropanesulfonic acid, salts of α -acrylamidomethylpropanesulfonic acid, 2-sulfoethyl methacrylate, salts of 2-sulfoethyl methacrylate, acrylamido-2-methylpropanesulfonic Acid (AMPS), salts of acrylamido-2-methylpropanesulfonic acid, and styrenesulfonate (SS).

Examples of nonionic monomers include vinyl acetate, amides of alpha-ethylenically unsaturated carboxylic acids, esters of alpha-ethylenically unsaturated monocarboxylic acids with hydrogenated or fluorinated alcohols, polyethylene oxide (meth) acrylates (i.e., polyethoxylated (meth) acrylic acid), monoalkyl esters of alpha-ethylenically unsaturated dicarboxylic acids, monoalkylamides of alpha-ethylenically unsaturated dicarboxylic acids, vinyl nitriles, vinylamine amides, vinyl alcohols, vinyl pyrrolidones, and vinyl aromatics.

Suitable nonionic monomers include styrene, acrylamide, methacrylamide, acrylonitrile, methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, 2-ethyl-hexyl acrylate, 2-ethyl-hexyl methacrylate, 2-hydroxyethyl acrylate, and 2-hydroxyethyl methacrylate.

The anionic counterion (X-) associated with the synthetic cationic polymer can be any known counterion so long as the polymer remains soluble or dispersible in water, in the hair care composition, or in a coacervate phase in the hair care composition, and so long as the counterion is physically and chemically compatible with the essential components of the hair care composition, or does not otherwise unduly impair product performance, stability, or aesthetics. Non-limiting examples of such counterions include halide ions (e.g., chloride, fluoride, bromide, iodide), sulfate, and methosulfate.

The cationic polymers described herein can help provide an alternative hydrophobic F layer to damaged hair, especially chemically treated hair. The microscopically thin F-layer helps to seal moisture and prevent further damage while providing natural weatherability. Chemical treatment can damage the hair cuticle and peel it away from the protective F-layer. When the F-layer is peeled off, the hair becomes increasingly hydrophilic. It has been found that when lyotropic liquid crystals are applied to chemically treated hair, the hair becomes more hydrophobic and more natural-like in both look and feel. Without being bound by any theory, it is believed that the lyotropic liquid crystal complex forms a hydrophobic layer or film that covers the hair fibers and protects the hair, as does a natural F-layer. The hydrophobic layer restores the hair to a generally untreated, healthier state. Lyotropic liquid crystals are formed by mixing the synthetic cationic polymers described herein with the anionic detersive surfactant component of the aforementioned hair care compositions. Synthetic cationic polymers have relatively high charge densities. It should be noted that some synthetic polymers with relatively high cationic charge density do not form lyotropic liquid crystals, mainly due to their unusual linear charge density. Such synthetic cationic polymers are described in WO 94/06403 to Reich et al. The synthetic polymers described herein can be formulated in stable hair care compositions that provide improved conditioning performance against damaged hair.

The cationic synthetic polymers which form lyotropic liquid crystals have a cationic charge density of from about 2meq/gm to about 7meq/gm, and/or from about 3meq/gm to about 7meq/gm, and/or from about 4meq/gm to about 7 meq/gm. The cationic charge density may be about 6.2 meq/gm. The polymer may also have an m.wt. of from about 1,000 to about 5,000,000, and/or from about 10,000 to about 1,500,000, and/or from about 100,000 to about 1,500,000.

Cationic synthetic polymers that provide enhanced conditioning and benefit agent deposition without the need to form lyotropic liquid crystals may have a cationic charge density of from about 0.7meq/gm to about 7meq/gm, and/or from about 0.8meq/gm to about 5meq/gm, and/or from about 1.0meq/gm to about 3 meq/gm. The polymer also has an m.wt. of about 1,000 to about 1,500,000, about 10,000 to about 1,500,000, and about 100,000 to about 1,500,000.

suitable cationic cellulose polymers are the salts of hydroxyethyl cellulose reacted with trimethylammonium substituted epoxide, known in the industry (CTFA) as polyquaternium 10 and available from Dow/Amerchol Corp. (Edison, n.j., USA) as their Polymer LR, JR and KG Polymer series. Non-limiting examples include: JR-30M, KG-30M, JP, LR-400, and mixtures thereof. Other suitable types of cationic cellulose include the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide, referred to in the industry (CTFA) as polyquaternary ammonium salts 24. These materials are available from Dow/Amerchol Corp under the trade name Polymer LM-200. Other suitable types of cationic cellulose include the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide and trimethyl ammonium-substituted epoxide, which are known in the industry (CTFA) as polyquaternary ammonium salts 67. These materials are available from Dow/Amerchol Corp, under the trade names SoftCAT Polymer SL-5, SoftCAT Polymer SL-30, Polymer SL-60, Polymer SL-100, Polymer SK-L, Polymer SK-M, Polymer SK-MH, and Polymer SK-H.

The concentration of the cationic polymer ranges from about 0.01% to about 5%, from about 0.08% to about 3%, from about 0.1% to about 2%, and/or from about 0.2% to about 1%, by weight of the hair care composition.

Anionic polymers

The hair care composition may further comprise one or more anionic polymers. Anionic polymers are polymers comprising anionic functional groups. Non-limiting examples of anionic functional groups include carboxylate, sulfonate, sulfate, phosphonate, phosphate, nitrate, and the like. The anionic polymer may be a homopolymer, i.e., a polymer constructed using one type of monomer, or a copolymer, i.e., a polymer constructed using more than one type of monomer (including one or more monomers having anionic functional groups and/or other monomers containing non-anionic functional groups). The hair care composition may comprise from about 0.1% to about 10% of the anionic polymer, from about 0.25% to about 8% of the anionic polymer, or from about 0.5% to about 5% of the anionic polymer, or from about 1% to about 2.5% of the anionic polymer.

The anionic polymer may be a polyacrylate or polyacrylamide polymer. The hair care composition may comprise an anionic polymer which is a homopolymer based on acrylic acid, methacrylic acid or other related derivatives, non-limiting examples including polyacrylates, polymethacrylates, polyethylacrylates and polyacrylamides.

The anionic polymer may be an alkali-swellable and hydrophobically modified alkali-swellable acrylic copolymer or methacrylate copolymer, non-limiting examples of which include acrylic acid/acrylnitrogen copolymer, acrylate/steareth-20 itaconate copolymer, acrylate/cetyleth-20 itaconate copolymer, acrylate/aminoacrylate/C10-30 alkyl PEG-20 itaconate copolymer, acrylate/aminoacrylate copolymer, acrylate/steareth-20 methacrylate copolymer, acrylate/beheneth-25 methacrylate copolymer, acrylate/steareth-20 methacrylate crosspolymer, acrylic acid/steareth-20, acrylic acid/stearyl alcohol copolymer, acrylate/beheneth-25 methacrylate/HEMA crosspolymer, acrylate/vinyl neodecanoate crosspolymer, acrylate/vinyl isodecanoate crosspolymer, enoate/palmitoylether-25 acrylate copolymer, acrylic acid/acrylamidomethylpropane sulfonic acid copolymer, and acrylate/C10-C30 alkyl acrylate crosspolymer.

The anionic polymer may be a soluble crosslinked acrylic polymer, non-limiting examples of which include carbomers.

The anionic polymer may be an associative polymer, non-limiting examples include: hydrophobically modified alkali swellable emulsions, non-limiting examples include hydrophobically modified polyacrylates; hydrophobically modified polyacrylic acids and hydrophobically modified polyacrylamides; hydrophobically modified polyethers wherein these materials may have a hydrophobic moiety selected from the group consisting of cetyl, stearyl, oleyl, and combinations thereof.

Non-limiting examples of anionic polymers include: C-LC/SD-PC: sodium polyaspartate; poly (2-acrylamido-2-methyl-1-propanesulfonic acid) having a MW of about 2,000,000; poly (2-acrylamido-2-methyl-1-propanesulfonic acid-co-acrylonitrile) acrylonitrile; poly (4-styrenesulfonic acid-co-maleic acid) sodium salt having a MW of about 20,000; PVM/MA copolymers; II Polymer: sodium polystyrene sulfonate having a MW of about 70,000 or 200,000 or1,000,000; polystyrene sulfonate having a MW of about 75,000; ammonium polystyrene sulfonate having a MW of about 200,000; MIRUSTYLE X-HP lanolin polyether-40 sodium maleate/styrene sulfonate copolymer; MIRUSTYLE X-HV methoxy PEG-16 sodium maleate/styrene sulfonate copolymer; poly anethole sulfonic acid sodium salt; covacryl MV 60: sodium polyacrylate having a MW of about 2,100 or 5,100 or 8,000 or 15,000; covacryl SP: polyacrylic acid; poly (vinyl sulfate) potassium salt having a MW of about 170,000; poly (vinylsulfonic acid, sodium salt); EcoMoothTM statin: ethylene/sodium acrylate copolymers; fixate Plus polymer: polyacrylate-14; fixate Superhold polymers: polyacrylate-2 crosslinked polymer; fixomer A-30 Polymer: methacrylic acid (and) methacrylic acid/sodium acrylamidomethylpropane sulfonate copolymer, hyafactor (tm) -PGA: sodium polyglutamate; DSP 2 KTM: sodium polyitaconate; sodium acrylate/sodium acryloyldimethyl taurate copolymer; CA 66: VA/crotonate copolymers; CAN: VA/crotonate/vinyl neodecanoate copolymer; acrylate/methacrylamide copolymers; carbomer; sodium carbomer; HSP-1180: polyacrylamide methyl propane sulfonic acid; sodium polynaphthalenesulfonate; purified sodium carboxymethylcellulose (CMC) of BlanoseTM cellulose gum: cellulose gum; cellulose gum (CMC): cellulose gum; fixatet TMDesign Polymer: polyacrylate-32; CFT: xanthan gum; CAN: VA/crotonate/vinyl neodecanoate copolymer; fixomer A-30 Polymer: methacrylic acid (and) methacrylic acid/sodium acrylamidomethylpropane sulfonate copolymer; biogel-1; PS-112: polydimethylsiloxane PEG-7 phosphate; PS-112 anionic guar: carboxymethyl hydroxypropyl guar; carrageenan; sodium carrageenan; poly (methacrylic acid) with MW of about 100,000; poly (ethyl acrylate/acrylic acid); poly (methyl methacrylate/methacrylic acid) with MW of about 100,000 [90:10 monomer ratio ]; poly (methyl methacrylate/methacrylic acid) with MW of about 1,200,000 [75:25 monomer ratio ]; poly (methyl methacrylate/methacrylic acid) with MW of about 1,200,000(500,000); poly (methyl methacrylate/methacrylic acid) [80:20 monomer ratio ]; poly (styrenesulfonic acid/maleic acid), sodium salt with MW of about 15,000; ammonium poly (methacrylate), 30% aqueous, MW about 15,000; poly (butadiene/maleic acid), 1:1, 42% aqueous, MW about 10,000-15,000; poly (maleic acid), 50% aqueous solution, MW about 800-; poly (vinyl phosphonic acid), 30% solution, MW about 24,000; poly (vinyl phosphoric acid), sodium salt with MW of about 200,000; poly (vinylsulfonic acid) sodium salt, 25% aqueous solution, MW about 4,000 and 6,000; poly (acrylic acid), powder with MW of about 4,000,000; poly (acrylic acid), 50% aqueous solution, MW about 5,000; poly (acrylic acid), sodium salt, powder with MW of about 2,000; poly (acrylic acid), sodium salt, 40% solution, MW about 3,000; all of which are available from Polysciences, Inc.

Thickening polymer

the hair care composition may comprise a thickening polymer to increase the viscosity of the composition. Suitable thickening polymers may be used. The hair care composition may comprise from about 0.5% to about 10% thickening polymer, alternatively from about 0.8% to about 8% thickening polymer, alternatively from about 1.0% to about 5% thickening polymer, and from about 1% to about 4% thickening polymer. The thickening polymer modifier can be polyacrylate, polyacrylamide thickener. The thickening polymer may be an anionic thickening polymer.

scalp care compositions may contain a thickening polymer that is a homopolymer based on acrylic acid, methacrylic acid or other related derivatives, non-limiting examples include polyacrylates, polymethacrylates, polyethylacrylates and polyacrylamides.

The thickening polymer may be an alkali-swellable and hydrophobically modified alkali-swellable acrylic copolymer or methacrylate copolymer, non-limiting examples include acrylic acid/acrylnitrogen copolymer, acrylate/steareth-20 itaconate copolymer, acrylate/cetyleth-20 itaconate copolymer, acrylate/aminoacrylate/C10-30 alkyl PEG-20 itaconate copolymer, acrylate/aminoacrylate copolymer, acrylate/steareth-20 methacrylate copolymer, acrylate/beheneth-25 methacrylate copolymer, acrylate/steareth-20 methacrylate crosspolymer, acrylic acid/stearyl ethoxylate-20, acrylic acid/, Acrylate/beheneth-25 methacrylate/HEMA crosspolymer, acrylate/vinyl neodecanoate crosspolymer, acrylate/vinyl isodecanoate crosspolymer, enoate/palmitoylether-25 acrylate copolymer, acrylic acid/acrylamidomethylpropane sulfonic acid copolymer, and acrylate/C10-C30 alkyl acrylate crosspolymer.

The thickening polymer may be a soluble crosslinked acrylic polymer, non-limiting examples of which include carbomers.

The thickening polymer may be an associative polymer thickener, non-limiting examples of which include: hydrophobically modified alkali swellable emulsions, non-limiting examples include hydrophobically modified polyacrylates; hydrophobically modified polyacrylic acids and hydrophobically modified polyacrylamides; hydrophobically modified polyethers wherein these materials may have a hydrophobic moiety selected from the group consisting of cetyl, stearyl, oleyl, and combinations thereof.

the thickening polymer may be used in combination with polyvinylpyrrolidone, cross-linked polyvinylpyrrolidone and derivatives. The thickening polymer may be combined with polyvinyl alcohol and derivatives. The thickening polymer may be combined with polyaziridine and derivatives.

The thickening polymer may be combined with an alginic acid-based material, non-limiting examples of which include sodium alginate and propylene glycol alginate.

The thickening polymer may be used in combination with a polyurethane polymer, non-limiting examples of which include: non-limiting examples of hydrophobically modified alkoxylated urethane polymers include PEG-150/decanol/SMDI copolymer, PEG-150/stearyl alcohol/SMDI copolymer, polyurethane-39.

the thickening polymer may be combined with an associative polymer thickener, non-limiting examples of which include: a hydrophobically modified cellulose derivative; and hydrophilic moieties having repeating ethyleneoxy groups of 10-300, 30-200, and 40-150 repeating units. Non-limiting examples of this type include PEG-120-methyl glucose dioleate, PEG- (40 or 60) sorbitan tetraoleate, PEG-150 pentaerythritol tetrastearate, PEG-55 propylene glycol oleate, PEG-150 distearate.

the thickening polymer may be combined with cellulose and derivatives, non-limiting examples including microcrystalline cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, ethyl cellulose; nitrocellulose; cellulose sulfate; cellulose powder; hydrophobically modified cellulose.

Thickening polymers may be combined with guar and guar derivatives, non-limiting examples include hydroxypropyl guar and hydroxypropyl guar hydroxypropyltrimonium chloride.

The thickening polymer may be blended with polyethylene oxide; polypropylene oxide; and POE-PPO copolymer.

The thickening polymer may be combined with a polyalkylene glycol characterized by the general formula:

Wherein R is hydrogen, methyl, or a mixture thereof, preferably hydrogen, and n is an integer having an average number of 2,000-180,000, or 7,000-90,000, or 7,000-45,000. Non-limiting examples of this type include PEG-7M, PEG-14M, PEG-23M, PEG-25M, PEG-45M, PEG-90M, or PEG-100M.

Thickening polymers may be combined with silica, non-limiting examples include fumed silica, precipitated silica, and silica surface treated with silicone.

The thickening polymer may be combined with a water-swellable clay; non-limiting examples include laponite, bentonite, montmorillonite, smectite, and hectorite.

The thickening polymer may be combined with gums, non-limiting examples of which include xanthan gum, guar gum, hydroxypropyl guar gum, gum arabic, tragacanth gum, galactan, carob gum, karaya gum and locust bean gum.

The thickening polymer may be combined with: dibenzylidene sorbitol, algin, pectin, agar, quince seed (Cydonia oblonga Mill)), starch (obtained from rice, corn, potato, wheat, etc.), starch derivatives (e.g., carboxymethyl starch, methyl hydroxypropyl starch), algae extracts, dextran, succinoglucan (succinoglucan), and pulleran.

Non-limiting examples of thickening polymers include acrylamide/ammonium acrylate copolymer (and) polyisobutylene (and) polysorbate 20; acrylamide/sodium acryloyldimethyl taurate copolymer/isohexadecane/polysorbate 80, ammonium acryloyldimethyl taurate/VP copolymer, sodium acrylate/sodium acryloyldimethyl taurate copolymer, acrylate crosspolymer-4, acrylate crosspolymer-3, acrylate/behenyl polyether-25 methacrylate copolymer, acrylate/acrylic acid C10-C30 alkyl ester crosspolymer, acrylate/stearyl polyoxyethylene ether-20 itaconate copolymer, ammonium polyacrylate/isohexadecane/PEG-40 castor oil; carbomer, sodium carbomer, cross-linked polyvinylpyrrolidone (PVP), polyacrylamide/C13-14 isoparaffin/laureth-7, polyacrylate 13/polyisobutylene/polysorbate 20, polyacrylate crosspolymer-6, polyamide-3, polyquaternium-37 (and) hydrogenated polydecene (and) trideceth-6, acrylamide/sodium acryloyldimethyl taurate/acrylic acid copolymer, sodium acrylate/sodium acryloyldimethyl taurate/dimethylacrylamide, cross-linked polymer (and) isohexadecane (and) polysorbate 60, sodium polyacrylate. Exemplary commercially available thickening polymers include: ACULYNTM 28, ACULYNTM 33, ACULYNTM 88, ACULYNTM22, ACULYNTM Excel, Aqua SF-1, ETD 2020, Ultrez 20, Ultrez 21, Ultrez 10, Ultrez 30, 1342, Aqua SF-2 polymer, Sepigel TM 305, Simulgel TM 600, Sepimax Zen, SMART 1000, TTA, SC-Plus, PLUS, AVC, Stabylen 30, and combinations thereof.

Gel networks

In the present invention, a gel network may be present. The gel network component of the present invention may comprise at least one fatty amphiphile. As used herein, "fatty amphiphile" refers to a compound having a hydrophobic tail group defined as an alkyl, alkenyl (containing up to 3 double bonds), alkylaryl, or branched alkyl group having a length of C12-C70 and a hydrophilic head group that renders the compound water insoluble, wherein the compound also has a net charge neutrality at the pH of the shampoo composition.

The shampoo compositions of the present invention comprise a fatty amphiphile as part of a preformed dispersed gel network phase in an amount of from about 0.05% to about 14%, preferably from about 0.5% to about 10%, and more preferably from about 1% to about 8%, by weight of the shampoo composition.

According to the present invention, a suitable fatty amphiphile or suitable mixture of two or more fatty amphiphiles has a melting point of at least about 27 ℃. As used herein, Melting point can be measured by standard Melting point methods as described in U.S. Pharmacopeia, USP-NF General channel <741> "Melting range or temperature". The melting point of a mixture of two or more substances is determined by mixing the two or more substances at a temperature above the respective melting points and then allowing the mixture to cool. If the resulting composite is a homogeneous solid below about 27 deg.C, the mixture has a melting point suitable for use in the present invention. Mixtures of two or more fatty amphiphiles are also suitable for use in the present invention, provided that the mixture has a composite melting point of at least about 27 ℃, wherein the mixture comprises at least one fatty amphiphile having an individual melting point of less than about 27 ℃.

suitable fatty amphiphiles of the present invention include fatty alcohols, alkoxylated fatty alcohols, fatty phenols, alkoxylated fatty phenols, fatty amides, alkoxylated fatty amides, fatty amines, fatty alkylamidoalkylamines, fatty alkoxylated amines, fatty carbamates, fatty amine oxides, fatty acids, alkoxylated fatty acids, fatty diesters, fatty sorbitan esters, fatty sugar esters, methyl glucoside esters, fatty glycol esters, monoglycerides, diglycerides and triglycerides, polyglycerol fatty esters, alkyl glyceryl ethers, propylene glycol fatty esters, cholesterol, ceramides, fatty silicone waxes, fatty glucamides and phospholipids, and mixtures thereof.

In the present invention, the shampoo composition may comprise a fatty alcohol gel network. These gel networks are formed by mixing a fatty alcohol and a surfactant in a ratio of about 1:1 to about 40:1, about 2:1 to about 20:1, and/or about 3:1 to about 10: 1. The formation of the gel network involves heating a dispersion of fatty alcohol in water with a surfactant to a temperature above the melting point of the fatty alcohol. During the mixing process, the fatty alcohol melts, allowing the surfactant to partition into fatty alcohol droplets. The surfactant carries the water with it into the fatty alcohol. This turns isotropic fatty alcohol drops into liquid crystalline phase drops. When the mixture is cooled below the chain melting temperature, the liquid crystalline phase transforms into a solid crystalline gel network. The gel network provides a stabilizing benefit to cosmetic creams and hair conditioners. In addition, they also deliver the conditioning feel benefits of hair conditioners.

The fatty alcohol may be included in the fatty alcohol gel network at a level of from about 0.05 wt% to about 14 wt% by weight. For example, the fatty alcohol may be present in an amount ranging from about 1% to about 10% by weight, and/or from about 6% to about 8% by weight.

Fatty alcohols useful herein include those having from about 10 to about 40 carbon atoms, from about 12 to about 22 carbon atoms, from about 16 to about 22 carbon atoms, or from about 16 to about 18 carbon atoms. These fatty alcohols may be linear or branched and may be saturated or unsaturated. Non-limiting examples of fatty alcohols include cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof. Mixtures of cetyl and stearyl alcohols in a ratio of about 20:80 to about 80:20 are suitable.

Preparation of gel network: the vessel was charged with water and the water was heated to about 74 ℃. Cetyl alcohol, stearyl alcohol, and SLES surfactants were added to the heated water. After incorporation, the resulting mixture was passed through a heat exchanger where the mixture was cooled to about 35 ℃. Upon cooling, the fatty alcohol and surfactant crystallize to form a crystalline gel network. Table 1 provides the components of the exemplary gel network compositions and their corresponding amounts.

TABLE 1

Gel network component

1. Water-miscible solvents

Carriers useful in hair care compositions can include aqueous solutions of water and lower alkyl alcohols, polyols, ketones having 3 to 4 carbon atoms, C1-C6 esters of C1-C6 alcohols, sulfoxides, amides, carbonates, ethoxylated and propoxylated C1-C10 alcohols, lactones, pyrrolidones, and mixtures thereof. Non-limiting lower alkyl alcohols are monohydric alcohols having from 1 to 6 carbons, such as ethanol and isopropanol. Non-limiting examples of polyols useful in the present invention include propylene glycol, dipropylene glycol, butylene glycol, hexylene glycol, glycerin, propylene glycol, and mixtures thereof.

The hair care composition may comprise a hydrotrope/viscosity modifier which is an alkali metal or ammonium salt of a lower alkyl benzene sulphonate, such as sodium xylene sulphonate, sodium cumene sulphonate or sodium toluene sulphonate.

In the present invention, the hair care composition may comprise silicone/PEG-8 silicone/PEG-9 silicone/PEG-n silicone/silicone ether (n may be another integer), non-limiting examples include PEG 8-dimethicone a208) MW 855, PEG8 dimethicone D208 MW 2706.

C. Propellants or foaming agents

The hair care compositions described herein may comprise from about 1% to about 10% of a propellant or foaming agent, alternatively from about 2% to about 8% of a propellant or foaming agent, by weight of the hair care composition.

The propellant or foaming agent may comprise one or more volatile materials which are in the gaseous state and which may carry other components of the hair care composition in the form of particles or droplets or as a foam. The propellant or blowing agent may have a boiling point in the range of about-45 ℃ to about 5 ℃. The propellant or blowing agent may be liquefied when packaged under pressure in a conventional aerosol container. The rapid boiling of the propellant or foaming agent upon exiting the aerosol foam dispenser can aid in the atomization or foaming of the other components of the hair care composition.

Aerosol propellants or blowing agents useful in aerosol compositions may comprise chemically inert hydrocarbons such as propane, n-butane, isobutane, cyclopropane, and mixtures thereof, and halogenated hydrocarbons such as dichlorodifluoromethane, 1-dichloro-1, 1,2, 2-tetrafluoroethane, 1-chloro-1, 1-difluoro-2, 2-trifluoroethane, 1-chloro-1, 1-difluoroethylene, 1-difluoroethane, dimethyl ether, chlorodifluoromethane, trans-1, 3,3, 3-tetrafluoropropene, and mixtures thereof. The propellant or blowing agent may comprise hydrocarbons such as isobutane, propane and butane-these materials may be used for their low ozone reactivity and may be used as the sole component where they have a vapor pressure in the range of from about 1.17 bar to about 7.45 bar, or from about 1.17 bar to about 4.83 bar, or from about 2.14 bar to about 3.79 bar at 21.1 ℃.

D. Scalp health agent

In the present invention, in addition to the antifungal/antidandruff efficacy provided by the surfactant soluble antidandruff agent, one or more scalp health agents may be added to provide scalp benefits. This group of materials is diverse and provides a wide range of benefits including humectants, barrier improving agents, antifungal agents, antimicrobial and antioxidant agents, anti-itch agents, sensates, and other anti-dandruff agents such as polyvalent metal salts of pyrithione, non-limiting examples including Zinc Pyrithione (ZPT) and copper pyrithione, sulfur or selenium sulfide. Such scalp health agents include, but are not limited to: vitamins E and F, salicylic acid, niacinamide, caffeine, panthenol, zinc oxide, zinc carbonate, basic zinc carbonate, glycols, glycolic acid, PCA, PEG, erythritol, glycerol, triclosan, lactic acid, hyaluronate, allantoin and other ureas, betaine, sorbitol, glutamate, xylitol, menthol, menthyl lactate, isocyclomone, benzyl alcohol, and compounds comprising the following structure:

R1 is selected from H, alkyl, aminoalkyl, alkoxy;

Q ═ H2, O, -OR1, -N (R1)2, -OPO (OR1) x, -PO (OR1) x, -P (OR1) x, where x ═ 1-2;

V ═ NR1, O, -OPO (OR1) x, -PO (OR1) x, -P (OR1) x, where x ═ 1-2;

W＝H、O；

For n-0, X, Y is independently selected from H, aryl, naphthyl;

for n ≧ 1, X, Y ═ aliphatic CH2 or aromatic CH and Z is selected from aliphatic CH2, aromatic CH or a heteroatom;

A ═ lower alkoxy, lower alkylthio, aryl, substituted aryl, or fused aryl; and

The stereochemistry may vary at the position of the mark.

And natural extracts/oils including peppermint oil, spearmint, argan oil, jojoba oil and aloe vera.

E. optional ingredients

in the present invention, the hair care composition may further comprise one or more optional ingredients, including benefit agents. Suitable benefit agents include, but are not limited to, conditioning agents, cationic polymers, silicone emulsions, anti-dandruff agents, gel networks, chelating agents, and natural oils such as sunflower or castor oil. Additional suitable optional ingredients include, but are not limited to, perfumes, perfume microcapsules, colorants, particles, antimicrobial agents, foam inhibitors, antistatic agents, rheology modifiers and thickeners, suspending materials and structurants, pH adjusting and buffering agents, preservatives, pearlescers, solvents, diluents, antioxidants, vitamins, and combinations thereof. In the present invention, the composition may have from about 0.5% to about 7% perfume.

Such optional ingredients should be physically and chemically compatible with the components of the composition, and should not otherwise unduly impair product stability, aesthetics or performance. CTFA Cosmetic Ingredient Handbook, tenth edition (published by Cosmetic, Toiletry, and france Association, Inc. (Washington, d.c.) (2004) (hereinafter "CTFA") describes a wide variety of non-limiting substances that can be added to the compositions herein.

1. Conditioning agent

The conditioning agent of the hair care composition may be a silicone conditioning agent. The silicone conditioning agent can include a volatile silicone, a non-volatile silicone, or a combination thereof. The concentration of silicone conditioning agent typically ranges from about 0.01% to about 10%, from about 0.1% to about 8%, from about 0.1% to about 5%, and/or from about 0.2% to about 3%, by weight of the composition. Non-limiting examples of suitable silicone conditioning agents and optional silicone suspending agents are described in U.S. reissue patent No.34,584, U.S. patent No.5,104,646, and U.S. patent No.5,106,609, the descriptions of which are incorporated herein by reference.

The silicone conditioning agents used in the compositions of the present invention may have a viscosity of from about 20 centistokes ("csk") to about 2,000,0000 centistokes ("csk"), from about 1,000csk to about 1,800,000csk, from about 10,000csk to about 1,500,000csk, and/or from about 20,000csk to about 1,500,000csk, as measured at 25 ℃.

The dispersed silicone conditioning agent particles typically have a volume average particle size in the range of from about 0.01 microns to about 60 microns. For small particles applied to hair, the volume average particle size typically ranges from about 0.01 microns to about 4 microns, from about 0.01 microns to about 2 microns, from about 0.01 microns to about 0.5 microns.

Additional information on silicones, including sections discussing silicone fluids, compounds and resins and silicone preparation, can be found in Encyclopedia of Polymer Science and Engineering, Vol.15, 2 nd edition, p.204-308, John Wiley & Sons, Inc. (1989), which is incorporated herein by reference.

Emulsions and Emulsion StabilitySilicone emulsions suitable for use in the present invention include, but are not limited to, emulsions of insoluble silicones. These can be prepared via Emulsion polymerization as described according to U.S. patent 6,316,541 or U.S. patent 4,476,282 or U.S. patent application publication 2007/0276087, or they can be emulsified after polymerization is complete via a variety of emulsification methods as described in U.S. patent 9,255,184B2 or U.S. patent 7,683,119 or Emulsions and Emulsion Stability, CRC Press, 2005, edited by Johan Sjoblom. Based on the functionality of the silicone used, the emulsification method, and the desired emulsion particle size, these references can be consulted to obtain a non-limiting list of suitable emulsifiers and emulsifier blends. Thus, suitable insoluble polysiloxanes include polysiloxanes, such as alpha, omega-hydroxy terminated polysiloxanes or alpha, omega-alkoxy terminated polysiloxanes having an internal phase viscosity of from about 5csk to about 500,000 csk. For example, the insoluble silicone may have an internal phase viscosity of less than 400,000csk, preferably less than 200,000csk, more preferably from about 10,000csk to about 180,000 csk. The insoluble silicone may have an average particle size in the range of about 10nm to about 10 microns. The average particle size may range from about 15nm to about 5 microns, from about 20nm to about 1 micron, or from about 25nm to about 550nm, or from about 1 micron to 10 microns. The concentration of dispersed silicone in the emulsion may range from about 5% to 90%, or 20% to 85%, or 30% to 80%, by weight of the emulsion composition.

The average molecular weight of The insoluble silicone, The internal phase viscosity of The insoluble silicone, The viscosity of The silicone emulsion, and The size of The particles comprising The insoluble silicone are determined by methods commonly used by those skilled in The art, such as The methods disclosed in The Analytical Chemistry of Silicones, John Wiley & Sons, inc. For example, the viscosity of the silicone emulsion can be measured at 30 ℃ using a Brookfield viscometer with spindle 6 at 2.5 rpm. The silicone emulsion may also contain additional emulsifiers and anionic surfactants.

Other classes of silicones suitable for use in the compositions of the present invention include, but are not limited to: i) silicone fluids, including but not limited to silicone oils, which are flowable substances having less than about 1,000,000csk measured at 25 ℃; ii) an aminosilicone comprising at least one primary, secondary or tertiary amine; iii) a cationic silicone comprising at least one quaternary ammonium functional group; iv) a silicone gum; comprising a material having a viscosity greater than or equal to 1,000,000csk measured at 25 ℃; v) a silicone resin comprising a highly cross-linked polymeric silicone system; vi) a high refractive index silicone having a refractive index of at least 1.46, and vii) mixtures thereof.

The conditioning agent in the hair care composition of the present invention may further comprise at least one organic conditioning material such as an oil or wax, alone or in combination with other conditioning agents such as the silicones described above. The organic material may be non-polymeric, oligomeric or polymeric. It may be in the form of an oil or wax, and may be added as a neat formulation or in a pre-emulsified form. Some non-limiting examples of organic conditioning materials include, but are not limited to: i) a hydrocarbon oil; ii) a polyolefin; iii) fatty esters; iv) a fluorinated conditioning compound; v) a fatty alcohol; vi) alkyl glucosides and alkyl glucoside derivatives; vii) quaternary ammonium compounds; viii) polyethylene glycols and polypropylene glycols having a molecular weight of up to about 2,000,000, including those having the CTFA designation PEG-200, PEG-400, PEG-600, PEG-1000, PEG-2M, PEG-7M, PEG-14M, PEG-45M, and mixtures thereof.

2. Emulsifier

A wide variety of anionic and nonionic emulsifiers can be used in the hair care compositions of the present invention. Anionic and nonionic emulsifiers may be monomeric or polymeric in nature. For example, examples of monomers include, but are not limited to, alkyl ethoxylates, alkyl sulfates, soaps, and fatty acid esters, and derivatives thereof. By way of illustration and not limitation, examples of polymers include polyacrylates, polyethylene glycols, and block copolymers, and derivatives thereof. Naturally occurring emulsifiers such as lanolin, lecithin and lignin and their derivatives are also non-limiting examples of useful emulsifiers.

3. Chelating agents

The hair care composition may further comprise a chelating agent. Suitable chelating agents include those listed in Critical Stability Constants volume 1 of hose lithium in A E Martel & R M Smith (Plenum Press, New York & London (1974)) and Metal Complexes in Aqueous solutions of A E Martel & R D Handcock (Plenum Press, New York & London (1996)), both of which are incorporated herein by reference. The term "salts and derivatives thereof" when referring to chelating agents refers to salts and derivatives thereof having the same functional structure (e.g. the same chemical backbone) as the chelating agent to which they refer, and having similar or better chelating properties. The term includes alkali metal, alkaline earth metal, ammonium, substituted ammonium (i.e., monoethanolamine, diethanolamine, triethanolamine) salts, esters, and mixtures thereof of chelating agents having an acidic moiety, especially all sodium, potassium or ammonium salts. The term "derivative" also includes "chelating surfactant" compounds, such as those exemplified in U.S. patent No.5,284,972, as well as macromolecules containing one or more chelating groups having the same functional structure as the parent chelating agent, such as the polymer EDDS (ethylenediamine disuccinic acid) disclosed in U.S. patent No.5,747,440.

The chelating agent may be incorporated in the compositions herein in an amount ranging from 0.001% to 10.0%, preferably from 0.01% to 2.0% by total weight of the composition.

non-limiting classes of chelating agents include carboxylic acids, aminocarboxylic acids, including amino acids, phosphoric acids, phosphonic acids, polyphosphonic acids, polyethyleneimines, multifunctional substituted aromatic compounds, their derivatives, and salts.

Non-limiting chelating agents include the following and their salts. Ethylenediaminetetraacetic acid (EDTA), ethylenediaminetriacetic acid, ethylenediamine-N, N '-disuccinic acid (EDDS), ethylenediamine-N, N' -diaminetetraacetic acid (EDDG), salicylic acid, aspartic acid, glutamic acid, glycine, malonic acid, histidine, Diethylenetriaminepentaacetate (DTPA), N-hydroxyethylethylenediaminetriacetic acid, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraminehexaacetate, ethanoldiglycine, propylenediaminetetraacetic acid (PDTA), methylglycinediacetic acid (MODA), diethylenetriaminepentaacetic acid, methylglycinediacetic acid (MGDA), N-acyl-N, N ', N' -ethylenediaminetriacetic acid, nitrilotriacetic acid, ethylenediaminedipentanedioic acid (EDGA), 2-hydroxypropylenediaminedisuccinic acid (HPDS), glycinamide-N, N '-disuccinic acid (GADS), 2-hydroxypropanediamine-N-N' -disuccinic acid (HPDDS), N-2-hydroxyethyl-N, N-diacetic acid, glyceriminodiacetic acid, iminodiacetic acid-N-2-hydroxypropylsulfonic acid, aspartic acid N-carboxymethyl-N-2-hydroxypropyl-3-sulfonic acid, alanine-N, N '-diacetic acid, aspartic acid N-monoacetic acid, iminodisuccinic acid, diamine-N, N' -dimer acid, monoamide-N, N '-dimer acid, diaminoalkylbis (sulfosuccinic acid) (DDS), ethylenediamine-N-N' -bis (o-hydroxyphenylacetic acid)), (HPDDS), N, N ' -bis (2-hydroxybenzyl) ethylenediamine-N, N ' -diacetic acid, ethylenediamine tetrapropionate, triethylenetetramine hexaacetate, diethylenetriamine pentaacetate, dipicolinic acid, Ethylenedicysteine (EDC), ethylenediamine-N, N ' -bis (2-hydroxyphenylacetic acid) (EDDHA), glutamic acid diacetic acid (GLDA), Hexamethyleneaminocarboxylate (HBED), polyethyleneimine, 1-hydroxydiphosphonate, aminotri (methylenephosphonic Acid) (ATMP), nitrilotrimethylene phosphonate (NTP), ethylenediamine tetramethylenephosphonate, diethylenetriamine pentamethylenephosphonate (DTPMP), ethane-1-Hydroxydiphosphonate (HEDP), 2-phosphinobutane-1, 2, 4-tricarboxylic acid, polyphosphoric acid, sodium tripolyphosphate, sodium hydrogen phosphate, Tetrasodium diphosphate, hexametaphosphoric acid, sodium metaphosphate, phosphonic acids and derivatives, aminoalkylene-poly (alkylenephosphonic acids), aminotri (1-ethylphosphonic acid), ethylenediaminetetra (1-ethylphosphonic acid), aminotri (1-propylphosphonic acid), aminotri (isopropylphosphonic acid), ethylenediaminetetra (methylenephosphonic acid) (EDTMP), 1, 2-dihydroxy-3, 5-disulfobenzene.

Aqueous carrier

The hair care composition may be in the form of a pourable liquid (at ambient conditions). Thus, such compositions will typically comprise a carrier present at a level of from about 40% to about 85%, alternatively from about 45% to about 80%, alternatively from about 50% to about 75%, by weight of the hair care composition. The carrier may comprise water, or a miscible mixture of water and organic solvent, and in one aspect may comprise water with minimal or insignificant concentrations of organic solvent, except for those additionally incidentally incorporated into the composition as minor ingredients of other necessary or optional components.

Carriers useful in the hair care compositions of the present invention may include water and aqueous solutions of lower alkyl alcohols and polyols. Lower alkyl alcohols useful herein are monohydric alcohols having from 1 to 6 carbons, in one aspect, ethanol and isopropanol. Exemplary polyols useful herein include propylene glycol, hexylene glycol, glycerin, and propane diol.

G. Foam dispenser

The hair care compositions described herein may be provided in a foam dispenser. The foam dispenser may be an aerosol foam dispenser. The aerosol foam dispenser may comprise a reservoir for holding the hair treatment composition. The reservoir may be made of any suitable material selected from the group consisting of plastics, metals, alloys, laminates, and combinations thereof. And the reservoir may be single use. The reservoir may be removed from the aerosol foam dispenser. Alternatively, the reservoir may be integral with the aerosol foam dispenser. Also, there may be two or more reservoirs.

The foam dispenser may also be a mechanical foam dispenser. The mechanical foam dispenser may be selected from the group consisting of squeeze foam dispensers, pump foam dispensers, other mechanical foam dispensers, and combinations thereof. The mechanical foam dispenser may be a squeeze foam dispenser. Non-limiting examples of suitable pump dispensers include those described in WO 2004/078903, WO 2004/078901, and WO 2005/078063, and may be provided by Albea (60Electric ave., Thomaston, CT 06787USA) or Rieke Packaging Systems (500West seven St., Auburn, Indiana 46706).

The mechanical foam dispenser may comprise a reservoir for holding the hair treatment composition. The reservoir may be made of any suitable material selected from the group consisting of plastics, metals, alloys, laminates, and combinations thereof. The reservoir may be a refillable reservoir, such as a pour-in or screw-in reservoir, or the reservoir may be disposable. The reservoir may also be removable from the mechanical foam dispenser. Alternatively, the reservoir may be integrated with a mechanical foam dispenser. Also, there may be two or more reservoirs.

The reservoir may be comprised of a substance selected from the group consisting of a rigid substance, a flexible substance, and combinations thereof. When an internal partial vacuum is applied to the reservoir, the reservoir may be comprised of a rigid substance if it does not collapse under external atmospheric pressure.

H. Product form

The hair care compositions of the present invention may be presented in the form of typical hair care formulations. They may be in the form of solutions, dispersions, emulsions, powders, talc, encapsulates, spheres, sponges, solid dosage forms, foams, and other delivery mechanisms. The compositions of the present invention may be hair tonics, leave-on hair products such as treatments and styling products, rinse-off hair products such as shampoos and personal cleansing products, and treatment products; and any other form that can be applied to hair.

I. Applicator device

In the present invention, the hair care composition can be dispensed from the applicator for direct dispensing to an area of the scalp. Direct dispensing via a directional delivery applicator onto the scalp enables the direct deposition of undiluted cleanser where cleansing requirements are highest. This also minimizes the risk of eye contact with the cleaning solution.

the applicator is attached or attachable to a bottle containing the cleansing hair care composition. The applicator may consist of a base that receives or extends to a single or multiple tines. The tines have an opening that can be located at the tip, the base, or any point between the tip and the base. These openings allow the product to be dispensed from the bottle directly onto the hair and/or scalp.

Alternatively, the applicator may also consist of brush-like bristles attached to or extending from the base. In this case, the product will be dispensed from the base and the bristles will allow product dispensing via a combing or brushing motion.

the applicator and tine design and substance can also be optimized to achieve scalp massage. In this case, it is advantageous that the tine or bristle geometry at the tip is more rounded, similar to a ball applicator for eye creams. It may also be more advantageous for the substance to be smoother and softer; for example, a metal or metal-like finish, "rubber-like material".

Viscosity measurement

The viscosity of the shampoo can be measured for 2.5mL of sample at 3 minutes at 2s-1, 27 ℃ using a conical plate Brookfield RS rheometer with cone C75-1.

In the present invention, the surfactant composition, wherein only the surfactant soluble anti-dandruff agent has a viscosity of less than about 5000cps at 2s-1 and cannot be thickened to above 5000cps at 2s-1 with sodium chloride salts in the range of about 0.1% to 3%. Further, in the present invention, the surfactant composition having only the surfactant soluble anti-dandruff agent therein has a viscosity of less than about 4000cps at 2s-1 and cannot be thickened to above 4000cps at 2s-1 with sodium chloride salt in the range of about 0.1% to 3%. In the present invention, the surfactant composition, wherein only the surfactant soluble anti-dandruff agent has a viscosity of less than about 3000cps at 2s-1 and cannot be thickened to above 3000cps at 2s-1 with sodium chloride salts in the range of about 0.1% to 3%. In the present invention, the surfactant composition, wherein only the surfactant soluble anti-dandruff agent has a viscosity of less than about 2000cps at 2s-1 and cannot be thickened to above 2000cps at 2s-1 with sodium chloride salts in the range of about 0.1% to 3%.

Measurement of% transmittance (T%)

Techniques for analyzing complex coacervate formation are known in the art. One method of assessing coacervate formation of a transparent or translucent composition upon dilution is to measure the percentage of light transmitted through the diluted sample (T%) using a spectrophotometer. Higher levels of coacervate formation are generally achieved as the measured percent light transmittance (T%) value of the dilution decreases. Diluted samples of water to composition in different weight ratios, for example 2 parts water to 1 part composition (2:1), or 7.5 parts water to 1 part composition (7.5:1), or 16 parts water to 1 part composition (16:1), or 34 parts water to 1 part composition (34:1), can be prepared and the% T of each diluted sample measured. Examples of possible dilution ratios may include 2:1, 3:1, 5:1, 7.5:1, 11:1, 16:1, 24:1, or 34: 1. By averaging the T% values of the samples across a range of dilution ratios, it can be simulated and determined how much coacervate the composition will on average form when the consumer applies the composition to wet hair, lather, and then rinse it off. The mean T% can be calculated by taking the numerical mean of the individual T% measurements for the following dilution ratios: 2:1, 3:1, 5:1, 7.5:1, 11:1, 16:1, 24:1, and 34: 1.

T% can be measured by ultraviolet/visible (UV/VI) spectrophotometry, which determines the transmission of UV/VIs light through a sample. It has been shown that a wavelength of 600nm is sufficient to characterize the transmittance of light through the sample. In general, it is best to follow specific instructions relating to the particular spectrophotometer being used. Typically, the procedure for measuring percent transmission begins with setting the spectrophotometer to 600 nm. Then, a calibration "blank" was run, and the readout was calibrated to 100% transmission. Individual test samples were then placed in a cuvette designed to fit a particular spectrophotometer, and care was taken to ensure that there were no air bubbles within the sample before T% was measured by the spectrophotometer at 600 nm. Alternatively, multiple samples can be measured simultaneously by using a spectrophotometer (such as SpectraMax M-5 available from Molecular Devices). Multiple diluted samples can be prepared in 96-well plates (VWR catalog number 82006-. The flat bottom plate was placed in SpectraMax M-5 and T% was measured using Software Pro v.5 (TM) Software from Molecular Devices.

Measurement of antidandruff agent deposition

in vivo deposition of a surfactant soluble anti-dandruff agent, such as Octopirox, on the scalp can be determined by ethanol extraction of the agent after the scalp is treated with a cleansing composition containing a surfactant soluble agent and rinsed off. The concentration of the reagent in the extraction solvent or solution was measured by HPLC. Quantification was performed by reference to a standard curve. The concentration detected by HPLC was converted to the amount collected in grams by using the concentration multiplied by volume.

The percent of agent deposited can be calculated using the following formula:

The deposition efficiency can be calculated using the following formula:

Sample calculation of% piroctone olamine deposited, wherein:

deposited reagent gram number 1.8X 10-6

The extracted scalp area is 1cm2

Piroctone olamine in shampoo 1.0%

gram of shampoo applied is 5g

area of scalp treated 300cm2

Deposited piroctone olamine%

Sample calculation of deposition efficiency, wherein:

Piroctone olamine deposited from the example formulation%

Piroctone olamine deposited from control formulation%

Deposition efficiency 8.6 ×

preparation of shampoo compositions

Shampoo compositions are prepared by adding the remaining portions of surfactant, anti-dandruff agent, fragrance, viscosity modifier, cationic polymer and water with sufficient agitation to ensure a uniform mixture. The mixture may be heated to 50-75 ℃ to accelerate dissolution of the soluble reagent and then cooled. The product pH may be adjusted as needed to provide shampoo compositions of the present invention suitable for application to human hair and scalp, and may vary within the range of from about pH 4 to 9, or from about pH 4 to 6, or from about pH 4 to 5.5, or from about pH 4 to 5, based on the selection of the particular detersive surfactant and/or other components.

Non-limiting examples

The shampoo compositions illustrated in the following examples can be prepared by conventional formulation and mixing methods. Unless otherwise indicated, all exemplified amounts are listed as weight percentages based on the active substance and do not include trace amounts of substances such as diluents, preservatives, colored solutions, imaginary ingredients, botanical drugs, and the like. All percentages are by weight unless otherwise indicated.

Results