阅读说明：本技术 高介电温度稳定兼具储能特性的钛酸铋钠基无铅铁电陶瓷材料及其制备方法 (Sodium bismuth titanate based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage characteristic and preparation method thereof ) 是由 杨祖培 周启媛 晁小练 彭战辉 于 2021-09-14 设计创作，主要内容包括：本发明公开了一种高介电温度稳定兼具储能特性的钛酸铋钠基无铅铁电陶瓷材料及其制备方法,该陶瓷材料的通式为(1-x)Bi-(0.5)Na-(0.5)TiO-(3)-xCaSnO-(3),其中x的取值为0.10～0.15。本发明通过配料、球磨、预烧、过筛、压片、烧结制备而成。本发明制备方法简单、成本低廉、重复性好、成品率高。其中x＝0.12时,陶瓷材料在基准温度下的介电常数为ε-(r150℃)＝840、介电损耗tanδ-(150℃)＝0.003,在-94～500℃的温度范围内,容温变化率满足TCC-(150℃)≤±15％,其介电常数随温度变化小,具有优异的温度稳定性,同时具有好的储能性能。(The invention discloses a sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property and a preparation method thereof, wherein the general formula of the ceramic material is (1-x) Bi 0.5 Na 0.5 TiO 3 ‑xCaSnO 3 Wherein the value of x is 0.10-0.15. The invention is prepared by batching, ball milling, presintering, sieving, tabletting and sintering. The preparation method is simple, low in cost, good in repeatability and high in yield. Wherein x is 0.12, the dielectric constant of the ceramic material at the reference temperature is ε r150℃ 840, dielectric loss tan δ 150℃ 0.003, and the change rate of the capacity temperature meets TCC in a temperature range of-94 to 500 DEG C 150℃ Less than or equal to +/-15%, small change of dielectric constant with temperature, and excellent temperatureHigh stability and high energy-storing performance.)

1. A sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property is characterized in that: the general formula of the ceramic material is (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Wherein the value of x is 0.10-0.15。

2. The sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property as claimed in claim 1, wherein: the value of x is 0.12, the high dielectric temperature stability range of the ceramic material is-100-500 ℃, the dielectric constant is 800-1000 at the reference temperature of 150 ℃, and the dielectric loss is 0.001-0.010.

3. A method for preparing the sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property as claimed in claim 1, characterized in that it comprises the following steps:

(1) ingredients

According to (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Respectively weighing CaCO with the purity of over 98.00 percent and the purity of over 99.00 percent₃、SnO₂Mixing Na₂CO₃、Bi₂O₃、TiO₂Mixing, filling into nylon can, and mixing with CaCO₃、SnO₂Mixing uniformly, putting into another nylon tank, then taking zirconium balls as grinding balls and absolute ethyl alcohol as a ball milling medium, fully mixing and ball milling for 20-24 hours, separating the zirconium balls, drying at 60-90 ℃ for 12-24 hours, grinding with a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Mixture and CaSnO₃Mixing;

(2) pre-firing

Bi obtained in the step (1)_0.5Na_0.5TiO₃Mixture and CaSnO₃The mixture is respectively placed in an alumina crucible, compacted by an agate rod and covered by a cover, and Bi is added_0.5Na_0.5TiO₃Pre-burning the mixture for 2 to 4 hours at 850 to 950 ℃, and then carrying out CaSnO₃Pre-burning the mixture at 1100-1300 ℃ for 8-12 hours, then naturally cooling to room temperature, grinding with a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Pre-burning powder;

(3) secondary ball milling

Bi obtained in the step (2)_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Putting the pre-sintered powder into a nylon tank, fully mixing and ball-milling for 20-24 hours, drying for 12-24 hours at the temperature of 60-90 ℃, grinding by using a mortar, and sieving by using a 180-mesh sieve to obtain (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Mixing;

(4) tabletting

Mixing the (1-x) Bi of the step (3)_0.5Na_0.5TiO₃-xCaSnO₃Pressing the mixture into a cylindrical blank by using a powder tablet press, and then carrying out cold isostatic pressing for 5-7 minutes under the pressure of 150-200 MPa;

(5) pressureless closed sintering

And (2) placing the cylindrical blank on a zirconium oxide flat plate, placing the zirconium oxide flat plate in an alumina closed sagger, heating to 1000-1200 ℃ at the heating rate of 2-5 ℃/min, sintering at the constant temperature for 2-4 hours, and naturally cooling to room temperature along with a furnace to prepare the bismuth sodium titanate-based lead-free ferroelectric ceramic material.

4. The method for preparing the sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property as claimed in claim 3, wherein: in the step (5), the cylindrical blank is placed on a zirconia flat plate, the zirconia flat plate is placed in an alumina closed sagger, the temperature is raised to 1170 ℃ at the heating rate of 3 ℃/minute, the cylindrical blank is sintered for 3 hours at constant temperature, and the cylindrical blank is naturally cooled to the room temperature along with the furnace.

Technical Field

The invention belongs to the technical field of ceramic materials, and particularly relates to a sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage characteristics and a preparation method thereof.

Background

The human society has entered the informatization process with the continuous development of science and technology, the rapid development of electronic science and technology and the wide application of products thereof, and the research and development of electronic functional ceramics are accelerated. The ceramic capacitor has the characteristics of small volume, large specific volume, high integration, low cost and the like, and is widely applied to various electronic industries. However, the working environment in the application field is complicated, and it is increasingly difficult to meet the current use requirements of electronic products, for example, the working temperature generally required by an automobile control system reaches more than 150 ℃, the temperature range of the working environment in some fields is more strict, and some fields are even far higher than the conventional working temperature, for example, the industrial fields of national defense, manned aerospace, rocket satellites, oil drilling and the like. Such electronic devices require not only capacitors with high dielectric properties, but also good temperature stability over a wide temperature range. Therefore, the search and development of lead-free high-dielectric-temperature stable ceramic materials for industrialization has become one of the hot spots. Bi_0.5Na_0.5TiO₃The base dielectric ceramic has a high Curie temperature (T)_c520 ℃), is insensitive to sintering atmosphere, is insensitive to environmental humidity, and has good repeatability of preparation process. So that it is currently used as an excellent high-temperature dielectric material and Bi_0.5Na_0.5TiO₃The phase structure of the base ceramic has adjustability, and when the ceramic presents a relaxation ferroelectric phase, the base ceramic has better energy storage performance. In the development of high-quality dielectric materials, high dielectric temperature stability and high energy storage are equally important. At present, the application of high dielectric temperature stability and high energy storage property is rarely reported.

Disclosure of Invention

The invention aims to provide a sodium bismuth titanate-based lead-free ferroelectric ceramic material with high dielectric temperature stability and energy storage property, and a preparation method with simple process, good repeatability and low cost.

For the above purpose, the ceramic material of the present invention has the general formula (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Wherein the value of x is 0.10-0.15, and preferably the value of x is 0.12.

The preparation method of the bismuth sodium titanate based lead-free ferroelectric ceramic material comprises the following steps:

1. ingredients

According to (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Respectively weighing CaCO with the purity of over 98.00 percent and the purity of over 99.00 percent₃、SnO₂Mixing Na₂CO₃、Bi₂O₃、TiO₂Mixing, filling into nylon can, and mixing with CaCO₃、SnO₂Mixing uniformly, putting into another nylon tank, then taking zirconium balls as grinding balls and absolute ethyl alcohol as a ball milling medium, fully mixing and ball milling for 20-24 hours, separating the zirconium balls, drying at 60-90 ℃ for 12-24 hours, grinding with a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Mixture and CaSnO₃Mixing;

2. pre-firing

Bi obtained in step 1_0.5Na_0.5TiO₃Mixture and CaSnO₃The mixture is respectively placed in an alumina crucible, compacted by an agate rod and covered by a cover, and Bi is added_0.5Na_0.5TiO₃Pre-burning the mixture for 2 to 4 hours at 850 to 950 ℃, and then carrying out CaSnO₃Pre-burning the mixture at 1100-1300 ℃ for 8-12 hours, then naturally cooling to room temperature, grinding with a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Pre-burning powder;

3. secondary ball milling

Bi obtained in step 2_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Putting the pre-sintered powder into a nylon tank, fully mixing and ball-milling for 20-24 hours, drying for 12-24 hours at the temperature of 60-90 ℃, grinding by using a mortar, and sieving by using a 180-mesh sieve to obtain (1-x) Bi_0.5Na_0.5TiO₃-xCaSnO₃Mixing;

4. tabletting

Adding (1-x) Bi of step 3_0.5Na_0.5TiO₃-xCaSnO₃Pressing the mixture into a cylindrical blank by using a powder tablet press, and then carrying out cold isostatic pressing for 5-7 minutes under the pressure of 150-200 MPa;

5. pressureless closed sintering

And (3) placing the cylindrical blank on a zirconium oxide flat plate, placing the zirconium oxide flat plate in an alumina closed sagger, heating to 1000-1200 ℃ at the speed of 2-5 ℃/min, sintering at constant temperature for 2-4 hours, and naturally cooling to room temperature along with a furnace to prepare the bismuth sodium titanate-based lead-free ferroelectric ceramic material.

In the above step 5, the temperature is preferably raised to 1170 ℃ at a rate of 3 ℃/min and the sintering is carried out for 3 hours.

The invention has the following beneficial effects:

1. the invention passes through to Bi_0.5Na_0.5TiO₃Introducing a second component CaSnO into the matrix₃Thereby generating the effects of peak shift and peak pressure, causing the action effects of relaxation property and the like, and obtaining the high dielectric temperature stable type dielectric ceramic material with high dielectric constant and low capacitance temperature change rate.

2. The invention selects Bi_0.5Na_0.5TiO₃System for A site Ca²⁺Substituted, Sn at the B-position⁴⁺By substitution of Ca²⁺、Sn⁴⁺The introduction of the method reduces the grain size, improves the compactness of the ceramic, enables the ceramic to be gradually changed into a relaxor ferroelectric from a normal ferroelectric, and the Curie temperature to move towards the room temperature, is beneficial to obtaining a slender P-E curve, and finally obtains the ceramic material with better energy storage performance.

3. In the preparation process of the ceramic material, the invention adopts a two-step synthesis preparation method to ensure that the base material Bi_0.5Na_0.5TiO₃And a second component CaSnO₃The pure perovskite solid solution is formed, the generation of a second phase is avoided, and compared with a one-pot mixing preparation method, the preparation method disclosed by the invention can realize solid solution of the dopant and the matrix material to the greatest extent. In addition, an advanced cold isostatic pressing technology is used, so that the waste of samples is avoided, and the preparation period of the ceramic is shortened; meanwhile, the blank formed by cold isostatic pressing has high density, uniform and consistent density and internal stress of the blankThe method has the advantages of small size, reduction of defects of cracking, layering and the like of the blank, guarantee of the quality of the ceramic, and establishment of a foundation for excellent experimental results.

Drawings

FIG. 1 is an XRD pattern of the ceramic materials prepared in examples 1-3 and comparative example.

FIG. 2 is a graph of the dielectric constant and dielectric loss for the comparative ceramic material at different test frequencies.

FIG. 3 is a graph of the dielectric constant and dielectric loss for the ceramic material prepared in example 3 at different test frequencies.

FIG. 4 is a graph showing Deltaε/ε at 1kHz for ceramic materials prepared in comparative examples and examples 1 to 3_150℃Curve as a function of temperature T.

FIG. 5 is a graph showing the change of dielectric constant with temperature at 1kHz for the ceramic materials prepared in comparative example and examples 1 to 3.

FIG. 6 is a graph showing the dielectric loss at 1kHz as a function of temperature for the ceramic materials prepared in comparative examples and examples 1 to 3.

FIG. 7 is a bipolar P-E curve of the ceramic material prepared in examples 1 to 3 under an electric field of 100 kV/cm.

FIG. 8 is a bipolar P-E curve of the ceramic material prepared in example 3 under different electric fields.

Detailed Description

The invention will be further described in detail with reference to the following figures and examples, but the scope of the invention is not limited to these examples.

Comparative example

1. Ingredients

According to Bi_0.5Na_0.5TiO₃2.5232gNa with a purity of over 98.00% is weighed respectively₂CO₃、11.0963g Bi₂O₃、7.2855g TiO₂Mixing Na₂CO₃、Bi₂O₃、TiO₂Mixing, loading into nylon tank, mixing with zirconium ball as grinding ball and anhydrous ethanol as ball milling medium, ball milling for 24 hr, separating zirconium ball, and grinding at 80 deg.CDrying at 12 deg.C for 12 hr, and grinding with mortar to obtain Bi_0.5Na_0.5TiO₃And (3) mixing.

2. Pre-firing

Bi obtained in step 1_0.5Na_0.5TiO₃Placing the mixture in an alumina crucible, compacting by an agate rod, covering, presintering at 850 ℃ for 2 hours to obtain Bi_0.5Na_0.5TiO₃Pre-sintering the powder.

3. Secondary ball milling

Bi obtained in step 2_0.5Na_0.5TiO₃The pre-sintered powder is filled into a nylon tank, fully mixed and ball-milled for 24 hours, dried for 12 hours at 80 ℃, ground by a mortar and sieved by a 180-mesh sieve.

4. Tabletting

The pre-sintered powder after passing through the 180-mesh sieve was pressed into a cylindrical blank having a diameter of 11.5mm and a thickness of 0.8mm by a powder tablet press, and then subjected to cold isostatic pressing under a pressure of 180MPa for 5 minutes.

5. Pressureless closed sintering

Placing the cylindrical blank on a zirconia flat plate, placing the zirconia flat plate in an alumina closed sagger, heating to 1150 ℃ at the rate of 3 ℃/min, sintering at constant temperature for 3 hours, naturally cooling to room temperature along with a furnace, and preparing the Bi with the component formula_0.5Na_0.5TiO₃The lead-free bismuth sodium titanate ferroelectric ceramic material.

Example 1

1. Ingredients

According to 0.90Bi_0.5Na_0.5TiO₃-0.10CaSnO₃2.1360g of Na with a purity of more than 98.00% were weighed out separately₂CO₃、9.3934g Bi₂O₃、6.4758g TiO₂And 0.8912g of CaCO with a purity of 99.00% or more₃、1.3364g SnO₂Mixing Na₂CO₃、Bi₂O₃、TiO₂Mixing, filling into nylon can, and mixing with CaCO₃、SnO₂Mixing, loading into another nylon tank, mixing with zirconium balls as grinding balls and absolute ethanol as ball-milling medium, ball-milling for 24 hr, separating zirconium balls, and ball-milling in a ball millDrying at 80 ℃ for 12 hours, grinding with a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Mixture and CaSnO₃And (3) mixing.

2. Pre-firing

Bi obtained in step 1_0.5Na_0.5TiO₃Mixture and CaSnO₃The mixture is respectively placed in an alumina crucible, compacted by an agate rod and covered by a cover, and Bi is added_0.5Na_0.5TiO₃Pre-burning the mixture at 850 ℃ for 2 hours, and then carrying out CaSnO₃The mixture is preburnt at 1200 ℃ for 12 hours, then naturally cooled to room temperature, and ground by a mortar to respectively obtain Bi_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Pre-sintering the powder.

3. Secondary ball milling

Bi obtained in step 2_0.5Na_0.5TiO₃Pre-sintered powder and CaSnO₃Putting the pre-sintered powder into a nylon tank, fully mixing and ball-milling for 24 hours, drying for 12 hours at 80 ℃, grinding by using a mortar, and sieving by using a 180-mesh sieve to obtain 0.90Bi_0.5Na_0.5TiO₃-0.10CaSnO₃And (3) mixing.

4. Tabletting

Mixing the 0.90Bi of the step 3_0.5Na_0.5TiO₃-0.10CaSnO₃The mixture was pressed into a cylindrical blank having a diameter of 11.5mm and a thickness of 0.8mm by a powder tablet press, and then subjected to cold isostatic pressing under a pressure of 180MPa for 5 minutes.

5. Pressureless closed sintering

Placing the cylindrical blank on a zirconia flat plate, placing the zirconia flat plate in an alumina closed sagger, heating to 1170 ℃ at the heating rate of 3 ℃/min, sintering at constant temperature for 3 hours, naturally cooling to room temperature along with a furnace, and preparing the material with the molecular formula of 0.90Bi_0.5Na_0.5TiO₃-0.10CaSnO₃The bismuth sodium titanate-based lead-free ferroelectric ceramic material.

Example 2

In step 1 of this example, 0.88Bi is used_0.5Na_0.5TiO₃-0.12CaSnO₃Respectively weighing 2.0834 with purity of over 98.00%g Na₂CO₃、9.1619g Bi₂O₃、6.3162g TiO₂And 1.0668g of CaCO with a purity of 99.00% or more₃、1.5598g SnO₂The other steps are the same as example 1, and the preparation component has a formula of 0.88Bi_0.5Na_0.5TiO₃-0.12CaSnO₃The bismuth sodium titanate-based lead-free ferroelectric ceramic material.

Example 3

In step 1 of this example, Bi is 0.85_0.5Na_0.5TiO₃-0.15CaSnO₃2.0049g of Na with a purity of more than 98.00% were weighed out separately₂CO₃、8.8169g Bi₂O₃、6.0784g TiO₂And 1.3285g of CaCO with a purity of 99.00% or more₃、1.9923g SnO₂The other steps are the same as example 1, and the preparation component has a formula of 0.85Bi_0.5Na_0.5TiO₃-0.15CaSnO₃The bismuth sodium titanate-based lead-free ferroelectric ceramic material.

One surface of each selected ceramic material prepared in the above examples 1 to 3 and comparative example is ground by 320-mesh sand paper, then ground by 800-mesh sand paper, finally polished to 0.5mm thickness by 1500-mesh sand paper and carborundum, cleaned by alcohol ultrasonic and rubbed, ground into powder, and subjected to XRD test by using a Nippon MiniFlex600 type diffractometer, 4294A, E4980A dielectric analyzer manufactured by Agilent technologies, and ferroelectric tester manufactured by Radiat corporation, USA, and the results are shown in FIGS. 1 to 8.

As can be seen from FIG. 1, the ceramics of all components formed a pure perovskite structure, no second phase was observed, indicating the second component CaSnO₃Is completely dissolved in Bi_0.5Na_0.5TiO₃In the host lattice of (1). From FIG. 2 and FIG. 3 are comparative example and CaSnO, respectively₃The dielectric thermogram of example 3 with the largest doping amount has a test temperature range of-150 to 500 ℃. As the frequency increases, the dielectric constant decreases, the dielectric loss increases, and the peak position gradually shifts from a high temperature to room temperature. Description with CaSnO₃The doping amount is increased to generate the polar nanometer microThe ceramic material has enhanced relaxivity and evolves into a relaxor ferroelectric, and along with CaSnO₃The curie temperature gradually moves to the room temperature by increasing the doping amount, that is, the relaxor ferroelectric phase is adjusted to be near the room temperature. FIG. 4 shows the ceramic material Δ ε/ε_150℃The rate of change of dielectric constant (. DELTA.. di-elect cons./ε) is generally considered to be a graph showing the change in temperature T_150℃) Not more than 15 percent, namely the ceramic material has good temperature stability of dielectric constant, and CaSnO₃The addition of (2) effectively widens the dielectric constant temperature stability of the ceramic material, and when x is 0.12, the ceramic material has the widest temperature stability range, namely-94 ℃ to 500 ℃, and shows good temperature stability. FIGS. 5 and 6 show the relative dielectric constant (. epsilon.) of the ceramic material at 1kHz_r) And dielectric loss (tan. delta.) as a function of temperature, it is clear that the addition of CaSnO₃The dielectric property of the system is obviously influenced. Compared with the comparative example, the ceramic material of example 2 has a larger relative dielectric constant (840) at the reference temperature of 150 ℃ and is accompanied by a lower dielectric loss (0.003), and the ceramic material of example 1-3 has the potential application in the high-temperature field. FIG. 7 is a P-E curve of a ceramic material under the same electric field, which can be obtained from the graph along with CaSnO₃The energy storage characteristic of the ceramic material is greatly improved by increasing the doping amount, and the electric hysteresis loop is changed from a circular shape at the beginning to a slender electric hysteresis loop with relaxation characteristic. FIG. 8 shows 0.85Bi_0.5Na_0.5TiO₃-0.15CaSnO₃The P-E curve of the ceramic material under different electric fields has the total energy storage density of 1.6J/cm when E is 160kV/cm³Effective energy storage density of 1.1J/cm³Thus, the material has better energy storage performance. Therefore, the sodium bismuth titanate-based ceramic material disclosed by the invention has high temperature stability and energy storage performance, and is expected to become a ceramic capacitor material widely applied under extreme conditions.