阅读说明：本技术 一种兰炭助燃剂 (Semi-coke combustion improver ) 是由 胡雅 廖致远 伍林 邵永杰 刘盈 杨小于 张保国 周义来 陈奡 于 2021-08-20 设计创作，主要内容包括：本发明提供了一种兰炭助燃剂,由以下重量比的组分混合而成：高锰酸钾1-3份、硝酸铵3-5份、氯化钙5-9份、十二烷基苯磺酸钠1-5份、碱式碳酸铜6-10份、活性炭30-50份。所述的兰炭助燃剂的各组分能过60目筛。所述的兰炭助燃剂与兰炭按照重量比3:100进行混合。本发明的兰炭助燃剂经实验验证,能大幅降低兰炭的着火点,减少兰炭的燃尽时间,使得兰炭燃烧完全充分,降低兰炭燃烧产生的氮氧化物和硫化物气体排放量,该兰炭助燃剂的应用效果好,使兰炭的燃烧效果以及燃烧后的清洁度都有所提高,实用性强,适合大规模应用。(The invention provides a semi-coke combustion improver which is prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon. Each component of the semi-coke combustion improver can pass through a 60-mesh sieve. The semi-coke combustion improver is mixed with the semi-coke according to the weight ratio of 3: 100. Experiments prove that the semi-coke combustion improver can greatly reduce the ignition point of the semi-coke, reduce the burnout time of the semi-coke, ensure the complete and sufficient combustion of the semi-coke, and reduce the discharge amount of nitrogen oxide and sulfide gas generated by the combustion of the semi-coke.)

1. The semi-coke combustion improver is characterized by being prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon.

2. The semi-coke combustion improver as set forth in claim 1, wherein: the granularity of each component of the semi-coke combustion improver can pass through a 60-mesh sieve.

3. The semi-coke combustion improver as set forth in claim 2, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 8-10 parts, and the active carbon is 30-50 parts.

4. The semi-coke combustion improver as set forth in claim 3, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 10 parts, and the active carbon is 30-50 parts.

5. The semi-coke combustion improver as set forth in claim 4, wherein: the potassium permanganate is 3 parts, the ammonium nitrate is 5 parts, the calcium chloride is 9 parts, the sodium dodecyl benzene sulfonate is 5 parts, the basic copper carbonate is 10 parts, and the active carbon is 30 parts.

Technical Field

The invention belongs to the technical field of flame retardants, and particularly relates to a semi-coke combustion improver.

Background

The basic characteristics of natural resources in China are rich coal, poor oil and little gas, which determines the important position of coal in primary energy. Coal is relatively abundant in storage compared to oil and natural gas, and accounts for 11.60% of world reserves. The total amount of coal resources in China is 5.6 trillion tons, wherein the proven reserves are 1 trillion tons, which account for 11 percent of the total reserves in the world, and the coal-producing large country in the world is the first coal-producing large country. However, as people continuously mine, the storage capacity of coal is less and less, and coal is a non-renewable resource, so that how to improve the combustion rate and the utilization rate of coal becomes a research focus.

Semi coke is a solid product of low-temperature destructive distillation step conversion in low-metamorphic coal, is determined to be a cleaner energy source, and has the characteristics of high fixed carbon, high chemical activity, low ash content, low aluminum, low sulfur, low phosphorus and the like. The semi-coke has better quality and combustion performance than anthracite, and has lower price than anthracite. The low-rank coal reserves in China are rich, the development of the semi-coke industry is the requirement of the national energy optimization strategy, the semi-coke has wide prospect and sufficient market. Based on the above excellent characteristics, the semi-coke has attracted high attention as an alternative fuel for domestic and foreign enterprises, and the semi-coke with low price is always explored as an alternative fuel. Although various coal additives and combustion improvers are available on the market, combustion improvers capable of really solving the problem of burning of semi-coke are not available, the semi-coke has a high burning ignition point, is extremely easy to burn incompletely and insufficiently in the burning process, and has high content of nitrogen oxides and sulfides generated by burning, so that environmental pollution is extremely easy to cause.

The invention patent with publication number CN102229835A provides an environment-friendly energy-saving combustion improver for coal, which can prolong the combustion time by adding various high-hardness solid metal oxides to ensure more complete combustion(ii) a The invention patents with publication numbers of CN106336929A, CN105132076A and CN111534356A use nano materials for combustion supporting, but the formulation components of the three patents are relatively complex, part of the substances are easy to generate toxic substances, the substances are easy to explode in the combustion process, and the industrial application effect is very limited; the invention patents with publication numbers of CN102453583A, CN102888260A and CN103146456A simplify the combustion improver of the industrial formula into four components, and although the invention patents have the characteristics of simple and convenient process, low cost and the like, the combustion improver has very limited combustion-supporting effect on the semi coke; the invention patent with publication number CN104987913A discloses a combustion improver added with activated carbon as a leavening agent and an adsorbent, wherein CaCl is added₂Can improve the calcium-sulfur ratio and effectively reduce SO₂The emission amount is reduced, but the formula cannot reduce the burning ignition point of the semi-coke; the invention patents with publication numbers CN104774671A, CN106753683A and CN108611155A add more than one oxidant in the combustion improver formula, but economically limit the application of the combustion improver in industry; in the invention patent with publication number CN 102517119A, sodium dodecyl benzene sulfonate with emulsification is added in the formula of combustion improver, but the industrial applicability of diesel oil and cyclopentadienylferrocene is not great in the formula.

Disclosure of Invention

In order to solve the problems in the background art, the invention provides a semi-coke combustion improver.

The semi-coke combustion improver is prepared by mixing the following components in percentage by weight: 1-3 parts of potassium permanganate, 3-5 parts of ammonium nitrate, 5-9 parts of calcium chloride, 1-5 parts of sodium dodecyl benzene sulfonate, 6-10 parts of basic copper carbonate and 30-50 parts of activated carbon.

Furthermore, the particle size of each component of the semi-coke combustion improver can pass through a 60-mesh sieve.

Further, the potassium permanganate accounts for 3 parts, the ammonium nitrate accounts for 5 parts, the calcium chloride accounts for 9 parts, the sodium dodecyl benzene sulfonate accounts for 5 parts, the basic copper carbonate accounts for 8-10 parts, and the activated carbon accounts for 30-50 parts.

Further, 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30-50 parts of active carbon.

Furthermore, the potassium permanganate accounts for 3 parts, the ammonium nitrate accounts for 5 parts, the calcium chloride accounts for 9 parts, the sodium dodecyl benzene sulfonate accounts for 5 parts, the basic copper carbonate accounts for 10 parts, and the activated carbon accounts for 30 parts.

When the semi-coke combustion improver is used, the semi-coke combustion improver and the semi-coke are mixed according to the weight ratio of 3: 100.

Compared with the prior art, the semi-coke combustion improver has the advantages that the types of the formula components are less, the formula component products are easy to obtain, and the cost is low; potassium permanganate added into the combustion improver has the characteristic of generating oxygen by decomposition, so that the peroxy combustion is realized during the burning of the semi coke, the proportion of incomplete burning of the semi coke is reduced, and the burnout rate is improved; calcium chloride and ammonium nitrate are added into the combustion improver, so that the ignition point of the semi-coke can be reduced, the ignition time can be shortened, and the calcium chloride can also combine with sulfur dioxide to play a role in reducing the emission of sulfides; basic copper carbonate is added into the combustion improver, and the basic copper carbonate is decomposed at high temperature to generate copper oxide, so that the reduction of nitric oxide into nitrogen and oxygen can be promoted, and the emission of nitrogen oxides is reduced; the combustion improver is added with sodium dodecyl benzene sulfonate and active carbon, and the sodium dodecyl benzene sulfonate is used as a surfactant to provide more adsorption sites for the active carbon to adsorb redundant nitric oxides and sulfides. Experiments prove that the semi-coke combustion improver can greatly reduce the ignition point of the semi-coke, reduce the burnout time of the semi-coke, ensure the complete and sufficient combustion of the semi-coke, and reduce the discharge amount of nitrogen oxide and sulfide gas generated by the combustion of the semi-coke.

Drawings

FIG. 1 is a TG curve of semi-coke combustion.

Detailed Description

The embodiments of the present invention will be described in detail with reference to the accompanying drawings, but the embodiments are not limited to the invention, and the advantages of the invention will be understood more clearly by the description. All modifications which can be derived or suggested by a person skilled in the art from the disclosure of the present invention are to be considered within the scope of the invention. The positional relationships described in the embodiments are all the same as those shown in the drawings, and other portions not described in detail in the embodiments are all the related art.

Example 1

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The ignition point of the combustion is averagely reduced by 63 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 22 min.

Example 2

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 66 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 4 percent, and the burnout time is averagely reduced by 22 min.

Example 3

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 3 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 2 percent, and the burnout time is averagely reduced by 25 min.

Example 4

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the fuel is averagely reduced by 68 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 27 min.

Example 5

The semi-coke combustion improver consists of the following components in percentage by mass: adding 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 30 parts by weight of active carbon into a pulverizer, pulverizing, and sieving with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 25 min.

Example 6

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 4 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 28 min.

Example 7

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 5 parts by weight of calcium chloride, 1 part by weight of sodium dodecyl benzene sulfonate, 10 parts by weight of basic copper carbonate and 40 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 60 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 25 min.

Example 8

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 7 parts by weight of calcium chloride, 3 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of basic copper carbonate and 30 parts by weight of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 32 min.

Example 9

The semi-coke combustion improver consists of the following components in percentage by mass: 1 part by weight of potassium permanganate, 5 parts by weight of ammonium nitrate, 9 parts by weight of calcium chloride, 5 parts by weight of sodium dodecyl benzene sulfonate, 8 parts by weight of basic copper carbonate and 30 parts by weight of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 27 min.

Example 10

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 40 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 70 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 3 percent, and the burnout time is averagely reduced by 27 min.

Example 11

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 3 percent, and the burnout time is averagely reduced by 30 min.

Example 12

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 3 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the gas burner is averagely reduced by 71 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 33 min.

Example 13

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The ignition point of the combustion is averagely reduced by 63 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 2 percent, and the burnout time is averagely reduced by 32 min.

Example 14

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 32 min.

Example 15

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 4 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 50 parts of activated carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 30 min.

Example 16

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the burner is averagely reduced by 68 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 31 min.

Example 17

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.

Example 18

The semi-coke combustion improver consists of the following components in percentage by mass: 2 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 40 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 65 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 34 min.

Example 19

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point of the burner is averagely reduced by 68 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 30 min.

Example 20

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 33 min.

Example 21

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 3 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 5 percent, and the burnout time is averagely reduced by 28 min.

Example 22

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 4 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 72 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 6 percent, and the burnout time is averagely reduced by 28 min.

Example 23

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 4 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 73 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 4 percent, and the burnout time is averagely reduced by 33 min.

Example 24

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 74 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.

Example 25

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 5 parts of calcium chloride, 1 part of sodium dodecyl benzene sulfonate, 6 parts of basic copper carbonate and 30 parts of active carbon. Adding the mixture into a pulverizer to be pulverized and then sieving the pulverized mixture with a 60-mesh sieve to obtain a powdery combustion improver mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 62 ℃, the emission of nitrogen oxides and sulfide gases is averagely reduced by 5 percent, and the burnout time is averagely reduced by 34 min.

Example 26

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 7 parts of calcium chloride, 3 parts of sodium dodecyl benzene sulfonate, 8 parts of basic copper carbonate and 40 parts of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 69 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 2 percent, and the burnout time is averagely reduced by 34 min.

Example 27

The semi-coke combustion improver consists of the following components in percentage by mass: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 10 parts of basic copper carbonate and 30 parts of active carbon. Adding into a pulverizer, pulverizing, and sieving with 60 mesh sieve to obtain powdered mixture. And semi coke according to the weight ratio of 3:100, and mixing the components. The combustion ignition point is averagely reduced by 75 ℃, the emission of nitrogen oxide and sulfide gas is averagely reduced by 6%, and the burnout time is averagely reduced by 35 min.

As described in the above-mentioned examples 24 and 27, when the components in the combustion improver are: 3 parts of potassium permanganate, 5 parts of ammonium nitrate, 9 parts of calcium chloride, 5 parts of sodium dodecyl benzene sulfonate, 8-10 parts of basic copper carbonate and 30 parts of active carbon, and particularly when the basic copper carbonate is 10 parts by weight, the burning effect of the semi coke is best.

The burning test is carried out on the semi-coke added with the combustion improver of the embodiment 27 and the semi-coke, the experimental group is the semi-coke added with the combustion improver of the embodiment 27, the comparison group is the semi-coke, the TG curve is shown in figure 1, the ignition point of the semi-coke added with the combustion improver is reduced by about 74 ℃, the burn-up rate is improved by about 6 percent, and the burning effect of the semi-coke is obviously improved.

The preferred embodiments of the present invention have been described in detail with reference to the accompanying drawings and specific examples, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications can be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are within the protective scope of the present invention.