Multi-metal and microcrystalline glass mixing and melting equipment with non-ore-selection full-charging function

文档序号:1961475 发布日期:2021-12-14 浏览:18次 中文

阅读说明:本技术 一种不选矿全入炉的多金属与微晶玻璃混熔炼设备 (Multi-metal and microcrystalline glass mixing and melting equipment with non-ore-selection full-charging function ) 是由 赵凤宇 于 2018-05-16 设计创作,主要内容包括:本发明属于多金属冶炼领域,具体地说就是一种不选矿全入炉的多金属与微晶玻璃混熔炼设备,包括:第一炉室、第二炉室、第三炉室、第四炉室、第五炉室、隔墙、喷粉器孔、激光发射器孔、底插式电极、玻璃液、铁合金流液口、超重金属流液口、流液通道、加料口、炉体,炉体内腔通过四个竖向平行隔墙分成五个炉室:第一炉室、第二炉室、第三炉室、第四炉室、第五炉室,每个炉室的底部均安装环形排布的底插式电极;每个隔墙的上部开设火焰通道,每个隔墙的下部开设流液通道,相邻炉室之间分别通过火焰通道和流液通道相通。本发明可以解决现有技术中采矿、选矿要求较高,以及钒钛的分离困难等问题。(The invention belongs to the field of multi-metal smelting, in particular to multi-metal and glass ceramic mixed smelting equipment which is not subjected to mineral separation and is fed into a furnace completely, comprising: the furnace comprises a first furnace chamber, a second furnace chamber, a third furnace chamber, a fourth furnace chamber, a fifth furnace chamber, a partition wall, a powder sprayer hole, a laser emitter hole, a bottom-inserted electrode, molten glass, a ferroalloy liquid flow port, an overweight metal liquid flow port, a liquid flow channel, a feed port and a furnace body, wherein the inner cavity of the furnace body is divided into five furnace chambers through four vertical parallel partition walls: the furnace comprises a first furnace chamber, a second furnace chamber, a third furnace chamber, a fourth furnace chamber and a fifth furnace chamber, wherein bottom inserting electrodes which are annularly arranged are arranged at the bottom of each furnace chamber; the upper part of each partition wall is provided with a flame channel, the lower part of each partition wall is provided with a fluid channel, and adjacent furnace chambers are respectively communicated with each other through the flame channel and the fluid channel. The invention can solve the problems of high mining and mineral separation requirements, difficult vanadium-titanium separation and the like in the prior art.)

1. The utility model provides a many metals of non-ore selection full income stove and glass ceramics mixing and smelting equipment which characterized in that includes: first furnace chamber, second furnace chamber, third furnace chamber, fourth furnace chamber, fifth furnace chamber, partition wall, duster hole, laser emitter hole, bottom plug-in electrode, glass liquid, ferroalloy flow mouth, overweight metal flow mouth, flow liquid passageway, charge door, furnace body, specific structure is as follows:

the furnace body inner chamber is divided into five furnace chambers through four vertical parallel partition walls: the furnace comprises a first furnace chamber, a second furnace chamber, a third furnace chamber, a fourth furnace chamber and a fifth furnace chamber, wherein bottom inserting electrodes which are annularly arranged are arranged at the bottom of each furnace chamber; the upper part of each partition wall is provided with a flame channel, the lower part of each partition wall is provided with a fluid channel, and adjacent furnace chambers are respectively communicated with each other through the flame channel and the fluid channel;

arranging an iron alloy flow port, an overweight metal flow port and a feeding port on the side surface of the first furnace chamber, wherein the iron alloy flow port is higher than the overweight metal flow port; powder sprayer holes are formed in the upper spaces of the second furnace chamber and the fourth furnace chamber, and powder sprayers corresponding to the powder sprayer holes are respectively installed in the second furnace chamber and the fourth furnace chamber; laser emitter holes are formed in the upper space of the third furnace chamber, and four groups of laser emitters corresponding to the laser emitter holes are arranged in the third furnace chamber; and a cooling and bubbling device is arranged in the fifth furnace chamber and is used for clarifying the microcrystalline glass liquid.

2. The multi-metal and microcrystalline glass mixing and melting equipment which is not beneficiated and fully charged according to claim 1, wherein a furnace cover is arranged at the top of the furnace body, and a furnace bottom is arranged at the bottom of the furnace body.

3. The multi-metal and glass-ceramic mixing and melting equipment which is not subjected to mineral separation and is fed into a furnace completely according to claim 1, is characterized in that two powder sprayer holes are respectively formed in the left side and the right side of the upper space of the second furnace chamber and the fourth furnace chamber, the second furnace chamber and the fourth furnace chamber are respectively provided with a powder sprayer corresponding to the powder sprayer holes, and the powder sprayer of the second furnace chamber sprays an explosive agent and a catalyst to crack carbon dioxide and steam molecules to synthesize 'hydrogen carbon monooxide' ultra-combustion; the fourth furnace chamber powder sprayer sprays an adsorbent and a settling agent, and drops residual dioxin and carbon atoms in glass liquid, and the residual dioxin and the carbon atoms are mixed and melted into a glass forming object through electromagnetic stirring of the bottom insertion type electrode.

4. The multi-metal and glass-ceramic mixing and melting equipment which is not beneficiated and is fully charged into the furnace according to claim 1, characterized in that two laser emitter holes are respectively arranged on the left side and the right side of the upper space of a third furnace chamber, four groups of laser emitters corresponding to the laser emitter holes are arranged in the third furnace chamber, and the laser emitters continuously scan the inside of the furnace at 90 degrees and are used for the resynthesis and combustion of residual carbon and oxyhydrogen.

5. The multi-metal and microcrystalline glass mixing and melting equipment which is not beneficiated and is fully charged into the furnace according to claim 1, wherein the clarified glass liquid in the fifth furnace chamber flows out of a discharge hole at the rear part of the fifth furnace chamber, enters a water quenching pool, is discharged and quenched with water, and is made into a microcrystalline glass product through a forming machine; the residual low point gasified metal and hot gas in the fifth furnace chamber are pumped into the underground condensing chamber by a strong smoke extractor through a circulating flue to be forcedly reduced into light metal powder, and the light metal powder enters the flame in the fifth furnace chamber and is transmitted to the power generation boiler chamber through a pipeline.

6. The multi-metal and microcrystalline glass mixing and melting equipment which is not beneficiated and is fully charged into a furnace according to claim 1, wherein an overweight metal liquid flow port is positioned 4-6 cm away from the bottom of the furnace, has a cross-sectional dimension of 8-12 x 8-12 cm, and is used for flowing out overweight metal liquid with the density of more than 10 g/cc; the ferroalloy liquid flow port is located 20-30 cm away from the furnace bottom, the cross section of the ferroalloy liquid flow port is 8-12 multiplied by 8-12 cm, and the ferroalloy liquid flow port is used for flowing out molten metal with the density of 7-9.9 g/cc.

7. The multi-metal and microcrystalline glass mixing and melting equipment without mineral separation and feeding into the furnace completely according to claim 1, wherein production raw materials of the multi-metal and microcrystalline glass are fed into a first furnace chamber through a feeding port, the first furnace chamber is a sunken furnace chamber, a flow channel which is directly communicated with a second furnace chamber is located in the position 50-70 cm away from the bottom of the first furnace chamber in the middle of a partition wall, and the cross section of the flow channel is 20-40 x 20-40 cm.

8. The multi-metal and microcrystalline glass mixing and melting equipment for the whole non-mineral-separation charging furnace according to any one of claims 1 to 7, wherein when in use, the microcrystalline glass is a composite material with silicon dioxide, aluminum, magnesium and calcium as main raw materials, a metal nucleating agent vanadium and titanium are added during production, vanadium titano-magnetite is ground to 30-50 meshes of full components and is directly charged into the furnace for melting, the central temperature of a ring electrode of a bottom-inserted electric melting furnace is 2000-2200 ℃, the bottom-inserted electric melting furnace has an electromagnetic stirring function, and mineral powder with the particle size of 30-50 meshes is completely melted under the catalysis of nepheline for 3-5 minutes; because of the density difference, layering is generated in the first sunken furnace chamber, iron with high density and trace heavy metals are deposited on the bottom layer and flow out from an overweight metal flow port arranged at the bottom, and vanadium-titanium and silicon-aluminum-magnesium-calcium float on the upper layer and flow into the rear furnace chamber at a high position in sequence until additives with different functions sprayed into each furnace chamber are completed, and the additives flow into a discharge port of rear glass liquid after being mixed and melted.

9. The multi-metal and glass-ceramic mixing and melting equipment which is not beneficiated and is fully charged into the furnace according to claim 8, characterized in that for the light metal with low melting point, the light metal is gasified and discharged to the condensing chamber together with dust into the powerful air pump arranged in the fifth furnace chamber to be reduced into solid metal powder.

Technical Field

The invention belongs to the field of multi-metal smelting, and particularly relates to multi-metal and glass ceramic mixing and smelting equipment which is not subjected to mineral separation and is fed into a furnace completely.

Background

At present, the multi-metal smelting process needs to crush ores to about 200 meshes, and then the ores are made into pellets through flotation and magnetic separation and then are smelted in a furnace. Not only consumes a large amount of ore dressing investment, electric charge, water charge and labor charge, but also causes serious pollution to the environment. The main component of many minerals is mainly silicon dioxide, taking vanadium-titanium magnetite as an example, every 1 ton of crushed ore can magnetically separate 15 wt% of iron powder, which is rich ore, more than 80 wt% of iron powder is silicon-magnesium-calcium, the total content of vanadium and titanium is about 2 wt%, and the separation of vanadium and titanium is very difficult, and 75 wt% of vanadium and titanium can be obtained only by multiple purifications by sulfuric acid method and electrolytic method.

The traditional metallurgical technology is from mining, smelting in a furnace and deslagging again, common metal deposits are formed by mixing several or even dozens of different elements, and almost no pure metal deposits exist, so that ores which are dozens of times of blasting are caused in mining, and great investment is used for mineral separation. The inventors have also found that metallurgical slags are typically water quenched to cool with thousands of temperatures, and if used as glass ceramics are of course heated to more than a thousand degrees celsius. And if a metal melting furnace and a glass-ceramic melting furnace are connected, depending on the density of metal and glass, do not allow layered outflow? After a decade of experiments, the inventor finally developed a new process and a new apparatus that can simultaneously produce 3 kinds of metals with different densities and high-performance glass ceramics.

Disclosure of Invention

The invention aims to provide multi-metal and glass ceramic mixed smelting equipment which is not subjected to mineral separation and is fed into a furnace completely, and solves the problems of high mining and mineral separation requirements, difficulty in vanadium and titanium separation and the like in the prior art.

The technical scheme of the invention is as follows:

the utility model provides a many metals of non-ore selection full entry stove and glass ceramics mixing and smelting equipment, includes: first furnace chamber, second furnace chamber, third furnace chamber, fourth furnace chamber, fifth furnace chamber, partition wall, duster hole, laser emitter hole, bottom plug-in electrode, glass liquid, ferroalloy flow mouth, overweight metal flow mouth, flow liquid passageway, charge door, furnace body, specific structure is as follows:

the furnace body inner chamber is divided into five furnace chambers through four vertical parallel partition walls: the furnace comprises a first furnace chamber, a second furnace chamber, a third furnace chamber, a fourth furnace chamber and a fifth furnace chamber, wherein bottom inserting electrodes which are annularly arranged are arranged at the bottom of each furnace chamber; the upper part of each partition wall is provided with a flame channel, the lower part of each partition wall is provided with a fluid channel, and adjacent furnace chambers are respectively communicated with each other through the flame channel and the fluid channel;

arranging an iron alloy flow port, an overweight metal flow port and a feeding port on the side surface of the first furnace chamber, wherein the iron alloy flow port is higher than the overweight metal flow port; powder sprayer holes are formed in the upper spaces of the second furnace chamber and the fourth furnace chamber, and powder sprayers corresponding to the powder sprayer holes are respectively installed in the second furnace chamber and the fourth furnace chamber; laser emitter holes are formed in the upper space of the third furnace chamber, and four groups of laser emitters corresponding to the laser emitter holes are arranged in the third furnace chamber; and a cooling and bubbling device is arranged in the fifth furnace chamber and is used for clarifying the microcrystalline glass liquid.

The multi-metal and microcrystalline glass mixing and melting equipment for non-mineral separation full-feeding furnace is characterized in that a furnace cover is arranged at the top of a furnace body, and a furnace bottom is arranged at the bottom of the furnace body.

The multi-metal and glass-ceramic mixed smelting equipment with non-beneficiation and full-entry furnace is characterized in that two powder sprayer holes are respectively formed in the left side and the right side of the upper space of a second furnace chamber and the right side of the upper space of a fourth furnace chamber, the second furnace chamber and the fourth furnace chamber are respectively provided with a powder sprayer corresponding to the powder sprayer holes, and the powder sprayers of the second furnace chamber spray an explosive and a catalyst for cracking carbon dioxide and steam molecules to synthesize 'hydrogen carbon monooxide' and perform excessive combustion; the fourth furnace chamber powder sprayer sprays an adsorbent and a settling agent, and drops residual dioxin and carbon atoms in glass liquid, and the residual dioxin and the carbon atoms are mixed and melted into a glass forming object through electromagnetic stirring of the bottom insertion type electrode.

The multi-metal and microcrystalline glass mixing and melting equipment for non-beneficiation full-feeding furnace is characterized in that two laser emitter holes are respectively formed in the left side and the right side of the upper space of a third furnace chamber, four groups of laser emitters corresponding to the laser emitter holes are installed in the third furnace chamber, and the laser emitters continuously scan the interior of the furnace at 90 degrees and are used for resynthesis and combustion of residual carbon and oxyhydrogen.

In the mixed smelting equipment for the non-beneficiation fully-fed furnace for the multi-metal and microcrystalline glass, the clarified glass liquid in the fifth furnace chamber flows out of a discharge port at the rear part of the fifth furnace chamber and enters a water quenching tank for discharging and water quenching, and a microcrystalline glass product is prepared by a forming machine; the residual low point gasified metal and hot gas in the fifth furnace chamber are pumped into the underground condensing chamber by a strong smoke extractor through a circulating flue to be forcedly reduced into light metal powder, and the light metal powder enters the flame in the fifth furnace chamber and is transmitted to the power generation boiler chamber through a pipeline.

The non-beneficiation full-charging multi-metal and microcrystalline glass mixing and melting equipment is characterized in that an overweight metal liquid flowing port is positioned 4-6 cm away from the furnace bottom, the cross section size of the overweight metal liquid flowing port is 8-12 multiplied by 8-12 cm, and the overweight metal liquid flowing port is used for flowing out of overweight metal liquid with the density of more than 10 g/cc; the ferroalloy liquid flow port is located 20-30 cm away from the furnace bottom, the cross section of the ferroalloy liquid flow port is 8-12 multiplied by 8-12 cm, and the ferroalloy liquid flow port is used for flowing out molten metal with the density of 7-9.9 g/cc.

The multi-metal and microcrystalline glass mixed smelting equipment with no ore dressing and full furnace feeding is characterized in that production raw materials of multi-metal and microcrystalline glass are fed into a first furnace chamber through a feeding port, the first furnace chamber is a sunken furnace chamber, a liquid flowing channel which is formed by the first furnace chamber and a second furnace chamber in a direct connection mode is located at a position 50-70 cm away from the bottom of the first furnace chamber in the middle of a partition wall, and the cross section of the liquid flowing channel is 20-40 multiplied by 20-40 cm.

When the multi-metal and microcrystalline glass mixed smelting equipment which is not subjected to mineral separation and is fed into a furnace completely is used, the microcrystalline glass is a composite material taking silicon dioxide, aluminum, magnesium and calcium as main raw materials, a metal nucleating agent vanadium and titanium are added during production, vanadium-titanium magnetite ore is ground to 30-50 meshes of total components and directly fed into the furnace for smelting, the central temperature of an annular electrode of a bottom-inserted electric melting furnace is 2000-2200 ℃, the electromagnetic stirring function is provided, and mineral powder with the particle size of 30-50 meshes is completely smelted under the catalysis of nepheline for 3-5 minutes; because of the density difference, layering is generated in the first sunken furnace chamber, iron with high density and trace heavy metals are deposited on the bottom layer and flow out from an overweight metal flow port arranged at the bottom, and vanadium-titanium and silicon-aluminum-magnesium-calcium float on the upper layer and flow into the rear furnace chamber at a high position in sequence until additives with different functions sprayed into each furnace chamber are completed, and the additives flow into a discharge port of rear glass liquid after being mixed and melted.

The multi-metal and microcrystalline glass mixing and melting equipment which is not subjected to beneficiation and is fed into the furnace completely can gasify scattered light metal with low melting point, and the gasified light metal and the dust enter a strong air extractor arranged in a fifth furnace chamber together to be discharged into a condensing chamber to be reduced into solid metal powder.

The invention has the advantages and beneficial effects that:

1. the invention provides a furnace with multiple purposes, which not only saves the investment of a smelting furnace, but also can not select impurities and content of raw materials, can achieve the standard of high-grade products by artificially adding a regulator according to the performance requirements of the products as long as the test is accurate, does not discharge waste residues, waste gases and waste water, and belongs to a clean production process.

2. The invention only needs to crush the ore to about 40 meshes, and can directly feed the ore into the furnace in full composition, and only the grinding cost is saved by 75 percent when the ore is ground to 200 meshes and then magnetically separated or floated, and the invention has no selection of the components, no purification of impurities, no low-grade stripping layer and ore dressing tailings, can save 90 percent of the land acquisition cost of the mine, and reduce 95 percent of the environmental damage.

Drawings

FIG. 1 is a schematic structural view of the melting apparatus of the present invention.

FIG. 2 is a schematic external view of the melting apparatus of the present invention.

In the figure, 1 a first furnace chamber; 2 a second furnace chamber; 3 a third furnace chamber; 4 a fourth furnace chamber; 5 a fifth furnace chamber; 6, partition walls; 7, a duster hole; 8 laser emitter holes; 9 bottom plug-in electrodes; 10, glass liquid; 11 ferroalloy liquid flow ports; 12 an extra heavy metal tapping; 13 water quenching pool; 14 a flow channel; 15, a furnace bottom; 16 furnace covers; 17 a feed inlet; 18 a discharge hole; 19 furnace body; 20 a viewing port; 21 flame-throwing port.

Detailed Description

As shown in figures 1-2, the multi-metal and glass-ceramic mixed smelting equipment of the invention which is not beneficiated and is fully charged into the furnace adopts a bottom-inserting type electric melting furnace, and mainly comprises: the furnace comprises a first furnace chamber 1, a second furnace chamber 2, a third furnace chamber 3, a fourth furnace chamber 4, a fifth furnace chamber 5, a partition wall 6, a powder sprayer hole 7, a laser emitter hole 8, a bottom-inserted electrode 9, molten glass 10, a ferroalloy liquid flow port 11, an overweight metal liquid flow port 12, a water quenching tank 13, a liquid flow channel 14, a furnace bottom 15, a furnace cover 16, a charging hole 17, a discharging hole 18, a furnace body 19 and the like, and has the following specific structures:

the top of furnace body 19 sets up bell 16, and the bottom of furnace body 19 sets up stove bottom 15, and furnace body 19 inner chamber is divided into five furnace chambers through four vertical parallel partition walls 6: the furnace comprises a first furnace chamber 1, a second furnace chamber 2, a third furnace chamber 3, a fourth furnace chamber 4 and a fifth furnace chamber 5, wherein bottom insertion type electrodes 9 which are annularly arranged are arranged at the bottom of each furnace chamber. The upper part of each partition wall 6 is provided with a flame channel, the lower part of each partition wall 6 is provided with a fluid channel 14, the adjacent furnace chambers are respectively communicated with the fluid channel 14 through the flame channel, and the cross section of the fluid channel 14 is 30 multiplied by 30 cm.

An iron alloy flow port 11, an overweight metal flow port 12 and a feeding port 17 are arranged on the side surface of the first furnace chamber 1, the iron alloy flow port 11 is higher than the overweight metal flow port 12, the overweight metal flow port 12 is positioned at a position which is only 5 cm away from the furnace bottom, the cross section size is 10 multiplied by 10 cm, and the overweight metal flow port is used for flowing out overweight metal liquid with the density of more than 10 g/cubic cm; the ferroalloy liquid flow port 11 is positioned 25 cm away from the furnace bottom, has the cross section size of 10 multiplied by 10 cm and is used for flowing out molten metal with the density of 7-9.9 g/cubic cm; in addition, a feeding port 17, an observation port 20 and a fire-spraying port 21 are respectively arranged on one side surface of a furnace body 19 of the electric melting furnace, materials (multi-metal and microcrystalline glass production raw materials) are fed through the feeding port 17 and are sent into a first furnace chamber 1, the first furnace chamber 1 is a sunken furnace chamber, and a flow channel 14 which is directly communicated with the first furnace chamber 1 and a second furnace chamber 2 is positioned in the middle of a partition wall 6 and is 60 cm away from the bottom of the first furnace chamber 1; the observation was made through the observation port 20, and the flaming was performed through the flaming port 21 (see fig. 2).

Two powder sprayer holes 7 are respectively arranged at the left side and the right side of the upper space of the second furnace chamber 2 and the fourth furnace chamber 4, the second furnace chamber 2 and the fourth furnace chamber 4 are respectively provided with a powder sprayer corresponding to the powder sprayer holes 7, and the powder sprayer of the second furnace chamber 2 sprays an explosive and a catalyst for cracking carbon dioxide and steam molecules to synthesize 'hydrogen carbon monooxygen' over-value combustion; the fourth furnace chamber 4 is sprayed with an adsorbent and a settling agent, and the residual dioxin and carbon atoms fall into the molten glass 10 and are mixed and melted into a glass formation through electromagnetic stirring of the bottom-inserted electrode 9.

Two laser emitter holes 8 are respectively formed in the left side and the right side of the upper space of the third furnace chamber 3, four groups of laser emitters corresponding to the laser emitter holes 8 are installed in the third furnace chamber 3, and the laser emitters continuously scan the laser into the furnace at 90 degrees and are used for resynthesis and combustion of residual carbon and oxyhydrogen.

The fifth furnace chamber 5 is provided with a cooling and bubbling device for clarifying the microcrystalline glass liquid 10, the clarified glass liquid 10 flows out of a discharge port 18 at the rear part of the fifth furnace chamber 5 and enters a water quenching tank 13 for discharging and water quenching, and a microcrystalline glass product is prepared by a forming machine; the residual low point gasified metal and hot gas in the fifth furnace chamber 5 are pumped into the underground condensing chamber by a strong smoke extractor through a circulating flue to be forcibly reduced into light metal powder. And the flame entering the fifth furnace chamber 5 is transmitted to the power generation boiler chamber through the pipeline.

When in use, the microcrystalline glass is a composite material taking silicon dioxide, aluminum, magnesium and calcium as main raw materials, a metal nucleating agent needs to be added during manufacturing, and vanadium and titanium are the best nucleating agents. The invention uses a multi-chamber bottom-inserting type electric melting furnace, vanadium titano-magnetite only is ground to 40 meshes, and the vanadium titano-magnetite can be directly fed into the furnace for melting, because the central temperature of a ring electrode of the bottom-inserting type electric melting furnace reaches 2200 ℃, and the bottom-inserting type electric melting furnace has the electromagnetic stirring function, and the ore powder with the grain size of 40 meshes is nepheline (the nepheline is aluminosilicate containing 15 wt% of sodium and potassium, and the chemical composition of the nepheline is KNa3(AlSiO4)4) The full melting can be realized after 4 minutes of catalysis, because of density difference, layering is generated in the first sinking furnace chamber, iron with high density and trace heavy metals are deposited on the bottom layer and flow out from an overweight metal flow port 12 arranged at the bottom, and vanadium titanium, silicon-aluminum-magnesium-calcium and the like float on the upper layer and flow into the furnace chambers behind the high position in sequence until additives with different functions sprayed into each furnace chamber are finished, and the additives flow to a discharge port 18 of the following molten glass 10 after mixed melting. In addition, for the scattered light metals with low melting points, the light metals are gasified and enter the strong air pump arranged in the fifth furnace chamber 5 together with dust to be discharged to the condensing chamber to be reduced into solid metal powder, and the light metals are all valuable products. The whole smelting process has no discharge of waste gas, waste water and waste residue, and belongs to a completely clean process.

The results of the examples show that the microcrystalline glass raw material adopted by the invention is only needed to be coarsely ground to 40 meshes, and the grinding cost can be saved by 75% when the microcrystalline glass raw material is ground to 200 meshes with mineral dressing; the raw material components are not selected, the impurities are not purified, the scale of damage to vegetation of mines can be greatly reduced, and a new channel is developed for protecting the ecological environment.

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