阅读说明：本技术 一种高炉协同处置铁质危废压块的新工艺方法 (Novel process method for cooperatively treating iron hazardous waste briquettes by blast furnace ) 是由 徐建根 曾其雄 曾成勇 罗文� 周浩亨 鄢永普 余梦超 张正冰 王莉萍 于 2021-08-23 设计创作，主要内容包括：本发明公开了一种高炉协同处置铁质危废压块的新工艺方法,首先,对铁质危废hw49、hw08、hw09进行预处理,铁质危废hw49、hw08、hw09进行混合压块处理,使其符合使用要求。然后,将所述预处理后的所述铁质危废hw49、hw08、hw09与炼铁原料混合,最后进入高炉。本发明的高炉协同处置铁质危废压块的新工艺方法,无需改变原有的高炉的工艺,处理工艺技术和操作要求简单,具有燃烧完全,处置彻底,处置成本低,工艺和操作简单的优点。(The invention discloses a novel process method for cooperatively treating iron hazardous waste briquettes in a blast furnace, which comprises the steps of pretreating iron hazardous waste hw49, hw08 and hw09, and carrying out mixed briquetting treatment on the iron hazardous waste hw49, hw08 and hw09 to enable the iron hazardous waste briquettes to meet the use requirements. And then mixing the pretreated iron hazardous wastes hw49, hw08 and hw09 with iron-making raw materials, and finally feeding the mixture into a blast furnace. The novel process method for the blast furnace to cooperatively treat the iron hazardous waste briquettes does not need to change the original process of the blast furnace, has simple treatment process technology and operation requirements, and has the advantages of complete combustion, thorough treatment, low treatment cost and simple process and operation.)

1. A novel process method for the blast furnace to cooperatively treat iron hazardous waste briquettes is characterized by comprising the following steps: the iron hazardous waste comprises hw49, hw08 and hw09, and the process method comprises the following steps:

(1) pretreatment: identifying, mixing and briquetting the iron hazardous wastes hw49, hw08 and hw09, and performing film covering treatment, wherein the mass mixing ratio of hw49, hw08 and hw09 is 2: 1: 1;

(2) proportioning according to the proportion: mixing the pretreated iron dangerous waste hw49, hw08 and hw09 with raw materials, wherein the proportion of the iron dangerous waste hw49, hw08 and hw09 is lower than 10 percent of that of the raw materials;

(3) blast furnace ironmaking: the mixed iron hazardous wastes hw49, hw08 and hw09 and raw materials enter a blast furnace for smelting;

(3.1) heating the blast furnace: and carrying out primary heating treatment on the iron dangerous wastes hw49, hw08 and hw09 during smelting in the blast furnace until the smelting is finished.

2. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 1, characterized in that: the pretreatment in the step (1) comprises the following steps:

(1.1) incoming material identification: identifying the iron dangerous wastes hw49, hw08 and hw09, and transporting the iron dangerous wastes hw49, hw08 and hw09 meeting the requirements to a pretreatment site in a closed manner;

(1.2) rinsing: after the iron dangerous wastes hw49, hw08 and hw09 are transported to a pretreatment site in a closed manner, the site where the iron dangerous wastes hw49, hw08 and hw09 are stacked is washed, and sewage enters a sewage collection system;

(1.3) mixing: the iron hazardous waste hw08 and hw09 are filled into the iron hazardous waste hw49 in proportion;

(1.4) briquetting coating: and briquetting the mixed iron hazardous wastes hw49, hw08 and hw09, and coating a film.

3. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 1, characterized in that: the initial temperature in the blast furnace is 2200 ℃ and the maximum treatment temperature in the blast furnace is 2400 ℃.

4. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 2, characterized in that: the addition amount of the blast furnace is less than 10 percent.

5. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 1, characterized in that: the iron dangerous waste hw49, hw08 and hw09 are waste hollow iron barrels, and the oil content of the wall built in the hollow iron barrels is less than 5%.

6. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 2, characterized in that: the volume of the compact is 100 x 100mm to 150 x 150 mm.

7. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 2, characterized in that: the number of layers of the film covering treatment is more than or equal to three.

8. The new process method for the blast furnace to cooperatively dispose the ferruginous hazardous waste briquette as set forth in claim 1, characterized in that: the pretreatment also includes organic waste gas treatment.

Technical Field

The invention relates to the field of chemical production, in particular to a novel process method for cooperatively treating iron hazardous waste briquettes by a blast furnace.

Background

The packing container for mineral oil, paint, emulsion, organic solvent and other matter is used as the waste container for polluting toxic and inflammable dangerous waste. The metal product machining industry honing, grinding and polishing processes, and the oily metal scraps which are dangerous wastes and generated in the machining process by using cutting oil or cutting fluid belong to dangerous wastes. The iron waste paint bucket and the oily iron metal chips are characterized in that the components mainly comprise Fe and other pollutants, and the main components are consistent with that of the molten iron of a blast furnace product.

Introduction of the prior disposal technology:

resource utilization:

and the hw49 iron waste barrel is refurbished and sold after being cleaned, shaped, shot-blasted and painted. The advantages are that: resource utilization and relatively mature process. The disadvantages are as follows: the waste barrel is relatively intact, and basically has no recycling value on deformed or damaged waste barrels; large sewage quantity, low efficiency, small treatment capacity and low productivity.

The Hw49 iron waste barrel is renovated and sold after the processes of cover cutting, liquid leaching by heating, sand blasting and oil removing, shaping, shot blasting, capping and paint spraying. The advantages are that: resource utilization, relatively mature process and no sewage treatment. The disadvantages are as follows: the process is long, the waste barrel is relatively intact, the treatment capacity is small, the efficiency is low, the treatment capacity is small, and the economic benefit is general.

And allowing the Hw49 to enter a blast furnace for smelting after liquid leaching and briquetting. The advantages are that: large treatment capacity and resource utilization. The disadvantages are as follows: about 2 percent of the leachate needs to be treated by a professional disposal unit, which wastes the characteristics of an iron packaging container.

And the oil-bearing iron metal chips Hw08 and Hw09 need mechanical liquid leaching, centrifugal drying for deoiling, iron wood shavings adding, mechanical briquetting and blast furnace smelting. The advantages are that: resource utilization and mature process. The disadvantages are as follows: more than 50% of iron wood shavings are added to be pressed into blocks for forming, more than 50% of centrifugal leaching liquid is still dangerous waste, and needs to be treated by professional treatment enterprises.

Disclosure of Invention

The invention aims to solve the technical problem of providing a novel process method for the blast furnace to cooperatively treat iron hazardous waste briquettes aiming at the defects of the prior art.

The invention realizes the purpose through the following technical scheme: a novel process method for cooperatively treating iron hazardous waste briquettes by a blast furnace comprises the following steps: the iron hazardous waste comprises hw49, hw08 and hw09, and the process method comprises the following steps:

(1) pretreatment: identifying, mixing and briquetting the iron hazardous wastes hw49, hw08 and hw09, and performing film covering treatment, wherein the mass mixing ratio of hw49, hw08 and hw09 is 2: 1: 1;

(2) proportioning according to the proportion: mixing the pretreated iron dangerous waste hw49, hw08 and hw09 with raw materials, wherein the proportion of the iron dangerous waste hw49, hw08 and hw09 is lower than 10 percent of that of the raw materials;

(3) blast furnace ironmaking: the mixed iron hazardous wastes hw49, hw08 and hw09 and raw materials enter a blast furnace for smelting;

(3.1) heating the blast furnace: and carrying out primary heating treatment on the iron dangerous wastes hw49, hw08 and hw09 during smelting in the blast furnace until the smelting is finished.

As a further optimization scheme of the invention, the pretreatment of the step (1) comprises the following steps:

(1.1) incoming material identification: identifying the iron dangerous wastes hw49, hw08 and hw09, and transporting the iron dangerous wastes hw49, hw08 and hw09 meeting the requirements to a pretreatment site in a closed manner;

(1.2) rinsing: after the iron dangerous wastes hw49, hw08 and hw09 are transported to a pretreatment site in a closed manner, the site where the iron dangerous wastes hw49, hw08 and hw09 are stacked is washed, and sewage enters a sewage collection system;

(1.3) mixing: the iron hazardous waste hw08 and hw09 are filled into the iron hazardous waste hw49 in proportion;

(1.4) briquetting coating: and briquetting the mixed iron hazardous wastes hw49, hw08 and hw09, and coating a film.

As a further optimization scheme of the invention, the initial temperature in the blast furnace is 2200 ℃, and the maximum treatment temperature in the blast furnace is 2400 ℃.

In a further optimized scheme, the addition amount of the blast furnace is less than 10%.

According to the further optimization scheme, the iron dangerous waste hw49, hw08 and hw09 are waste empty iron barrels, and the oil content of the wall built in the empty iron barrels is less than 5%.

As a further preferred embodiment of the invention, the volume of the compact is 100 × 100mm to 150 × 150 mm.

According to a further optimization scheme, the number of layers of the film coating treatment is more than or equal to three.

As a further optimization of the present invention, the pretreatment further comprises organic waste gas treatment.

Compared with the prior art, the invention has the following beneficial effects:

the oily iron metal chips hw49, hw08 and hw09 are proportionally loaded into an iron waste barrel, and are pressed into a briquette and covered with a film to be used as a blast furnace raw material to be put into a furnace for ironmaking, so that the waste iron and the waste oil are recycled, the disposal quantity is large, and no residual material is left.

The equipment investment is less, the equipment investment is needed for pretreatment briquetting and film coating, and the blast furnace ironmaking process utilizes the original equipment.

The original process of the iron-making blast furnace is not changed, the process and the operation are simple, the disposal cost is basically zero, and the economic benefit is good.

The disposal temperature is up to 2400 ℃, the waste iron is completely melted into molten iron, a small amount of inorganic matters are completely subjected to slagging and vitrification, a small amount of organic matters are completely decomposed and combusted, and the disposal is thorough.

Iron hw49, hw08 and hw09 enter the main adhesive tape below the groove through a pressing block and a film, then enter the blast furnace, and are connected with a blast furnace environment dust removal system, so that the emission is up to the standard, and the environment is not polluted.

The slag flushing water of the blast furnace ironmaking process is recycled, is not discharged outside, and has no redundant pollution.

The mass mixing ratio of hw49, hw08 and hw09 is set as 2: 1: 1, ensuring better smelting effect and no more impurities.

Drawings

FIG. 1 is a schematic flow chart of a new process for the blast furnace co-processing of iron hazardous waste briquettes;

FIG. 2 is a schematic flow diagram of the pretreatment steps in the novel process for the blast furnace co-processing of iron-containing hazardous waste briquettes;

Detailed Description

The present application will now be described in further detail with reference to the drawings, it should be noted that the following detailed description is given for illustrative purposes only and is not to be construed as limiting the scope of the present application, as those skilled in the art will be able to make numerous insubstantial modifications and adaptations to the present application based on the above disclosure.

Examples

The new process method for the blast furnace to cooperatively treat the iron hazardous waste briquette has no additional equipment in the process flow of the blast furnace, and the pretreatment is additionally provided with partial equipment for briquetting. And (3) smelting the briquetting raw material mixed with the iron dangerous waste hw49, hw08 and hw09 in a blast furnace, wherein the iron dangerous waste hw49, hw08 and hw09 account for 0.14 percent of the whole raw material consumption ratio and are smaller in proportion.

The new process method for the blast furnace to cooperatively dispose the iron hazardous waste briquette as shown in fig. 1, wherein the iron hazardous waste comprises hw49, hw08 and hw09, and the process method comprises the following steps:

(1) pretreatment: and identifying, mixing and coating the iron hazardous wastes hw49, hw08 and hw09, wherein the volume of the briquette is 100 × 100mm-150 × 150mm, and the number of layers of coating treatment is more than or equal to three. And the mass mixing ratio of the hw49, the hw08 and the hw09 is 2: 1: 1. wherein the step (1) specifically comprises the following steps, as shown in fig. 2:

(1.1) incoming material identification: identifying the iron dangerous wastes hw49, hw08 and hw09, and transporting the iron dangerous wastes hw49, hw08 and hw09 meeting the requirements to a pretreatment site in a closed manner;

(1.2) rinsing: after the iron dangerous wastes hw49, hw08 and hw09 are transported to a pretreatment site in a closed manner, the site where the iron dangerous wastes hw49, hw08 and hw09 are stacked is washed, and sewage enters a sewage collection system;

(1.3) mixing: the iron hazardous waste hw08 and hw09 are filled into the iron hazardous waste hw49 in proportion;

(1.4) briquetting coating: and briquetting the mixed iron hazardous wastes hw49, hw08 and hw09, and coating a film.

(2) Proportioning according to the proportion: mixing the pretreated iron dangerous waste hw49, hw08 and hw09 with raw materials, wherein the proportion of the iron dangerous waste hw49, hw08 and hw09 is lower than 10 percent of that of the raw materials;

(3) blast furnace ironmaking: and (3) feeding the mixed iron hazardous wastes hw49, hw08 and hw09 and raw materials into a blast furnace for smelting.

(4.1) heating the blast furnace: and carrying out primary heating treatment on the iron dangerous wastes hw49, hw08 and hw09 during smelting in the blast furnace until the smelting is finished. The initial temperature in the blast furnace is 2200 ℃ and the maximum treatment temperature in the blast furnace is 2400 ℃. By raising the temperature, the smelting of other substances can be completed, and the energy consumption can be effectively reduced by stage smelting. In the treatment process, the tail gas enters a tail gas treatment system and is discharged after being treated to be qualified.

In summary, in this embodiment, the waste iron bucket is required to be an empty iron bucket, only the wall and the bottom of the empty iron bucket are allowed to be stained with part of the wall hanging residual liquid, and the oil content of the wall hanging in the empty iron bucket is less than 5%. The process comprises the steps of firstly transporting the iron dangerous wastes hw49, hw08 and hw09 to a designated site according to the regulations, then checking whether the actual wastes are consistent with the wastes in the waste label and disposal contract according to the regulations of the hazardous waste transfer bill management method, and then judging whether the wastes can enter. In the briquetting process, the hw08 and hw09 are filled into an iron waste barrel hw49, and the mixing ratio of hw49, hw08 and hw09 is 2: 1: 1, pre-treating the briquettes to 100 × 100-. And finally, transporting the coke to a blast furnace tank by a special vehicle, loading the coke into a main adhesive tape under the blast furnace tank from a movable belt according to the batch number of the blast furnace, then feeding the coke into a main adhesive tape for feeding, and finally feeding the coke into the blast furnace. Wherein the adding amount of the pressed hw49, hw08 and hw09 is less than 10 percent of the raw materials. After blast furnace smelting, the scrap iron enters molten iron, the organic matter is partially volatilized and enters a blast furnace gas system to be used as fuel, and part of the fuel is combusted and heated after partial decomposition, distillation and coking in the blast furnace to replace part of the fuel.

The blast furnace in this example has an effective volume of 2500m³The original design has the production capacity of 400 kiloton/a and the actual yield of 460 kiloton/a. The furnace body is a thin lining structure integrating a short and fat type furnace body and a brick wall, a combined soft water closed circulating system, a double-rectangular iron tapping field, 3 tapholes, 30 air ports and three internal combustion type hot blast furnaces and one top combustion type hot blast furnace are adopted. The basic charge structure is: 80% of sintered coke, 20% of lump ore, 60% of factory dry quenching coke and 40% of outsourcing coke. 12800d/t of daily molten iron, 21000d/t of consumed ore, 2500t/d of consumed coke and 900t/d of consumed coal powder.

The blast furnace process flow of the invention has no additional equipment, and the iron materials hw49, hw08 and hw09 are pressed into blocks and coated with films and then directly enter the blast furnace to be smelted. The iron hw49, hw08 and hw09 briquetting treatment capacity is 30t/d, the iron hw49, hw08 and hw09 briquetting treatment capacity accounts for 0.14 percent of the whole ore consumption proportion, the proportion is extremely small, the fluctuation of total (Fe) components is about 0.05 percent, namely, the furnace entering grade after the materials are added is 58.55 percent under the assumption that the furnace entering grade of the blast furnace is all (Fe). The method meets the requirement of the blast furnace raw materials on the fluctuation of the raw materials. The product water slag, dry slag, slag flushing water, coal gas dedusting ash, dust under the groove and the like reach the danger removal and harmless requirements of hw49 after the test of the product. The iron materials of hw49, hw08 and hw09 are subjected to harmless treatment by utilizing high temperature (2100-2300 ℃) in the blast furnace smelting process, so that the requirement of the cooperative treatment of the iron materials of hw49, hw08 and hw09 entering the blast furnace is met.

In this embodiment, the blast furnace capacity, energy consumption, heavy metals of slag, heavy metals of water, and heavy metals of fly ash are monitored, and the data are as follows:

conditions of the furnace

Slag flushing water

Dry slag and granulated slag in front of furnace

	Slag sample mg/kg	Slag sample mg/kg	Slag sample mg/kg	Slag sample mg/kg
					Date	5.14	5.15	5.16	5.17
Hexavalent chromium
					Inorganic fluorides	3.20	3.65	3.25	3.75
Chloride ion	63	41	54	26
					Sodium salt	3450	3450	2750	3050
Potassium salt	4240	3240	2840	2700
					Lead (II)
Chromium (III)	3.28	4.33	5.42	2.21
					Zinc	4.41	9.81	8.42	4.73

Gas ash

	Gas ash mg/kg	Gas ash mg/kg	Gas ash mg/kg
				Date	5.14	5.15	5.16
Hexavalent chromium	ND	ND	ND
				Inorganic fluorides	65.6	79.7	69.8
Chloride ion	18300	16600	15700
				Sodium salt	1066	1157	1082
Potassium salt	2655	2455	2340
				Lead (II)	855	845	874
Chromium (III)	13.7	13.1	13.5
				Zinc	9348	10540	11730

Dust removal ash under groove

Environmental monitoring (5.14 and 5.17)

The above-described embodiments are merely illustrative of the preferred embodiments of the present invention and do not limit the spirit and scope of the present invention. Various modifications and improvements of the technical solutions of the present invention may be made by those skilled in the art without departing from the design concept of the present invention, and the technical contents of the present invention are all described in the claims.