阅读说明：本技术 一种铂单原子催化剂及其制备方法和应用 (Platinum monatomic catalyst and preparation method and application thereof ) 是由 马炜 王丽明 胡婷婷 周震 于 2021-11-11 设计创作，主要内容包括：本发明提供一种铂单原子催化剂,结构为Pt-Ni-(x)Fe-(1-x)(OH)-(2)/CNTs纳米片,其中x取值为1/5-1/2；由如下制备工艺制备得到：将经过氧化处理的碳纳米管溶解在去除氧气的去离子水中；将适量六亚甲基四胺、氟化铵、六水合氯化镍和四水合氯化亚铁溶解于步骤S1的溶液中,其中六水合氯化镍和四水合氯化亚铁中Ni与Fe的摩尔比为1-4:1；将步骤S2的混合溶液在密封的反应釜中反应,得到Ni-(x)Fe-(1-x)(OH)-(2)/CNTs催化剂；将适量的H-(2)PtCl-(6)·6H-(2)O加入步骤S3的Ni-(x)Fe-(1-x)(OH)-(2)/CNTs催化剂中,在室温下氧化得到铂单原子催化剂Pt-Ni-(x)Fe-(1-x)(OH)-(2)/CNTs；其中Pt和Fe的摩尔比为1:1-4。本发明提供的铂单原子催化剂,具有铂单原子负载量高,金属利用率高,催化活性好等特点可广泛应用于电解水、空气电池等领域。本发明还提供一种铂单原子催化剂的制备方法及在电解水中的应用。(The invention provides a platinum monatomic catalyst with a structure of Pt-Ni x Fe 1‑x (OH) 2 The CNTs nano-sheet, wherein x is 1/5-1/2; the preparation method comprises the following steps: dissolving the carbon nano tube subjected to oxidation treatment in deionized water without oxygen; dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1; reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni x Fe 1‑x (OH) 2 CNTs catalyst; adding appropriate amount of H 2 PtCl 6 ·6H 2 O addition to Ni of step S3 x Fe 1‑x (OH) 2 In a/CNTs catalyst, oxygen at room temperatureObtaining the Pt monatomic catalyst Pt-Ni by chemical reaction x Fe 1‑x (OH) 2 CNTs; wherein the molar ratio of Pt to Fe is 1: 1-4. The platinum monatomic catalyst provided by the invention has the characteristics of high platinum monatomic load, high metal utilization rate, good catalytic activity and the like, and can be widely applied to the fields of electrolytic water, air batteries and the like. The invention also provides a preparation method of the platinum monatomic catalyst and application of the platinum monatomic catalyst in electrolytic water.)

1. The platinum monatomic catalyst is characterized by having a structure of Pt-Ni_xFe_1-x(OH)₂The CNTs nano-sheet, wherein x is 1/5-1/2; the platinum monatomic catalyst is prepared by the following preparation process:

step S1, dissolving the carbon nano tube after oxidation treatment in the deionized water without oxygen;

step S2, dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1;

step S3, reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni_xFe_1-x(OH)₂CNTs catalyst;

step S4, adding appropriate amount of H₂PtCl₆·6H₂O addition to Ni of step S3_xFe_1-x(OH)₂In the CNTs catalyst, the platinum monoatomic catalyst Pt-Ni is obtained by oxidation at room temperature_xFe_1-x(OH)₂CNTs; wherein the molar ratio of Pt to Fe is 1: 1-4.

2. The platinum monatomic catalyst as recited in claim 1, wherein the amount of the carbon nanotubes is 0.2 to 1mg of the carbon nanotubes dissolved in 1ml of deionized water in step S1.

3. The platinum monatomic catalyst as recited in claim 1, wherein the reaction temperature is 120-160 ℃ and the reaction time is 6-8 hours in step S3.

4. The platinum monatomic catalyst as recited in claim 1, wherein the oxidation time is 12 to 36 hours in step S4.

5. A preparation method of a platinum monatomic catalyst is characterized by comprising the following steps:

step S1, dissolving the carbon nano tube after oxidation treatment in the deionized water without oxygen;

step S2, dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1;

step S3, reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni_xFe_1-x(OH)₂a/CNTs catalyst, wherein x is 1/5-1/2;

step S4, adding appropriate amount of H₂PtCl₆·6H₂O addition to Ni of step S3_xFe_1-x(OH)₂In the CNTs catalyst, the platinum monoatomic catalyst Pt-Ni is obtained by oxidation at room temperature_xFe_1-x(OH)₂CNTs nano-sheet; wherein the molar ratio of Pt to Fe is 1: 1-4.

6. The method of claim 5, wherein in step S1, the carbon nanotubes are dissolved in an amount of 0.2-1 mg/ml deionized water.

7. The method as set forth in claim 5, wherein the reaction temperature is 120-160 ℃ and the reaction time is 6-8h in step S3.

8. The method of claim 5, wherein the oxidation time is 12 to 36 hours in step S4.

9. Use of the platinum monatomic catalyst of claim 1 in the electrolysis of water.

Technical Field

The invention relates to the technical field of catalysts, in particular to a platinum monatomic catalyst and a preparation method and application thereof.

Background

The hydrogen plays an important role in chemical production, is an environment-friendly substitute of fossil fuels, and the preparation of the catalyst with high efficiency, low cost and high stability is an important subject of hydrogen energy research. The hydrogen production by water electrolysis has the characteristics of high efficiency, no pollution and the like, and is widely used for development and research of hydrogen energy, wherein a four-electron transfer path of an anode oxygen evolution reaction is a difficulty for preventing the hydrogen production efficiency by water electrolysis from being improved, so that a large number of OER catalysts are designed to reduce overpotential and accelerate reaction kinetics so as to bring higher energy conversion efficiency. At present, the catalyst with best performance in electrolyzing water is a noble metal RuO₂And Pt, but because the catalytic activity of noble metals in alkaline solution is generally lower than that of metal Ni, and because the noble metals are expensive and rare, the noble metals are not suitable for large-scale application, non-noble metals, especially transition metals, become hot spots for research of hydrogen evolution catalysts. In recent years, researchers find that defect structures in catalysts play a crucial role in electrocatalytic reactions by changing charge distribution in the reaction process, increasing disorder of atomic arrangement and the like, but the stability of most catalysts still needs to be improved. With the development and research of nanotechnology, it is found that unsaturated coordination atoms on the surface of a catalyst are generally catalytic active sites, and when the size of a nanocrystal is reduced to a cluster or a single atom, the energy level and the electronic structure of the nanocrystal are changed, so that the performance of the catalyst is different from that of a traditional nanocatalyst. The monatomic catalyst has the characteristics of high atom utilization rate, good catalytic activity, excellent selectivity and the like, and is widely concerned by researchers, but most monatomic catalysts are preparedThe preparation conditions are harsh, the loading capacity is low, and the batch production of the catalyst is difficult to realize.

In view of the above, the present invention is directed to a new process for preparing a platinum monatomic catalyst to solve the above problems.

Disclosure of Invention

The technical problem to be solved by the invention is to provide a platinum monatomic catalyst which has the characteristics of high platinum monatomic load, high metal utilization rate, good catalytic activity and the like, and the preparation process is simple and easy to operate, and can be widely applied to the fields of electrolytic water, air batteries and the like.

In order to solve the problems, the technical scheme of the invention is as follows:

a Pt-Ni catalyst with high catalytic activity and high catalytic activity_xFe_1-x(OH)₂The CNTs nano-sheet, wherein x is 1/5-1/2; the platinum monatomic catalyst is prepared by the following preparation process:

step S1, dissolving the carbon nano tube after oxidation treatment in the deionized water without oxygen;

step S2, dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1;

step S3, reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni_xFe_1-x(OH)₂CNTs catalyst;

step S4, adding appropriate amount of H₂PtCl₆·6H₂O addition to Ni of step S3_xFe_1-x(OH)₂In the CNTs catalyst, the platinum monoatomic catalyst Pt-Ni is obtained by oxidation at room temperature_xFe_1-x(OH)₂CNTs; wherein the molar ratio of Pt to Fe is 1: 1-4.

Further, in step S1, the amount of carbon nanotubes is 0.2-1mg per ml of deionized water.

Further, in step S3, the reaction temperature is 120-160 ℃ and the reaction time is 6-8 h.

Further, in step S4, the oxidation time is 12-36 h.

The invention also provides a preparation method of the platinum monatomic catalyst, which comprises the following steps:

step S1, dissolving the carbon nano tube after oxidation treatment in the deionized water without oxygen;

step S2, dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1;

step S3, reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni_xFe_1-x(OH)₂a/CNTs catalyst, wherein x is 1/5-1/2;

step S4, adding appropriate amount of H₂PtCl₆·6H₂O addition to Ni of step S3_xFe_1-x(OH)₂In the CNTs catalyst, the platinum monoatomic catalyst Pt-Ni is obtained by oxidation at room temperature_xFe_1-x(OH)₂CNTs nano-sheet; wherein the molar ratio of Pt to Fe is 1: 1-4.

Further, in step S1, the amount of carbon nanotubes added is 0.2-1mg per ml of deionized water.

Further, in step S3, the reaction temperature is 120-160 ℃ and the reaction time is 6-8 h.

Further, in step S4, the oxidation time is 12-36 h.

The invention also provides an application of the platinum monatomic catalyst in electrolytic water.

Compared with the prior art, the platinum monatomic catalyst provided by the invention and the preparation method and the application thereof have the beneficial effects that:

according to the platinum monatomic catalyst and the preparation method thereof, provided by the invention, platinum atoms are loaded on nickel-iron hydroxide by adopting an in-situ oxidation method, a defect structure is formed in the oxidation process, and the platinum atoms are anchored at a defect position, so that the loading amount of the platinum monatomic reaches 6.15%, and the catalyst has the characteristics of high utilization rate of noble metal, good stability and the like; the preparation method is mild and simple, and can reduce the production cost to a greater extent.

The platinum monatomic catalyst provided by the invention has good catalytic performance, can be widely applied to the fields of electrolytic water, air batteries, lubricants and the like, and is an efficient and stable electrolytic water catalyst.

Drawings

In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without creative efforts.

FIG. 1 shows Pt-Ni prepared in examples 1-3 of the process of the present invention_2/3Fe_1/3(OH)₂X-ray diffraction pattern of/CNTs catalyst;

FIG. 2 shows Pt-Ni prepared in examples 1-3 of the process of the present invention_2/3Fe_1/3(OH)₂An X-ray photoelectron spectrum of O1s in the CNTs catalyst;

FIG. 3 shows Pt-Ni prepared in examples 1-3 of the process of the present invention_2/3Fe_1/3(OH)₂An X-ray photoelectron spectrum of Pt 4f in the/CNT catalyst;

FIG. 4 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂Transmission electron micrograph of/CNTs-24 material;

FIG. 5 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂CO adsorption curve of/CNTs-24 material;

FIG. 6 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂A transmission electron microscope image corrected by spherical aberration of the/CNTs-24 material;

FIG. 7 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂The X-ray absorption near-edge structure spectrum of the/CNTs-24 material;

FIG. 8 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂Solar energy conversion efficiency of/CNTs-24 material；

FIG. 9 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂Faradaic efficiency of hydrogen and oxygen production of/CNTs-24 material;

FIG. 10 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂The stability of the/CNTs-24 material in the full hydrolysis reaction.

Detailed Description

The following description of the present invention is provided to enable those skilled in the art to better understand the technical solutions in the embodiments of the present invention and to make the above objects, features and advantages of the present invention more comprehensible.

The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual values, and between the individual values may be combined with each other to yield one or more new ranges of values, which ranges of values should be considered as specifically disclosed herein.

A preparation method of a platinum monatomic catalyst comprises the following steps:

step S1, dissolving the carbon nano tube after oxidation treatment in the deionized water without oxygen;

specifically, the process for oxidation treatment of the carbon nanotubes comprises the following steps:

dissolving a carbon nano tube, potassium nitrate and potassium permanganate into concentrated sulfuric acid, adding a proper amount of deionized water after reacting for a period of time, ensuring that the temperature does not exceed 80 ℃ in the dropping process, then adding a proper amount of hydrogen peroxide, reacting for a period of time, washing the solution to be neutral, and then freeze-drying to obtain an oxidized carbon nano tube;

dissolving 0.2-1mg of carbon nano tubes in 1ml of deionized water after oxidation treatment, and obtaining a uniformly dispersed carbon nano tube solution by adopting an ultrasonic dispersion process; to prevent Fe in the reaction process²⁺Is oxidized by the dissolved oxygen in the water,ensuring that the water used is deionized water for removing oxygen, such as a method of introducing nitrogen and removing oxygen.

Step S2, dissolving a proper amount of hexamethylenetetramine, ammonium fluoride, nickel chloride hexahydrate and ferrous chloride tetrahydrate in the solution obtained in the step S1, wherein the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1-4: 1;

specifically, the amounts of hexamethylenetetramine and ammonium fluoride are 2mol and 0.6mol, respectively, the molar ratio of Ni to Fe in the nickel chloride hexahydrate and the ferrous chloride tetrahydrate is 1:1-4:1, for example, the molar ratio of Ni to Fe is 4:1, 3:1, 2:1, or 1:1, or other ratios within this range; and the amounts of the hexamethylenetetramine and the ammonium fluoride are kept unchanged in the implementation process, and the total amount of Ni ions and Fe ions in the solution is kept unchanged.

Step S3, reacting the mixed solution obtained in the step S2 in a sealed reaction kettle to obtain Ni_xFe_1-x(OH)₂a/CNTs catalyst, wherein x is 1/5-1/2;

specifically, the reaction temperature is 120-160 ℃, such as 120 ℃, 130 ℃, 140 ℃, 150 ℃ or 160 ℃, and can also be other temperature values in the range; the reaction time is 6-8 h.

Step S4, adding appropriate amount of H₂PtCl₆·6H₂O addition to Ni of step S3_xFe_1-x(OH)₂In the CNTs catalyst, the platinum monoatomic catalyst Pt-Ni is obtained by oxidation at room temperature_xFe_1-x(OH)₂CNTs nano-sheet; wherein the molar ratio of Pt to Fe is 1: 1-4.

Specifically, the oxidation time is 12-36h, and the molar ratio of Pt and Fe is 1:1, 1:2, 1:3 or 1:4, or other ratios within the range of 1:1-4 can be adopted.

The platinum monatomic catalyst and the method for preparing the same according to the present invention will be described in detail below with reference to specific examples.

Example 1

Weighing 1g of carbon nano tube, 0.3g of potassium nitrate and 1g of potassium permanganate, dissolving the carbon nano tube, the potassium nitrate and the potassium permanganate in 50ml of concentrated sulfuric acid, reacting for 6 hours, adding 230ml of deionized water, ensuring the temperature to be not more than 80 ℃ in the dropping process, then adding 2ml of hydrogen peroxide, and reactingAfter 1h, washing the solution to neutrality, and finally freeze-drying to obtain the carbon nano tube subjected to oxidation treatment. Weighing 10mg of oxidized carbon nanotube, dissolving in 40ml of deionized water which is introduced with 30min of nitrogen, and performing ultrasonic dispersion for 30min to obtain a uniformly dispersed carbon nanotube solution. Then weighing 2mmol of hexamethylenetetramine, 0.6mmol of ammonium fluoride, 0.2mmol of nickel chloride hexahydrate, 0.1mmol of ferrous chloride tetrahydrate and the uniformly dispersed carbon nanotube solution, adding the mixture and the uniformly dispersed carbon nanotube solution into a 100ml reaction kettle, reacting for 6 hours at 120 ℃, filtering and washing to obtain Ni_2/3Fe_1/3(OH)₂CNTs. Ni obtained by oxidation with 13ml of a 2mM chloroplatinic acid solution_2/3Fe_1/3(OH)₂/CNTs, the oxidation time is 12h, and Pt-Ni with a defect structure loaded by a platinum monoatomic atom is obtained by filtering and washing_2/3Fe_1/3(OH)₂CNTs-12 material.

Example 2

Weighing 1g of carbon nanotube, 0.3g of potassium nitrate and 1g of potassium permanganate, dissolving the carbon nanotube, the potassium nitrate and the potassium permanganate in 50ml of concentrated sulfuric acid, reacting for 6 hours, adding 230ml of deionized water, dropwise adding the deionized water at a temperature not exceeding 80 ℃, then adding 2ml of hydrogen peroxide, reacting for 1 hour, washing the solution to be neutral, and finally freeze-drying to obtain the carbon nanotube subjected to oxidation treatment. Weighing 10mg of oxidized carbon nanotube, dissolving in 40ml of deionized water which is introduced with 30min of nitrogen, and performing ultrasonic dispersion for 30min to obtain a uniformly dispersed carbon nanotube solution. Then weighing 2mmol of hexamethylenetetramine, 0.6mmol of ammonium fluoride, 0.2mmol of nickel chloride hexahydrate, 0.1mmol of ferrous chloride tetrahydrate and the uniformly dispersed carbon nanotube solution, adding the mixture and the uniformly dispersed carbon nanotube solution into a 100ml reaction kettle, reacting for 6 hours at 120 ℃, filtering and washing to obtain Ni_2/3Fe_1/3(OH)₂CNTs. Ni obtained by oxidation with 13ml of a 2mM chloroplatinic acid solution_2/3Fe_1/3(OH)₂/CNTs, the oxidation time is 24h, and Pt-Ni with a defect structure loaded by a platinum monoatomic atom is obtained by filtering and washing_2/3Fe_1/3(OH)₂CNTs-24 material.

Example 3

Weighing 1g of carbon nano tube, 0.3g of potassium nitrate and 1g of potassium permanganate, dissolving in 50ml of concentrated sulfuric acid, and reactingAnd after 6 hours, adding 230ml of deionized water, ensuring that the temperature does not exceed 80 ℃ in the dropping process, then adding 2ml of hydrogen peroxide, reacting for 1 hour, washing the solution to be neutral, and finally freeze-drying to obtain the carbon nano tube subjected to oxidation treatment. Weighing 10mg of oxidized carbon nanotube, dissolving in 40ml of deionized water which is introduced with 30min of nitrogen, and performing ultrasonic dispersion for 30min to obtain a uniformly dispersed carbon nanotube solution. Then weighing 2mmol of hexamethylenetetramine, 0.6mmol of ammonium fluoride, 0.2mmol of nickel chloride hexahydrate, 0.1mmol of ferrous chloride tetrahydrate and the uniformly dispersed carbon nanotube solution, adding the mixture and the uniformly dispersed carbon nanotube solution into a 100ml reaction kettle, reacting for 6 hours at 120 ℃, filtering and washing to obtain Ni_2/3Fe_1/3(OH)₂CNTs. Ni obtained by oxidation with 13ml of 1.93mM chloroplatinic acid solution_{2/ 3}Fe_1/3(OH)₂/CNTs, the oxidation time is 36h, and Pt-Ni with a defect structure loaded by a platinum monoatomic atom is obtained by filtering and washing_{2/ 3}Fe_1/3(OH)₂CNTs-36 material.

Referring to FIGS. 1 to 3, FIG. 1 shows Pt-Ni prepared according to examples 1 to 3 of the present invention_2/3Fe_1/3(OH)₂X-ray diffraction pattern of/CNTs catalyst; FIG. 2 shows Pt-Ni prepared in examples 1-3 of the process of the present invention_2/3Fe_1/3(OH)₂An X-ray photoelectron spectrum of O1s in the CNTs catalyst; FIG. 3 shows Pt-Ni prepared in examples 1-3 of the process of the present invention_{2/ 3}Fe_1/3(OH)₂X-ray photoelectron spectrum of Pt 4f in/CNT catalyst. As can be seen from FIG. 1, with NiFe (OH)₂Correspondingly, FeOOH phase exists in the catalyst, which indicates that the catalyst contains Fe in the reaction process²⁺Oxidized to FeOOH, and because of the different proportion of NiFe during the synthesis, there is Ni (OH) in XRD₂The existence of phase indicates that part of Ni forms double hydroxide with Fe in the reaction process, and part of Ni still reacts with Ni (OH)₂(ii) present;

as can be seen from FIG. 2, the peaks at 530.4eV, 532eV and 533.4eV are for metal oxygen, metal-hydroxyl oxygen and hydroxyl oxygen in water, respectively, and the peak at 531.4eV is attributable to oxygen defects, wherein the proportion of oxygen defects is 13.4%, 17.2% and 19.2%, respectively, indicating that the content of oxygen defects increases with the increase in reaction time;

as can be seen from FIG. 3, peaks at 68.5eV and 71.5eV belong to the 3P orbital of Ni, and peaks at 72.1eV and 75.3eV are represented by Pt⁰⁺While the peaks at 73eV and 76.3eV are Pt²⁺，Pt²⁺Is monodisperse Pt atom, and has an oxidation time of 12h²⁺/Pt⁰⁺The ratio of (A) to (B) is 1.02, and Pt is oxidized for 24h²⁺/Pt⁰⁺The ratio of (A) to (B) is 3.82, and Pt is oxidized for 36h²⁺/Pt⁰⁺The ratio of (a) to (b) is 2.86. The reason why the proportion is minimum when the reaction is carried out for 12h is that the reaction time is too short to completely oxidize Fe; the reason for the smaller proportion for 36h of oxidation than for 24h is that the reaction time is too long, resulting in some Pt agglomeration. Therefore, the oxidation conditions for 24h are optimal.

Referring to FIGS. 4-7 in combination, FIG. 4 shows Pt-Ni prepared according to example 2 of the present invention_2/3Fe_1/3(OH)₂Transmission electron micrograph of/CNTs-24 material; FIG. 5 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂CO adsorption curve of/CNTs-24 material; FIG. 6 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂A transmission electron microscope image corrected by spherical aberration of the/CNTs-24 material; FIG. 7 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂The X-ray absorption near-edge structure spectrum of the/CNTs-24 material. Pt-Ni shown in FIG. 4_2/3Fe_1/3(OH)₂The transmission electron microscope picture of the/CNTs-24 material can see that obvious holes exist on the lattice stripes, which indicates that lattice distortion is formed in the reaction process, and confirms that the defect structure exists. 0.24nm lattice fringes corresponding to NiFe (OH)₂The (015) crystal plane in the figure, and the diffraction ring in the inset corresponds to the XRD result;

Pt-Ni shown in FIG. 5_2/3Fe_1/3(OH)₂CNTs-24, CO has two main absorption peaks at 2115cm^-1And 2025cm^-1. The two peaks are respectively a CO adsorption peak of positive valence platinum and a linear adsorption peak of CO on a monodisperse active site, and are both characteristic adsorption peaks of monodisperse platinum atoms；

Pt-Ni shown in FIG. 6_2/3Fe_1/3(OH)₂The spherical aberration correction transmission electron microscope picture of/CNTs-24 shows that the platinum monoatomic atoms are uniformly dispersed, and part of the monoatomic atoms are regularly arranged on the crystal lattice; Pt-Ni shown in FIG. 7_2/3Fe_1/3(OH)₂The X-ray absorption near-edge structure spectrum of/CNTs-24 can also indicate that Pt-Ni_2/3Fe_1/3(OH)₂The platinum is present as a single atom in the/CNTs-24.

The Pt-Ni of example 2 was applied to a solar cell panel to provide a stable voltage_2/3Fe_1/3(OH)₂the/CNTs-24 catalyst is dispersed uniformly by isopropanol, water and naphthol solution in an ultrasonic mode, then is dripped on a platinum carbon electrode, and the oxygen evolution performance of the catalyst is tested in 1M KOH solution; the catalyst was dropped on the treated nickel foam as cathode and anode and tested for full water splitting performance and solar conversion efficiency in 1M KOH solution.

Please refer to FIG. 8 and FIG. 9 in combination, in which FIG. 8 shows Pt-Ni prepared by example 2 in the method of the present invention_2/3Fe_1/3(OH)₂The solar energy conversion efficiency of the/CNTs-24 material; FIG. 9 shows Pt-Ni prepared in example 2 of the method of the present invention_2/3Fe_1/3(OH)₂Faradaic efficiencies for hydrogen and oxygen production of the/CNTs-24 material. As can be seen from fig. 8, the solar energy conversion efficiency at the first hour is 11.69%, and after the 4h test, the solar energy conversion efficiency is reduced to only 11.65%, which indicates that the catalyst prepared by the present invention has stable solar energy conversion efficiency. The faradaic efficiencies of the catalyst for hydrogen production and oxygen production were calculated to be 98.81% and 98.12%, respectively.

Please refer to FIG. 10, which shows Pt-Ni prepared by example 2 of the present invention_2/3Fe_1/3(OH)₂The stability of the/CNTs-24 material in the full hydrolysis reaction is tested for 15h, the catalyst still has better stability, and has certain advantages compared with commercial ruthenium oxide and platinum carbon, which indicates that the catalyst prepared by the invention has certain commercial application prospect.

The platinum monatomic catalyst provided by the invention can be applied to the fields of air batteries, lubricants and the like.

Compared with the prior art, the platinum monatomic catalyst provided by the invention and the preparation method and the application thereof have the beneficial effects that:

according to the platinum monatomic catalyst and the preparation method thereof, provided by the invention, platinum atoms are loaded on nickel-iron hydroxide by adopting an in-situ oxidation method, a defect structure is formed in the oxidation process, and the platinum atoms are anchored at a defect position, so that the loading amount of the platinum monatomic reaches 6.15%, and the catalyst has the characteristics of high utilization rate of noble metal, good stability and the like; the preparation method is mild and simple, and can reduce the production cost to a greater extent.

The platinum monatomic catalyst provided by the invention has good catalytic performance, can be widely applied to the fields of electrolytic water, air batteries, lubricants and the like, and is an efficient and stable electrolytic water catalyst.

The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. Various changes, modifications, substitutions and alterations to these embodiments will occur to those skilled in the art without departing from the spirit and scope of the present invention.