阅读说明：本技术 一种改善香料或香料混合物性能的方法 (Method for improving performance of spice or spice mixture ) 是由 阿德利诺·中野馨 C·B·劳伦科 F·卡尔维特 C·C·杜鲁 L·勒莫夫 T·M·巴宁 于 2019-03-11 设计创作，主要内容包括：提出一种改善香料或香料混合物性能的方法,包括或由以下步骤组成：(a)提供至少一种能够被热激活的香料；(b)任选地将步骤(a)所述的至少一种香料掺入化妆品或洗涤剂组合物中；(c)将步骤(a)所述的至少一种香料或步骤(b)的所述化妆品组合物施用于人发；和(d)将头发进行热处理,其中所述至少一种香料选自由具备定义的沸点,LogP值和/或扩散系数的香料组成的组。(A method for improving the performance of a perfume or perfume mixture is proposed, comprising or consisting of the following steps: (a) providing at least one heat-activatable fragrance; (b) optionally incorporating at least one perfume of step (a) into a cosmetic or detergent composition; (c) applying the at least one fragrance of step (a) or the cosmetic composition of step (b) to human hair; and (d) subjecting the hair to a heat treatment, wherein the at least one perfume is selected from the group consisting of perfumes having defined boiling points, LogP values and/or diffusion coefficients.)

1. A method of improving the performance of a perfume or perfume mixture comprising or consisting of the steps of:

(a) providing at least one heat-activatable fragrance;

(b) optionally incorporating at least one perfume of step (a) into a cosmetic or detergent composition;

(c) applying the at least one fragrance of step (a) or the cosmetic composition of step (b) to human hair; and

(d) the hair is subjected to a heat treatment,

wherein the at least one perfume is selected from the group consisting of perfumes having the following parameters:

(i) a Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9;

wherein the heat treatment is hair drying and/or flat ironing and/or curling.

2. The method of claim 1, wherein said at least one fragrance is selected from the group consisting of

Methoxyacetophenone crystals

Acetophenone

2-acetyl thiazole

C8 aldehydes

So-called C18 aldehydes

Galbanum ester

Acetic acid pentyl ester

Pure anisic aldehyde

Benzaldehyde DD

Benzyl acetate

Carboxylic acid benzyl ester

Butyl acetate

Coumarin (E)

P-cresol

P-cresol methyl ether

·

Cyclohexyl acetate

Delta-decalactone

Gamma-decalactone

Benzoic acid ethyl ester

Butyric acid ethyl ester

Ethyl caproate

Ethyl maltol

Phenoxyacetic acid ethyl ester

Ethyl phenylacetate

Propionic acid ethyl ester

Ethyl vanillin

·EXOVERT HIGH IMPACT

Fenchyl alcohol

·

15% furanone in PG

Piperonal

Gamma-heptanolactone

·HERBAC

Trans-2-hexenal

Cis-trans-acetic acid 3-hexenyl ester

Cis-3-hexeneacetic acid ester

N-hexyl acetate

Hydratropic aldehyde dimethyl acetal

Indole FF (═ 130437) 10% DPG indole FF

Isoamyl acetate

Isoborneol (Isoborneol)

Isobutyl acetate

Isobutyl methoxypyrazine-3, 2

Isoeugenol

Isoeugenol 10% DPG

Isooctanone

Isopropyl methoxypyrazine-2, 3

Isopropylmethylthiazole-2, 4

Apple ester

Folyl acetal

·LEAFOVERT 10％DPG

·

Glossy privet aldehyde

Methylpentanoic acid ethyl ester

Ethyl methylpentanoate 10% DPG

Menthone L/isomenthone D

Menthone/isomenthone RAC.

P-methylacetophenone

Methyl anthranilate (═ 130085). benzoic acid methyl ester

Hexanoic acid methyl ester

Methyl Dantilisi

4-methyl guaiacol

2-Octylynoic acid methyl ester

10% DPG of methylcobalide

Phenylacetic acid methyl ester

PF methyl salicylate

·METIL-6-HEPTEN-5-ONA-2 SUPRA

Dimethyl phenylpropanol

Trans, cis-2, 6-nonadienal

2, 6-Nondeal

Delta-nonalactone

10% DPG of. gamma. -octalactone

Delta-octalactone

Gamma-octalactone

Octanone-2

Octanone-3

·OXANTHIA 50％IN TEC

·OXANTHIA 50％IN TEC 0,2％DPG

·

Phenylacetaldehyde

Phenylacetaldehyde dimethyl acetal

Phenylethanolic BA FREE

Benzoic acid phenethyl ester

Isoamyl acetate

Isoamyl acetate 10% DPG

Styrofoam acetate

Trans 2 hexenal 10% DPG

New glossy privet aldehyde

Vanillin 10% DPG

Vanillin

·VERTOCITRAL

Ligustral 10% DPG

·VERTOPRENAL

3. The method of claim 1, wherein the cosmetic composition is a hair care composition.

4. The method of claim 1, wherein the detergent composition is an ironing aid.

5. The method of claim 1, wherein the at least one fragrance or the cosmetic composition is applied to wet hair.

6. The method of claim 1, wherein the at least one fragrance or the cosmetic composition is applied to dry hair.

7. The method of claim 1, wherein the performance improvement relates to perfume intensity.

8. The method of claim 1, wherein the performance improvement relates to perfume sustainability.

9. A cosmetic composition comprises one, two, three, four or more fragrances selected from the group consisting of fragrances having the following parameters

(i) A Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9.

10. The composition of claim 9 is a hair care composition.

11. A detergent composition comprising one, two, three, four or more perfumes selected from the group consisting of perfumes having the following parameters

(i) A Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9.

12. The composition of claim 11 is an ironing aid.

13. Cosmetic compositions according to claim 9 and/or detergent compositions according to claim 11 containing the perfume encapsulated.

Technical Field

The present invention relates to the field of hair cosmetics and identifies a plurality of fragrances which, when subjected to higher temperatures, exhibit improved properties with respect to their strength and/or their substantivity to human hair.

Background

It is known in the art that thousands of molecules exhibit specific odors, making them fragrances. The ability of a molecule to act as a fragrance, although the olfactory impression is always subjective, is independent of the specific chemical structure. Alcohols, aldehydes, ketones, nitriles, carboxylic acids and all types of hydrocarbons, small and large molecules, cyclic and acyclic, saturated and unsaturated species among them are found.

Many of these materials are less stable, especially when exposed to higher temperatures. This is not usually a serious problem because the corresponding products into which these molecules are formulated are used at ambient temperature, but there are applications where higher stability at temperatures of about 100 ℃ and above is required, especially during perming. Of particular interest are perfumes which are activated at higher temperatures (so-called "heat-activated" perfumes), which means that they show better performance at higher temperatures than at lower temperatures.

Prior Art

Perfume compositions containing a large number of discrete materials advertised as "heat activated" are known on the market. Examples of market products include "Uniq One" (Luhua nong), "series Expert" (Eriya), and K Discipine (K miracast).

Disclosure of Invention

Due to the fact that these mixtures contain dozens or even more than a hundred different fragrances, it is completely unknown which specific parts of the mixture can be heat activated and which cannot. Thus, the prior art does not provide any guidance to identify corresponding fragrance molecules to develop heat-activated perfume compositions with improved performance.

It was therefore an object of the present invention to identify hair cosmetics which form part of the so-called leave-on hair cosmetics and which are said to be capable of being heat-activated, for example to achieve greater strength and/or better substantivity (permanent effect) during flat or curl or drying.

The object of the present invention is a process for improving the properties of a perfume or a perfume mixture, comprising or consisting of the following steps:

(a) providing at least one heat-activatable fragrance;

(b) optionally incorporating at least one perfume of step (a) into a cosmetic or detergent composition;

(c) applying the at least one fragrance of step (a) or the cosmetic composition of step (b) to human hair; and

(d) subjecting the hair to a heat treatment, wherein the at least one perfume is selected from the group consisting of perfumes having the following parameters:

(i) a Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9;

wherein the heat treatment is hair drying and/or flat ironing and/or curling.

Although the parameter "diffusivity" is well known to experts in the perfuming agent field, it should be noted that this value provides information about the remote irradiation of the perfume compound. The higher the value, the faster the material is perceived, and the greater the strength. The rating is defined as no effect within 1-3 minutes to a high effect within 9-10 seconds.

The diffusivity was determined by smelling 0.5 grams of material in a petri dish 50 cm away from the panelist. The tray is opened according to the signal, time stopped and intensity aligned when activated. Each material was evaluated 3 times by 8 panelists. The measurement should be performed in an environment that excludes convection or air flow. (strength rating: 1 no odor to 5 strong odor; time rating: <10 sec 4.5, <20 sec 4, <40 sec 3.5, <60 sec 3, <80 sec 2.5, <100 sec 2, <130 sec 1, <200 sec 0.5, >200 sec 0; two parts add up to give a diffusivity value)

Surprisingly, it has been observed that perfumes or perfume mixtures, whether used directly or as part of a cosmetic or detergent composition, exhibit improved intensity and/or long lasting effect when subjected to higher temperatures, such as when dried using a conventional hair dryer or flat iron using a hair straightener or curling iron. Similar effects are obtained when the perfume or the composition comprising the perfume is applied to textile fibres and these textiles are subjected to ironing.

Perfume

Fragrances which can be heat-activated within the meaning of the present invention are selected from the following group:

p-methoxyacetophenone crystals

Acetophenone

2-acetyl thiazole

C8 aldehydes

So-called C18 aldehydes

Galbanum ester

Acetic acid pentyl ester

Pure anisic aldehyde

Benzaldehyde DD

Benzyl acetate

Carboxylic acid benzyl ester

Butyl acetate

Coumarin (E)

P-cresol

P-cresol methyl ether

·

Cyclohexyl acetate

Delta-decalactone

Gamma-decalactone

Benzoic acid ethyl ester

Butyric acid ethyl ester

Ethyl caproate

Ethyl maltol

Phenoxyacetic acid ethyl ester

Ethyl phenylacetate

Propionic acid ethyl ester

Ethyl vanillin

·EXOVERT HIGH IMPACT

Fenchyl alcohol

·

15% furanone in PG

Piperonal

Gamma-heptanolactone

·HERBAC

Trans-2-hexenal

Cis-trans-acetic acid 3-hexenyl ester

Cis-3-hexeneacetic acid ester

N-hexyl acetate

Hydratropic aldehyde dimethyl acetal

Indole FF (═ 130437) 10% DPG

Indole FF

Isoamyl acetate

Isoborneol (Isoborneol)

Isobutyl acetate

Isobutyl methoxypyrazine-3, 2

Isoeugenol

Isoeugenol 10% DPG

Isooctanone

Isopropyl methoxypyrazine-2, 3

Isopropylmethylthiazole-2, 4

Apple ester

Folyl acetal

·LEAFOVERT 10％DPG

·

Glossy privet aldehyde

Methylpentanoic acid ethyl ester

Ethyl methylpentanoate 10% DPG

Menthone L/isomenthone D

Menthone/isomenthone RAC.

P-methylacetophenone

Methyl anthranilate (130085)

Benzoic acid methyl ester

Hexanoic acid methyl ester

Methyl Dantilisi

4-methyl guaiacol

2-Octylynoic acid methyl ester

10% DPG of methylcobalide

Phenylacetic acid methyl ester

PF methyl salicylate

·METIL-6-HEPTEN-5-ONA-2SUPRA

Dimethyl phenylpropanol

Trans, cis-2, 6-nonadienal

2, 6-Nondeal

Delta-nonyl lactones

10% DPG of. gamma. -octalactone

Delta-octalactone

Gamma-octalactone

Octanone-2

Octanone-3

·OXANTHIA 50％IN TEC

·OXANTHIA 50％IN TEC 0,2％DPG

·

Phenylacetaldehyde

Phenylacetaldehyde dimethyl acetal

Phenylethanolic BA FREE

Benzoic acid phenethyl ester

Isoamyl acetate

Isoamyl acetate 10% DPG

Styrofoam acetate

Trans 2 hexenal 10% DPG

New glossy privet aldehyde

Vanillin 10% DPG

Vanillin

·VERTOCITRAL

Ligustral 10% DPG

·VERTOPRENAL

The invention also includes mixtures of one, two, three, four or more of said fragrances.

Cosmetic composition

The perfume as defined above may be applied to human hair as such or dissolved in a carrier such as ethanol or aqueous ethanol, or may be incorporated into cosmetic compositions, especially hair care compositions. Thus, another object of the present invention relates to a cosmetic composition comprising one, two, three, four or more fragrances as defined above.

In particular, the present invention relates to a cosmetic composition, preferably a hair care composition, comprising one, two, three, four or more fragrances selected from the following fragrances:

(i) a Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9.

Hair compositions comprising said perfumes are usually of the "leave-on" type, subjected to higher temperatures once they are applied. In the case of drying hair using a conventional hair dryer, temperatures of up to about 80 ℃ may be reached, and the corresponding product left on the hair fibres may represent a typical cosmetic or personal care product for hair care, such as shampoo, conditioner or any other type of hair after-treatment product.

The composition may comprise a working amount of a perfume as defined above, e.g. from about 0.1 to about 10% b.w., preferably from about 0.5 to about 8% b.w., especially from about 1% to about 5% b.w. -calculated on the composition. Hair or personal care compositions may be, for example, cosmetic creams, lotions, sprays, lotions, ointments, gels, mousses, or the like. Typical examples are shampoos, conditioners and corresponding "two-in-one" products.

The cosmetic compositions according to the invention may contain various ingredients and adjuvants, such as antidandruff agents, anti-irritants, irritation-inhibiting agents, antioxidants, astringents, antiperspirant agents, bactericides, antistatic agents, binders, buffers, carriers, chelating agents, cell stimulants, cleaning agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, color fixatives, foam formers, foam stabilizers, antifoams, foam boosters, gelling agents, gel formers, hair care agents, hair styling agents, hair straightening agents, moisturizers, humectants, moisturizers, bleaches, strengthening agents, soil release agents, optical brighteners, macerators, soil repellents, friction reducers, lubricants, moisturizing creams, ointments, opacifiers, plasticizers, covering agents, polish, glossers, polymers, powders, proteins, protein based agents, Fatting agents, abrasives, silicones, hair-growing agents, coolants, skin coolants, warming agents, skin warming agents, stabilizers, UV absorbers, UV filters, detergents, odorants, polyols, surfactants, electrolytes, organic solvents or silicone derivatives and the like as additional adjuvants and additives.

Surface active agent

Preferred auxiliaries and additives are anionic and/or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are mentioned in the paragraph relating to emulsifiers.

Typical examples of anionic and zwitterionic surfactants include: almond oil amidopropyl amine oxide, almond oil amidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkanol ammonium sulfate, C12-16 alkanol ammonium sulfate, octanol polyether ammonium sulfate, ammonium cocoyl glyceride ammonium sulfate, cocoyl isethionate, cocoyl ammonium sarcosinate, C12-15 alkanol ammonium sulfate, C9-10 perfluoroalkyl ammonium sulfonate, dinonyl ammonium sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-7, ammonium laureth-8, ammonium laureth sulfate, ammonium laureth-5, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-6, ammonium laureth-8, ammonium laureth sulfate, ammonium laureth-15, ammonium laureth-5, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-7, ammonium laureth-12, ammonium laureth-sulfate, ammonium laureth-6, ammonium laureth-2, ammonium laureth-6, ammonium laureth-2, ammonium laureth-6, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-9, ammonium laureth-4, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-9, ammonium laureth-2, ammonium laureth-sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl polyether sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel oleyl sulfate, ammonium stearate, ammonium tallate, isostearoyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearoyl hydrolyzed collagen AMP salt, isostearoyl hydrolyzed keratin AMP salt, isostearoyl hydrolyzed soybean AMP salt, isostearoyl hydrolyzed wheat AMP salt, bisoleamidopropyl betaine, arachidic acid, hexyldecanol phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 esters, babassu seed oil acid, babassu oleamidopropyl amine oxide, babassu oleamidopropyl betaine, beeswax acid, behenamidopropyl betaine oxide, behenamidopropyl betaine, and the like, Beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyl polydimethyl siloxane polyglycerol-3, butyl phenol polyether-5 carboxylic acid, butyl phenol polyether-19 carboxylic acid, butyl dimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyl dimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside decanoate, butyl glucoside hydroxypropyl trimethyl ammonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane/cycloalkane, C10-14 alkylbenzene sulfonic acid, C12-14 alkyl di (aminoethyl) glycine HCl, C9-15 alcohol phosphate, Candida/glucose/rapeseed methyl oleate fermentation product, Canola oil amidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, caprylyl/caproyl amidopropyl betaine, caprylyl polyether-4 carboxylic acid, caprylyl polyether-6 carboxylic acid, caprylyl polyether-9 carboxylic acid, caprylic acid, caprylyl collagen amino acids, caprylyl glycine, caprylyl hydrolyzed collagen, caprylyl hydrolyzed keratin, caprylyl keratin amino acids, caprylyl silk amino acids, octyl/decyl glucoside, octyl/decyl wheat bran/straw glycosides, octyl glucoside, octyl glyceryl ether, octyl pyrrolidone, carnitine, ceteareth-20, ceteareth-23, ceteareth-24, ceteareth-25, ceteareth-27, ceteareth-28, ceteareth-29, Ceteareth-30, ceteareth-33, ceteareth-34, ceteareth-40, ceteareth-50, ceteareth-55, ceteareth-60, ceteareth-80, ceteareth-100, ceteareth-25 carboxylic acid, ceteareth-2 phosphate, ceteareth-4 phosphate, ceteareth-5 phosphate, diceteceteth-10 phosphate, ceteth-20, ceteth-23, ceteth-24, ceteth-25, ceteth-30, ceteth-40, ceteth-45, ceteth-150, Ceteth-8 phosphate, ceteth-10 phosphate, ceteth-20 phosphate, ceteth-22, ceteth-24, ceteth-25, ceteth-30, cetyl betaine, chamomile (CHRYSANTHEMUM SINENSE) flower extract, C12-14 hydroxyalkyl hydroxyethyl beta-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropyl amine oxide, cocamidopropyl betaine amide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocamidobutyric acid, cocamidopropionic acid, cocath-7 carboxylic acid, cocath-4 glucoside, cocamidoamphopropionic acid, cocamidoamphopropionate salt, cocoamidoamphopropionate, coco-L-beta-alanine, cocoamidopropyl hydroxysultaine, coco-L-beta-alanine, coco-beta-hydroxy-beta-alanine, coco-hydroxy-beta-alanine, coco-beta-hydroxy-beta-alanine, coco-beta-hydroxy-beta-hydroxy-beta-alanine, and coco-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy, Cocoyl betaine, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed rice protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed soy protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, cocoyl glucoside hydroxypropyl trimethyl ammonium chloride, cocoyl hydroxy sulfobetaine, cocoyl morpholine oxide, cocoyl acid, cocoyl glyceryl polyether-8 esters, cocoyl/oleamidopropyl betaine, cocoyl-sulfobetaine, (coco/sunflower seed oil) amidopropyl betaine, cocoyl choline methyl sulfate, cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, cocoyl betaine, cocoyl glyceryl betaine, cocoyl-L-, Corn oleic acid, cottonseed oil glyceryl polyether-8 esters, C10-16 alkanol polyether-1, C10-16 alkanol polyether-2, C11-13 alkanol polyether-6, C11-13 alkanol polyether-9, C11-13 alkanol polyether-10, C11-15 alkanol polyether-30, C11-15 alkanol polyether-40, C12-13 alkanol polyether-1, C12-13 alkanol polyether-23, C12-14 alkanol polyether-5, C12-14 alkanol polyether-9, C13-15 alkanol polyether-21, C14-15 alkanol polyether-8, C20-22 alkanol polyether-30, C20-40 alkanol polyether-40, C20-40 alkanol polyether-95, C22-24-Alkanopolyether-33, C30-50-Alkanopolyether-40, C9-11-Alkanopolyether-6-carboxylic acid, C9-11-Alkanopolyether-8-carboxylic acid, C11-15-Alkantherpolyether-7-carboxylic acid, C12-13-Alkanther5-carboxylic acid, C12-13-Alkanther7-carboxylic acid, C12-13-Alkanther8-carboxylic acid, C12-13-Alkanther12-carboxylic acid, C12-15-Alkanther7-carboxylic acid, C12-15-Alkanther8-carboxylic acid, C12-15-Alkanther12-carboxylic acid, C14-15-Alkanther8-carboxylic acid, C6-10-Alkanther4-phosphate, C12-13-Alkanther2-phosphate, C12-13-Alkanther10-phosphate, C12-15-alkanolpolyether-6-phosphate, C12-15-alkanolpolyether-8-phosphate, C12-15-alkanolpolyether-10-phosphate, C12-16-alkanolpolyether-6-phosphate, C4-18 perfluoroalkyl ethyl mercaptopropyltrimethylammonium chloride, macrococoma fatty acid amidopropyl betaine, C12-13-alcohol sulfate DEA salt, C12-15-alcohol sulfate DEA salt, ceteareth-2-phosphate DEA salt, cetyl sulfate DEA salt, cocoyl amphoteric dipropionate DEA salt, C12-13-alkanolpolyether-3-sulfate DEA salt, cyclopropyl oleate DEA salt, dodecylbenzene sulfonate DEA salt, isostearic acid DEA salt, laureth sulfate DEA salt, lauryl sulfate DEA salt, linoleate DEA salt, methyl myristate sulfonate DEA salt, myristyl alcohol ether sulfate DEA salt, myristyl sulfate DEA salt, dodecyl benzene sulfonate DEA salt, isostearic acid DEA salt, laureth sulfate DEA salt, lauryl sulfate DEA salt, linoleate DEA salt, methyl myristate DEA salt, myristyl ether sulfate DEA salt, myristic acid DEA salt, myristyl alcohol sulfate DEA salt, oleyl alcohol polyether-5 phosphate DEA salt, oleyl alcohol polyether-20 phosphate DEA salt, DEA PG-oleate, decyl alcohol polyether-7 carboxylic acid, decyl alcohol polyether-7 glucoside, decyl alcohol polyether-9 phosphate ester, decyl amine oxide, decyl betaine, undecyl glucoside, decyl tetradecyl alcohol polyether-30, decyl tetradecyl tetramine oxide, lauramide-MEA sulfosuccinate diammonium, lauryl alcohol sulfosuccinate diammonium, oleamido PEG-2 sulfosuccinate diammonium, dibutoxymethane, di C12-15 alkanol polyether-2 phosphate ester, di C12-15 alkanol polyether-4 phosphate ester, di C12-15 alkanol polyether-6 phosphate ester, di C12-15 alkanol polyether-8 phosphate ester, Di C12-15 alkanolpolyether-10 phosphate, didodecyl butane tetraformate, laureth sulfate diethylamine salt, diethyl hexyl sulfosuccinate sodium, di (hydroxyethyl) C8-10 alkoxypropylamine oxide, di (hydroxyethyl) C9-11 alkoxypropylamine oxide, di (hydroxyethyl) C12-15 alkoxypropylamine oxide, di (hydroxyethyl) cocoamine oxide, di (hydroxyethyl) laurylamine oxide, di (hydroxyethyl) stearylamine oxide, di (hydroxyethyl) tallowylamine oxide, polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane PEG-10 phosphate, polydimethylsiloxane PEG/PPG-7/4 phosphate, polydimethylsiloxane PEG/PPG-12/4 phosphate, polydimethylsiloxane/polyglycerol-3 cross-linked polymer, Polydimethyl siloxane propyl PG-betaine, dimyristyl alcohol phosphate, dioleamide ethyl hydroxyethyl methyl ammonium methyl sulfate, hydrogenated coco acid DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium caprylyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenoyl glutamate, disodium babassu oleyl MEA-sulfosuccinate, disodium decanoyl amphodiacetate, disodium decanoyl amphodipropionate, disodium octanoyl amphodiacetate, disodium octanoyl amphodipropionate, disodium octanoyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl sulfosuccinate, disodium cocoamido MEA-sulfosuccinate, disodium cocoamido MIPA PEG-4 sulfosuccinate, disodium cocoamido MIPA-sulfosuccinate, Disodium cocoamido PEG-3 sulfosuccinate, disodium cocoeth-3 sulfosuccinate, disodium cocoamphocarboxyethylhydroxypropyl sulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium coco-glucoside sulfosuccinate, disodium coco-sulfosuccinate, disodium cocobutylgluceth-10 sulfosuccinate, disodium cocoylglutamate, disodium C12-14 alkanolpolyether-1 sulfosuccinate, disodium C12-14 alkanolpolyether-2 sulfosuccinate, disodium C12-15 alkanolpolyether sulfosuccinate, disodium C12-14 secondary alkanolpolyether-3 sulfosuccinate, disodium C12-14 secondary alkanolpolyether-5 sulfosuccinate, disodium coco-3 sulfosuccinate, disodium C12-14 secondary alkanolpolyether-5 sulfosuccinate, Disodium C12-14 secondary alkanolamine-7 sulfosuccinate, disodium C12-14 secondary alkanolamine-9 sulfosuccinate, disodium C12-14 secondary alkanolamine-12 sulfosuccinate, disodium decyl polyether-5 sulfosuccinate, disodium decyl polyether-6 sulfosuccinate, disodium decyl phenyl ether disulfonate, disodium dihydroxyethyl sulfosuccinoyl undecylenate, disodium cocoyl ethylenediamine PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamic acid, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-MEA-sulfosuccinate, disodium isostearamide amphodiacetate, disodium isostearamide dipropionate, Disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauramido MEA-sulfosuccinate, disodium lauramido MIPA glycol sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth-5 carboxy amphodiacetic acid, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laureth-dihydroxypropyl sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauriminodipropionate, Disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, disodium lauroglutamate, disodium laurphenylether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleamide amphodipropionate, disodium oleyl polyether-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium PEG-4 cocamide MIPA-sulfosuccinate, disodium N-lauroamphoaspartate, disodium laurylphosphate, disodium laurylphosphateglutamate, disodium laurylphosphatedisulfonate, disodium laurylphosphatesulfosuccinate, disodium laurylphosphatedisulfonate, disodium laurylphosphateMEA-10, disodium oleamide MEA sulfosuccinate, disodium linolosuccinate, disodium linoleamide MIPA-2 sulfosuccinate, disodium linoleamide PEG-2 sulfosuccinate, disodium linoleamide, Disodium PEG-12 dimethicone sulfosuccinate, disodium PEG-8 palmitoleic acid glyceride sulfosuccinate, disodium PPG-2-isodecylpolyether-7 carboxy amphodiacetate, disodium ricinoleic acid amide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soy oleoyl amphodiacetate, disodium stearamide MEA-sulfosuccinate, disodium stearimidodipropionate, disodium stearyl amphodiacetate, disodium stearyl glutamate, disodium sulfosuccinate monoacyl stearylamine, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tall oil amide MEA sulfosuccinate, disodium tallow amphodiacetate, disodium soy oleoyl amphoacetate, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfopalmitate, disodium tallowamide MEA sulfosuccinate, disodium tallow amidoMEA sulfosuccinate, disodium tallow amphodiacetate, sodium soy alcohol sulfosuccinate, sodium glyceryl monostearate, sodium lauryl sulfate, disodium tallowamide MEA sulfosuccinate, sodium lauryl sulfate, disodium tallowamide, Disodium tallowimino dipropionate, disodium sulfosuccinamate monotallow amine, disodium tridecanol sulfosuccinate, disodium undecylenamide MEA sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenoglutamic acid, disodium triticale oleoyl MEA sulfosuccinate, disodium triticale oleamide PEG-2 sulfosuccinate, disodium wheat oleamido amphodiacetate, di-TEA cocamide diacetate, bis-TEA oleamido PEG-2 sulfosuccinate, bis-TEA palmitoyl aspartate, sodium ditridecyl sulfosuccinate, dodecylbenzene sulfonic acid, erucylamidopropyl hydroxysultaine, ethylhexanol polyether-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, octyl glyceryl ether, hexyl decanoate, disodium undecylenoyl MEA sulfosuccinate, disodium triticum oleamido oleate, disodium triticum oleamido-2 sulfosuccinate, disodium wheat oleamido amphooleamido amphoacetate, disodium oleamido-2 sulfosuccinate, disodium oleamido-2, cocoyl diacetate, disodium cocoyl acetate, and octyl glyceryl ether, Hydrogenated coconut oil acid, hydrogenated lanolin alcohol polyether-25, hydrogenated menhaden oil fatty acid, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow acyl glutamic acid, hydrogenated Candida extract, Hydroxycetyl polyether-60, hydroxyethyl acetoxymethylammonium PG-polydimethylsiloxane, laureth sulfate hydroxyethylbutylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl/hydroxymyristyl betaine, hydroxystearic acid, amidohydroxysuccinimide C10-40 isoalkanoic acid ethylhexyl ester, amidohydroxysuccinimide C21-22 isoalkanoic acid ethylhexyl ester, hydroxysulfobetaine, IPDI/PEG-15 Soy oil amine oxide, IPDI/PEG-15 Soy oil amine EtOH methyl sulfate copolymer, IPDI/PEG-15 Soy oil Glycine ester copolymer, lsoceteth-30, Isolauryl ether-4 phosphate, Isopolyglyceryl-3 Dimethicone, Isolaurylamine lanolate, Isolaurylbenzenesulfonic acid Isopropylamine salt, Isostearamidopropyl betaine, Isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearyl hydrolyzed collagen, Jojoba oil PEG-150 esters, Jojoba wax PEG-80 esters, Hojojoba wax PEG-120 esters, lanonol polyether-20, lanonol polyether-25, lanonol polyether-40, lanonol polyether-50, lanonol polyether-60, lanonol polyether-75, lanonol acid, lauramidopropyl amine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramidooxide, lauramidopropionic acid, lauryldimethylhydroxypropyldecyl glucoside ammonium chloride, lauryldimethylglucidohydroxypropylammonium chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3-carboxylic acid, Laureth-4-carboxylic acid, laureth-5-carboxylic acid, laureth-6-carboxylic acid, laureth-8-carboxylic acid, laureth-10-carboxylic acid, laureth-11-carboxylic acid, laureth-12-carboxylic acid, laureth-13-carboxylic acid, laureth-14-carboxylic acid, laureth-17-carboxylic acid, laureth-6-citric acid ester, laureth-7-citric acid ester, laureth-1-phosphate ester, laureth-2-phosphate ester, laureth-3-phosphate ester, laureth-4-phosphate ester, laureth-7-phosphate ester, laureth-8-phosphate ester, laureth-7-tartaric acid ester, lauric acid, iminodipropionic acid, laureth-7-tartaric acid ester, laureth-dipropylene glycol, laureth-5-carboxylic acid, laureth-6-carboxylic acid, laureth-8-carboxylic acid, laureth-10-carboxylic acid, laureth-6-citric acid, laureth-7-citric acid, laureth-1-phosphate ester, laureth-2-phosphate ester, laureth-3-4-phosphate ester, laureth-7-phosphate ester, laureth-4-di-propylene glycol, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-di-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth, Lauroyl amphodipropionic acid, lauroyl beta-aminopropionic acid, lauroyl collagen amino acids, lauroyl ethyltrimethylammonium methylsulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methylglucamide, lauroyl sarcosine, lauroyl silk amino acids, lauryl betaine, lauryl dimethicone/polyglyceryl-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside hydroxypropyl trimethyl ammonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, lauryl methylglucamine, (lauryl/myristyl) glycol hydroxypropyl ether, (lauryl/myristyl) wheat bran/straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, lauryl dimethyl silicone gum amino acid, lauryl ethyl trimethyl ammonium methosulfate, lauryl dimethyl silicone gum, lauryl dimethyl ammonium chloride, lauryl glucoside hydroxypropyl ammonium chloride, lauryl hydroxyethyl ammonium chloride, lauryl dimethyl silicone, Lauryl pyrrolidone, lauryl dimethyl sulfobetaine, linoleic acid, linolenic acid, linoleic acid, lysine cocoate, macadamia nut oil glyceryl polyether-8 esters, magnesium cocoeth sulfate, magnesium isododecylphenyl sulfonate, magnesium laureth-11 carboxylate, magnesium laureth sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methylcocoyltaurate, magnesium myristyl polyether sulfate, magnesium oleyl polyether sulfate, magnesium cocoeth sulfate/TEA salt, Mannich ice river mud, coconut MEA salt, MEA salt of laureth-6 carboxylic acid, MEA salt, and MEA salt, Lauryl alcohol sulfate ester MEA salt, PPG-6-lauryl alcohol polyether-7 carboxylic acid MEA salt, PPG-8-stearyl alcohol polyether-7 carboxylic acid MEA salt, undecylenic acid MEA salt, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxy PEG-450 amido glutaryl succinamide, methoxy PEG-450 amido hydroxysuccinimide succinate, methoxy PEG-450 maleimide, methyl morpholine oxide, cow milk amide propyl amine oxide, cow milk amide propyl betaine, mink oil amide propyl amine oxide, mink oil amide propyl betaine, C12-15 alkanol polyether sulfate ester MIPA salt, dodecyl benzene sulfonic acid MIPA salt, lauryl alcohol polyether MIPA salt, lauryl alcohol sulfate ester MIPA salt, Mixed isopropanolamine lanolate, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristyl polyether-3 carboxylic acid, myristyl polyether-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristyl amide propyl amine oxide, myristyl amide propyl betaine, myristyl amide propyl dimethylamine phosphate, myristyl amide propyl hydroxysultaine, myristyl amide propyl PG-dimethyl ammonium chloride phosphate, myristyl amine oxide, myristyl amino propionic acid, myristic acid, myristyl ethyl trimethyl ammonium methyl sulfate, myristyl glutamic acid, myristoyl hydrolyzed collagen, myristoyl sarcosine, myristoyl betaine, myristyl/cetyl amine oxide, myristoyl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, myristoyl dimethyl hydroxypropyl cocoyl glucoside chloride, Myristyl glucoside, myristyl phosphate ester, nonylphenol polyether-20, nonylphenol polyether-23, nonylphenol polyether-25, nonylphenol polyether-30, nonylphenol polyether-35, nonylphenol polyether-40, nonylphenol polyether-44, nonylphenol polyether-50, nonylphenol polyether-100, nonylphenol polyether-120, nonylphenol polyether-5 carboxylic acid, nonylphenol polyether-8 carboxylic acid, nonylphenol polyether-10 carboxylic acid, nonylphenol polyether-3 phosphate ester, nonylphenol polyether-4 phosphate ester, nonylphenol polyether-6 phosphate ester, nonylphenol polyether-9 phosphate ester, nonylphenol polyether-10 phosphate ester, dinonylol polyether-30, dinonylol polyether-49, dinonylol polyether-100, dinonylol polyether-150, nonylphenol polyether-30, dinonylol polyether-49, dinonylol polyether-100, Dinonylphenolpolyether-7 phosphate, dinonylphenolpolyether-8 phosphate, dinonylphenolpolyether-9 phosphate, dinonylphenolpolyether-10 phosphate, dinonylphenolpolyether-11 phosphate, dinonylphenolpolyether-15 phosphate, dinonylpolyether-24 phosphate, oat oleamidopropyl betaine, octylphenolpolyether-16, octylphenolpolyether-25, octylphenolpolyether-30, octylphenolpolyether-33, octylphenolpolyether-40, octylphenolpolyether-70, octylphenolpolyether-20 carboxylic acid, octyldodecanol polyether-20, octyldodecanol polyether-25, octyldodecanol polyether-30, oleamidopropyl amine oxide, oleamidopropyl betaine, oleamidopropyl (hydroxysulfo) propyl dimethylammonium, oleamido oxide, Oleic acid, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleyl polyether-20, oleyl polyether-23, oleyl polyether-24, oleyl polyether-25, oleyl polyether-30, oleyl polyether-35, oleyl polyether-40, oleyl polyether-44, oleyl polyether-50, oleyl polyether-3 carboxylic acid, oleyl polyether-6 carboxylic acid, oleyl polyether-10 carboxylic acid, oleyl betaine, olivamidopropylamine oxide, olivamidopropyl betaine, olive oleic acid, olivetoyl hydrolyzed wheat protein, ophiopogon root extract stearate, ozonized oleyl polyether-10, ozonized PEG-10 oleate, ozonized PEG-14 oleate, ozonized polysorbate 80, palmitoleic acid, palmitoleylamidopropyl betaine, palmitoleyl polyether-2 phosphate, Palmitoylamidopropylamine oxide, palmitoylamidopropylbetaine, palmitoylamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoylglycine, palmitoylhydrolyzed collagen, palmitoylhydrolyzed milk protein, palmitoylhydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptides, palmitoyl silk amino acids, palmitoleic acid amidopropylbetaine, peach kernel oil glyceryl polyether-8 esters, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocoamide, coconut oil, PEG-8 cocoamine, PEG-12 cocoamine, PEG-150 behenate, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl cocoate, PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl soya oleate, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl tallowate, PEG-80 glyceryl tallowate, PEG-82 glyceryl tallowate, PEG-130 glyceryl tallowate, PEG-200 glyceryl tallowate, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-30 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-60 hydrogenated castor oil, and PEG-30 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitoleid, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate, PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojoba acid, PEG-40 jojoba acid, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60, PEG-70 lanolin, PEG-75 lanolin, PEG-85 lanolin, PEG-100 lanolin, PEG-150 lanolin, PEG-75 lanolin oil, PEG-2 lauramide, PEG-3 laurylamine oxide, PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannide laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanate, PEG-30 oleylamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglyceryl-2 tristearate, PEG/PPG-28/21 acetate polydimethylsiloxane, PEG/PPG-24/18 butyl ether polydimethylsiloxane, PEG/PPG-3/17 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-8/55 copolymer, PEG/PPG-10/30 copolymer, PEG/PPG-10/65 copolymer, PEG/PPG-12/35 copolymer, PEG/PPG-16/17 copolymer, PEG/PPG-20/9 copolymer, PEG/PPG-20/20 copolymer, PEG/PPG-20/60 copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-2 copolymer, PEG/PPG-3538 copolymer, PEG/PPG-3552 copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-24/18 copolymer, PEG/PPG-24/18 copolymer, and PEG/PEG-5/35 copolymer, and PEG/24/18 copolymer, and/PEG/5/35 copolymer, and/PEG/, PEG/PPG-22/25 copolymer, PEG/PPG-28/30 copolymer, PEG/PPG-30-35 copolymer, PEG/PPG-30/55 copolymer, PEG/PPG-35/40 copolymer, PEG/PPG-50/40 copolymer, PEG/PPG-150/35 copolymer, PEG/PPG-160/30 copolymer, PEG/PPG-190/60 copolymer, PEG/PPG-200/40 copolymer, PEG/PPG-300/55 copolymer, PEG/PPG-20/22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG/PPG-4/2 propyl heptyl ether, PEG/PPG-6/2 propyl heptyl ether, PEG/PPG-300/55 copolymer, PEG/PPG-20/22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG/PPG-4/2 propyl heptyl ether, PEG-7/PPG-2 propyl heptyl ether, PEG/PPG-8/2 propyl heptyl ether, PEG/PPG-10/2 propyl heptyl ether, PEG/PPG-14/2 propyl heptyl ether, PEG/PPG-40/2 propyl heptyl ether, PEG/PPG-10/2 ricinoleate, PEG/PPG-32/3 ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate, PEG-120 propylene glycol stearate, PEG-5 rapeseed sterol, PEG-10 rapeseed sterol, PEG-40 ricinoleamide, PEG-75 tallow resin glycerides, PEG-75 buckeye resin glycerides, PEG-20 sorbitan cocoate, PEG-20 sorbitan isostearate, PEG-40 sorbitan lanolate, PEG-75 sorbitan lanolate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, PEG-40 sorbitan stearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soy sterol, PEG-2 stearamide carboxylic acid, PEG-9 stearamide carboxylic acid, PEG-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-10 sorbitan laurate, PEG-20 sorbitan laurate, PEG-40 sorbitan laurate, PEG-10 sorbitan laurate, PEG-20 sorbitan laurate, and PEG-10 sorbitan laurate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallowate, PEG-50 tallowamide, PEG-2 tallowamide DEA, PEG-20 tallowate, PEG-66 trihydroxystearin, PEG-200 trihydroxystearin, PEG-60 camellia oleate glycerides, pelargonic acid, pentadecylphenol polyether-200, phenol polyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 182, PEG-50 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallowamide, PEG-50 tallowamide, PEG-2 tallowamide DEA, PEG-20 tallowester, PEG-66 trihydroxystearin, PEG-200 triolein, PEG-60 camellia oleate glycerides, pelargonic acid, pentadecylphenol polyether-200, phenolpolyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 182, poloxamer 183, poloxamer 184, and poloxamer including glycerol Poloxamer 188, poloxamer 217, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 288, poloxamer 334, poloxamer 335, poloxamer 338, poloxamine 908, poloxamine 1508, dimethicone PEG/PPG-24/19 butyl ether silsesquioxane, dimethicone PPG-13 butyl ether silsesquioxane, Polyglyceryl-6 decanoate, Polyglyceryl-10 dilaurate, Polyglyceryl-20 heptaoctanoate, Polyglyceryl-20 hexacaprylate, Polyglyceryl-2 lauryl ether, Polyglyceryl-10 lauryl ether, Polyglyceryl-20 octoate, Polyglyceryl-6 pentacaprylate, Polyglyceryl-3 dimethicone ethyl dimethicone, Polyglyceryl-6 tetracaprylate, poloxamer 334, poloxamer, Polyglycerol-10 tetralaurate, polyglycerol-6 tricaprylate, polyglycerol-10 trilaurate, polyquaternium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, polyquaternium-81, polyquaternium-82, kumaderrro kamura (POMADERRIS KUMERAHOU) flower/leaf extract, PORIA (PORIA COCOS) extract, potassium abietyl hydrolyzed collagen, potassium babassu oleate, potassium behenate, potassium C9-15 alcohol phosphate, potassium C11-15 alcohol phosphate, potassium C12-13 alcohol phosphate, potassium C12-14 alcohol phosphate, potassium caprate, dipotassium octanoyl glutamate, potassium octanoyl hydrolyzed rice protein, potassium ricinoleate, potassium cocoyl oleate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, corn, Potassium cocoyl keratinate, potassium cocoyl oat protein hydrolysate, potassium cocoyl potato protein hydrolysate, potassium cocoyl rice bran protein hydrolysate, potassium cocoyl rice protein hydrolysate, potassium cocoyl silk hydrolysate, potassium cocoyl soy protein hydrolysate, potassium cocoyl wheat protein hydrolysate, potassium cocoyl yeast protein hydrolysate, potassium cocoyl PCA, potassium cocoyl sarcosinate, potassium cocoyl taurate, potassium corn oleate, potassium cyclopropyl oleate, potassium dihydroxyethyl cocoyl amine oxide phosphate, potassium dimethicone PEG-7 phosphate, potassium dodecylbenzenesulfonate, potassium cannabinoleate, potassium hydrogenated cocoyl oleate, potassium hydrogenated palmitate oleate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium lanolin, potassium laurate, potassium laureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium cocoyl sulfate, potassium cocoyl rice protein hydrolysate, potassium cocoyl silk protein, potassium cocoyl soy protein hydrolysate, potassium cocoyl wheat protein hydrolysate, potassium cocoyl yeast protein hydrolysate, potassium cocoyl calcium carbonate, potassium cocoyl calcium cocoyl sulfate, potassium cocoyl coconut acid, potassium cocoyl fatty acid, potassium salt, potassium lauryl ether-3 fatty acid, potassium lauryl ether-4 fatty acid, potassium lauryl ether fatty acid, potassium salt, potassium lauryl ether fatty acid, potassium salt, potassium lauryl ether fatty acid, potassium salt of fatty acid, sodium salt of sodium lauryl ether, potassium cocoyl fatty acid, sodium lauryl ether, sodium salt of sodium lauryl ether, potassium cocoyl fatty acid, sodium lauryl ether, sodium salt of sodium lauryl ether, sodium lauryl, Potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soybean protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methylcocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olive oleate, potassium oleanoyl hydrolyzed oat protein, potassium oleanoyl hydrolyzed wheat protein, potassium olivetoyl/lauroyl wheat amino acid, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl sulfate, potassium linoleate, potassium olive oleoyl PCA, potassium palmitoleate, potassium palmitate, potassium palmitoyl hydrolyzed zein, potassium palmitoyl hydrolyzed oat protein, potassium palmitoyl hydrolyzed rice protein, potassium palmitoyl hydrolyzed almond protein, potassium palmitoyl hydrolyzed wheat protein, potassium palmate oleate, potassium arachinate, potassium rapeseed oleate, potassium ricinoleate, potassium safflower oleate, potassium soyate, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tallate, potassium tallowate, potassium taurate laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellianate, potassium undecylenate, potassium undecylenoyl hydrolyzed collagen, Undecenoylated potassium rice protein, PPG-30-Butanethole-30, PPG-36-Butanethole-36, PPG-38-Butanethole-37, PPG-30-octanol polyether-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2C9-11 alcohol polyether-8, PPG-1-decanol polyether-5, PPG-3-decanol polyether-2 carboxylic acid, PPG-30-ethylhexanol polyether-4 phosphate, PPG-20-glyceryl polyether-30, PPG-2 hydroxyethyl coconut oil/isostearamide, PPG-2-isodecanol polyether-8, PPG-2-isodecanol polyether-10, PPG-2-isodecanol polyether-18, PPG-2-decylpolyether-25, PPG-4-decylpolyether-10, propyltrimethylammonium hydrolyzed collagen, Quaternary ammonium salt-24, Quaternary ammonium salt-52, Quaternary ammonium salt-87, rapeseed oleic acid, Rice bran acid, Rice oil Glycerol-8 esters, ricinoleic acid amidopropyl betaine, ricinoleic acid polyether-40, safflower oleic acid, Sapindus Oahuensis fruit extract, Saponaria OFFICINALIS (Saponaria OFFICINALIS) root powder, saponin, potassium soap, Sodium/potassium soap, soap base, potassium soap base, sesame oil Glycerol-8 esters, sesame oil amidopropyl amine oxide, sesame amidopropyl betaine, shea butter Glycerol polyether-8 esters, Sodium arachinate, Sodium Arga-nampooacetate, mukul, mukui palm oil Sodium, Sodium avocado oleate, Sodium, Sodium babassu oleoyl amphoacetate, sodium babassu oleate, sodium babassu oil sulfate, sodium behenate, sodium bisglycol ricinoleate sulfosuccinate, sodium bishydroxyethyl glycinate coco glucoside crosslinked copolymer, sodium bishydroxyethyl glycinate lauryl glucoside crosslinked copolymer, sodium borage oil amidopropyl PG-dimethylammonium chloride phosphate, sodium butylphenoxide polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkyl sulfonate, sodium C14-18 alkyl sulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12-13 alkyl sulfate, sodium C12-15 alkyl sulfate, sodium C12-18 alkyl sulfate, sodium C16-20 alkyl sulfate, sodium C9-22 secondary alkyl sulfonate, sodium C14-17 secondary alkyl sulfonate, Sodium caprate, sodium decanoyl amphoacetate, sodium decanoyl amphohydroxypropyl sulfonate, sodium decanoyl amphopropionate, sodium decanoyl methyltaurate, sodium caprylate, sodium octanol polyether-2 carboxylate, sodium octanol polyether-9 carboxylate, sodium octanoyl amphoacetate, sodium octanoyl amphohydroxypropyl sulfonate, sodium octanoyl amphopropionate, disodium octanoyl glutamate, sodium octanoyl hydrolyzed wheat protein, sodium octyl PG-sulfonate, sodium octyl sulfonate, sodium ricinoleate, sodium cetostearyl-13 carboxylate, sodium cetostearyl sulfate, sodium ceteth-13 carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimethylammonium phosphate, sodium cocoamidopropionate, sodium cocoeth sulfate, sodium cocoeth-30 sulfate, sodium cocoyl amphoacetate, sodium cocoate, Sodium cocoyl amphoacetate, sodium cocoyl amphohydroxypropyl sulfonate, sodium cocoyl amphopropionate, sodium cocoyl cocoate, sodium cocoyl alcohol/babassu alcohol sulfate, sodium cocoyl glucoside hydroxypropyl phosphate, sodium cocoyl glucoside hydroxypropyl sulfonate, sodium cocoyl glucoside tartrate, sodium cocoyl alcohol glyceryl ether sulfonate, sodium cocoyl alcohol/hydrogenated tallow alcohol sulfate, sodium cocoyl iminodiacetate, sodium cocoyl monoglyceride sulfate, sodium cocoyl monoglyceride sulfonate, sodium cocoyl PG-dimethyl ammonium chloride phosphate, sodium cocoyl alcohol sulfate, sodium cocoyl sulfoacetate, sodium cocoyl amido propionate, sodium cocoyl amino acid, sodium cocoyl collagen amino acid, disodium cocoyl glutamate, sodium cocoyl glutamate, sodium cocoyl glucoside, sodium cocoyl glyceryl ether phosphate, sodium cocoyl alcohol sulfate, sodium cocoyl amido propionate, sodium cocoyl amido amino acid, sodium cocoyl collagen amino acid, sodium cocoyl glutamate, sodium cocoyl glucoside, and sodium cocoyl glucoside, Sodium cocoyl glycinate, Sodium cocoyl/hydrogenated tallow glutamate, Sodium cocoyl collagenate, Sodium cocoyl keratin hydrolysate, Sodium cocoyl rice protein hydrolysate, Sodium cocoyl fibroin hydrolysate, Sodium cocoyl soy protein hydrolysate, Sodium cocoyl sweet tonsil protein, Sodium cocoyl wheat protein glutamate, Sodium cocoyl isethionate, Sodium cocoyl methylaminopropionate, Sodium cocoyl oat amino acid, Sodium Sodium cocoyl/palmitoyl/Sunfoweryl glutamate, Sodium cocoyl prolinate, Sodium cocoyl sarcosinate, Sodium cocoyl taurate, Sodium cocoyl threonine, Sodium cocoyl wheat amino acid, Sodium C12-14 olefin sulfonate, Sodium C14-16 olefin sulfonate, Sodium C14-18 olefin sulfonate, Sodium C16-18 olefin sulfonate, Sodium corn oleoyl amphoteric Sodium propionate, Sodium cocoyl threonine, Sodium cocoyl wheat amino acid, Sodium C12-14 olefin sulfonate, Sodium C14-16 olefin sulfonate, Sodium C14-18 olefin sulfonate, Sodium C16-18 olefin sulfonate, Sodium corn oleoyl amphoteric Sodium corn oil propionate, Sodium keratide propionate, Sodium cocoyl Sodium keratide, Sodium cocoate, Sodium keratide, Sodium cocoated Sodium keratide, Sodium kerati, Sodium lauroamphoacetate from cottonseed, sodium phosphate ester of C13-15 alkanol polyether-8 butanol, sodium carboxylate of C9-11 alkanol polyether-6, sodium carboxylate of C11-15 alkanol polyether-7, sodium carboxylate of C12-13 alkanol polyether-5, sodium carboxylate of C12-13 alkanol polyether-8, sodium carboxylate of C12-13 alkanol polyether-12, sodium carboxylate of C12-15 alkanol polyether-6, sodium carboxylate of C12-15 alkanol polyether-7, sodium carboxylate of C12-15 alkanol polyether-8, sodium carboxylate of C14-15 alkanol polyether-8, sodium carboxylate of C12-14 secondary alkanol polyether-8, sodium sulfonate of C14-15 alkanol polyether-PG, sodium phosphate of C12-13 alkanol polyether-2, sodium phosphate of C13-15 alkanol polyether-8, sodium sulfate of C9-15 alkanol polyether-3, sodium sulfate of C13-15 alkanol polyether-8, sodium, Sodium C10-15 alkanolpolyether sulfate, sodium C10-16 alkanolpolyether-2 sulfate, sodium C12-13 alkanolpolyether sulfate, sodium C12-15 alkanolpolyether sulfate, sodium C12-15 alkanolpolyether-3 sulfate, sodium C13-15 alkanolpolyether-3 sulfate, sodium C12-14 secondary alkanolpolyether-3 sulfate, sodium C12-15 alkanolpolyether-3 sulfonate, sodium C12-15 alkanolpolyether-7 sulfonate, sodium C12-15 alkanolpolyether-15 sulfonate, sodium decanoeth-2 carboxylate, sodium decanoeth sulfate, sodium decylbenzenesulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di (laureth-7) citrate, sodium di (laureth-10) phosphate, sodium dilinoamidinopropyl PG-dimethylammonium chloride phosphate, sodium decyl glucoside, Sodium dimerized linoleate, sodium di (oleyl polyether-8) phosphate, sodium dodecylbenzenesulfonate, sodium ethyl 2-sulfolaurate, sodium glyceryl oleate phosphate, sodium grapeseed amidopropyl PG-dimethylammonium chloride phosphate, sodium grapeseed acylamino amphoacetate, sodium grapeseed acylamino, sodium cannabinoyl amphoacetate, sodium hexanoeth-4 carboxylate, sodium hydrogenated coconate, sodium hydrogenated cocoyl methyl hydroxyethyl sulfonate, sodium hydrogenated palmityl oleate, sodium hydrogenated tallow, sodium hydrogenated tallowoyl glutamate, sodium lauryl dimethylammonium ethyl phosphate, sodium hydroxypropyl palmityl oleate, sodium hydroxypropyl decyl glucoside cross-linked polymer phosphate, sodium hydroxypropyl lauryl glucoside cross-linked polymer phosphate, sodium hydroxypropyl cocoyl glucoside cross-linked polymer sulfonate, sodium hydroxypropyl decyl glucoside cross-linked polymer sulfonate, sodium lauryl glucoside cross-linked polymer sulfate, sodium lauryl benzene sulfonate, sodium 2-sulfolaurate, sodium glyceryl oleate phosphate, sodium cocoyl chloride, sodium cocoyl glucoside cross-linked polymer sulfate, sodium lauryl dimethyl cocoyl glucoside, sodium lauryl cocoyl glucoside, sodium caproate, sodium cocoyl glucoside cross-linked polymer sulfate, sodium cocoyl glucoside, Sodium hydroxypropyl sulfonate lauryl glucoside cross-linked polymer, sodium hydroxystearate, sodium isostearate, sodium isosteareth-6 carboxylate, sodium isosteareth-11 carboxylate, sodium isosteareth amphoacetate, sodium isosteareth amphopropionate, sodium N-isosteareth methyltaurate, sodium lanolate sulfate, sodium lanolate, sodium lard, sodium lauramidodiacetate, sodium lauraminopropionate, sodium laurate, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, Sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, disodium lauriminodipropionate, sodium lauroamphohydroxypropylsulfonate, sodium lauroamphoPG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycinate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl levulinate, sodium lauroyl sulfate, sodium lauroyl hydroxypropylate, sodium lauroyl levulinate, sodium lauroyl, Sodium lauroyl methyl isethionate, sodium lauroyl Millet amino acid, sodium lauroyl/myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl bis (ethylenediamino) aminoacetate, sodium lauryl glucarate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl diglycol carboxylate, sodium lauryl hydroxyacetamide sulfate, disodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia nut oil, sodium mango oleoyl amphoacetate, sodium mango seed oil, PPG polyether-2 sulfosuccinate/MEA, sodium methoxy-2 acetate, sodium methylcocoyl taurate, sodium PPG polyether-2 sulfosuccinate/MEA, sodium methyl cocoyl taurate, Sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate, sodium isopalmitoyl methyl taurate, sodium methyl taurate cocoyl methyl taurate, sodium myristyl polyether sulfate, sodium myristate, sodium myristoyl amphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristoyl sulfate, sodium nonylphenol polyether-6 phosphate, sodium nonylphenol polyether-9 phosphate, sodium nonylphenol polyether-1 sulfate, sodium nonylphenol polyether-3 sulfate, sodium nonylphenol polyether-4 sulfate, sodium nonylphenol polyether-6 sulfate, Sodium nonylphenol polyether-8 sulfate, sodium nonylphenol polyether-10 sulfate, sodium nonylphenol polyether-25 sulfate, sodium octylphenol polyether-2 ethanesulfonate, sodium octylphenol polyether-2 sulfate, sodium octylphenol polyether-6 sulfate, sodium octylphenol polyether-9 sulfate, sodium oleate, sodium oleamidoamphoacetate, sodium oleamidoamphohydroxypropyl sulfonate, sodium oleamidoamphopropionate, sodium oleamidohydrolyzed collagen, sodium oleamidoisethionate, sodium oleyl polyether sulfate, sodium oleamidomethyl isethionate, sodium oleyl sulfate, sodium oleamidoamphoacetate, sodium oleamidooleate, sodium oleamidoglutamate, sodium palmitomidoamphoacetate, sodium palmitooleate, sodium palmitoyl glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium linoleate, sodium palmitamide oleate, Sodium palmitoyl isethionate, Sodium palmitoyl glutamate, Sodium passion fruit oleate, Sodium arachidoyl amphoacetate, Sodium arachidonate, Sodium PEG-6 cocoamidocarboxylate, Sodium PEG-8 cocoamidocarboxylate, Sodium PEG-4 cocoamidosulfate, Sodium PEG-3 lauramidocarboxylate, Sodium PEG-4 lauramidocarboxylate, Sodium PEG-8 palmitanate, pentaerythrityl hydroxypropyl Sodium iminodiacetate dendrimer, Sodium propoxy PPG-2 acetate, Sodium rapeseed oleate, Sodium rice bran oleoyl amphoacetate, Sodium ricinoleate, Sodium isoacyl amphoacetate, Sodium Sodium Rose hippopapholate, Sodium rosinate, Sodium safflower oleate, Sodium saffloaloyl hydrolyzed soy protein, Sodium sesame seed oleate, Sodium sesame oleoyl amphoacetate, Sodium tallowoyl amphoacetate, Sodium laurylsulfonate, Sodium arachidonate, Sodium cocoamphoacetate, Sodium lauridonate, Sodium oleate, Sodium cocoamphoacetate, Sodium cocoate, Sodium cocoamphoacetate, Sodium palmitate, Sodium cocoamphoacetate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium, Sodium soyate, Sodium soyaetoyl hydrolyzed collagen, Sodium stearate, Sodium stearyl amphoacetate, Sodium stearyl amphohydroxypropyl sulfonate, Sodium stearyl amphopropionate, Sodium stearyl casein, Sodium stearyl glutamate, Sodium stearyl hyaluronate, Sodium stearyl hydrolyzed collagen, Sodium stearyl hydrolyzed zein, Sodium stearyl hydrolyzed silk, Sodium stearyl hydrolyzed soy protein, Sodium stearyl hydrolyzed wheat protein, Sodium stearyl lactalbumin, Sodium Sodium stearyl methyl isethionate, Sodium stearyl oat protein, Sodium stearyl pea protein, Sodium stearyl soy protein, Sodium stearyl dimethylglycinate, Sodium stearyl sulfate, Sodium sunflower oleoyl amphoacetate, Sodium cumaroyl lipopeptide, Sodium sweet mandelyl amphoacetate, Sodium sweet almond oleate, Sodium talloyl amphopropionate, Sodium tallowate, Sodium tallowoyl amphoacetate, Sodium tallow fatty acid, sodium tallow fatty acid ester sulfate, sodium calanolide (calaphllum INOPHYLLUM) oleate, sodium taurate, sodium cocoyl methyl taurate, sodium taurate laurate, sodium lauroyl collagen amino acid/TEA salt, sodium lauroyl hydrolyzed collagen/TEA salt, sodium lauroyl hydrolyzed keratin salt/TEA salt, sodium lauroyl keratin amino acid/TEA salt, sodium undecylenoyl collagen amino acid/TEA salt, sodium undecylenoyl hydrolyzed collagen/TEA salt, sodium undecylenoyl hydrolyzed zein protein/TEA salt, sodium undecylenoyl hydrolyzed soy protein/TEA salt, sodium undecylenoyl hydrolyzed wheat protein/TEA salt, cocoa mass (THEOBROMA gradiflower) oleate, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, Sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium trideceth sulfate, sodium trimethylolpropane hydroxypropyl iminodiacetate dendrimer, sodium undecyleth-5 carboxylate, sodium undecylenate amphoacetate, sodium undecylenate propionate, disodium undecylenate glutamate, sodium wheatgerm oleoyl amphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean oleylpropylamine oxide, soybean oleylpropyl betaine, soybean oleyl polyether-8 esters, isostearamidopropylamine oxide, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium undecylenate polyether-5 carboxylate, sodium undecylenate amphoacetate, sodium undecylenate amphopropionate, disodium undecylenate glutamate, sodium wheat germ oleoyl amphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean oleyl propionate, soybean oleyl propylamine oxide, soybean oleyl betaine, sodium isostearamidopropylamine oxide, sodium isostearyl betaine, sodium trideceth-8 esters, sodium trideceth-12 carboxylate, sodium trideceth-12, sodium trideceth-5 carboxylate, sodium undecylenate sulfate, sodium undecylenate-8, sodium undecylenate-2, sodium undecylenate-8, sodium undecylenate-2, sodium undecylenate, Stearamidopropyl betaine, stearylamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, steareth-80, steareth-100, steareth-2 phosphate, steareth-3 phosphate, stearic acid, stearyloxypropyl trimethylammonium chloride, stearoylglutamic acid, stearoyl sarcosine, stearyl betaine, stearyldimethylbutyl glucoside hydroxypropylammonium chloride, stearyldimethyldecyl glucoside hydroxypropylammonium chloride, stearyldilauryl glucoside ammonium chloride, sulfated castor oil, sulfated coconut oil, and mixtures thereof, Sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oil amide MEA, sunflower oil oleic acid, sunflower oil amide propyl hydroxyethyl dimethyl ammonium chloride, sunflower oil glyceryl polyether-8 esters, tall oil acid, tallow amidopropyl amine oxide, tallow amidopropyl betaine, tallow amidopropyl hydroxysultaine, tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow acyl ethyl glucoside, abietyl hydrolyzed collagen salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol TEA sulfate, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate salt, TEA C14-17 secondary alkyl sulfonate salt, low erucic acid seed oleate TEA salt, Cocamide diacetate TEA salt, cocoate TEA salt, cocoyl sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamate TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soy protein TEA salt, cocoyl sarcosine TEA salt, dimethicone PEG-7 phosphate TEA salt, dodecylbenzene sulfonate TEA salt, hydrogenated cocoyl acid TEA salt, hydrogenated tallow acyl glutamate TEA salt, isostearic acid TEA salt, TEA-isostearoyl hydrolyzed collagen TEA salt, lauramidopropionic acid TEA salt, lauric acid/myristic acid TEA salt, laureth sulfate TEA salt, lauroyl collagen amino acid TEA salt, lauroyl glutamate TEA salt, lauroyl hydrolyzed collagen TEA salt, lauroyl keratin amino acid TEA salt, lauroyl methylaminopropionic acid salt, Lauroyl/myristoyl aspartate TEA salt, lauroyl sarcosinate TEA salt, lauryl phosphate TEA salt, lauryl sulfate TEA salt, myristoyl aminopropionate TEA salt, myristic acid TEA salt, myristoyl hydrolyzed collagen TEA salt, oleic acid TEA salt, oleoyl hydrolyzed collagen TEA salt, oleoyl sarcosinate TEA salt, oleyl sulfate TEA salt, palmitic acid TEA salt, palm kernel sarcosinate TEA salt, PEG-3 cocamide sulfate TEA salt, pinoceric acid TEA salt, stearic acid TEA salt, tall acid TEA salt, tridecyl benzene sulfonate TEA salt, undecylenic acid TEA salt, undecylenoyl hydrolyzed collagen TEA salt, tetramethyl decyndiol, dicarboxyethyl stearyl sulfosuccinate tetrasodium, laureth TIPA salt, lauryl sulfate TIPA salt, myristic acid TIPA salt, stearic acid TIPA salt, tocopherol phosphate, trehalose undecylenate, TM-C12-15-Alkanopolyether-2 phosphate, TM-C12-15-Alkanopolyether-6 phosphate, TM-C12-15-Alkanopolyether-8 phosphate, TM-C12-15-Alkanopolyether-10 phosphate, trideceth-20, trideceth-50, trideceth-3-carboxylic acid, trideceth-4-carboxylic acid, trideceth-7-carboxylic acid, trideceth-8-carboxylic acid, trideceth-15-carboxylic acid, trideceth-19-carboxylic acid, trideceth-10 phosphate, tridecylbenzenesulfonic acid, tris (laureth-9) citrate, trimethylolpropane hydroxypropyl bishydroxyethylamine dendrimer, tris (lauroamphoPG-sodium acetate chloride) phosphate, tris (lauroampho PG-sodium acetate chloride) phosphate, Undecanoic acid, undecyleth-5 carboxylic acid, undecylenamidopropylamine oxide, undecylenamidopropylbetaine, undecylenic acid, undecylenoyl collagen amino acid, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acids, undecyl glucoside, wheat germ oleic acid, wheat germ oleamidopropyl amine oxide, wheat germ oleamidopropyl betaine, YUCCA (YUCCA SCHIDIGERA) leaf/root/stem extract, YUCCA SCHIDIGERA stem extract, zinc cocoeth sulfate, and zinc cocoeth sulfate.

Preferred compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, coco glucoside and ammonium laureth sulfosuccinate.

The percentage content of surfactant in the formulation may be from 0.1 to 10% by weight, and preferably from 0.5 to 5% by weight, based on the formulation.

Oil body

The composition may also comprise oil bodies, also known as lipids, such as:

(i) linear or branched saturated paraffins (mineral oils) having 15 or more carbon atoms, in particular having from 18 to 45 carbon atoms;

(ii) esters having 12 or more carbon atoms of linear or branched fatty acids having 6 to 30 carbon atoms and linear or branched, saturated or unsaturated mono-, di-or triols having 3 to 30 carbon atoms, these esters having no free hydroxyl groups;

(iii) esters of benzoic acid and straight or branched, saturated or unsaturated monoalkanols having 8 to 20 carbon atoms;

(iv) monoesters or diesters of alcohols having 3 to 30 carbon atoms with naphthalene-monocarboxylic or dicarboxylic acids; especially naphthalene-monocarboxylic acid C₆-C₁₈di-C esters and naphthalenedicarboxylic acids₆-C₁₈An ester;

(v) straight or branched, saturated or unsaturated di-C₆-C₁₈-an alkyl ether;

(vi) a silicone oil;

(vii) 2-alkyl-1-alkanols of the general formula (III)

Wherein

Q1 is a straight or branched chain alkyl group having 6 to 24 carbon atoms, and

q2 is a straight or branched chain alkyl group having 4 to 16 carbon atoms.

The oil phase or oil component in the narrow (and preferred) sense of the invention, i.e. the oil phase or oil component of the substances defined in the invention or of the substances present in only a small fraction, comprises the following substance groups:

(i) linear or branched saturated paraffins having from 20 to 32 carbon atoms;

(ii) esters having at least 14 carbon atoms of linear or branched saturated fatty acids having 8 to 24 carbon atoms and linear or branched, saturated or unsaturated mono-, di-or triols having 3 to 24 carbon atoms, which esters are free of free hydroxyl groups;

(iii) esters of benzoic acid and straight or branched chain saturated monoalkanols having 10 to 18 carbon atoms;

(iv) alkyl glycol dicaprylate/dicaprate, especially propylene glycol dicaprylate/dicaprate;

(v) linear or branched saturated di-C6-C18-alkyl ethers, especially (linear) di-C6-C12-alkyl ethers;

(vi) a silicone oil selected from the group consisting of cyclotrisiloxane, cyclopentasiloxane, dimethylpolysiloxane, diethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, and mixtures thereof;

(vii) 2-alkyl-1-alkanols having 12 to 32C atoms of the formula (III), in which Q₁Is a (preferably linear) alkyl group having 6 to 18C atoms and Q2 is a (preferably linear) alkyl group having 4 to 16C atoms.

The oil phase in the narrowest (and most preferred) sense of the invention comprises the following group of substances:

(i) linear or branched saturated alkanes having 20 to 32 carbon atoms, such as isoeicosane or squalane;

(ii) esters having at least 16 carbon atoms of linear or branched saturated fatty acids having 8 to 18 carbon atoms and linear or branched, saturated mono-, di-or triols having 3 to 18 carbon atoms, which esters are free of free hydroxyl groups;

(iii) esters of benzoic acid with straight-chain or branched saturated monoalkanols having 12 to 15 carbon atoms, especially benzoic acid C_12-15-an alkyl ester;

(iv) alkyl glycol dicaprylate/dicaprate, especially propylene glycol dicaprylate/dicaprate;

(v) straight chain di-C₆-C₁₀Alkyl ethers, especially di-n-octyl ether (dioctyl ether);

(vi) silicone oil selected from the group of undecylcyclotrisiloxane, cyclomethicone, decamethylcyclopentasiloxane, dimethylpolysiloxane, diethylpolysiloxane, methylphenylpolysiloxane and diphenylpolysiloxane;

(vii) 2-alkyl-1-alkanols having 12 to 32C atoms of the formula (III), in which Q₁Is a (preferably linear) alkyl group having 6 to 18C atoms and Q2 is a (preferably linear) alkyl group having 4 to 16C atoms.

Particularly preferred components of type (i) in the oil phase are as follows: isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyl decyl stearate, 2-octyl dodecyl palmitate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, 2-ethylhexyl isostearate, isotridecyl isononanoate, 2-ethylhexyl cocoate, caprylic/capric triglyceride, alkyl glycol dicaprylate/dicaprate, especially propylene glycol dicaprylate/dicaprate; and synthetic, semi-synthetic and natural mixtures of these esters, such as jojoba oil.

The fatty acid triglycerides (oil component of type (i) in the oily phase) may also be in the form of synthetic, semi-synthetic and/or natural oils or components, such as olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and mixtures thereof.

Particularly preferred types of oil components (vii) in the oil phase are the following: 2-butyl-1-octanol, 2-hexyl-1-decanol, 2-octyl-1-dodecanol, 2-decyltetradecanol, 2-dodecyl-1-hexadecanol and 2-tetradecyl-1-octadecanol.

An especially preferred oil component in the oil phase is a composition comprising benzoic acid C₁₂-C₁₅Mixture of alkyl esters and 2-ethylhexyl isostearate, containing benzoic acid C₁₂-C₁₅Mixture of alkyl ester and isotridecyl isononanoate, containing benzoic acid C₁₂-C₁₅-a mixture of alkyl esters, 2-ethylhexyl isostearate and isotridecyl isononanoate, a mixture comprising cyclomethicone and isotridecyl isononanoate, and a mixture comprising cyclomethicone and 2-ethylhexyl isostearate.

Suitable oil bodies, which are constituents of O/W emulsions, are, for example, based on Guerbet alcohols having from 6 to 18, preferably from 8 to 10, carbon atoms, esters of linear C6-C22-fatty acids with linear or branched C6-C22-aliphatic alcohols or esters of branched C6-C13-carboxylic acids with linear or branched C6-C22-aliphatic alcohols, such as, for example, myristyl myristate, palmTetradecyl acid ester, tetradecyl stearate, tetradecyl isostearate, tetradecyl oleate, tetradecyl behenate, tetradecyl erucate, hexadecyl myristate, hexadecyl palmitate, hexadecyl stearate, hexadecyl isostearate, hexadecyl oleate, hexadecyl behenate, hexadecyl erucate, octadecyl myristate, octadecyl palmitate, octadecyl stearate, octadecyl isostearate, octadecyl oleate, octadecyl behenate, octadecyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, etc, Erucic acid oleyl ester, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, erucic acid behenyl ester, erucic acid ester, erucic acid ester, stearic acid erucic acid ester, isostearic acid erucic acid ester, oleic acid erucic acid ester, erucic acid ester, and erucic acid ester. Furthermore suitable are esters of linear C6-C22-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38-alkylhydroxycarboxylic acids with linear or branched C6-C22-aliphatic alcohols, in particular dioctyl malate, esters of linear and/or branched fatty acids with polyhydric alcohols, such as, for example, propylene glycol, dimer diol (Dimerdiol) or trimer triol (trimerdiol)), and/or Guerbet alcohol, triglycerides based on C6-C10-fatty acids, liquid mono-/di-/triglyceride mixtures based on C6-C18-fatty acids, esters of C6-C22-aliphatic alcohols and/or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C2-C12-dicarboxylic acids with linear or branched alcohols having from 1 to 22 carbon atoms or polyhydric alcohols having from 2 to 10 carbon atoms and from 2 to 6 hydroxyl groups, Vegetable oils, branched primary alcohols, substituted cyclohexanes, carbonates of straight-chain and branched C6-C22-aliphatic alcohols, such as, for example, dioctyl carbonate (C: (C) CC), Guerbet carbonates based on aliphatic alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with straight-chain and/or branched C6-C22-alcohols (e.g. C6-C22-C H-CTN), straight-chain or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl radical, such as, for example, dioctanoyl ethers (C-O-), (C-O-H-) and (C-O-H-), (C-H-O-H-O-H-O-H-HOE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicone, silicone methyl silicone oil grades, etc.) and/or aliphatic or cycloalkanes, such as, for example, squalane, squalene or dialkylcyclohexane.

Emulsifier

Other nonionic or cationic surfactants may also be added to the formulation as emulsifiers, including, for example:

2 to 30 mol of ethylene oxide and/or 0 to 5 mol of propylene oxide with linear C_8-22Aliphatic alcohol, and C_12-22An addition product of a fatty acid and an alkylphenol having 8 to 15 carbon atoms in the alkyl group;

c of addition products of 1 to 30 mol of ethylene oxide to glycerol_12/18Fatty acid mono-and diesters;

saturated and unsaturated fatty acid glycerol mono-and diesters and sorbitan mono-and diesters containing from 6 to 22 carbon atoms and ethylene oxide addition products thereof;

addition products of 15 to 60 mol of ethylene oxide to castor oil and/or hydrogenated castor oil;

Polyol esters, in particular polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dipolymer oleoisostearate. Also suitable are mixtures of a plurality of such compounds;

addition products of 2 to 15 mol of ethylene oxide to castor oil and/or hydrogenated castor oil;

based on straight-chain, branched, unsaturated or saturated C_6/22Fatty acid, fatty acid,Ricinoleic acid and partial esters of 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g. cellulose);

mono-, di-and trialkyl phosphates and mono-, di-and/or tri-PEG alkyl phosphates and salts thereof;

lanolin alcohols;

polysiloxane/polyalkylpolyether copolymers and corresponding derivatives;

mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohols and/or C_6-22Mixed fats of fatty acids, methyl glucose and polyhydric alcohols, preferably glycerol or polyglycerin;

polyglycols and

glycerol carbonate.

Addition products of ethylene oxide and/or propylene oxide with aliphatic alcohols, fatty acids and alkylphenols, mono-and diesters of glycerol and sorbitan mono-and diesters of fatty acids or castor oil are commercially available products. Here, a homologous mixture is meant whose average degree of alkoxylation corresponds to the proportion of ethylene oxide and/or propylene oxide and matrix used for the addition reaction. The C12/18 fatty acid mono-and diesters of ethylene oxide with glycerol addition products are known for use as superfatting agents in cosmetic formulations. Preferred emulsifiers are listed in detail below:

Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride and technical mixtures thereof still containing small amounts of triglycerides originating from the production process. Addition products of from 1 to 30 and preferably from 5 to 10 mol of ethylene oxide to the abovementioned partial glycerides are likewise suitable.

Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan monooleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan erucate, sorbitan trilerucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diferucate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan sesquistearate, and mixtures thereof, Sorbitan ditartrate, sorbitan tritartrate, sorbitan mono-citrate, sorbitan sesquicitrate, sorbitan di-citrate, sorbitan tri-citrate, sorbitan mono-maleate, sorbitan sesquimaleate, sorbitan dimaleate and technical mixtures thereof. Addition products of from 1 to 30 and preferably from 5 to 10 mol of ethylene oxide to the sorbitan esters mentioned above are likewise suitable.

A polyglycerol ester. A typical example of a suitable polyglycerol ester is polyglycerol-2 dipolyhydroxystearate (CPGPH), polyglyceryl-3-diisostearate (poly (glycerol-3-diisostearate) (PGPH)TGI), polyglyceryl-4 isostearate ((II)GI 34), polyglycerin-3 oleate, polyglycerin-3 diisostearate (PDI), polyglycerol-3 methylglucdistearate (Tego)450) Polyglycerol-3 beeswax (Cera)) Polyglycerol-4-decanoate (polyglycerol decanoate T2010/90), polyglycerol-3-cetyl ether (C: (C))NL), polyglycerol-3 distearate (C)GS 32 and polyglycerol polyricinoleate: (WOL 1403), polyglycerol diisostearate (polyglyceryl diisostearate) ester, and mixtures thereof. Examples of other suitable polyol esters are mono-, di-and triesters of lauric, coconut, tallow, palmitic, stearic, oleic, behenic acid and the like with trimethylolpropane or pentaerythritol, optionally reacted with 1 to 30 moles of ethylene oxide.

The cationic active surfactant contains a hydrophobic polymer group required for having surface activity in a cation by dissociation in an aqueous solution. An important group of representatives of the cationic surfactants are the general formula (R)¹R²R³R⁴N⁺)X^-The tetraalkylammonium salt of (1). Herein, R is ¹Is represented by C₁-C₈Alk (en) yl, R²、R³And R⁴Independently of one another, represent alk (en) yl groups having from 1 to 22 carbon atoms. X is a counter ion, preferably selected from the group consisting of halides, alkyl sulfates and alkyl carbonates. Particular preference is given to cationic surfactants in which the nitrogen radical is substituted by two long acyl radicals and two short alk (en) yl radicals.

Ester quaternary ammonium salt. One group of cationic surfactants particularly useful as co-surfactants in the present invention are the so-called esterquats. Esterquats are usually referred to as quaternized fatty acid triethanolamine ester salts. They are known compounds and can be obtained by processes relevant to the preparation of organic chemistry. In this connection reference is made to international patent application WO 91/01295a1, in which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture and the whole is subsequently quaternized with dimethyl sulfate or ethylene oxide. Furthermore, german patent DE 4308794C 1 describes a process for preparing solid ester quaternary ammonium salts in which the quaternization of the triethanolamine ester is carried out in the presence of suitable dispersants, preferably fatty alcohols.

Typical examples of ester quats suitable for use in the present invention are products wherein the acyl component is derived from a monocarboxylic acid of the formula RCOOH wherein RCO is an acyl group containing 6 to 10 carbon atoms-the amine component is Triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, the so-called head fractionated fatty acids. It is preferred to use ester quaternary ammonium salts in which the acyl component is derived from a monocarboxylic acid containing from 8 to 10 carbon atoms. Other esterquats are those in which the acyl component is derived from a dicarboxylic acid, such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and/or dodecanedioic acid, but adipic acid is preferred. In general, it is preferred to use esterquats whose acyl component is derived from a mixture of monocarboxylic acids having from 6 to 22 carbon atoms and adipic acid. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat is from 1:99 to 99:1, and preferably from 50:50 to 90:10 and more particularly from 70:30 to 80: 20. In addition to the quaternized fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of mono/dicarboxylic acid mixtures with diethanolylamine or 1, 2-dihydroxypropyldialkylamine. Esterquats can be obtained from fatty acids and from the corresponding triglycerides in admixture with the corresponding dicarboxylic acids. One such process, which is representative of the relevant prior art, is proposed by european patent EP 0750606B 1. To prepare the quaternized esters, mixtures of mono-and dicarboxylic acids and triethanolamine in a molar ratio of 1.1:1 to 3:1, based on available carboxyl functional groups, can be used. In view of the properties of esterquats, ratios of 1.2:1 to 2.2:1, and in particular of 1.5:1 to 1.9:1, have proved particularly advantageous. Preferred esterquats are technical mixtures of mono-, di-and triesters having an average degree of esterification of from 1.5 to 1.9.

It is further advantageous to use a combination of anionic and/or amphoteric surfactants with one or more nonionic surfactants. In a preferred embodiment according to the present invention, the composition further comprises an emulsifier selected from the group consisting of:

alkyl phosphate derivatives

Glycerol oleic acid citrate derivative

Glycerol stearate citrate derivative

Stearic acid ester

Sorbitol ester

Ethoxylated sorbitol ester

Ethoxylated mono-, di-and triglycerides

Methyl glucose ester

Superfatting agent and consistency factor

Superfatting agents may be selected from substances such as, for example, lanolin and lecithin, and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, where fatty acid alkanolamides may also be used as foam stabilizers.

The main consistency factors used are fatty or hydroxy fatty alcohols and partial glycerides, fatty acids or hydroxy fatty acids containing from 12 to 22 and preferably from 16 to 18 carbon atoms. Preference is given to using combinations of these substances with alkyl oligoglucosides and/or fatty acids of the same chain length N-methylglucamides and/or polyglycerol poly-12-hydroxystearate.

Thickeners and rheological additives

Suitable thickeners are polymeric thickeners, e.g.Class (hydrophilic silica), polysaccharides, more particularly xanthan gum, guar gum, agar, alginates and cellulose acetateSodium salts (tyloses), carboxymethylcellulose and hydroxyethyl and hydroxypropyl cellulose, and the relatively high molecular weight polyethylene glycol mono-and diesters of fatty acids, polyacrylates (e.g., sodium hydroxide, and sodium hydroxide, sodium hydroxide[Goodrich]Or[Sigma]) Polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyhydric alcohols, such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates of narrow homologue distribution and electrolytes, such as sodium chloride and ammonium chloride.

Polymer and method of making same

Suitable polymers are used to improve the spreadability of the composition on the skin or hair, or to improve the water and/or perspiration resistance and/or abrasion resistance of the formulation and to improve the protection factor of the composition. Examples of such polymers are: VP/eicosene copolymers sold under the trade name Antaron V-220 by International Specialty Products, VP/hexadecene copolymers sold under the trade names Antaron V-216 and Antaron V-516 by International Specialty Products, Tricontanyl PVP sold under the trade name Antaron WP-660 by International Specialty Products, Versagel MC and MD isohexadecane and ethylene/propylene/styrene copolymers and butylene/styrene copolymers sold under the trade names Versagel MC and MD by Penreco, hydrogenated polyisobutene and ethylene/propylene/styrene copolymers and butylene/styrene copolymers sold under the trade names Versagel ME by Penreco, acrylate/octylacrylamide copolymers sold under the trade names Dermacryl 79, Dermacryl AQF and Dermacryl-macrocryl LT by Akzo Nobel, polyurethane copolymers sold under the trade name Avalure UR 450 and AVI, such as PPG/IPD 17/PPG PA 525 copolymers, polyurethane copolymers sold under the trade name DMI-P450 by Noveon, Polyurethanes-2 and-4 sold under the trade names Avalure UR-405, -410, -425, -430 and-445525 by Noveon, polyurethane 5 and butyl acetate and isopropanol sold under the trade names Avalure UR-510 and-525 by Noveon, polyurethanes-1 and-6 sold under the trade name Luviset PUR by BASF, hydrodimeric dioleyl/dimethyl carbonate copolymer sold under the trade name Cosmedia DC by Cognis.

Of course, as is known to those skilled in the art of cosmetic, dermatological and pharmacological compositions, this is not an exhaustive list and other suitable polymers not listed here may be used. Examples of such polymers are found in the latest version of the CTFA international cosmetic ingredient dictionary.

The amount of polymer used to achieve the desired effect in the formulation is from 0.10% to 5.0% by weight of the composition, especially from 0.25% to 3.0% by weight of the composition.

Pearly wax

Suitable pearlescent waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut oil fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with aliphatic alcohols having 6 to 22 carbon atoms, especially the long-chain esters of tartaric acid; fatty substances having a total of at least 24 carbon atoms, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, especially laurone and distearyl ether; fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of epoxy olefins having 12 to 22 carbon atoms with aliphatic alcohols having 12 to 22 carbon atoms and/or polyols having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

Silicone

Suitable silicones are selected from the group consisting of theophylline methylsilanol mannuronate, acetylmethionyl methylsilanol elastin ester acrylate/behenyl acrylate, acrylate/behenyl methacrylate/dimethicone methacrylate copolymer, acrylate/bis-hydroxypropyl dimethicone crosspolymer, acrylate/dimethicone copolymer, acrylate/dimethicone methacrylate/ethylhexyl acrylate copolymer, acrylate/dimethiconol acrylate copolymer, acrylate/ethylhexyl acrylate/dimethicone methacrylate copolymer, ethylhexylacrylate/dimethicone methacrylate copolymer, and mixtures thereof, Acrylic acid (ester)/octylacrylamide/diphenylamino terminal polydimethylsiloxane copolymer, acrylic acid (ester)/polytrimethylsiloxane methacrylate copolymer, acrylic acid (ester)/propylpolytrimethylsiloxane methacrylate copolymer, acrylic acid (ester)/stearyl acrylate/polydimethylsiloxane methacrylate copolymer, acrylic acid (ester)/tridecyl acrylate/triethoxysilylpropanol methacrylate/polydimethylsiloxane methacrylate copolymer, acrylic acid (ester)/trifluoropropyl methacrylate/polytrimethylsiloxane methacrylate copolymer, aminodipropylpolydimethylsiloxane, aminoethylaminopropylpolydimethylsiloxane, aminopropylpolydimethylsiloxane, aminodipropylpolydimethylsiloxane, acrylic acid (ester)/propylmethacrylate copolymer, acrylic acid (ester)/stearyl acrylate/stearyl methacrylate copolymer, and the like, Aminopropylphenyl trimethicone, aminopropyltriethoxysilane, polydimethyl siloxane PEG-7 ammonium sulfate, aminoterminal polydimethylsiloxane hydroxystearate, aminoterminal polydimethylsiloxane/silsesquioxane copolymer, carboxydecyl trisiloxane ascorbate, methylsilanol ascorbate pectate, behenoxy polydimethylsiloxane, behenyltrimethylammonium polydimethylsiloxane PEG-8 phthalate, behenyl polydimethylsiloxane, bisaminoPEG/PPG-41/3 aminoethyl PG-propyl polydimethylsiloxane, bis-aminopropyl/ethoxyaminopropyl polydimethylsiloxane, bis (butyl benzoate) diaminotriazine aminopropyltrisiloxane, bis-butyldimethylsiloxane polyglycerol-3, di-butyldimethylsiloxane, Bis-butoxyaminoterminated polydimethylsiloxane/PEG-60 copolymer, bis (C13-15 alkoxy) hydroxybutyramimidoterminated polydimethylsiloxane, bis (C13-15 alkoxy) PG-aminoterminated polydimethylsiloxane, bis- (C1-8 alkyllauroyllysyldecyxamide) polydimethylsiloxane, bis-cetylcetyl polydimethylsiloxane, bis-cetyl/PEG-8 cetyl PEG-8 dimethylsiloxane, bis-diphenylethyldisiloxane, bis-ethylethylmethicone, bis-glucamidoethyl-aminopropyldisiloxane, bis-hydrogenpolydimethylsiloxane, bis-hydroxyethoxypropyldisiloxane bis-hydroxylauryl, polydimethylsiloxane/IPDI copolymer, bis (C13-15 alkoxy) hydroxybutyramido-aminoterminated polydimethylsiloxane, bis- (C1-8 alkoxy) PG-aminobutylmethicone, bis- (C1-8 alkyllauroyllysyldecylamide-decylamide) polydimethylsiloxane, bis-cetylcetyl-dimethicone, bis-cetyl/PEG-8-dimethicone, bis-hydroxyethylmethicone, bis-hydroxyethylsiloxane, bis-hydioxypropyldisiloxane, dimethicone/IPDI copolymer, and combinations thereof, Bis-hydroxy/methoxyaminoterminated polydimethylsiloxane, bis-hydroxypropyl dimethylsiloxane behenate, bis-hydroxypropyl polydimethylsiloxane/SMDI copolymer, bis-isobutyl PEG-14/polydimethylsiloxane copolymer, bis-isobutyl PEG-15/polydimethylsiloxane copolymer, bis-isobutyl PEG/PPG-20/35/polydimethylsiloxane copolymer, bis-isobutyl PEG/PPG-10/7/polydimethylsiloxane copolymer, bis-isobutyl PEG-24/PPG-7/polydimethylsiloxane copolymer, bis-PEG-1 polydimethylsiloxane, bis-PEG-4 polydimethylsiloxane, bis-PEG-8 polydimethylsiloxane, bis-isobutyl PEG-14/polydimethylsiloxane, bis-PEG-12 polydimethylsiloxane, bis-PEG-20 polydimethylsiloxane, bis-PEG-12 polydimethylsiloxane beeswax, bis-PEG-12 polydimethylsiloxane candelilla wax, bis-PEG-15 polydimethylsiloxane/IPDI copolymer, bis-PEG-15 methyl ether polydimethylsiloxane, bis-PEG-18 methyl ether dimethylsilane, bis-PEG/PPG-14/14 polydimethylsiloxane, bis-PEG/PPG-15/5 polydimethylsiloxane, bis-PEG/PPG-18/6 polydimethylsiloxane, bis-PEG/PPG-20/20 polydimethylsiloxane, bis-PEG/PPG-16/16 PEG/PPG-16/16 polydimethylsiloxane, bis-PEG/PPG-20/5 PEG/PPG-20/5 polydimethylsiloxane, bisphenylhexamethylsiloxane, bis-phenylpropyldimethicone, bis-polyvinyldimethicone, bis (polyglyceryl-3 hydroxyphenylpropyl) dimethicone, bis- (polyglyceryl-7 hydroxyphenylpropyl) dimethicone, bis-PPG-15 dimethicone/IPDI copolymer, bis (PPG-7 undecenylpolyether-21) dimethicone, bis-stearyldimethicone, bis-trimethylsilylethyldisiloxanyl dimethicone, bis-vinylpolydimethylsiloxane/dimethicone copolymer, Glass seed oil PEG-7 polydimethylsiloxanes, butyl acrylate/C6-14 perfluoroalkyl alcohol acrylate/mercaptopropyl polydimethyl siloxane copolymer, butyl acrylate/hydroxypropyl polydimethyl siloxane acrylate copolymer, butyl polydimethyl siloxane acrylate/cyclohexyl methacrylate/ethylhexyl acrylate copolymer, butyl polydimethyl siloxane methacrylate/methyl methacrylate crosspolymer, t-butyl dimethyl silyl grape seed extract, butyl polydimethyl siloxane ethylene/propylene/ethylene norbornene copolymer, C6-8 alkyl C3-6 alkyl glucoside polydimethylsiloxane, C20-24 alkyl polydimethylsiloxane, C24-28 alkyl polydimethylsiloxane, C26-28 alkyl polydimethylsiloxane, poly (ethylene glycol methyl methacrylate-co-ethyl methacrylate copolymer, poly (ethylene-co-ethyl methacrylate-co-ethyl methacrylate copolymer, poly (ethylene-ethyl methacrylate copolymer), poly (ethyl methacrylate-ethyl methacrylate copolymer), methyl methacrylate copolymer, ethyl methacrylate-ethyl methacrylate copolymer, methyl methacrylate-ethyl methacrylate copolymer, methyl methacrylate copolymer, C20-7-alkyl polydimethylsiloxane, C-7-alkyl polydimethylsiloxane, C-alkyl polydimethylsiloxane, C-7-alkyl polydimethylsiloxane, C-7-C-alkyl polydimethylsiloxane, C-PEG-C-7-C-7-alkyl polydimethylsiloxane, C-7-C-alkyl polydimethylsiloxane, C-7-C-alkyl polydimethylsiloxane, C-alkyl polydimethylsiloxane, C-alkyl polydimethylsiloxane, C-7-C, C30-45 alkyl polydimethylsiloxane, C30-60 alkyl polydimethylsiloxane, C32 alkyl polydimethylsiloxane, C30-45 alkyl polydimethylsiloxane/cyclohexene oxide crosslinked polymer, C26-28 alkanol dimethylsilylpropylsilsesquioxane, C30-45 alkanol dimethylsilylpropylsilsesquioxane, C20-24 alkyl polymethylsiloxane, C24-28 alkyl polymethylsiloxane, C26-28 alkyl polymethylsiloxane, C30-45 alkyl polymethylsiloxane, C20-28 alkyl perfluorodecylethoxy polydimethylsiloxane, C26-54 alkyl tetradecane polydimethyl siloxane, octyl polydimethylsiloxane ethoxyglucoside, octyl polymethylsiloxane, octyl trimethicone, methyl silicone, carboxydecyl trisiloxane, castor oil bis-hydroxypropyl dimethicone, cetyl dimethicone, cetearyl dimethicone crosspolymer, cetearyl dimethicone/vinyl dimethicone crosspolymer, cetearyl methicone, cetearyl carboxydecyl PEG-8 dimethicone salt, cetearyl dimethicone PEG-7 phthalate salt, cetyl behenyl dimethicone salt, cetyl dimethicone/divinyl dimethicone crosspolymer, cetyl hexacyano dimethicone, cetoxy dimethicone, cetyl PEG-8 dimethicone, cetyl PEG/PPG-15/15 butyl ether dimethicone, cetyl dimethicone, and mixtures thereof, Cetyl PEG/PPG-7/3 polydimethylsiloxane, cetyl PEG/PPG-10/1 polydimethylsiloxane, cetyl triethylammonium polydimethylsiloxane PEG-8 phthalate, cetyl triethylammonium polydimethylsiloxane PEG-8 succinate, copper methyl silanol acetyl tyrosine, copper methyl silanol PCA, C4-14 perfluoroalkoxyethyl polydimethylsiloxane, cycloethoxymethicone, cycloheptasiloxane, cyclohexasiloxane, cyclomethicone, cyclopentadimethicone, cyclophenylpolymethicone, cyclotetrasilyl tetramethicone, cyclovinylpolymethoxysilane, cystine bis-PG-propylsilanetriol, DEA PG-propyl PEG/PPG-18/21 polydimethylsiloxane, poly (N-methyl ethyl methacrylate), poly (N-ethyl methacrylate), poly (propylene glycol), poly (, Diisostearoyl trimethylolpropane siloxysilicate, dilauroyl trimethylolpropane siloxanyl silicate, dilinoleamidopropyl dimethylamine polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane crosspolymer-3, polydimethylsiloxane/divinylpolydimethylsiloxane/silsesquioxane crosspolymer, polydimethylsiloxane ethoxyglucoside, polydimethylsiloxane hydroxypropyl trimonium chloride, polydimethylsiloxane/mercaptopropyl methicone copolymer, polydimethylsiloxane PEG-15 acetate, polydimethylsiloxane PEG-8 adipate, polydimethylsiloxane PEG-7 avocado oleate, polydimethylsiloxane PEG-8 avocado oleate, sodium lauryl sulfate, sodium chloride, sodium lauryl sulfate, Polydimethylsiloxane PEG-8 beeswax, polydimethylsiloxane PEG-8 benzoate, polydimethylsiloxane PEG-8 borage oleate, polydimethylsiloxane PEG-7 cocoate, polydimethylsiloxane/PEG-10 crosspolymer, polydimethylsiloxane PEG-10/15 crosspolymer, polydimethylsiloxane PEG-15 crosspolymer, polydimethylsiloxane PEG-7 isostearate, polydimethylsiloxane PEG-8 isostearate, polydimethylsiloxane PEG-7 lactate, polydimethylsiloxane PEG-8 lanolate, polydimethylsiloxane PEG-8 laurate, polydimethylsiloxane PEG-8 kohlrabi seed oil, polydimethylsiloxane PEG-7 octyldodecanol citrate, polydimethylsiloxane, Polydimethylsiloxane PEG-7 olive oleate, polydimethylsiloxane PEG-8 olive oleate, polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane PEG-8 phosphate, polydimethylsiloxane PEG-10 phosphate, polydimethylsiloxane PEG-7 phthalate, polydimethylsiloxane PEG-8 polyacrylate, polydimethylsiloxane PEG/PPG-20/23 benzoate, polydimethylsiloxane PEG/PPG-7/4 phosphate, polydimethylsiloxane PEG/PPG-12/4 phosphate, polydimethylsiloxane PEG-7 succinate, polydimethylsiloxane PEG-8 succinate, polydimethylsiloxane PEG-7 sulfate, polydimethylsiloxane PEG-7 undecanoate, polydimethylsiloxane PG-diethylmethylammonium chloride, polydimethylsiloxane/phenylvinyl polydimethylsiloxane crosspolymer, polydimethylsiloxane/polyglycerin-3 crosspolymer, polydimethylsiloxane/PPG-20 crosspolymer, polydimethylsiloxane propyl ethylenediamine behenate, polydimethylsiloxane propyl PG-betaine, polydimethylsiloxane/silsesquioxane copolymer, silylated polydimethylsiloxane, polydimethylsiloxane/vinyl polydimethylsiloxane crosspolymer, polydimethylsiloxane/vinyl trimethylsiloxysilicate crosspolymer, dimethiconol arginine, dimethiconol cerate, dimethicone copolyol, and silicone, and the like, Dimethiconol behenate, dimethiconol chicoric acid, dimethiconol candelilla wax, dimethiconol carnauba palmitate, dimethiconol cysteine, dimethiconol deluba oleate, dimethiconol fluoroalcohol dimolylinoleate, dimethiconol hydroxystearate, dimethiconol Indian iron resinate, dimethiconol/IPDI copolymer, dimethiconol isostearate, dimethiconol candelilla oleate, dimethiconol lactate, dimethiconol meadowfoam seed oil, dimethiconol methionine, dimethiconol/methylsilanol/silicate crosslinked polymer, dimethiconol long leaf bergamot wood oleate, chenopodium album linum linn Dimethiconol panthenol, dimethiconol salicylate, dimethicone/silica crosspolymer, dimethiconol/silsesquioxane copolymer, dimethiconol stearate, dimethiconol/stearyl methicone/phenyl trimethicone copolymer, dimethoxysilanediaminopropyl dimethicone, dimethylaminopropionyl PCA dimethicone, dimethyloxobenzodioxan, dimethiconol hyaluronate, dioleyl tocopheryl methylsilanol, diphenylaminoterminated dimethicone, diphenyl dimethicone crosspolymer, diphenyl dimethicone/vinyl diphenyl dimethicone/silsesquioxane crosspolymer, dimethyl silicone/vinyl diphenyl silicone/silsesquioxane crosspolymer, dimethyl silicone polymer, diphenylethylbenzyloxydimethylsiloxane, diphenylisopropylpolydimethylsiloxane, diphenylsiloxyphenyl/propyltrimethicone, diphenylsiloxyphenyltrimethicone, disiloxane, aminoterminal polydimethylsiloxane/disuccinimidyl disodium, PEG-12 polydimethylsiloxane disodium sulfosuccinate, PEG-8 lauryl polydimethylsiloxane disodium sulfosuccinate, divinylpolydimethylsiloxane/polydimethylsiloxane copolymer, divinylpolydimethylsiloxane/polydimethylsiloxane crosspolymer, cresolquzole trisiloxane, ethylhexyl acrylate/VP/polydimethylsiloxane methacrylate copolymer, ethylmethicone, ethyltrisiloxane, fluoro C2-8 alkyl polydimethylsiloxane, di-methyl siloxane, di-ethyl siloxane, di-methyl siloxane, di-ethyl tri-methyl siloxane, di-ethyl tri-methyl siloxane, di-ethyl siloxane, di-methyl siloxane, di-ethyl tri-methyl siloxane, di-ethyl siloxane, di-methyl siloxane, di-ethyl tri-ethyl siloxane, di-ethyl tri-ethyl siloxane, di-methyl siloxane, di-ethyl tri-methyl siloxane, di-ethyl siloxane, di-methyl siloxane, di-ethyl tri-ethyl tri-methyl siloxane, di-ethyl tri-ethyl siloxane, di-ethyl siloxane, di-ethyl-methyl siloxane, di-ethyl acrylate, di-ethyl acrylate, di-ethyl, Glucosamidopropylaminopropyl polydimethylsiloxane, 4- (2-beta-glucopyranosyloxypropyl) -2-hydroxybenzophenone, glyceryl undecyl polydimethylsiloxane, glycidoxy polydimethylsiloxane, polyhexamethylmethylsiloxane, hexyl polydimethylsiloxane, hexyl methicone, hexyl trimethoxysilane, hydrogenated polydimethylsiloxane/octyl silsesquioxane copolymer, hydrolyzed collagen PG-propyldimethiconol, hydrolyzed collagen PG-propylmethylsilane diol, hydrolyzed collagen PG-propylsilantriol, hydrolyzed keratin PG-propylmethylsilane diol, hydrolyzed sesame protein PG-propylmethylsilane diol, hydrolyzed silk PG-propylmethylsilane diol, hydrolyzed cotton protein PG-propylmethylsilane diol, hydrogenated cotton seed oil, cotton seed oil, Hydrolyzed silk PG-propylmethylsilanediol crosspolymer, hydrolyzed soy protein/polydimethylsiloxane PEG-7 acetate, hydrolyzed soy protein PG-propylmethylsilanediol, hydrolyzed vegetable protein PG-propylsilanetriol, hydrolyzed wheat (TRITICUM VULGARE) protein/cystine bis-PG-propylsilanetriol copolymer, hydrolyzed wheat protein/polydimethylsiloxane PEG-7 acetate, hydrolyzed wheat protein/polydimethylsiloxane PEG-7 phosphate copolymer, hydrolyzed wheat protein PG-propylmethylsilanediol, hydrolyzed wheat protein PG-propylsilanetriol, hydroxyethylacetoxymethylammonium PG-polydimethylsiloxane, hydroxypropylpolydimethylsiloxane behenate, hydroxypropylpolydimethylsiloxane isostearate, hydrolyzed soy protein/polydimethylsiloxane isopropyl alcohol, hydrolyzed soy protein/chitosan/propylene glycol copolymer, hydrolyzed wheat protein PG-propylene glycol copolymer, hydroxyethylacetoxymethylammonium PG-polydimethylsiloxane, hydroxypropylpolydimethylsiloxane behenate, hydroxypropylpolydimethylsiloxane isostearate, hydrolyzed soy protein/polydimethylsiloxane, hydrolyzed soy protein PG-7 acetate, hydrolyzed soy protein-propylmethylsilanediol, hydrolyzed soy protein-propylene glycol, hydrolyzed soy protein-propylene glycol-propylene glycol, hydrolyzed soy protein-propylene glycol copolymer, hydrolyzed soy protein-propylene-silicone glycol copolymer, hydrolyzed soy protein-7-propylene-7 phosphate copolymer, hydrolyzed soy protein-propylene-silicone glycol, hydrolyzed soy protein-propylene-silicone glycol copolymer, hydrolyzed soy protein-propylene glycol, hydrolyzed soy protein-propylene glycol, hydrolyzed soy protein-propylene-silicone glycol, and propylene-silicone glycol copolymer, hydrolyzed soy protein-propylene-silicone glycol, hydrolyzed soy protein-propylene-silicone-propylene-silicone glycol, and propylene-silicone glycol copolymer, hydrolyzed soy protein-propylene-silicone-propylene-silicone glycol copolymer, hydrolyzed soy protein-propylene-silicone glycol, hydrolyzed silicone-silicone glycol, and propylene-silicone glycol copolymer, and propylene-silicone glycol copolymer, hydrolyzed silicone-propylene-, Hydroxypropyl dimethicone stearate, isobutyl methacrylate/bis-hydroxypropyl dimethicone acrylate copolymer, isobutyl methacrylate/trifluoroethyl methacrylate/bis-hydroxypropyl dimethicone acrylate copolymer, isoamyl trimethoxycinnamate trisiloxane, iso-polyglyceryl-3 dimethicone, iso-polyglyceryl-3 dimethiconol, titanium iso-propyltri-stearate/triethoxysilylethyl, dimethiconoethyl dimethicone crosspolymer, iso-stearyl carboxydecyl PEG-8 dimethicone, lactyl methylsilanol elastin ester, lauryl dimethicone PEG-15 crosspolymer, lauryl dimethicone PEG-10 phosphate ester, methyl silicone, ethyl acrylate, methyl silicone, lauryl dimethicone/polyglyceryl-3 crosspolymer, lauryl methicone, lauryl PEG-8 dimethicone, lauryl PEG-10 methyl ether dimethicone, lauryl PEG-9 dimethiconoethyl dimethicone, lauryl PEG/PPG-18/18 methicone, lauryl benzisopropyl methicone, lauryl phenylpropyl methicone, lauryl dimethiconoethyl dimethicone/divinyl dimethicone crosspolymer, lauryl polyglyceryl-3 dimethiconoethyl dimethicone, lauryl trimethicone, linoleamidopropyl PG-dimethyl ammonium chloride phosphate dimethicone, methacryloxypropyl trimethoxysilane, lauryl dimethicone, and mixtures thereof, Polymethylsiloxane, methoxy amino-terminated polydimethylsiloxane/silsesquioxane copolymer, methoxy cinnamamide propyl polysilsesquioxane, methoxy cinnamoyl propyl silsesquioxane silicate, methoxy PEG-13 ethyl polysilsesquioxane, methoxy PEG/PPG-7/3 aminopropyl polydimethylsiloxane, methoxy PEG/PPG-25/4 polydimethylsiloxane, methoxy PEG-10 propyl trimethoxysilane, methyl eugenol PEG-8 polydimethylsiloxane, methyl polysiloxane emulsion, methylsilanol acetyl methionine ester, methylsilanol acetyl tyrosine ester, methylsilanol ascorbic acid, methylsilanol carboxymethylphylline alginate, methylsilanol elastin ester, methylsilanol glycyrrhizate, methylsilanol hydroxyproline ester, methoxy cinnamoyl propyl silsesquioxane silicate, methoxy PEG-13 ethyl polysilsesquioxane, methoxy PEG/PPG-7/3 aminopropyl polydimethylsiloxane, methoxy PEG/PPG-25/4 polydimethylsiloxane, methoxy PEG-10 propyl trimethoxysilane, methyl eugenol PEG-8 polydimethylsiloxane, methyl polysiloxane emulsion, methylsilanol acetyl methionine ester, methylsilanol acetyl tyrosine ester, methylsilanol ascorbic acid, methylsilanol carboxymethyl theophylline, methyl ester, methyl silanol ester, methyl ester, ester, Methylsilanol hydroxyprolinate aspartate, methylsilanol mannuronate, methylsilanol PCA ester, methylsilanol PEG-7 glyceryl cocoate, methylsilanol/silicate crosspolymer, methylsilanol spirulina protein ester, methylsilanol tri-PEG-8 glyceryl cocoate, methylpolytrimethylsiloxane, methyltrimethoxysilane, myristamidopropyl dimethyl amine polydimethylsiloxane PEG-7 phosphate, myristyl methicone, myristyl trisiloxane, nylon-611/dimethicone copolymer, PCA dimethicone, PEG-7 amino terminal dimethicone, PEG-8 cetyl dimethicone, PEG-3 dimethicone, methyl silanol, methyl alcohol PEG-7 glyceryl cocoate, methyl alcohol/silicone ester, methyl alcohol trisiloxane, methyl alcohol tri-ethyl alcohol, methyl alcohol tri-methyl alcohol co-8 amino acid ester, methyl alcohol poly (methyl alcohol) methyl alcohol co-dimethyl siloxane, methyl alcohol tri-8 methyl alcohol poly (methyl alcohol) methyl alcohol co-dimethyl siloxane, methyl alcohol tri-dimethyl siloxane, methyl alcohol tri-8 methyl alcohol, methyl alcohol tri-dimethyl siloxane, methyl alcohol, methyl, PEG-6 polydimethylsiloxane, PEG-7 polydimethylsiloxane, PEG-8 polydimethylsiloxane, PEG-9 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-12 polydimethylsiloxane, PEG-14 polydimethylsiloxane, PEG-10 polydimethylsiloxane crosspolymer, PEG-12 polydimethylsiloxane crosspolymer, PEG-8 polydimethylsiloxane dilinoleate, PEG-8 dilinoleate/dilinoleate copolymer, PEG-10 polydimethylsiloxane/vinyl polydimethylsiloxane crosspolymer, PEG-8 distearylmethylammonium chloride PG-polydimethylsiloxane, PEG-10/lauryl polydimethylsiloxane crosspolymer, PEG-10 polydimethylsiloxane crosspolymer, PEG-8 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-8 polydimethylsiloxane, PEG-9 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-14 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-8 polydimethylsiloxane, PEG-9 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-8 dilinoleate/dilinoleate copolymer, PEG-9 polydimethylsiloxane, PEG-co-polymer, PEG-co-polydimethylsiloxane, PEG-co-polymer, PEG-9-polydimethylsiloxane, PEG-co-polydimethylsiloxane, PEG-and PEG-8-polydimethylsiloxane, PEG-15/lauryl dimethicone crosspolymer, PEG-15/lauryl dimethicone ethyl dimethicone crosspolymer, PEG-8 methicone, PEG-6 methicone acetate, PEG-6 methyl ether dimethicone, PEG-7 methyl ether dimethicone, PEG-8 methyl ether dimethicone, PEG-9 methyl ether dimethicone, PEG-10 methyl ether dimethicone, PEG-11 methyl ether dimethicone, PEG-32 methyl ether dimethicone, PEG-8PEG-8 methyl ether triethoxysilane, PEG-10 nonafluorohexyl dimethicone copolymer, PEG-4PEG-12 dimethicone, PEG-8PG cocoyl glucoside dimethicone, silicone, PEG-9 Dimethylsiloxyethyl polydimethylsiloxane, PEG/PPG-20/22 butyl ether polydimethylsiloxane, PEG/PPG-22/22 butyl ether polydimethylsiloxane, PEG/PPG-23/23 butyl ether polydimethylsiloxane, PEG/PPG-24/18 butyl ether polydimethylsiloxane, PEG/PPG-27/9 butyl ether polydimethylsiloxane, PEG/PPG-3/10 polydimethylsiloxane, PEG/PPG-4/12 polydimethylsiloxane, PEG/PPG-6/4 polydimethylsiloxane, PEG/PPG-6/11 polydimethylsiloxane, PEG/PPG-8/14 polydimethylsiloxane, PEG/PPG-8/26 polydimethylsiloxane, poly (ethylene glycol-co-propylene glycol-co-butylene-propylene glycol-co-butylene glycol-propylene glycol-co-butylene-propylene glycol-butylene-propylene glycol-ethylene glycol-propylene glycol-butylene glycol-propylene glycol-butylene glycol-propylene glycol-butylene glycol-propylene glycol-butylene glycol-2, PEG/PPG-10/2 polydimethylsiloxane, PEG/PPG-12/16 polydimethylsiloxane, PEG/PPG-12/18 polydimethylsiloxane, PEG/PPG-14/4 polydimethylsiloxane, PEG/PPG-15/5 polydimethylsiloxane, PEG/PPG-15/15 polydimethylsiloxane, PEG/PPG-16/2 polydimethylsiloxane, PEG/PPG-16/8 polydimethylsiloxane, PEG/PPG-17/18 polydimethylsiloxane, PEG/PPG-18/6 polydimethylsiloxane, PEG/PPG-18/12 polydimethylsiloxane, PEG/PPG-18/18 polydimethylsiloxane, PEG/PPG-19/19 polydimethylsiloxane, poly (ethylene glycol-co-propylene glycol-co-ethylene glycol-propylene glycol-co-ethylene glycol-co-ethylene glycol-co-propylene glycol-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene-co-, PEG/PPG-20/6 polydimethylsiloxane, PEG/PPG-20/15 polydimethylsiloxane, PEG/PPG-20/20 polydimethylsiloxane, PEG/PPG-20/23 polydimethylsiloxane, PEG/PPG-20/29 polydimethylsiloxane, PEG/PPG-22/23 polydimethylsiloxane, PEG/PPG-22/24 polydimethylsiloxane, PEG/PPG-23/6 polydimethylsiloxane, PEG/PPG-25/25 polydimethylsiloxane, PEG/PPG-27/27 polydimethylsiloxane, PEG/PPG-30/10 polydimethylsiloxane, PEG/PPG-25/25 polydimethylsiloxane/acrylic acid (ester) copolymer, poly (ethylene glycol-co-propylene glycol) (PEG/PPG-20/6), poly (ethylene glycol-co-propylene glycol) (PEG/PPG-20/15 polydimethylsiloxane), poly (ethylene glycol-co-propylene glycol) (PEG/PPG-25/25 polydimethylsiloxane), poly (ethylene glycol-co-propylene glycol) (PEG/poly (propylene glycol-co-propylene glycol) (PEG/PPG-co-20/15)), poly (propylene glycol-co-ethyleneglycol-co-ethyleneglycol-20/15), poly (propylene glycol-co-propylene glycol (ethylene glycol-co-ethylene glycol-co-propylene glycol-co-ethylene glycol-co-3552), poly (ethylene glycol-co-ethylene-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-ethylene glycol-co-20/23), and poly (PEG/co-ethylene-co-p-ethylene-co-20/15), and poly (PEG/co-p-co-20/23), and poly (PEG/poly (ethylene-co-3), and co-3), and poly (PEG/poly (ethylene-co-3), and poly (co-p-co-3) and poly (PEG/poly (ethylene-p-3) and co-p-3) and poly (co-3) and poly (ethylene-co-p-co-3), and co-3), PEG/PPG-20/22 methyl ether polydimethylsiloxane, PEG/PPG-24/24 methyl ether glycidoxy polydimethylsiloxane, PEG/PPG-10/3 oleyl ether polydimethylsiloxane, PEG/PPG-5/3 trisiloxane, PEG-4 trifluoropropyl polydimethylsiloxane copolymer, PEG-8 trifluoropropyl polydimethylsiloxane copolymer, PEG-10 trifluoropropyl polydimethylsiloxane copolymer, PEG-8 trisiloxane, perfluorooctyl triethoxysilylethyl methicone, perfluorononyl polydimethylsiloxane/methicone/amodimethicone crosspolymer, perfluorononyl ethyl carboxydecyl behenyl polydimethylsiloxane, dimethicone, and dimethicone, and one, Perfluorononylethylcarboxadecylhexacyanodimethicone, perfluorononylethylcarboxadecyllauryl/behenyl dimethicone, perfluorononylethylcarboxadecyllauryl dimethicone, perfluorononylethylcarboxadecylPEG-8 dimethicone, perfluorononylethylcarboxadecylPEG-10 dimethicone, perfluorononylethyldimethicone copolymer, perfluorononylethyl PEG-8 dimethicone, perfluorononylethylstearyldimethicone, perfluorooctylethyl/diphenyldimethicone copolymer, perfluorooctylethyltriethoxysilane, perfluorooctylethanotrimethoxysilane, perfluorooctylethyltrisiloxane, perfluorooctyltriethoxysilane, PG-amino-terminal dimethicone, Phenylethyl polydimethylsiloxane, phenylethyl disiloxane, diphenyl polydimethylsiloxane, diphenyl isopropyl polydimethylsiloxane, phenyl polymethylsiloxane, phenyl polymethylsiloxanol, phenylpropyl dimethylsiloxy silicate, phenylpropyl ethyl polymethylsiloxane, phenylpropyl trimethicone/diphenyl methicone, phenyl trimethicone, divinyl disiloxane platinum, polyacrylate-6, polydiethylsiloxane, polydimethyl hydroxyethyl polydimethylsiloxane/divinyl dimethicone crosspolymer, polydimethyl siloxyethyl polydimethylsiloxane/methicone copolymer, polydimethyl siloxane PEG/PPG-24/19 butyl ether silsesquioxane, polydimethyl siloxane PPG-13 butyl ether silsesquioxane, diphenyl isopropyl dimethicone, phenyl dimethicone propyl dimethicone, phenyl dimethicone, divinyl disiloxane platinum, polyacrylate-6, polydiethyl silicone, polydimethyl hydroxyethyl polydimethylsiloxane/divinyl dimethicone crosspolymer, polydimethyl siloxane PPG-24/19 butyl ether silsesquioxane, dimethyl silicone PPG-13 butyl ether silsesquioxane, dimethyl silicone, polyglycerol-3 disiloxane polydimethylsiloxane, polyglycerol-3/lauryl dimethiconoethyl polydimethylsiloxane crosspolymer, polyglycerol-3 polydimethylsiloxane, poly (ethylene glycol adipate)/bis-hydroxyethoxypropyl polydimethylsiloxane copolymer, polymethylsilsesquioxane/trimethylsiloxysilicate, polyphenylsilsesquioxane, polypropylsilsesquioxane, polysiloxane-1, polysiloxane-2, polysiloxane-3, polysiloxane-4, polysiloxane-5, polysiloxane-6, polysiloxane-7, polysiloxane-8, polysiloxane-9, polysiloxane-10, polysiloxane-11, polysiloxane-12, polysiloxane-11, polysiloxane-4, and the like, Polysiloxane-13, polysiloxane-14, polysiloxane-15, polysiloxane-16, polysiloxane-17, polysiloxane-18, polysiloxane-19, polysiloxane-20, polysiloxane-21, polysiloxane-18 cetyl phosphate, polysiloxane-1 crosspolymer, polysiloxane-18 stearate polyurethane-10, methylsiloxane PEG-7 panthenol potassium phosphate, polydimethylsiloxane PEG-7 potassium phosphate, PPG-12 butyl ether polydimethylsiloxane, PPG-2 polydimethylsiloxane, PPG-12 polydimethylsiloxane, PPG-27 polydimethylsiloxane, PPG-4 oleyl polyether-10 polydimethylsiloxane, propoxytetramethylpiperidinyldimethicone polydimethylsiloxane, propyltrimethicone, silicone-1 crosspolymer, silicone-1, silicone-10, silicone-4, dimethicone, silicone-2, silicone-12 dimethicone, PPG-27 dimethicone, PPG dimethicone, silicone-4 oleyl polyether-10 dimethicone, propoxytetramethylpiperidinyldimethicone, propyldimethicone, silicone-2, silicone-12, silicone-17, silicone-2, silicone-1, silicone-2, silicone, quaternary ammonium salt-80, retinoxytrimethylsilane, silanediol salicylate, silanetriol arginine ester, silanetriol glutamate, silanetriol lysine ester, silanetriol melanin ester, silanetriol trehalose ether, silica, polydimethylsiloxane silylated silica, dimethylsilylated silica, silylated silica, silicon carbide, polysiloxane Quaternary ammonium salt-1, polysiloxane Quaternary ammonium salt-2 panthenol succinate, polysiloxane Quaternary ammonium salt-3, polysiloxane Quaternary ammonium salt-4, polysiloxane Quaternary ammonium salt-5, polysiloxane Quaternary ammonium salt-6, polysiloxane Quaternary ammonium salt-7, polysiloxane Quaternary ammonium salt-8, polysiloxane Quaternary ammonium salt-9, polysiloxane Quaternary ammonium salt-10, and mixtures thereof, Polysiloxane quaternary ammonium salt-11, polysiloxane quaternary ammonium salt-12, polysiloxane quaternary ammonium salt-15, polysiloxane quaternary ammonium salt-16/glycidoxy polydimethylsiloxane cross-linked polymer, polysiloxane quaternary ammonium salt-17, polysiloxane quaternary ammonium salt-18, polysiloxane quaternary ammonium salt-19, polysiloxane quaternary ammonium salt-20, polysiloxane quaternary ammonium salt-21, polysiloxane quaternary ammonium salt-22, polysiloxane quaternary ammonium salt-24, polysiloxane quaternary ammonium salt-25, siloxane triol alginate, siloxane triol phytate, silicone resin, carboxydecyl PEG-8 dimethyl siloxane sodium, dimethyl siloxane PEG-7 sodium acetylmethyltaurate, dimethyl silanol sodium hyaluronate, sodium lactate methylsilanol, sodium lactate, and the like, Sodium mannuronate methylsilanol, sodium PCA methylsilanol, PG-propyl dimethicone thiosulfate copolymer sodium, PG-propyl sodium thiosulfate dimethicone, propoxy hydroxypropyl sodium thiosulfate silica, sorbitol silanediol, soy triethoxysilylpropyl dimethylammonium chloride, sLalammonium chloride dimethicone PEG-8 phthalate, stearamidopropyl dimethicone, stearyl dimethyl ammonium hydroxypropyl panthenol PEG-7 dimethicone phosphate chloride, stearyl dimethyl ammonium hydroxypropyl PEG-7 dimethicone phosphate chloride, stearyl dimethicone/dimethicone copolymer, stearyl trimethicone, stearyl aminopropyl methicone, sodium PCA methylsilanol, PG-propyl dimethicone thiosulfate copolymer sodium, PG-propyl dimethicone, sodium lauryl sulfate, sodium lauryl dimethyl silicone sulfate, sodium lauryl dimethyl silicone, sodium lauryl sulfate, sodium lauryl dimethyl silicone sulfate, sodium lauryl dimethyl silicone, sodium lauryl sulfate, sodium lauryl dimethyl silicone, sodium lauryl dimethyl silicone, sodium methyl silicone, sodium lauryl dimethyl silicone, sodium methyl silicone, sodium lauryl dimethyl silicone, sodium methyl silicone, sodium lauryl silicone, sodium methyl silicone, sodium lauryl silicone, sodium methyl silicone, stearyl dimethicone, stearyl/lauryl methacrylate crosspolymer, stearyl methicone, stearyl triethoxysilane, stearyl trimethicone, styrene/acrylates/dimethicone acrylate crosspolymer, styrene/acrylates/dimethicone copolymer, dimethicone PEG-7 phosphate TEA salt, (tetrabutoxy) propyl trisiloxane, tetramethyl hexaphenyl tetrasiloxane, tetramethyl tetraphenyl trisiloxane, tocopheryl oxypropyltrisiloxane, trideceth-9 PG-amodimethicone, triethoxyoctyl silane, dimethicone/methicone copolymer, triethoxysilylethyl dimethicone ethyl dimethicone, and mixtures thereof, Triethoxysilylethylethylpolydimethylsilyloxyethylhexylpolydimethylsiloxane, triethoxysilylpropylcarbamoylethoxypropylbutylpolydimethylsiloxane, trifluoromethyl C1-4 alkylpolydimethylsiloxane, trifluoropropylcyclopentasiloxane, trifluoropropylcyclotetrasiloxane, trifluoropropylpolydimethylsiloxane/PEG-10 crosspolymer, trifluoropropylpolydimethylsiloxane/trifluoropropyldivinylpolydimethylsiloxane crosspolymer, trifluoropropylpolydimethylsiloxane/vinyltrifluoropropylpolydimethylsiloxane/silsesquioxane crosspolymer, trifluoropropyldimethiconol, trifluoropropyldimethyl/trimethylsiloxysilicate, trifluoropropylmethylsiloxane, trimethoxyoctylsilane, di-or tri-ethylsilylethylsiloxane, di-or tri-propyldimethylsiloxysilicate, di-or tri-propyldimethylsiloxane, di-or tri-propyldimethylsiloxysiloxane, di-or tri-propyldimethylsiloxysilicate, di-or tri-propyldimethylsiloxane, di-or tri-or-substituted trimethylsiloxysilane, di-or tri-substituted trimethylsiloxane, and mixtures thereof, Trimethoxysilylpolydimethylsiloxane, trimethylpentaphenyltrisiloxane, trimethylsiloxyaminodimethylsiloxane, trimethylsiloxyphenylpolydimethylsiloxane, trimethylsiloxysilicate/polydimethylsiloxane crosslinked copolymer, trimethylsiloxysilicate/polydimethylsiloxane crosslinked polymer, trimethylsiloxysilylcarbamoylpullulan, trimethylsilylhydrolyzed conchiolin PG-propylmethylsilanediol crosslinked polymer, trimethylsilylhydrolyzed silk PG-propylmethylsilanediol crosslinked polymer, trimethylsilylhydrolyzed wheat protein PG-propylmethylsilanediol crosslinked polymer, trimethylsilylpullulan, trimethylsilanoldisiloxyethanolate, trimethylsilyltrimethylsilanoldimethylsilyloxyethanol, trimethylsilyltrisilyl-crosslinked polymer, trimethylsilyltrisilyl-aminoorganosiloxane crosslinked polymer, trimethylsilyltrisilyl-aminoglycolate, trimethylsilyltrisilyl-crosslinked polymer, trimethylsilyltrisiloxyglycolate, trimethylsilyltrisiloxane, trimethylsilylsilicone-crosslinked polymer, trimethylsilylsilicone-modified with a silicone-alcohol, trimethylsilylsilicone-alcohol, and a-alcohol-conjugated polymer, and a polymer, Trimethylsilanol trisiloxylactate, trimethylsilanol trisiloxysalicylate, polytriphenyltrimethicone, trisiloxane, tris (tributoxysilyloxy) methylsilane, undecene polydimethylsiloxane, vinyl polydimethylsiloxane/lauryl polydimethylsiloxane crosspolymer, vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane crosspolymer, vinyl dimethyl/trimethylsiloxysilicate/stearyl polydimethylsiloxane crosspolymer, VP/dimethylaminoethyl methacrylate/polyethylene glycol polycarbamate, zinc carboxydecyltrisiloxane and zinc polydimethylsiloxane PEG-8 succinate and mixtures thereof.

The silicones contained in the mixture according to the invention are more preferably polydimethylsiloxanes, cyclomethicones, phenyltrimethicones, cyclohexasiloxanes and cyclopentadimethicones. A detailed description of suitable volatile silicone compounds is found in Todd et al.91,27(1976)。

Wax and stabilizer

In addition to the natural oils used, the formulations may also contain waxes, especially natural waxes such as candelilla wax, carnauba wax, japan wax, ludwigia chinensis (esparto grass wax), cork wax, ouricury wax (guaruma wax), rice bran oil wax, sugar cane wax, ouricury wax (ouricury wax), montan wax, beeswax, shellac wax (shellac wax), spermaceti wax, lanolin (wood wax), tail fat (uropygial fat), (pure) ozokerite, ozokerite (paraffin), vaseline, petroleum wax and microwax; chemically modified waxes (hard waxes) such as, for example, montan ester waxes (montan ester waxes), sasol waxes (sasol waxes), hydrogenated jojoba waxes (jojoba waxes) and synthetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.

Metal salts of fatty acids, such as, for example, magnesium, aluminum and/or zinc salts of stearic acid or ricinoleic acid, can be used as stabilizers.

1, 2-alkanediols

In a particularly preferred embodiment, the composition may contain 1, 2-alkanediols having up to 12 carbon atoms, such as 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol, 1, 2-decanediol, mixtures of 1, 2-hexanediol and 1, 2-octanediol, mixtures of 1, 2-hexanediol and 1, 2-decanediol, mixtures of 1, 2-octanediol and 1, 2-decanediol, 1, 2-hexanediol, mixtures of 1, 2-octanediol and 1, 2-decanediol, preferably in amounts of from 0.1 to about 10, preferably from about 1 to about 8% by weight.

Fatty alcohols

The composition may also include a fatty alcohol having 6 to 30C atoms. The fatty alcohols herein may be saturated or unsaturated and straight or branched. Furthermore, these fatty alcohols may in some cases be part of the oil phase (III) if they comply with the definitions given there. Alcohols which may be used are, for example, decanol, decenol, octanol, octenol, dodecanol, dodecenol, octadienol, decadienol, dodecadienol, oleyl alcohol, ricinoleyl alcohol, sinapyl alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, octanoyl alcohol, octanol, linolenyl alcohol and behenyl alcohol, and guerbet alcohols thereof, for example 2-octyl-1-dodecanol, it being possible in fact to extend the above table to other alcohols having the relevant structural chemistry as required. The fatty alcohols are preferably derived from natural fatty acids, usually prepared by reduction from the corresponding esters of the fatty acids. Fatty alcohol fractions formed by the reduction of natural fats and fatty oils, such as tallow, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower seed oil, palm kernel oil, linseed oil, corn oil, castor oil, rapeseed oil, sesame oil, cocoa butter, and coconut fat, may further be used.

Primary sunscreens

The primary sunscreen agents in the context of the present invention are, for example, organic substances (light-filtering substances) which are liquid or crystalline at room temperature and which are capable of absorbing ultraviolet radiation and in turn of releasing the absorbed energy, for example heat, in the form of long-wave radiation.

The preparations according to the invention advantageously contain at least one UV-A filter substance and/or at least one UV-B filter substance and/or a broad-band filter substance and/or at least one inorganic dye. The preparations according to the invention preferably contain at least one UV-B filter or one broad-band filter, more particularly at least one UV-A filter and at least one UV-B filter.

Preferred cosmetic compositions, preferably the topical formulations according to the present invention, contain one, two, three or more sunscreens selected from the group consisting of 4-aminobenzoic acid and derivatives, salicylic acid derivatives, benzophenone derivatives, dibenzoylmethane derivatives, diphenyl acrylate, 3-imidazolyl-4-ylacrylic acid and esters thereof, benzofuran derivatives, benzylidene malonate derivatives, polymeric UV absorbers containing one or more organosilicon radicals, cinnamic acid derivatives, camphor derivatives, triphenylamine-s-triazine derivatives, 2-hydroxyphenylbenzotriazole derivatives, phenylbenzimidazole sulfonic acid derivatives and salts thereof, menthyl anthranilate, benzotriazole derivatives and indole derivatives.

Furthermore, it is advantageous to combine the compounds of formula (I) with an active ingredient which penetrates into the skin and protects the skin cells from sun-induced damage from the inside and reduces the level of skin matrix metalloproteinases. Preferred ingredients, so-called aryl hydrocarbon receptor antagonists, are described in WO 2007/128723, which is hereby incorporated by reference. 2-benzylidene-5, 6-dimethoxy-3, 3-dimethylinden-1-one is preferred.

The UV filter substances cited below which can be used in the present invention are preferred, but not limited to these substances.

Preferably used UV filter substances are selected from the group comprising:

p-aminobenzoic acid

Ethoxylated (25mol) Ethyl p-aminobenzoate (INCI name: PEG-25PABA)

2-ethylhexyl p-dimethylaminobenzoate

N-propoxylation (2mol) of ethyl p-aminobenzoate

Glycerol p-aminobenzoate

Homomenthyl salicylate (homosalate) (Neo))

2-ethylhexyl salicylate (Neo)OS)、

Triethanolamine salicylate

Salicylic acid 4-isopropyl benzyl ester

Menthyl anthranilate (Neo)MA)

Diisopropyl cinnamic acid ethyl ester

2-ethylhexyl p-methoxycinnamate (Neo)AV)

Diisopropyl cinnamic acid methyl ester

Isoamyl p-methoxycinnamate (Neo) E 1000)

Diethanolamine p-methoxycinnamate

P-methoxy isopropyl cinnamate

2-Phenylbenzimidazole sulfonic acids and salts (Neo)Hydro)

3- (4' -trimethylammonium) -benzylidene-camphyl-2-one sulfate methyl ester

Beta-imidazole-4 (5) -acrylic acid (urocanic acid)

3- (4' -sulfo) benzylidene-camphyl-2-one and salts

3- (4' -methylbenzylidene) -D, L-Camphor (Neo)MBC)

3-benzylidene-D, L-camphor

N- [ (2 and 4) - [2- (oxoboren-3-yl) methyl ] benzyl ] -acrylamide Polymer

4,4' - [ (6- [4- (1, 1-dimethyl) -aminocarbonyl) phenylamino group]-1,3, 5-triazine-2, 4-diyl) diimino]Di- (2-ethylhexyl benzoate) ((L))HEB)

Benzalmalonate-polysiloxanes (A), (B), (CSLX)

Glyceryl ethyl hexanoate Dimethoxycinnamate

Dipropylene glycol salicylate

4,4',4 "- (1,3, 5-triazine-2, 4, 6-triyltrienylamino) -tris (2-ethylhexyl) benzoate (═ 2,4, 6-trianilino- (p-carbonyl-2 ' -ethylhexyl-1 ' -oxy) -1,3, 5-triazine) (p-tert-butyl-ethyl-2 ' -hydroxy-ethyl-1 ' -oxy)T150)

The broad-wave filter substance preferably in combination with one or more compounds of formula (I) in the formulations according to the invention is selected from the group comprising

2-cyano-3, 3-diphenylpropenoic acid-2-ethylhexyl ester (Neo)303)

2-cyano-3, 3' -diphenylacrylic acid ethyl ester

2-hydroxy-4-methoxybenzophenone (Neo) BB)

2-hydroxy-4-methoxybenzophenone-5-sulfonic acid

Dihydroxy-4-methoxybenzophenone

2, 4-Dihydroxybenzophenone

Tetrahydroxybenzophenone

2,2 '-dihydroxy-4, 4' -dimethoxybenzophenone

2-hydroxy-4-n-octoxy-benzophenone

2-hydroxy-4-methoxy-4' -methylbenzophenone

Sodium hydroxymethoxybenzophenone sulfonate

Disodium 2,2' -dihydroxy-4, 4' -dimethoxy-5, 5' -disulfo-benzophenone

Phenol, 2- (2H-benzotriazol-2-yl) -4-methyl-6- (2-methyl-3 (1,3,3, 3-tetramethyl-1- (trimethylsilyl) -oxy) -disilyloxy) -propyl) ((ii)XL)

2,2' -methylene-bis- (6- (2H-benzotriazol-2-yl) -4-1,1,3, 3-tetramethylbutyl) -phenol) (M)

2, 4-bis- [4- (2-ethylhexyloxy) -2-hydroxyphenyl ] -1,3, 5-triazine

2, 4-bis [ { (4- (2-ethyl-hexyloxy) -2-hydroxy } phenyl]-6- (4-methoxyphenyl) -1,3, 5-triazine (S)

2, 4-bis- [ { (4- (3-sulfonic acid) -2-hydroxypropoxy) -2-hydroxy } phenyl ] -6- (4-methoxyphenyl) -1,3, 5-triazine sodium salt

2, 4-bis- [ { (3- (2-propoxy) -2-hydroxypropoxy) -2-hydroxy } phenyl ] -6- (4-methoxyphenyl) -1,3, 5-triazine

2, 4-bis- [ {4- (2-ethylhexyloxy) -2-hydroxy } phenyl ] -6- [4- (2-methoxyethylcarbonyl) phenylamino ] -1,3, 5-triazin-2, 4-bis- [ {4- (3- (2-propoxy) -2-hydroxypropoxy) -2-hydroxy } phenyl ] -6- [4- (2-ethylcarbonyl) phenylamino ] -1,3, 5-triazine

2, 4-bis- [ {4- (2-ethylhexyloxy) -2-hydroxy } phenyl ] -6- (1-methylpyrrol-2-yl) -1,3, 5-triazine

2, 4-bis- [ { 4-tris- (trimethylsiloxysilylpropoxy) -2-hydroxy } phenyl ] -6- (4-methoxyphenyl) -1,3, 5-triazine

2, 4-bis- [ {4- (2 "-methylpropoxyalkenyl) -2-hydroxy } phenyl ] -6- (4-methoxyphenyl) -1,3, 5-triazine

2, 4-bis- [ {4- (1 ', 1', 1 ', 3', 5 ', 5', 5 '-heptamethylsiloxy-2' -methylpropoxy) -2-hydroxy } phenyl ] -6- (4-methoxyphenyl) -1,3, 5-triazine

The compositions may contain other typical cleaning and detergent composition ingredients such as UV-A filter substances, which in the formulations according to the invention are preferably combined with one or more compounds of the formula (I) and selected from the group comprising

4-isopropyl-dibenzoylmethane

P-xylylene-dibamane sulfonic acid and salts

4-tert-butyl-4' -methoxydibenzoylmethane (avobenzone) or-

Phenylene-bis-benzimidazolyl-tetrasulfonic acid disodium salt

2, 2' - (1, 4-phenylene) -bis- (1H-benzimidazole-4, 6-disulfonic acid), monosodium salt

2- (4-diethylamino-2-hydroxybenzoyl) -benzoic acid hexyl ester

Indanylidene compounds according to DE 10055940 a1(═ WO 2002038537)

The compositions may contain other typical cleaning and detergent composition ingredients such as UV filters, which are preferably combined with one or more compounds of formula (I) in the formulations according to the invention and selected from the group consisting of

P-aminobenzoic acid

3- (4' -trimethylammonium) -benzylidenecamphyl-2-one methyl sulfate

Homomenthyl salicylate (Neo)HMS)

2-hydroxy-4-methoxybenzophenone (Neo)BB)

2-Phenylbenzimidazolesulfonic acid (Neo)Hydro)

Terephthalylidene-dibamane sulfonic acid and salts thereof: (SX)

4-tert-butyl-4' -methoxydibenzoylmethane (Neo)357)

3- (4' -sulfo) benzylidene-camphyl-2-one and salts

2-cyano-3, 3-diphenylpropenoic acid-2-ethylhexyl ester (Neo)303)

N- [ (2 and 4) - [2- (oxoboren-3-yl) methyl ] benzyl ] -acrylamide Polymer

2-ethylhexyl p-methoxycinnamate (Neo)AV)

Ethoxylated (25mol) Ethyl p-aminobenzoate (INCI name: PEG-25PABA)

Isoamyl p-methoxycinnamate (Neo)E1000)

2,4, 6-Trianilino- (p-carbonyl-2 '-ethylhexyl-1' -oxy) -1,3, 5-triazine (T150)

Phenol, 2- (2H-benzotriazol-2-yl) -4-methyl-6- (2-methyl-3 (1,3,3, 3-tetramethyl-1- (trimethylsilyl) -oxy) -disilyloxy) -propyl) ((ii)XL)

4, 4' - [ (6- [4- (1, 1-dimethyl) -aminocarbonyl) phenylamino ] -1,3, 5-triazine-2, 4-diyl) diimino ] -bis- (2-ethylhexyl benzoate) (Uvasorb HEB)

3- (4' -methylbenzylidene) -D, L-Camphor (Neo)MBC)

3-benzylidene-camphor

2-ethylhexyl salicylate (Neo) OS)

4-dimethylaminobenzoic acid-2-ethylhexyl ester (Padimate O)

Hydroxy-4-methoxybenzophenone-5-sulfonic acid and the sodium salt

·2,2'-methylene-bis- (6- (2H-benzotriazol-2-yl) -4-1,1,3, 3-tetramethylbutyl) -phenol) ((2H-benzotriazol-2-yl) -4-methyl-butyl) -phenol)M)

Phenylene-bis-benzimidazolyl-tetrasulfonic acid disodium salt (Neo)AP)

2, 4-bis [ { (4- (2-ethylhexyloxy) -2-hydroxy } phenyl]-6- (4-methoxyphenyl) -1,3, 5-triazine (S)

Benzalmalonate-polysiloxanes (A), (B), (CSLX)

Menthyl anthranilate (Neo)MA)

2- (4-diethylamino-2-hydroxybenzoyl) -benzoic acid hexyl ester (b)A Plus)

Indanylidene compounds according to DE 10055940 (═ WO 02/38537).

Advantageous primary and secondary sunscreens are described in WO 2005123101 a 1. Advantageously these formulations contain at least one UVA filter substance and/or at least one UVB filter substance and/or at least one inorganic pigment. The formulations may be presented in various forms in the present invention, such as those typically used in sunscreen formulations. Thus, they may be in the form of a solution, a water-in-oil (W/O) or oil-in-water (O/W) emulsion, or a multiple emulsion, such as a water-in-oil-in-water (W/O/W) emulsion, a gel, an aqueous dispersion, a solid stick, or an aerosol.

In a further preferred embodiment the formulations according to the invention contain opacifying agents, i.e. in particular UV-filter substances and/or inorganic pigments (UV-filter pigments) in a total amount which enables the formulations according to the invention to have a photoprotective factor of greater than or equal to 2 (preferably greater than or equal to 5). The preparations of the invention are particularly suitable for protecting the skin and hair.

Secondary sunscreens

In addition to the primary sunscreen group described above, a secondary sunscreen in an antioxidant form may also be used. The antioxidant-type secondary sunscreen blocks the photochemical reaction chain that is initiated when ultraviolet light penetrates into the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and derivatives thereof, imidazoles (e.g. urocanic acid) and derivatives thereof, peptides such as D, L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g. anserine), carotenoids, carotenes (e.g. alpha-carotene, beta-carotene, lycopene) and derivatives thereof, chlorogenic acid and derivatives thereof, lipoic acid and derivatives thereof (e.g. dihydrolipoic acid), chlorothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and sugar radicals thereof, N-acetyl, methyl, ethyl, propyl, pentyl, butyl and lauryl, palmitoyl, oleyl, alpha-linoleoyl, cholesteryl and glycerides) and salts thereof, Dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionate and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low drug-resistant amounts of sulfoximine compounds (e.g., sulfoximine, homocysteine sulfoximine, sulfolane, penta-, hexa-and hepta-sulfoximine), and (metal) chelating agents (e.g., alpha-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), alpha-hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, bile extract, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and its derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and its derivatives, Vitamin C and its derivatives (e.g. ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and derivatives: ( Such as vitamin E acetate), vitamin a and derivatives (vitamin a palmitate) and the benzoic acid rosin ester of benzoin resin, rutinoleic acid and its derivatives, glycosyl rutin, ferulic acid, furfurylidenesorbitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (e.g. dispersion in ethanol), zinc and its derivatives (e.g. ZnO, ZnSO), and the like₄) Selenium and its derivatives (e.g. selenium methionine), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active compounds which are suitable for the purposes of the present invention.

Advantageous inorganic secondary photoprotective factors are pigments, preferably inorganic pigments based on finely divided metal oxides and/or other water-insoluble or sparingly water-soluble metal compounds, in particular Titanium (TiO)₂) Zinc (ZnO), iron (e.g. Fe)₂O₃) Zirconium (ZrO)₂) Silicon (SiO)₂) Manganese (e.g., MnO), aluminum (A1)₂O₃) Cerium (e.g. Ce) ₂O₃) Oxides of the corresponding metals, mixed oxides of the corresponding metals and mixtures of these oxides. These pigments are X-ray amorphous or non-X-ray amorphous. X-ray amorphous oxide pigments are metal oxides or semimetal oxides that have no or no recognizable crystal structure in X-ray diffraction experiments. Such pigments are generally obtainable by flame reaction, for example by reacting a metal or semimetal halide with hydrogen and air (or pure oxygen) in a flame. X-ray amorphous oxide pigments are used as thickeners and thixotropic agents, as flow aids for emulsion and dispersion stabilization and as carrier substances (for example for increasing the volume of finely divided powders). X-ray amorphous oxide pigments which are known and frequently used in cosmetic or dermatological galenic formulations are, for example, high-purity silicon oxides.

Preferably having a particle size in the range of 5 to 40 nm and 50 to 400m²G, preferably from 150 to 300m²High purity, X-ray amorphous silica pigment per gram active surface area (BET) wherein the particles are considered to be spherical particles of very uniform size. Macroscopically, the silica pigment is a loose white powder. Silica pigments and(CAS-No.7631-85-9) or Carb-O-Sil are commercially available under the names.

Advantageous effectsThe grade is, for example0X50,130,150,200,300,380,MQX 80,MOX 170,COK 84,R 202,R 805,R 812,R 972,R 974,R976。

The composition according to the invention may comprise from 0.1 to 20% by weight, advantageously from 0.5 to 10% by weight, more preferably from 1 to 5% by weight, of X-ray-amorphous oxide pigment, based on the total weight of the composition.

According to the invention, the non-X-ray amorphous inorganic pigments are advantageously in hydrophobic form, i.e. have been surface-treated to be water-repellent. Such surface treatment may comprise providing the pigment with a thin hydrophobic layer by methods known per se. Such methods include, for example, by creating a hydrophobic surface layer according to the following reaction

n TiO₂+m(RO)₃Si-R‘→n TiO₂(surf.)

Where n and m are the stoichiometric parameters used as desired and R' are the desired organic groups. For example, hydrophobic pigments prepared analogously to DE A3314742 are advantageous.

The total amount of inorganic pigments, in particular hydrophobic inorganic micro-pigments, in the finished cosmetic, dermatological and pharmaceutical compositions according to the invention may advantageously be selected from the range of 0.1 to 30 wt. -%, preferably 0.1 to 10.0 wt. -%, preferably 0.5 to 6.0 wt. -%, based on the total weight of the composition.

Antioxidant agent

It is generally preferred that the compositions of the present invention contain additional levels of antioxidants. Advantageous antioxidants which can be used according to the invention are all conventional or suitable for cosmetic, dermatological and pharmaceutical preparations Antioxidants in the formulation. Antioxidants preferably include, from the group consisting of amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and derivatives thereof, imidazoles (e.g., urocanic acid) and derivatives thereof, peptides, e.g., D, L-carnosine, D-carnosine, L-carnosine and derivatives thereof (e.g., anserine), carotenoids, carotenes (e.g., alpha-carotene, beta-carotene, lycopene) and derivatives thereof, chlorogenic acid and derivatives thereof, lipoic acid and derivatives thereof (e.g., dihydrolipoic acid), aurothioglucose, propylthiouracil, and other thiols (e.g., thioredoxin, glutathione, cysteine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, pentyl, butyl and lauryl, palmitoyl, oleyl, gamma-linoleyl, oleyl, and derivatives thereof, Cholesteryl group and oligoglycerol ester thereof), dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low drug-resistant amounts (e.g., pmol to μmol/kg) of sulfoximine compounds (e.g., sulfoximine, homocysteine sulfoximine, sulfolane, penta-, hexa-and hepta-sulfoximine), and (metal) chelators (e.g., α -hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α -hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, bile extract, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (preferably γ -linolenic acid, linoleic acid, oleic acid), folic acid and derivatives thereof, ubiquinone and ubiquinol and derivatives thereof, vitamin C and derivatives (e.g., ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (e.g., vitamin E acetate), vitamin A and derivatives (vitamin A palmitate), and the benzoic acid rosin ester of benzoin resin, rutinoleic acid and derivatives thereof, alpha-glucosylrutin, ferulic acid, furfurylideneglucitol (furylglucitol), carnosine, butylhydroxytoluene, butylhydroxyanisole, dehydroguaiaretic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, mannose and derivatives thereof, zinc and derivatives thereof (e.g., ZnO, ZnSO ₄) Selenium and its derivatives (e.g. selenomethionine), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and their derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids), derivatives of acetophenone such as hydroxyacetophenone and its mixtures with phenoxy-ethanol and/or pentane 1, 2-diol and/or hexane 1, 2-diol and/or octane 1, 2-diol are suitable according to the invention.

The amount of the above antioxidant(s) (one or more compounds) in the composition is preferably from 0.001 to 30 wt.%, more preferably from 0.05 to 20 wt.%, most preferably from 1 to 10 wt.%, based on the total weight of the composition.

Vitamin preparation

In a preferred embodiment, the composition of the invention may also advantageously comprise vitamins and vitamin precursors, all vitamins and vitamin precursors suitable or commonly used for cosmetic and/or dermatological applications being usable. Particular mention may be made here of vitamins and vitamin precursors, such as tocopherol, vitamin a, nicotinic acid and nicotinamide, other vitamins of the B complex, in particular biotin, and also vitamin C and panthenol and derivatives thereof, in particular esters and ethers of panthenol, and also cationically derivatized panthenol, for example panthenol triacetate, panthenol monoethyl ether and monoacetate thereof and cationic panthenol derivatives. If vitamin E and/or its derivatives represent antioxidants, it is advantageous to choose their respective concentrations in the range of 0.001 to 10% by weight, based on the total weight of the composition. If vitamin a or a vitamin a derivative, or carotene or a derivative thereof represents an antioxidant, it is advantageous to choose their respective concentration in the range of 0.001 to 10 wt. -% based on the total weight of the antioxidant.

Plant extracts

The compositions of the invention may comprise plant extracts, which are usually prepared by extraction of whole plants, but in individual cases may also be prepared by extraction only from the flowers and/or leaves, wood, bark or roots of the plants. As for the plant extracts that can be usedExtracts, in particular with reference to the industriverband listed by FrankfurtLeitfaden zur ihaltssoffdekkischer Mittel, third edition published by und Waschmittel e.V (IKW), in the guidelines for the Declaration of ingredients of Cosmetic Compositions (Manual of Declaration of the constraints of Cosmetic Compositions), in the tables beginning at page 44. Particularly advantageous plant extracts are from the following plants: aloe vera, witch hazel, algae, oak bark, rose bay poplar grass, nettle, wild sesame, hops, chamomile, yarrow, arnica, calendula, burdock root, horsetail, hawthorn, linden, almond, pine needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, tangerine, lemon, lime, grapefruit, apple, green tea, grapefruit, wheat, oat, barley, sage, thyme, rosemary, birch, mallow, oca, willow bark, stolonifera, coltsfoot, hibiscus, ginseng, and ginger root.

In this context, particular preference is given to aloe, chamomile, algae, rosemary, calendula, ginseng, cucumber, sage, nettle, linden jacquard, arnica and witch hazel extracts. Mixtures of two or more plant extracts may also be used. The extractant used for preparing the plant extract can be water, alcohol and their mixture. In this context, among the alcohols, not only lower alcohols such as ethanol and isopropanol but also polyols such as ethylene glycol, propylene glycol and butylene glycol are preferred, in particular both alone and in admixture with water as extractant. The plant extract may be used in pure form or in diluted form.

Skin lightening agent

Additional levels of skin lightening ingredients in the compositions according to the invention are also possible. Such skin lightening ingredients that may be used are for example, but not limited to, the following: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyrone), kojic acid derivatives, such as kojic acid dipalmitate, arbutin, ascorbic acid derivatives, resorcinol derivatives, such as 4- (1-phenylethyl) 1, 3-resorcinol, sulfur-containing molecules, such as glutathione or cysteine, alpha-hydroxy acids (such as citric acid, lactic acid, malic acid) and derivatives thereof, sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), N-acetyl tyrosine and derivatives, undecylenoyl phenylalanine, gluconic acid, chromone derivatives, such as aloin, flavonoids, and derivatives, Thymol derivatives, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, such as zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, such as preferably maslinic acid, sterols, such as ergosterol, benzofuranones, such as ligustilide, vinylguaiacol, ethylguaiacol, diacids (dionic acids), such as octadecenedioic acid and azelaic acid, inhibitors of the synthesis of nitrogen oxides, such as L-nitroarginine and its derivatives, 2, 7-dinitroindazole or thiocitrulline, metal chelators (such as alpha-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin, humic acid, gallic acid, bile extracts, bilirubin, biliverdin), retinoid compounds, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for lightening skin and hair, these compounds are used in the form of extracts from plants, such as bearberry extract, rice extract, papaya extract, licorice root extract or concentrated fractions of these substances, such as glabridin or licochalcone a, cassia extract, extracts from Rumex and Ramulus species, pine (pine) extract, vitis extract or stilbene derivatives, saxifrage, mulberry, scutellaria and/or vitis extracts concentrated therefrom.

Active substance for regulating hair pigmentation

Preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyrone), kojic acid derivatives, preferably 122178 dipalmitate, arbutin, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone derivatives, resorcinol derivatives, preferably 4-alkylresorcinol and 4- (1-phenylethyl) 1, 3-resorcinol (phenylethylresorcinol), cyclohexylcarbamates (preferably one or more cyclohexyl carbamates as disclosed in WO 2010/122178 and WO 2010/097480), sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyl tyrosine and derivatives, undecenylphenylalanine, citric acid, malic acid, salts and esters thereof, and salts thereof, Gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably ligustilide, vinylguaiacol, ethylguaiacol, diacids (dionic acids), preferably octadecenedioic acid and/or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and derivatives thereof, 2, 7-dinitroindazole or thiocitrulline, metal chelators (preferably alpha-hydroxy fatty acids, phytic acid, humic acid, cholic acid, bile extracts, EDTA, EGTA and derivatives thereof), retinoid compounds, soy milk and extracts, soy milk and soy milk extracts, Serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably being used in the form of extracts taken from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, pachyrhizus extract, cyperus extract, licorice root extract or components concentrated or isolated therefrom, preferably glabridin or licochalcone a, cassia extract, extracts of sorrel, extracts of pinus (pine), extracts of vitis or stilbene derivatives isolated or concentrated therefrom, saxifrage extract, scutellaria extract (scutellaria extract), grape extract and/or microalgae extract, especially tetragonia quadriceps extract.

The skin and hair tanning active ingredients which are advantageous in this respect are substrates or substrate analogs of tyrosinase, such as L-tyrosine, N-acetyl tyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids, such as caffeine, theobromine and theophylline and derivatives thereof, Pro-opiomelanocortin peptides, such as ACTH, alpha-MSH, peptide analogs thereof, and other substances which bind to melanocortin receptors, peptides, such as Val-Gly-Val-Ala-Pro-Gly, Lys-lle-Gly-Arg-Lys or Leu-Ile-Gly-Lys, purines, pyrimidines, folic acid, copper salts, such as copper gluconate, copper chloride or copper pyrrolidinate, 1,3, 4-oxadiazol-2-thiol, such as 5-pyrazin-2-yl-1, 3, 4-oxadiazole-2-thiol, curcumin, zinc diglycinate (zn (giy)2)), manganese (II) dicarbonate complexes ("pseudococcat-alases"), as described, for example, in EP 0584178, tetra-substituted cyclohexene derivatives, as described, for example, in WO2005/032501, isoprenoides, as described, for example, in WO2005/102252 and WO2006/010661, melanin derivatives, such as Melasyn-100 and MelanZe, diacyl glycerol, aliphatic or cyclic glycols, psoralens, prostaglandins and analogs thereof, activators of adenylate cyclase and compounds that activate the conversion of hair melanosomes into keratin cells, such as serine proteases or PAR-2 receptor agonists, extracts of plants and plant parts of the chrysanthemum genus, extracts of plants and plant parts of the sanguisorba genus, extracts of plants, extracts of the urucum extracts, extracts of the hair melanosomes, and, Rhubarb extract and microalgae extract, especially Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids that cause staining or browning of skin and hair (e.g., quercetin, rhamnose, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and geraniin, morin, quercetin, naringenin, hesperidin, phloridin, phloretin) may also be used.

The amounts of the aforementioned examples of further active ingredients (compound (s)) for regulating the pigmentation of the skin and hair in the products according to the invention are preferably from 0.00001 to 30% by weight, preferably from 0.0001 to 20% by weight, particularly preferably from 0.001 to 5% by weight, based on the total amount of the preparation.

Hair growth activator or inhibitor

The formulations and products according to the invention may also contain one or more hair growth activators, i.e. agents that stimulate hair growth. The hair growth activator preferably comprises from the group consisting of pyrimidine derivatives, such as 2, 4-diaminopyrimidine-3-oxide (Aminexil), 2, 4-diamino-6-piperidinopyrimidine-3-oxide (Minoxidil) and derivatives thereof, 6-amino-1, 2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and derivatives thereof, xanthine alkaloids, such as caffeine, theobromine and theophylline and derivatives thereof, quercetin and derivatives, dihydroquercetin (taxifolin) and derivatives thereof, potassium channel openers, antiandrogen drugs, synthetic or natural 5-reductase inhibitors, nicotinic acid esters, such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinates, proteins such as the tripeptide Lys-Pro-Val, diphencypren, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and derivatives thereof, cyproterone acetate, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (Tacrolimus ) and derivatives thereof, cyclosporin a and derivatives thereof, zinc and zinc salts, tea polyphenols, proanthocyanidins, procyanidins, phytosterols, such as beta-sitosterol, biotin, eugenol, (±) -beta-citronellol, panthenol, glycogen, e.g. of mussel origin, of microorganisms, seaweed, plants and parts of plants, e.g. plants of the following genera: dandelion (tanacetum or taraxacum), extracts of coprinus, vitex, coffee, paulina, cocoa, asarum duckweed, cucurbita or sophora, serenoa repens (saw palmetto), sophora flavescens, prunus africana, broomcorn millet, cimicifuga foetida, soybean, clove, cotinus coggygria, hibiscus rosa, tea tree, yerba mate, dinoflagellate equiseti, licorice, grape, apple, barley or hop, or/and rice or wheat hydrolysates.

Optionally, the formulations and products according to the invention may further comprise one or more hair growth inhibitors (as described above), i.e. a preparation that slows or prevents hair growth. The hair growth inhibitor preferably comprises, from the group consisting of activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors, such as alpha-difluoromethylornithine or pentacyclic triterpenoids such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5 alpha-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, gamma-glutamyltranspeptidase inhibitors, transglutaminase inhibitors, serine protease inhibitors of soy origin, serine protease inhibitors from microorganisms, algae, various microalgae or plants and parts of plants, such as extracts of Leguminosae, Solanaceae, Gramineae, Asclepiadaceae or Cucurbitaceae, Chondrus, Gloiopeltis, Mesona, Durvillea, Glycine, Ulmus, calendula, Hamamelis, Arnica, Salix, Hypericum or Gymnema.

Physiological cooling agent

The composition may also contain one or more substances with a physiological cooling effect (cooling agents), preferably selected from the following list: menthol and menthol derivatives (e.g., L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol, neomenthol), menthyl ethers (e.g., (I-menthoxy) -1, 2-propanediol, (I-menthoxy) -2-methyl-1, 2-propanediol, I-menthyl-methyl ether), menthyl esters (e.g., menthyl formate, menthyl acetate, menthyl isobutyrate, menthyl lactate, L-menthyl D-lactate, (2-methoxy) -menthyl acetate, (2-methoxyethoxy) menthyl acetate, menthyl pyroglutamate), menthyl carbonates (e.g., menthyl propylene glycol carbonate, menthyl ethylene glycol carbonate, menthyl glycol carbonate, menthol, menthyl acetate, menthol, menthyl lactate, menthol derivatives (e.g., (I-menthyl formate, menthyl acetate), menthyl acetate, menthyl lactate, menthol, and menthol derivatives, menthol derivatives, menthol, menthyl acetate, menthol, and menthol, and menthol, and menthol, and menthol, and menthol, and menthol, glyceryl menthyl carbonate or mixtures thereof), half esters of menthol with dicarboxylic acids or derivatives thereof (e.g. monomenthyl succinate, monomenthyl glutarate, monomenthyl malonate, O-menthyl succinate-N, N- (dimethyl) amide, O-menthyl succinate amide), menthane carboxylic acid amides (in this case preferably menthane carboxylic acid-N-acetamide [ WS3] or N α - (menthane carbonyl) glycine ethyl ester [ WS5] as described in US4,150,052, menthane carboxylic acid-N- (4-cyanophenyl) amide or menthane carboxylic acid-N- (4-cyanomethylphenyl) amide, methane carboxylic acid-N- (alkoxyalkyl) amides as described in WO2005049553a 1), menthone and menthone derivatives (e.g. L-menthone glycerol ketal), 2, 3-dimethyl-2- (2-propyl) -butyric acid derivatives (e.g. 2, 3-dimethyl-2- (2-propyl) -butyric acid-N-carboxamide [ WS23]), isopulegol or its esters (I- (-) -isopulegol, I- (-) -isopulegol acetate), menthane derivatives (e.g. p-menthane-3, 8-diol), cubebol or synthetic or natural mixtures containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (e.g. 3-methyl-2 (1-pyrrolidinyl) -2-cyclopenten-1-one) or tetrahydropyrimidin-2-one (e.g. iciline or related compounds as described in WO 2004/026840), pharmaceutical compositions containing these compounds, and methods of using them, Other carboxamides (e.g. N- (2- (pyridin-2-yl) ethyl) -3-p-menthanecarboxamide or related compounds), (1R,2S,5R) -N- (4-methoxyphenyl) -5-methyl-2- (1-isopropyl) cyclohexane-carboxamide [ WS12], oxamate (preferably as described in EP 2033688a 2).

Anti-inflammatory agent

The composition may also include an active anti-inflammatory compound and/or a redness-relieving and/or itch-relieving compound (anti-irritant). All active anti-inflammatory compounds or redness-relieving and/or itch-relieving compounds suitable for or commonly used in cosmetic, dermatological and pharmaceutical compositions may be used herein. Advantageously, the active anti-inflammatory compound and the redness-relieving and/or itch-relieving compound used are steroidal anti-inflammatory substances of corticosteroids, e.g. hydrocortisone, dexamethasone phosphate, methylprednisolone or cortisone, the list being extended by the addition of further steroidal anti-inflammatory agents. Nonsteroidal anti-inflammatory agents may also be used. Examples illustrated herein are oxicams, such as piroxicam or tenoxicam; salicylates, such as aspirin, disalicylic acid (disalicid), solprin or fendulx; acetic acid derivatives, such as diclofenac, clofenac, indomethacin, sulindac, tolmetin or clindanac; fenamates (fenamates), such as mefenamic acid, meclofenamic acid, flufenamic acid or niflumic acid; propionic acid derivatives, such as ibuprofen, naproxen, benoxaprofen; or pyrazoles, such as phenylbutazone, oxyphenbutazone, feprazone (febrazone) or azapropazone.

Alternatively, natural anti-inflammatory substances or substances that relieve redness and/or relieve itching may be used. Plant extracts, in particular highly active plant extract fractions, and highly pure active substances isolated from plant extracts can be used. Extracts, fractions and active substances from chamomile, aloe vera, myrrh, rubia, willow, salix rose bengal, oats, also especially from pure substances, such as bisabolol, apigenin-7-glucoside, boswellic acid, phytosterols, glycyrrhizin, glabridin and licochalcone a are particularly preferred. The formulations of the invention may also include mixtures of two or more active anti-inflammatory compounds. Bisabolol, boswellic acid, and extracts from oats and echinacea and highly pure active compounds isolated therefrom are particularly preferred for use in the present invention as anti-inflammatory substances and redness-alleviating and/or itch-alleviating substances, and alpha-bisabolol and extracts from oats and highly pure active compounds isolated therefrom are particularly preferred.

Preferred anti-inflammatory agents may be selected from the group consisting of:

(i) corticosteroid-type anti-inflammatory substances, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone phosphate, methylprednisolone or cortisone,

(ii) Non-steroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, salsalate, solprin or fendulx, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or cloclofenac (clindanac), fenamates such as mefenamic acid, meclofenamic acid, flufenamic acid or niflumic acid, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenbutazone, februne or azaacetone,

(iii) natural or naturally occurring anti-inflammatory substances or substances which relieve redness and/or itching, in particular extracts or fractions of chamomile, aloe vera, bisabolo, rubia, willow, oat, calendula, arnica, st-john's-wort, honeysuckle, rosemary, passion flower (Passiflora incarnata), witch hazel, ginger or purple daisy, or single active compounds thereof,

(iv) histamine receptor antagonists, serine protease inhibitors (e.g., soy extract), TRPV1 antagonists (e.g., 4-tert-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropionamide benzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamide), and TRPV3 antagonists.

The amount of anti-irritants (one or more compounds) in the composition is preferably from 0.0001% to 20% by weight, particularly preferably from 0.0001% to 10% by weight, in particular from 0.001% to 5% by weight, based on the total weight of the composition.

Antimicrobial agents

Suitable antimicrobial agents are in principle all substances which are able to combat gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N- (4-chlorophenyl) -N '- (3, 4-dichlorophenyl) urea, 2,4,4' -trichloro-2 '-hydroxy-diphenyl ether (triclosan), 4-chloro-3, 5-dimethyl-phenol, 2' -methylenebis (6-bromo-4-chlorophenol), 3-methyl-4- (1-methylethyl) phenol, 2-benzyl-4-chloro-phenol, 3- (4-chlorophenoxy) -1, 2-propanediol, butyl 3-iodo-2-propynylcarbamate, chlorhexidine, 3,4,4' -trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, peppermint oil, farnesol, phenoxyethanol, glycerol monodecanoate, glycerol monocaprylate, Glycerol Monolaurate (GML), Diglycerol Monodecanoate (DMC), N-alkylamines of salicylic acid, for example, N-octylsalicylamide or N-decylsalicylamide.

Enzyme inhibitors

Suitable enzyme inhibitors are, for example, esterase inhibitors. These enzyme inhibitors are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (Hydagen CAT). The above substances inhibit the enzyme activity, thereby reducing the generation of odor. Other substances suitable as esterase inhibitors are sterol sulfates or phosphates, for example lanosterol sulfate or phosphate, cholesterol sulfate or phosphate, campesterol sulfate or phosphate, stigmasterol sulfate or phosphate and sitosterol sulfate or phosphate; dicarboxylic acids and esters thereof, e.g. glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and esters thereof, e.g. citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate

Odor absorbers and antiperspirant actives

Suitable odor absorbers are substances which are capable of absorbing and largely retaining the taste-forming compounds. They reduce the partial pressure of the components and thus also the diffusion rate. It is important that the fragrance remain intact during this process. The odor absorbent has no effect on the bacteria. They contain, for example, complex zinc salts of ricinoleic acid as the main component, or as "fragrance-fixing agents" specific, mainly odour-neutralizing fragrances known to the person skilled in the art, for example extracts of cistus or styrax or some abietic acid derivatives. The odor masking agent is a fragrance or fragrance oil that, in addition to its function as an odor masking agent, also provides its respective fragrance to the deodorant. Fragrance oils which may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, fruit skins, roots, wood, herbs and grasses, pine needles and branches, and resins and balsams. Also suitable are animal products such as civet and castoreum. Typical synthetic aromatics are esters, ethers, aldehydes, ketones, alcohols and hydrocarbon products. Ester-based fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styrallyl propionate and benzyl salicylate. Ethers include, for example, benzylethyl ether; the aldehydes include, for example, linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and boraginal (bourgeonal); ketones include, for example, ionone and methyl cedryl ketone; the alcohol includes anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenethyl alcohol and terpineol; hydrocarbons include mainly terpenes and balsams. Less volatile essential oils commonly used as fragrance ingredients are also suitable as fragrance oils, such as sage oil, chamomile oil, clove oil, melissa oil, peppermint oil, cinnamon leaf oil, basswood flower oil, juniper oil, vetiver oil, frankincense oil, galbanum oil (galbanum oil), labdanum oil and lavender oil. Bergamot oil, dihydromyrcenol, lilial, neolilial, citronellol, phenethyl alcohol, alpha-hexylcinnamaldehyde, geraniol, benzyl acetone, cyclamen aldehyde, linalool, ethoxymethoxycycloundecane (boisabrene form), ambergris, indole, methyl dihydrojasmonate, sandelite, lemon oil, citrus oil, orange oil, allyl isopentyloxy acetate, cycloverral, lavender oil, sage oil, beta-damascenone, geranium oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose ether, romilat, ethyl 2-ethyl-hexanoate (irotyl), and 2-tert-butylcyclohexyl ethyl carbonate (floramat) are preferably used alone or in a mixture.

Suitable astringent antiperspirant actives are primarily salts of aluminium, zirconium or zinc. Suitable antistrophic active ingredients of this type are, for example, aluminum chloride, aluminum hydrochloride, aluminum dihydrochlorate, aluminum sesquihydrochloride and complexes thereof, for example with 1, 2-propanediol, aluminum hydroxy allantoate, aluminum chloride tartrate, aluminum zirconium trihydrochloride, aluminum zirconium tetrahydrohydrochloride, aluminum zirconium pentahydrochloride and complexes thereof, for example with amino acids such as glycine.

Film-forming agent and anti-dandruff agent

Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternary ammonium chitosan, polyvinylpyrrolidone, vinylpyrrolidone/vinyl acetate copolymers, acrylic polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and salts thereof and similar compounds.

Suitable anti-dandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6- (2,4, 4-trimethylpentyl) -2- (1H) -pyridinone monoethanolamine salt),(climbazole),(4-acetyl-1- {4- [2- (2, 4-dichlorophenyl) r-2- (1H-imidazol-1-ylmethyl) -1, 3-dioxolan-c-4-ylmethoxyphenyl } -piperazine, ketoconazole, neoconazole, selenium disulphide, colloidal sulphur, thiopolyethylene glycol sorbitan monooleate, thioricinol polyethoxylate, sulphur tar fractions, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sodium sulfosuccinate, sodium salt, and sodium salt, UD (protein/undecylenic acid concentrate), zinc pyrithione, aluminum pyrithione, and magnesium pyrithione/magnesium dipyrithiosulfate.

Carrier, hydrotrope and moisturizing modifier

Preferred cosmetic carrier materials are solid or liquid (including high viscosity substances) at 25 ℃ and 1013mbar, such as glycerol, 1, 2-propanediol, 1, 2-butanediol, 1, 3-propanediol, 1, 3-butanediol, ethanol, water and mixtures of two or more of said liquid carrier materials with water. Optionally, these formulations of the present invention can be prepared using preservatives or cosolvents. Other preferred liquid carrier materials which may be ingredients of the formulations of the present invention are selected from the group consisting of oils, such as vegetable, neutral and mineral oils.

Preferred solid carrier substances which can be constituents of the preparations according to the invention are hydrocolloids, such as starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose equivalent of 5 to 25, preferably 10-20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum ghatti, traganth, karaya, carrageenan, pullulan, curdlan, xanthan, gellan, guar, carob flour, alginate, agar, pectin and inulin, and mixtures of two or more of these solid substances, in particular maltodextrin (preferably with a dextrose equivalent of 15 to 20), lactose, silicon dioxide and/or glucose.

In addition, hydrotropes, such as ethanol, isopropanol or polyols, may be used to improve flowability. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. Such polyols may contain other functional groups, more specifically amino groups, or may be modified with nitrogen. Typical examples are:

glycerol;

alkanediols, such as ethylene glycol, diethylene glycol, propylene glycol, butanediol, hexanediol and polyethylene glycols having an average molecular weight of from 100 to 1000 dalton;

oligoglycerol technical mixtures with a degree of self-condensation of 1.5 to 10, such as diglycerol technical mixtures with a diglycerol content of 40 to 50% by weight;

methylol compounds, such as trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol, in particular;

lower alkyl glycosides, especially those containing from 1 to 8 carbon atoms in the alkyl radical, such as methyl glycoside and butyl glycoside;

sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol;

sugars containing 5 to 12 carbon atoms, such as glucose or sucrose;

aminosugars, such as glucosamine;

glycol amines, such as diethanolamine or 2-aminopropane-1, 3-diol.

Preferred moisturizing modulators include sodium lactate, urea, alcohols, sorbitol, glycerol, propylene glycol, aliphatic 1, 2-diols having 5 to 10C atoms, collagen, elastin or hyaluronic acid, diacyl adipate, petrolatum, ectoin (ectoin), urocanic acid, lecithin, panthenol, phytantriol, lycopene, algae extracts, ceramides, cholesterol, glycolipids, chitosan, chondroitin sulfate, polyamino acids and polyaminosaccharides, lanolin esters, amino acids, alpha-hydroxy acids (e.g. citric acid, lactic acid, maleic acid) and derivatives thereof, saccharides (e.g. inositol), alpha-hydroxy fatty acids, phytosterols, triterpenic acids, e.g. betulinic acid or ursolic acid, seaweed extracts.

Preservative

Preferred preservatives herein are, for example, benzoic acid, esters and salts thereof, propionic acid and salts thereof, salicylic acid and salts thereof, 2, 4-hexadienoic acid (sorbic acid) and salts thereof, formaldehyde and paraformaldehyde, 2-hydroxydiphenyl ether and salts thereof, 2-zinc dithiopyrridine-N-oxide (2-zinc pyridopyrridine-N-oxide), inorganic sulfites and bisulfites, sodium iodide, chlorobutanol (chlorobutanol), 4-ethylmercury (II) -5-amino-1, 3-bis (2-hydroxybenzoic acid) and salts and esters thereof, palmitic acid, formic acid, 1, 6-bis (4-amidino-2-bromophenyloxy) -N-hexane and salts thereof, ethylmercury (II) -sodium salt of thiosalicylic acid, phenylmercuric acid and salts thereof, 10-undecenoic acid and salts thereof, hexadecanoic acid, formic acid, benzoic acid, 1, 6-bis (4-amidino-2-bromophenyloxy) -N-hexane and salts thereof, ethylmercury (II) -sodium salt of thiosalicylic acid, phenylmercuric acid and salts thereof, 10-undecenoic acid and salts thereof, and salts thereof, 5-amino-1, 3-bis (2-ethylhexyl) -5-methyl-hexahydropyridine, 5-bromo-5-nitro-1, 3-dioxane, 2-bromo-2-nitro-1, 3-propanediol, 2, 4-dichlorobenzyl alcohol, N- (4-chlorophenyl) -N '- (3, 4-dichlorophenyl) urea, 4-chloro-m-cresol, 2,4, 4' -trichloro-2 '-hydroxy-diphenyl ether, 4-chloro-3, 5-dimethylphenol, 1' -methylene-bis (3- (1-hydroxymethyl-2, 4-dioxoimidazolidin) -5-yl) urea), urea, and mixtures thereof, Poly- (hexamethylene biguanide) hydrochloride, 2-phenoxyethanol, hexamethylenetetramine, 1- (3-chloroallyl) -3,5, 7-triaza-1-azoniaadamantane chloride, 1- (4-chlorophenoxy) -1- (1H-imidazol-1-yl) -3, 3-dimethyl-2-butanone, 1, 3-bis (hydroxymethyl) -5, 5-dimethyl-2, 4-imidazolidinedione, benzyl alcohol, pyridone ethanolamine salt (Octopirox), 1, 2-dibromo-2, 4-dicyanobutane, 2' -methylene-bis (6-bromo-4-chloro-phenol), bromochlorobenzene, 5-chloro-2-methyl-3 (2H) -isothiazolinone, and 2-propanoic acid Methyl-3 (2H) -isothiazolinone with a mixture of magnesium chloride and magnesium nitrate, 2-benzyl-4-chlorophenol, 2-chloroacetamide, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, 1-phenoxy-propan-2-ol, N-alkyl (C) ₁₂-C₂₂) Trimethyl-ammonium bromide and N-alkyl (C)₁₂-C₂₂) Trimethyl-ammonium chloride, 4-dimethyl-oxazolidine, N-hydroxymethyl-N- (1, 3-bis (hydroxymethyl) -2, 5-dioxoimidazolin-4-yl) -N' -methylolurea, 1, 6-bis (4-amidino-phenoxy) -N-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3, 7-dioxabicyclo(3.3.0) octane, 3- (4-chlorophenoxy) -1, 2-propanediol, benzethonium chloride, alkyl- (C)₈-C₁₈) -dimethyl-benzyl ammonium chloride, alkyl- (C)₈-C₁₈) -dimethyl-benzylammonium bromide, alkyl- (C)₈-C₁₈) -dimethyl-benzyl ammonium saccharide, benzyl hemiformal, 3-iodo-2-propynyl-butylcarbamate, sodium hydroxymethyl-aminoacetate and sodium hydroxymethyl-aminoacetate.

In each case, it is also advantageous to use substances in the compositions of the invention which are primarily intended to inhibit the growth of undesirable microorganisms on or in animal organisms. In this connection, in addition to conventional preservatives, further active compounds may be mentioned, in particular cosmetic-relevant products, such as triclosan, climbazol, octoxyglycerol, Octopirox (1-hydroxy-4-methyl-6- (2, 4, 4-trimethylpentyl) -2(1H) -pyridinone, 2-aminoethanol), chitosan, farnesol, glycerol monolaurate or combinations of the stated substances, in addition to a large number of conventional antibiotics. Ingredients having multifunctional properties, including the ability to reduce bacterial, yeast and mold growth, can also be used in the compositions encompassed by the present invention. These ingredients include, but are not limited to, pentane 1, 2-diol, hexane 1, 2-diol, octyl 1, 2-diol, decyl 1, 2-diol, tropolone, hydroxyacetophenone, ethylhexylglycerol, phenoxyethanol as a single ingredient or as a mixture of two or more ingredients

Furthermore, the compositions of the present invention may also comprise substances having a cooling effect. The individual active cooling compounds preferably used in the context of the present invention are listed below. The skilled person will be able to supplement the following list with a large number of other active cooling compounds; the active cooling compounds listed may also be used in combination with each other: l-menthol, d-menthol, racemic menthol, menthone glycerol acetal (trade name:MGA), menthyl lactate (trade name:ML, menthyl lactate is preferably l-menthyl lactateEsters, in particular l-menthyl lactate), menthol ethylaminooxalate(s) ((II)X-Cool), substituted menthyl-3-carboxylic acid amides (e.g., menthyl-3-carboxylic acid N-acetamide), 2-isopropyl-N-2, 3-trimethylbutanamide, substituted cyclohexanecarboxylic acid amides, 3-menthoxypropane-1, 2-diol, 2-hydroxyethyl menthyl carbonate, 2-hydroxypropyl menthyl carbonate, N-acetylglycine menthyl ester, isopulegol, menthyl hydroxycarboxylic acid esters (e.g., menthyl-3-hydroxybutyrate), menthyl monosuccinate, 2-mercaptocyclodecanone, menthyl-2-pyrrolidin-5-one formate, 2, 3-dihydroxy-p-menthyl, 3, 5-trimethylcyclohexanone glycerol ketal, ketals, mixtures thereof, and mixtures thereof, 3-menthyl-3, 6-di-trioxane ester, 3-menthyl methoxyacetate, and irine (icilin).

In a particularly preferred embodiment, the composition may comprise a preservative selected from 4-hydroxyacetophenone, o-cymen-5-ol or mixtures thereof.

Aromatic oil and aromatic agent

Suitable perfume oils are mixtures of natural and synthetic perfumes. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, orange blossom, ylang), stems and leaves (geranium, patchouli, bitter orange), fruits (fennel, coriander, caraway, juniper), fruit peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, aucklandia root, iris, calamus), wood (pine, sandalwood, guaiacum, cedar, rosewood), herbs and grasses (tarragon, lemon grass, sage, thyme), pine needles and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, red myrrh). Animal materials such as civet and castoreum may also be used. Typical synthetic fragrance compounds are esters, ethers, aldehydes, ketones, alcohols and hydrocarbon products. Examples of ester-based fragrance compounds are benzyl acetate, phenoxyethyl isobutyrate, p-tert-butyl cyclohexylacetate, linalyl acetate, dimethylbenzyl ortho acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, phenylglycine ethyl methyl ester, allyl cyclohexylpropionate, styrallyl propionate and benzyl salicylate. Ethers include, for example, benzylethyl ether; and the aldehydes include, for example, linear alkanal having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bergeraldehyde. Examples of suitable ketones are ionone, alpha-isomethylionone and methyl cedryl ketone. Suitable alcohols are anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenethyl alcohol and terpineol. The hydrocarbons mainly include terpenes and balsam. However, it is preferred to use a mixture of different fragrance compounds, which together produce a pleasant fragrance. Other suitable fragrance oils are the less volatile essential oils most commonly used as fragrance ingredients. Examples are sage oil, chamomile oil, clove oil, bee balm oil, peppermint oil, cinnamon leaf oil, lime flower oil, juniper berry oil, vetivert oil, frankincense oil, galbanum oil, labdanum oil and lavender oil. The following are preferably used, alone or in admixture: bergamot oil, dihydromyrcenol, lilial, neolilial, citronellol, phenylethyl alcohol, hexyl cinnamaldehyde, geraniol, benzyl acetone, cyclamen aldehyde, linalool, ethoxymethoxycycloundecane, ambergris, indole, methyl dihydrojasmonate (hedione), sandelic, citrus essential oils, citrus oil, orange oil, allyl amyl glycolate, cycloverral, lavender eye-catcher oil, sage oil, damascone, bourne oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, everyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose ether, romil, ethyl 2-ethyl-hexanoate (otiryl), and 2-tert-butylcyclohexyl ethyl carbonate (floramat).

Dye material

Suitable dyes are, for example, the publication "Kosmetische" of the German society for research and development of dyes (Farbstoff-kommision der Deutschen Forschungsgeseeinschaft)”，Any of the substances listed in Verlag Chemie, Weinheim, 1984, pages 81 to 106, as being suitable and approved for use in cosmetics. Examples include carmine a (c.i.16255), patent blue V (c.i.42051), indigo (c.i.73015), chlorophyllin (c.i.75810), quinoline yellow (c.i.47005), titanium dioxide (c.i.77891), indanthrene blue RS (c.i.69800), and madder red (c.i.58000). Luminol (Luminol) may also be used as a fluorescent dye. Advantageous color pigments are, for example, titanium dioxide, mica, iron oxides (e.g. Fe)₂O₃、Fe₃O₄FeO (OH)), and/or tin oxide. Advantageous dyes are, for example, carmine, berlin blue, chromium oxide green, ultramarine and/or manganese violet.

Preparation

Preferred compositions according to the invention are selected from products for treating, protecting, caring for and cleansing the skin and/or hair or as cosmetic products, preferably as leave-on products (meaning that one or more compounds of formula (I) remain on the skin and/or hair for a longer time than rinse-off products, thereby rendering their moisturizing and/or anti-aging and/or wound healing promoting effects more pronounced).

The formulations of the invention are preferably in the form of emulsions, for example W/O (water-in-oil), O/W (oil-in-water), W/O/W (water-in-oil-in-water), O/W/O (oil-in-water-in-oil) emulsions, PIT emulsions, pickering emulsions, emulsions with low oil content, micro-or nanoemulsions, solutions, for example in oils (fatty oils or fatty acid esters, in particular C6-C32 fatty acid C2-C30 esters) or silicone oils, dispersions, suspensions, creams, emulsions or milk, depending on the preparation method and ingredients, gels (including hydrogels, water-dispersible gels, oleogels), sprays (for example pump sprays or sprays containing propellants) or foam or dipping solutions for wiping cosmetics, detergents, such as soaps, syndets, washing liquors, shower and bath preparations, Bath products (capsules, oils, tablets, salt, bath salt, soap, etc.); effervescent preparations, skin care products such as emulsions (as described above), ointments, pastes, gels (as described above), oils, sesame oils, whey, powders (such as face powder, body powder), face masks, eyebrow pencils, lipsticks, roll-ons, pumps, aerosols (foaming, non-foaming or post-foaming), deodorants and/or antiperspirants, mouth washes and mouth rinses, foot care products (including exfoliants, deodorants), insect repellents, sunscreens, after-sun products, shaving products, after-shave creams, pre-and post-shave lotions, depilatories, hair care products such as shampoos (including 2-in-1 shampoos, antidandruff shampoos, baby shampoos, dry hair shampoos, concentrated shampoos), hair conditioners, hair tonics, hair dyes, styling creams, hair pomades, hair and curling lotions, hair gels, styling aids (such as gels or waxes), hair conditioners (hair conditioners, hair tonics, hair-styling aids (such as gels, hair tonics, hair-sprays, hair-setting aids, hair-setting agents, hair-setting aids, hair-setting agents, hair-setting, Relaxers), hair dyes such as short-time direct hair dyes, semi-permanent hair dyes, hair conditioners, hair care mousses, eye care products, make-up remover, or baby products.

The formulations of the invention are particularly preferably in the form of emulsions, in particular W/O, O/W, W/O/W, O/W/O emulsions, PIT emulsions, Pickering emulsions, emulsions with a low oil content, micro-or nanoemulsions, gels (including hydrogels, water-dispersible gels, oleogels), solutions, for example in oils (fatty oils or fatty acid esters, in particular C)₆-C₃₂Fatty acid C₂-C₃₀Esters) or solutions in silicone oils, or sprays (e.g., pump sprays or sprays with propellants).

The content of auxiliary substances and additives is 5 to 99% b.w., preferably 10 to 80% b.w., based on the total amount of the formulation. The person skilled in the art will readily be able to determine the amounts of cosmetic or dermatological auxiliaries and additives and fragrances to be used in each case by simple trial and error on the basis of the properties of the particular product.

The formulation may also contain up to 99% b.w., preferably, 5 to 80% b.w. of water, based on the total amount of the formulation.

Detergent composition

The fragrance as defined above may be applied to the textile or fibre directly or dissolved in a carrier such as ethanol or aqueous ethanol, or may be incorporated into a laundry composition, particularly an ironing aid composition. Accordingly, another object of the present invention relates to a detergent composition comprising one, two, three, four or more perfumes as defined above.

The invention relates in particular to a detergent composition, preferably an ironing aid, comprising one, two, three, four or more perfumes selected from the group consisting of:

(i) a Boiling Point (BP) of about 100 to about 310 ℃; and/or

(ii) A LogP value of about 1.0 to about 3.0; and/or

(iii) A diffusion coefficient of about 7 to about 9.

The incorporation of the perfume into capsules is particularly useful. In this particular embodiment, the capsules may be applied to textiles during a washing process and release the fragrance during ironing by rupturing the capsules.

The detergent compositions according to the invention may comprise any ingredient commonly found in such compositions, such as anionic, nonionic, cationic, amphoteric or zwitterionic (co-) surfactants, organic solvents, builders, enzymes and other adjuncts, such as anti-soiling agents, thickeners, colourants and perfumes, and the like.

Anionic and zwitterionic co-surfactants

Typical examples of anionic and zwitterionic surfactants include: almond oil amidopropyl amine oxide, almond oil amidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkanol ammonium sulfate, C12-16 alkanol ammonium sulfate, octanol polyether ammonium sulfate, ammonium cocoyl glyceride ammonium sulfate, cocoyl isethionate, cocoyl ammonium sarcosinate, C12-15 alkanol ammonium sulfate, C9-10 perfluoroalkyl ammonium sulfonate, dinonyl ammonium sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-7, ammonium laureth-8, ammonium laureth sulfate, ammonium laureth-5, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-6, ammonium laureth-8, ammonium laureth sulfate, ammonium laureth-15, ammonium laureth-5, ammonium laureth-7, ammonium laureth-9, ammonium laureth-12, ammonium laureth-7, ammonium laureth-12, ammonium laureth-sulfate, ammonium laureth-6, ammonium laureth-2, ammonium laureth-6, ammonium laureth-2, ammonium laureth-6, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-9, ammonium laureth-4, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-sulfate, ammonium laureth-2, ammonium laureth-9, ammonium laureth-2, ammonium laureth-sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl polyether sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel oleyl sulfate, ammonium stearate, ammonium tallate, isostearoyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearoyl hydrolyzed collagen AMP salt, isostearoyl hydrolyzed keratin AMP salt, isostearoyl hydrolyzed soybean AMP salt, isostearoyl hydrolyzed wheat AMP salt, bisoleamidopropyl betaine, arachidic acid, hexyldecanol phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 esters, babassu seed oil acid, babassu oleamidopropyl amine oxide, babassu oleamidopropyl betaine, beeswax acid, behenamidopropyl betaine oxide, behenamidopropyl betaine, and the like, Beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyl polydimethyl siloxane polyglycerol-3, butyl phenol polyether-5 carboxylic acid, butyl phenol polyether-19 carboxylic acid, butyl dimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyl dimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside decanoate, butyl glucoside hydroxypropyl trimethyl ammonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane/cycloalkane, C10-14 alkylbenzene sulfonic acid, C12-14 alkyl di (aminoethyl) glycine HCl, C9-15 alcohol phosphate, Candida/glucose/rapeseed methyl oleate fermentation product, Canola oil amidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, caprylyl/caproyl amidopropyl betaine, caprylyl polyether-4 carboxylic acid, caprylyl polyether-6 carboxylic acid, caprylyl polyether-9 carboxylic acid, caprylic acid, caprylyl collagen amino acids, caprylyl glycine, caprylyl hydrolyzed collagen, caprylyl hydrolyzed keratin, caprylyl keratin amino acids, caprylyl silk amino acids, octyl/decyl glucoside, octyl/decyl wheat bran/straw glycosides, octyl glucoside, octyl glyceryl ether, octyl pyrrolidone, carnitine, ceteareth-20, ceteareth-23, ceteareth-24, ceteareth-25, ceteareth-27, ceteareth-28, ceteareth-29, Ceteareth-30, ceteareth-33, ceteareth-34, ceteareth-40, ceteareth-50, ceteareth-55, ceteareth-60, ceteareth-80, ceteareth-100, ceteareth-25 carboxylic acid, ceteareth-2 phosphate, ceteareth-4 phosphate, ceteareth-5 phosphate, diceteceteth-10 phosphate, ceteth-20, ceteth-23, ceteth-24, ceteth-25, ceteth-30, ceteth-40, ceteth-45, ceteth-150, Ceteth-8 phosphate, ceteth-10 phosphate, ceteth-20 phosphate, ceteth-22, ceteth-24, ceteth-25, ceteth-30, cetyl betaine, chamomile (CHRYSANTHEMUM SINENSE) flower extract, C12-14 hydroxyalkyl hydroxyethyl beta-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropyl amine oxide, cocamidopropyl betaine amide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocamidobutyric acid, cocamidopropionic acid, cocath-7 carboxylic acid, cocath-4 glucoside, cocamidoamphopropionic acid, cocamidoamphopropionate salt, cocoamidoamphopropionate, coco-L-beta-alanine, cocoamidopropyl hydroxysultaine, coco-L-beta-alanine, coco-beta-hydroxy-beta-alanine, coco-hydroxy-beta-alanine, coco-beta-hydroxy-beta-alanine, coco-beta-hydroxy-beta-hydroxy-beta-alanine, and coco-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy-beta-hydroxy, Cocoyl betaine, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed rice protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed soy protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, cocoyl glucoside hydroxypropyl trimethyl ammonium chloride, cocoyl hydroxy sulfobetaine, cocoyl morpholine oxide, cocoyl acid, cocoyl glyceryl polyether-8 esters, cocoyl/oleamidopropyl betaine, cocoyl-sulfobetaine, (coco/sunflower seed oil) amidopropyl betaine, cocoyl choline methyl sulfate, cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, cocoyl betaine, cocoyl glyceryl betaine, cocoyl-L-, Corn oleic acid, cottonseed oil glyceryl polyether-8 esters, C10-16 alkanol polyether-1, C10-16 alkanol polyether-2, C11-13 alkanol polyether-6, C11-13 alkanol polyether-9, C11-13 alkanol polyether-10, C11-15 alkanol polyether-30, C11-15 alkanol polyether-40, C12-13 alkanol polyether-1, C12-13 alkanol polyether-23, C12-14 alkanol polyether-5, C12-14 alkanol polyether-9, C13-15 alkanol polyether-21, C14-15 alkanol polyether-8, C20-22 alkanol polyether-30, C20-40 alkanol polyether-40, C20-40 alkanol polyether-95, C22-24-Alkanopolyether-33, C30-50-Alkanopolyether-40, C9-11-Alkanopolyether-6-carboxylic acid, C9-11-Alkanopolyether-8-carboxylic acid, C11-15-Alkantherpolyether-7-carboxylic acid, C12-13-Alkanther5-carboxylic acid, C12-13-Alkanther7-carboxylic acid, C12-13-Alkanther8-carboxylic acid, C12-13-Alkanther12-carboxylic acid, C12-15-Alkanther7-carboxylic acid, C12-15-Alkanther8-carboxylic acid, C12-15-Alkanther12-carboxylic acid, C14-15-Alkanther8-carboxylic acid, C6-10-Alkanther4-phosphate, C12-13-Alkanther2-phosphate, C12-13-Alkanther10-phosphate, C12-15-alkanolpolyether-6-phosphate, C12-15-alkanolpolyether-8-phosphate, C12-15-alkanolpolyether-10-phosphate, C12-16-alkanolpolyether-6-phosphate, C4-18 perfluoroalkyl ethyl mercaptopropyltrimethylammonium chloride, macrococoma fatty acid amidopropyl betaine, C12-13-alcohol sulfate DEA salt, C12-15-alcohol sulfate DEA salt, ceteareth-2-phosphate DEA salt, cetyl sulfate DEA salt, cocoyl amphoteric dipropionate DEA salt, C12-13-alkanolpolyether-3-sulfate DEA salt, cyclopropyl oleate DEA salt, dodecylbenzene sulfonate DEA salt, isostearic acid DEA salt, laureth sulfate DEA salt, lauryl sulfate DEA salt, linoleate DEA salt, methyl myristate sulfonate DEA salt, myristyl alcohol ether sulfate DEA salt, myristyl sulfate DEA salt, dodecyl benzene sulfonate DEA salt, isostearic acid DEA salt, laureth sulfate DEA salt, lauryl sulfate DEA salt, linoleate DEA salt, methyl myristate DEA salt, myristyl ether sulfate DEA salt, myristic acid DEA salt, myristyl alcohol sulfate DEA salt, oleyl alcohol polyether-5 phosphate DEA salt, oleyl alcohol polyether-20 phosphate DEA salt, DEA PG-oleate, decyl alcohol polyether-7 carboxylic acid, decyl alcohol polyether-7 glucoside, decyl alcohol polyether-9 phosphate ester, decyl amine oxide, decyl betaine, undecyl glucoside, decyl tetradecyl alcohol polyether-30, decyl tetradecyl tetramine oxide, lauramide-MEA sulfosuccinate diammonium, lauryl alcohol sulfosuccinate diammonium, oleamido PEG-2 sulfosuccinate diammonium, dibutoxymethane, di C12-15 alkanol polyether-2 phosphate ester, di C12-15 alkanol polyether-4 phosphate ester, di C12-15 alkanol polyether-6 phosphate ester, di C12-15 alkanol polyether-8 phosphate ester, Di C12-15 alkanolpolyether-10 phosphate, didodecyl butane tetraformate, laureth sulfate diethylamine salt, diethyl hexyl sulfosuccinate sodium, di (hydroxyethyl) C8-10 alkoxypropylamine oxide, di (hydroxyethyl) C9-11 alkoxypropylamine oxide, di (hydroxyethyl) C12-15 alkoxypropylamine oxide, di (hydroxyethyl) cocoamine oxide, di (hydroxyethyl) laurylamine oxide, di (hydroxyethyl) stearylamine oxide, di (hydroxyethyl) tallowylamine oxide, polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane PEG-10 phosphate, polydimethylsiloxane PEG/PPG-7/4 phosphate, polydimethylsiloxane PEG/PPG-12/4 phosphate, polydimethylsiloxane/polyglycerol-3 cross-linked polymer, Polydimethyl siloxane propyl PG-betaine, dimyristyl alcohol phosphate, dioleamide ethyl hydroxyethyl methyl ammonium methyl sulfate, hydrogenated coco acid DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium caprylyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenoyl glutamate, disodium babassu oleyl MEA-sulfosuccinate, disodium decanoyl amphodiacetate, disodium decanoyl amphodipropionate, disodium octanoyl amphodiacetate, disodium octanoyl amphodipropionate, disodium octanoyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl sulfosuccinate, disodium cocoamido MEA-sulfosuccinate, disodium cocoamido MIPA PEG-4 sulfosuccinate, disodium cocoamido MIPA-sulfosuccinate, Disodium cocoamido PEG-3 sulfosuccinate, disodium cocoeth-3 sulfosuccinate, disodium cocoamphocarboxyethylhydroxypropyl sulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium coco-glucoside sulfosuccinate, disodium coco-sulfosuccinate, disodium cocobutylgluceth-10 sulfosuccinate, disodium cocoylglutamate, disodium C12-14 alkanolpolyether-1 sulfosuccinate, disodium C12-14 alkanolpolyether-2 sulfosuccinate, disodium C12-15 alkanolpolyether sulfosuccinate, disodium C12-14 secondary alkanolpolyether-3 sulfosuccinate, disodium C12-14 secondary alkanolpolyether-5 sulfosuccinate, disodium coco-3 sulfosuccinate, disodium C12-14 secondary alkanolpolyether-5 sulfosuccinate, Disodium C12-14 secondary alkanolamine-7 sulfosuccinate, disodium C12-14 secondary alkanolamine-9 sulfosuccinate, disodium C12-14 secondary alkanolamine-12 sulfosuccinate, disodium decyl polyether-5 sulfosuccinate, disodium decyl polyether-6 sulfosuccinate, disodium decyl phenyl ether disulfonate, disodium dihydroxyethyl sulfosuccinoyl undecylenate, disodium cocoyl ethylenediamine PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamic acid, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-MEA-sulfosuccinate, disodium isostearamide amphodiacetate, disodium isostearamide dipropionate, Disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauramido MEA-sulfosuccinate, disodium lauramido MIPA glycol sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth-5 carboxy amphodiacetic acid, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laureth-dihydroxypropyl sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauriminodipropionate, Disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, disodium lauroglutamate, disodium laurphenylether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleamide amphodipropionate, disodium oleyl polyether-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium PEG-4 cocamide MIPA-sulfosuccinate, disodium N-lauroamphoaspartate, disodium laurylphosphate, disodium laurylphosphateglutamate, disodium laurylphosphatedisulfonate, disodium laurylphosphatesulfosuccinate, disodium laurylphosphatedisulfonate, disodium laurylphosphateMEA-10, disodium oleamide MEA sulfosuccinate, disodium linolosuccinate, disodium linoleamide MIPA-2 sulfosuccinate, disodium linoleamide PEG-2 sulfosuccinate, disodium linoleamide, Disodium PEG-12 dimethicone sulfosuccinate, disodium PEG-8 palmitoleic acid glyceride sulfosuccinate, disodium PPG-2-isodecylpolyether-7 carboxy amphodiacetate, disodium ricinoleic acid amide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soy oleoyl amphodiacetate, disodium stearamide MEA-sulfosuccinate, disodium stearimidodipropionate, disodium stearyl amphodiacetate, disodium stearyl glutamate, disodium sulfosuccinate monoacyl stearylamine, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tall oil amide MEA sulfosuccinate, disodium tallow amphodiacetate, disodium soy oleoyl amphoacetate, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfopalmitate, disodium tallowamide MEA sulfosuccinate, disodium tallow amidoMEA sulfosuccinate, disodium tallow amphodiacetate, sodium soy alcohol sulfosuccinate, sodium glyceryl monostearate, sodium lauryl sulfate, disodium tallowamide MEA sulfosuccinate, sodium lauryl sulfate, disodium tallowamide, Disodium tallowimino dipropionate, disodium sulfosuccinamate monotallow amine, disodium tridecanol sulfosuccinate, disodium undecylenamide MEA sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenoglutamic acid, disodium triticale oleoyl MEA sulfosuccinate, disodium triticale oleamide PEG-2 sulfosuccinate, disodium wheat oleamido amphodiacetate, di-TEA cocamide diacetate, bis-TEA oleamido PEG-2 sulfosuccinate, bis-TEA palmitoyl aspartate, sodium ditridecyl sulfosuccinate, dodecylbenzene sulfonic acid, erucylamidopropyl hydroxysultaine, ethylhexanol polyether-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, octyl glyceryl ether, hexyl decanoate, disodium undecylenoyl MEA sulfosuccinate, disodium triticum oleamido oleate, disodium triticum oleamido-2 sulfosuccinate, disodium wheat oleamido amphooleamido amphoacetate, disodium oleamido-2 sulfosuccinate, disodium oleamido-2, cocoyl diacetate, disodium cocoyl acetate, and octyl glyceryl ether, Hydrogenated coconut oil acid, hydrogenated lanolin alcohol polyether-25, hydrogenated menhaden oil fatty acid, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow acyl glutamic acid, hydrogenated Candida extract, Hydroxycetyl polyether-60, hydroxyethyl acetoxymethylammonium PG-polydimethylsiloxane, laureth sulfate hydroxyethylbutylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl/hydroxymyristyl betaine, hydroxystearic acid, amidohydroxysuccinimide C10-40 isoalkanoic acid ethylhexyl ester, amidohydroxysuccinimide C21-22 isoalkanoic acid ethylhexyl ester, hydroxysulfobetaine, IPDI/PEG-15 Soy oil amine oxide, IPDI/PEG-15 Soy oil amine EtOH methyl sulfate copolymer, IPDI/PEG-15 Soy oil Glycine ester copolymer, lsoceteth-30, Isolauryl ether-4 phosphate, Isopolyglyceryl-3 Dimethicone, Isolaurylamine lanolate, Isolaurylbenzenesulfonic acid Isopropylamine salt, Isostearamidopropyl betaine, Isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearyl hydrolyzed collagen, Jojoba oil PEG-150 esters, Jojoba wax PEG-80 esters, Hojojoba wax PEG-120 esters, lanonol polyether-20, lanonol polyether-25, lanonol polyether-40, lanonol polyether-50, lanonol polyether-60, lanonol polyether-75, lanonol acid, lauramidopropyl amine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramidooxide, lauramidopropionic acid, lauryldimethylhydroxypropyldecyl glucoside ammonium chloride, lauryldimethylglucidohydroxypropylammonium chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3-carboxylic acid, Laureth-4-carboxylic acid, laureth-5-carboxylic acid, laureth-6-carboxylic acid, laureth-8-carboxylic acid, laureth-10-carboxylic acid, laureth-11-carboxylic acid, laureth-12-carboxylic acid, laureth-13-carboxylic acid, laureth-14-carboxylic acid, laureth-17-carboxylic acid, laureth-6-citric acid ester, laureth-7-citric acid ester, laureth-1-phosphate ester, laureth-2-phosphate ester, laureth-3-phosphate ester, laureth-4-phosphate ester, laureth-7-phosphate ester, laureth-8-phosphate ester, laureth-7-tartaric acid ester, lauric acid, iminodipropionic acid, laureth-7-tartaric acid ester, laureth-dipropylene glycol, laureth-5-carboxylic acid, laureth-6-carboxylic acid, laureth-8-carboxylic acid, laureth-10-carboxylic acid, laureth-6-citric acid, laureth-7-citric acid, laureth-1-phosphate ester, laureth-2-phosphate ester, laureth-3-4-phosphate ester, laureth-7-phosphate ester, laureth-4-di-propylene glycol, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-di-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth-4-carboxylic acid, laureth, Lauroyl amphodipropionic acid, lauroyl beta-aminopropionic acid, lauroyl collagen amino acids, lauroyl ethyltrimethylammonium methylsulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methylglucamide, lauroyl sarcosine, lauroyl silk amino acids, lauryl betaine, lauryl dimethicone/polyglyceryl-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside hydroxypropyl trimethyl ammonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, lauryl methylglucamine, (lauryl/myristyl) glycol hydroxypropyl ether, (lauryl/myristyl) wheat bran/straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, lauryl dimethyl silicone gum amino acid, lauryl ethyl trimethyl ammonium methosulfate, lauryl dimethyl silicone gum, lauryl dimethyl ammonium chloride, lauryl glucoside hydroxypropyl ammonium chloride, lauryl hydroxyethyl ammonium chloride, lauryl dimethyl silicone, Lauryl pyrrolidone, lauryl dimethyl sulfobetaine, linoleic acid, linolenic acid, linoleic acid, lysine cocoate, macadamia nut oil glyceryl polyether-8 esters, magnesium cocoeth sulfate, magnesium isododecylphenyl sulfonate, magnesium laureth-11 carboxylate, magnesium laureth sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methylcocoyltaurate, magnesium myristyl polyether sulfate, magnesium oleyl polyether sulfate, magnesium cocoeth sulfate/TEA salt, Mannich ice river mud, coconut MEA salt, MEA salt of laureth-6 carboxylic acid, MEA salt, and MEA salt, Lauryl alcohol sulfate ester MEA salt, PPG-6-lauryl alcohol polyether-7 carboxylic acid MEA salt, PPG-8-stearyl alcohol polyether-7 carboxylic acid MEA salt, undecylenic acid MEA salt, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxy PEG-450 amido glutaryl succinamide, methoxy PEG-450 amido hydroxysuccinimide succinate, methoxy PEG-450 maleimide, methyl morpholine oxide, cow milk amide propyl amine oxide, cow milk amide propyl betaine, mink oil amide propyl amine oxide, mink oil amide propyl betaine, C12-15 alkanol polyether sulfate ester MIPA salt, dodecyl benzene sulfonic acid MIPA salt, lauryl alcohol polyether MIPA salt, lauryl alcohol sulfate ester MIPA salt, Mixed isopropanolamine lanolate, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristyl polyether-3 carboxylic acid, myristyl polyether-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristyl amide propyl amine oxide, myristyl amide propyl betaine, myristyl amide propyl dimethylamine phosphate, myristyl amide propyl hydroxysultaine, myristyl amide propyl PG-dimethyl ammonium chloride phosphate, myristyl amine oxide, myristyl amino propionic acid, myristic acid, myristyl ethyl trimethyl ammonium methyl sulfate, myristyl glutamic acid, myristoyl hydrolyzed collagen, myristoyl sarcosine, myristoyl betaine, myristyl/cetyl amine oxide, myristoyl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, myristoyl dimethyl hydroxypropyl cocoyl glucoside chloride, Myristyl glucoside, myristyl phosphate ester, nonylphenol polyether-20, nonylphenol polyether-23, nonylphenol polyether-25, nonylphenol polyether-30, nonylphenol polyether-35, nonylphenol polyether-40, nonylphenol polyether-44, nonylphenol polyether-50, nonylphenol polyether-100, nonylphenol polyether-120, nonylphenol polyether-5 carboxylic acid, nonylphenol polyether-8 carboxylic acid, nonylphenol polyether-10 carboxylic acid, nonylphenol polyether-3 phosphate ester, nonylphenol polyether-4 phosphate ester, nonylphenol polyether-6 phosphate ester, nonylphenol polyether-9 phosphate ester, nonylphenol polyether-10 phosphate ester, dinonylol polyether-30, dinonylol polyether-49, dinonylol polyether-100, dinonylol polyether-150, nonylphenol polyether-30, dinonylol polyether-49, dinonylol polyether-100, Dinonylphenolpolyether-7 phosphate, dinonylphenolpolyether-8 phosphate, dinonylphenolpolyether-9 phosphate, dinonylphenolpolyether-10 phosphate, dinonylphenolpolyether-11 phosphate, dinonylphenolpolyether-15 phosphate, dinonylpolyether-24 phosphate, oat oleamidopropyl betaine, octylphenolpolyether-16, octylphenolpolyether-25, octylphenolpolyether-30, octylphenolpolyether-33, octylphenolpolyether-40, octylphenolpolyether-70, octylphenolpolyether-20 carboxylic acid, octyldodecanol polyether-20, octyldodecanol polyether-25, octyldodecanol polyether-30, oleamidopropyl amine oxide, oleamidopropyl betaine, oleamidopropyl (hydroxysulfo) propyl dimethylammonium, oleamido oxide, Oleic acid, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleyl polyether-20, oleyl polyether-23, oleyl polyether-24, oleyl polyether-25, oleyl polyether-30, oleyl polyether-35, oleyl polyether-40, oleyl polyether-44, oleyl polyether-50, oleyl polyether-3 carboxylic acid, oleyl polyether-6 carboxylic acid, oleyl polyether-10 carboxylic acid, oleyl betaine, olivamidopropylamine oxide, olivamidopropyl betaine, olive oleic acid, olivetoyl hydrolyzed wheat protein, ophiopogon root extract stearate, ozonized oleyl polyether-10, ozonized PEG-10 oleate, ozonized PEG-14 oleate, ozonized polysorbate 80, palmitoleic acid, palmitoleylamidopropyl betaine, palmitoleyl polyether-2 phosphate, Palmitoylamidopropylamine oxide, palmitoylamidopropylbetaine, palmitoylamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoylglycine, palmitoylhydrolyzed collagen, palmitoylhydrolyzed milk protein, palmitoylhydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptides, palmitoyl silk amino acids, palmitoleic acid amidopropylbetaine, peach kernel oil glyceryl polyether-8 esters, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocoamide, coconut oil, PEG-8 cocoamine, PEG-12 cocoamine, PEG-150 behenate, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl cocoate, PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl soya oleate, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl tallowate, PEG-80 glyceryl tallowate, PEG-82 glyceryl tallowate, PEG-130 glyceryl tallowate, PEG-200 glyceryl tallowate, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-30 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-60 hydrogenated castor oil, and PEG-30 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitoleid, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate, PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojoba acid, PEG-40 jojoba acid, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60, PEG-70 lanolin, PEG-75 lanolin, PEG-85 lanolin, PEG-100 lanolin, PEG-150 lanolin, PEG-75 lanolin oil, PEG-2 lauramide, PEG-3 laurylamine oxide, PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannide laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanate, PEG-30 oleylamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglyceryl-2 tristearate, PEG/PPG-28/21 acetate polydimethylsiloxane, PEG/PPG-24/18 butyl ether polydimethylsiloxane, PEG/PPG-3/17 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-8/55 copolymer, PEG/PPG-10/30 copolymer, PEG/PPG-10/65 copolymer, PEG/PPG-12/35 copolymer, PEG/PPG-16/17 copolymer, PEG/PPG-20/9 copolymer, PEG/PPG-20/20 copolymer, PEG/PPG-20/60 copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-2 copolymer, PEG/PPG-3538 copolymer, PEG/PPG-3552 copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG copolymer, PEG/PPG-20/65 copolymer, PEG/PPG-5/35 copolymer, PEG/PPG-24/18 copolymer, PEG/PPG-24/18 copolymer, and PEG/PEG-5/35 copolymer, and PEG/24/18 copolymer, and/PEG/5/35 copolymer, and/PEG/, PEG/PPG-22/25 copolymer, PEG/PPG-28/30 copolymer, PEG/PPG-30-35 copolymer, PEG/PPG-30/55 copolymer, PEG/PPG-35/40 copolymer, PEG/PPG-50/40 copolymer, PEG/PPG-150/35 copolymer, PEG/PPG-160/30 copolymer, PEG/PPG-190/60 copolymer, PEG/PPG-200/40 copolymer, PEG/PPG-300/55 copolymer, PEG/PPG-20/22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG/PPG-4/2 propyl heptyl ether, PEG/PPG-6/2 propyl heptyl ether, PEG/PPG-300/55 copolymer, PEG/PPG-20/22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG/PPG-4/2 propyl heptyl ether, PEG-7/PPG-2 propyl heptyl ether, PEG/PPG-8/2 propyl heptyl ether, PEG/PPG-10/2 propyl heptyl ether, PEG/PPG-14/2 propyl heptyl ether, PEG/PPG-40/2 propyl heptyl ether, PEG/PPG-10/2 ricinoleate, PEG/PPG-32/3 ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate, PEG-120 propylene glycol stearate, PEG-5 rapeseed sterol, PEG-10 rapeseed sterol, PEG-40 ricinoleamide, PEG-75 tallow resin glycerides, PEG-75 buckeye resin glycerides, PEG-20 sorbitan cocoate, PEG-20 sorbitan isostearate, PEG-40 sorbitan lanolate, PEG-75 sorbitan lanolate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, PEG-40 sorbitan stearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soy sterol, PEG-2 stearamide carboxylic acid, PEG-9 stearamide carboxylic acid, PEG-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-10 sorbitan laurate, PEG-20 sorbitan laurate, PEG-40 sorbitan laurate, PEG-10 sorbitan laurate, PEG-20 sorbitan laurate, and PEG-10 sorbitan laurate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallowate, PEG-50 tallowamide, PEG-2 tallowamide DEA, PEG-20 tallowate, PEG-66 trihydroxystearin, PEG-200 trihydroxystearin, PEG-60 camellia oleate glycerides, pelargonic acid, pentadecylphenol polyether-200, phenol polyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 182, PEG-50 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallowamide, PEG-50 tallowamide, PEG-2 tallowamide DEA, PEG-20 tallowester, PEG-66 trihydroxystearin, PEG-200 triolein, PEG-60 camellia oleate glycerides, pelargonic acid, pentadecylphenol polyether-200, phenolpolyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 182, poloxamer 183, poloxamer 184, and poloxamer including glycerol Poloxamer 188, poloxamer 217, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 288, poloxamer 334, poloxamer 335, poloxamer 338, poloxamine 908, poloxamine 1508, dimethicone PEG/PPG-24/19 butyl ether silsesquioxane, dimethicone PPG-13 butyl ether silsesquioxane, Polyglyceryl-6 decanoate, Polyglyceryl-10 dilaurate, Polyglyceryl-20 heptaoctanoate, Polyglyceryl-20 hexacaprylate, Polyglyceryl-2 lauryl ether, Polyglyceryl-10 lauryl ether, Polyglyceryl-20 octoate, Polyglyceryl-6 pentacaprylate, Polyglyceryl-3 dimethicone ethyl dimethicone, Polyglyceryl-6 tetracaprylate, poloxamer 334, poloxamer, Polyglycerol-10 tetralaurate, polyglycerol-6 tricaprylate, polyglycerol-10 trilaurate, polyquaternium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, polyquaternium-81, polyquaternium-82, kumaderrro kamura (POMADERRIS KUMERAHOU) flower/leaf extract, PORIA (PORIA COCOS) extract, potassium abietyl hydrolyzed collagen, potassium babassu oleate, potassium behenate, potassium C9-15 alcohol phosphate, potassium C11-15 alcohol phosphate, potassium C12-13 alcohol phosphate, potassium C12-14 alcohol phosphate, potassium caprate, dipotassium octanoyl glutamate, potassium octanoyl hydrolyzed rice protein, potassium ricinoleate, potassium cocoyl oleate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, corn, Potassium cocoyl keratinate, potassium cocoyl oat protein hydrolysate, potassium cocoyl potato protein hydrolysate, potassium cocoyl rice bran protein hydrolysate, potassium cocoyl rice protein hydrolysate, potassium cocoyl silk hydrolysate, potassium cocoyl soy protein hydrolysate, potassium cocoyl wheat protein hydrolysate, potassium cocoyl yeast protein hydrolysate, potassium cocoyl PCA, potassium cocoyl sarcosinate, potassium cocoyl taurate, potassium corn oleate, potassium cyclopropyl oleate, potassium dihydroxyethyl cocoyl amine oxide phosphate, potassium dimethicone PEG-7 phosphate, potassium dodecylbenzenesulfonate, potassium cannabinoleate, potassium hydrogenated cocoyl oleate, potassium hydrogenated palmitate oleate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium lanolin, potassium laurate, potassium laureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium cocoyl sulfate, potassium cocoyl rice protein hydrolysate, potassium cocoyl silk protein, potassium cocoyl soy protein hydrolysate, potassium cocoyl wheat protein hydrolysate, potassium cocoyl yeast protein hydrolysate, potassium cocoyl calcium carbonate, potassium cocoyl calcium cocoyl sulfate, potassium cocoyl coconut acid, potassium cocoyl fatty acid, potassium salt, potassium lauryl ether-3 fatty acid, potassium lauryl ether-4 fatty acid, potassium lauryl ether fatty acid, potassium salt, potassium lauryl ether fatty acid, potassium salt, potassium lauryl ether fatty acid, potassium salt of fatty acid, sodium salt of sodium lauryl ether, potassium cocoyl fatty acid, sodium lauryl ether, sodium salt of sodium lauryl ether, potassium cocoyl fatty acid, sodium lauryl ether, sodium salt of sodium lauryl ether, sodium lauryl, Potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soybean protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, potassium lauroyl sarcosinate, potassium lauroyl silk amino acid, potassium lauroyl wheat amino acid, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methylcocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olive oleate, potassium oleanoyl hydrolyzed oat protein, potassium oleanoyl hydrolyzed wheat protein, potassium olivetoyl/lauroyl wheat amino acid, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl sulfate, potassium linoleate, potassium olive oleoyl PCA, potassium palmitoleate, potassium palmitate, potassium palmitoyl hydrolyzed zein, potassium palmitoyl hydrolyzed oat protein, potassium palmitoyl hydrolyzed rice protein, potassium palmitoyl hydrolyzed almond protein, potassium palmitoyl hydrolyzed wheat protein, potassium palmate oleate, potassium arachinate, potassium rapeseed oleate, potassium ricinoleate, potassium safflower oleate, potassium soyate, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tallate, potassium tallowate, potassium taurate laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellianate, potassium undecylenate, potassium undecylenoyl hydrolyzed collagen, Undecenoylated potassium rice protein, PPG-30-Butanethole-30, PPG-36-Butanethole-36, PPG-38-Butanethole-37, PPG-30-octanol polyether-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2C9-11 alcohol polyether-8, PPG-1-decanol polyether-5, PPG-3-decanol polyether-2 carboxylic acid, PPG-30-ethylhexanol polyether-4 phosphate, PPG-20-glyceryl polyether-30, PPG-2 hydroxyethyl coconut oil/isostearamide, PPG-2-isodecanol polyether-8, PPG-2-isodecanol polyether-10, PPG-2-isodecanol polyether-18, PPG-2-decylpolyether-25, PPG-4-decylpolyether-10, propyltrimethylammonium hydrolyzed collagen, Quaternary ammonium salt-24, Quaternary ammonium salt-52, Quaternary ammonium salt-87, rapeseed oleic acid, Rice bran acid, Rice oil Glycerol-8 esters, ricinoleic acid amidopropyl betaine, ricinoleic acid polyether-40, safflower oleic acid, Sapindus Oahuensis fruit extract, Saponaria OFFICINALIS (Saponaria OFFICINALIS) root powder, saponin, potassium soap, Sodium/potassium soap, soap base, potassium soap base, sesame oil Glycerol-8 esters, sesame oil amidopropyl amine oxide, sesame amidopropyl betaine, shea butter Glycerol polyether-8 esters, Sodium arachinate, Sodium Arga-nampooacetate, mukul, mukui palm oil Sodium, Sodium avocado oleate, Sodium, Sodium babassu oleoyl amphoacetate, sodium babassu oleate, sodium babassu oil sulfate, sodium behenate, sodium bisglycol ricinoleate sulfosuccinate, sodium bishydroxyethyl glycinate coco glucoside crosslinked copolymer, sodium bishydroxyethyl glycinate lauryl glucoside crosslinked copolymer, sodium borage oil amidopropyl PG-dimethylammonium chloride phosphate, sodium butylphenoxide polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkyl sulfonate, sodium C14-18 alkyl sulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12-13 alkyl sulfate, sodium C12-15 alkyl sulfate, sodium C12-18 alkyl sulfate, sodium C16-20 alkyl sulfate, sodium C9-22 secondary alkyl sulfonate, sodium C14-17 secondary alkyl sulfonate, Sodium caprate, sodium decanoyl amphoacetate, sodium decanoyl amphohydroxypropyl sulfonate, sodium decanoyl amphopropionate, sodium decanoyl methyltaurate, sodium caprylate, sodium octanol polyether-2 carboxylate, sodium octanol polyether-9 carboxylate, sodium octanoyl amphoacetate, sodium octanoyl amphohydroxypropyl sulfonate, sodium octanoyl amphopropionate, disodium octanoyl glutamate, sodium octanoyl hydrolyzed wheat protein, sodium octyl PG-sulfonate, sodium octyl sulfonate, sodium ricinoleate, sodium cetostearyl-13 carboxylate, sodium cetostearyl sulfate, sodium ceteth-13 carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimethylammonium phosphate, sodium cocoamidopropionate, sodium cocoeth sulfate, sodium cocoeth-30 sulfate, sodium cocoyl amphoacetate, sodium cocoate, Sodium cocoyl amphoacetate, sodium cocoyl amphohydroxypropyl sulfonate, sodium cocoyl amphopropionate, sodium cocoyl cocoate, sodium cocoyl alcohol/babassu alcohol sulfate, sodium cocoyl glucoside hydroxypropyl phosphate, sodium cocoyl glucoside hydroxypropyl sulfonate, sodium cocoyl glucoside tartrate, sodium cocoyl alcohol glyceryl ether sulfonate, sodium cocoyl alcohol/hydrogenated tallow alcohol sulfate, sodium cocoyl iminodiacetate, sodium cocoyl monoglyceride sulfate, sodium cocoyl monoglyceride sulfonate, sodium cocoyl PG-dimethyl ammonium chloride phosphate, sodium cocoyl alcohol sulfate, sodium cocoyl sulfoacetate, sodium cocoyl amido propionate, sodium cocoyl amino acid, sodium cocoyl collagen amino acid, disodium cocoyl glutamate, sodium cocoyl glutamate, sodium cocoyl glucoside, sodium cocoyl glyceryl ether phosphate, sodium cocoyl alcohol sulfate, sodium cocoyl amido propionate, sodium cocoyl amido amino acid, sodium cocoyl collagen amino acid, sodium cocoyl glutamate, sodium cocoyl glucoside, and sodium cocoyl glucoside, Sodium cocoyl glycinate, Sodium cocoyl/hydrogenated tallow glutamate, Sodium cocoyl collagenate, Sodium cocoyl keratin hydrolysate, Sodium cocoyl rice protein hydrolysate, Sodium cocoyl fibroin hydrolysate, Sodium cocoyl soy protein hydrolysate, Sodium cocoyl sweet tonsil protein, Sodium cocoyl wheat protein glutamate, Sodium cocoyl isethionate, Sodium cocoyl methylaminopropionate, Sodium cocoyl oat amino acid, Sodium Sodium cocoyl/palmitoyl/Sunfoweryl glutamate, Sodium cocoyl prolinate, Sodium cocoyl sarcosinate, Sodium cocoyl taurate, Sodium cocoyl threonine, Sodium cocoyl wheat amino acid, Sodium C12-14 olefin sulfonate, Sodium C14-16 olefin sulfonate, Sodium C14-18 olefin sulfonate, Sodium C16-18 olefin sulfonate, Sodium corn oleoyl amphoteric Sodium propionate, Sodium cocoyl threonine, Sodium cocoyl wheat amino acid, Sodium C12-14 olefin sulfonate, Sodium C14-16 olefin sulfonate, Sodium C14-18 olefin sulfonate, Sodium C16-18 olefin sulfonate, Sodium corn oleoyl amphoteric Sodium corn oil propionate, Sodium keratide propionate, Sodium cocoyl Sodium keratide, Sodium cocoate, Sodium keratide, Sodium cocoated Sodium keratide, Sodium kerati, Sodium lauroamphoacetate from cottonseed, sodium phosphate ester of C13-15 alkanol polyether-8 butanol, sodium carboxylate of C9-11 alkanol polyether-6, sodium carboxylate of C11-15 alkanol polyether-7, sodium carboxylate of C12-13 alkanol polyether-5, sodium carboxylate of C12-13 alkanol polyether-8, sodium carboxylate of C12-13 alkanol polyether-12, sodium carboxylate of C12-15 alkanol polyether-6, sodium carboxylate of C12-15 alkanol polyether-7, sodium carboxylate of C12-15 alkanol polyether-8, sodium carboxylate of C14-15 alkanol polyether-8, sodium carboxylate of C12-14 secondary alkanol polyether-8, sodium sulfonate of C14-15 alkanol polyether-PG, sodium phosphate of C12-13 alkanol polyether-2, sodium phosphate of C13-15 alkanol polyether-8, sodium sulfate of C9-15 alkanol polyether-3, sodium sulfate of C13-15 alkanol polyether-8, sodium, Sodium C10-15 alkanolpolyether sulfate, sodium C10-16 alkanolpolyether-2 sulfate, sodium C12-13 alkanolpolyether sulfate, sodium C12-15 alkanolpolyether sulfate, sodium C12-15 alkanolpolyether-3 sulfate, sodium C13-15 alkanolpolyether-3 sulfate, sodium C12-14 secondary alkanolpolyether-3 sulfate, sodium C12-15 alkanolpolyether-3 sulfonate, sodium C12-15 alkanolpolyether-7 sulfonate, sodium C12-15 alkanolpolyether-15 sulfonate, sodium decanoeth-2 carboxylate, sodium decanoeth sulfate, sodium decylbenzenesulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di (laureth-7) citrate, sodium di (laureth-10) phosphate, sodium dilinoamidinopropyl PG-dimethylammonium chloride phosphate, sodium decyl glucoside, Sodium dimerized linoleate, sodium di (oleyl polyether-8) phosphate, sodium dodecylbenzenesulfonate, sodium ethyl 2-sulfolaurate, sodium glyceryl oleate phosphate, sodium grapeseed amidopropyl PG-dimethylammonium chloride phosphate, sodium grapeseed acylamino amphoacetate, sodium grapeseed acylamino, sodium cannabinoyl amphoacetate, sodium hexanoeth-4 carboxylate, sodium hydrogenated coconate, sodium hydrogenated cocoyl methyl hydroxyethyl sulfonate, sodium hydrogenated palmityl oleate, sodium hydrogenated tallow, sodium hydrogenated tallowoyl glutamate, sodium lauryl dimethylammonium ethyl phosphate, sodium hydroxypropyl palmityl oleate, sodium hydroxypropyl decyl glucoside cross-linked polymer phosphate, sodium hydroxypropyl lauryl glucoside cross-linked polymer phosphate, sodium hydroxypropyl cocoyl glucoside cross-linked polymer sulfonate, sodium hydroxypropyl decyl glucoside cross-linked polymer sulfonate, sodium lauryl glucoside cross-linked polymer sulfate, sodium lauryl benzene sulfonate, sodium 2-sulfolaurate, sodium glyceryl oleate phosphate, sodium cocoyl chloride, sodium cocoyl glucoside cross-linked polymer sulfate, sodium lauryl dimethyl cocoyl glucoside, sodium lauryl cocoyl glucoside, sodium caproate, sodium cocoyl glucoside cross-linked polymer sulfate, sodium cocoyl glucoside, Sodium hydroxypropyl sulfonate lauryl glucoside cross-linked polymer, sodium hydroxystearate, sodium isostearate, sodium isosteareth-6 carboxylate, sodium isosteareth-11 carboxylate, sodium isosteareth amphoacetate, sodium isosteareth amphopropionate, sodium N-isosteareth methyltaurate, sodium lanolate sulfate, sodium lanolate, sodium lard, sodium lauramidodiacetate, sodium lauraminopropionate, sodium laurate, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, Sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, disodium lauriminodipropionate, sodium lauroamphohydroxypropylsulfonate, sodium lauroamphoPG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycinate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl levulinate, sodium lauroyl sulfate, sodium lauroyl hydroxypropylate, sodium lauroyl levulinate, sodium lauroyl, Sodium lauroyl methyl isethionate, sodium lauroyl Millet amino acid, sodium lauroyl/myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl bis (ethylenediamino) aminoacetate, sodium lauryl glucarate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl diglycol carboxylate, sodium lauryl hydroxyacetamide sulfate, disodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia nut oil, sodium mango oleoyl amphoacetate, sodium mango seed oil, PPG polyether-2 sulfosuccinate/MEA, sodium methoxy-2 acetate, sodium methylcocoyl taurate, sodium PPG polyether-2 sulfosuccinate/MEA, sodium methyl cocoyl taurate, Sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate, sodium isopalmitoyl methyl taurate, sodium methyl taurate cocoyl methyl taurate, sodium myristyl polyether sulfate, sodium myristate, sodium myristoyl amphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristoyl sulfate, sodium nonylphenol polyether-6 phosphate, sodium nonylphenol polyether-9 phosphate, sodium nonylphenol polyether-1 sulfate, sodium nonylphenol polyether-3 sulfate, sodium nonylphenol polyether-4 sulfate, sodium nonylphenol polyether-6 sulfate, Sodium nonylphenol polyether-8 sulfate, sodium nonylphenol polyether-10 sulfate, sodium nonylphenol polyether-25 sulfate, sodium octylphenol polyether-2 ethanesulfonate, sodium octylphenol polyether-2 sulfate, sodium octylphenol polyether-6 sulfate, sodium octylphenol polyether-9 sulfate, sodium oleate, sodium oleamidoamphoacetate, sodium oleamidoamphohydroxypropyl sulfonate, sodium oleamidoamphopropionate, sodium oleamidohydrolyzed collagen, sodium oleamidoisethionate, sodium oleyl polyether sulfate, sodium oleamidomethyl isethionate, sodium oleyl sulfate, sodium oleamidoamphoacetate, sodium oleamidooleate, sodium oleamidoglutamate, sodium palmitomidoamphoacetate, sodium palmitooleate, sodium palmitoyl glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium linoleate, sodium palmitamide oleate, Sodium palmitoyl isethionate, Sodium palmitoyl glutamate, Sodium passion fruit oleate, Sodium arachidoyl amphoacetate, Sodium arachidonate, Sodium PEG-6 cocoamidocarboxylate, Sodium PEG-8 cocoamidocarboxylate, Sodium PEG-4 cocoamidosulfate, Sodium PEG-3 lauramidocarboxylate, Sodium PEG-4 lauramidocarboxylate, Sodium PEG-8 palmitanate, pentaerythrityl hydroxypropyl Sodium iminodiacetate dendrimer, Sodium propoxy PPG-2 acetate, Sodium rapeseed oleate, Sodium rice bran oleoyl amphoacetate, Sodium ricinoleate, Sodium isoacyl amphoacetate, Sodium Sodium Rose hippopapholate, Sodium rosinate, Sodium safflower oleate, Sodium saffloaloyl hydrolyzed soy protein, Sodium sesame seed oleate, Sodium sesame oleoyl amphoacetate, Sodium tallowoyl amphoacetate, Sodium laurylsulfonate, Sodium arachidonate, Sodium cocoamphoacetate, Sodium lauridonate, Sodium oleate, Sodium cocoamphoacetate, Sodium cocoate, Sodium cocoamphoacetate, Sodium palmitate, Sodium cocoamphoacetate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium palmitate, Sodium stearate, Sodium, Sodium soyate, Sodium soyaetoyl hydrolyzed collagen, Sodium stearate, Sodium stearyl amphoacetate, Sodium stearyl amphohydroxypropyl sulfonate, Sodium stearyl amphopropionate, Sodium stearyl casein, Sodium stearyl glutamate, Sodium stearyl hyaluronate, Sodium stearyl hydrolyzed collagen, Sodium stearyl hydrolyzed zein, Sodium stearyl hydrolyzed silk, Sodium stearyl hydrolyzed soy protein, Sodium stearyl hydrolyzed wheat protein, Sodium stearyl lactalbumin, Sodium Sodium stearyl methyl isethionate, Sodium stearyl oat protein, Sodium stearyl pea protein, Sodium stearyl soy protein, Sodium stearyl dimethylglycinate, Sodium stearyl sulfate, Sodium sunflower oleoyl amphoacetate, Sodium cumaroyl lipopeptide, Sodium sweet mandelyl amphoacetate, Sodium sweet almond oleate, Sodium talloyl amphopropionate, Sodium tallowate, Sodium tallowoyl amphoacetate, Sodium tallow fatty acid, sodium tallow fatty acid ester sulfate, sodium calanolide (calaphllum INOPHYLLUM) oleate, sodium taurate, sodium cocoyl methyl taurate, sodium taurate laurate, sodium lauroyl collagen amino acid/TEA salt, sodium lauroyl hydrolyzed collagen/TEA salt, sodium lauroyl hydrolyzed keratin salt/TEA salt, sodium lauroyl keratin amino acid/TEA salt, sodium undecylenoyl collagen amino acid/TEA salt, sodium undecylenoyl hydrolyzed collagen/TEA salt, sodium undecylenoyl hydrolyzed zein protein/TEA salt, sodium undecylenoyl hydrolyzed soy protein/TEA salt, sodium undecylenoyl hydrolyzed wheat protein/TEA salt, cocoa mass (THEOBROMA gradiflower) oleate, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, Sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium trideceth sulfate, sodium trimethylolpropane hydroxypropyl iminodiacetate dendrimer, sodium undecyleth-5 carboxylate, sodium undecylenate amphoacetate, sodium undecylenate propionate, disodium undecylenate glutamate, sodium wheatgerm oleoyl amphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean oleylpropylamine oxide, soybean oleylpropyl betaine, soybean oleyl polyether-8 esters, isostearamidopropylamine oxide, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium undecylenate polyether-5 carboxylate, sodium undecylenate amphoacetate, sodium undecylenate amphopropionate, disodium undecylenate glutamate, sodium wheat germ oleoyl amphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean oleyl propionate, soybean oleyl propylamine oxide, soybean oleyl betaine, sodium isostearamidopropylamine oxide, sodium isostearyl betaine, sodium trideceth-8 esters, sodium trideceth-12 carboxylate, sodium trideceth-12, sodium trideceth-5 carboxylate, sodium undecylenate sulfate, sodium undecylenate-8, sodium undecylenate-2, sodium undecylenate-8, sodium undecylenate-2, sodium undecylenate, Stearamidopropyl betaine, stearylamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, steareth-80, steareth-100, steareth-2 phosphate, steareth-3 phosphate, stearic acid, stearyloxypropyl trimethylammonium chloride, stearoylglutamic acid, stearoyl sarcosine, stearyl betaine, stearyldimethylbutyl glucoside hydroxypropylammonium chloride, stearyldimethyldecyl glucoside hydroxypropylammonium chloride, stearyldilauryl glucoside ammonium chloride, sulfated castor oil, sulfated coconut oil, and mixtures thereof, Sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oil amide MEA, sunflower oil oleic acid, sunflower oil amide propyl hydroxyethyl dimethyl ammonium chloride, sunflower oil glyceryl polyether-8 esters, tall oil acid, tallow amidopropyl amine oxide, tallow amidopropyl betaine, tallow amidopropyl hydroxysultaine, tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow acyl ethyl glucoside, abietyl hydrolyzed collagen salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol TEA sulfate, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate salt, TEA C14-17 secondary alkyl sulfonate salt, low erucic acid seed oleate TEA salt, Cocamide diacetate TEA salt, cocoate TEA salt, cocoyl sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamate TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soy protein TEA salt, cocoyl sarcosine TEA salt, dimethicone PEG-7 phosphate TEA salt, dodecylbenzene sulfonate TEA salt, hydrogenated cocoyl acid TEA salt, hydrogenated tallow acyl glutamate TEA salt, isostearic acid TEA salt, TEA-isostearoyl hydrolyzed collagen TEA salt, lauramidopropionic acid TEA salt, lauric acid/myristic acid TEA salt, laureth sulfate TEA salt, lauroyl collagen amino acid TEA salt, lauroyl glutamate TEA salt, lauroyl hydrolyzed collagen TEA salt, lauroyl keratin amino acid TEA salt, lauroyl methylaminopropionic acid salt, Lauroyl/myristoyl aspartate TEA salt, lauroyl sarcosinate TEA salt, lauryl phosphate TEA salt, lauryl sulfate TEA salt, myristoyl aminopropionate TEA salt, myristic acid TEA salt, myristoyl hydrolyzed collagen TEA salt, oleic acid TEA salt, oleoyl hydrolyzed collagen TEA salt, oleoyl sarcosinate TEA salt, oleyl sulfate TEA salt, palmitic acid TEA salt, palm kernel sarcosinate TEA salt, PEG-3 cocamide sulfate TEA salt, pinoceric acid TEA salt, stearic acid TEA salt, tall acid TEA salt, tridecyl benzene sulfonate TEA salt, undecylenic acid TEA salt, undecylenoyl hydrolyzed collagen TEA salt, tetramethyl decyndiol, dicarboxyethyl stearyl sulfosuccinate tetrasodium, laureth TIPA salt, lauryl sulfate TIPA salt, myristic acid TIPA salt, stearic acid TIPA salt, tocopherol phosphate, trehalose undecylenate, TM-C12-15-Alkanopolyether-2 phosphate, TM-C12-15-Alkanopolyether-6 phosphate, TM-C12-15-Alkanopolyether-8 phosphate, TM-C12-15-Alkanopolyether-10 phosphate, trideceth-20, trideceth-50, trideceth-3-carboxylic acid, trideceth-4-carboxylic acid, trideceth-7-carboxylic acid, trideceth-8-carboxylic acid, trideceth-15-carboxylic acid, trideceth-19-carboxylic acid, trideceth-10 phosphate, tridecylbenzenesulfonic acid, tris (laureth-9) citrate, trimethylolpropane hydroxypropyl bishydroxyethylamine dendrimer, tris (lauroamphoPG-sodium acetate chloride) phosphate, tris (lauroampho PG-sodium acetate chloride) phosphate, Undecanoic acid, undecyleth-5 carboxylic acid, undecylenamidopropylamine oxide, undecylenamidopropylbetaine, undecylenic acid, undecylenoyl collagen amino acid, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acids, undecyl glucoside, wheat germ oleic acid, wheat germ oleamidopropyl amine oxide, wheat germ oleamidopropyl betaine, YUCCA (YUCCA SCHIDIGERA) leaf/root/stem extract, YUCCA SCHIDIGERA stem extract, zinc cocoeth sulfate, and zinc cocoeth sulfate.

Nonionic (co) surfactants

An alcohol alkoxylate. The nonionic surfactants added are preferably alkoxylated and/or propoxylated, in particular primary alcohols which preferably contain 8 to 18 carbon atoms per mole of alcohol and on average 1 to 12 moles of Ethylene Oxide (EO) and/or 1 to 10 moles of Propylene Oxide (PO). Particular preference is given to C having a degree of ethoxylation of from 2 to 10, preferably from 3 to 8, and/or a degree of propoxylation of from 1 to 6, preferably from 1.5 to 5₈-C₁₆Alcohol alkoxylates, advantageously ethoxylates and/or propoxylates C₁₀-C₁₅Alcohol alkoxylates, in particular C₁₂-C₁₄An alcohol alkoxylate. The degrees of ethoxylation and propoxylation constitute statistical averages, which may be whole or fractional for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates/propoxylates, NRE/NRP). In addition to these nonionic surfactants, fatty alcohols having greater than 12EO may also be used. Examples thereof are (tallow) fatty alcohols with 14EO, 16EO, 20EO, 25EO, 30EO or 40 EO.

Alkyl glycosidesIn addition, as an additional nonionic surfactant, a surfactant satisfying the general formula RO (G)_xFor example as compounds, especially together with nonionic surfactants, wherein R is a linear or methyl-branched, especially 2-methyl-branched, aliphatic group having 8 to 22, preferably 12 to 18, carbon atoms, G represents a monosaccharide unit having 5 or 6 carbon atoms, preferably glucose. The degree of glycosylation x, which defines the distribution of mono-and oligoglycosides, is a number between 1 and 10, preferably between 1.1 and 1.4.

Fatty acid ester alkoxylates. Another preferred class of nonionic surfactants, either as sole nonionic surfactant or in combination with other nonionic surfactants, especially with alkoxylated fatty alcohols and/or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters, preferably containing from 1 to 4 carbon atoms in the alkyl chain, more particularly fatty acid methyl esters as described in Japanese patent application JP-A-58/217598 or preferably prepared by the process described in International patent application WO-A-90/13533. Particular preference is given to C having an average of from 3 to 15 EO, in particular from about 5 to 12 EO₁₂-C₁₈Fatty acid methyl ester

An amine oxide. Nonionic surfactants of the amine oxide type, such as N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and also of the fatty acid alkanolamide type, are also suitable. The amount of these nonionic surfactants is preferably not more than the amount of ethoxylated fatty alcohols, especially not more than half thereof.

Gemini surfactants. Other surfactants are the so-called gemini surfactants. Generally, such compounds are those containing two hydrophilic groups and two hydrophobic groups per molecule. These groups are usually separated from each other by a "spacer". Such spacers are typically carbon chains of sufficient length to allow the hydrophilic groups to be sufficiently distant to function independently of each other. Such surfactants are generally characterized by very small critical micelle concentrations and greatly reduce the surface tension of water. However, gemini surfactants in special cases refer not only to dimeric but also to trimeric surfactants. Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers of German patent application DE 4321022A 1 or dimer alcohol-bis-and trimer alcohol-tris-sulfates and-ether-sulfates according to International patent application 96/23768A 1. According to German patent application DE19513391A1, the end-capped dimeric and trimeric mixed ethers are characterized by their bifunctional and polyfunctional nature. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides such as those described in International patent applications WO 95/19953A1, WO 95/19954A1 and WO 95/19955A1 may also be used.

Cationic cosurfactant

A tetraalkylammonium salt. The cationic active surfactant in the aqueous solution contains hydrophobic polymeric groups necessary for the surface activity of the dissociated cations. Important representatives of cationic surfactants are the general formula (R)¹R²R³R⁴N⁺)X^-The tetraalkylammonium salt of (1). Wherein R is¹Represents C₁-C₈Alk (en) yl, R²、R³And R⁴Independently of one another, represent alk (en) yl groups having from 1 to 22 carbon atoms. X is a counter ion, preferably selected from the group consisting of halogen, alkyl sulfate and alkyl carbonate. Particular preference is given to cationic surfactants in which the nitrogen atom is substituted by two long acyl groups and two short alk (en) yl groups.

Ester quaternary ammonium salt. Cationic surfactants particularly useful as co-surfactants in the present invention are represented by the esterquats. Esterquats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds which can be obtained by relevant methods of preparing organic chemistry. Reference may be made to international patent application WO 91/01295a1, in which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed into the reaction mixture and subsequent overall quaternization with dimethyl sulfate or ethylene oxide. Furthermore, german patent DE 4308794C 1 describes a process for preparing solid ester quaternary ammonium salts in which the quaternization of the triethanolamine ester is carried out in the presence of suitable dispersants, preferably fatty alcohols.

A typical example of an ester quat suitable for use according to the present invention is a product whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and the amino component is Triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, the so-called head fractionated fatty acids. Ester quats are preferably used, the acyl component of which is derived from monocarboxylic acids having from 8 to 10 carbon atoms. Other esterquats are those whose acyl component is derived from a dibasic carbonic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and/or dodecanedioic acid, but preferably adipic acid. In general, it is preferred that the acyl group is derived from an esterquat of a mixture of a monocarboxylic acid having from 6 to 22 carbon atoms and adipic acid. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat is from 1:99 to 99:1 and preferably from 50:50 to 90:10 and in particular from 70:30 to 80: 20. In addition to the quaternized fatty acid triethanolamine ester salts, other suitable esterquats are mixtures of mono/dicarboxylic acids with diethanolylamine or 1, 2-dihydroxypropyldialkylamine. Esterquats can be obtained from fatty acids and the corresponding triglycerides in combination with the corresponding dicarboxylic acids. One such process, which may be considered representative of the relevant prior art, is described in european patent EP 0750606B 1. For the production of quaternized esters, the molar ratio of the mixture of mono-and dicarboxylic acids and triethanolamine-based on the available carboxyl functions-can be from 1.1:1 to 3: 1. In view of the properties of esterquats, particularly advantageous ratios have proven to be 1.2:1 to 2.2:1, and preferably 1.5:1 to 1.9: 1. Preferred esterquats are technical mixtures of mono-, di-and triesters having an average degree of esterification of from 1.5 to 1.9.

Amphoteric cosurfactants

A betaine. Amphoteric or zwitterionic surfactants possess a variety of functional groups which can be ionized in aqueous solution and thus-depending on the medium conditions-impart anionic or cationic properties to the compounds (see DIN 53900, month 7 1972). Near the isoelectric point (about pH4), amphoteric surfactants form internal salts and become weakly soluble or insoluble in water. Amphoteric surfactants are subdivided into the zwitterions and the betaines, which behave as zwitterions in solution. An amphiphile is an amphoteric electrolyte, i.e. a compound that has both acidic and basic hydrophilic groups and therefore behaves as an acid or as a base depending on the conditions. In particular, betaines are known surfactants which are produced primarily by carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting materials are preferably condensed with a halocarboxylic acid or a salt thereof, especially sodium chloroacetate, to form one mole of salt per mole of betaine. Addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Examples of suitable betaines are carboxyalkylation products of secondary amines, especially tertiary amines, which correspond to the formula R¹R²R³N-(CH₂)_qCOOX, wherein R¹Is an alkyl radical having from 6 to 22 carbon atoms, R ²Is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R³Is an alkyl radical having 1 to 4 carbon atoms, q is a number from 1 to 6, and X is an alkali and/or alkaline earth metal or ammonium. Typical examples are hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C_12/14Cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C_16/18Tallow alkyldimethylamine and industrial mixtures thereof, and in particular the carboxymethylation products of dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and industrial mixtures thereof.

Alkylamidobetaines. OthersSuitable betaines are carboxyalkylation products of amidoamines, which correspond to the formula R¹CO(R³)(R⁴)-NH-(CH₂)_p-N-(CH₂)_qCOOX, wherein R¹CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, R²Is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R³Is an alkyl radical having 1 to 4 carbon atoms, P is a number from 1 to 6, q is a number from 1 to 3, and X is an alkali and/or alkaline earth metal or ammonium. Typical examples are the reaction products of fatty acids having from 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, eleostearic acid, arachidonic acid, cis (9) -eicosenoic acid, behenic acid, erucic acid and technical mixtures thereof, with N, N-dimethylaminoethylamine, N-dimethylaminopropylamine, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which is condensed with sodium chloroacetate. Commercially available products include K andPK(Cognis Deutschland GmbH&co, KG) andBetaine(Goldschmidt)。

imidazoline. Other suitable starting materials for betaines for the purposes of the present invention are imidazolines. These substances are also known and can be reacted, for example, with 1 or 2 mol of C₆-C₂₂Cyclized condensation of fatty acids with polyfunctional amines, such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open chain betaines. Typical examples are the condensation products of the above mentioned fatty acids with AEEA, preferably lauric acid based imidazolines, which are subsequently ammonified with sodium chloroacetate. Commercially available products includeG(Cognis Deutschland GmbH&Co.,KG)。

The amount of (co) surfactant in the compositions of the invention is preferably from 0.1 to 90% by weight, in particular from 10 to 80% by weight, and particularly preferably from 20 to 70% by weight.

Organic solvent

The liquid light or heavy duty detergent may contain organic solvents, preferably those which are miscible with water. Polyglycols, ethers, alcohols, ketones, amides and/or esters in amounts of 0 to 90% by weight, preferably 0.1 to 70% by weight, in particular 0.1 to 60% by weight, are preferably used as organic solvents for this purpose. Low molecular weight polar substances such as methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerol, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide or mixtures thereof are preferred.

Enzyme

A cellulase. If present, the cellulase enzyme, optionally used in the ready-to-use detergent composition, is preferably incorporated in an amount sufficient to provide up to about 5mg, more preferably from about 0.01mg to about 3mg, of active enzyme per gram of the composition. Unless otherwise indicated, the compositions herein preferably contain from about 0.001% to about 5%, preferably 0.01% -1% by weight of a commercially available enzyme preparation.

Cellulases suitable for use in the present invention include bacterial or fungal cellulases. Preferably they have a pH optimum of 5 to 9.5. Suitable cellulases are fungal cellulases produced by Humicola insolens and Humicola strain DSM1800 or a fungus belonging to the genus Aeromonas which produces cellulase 212D, and cellulases extracted from the hepatopancreas of marine mollusks (Dolabella Auricula Solander), suitable cellulases also being disclosed in GB 2,075,028A. Furthermore, cellulases particularly suitable for use are disclosed in WO 1992013057 a 1. Most preferably, the cellulase used in the ready to use cleaning composition is available from NOVO Industries A/S under the tradenames CAREZYMEO and CELLUZYMEO.

Other enzymes. Additional enzymes may be included in the washing composition for various fabric washing purposes, including for example, removal of protein, carbohydrate, triglyceride based stains, and for prevention of mobile dye transfer and fabric repair. Additional enzymes to be incorporated include proteases, amylases, lipases and peroxidases, and mixtures thereof. Other types of enzymes may also be included. They may be obtained from any suitable source, for example plant, animal, bacterial, fungal and yeast sources. However, their choice is governed by a number of factors, such as pH-activity and/or stability optima, thermal stability, stability vs. active detergent, adjunct and potential for off-flavour development in use. In this regard, bacterial or fungal enzymes are preferred, such as bacterial amylases and proteases.

Enzymes are generally incorporated in an amount sufficient to provide up to about 5mg, more particularly from about 0.01mg to about 3mg, of active enzyme per gram of composition. Unless otherwise indicated, the compositions herein generally contain from about 0.001% to about 5%, preferably 0.01% -1% by weight of a commercially available enzyme preparation. The protease enzyme is typically present in such commercial preparations in an amount sufficient to provide an activity of 0.005 to 0.1 Anson Units (AU) per gram of composition.

Suitable examples of proteases are subtilisins obtained from specific strains of Bacillus subtilis and Bacillus licheniformis. Other suitable proteases are obtained from strains of Bacillus having maximum activity in the pH range of 8-12, under the registered trade mark by Novo Industries A/SDeveloped and sold. The preparation of this and similar enzymes is described in Novo patent GB 1,243,784. Commercially available proteolytic enzymes suitable for use in removing protein-based stains include those under the trade nameAndsold by Novo Industries A/S and under the trade nameSold by International Bio-Synthesis, Inc. Other proteases according to US 5,204,015 and US 5,244,791 include protease a; protease B and a protease manufactured by Genencor International, inc.

Amylases, including, for example, alpha-amylases such asInternational Bio-Synthesis, Inc. andNovo Industries。

suitable lipases for washing use include those produced by microorganisms of the Pseudomonas group, such as Pseudomonas stutzeri (Pseudomonas stutzeri) ATCC 19154. Such lipases are available under the trade name lipase P "Amano" from Amano Pharmaceutical co. Other commercially available lipases include Amano-CES, the lipase ex Chromobacterium viscosum, e.g., as Chromobacterium viscosum var. lipolyticum NRRLB 3673, available from Toyo Jozo Co., and Chromobacterium viscosum lipases available from U.S. Biochemical Corp. and Disoynth Co., and the lipase ex Pseudomonas adioli. The preferred lipase for use herein is that obtained from Humicola lanuginosaEnzymes (commercially available from Novo Industries A/S).

Peroxidase enzymes are used in combination with oxygen sources, such as percarbonates, perborates, persulfates, hydrogen peroxide, and the like. They are used for "solution bleaching", i.e. to prevent dyes or pigments released from one substrate during a washing operation from transferring to another substrate in the washing solution. Peroxidases are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidase such as chloro-and bromo-peroxidase. Detergent compositions containing peroxidase enzymes are disclosed, for example, in WO 1989099813 a 1.

An enzyme stabilizer. Enzymes for use herein are stabilized by the presence in the final detergent composition of a water-soluble source of calcium and/or magnesium ions which the composition provides to the enzyme. (calcium ions are generally somewhat more effective than magnesium ions and are preferred herein if only one type of cation is used). Additional stability can be provided by the presence of various other stabilizers of the disclosed technology, particularly borates: see US 4537706, which is incorporated herein in its entirety. Typical detergents, especially liquids, contain from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 5 to about 15, and most preferably from about 8 to about 12mmol of calcium ions per liter of the final composition. The formulations may contain water soluble calcium ions in the solid detergent composition in an amount sufficient to provide the above-mentioned amounts in the laundry liquor. Alternatively, natural water hardness is sufficient.

This means that the above amounts of calcium and/or magnesium ions are sufficient to provide enzyme stability. More calcium and/or magnesium ions may be added to the composition to provide an additional means of oil removal. Thus in general the compositions herein will generally contain from about 0.05% to about 2% by weight of a water soluble source of calcium or magnesium ions or both. The amount may of course vary with the amount and type of enzyme used in the composition.

The compositions herein may optionally, but preferably, contain various additional stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used in the composition in amounts of from about 0.25% to about 10%, preferably from about 0.5% to about 5%, more preferably from about 0.75% to about 3%, by weight of boric acid or other borate compound capable of forming boric acid in the composition (calculated on the basis of boric acid). Boric acid is preferred, although other compounds such as boric oxide, borax, and other alkali metal borates (e.g., sodium borate, sodium metaborate, sodium pyroborate, and sodium pentaborate) are suitable. Boronic acids (e.g., phenylboronic acid, butaneboronic acid, and p-bromophenylboronic acid) may also be suitably used.

Builder

A zeolite. Fine-grained synthetic zeolites containing bound water, preferably zeolite a and/or zeolite P, can be used as builders. Specially for treating diabetesAn additional preferred zeolite P is zeolite map. However, zeolite X and mixtures of zeolite A, X, Y and/or P are also suitable. Particularly preferred is the trade nameRX (commercially available product of Condea Augusta s.p.a.) co-crystallized sodium/potassium silicoaluminate of zeolite X and zeolite a. Preferably, spray-dried powdered zeolite can be used. In the case of addition of the zeolite in the form of a suspension, small amounts of nonionic surfactants may be added as stabilizers, for example 1 to 3% by weight, based on the zeolite, of ethoxylated C having 2 to 5 ethylene oxide groups ₁₂-C₁₈Fatty alcohols, C with 4 to 5 ethylene oxide groups₁₂-C₁₄Fatty alcohols or ethoxylated isotridecanol. Suitable zeolites have an average particle size of less than 10 μm (measurement method: volume distribution Coulter counter) and preferably contain from 18 to 22% by weight, more preferably from 20 to 22% by weight, of bound water. In addition, phosphates may also be used as builders.

A layered silicate. A suitable substitute or partial substitute for phosphates and zeolites is crystalline, layered sodium silicate. Such crystalline layered sodium silicates are described, for example, in European patent application EP 0164514A 1. Preferred crystalline layered silicates are those obtained by the process described, for example, in international patent application WO 91/08171a 1.

An amorphous silicate. Preferred builders also include the modulus (Na)₂O:SiO₂Ratio) of from 1:2 to 1:3.3, preferably from 1:2 to 1:2.8 and more preferably from 1:2 to 1:2.6, which has the characteristics of delayed dissolution and multiple washing cycles. This delayed dissolution behavior compared to conventional amorphous sodium silicates can be achieved in various ways, for example by surface treatment, compounding, compacting/compressing or by overdrying. In the context of the present invention, the term "amorphous" also means "X-ray amorphous". In other words, in X-ray diffraction tests, silicates do not give the typical X-ray reflection of any crystalline material, but at best have one or more peaks of scattered X-rays with a diffraction of several degrees The width of the corner. However, particularly good builder properties can be achieved when the silicate particles produce no distinct or even clear diffraction peaks in the electron diffraction test. This is understood to mean that the product has a crystallite range of 10 to several hundred nanometers, wherein preferably the value is at most 50 nanometers, in particular at most 20 nanometers. Such X-ray amorphous silicates of this type which likewise have delayed dissolution properties compared with conventional waterglasses are disclosed in German patent application DE 4400024A 1. Particularly preferred are compressed/densified amorphous silicates, composite amorphous silicates and overdried X-ray amorphous silicates.

A phosphate salt. It is also possible to use the commonly known phosphates as builders, provided that such use should not be avoided for ecological reasons. Particularly suitable are the sodium salts of orthophosphoric acid, pyrophosphoric acid and especially tripolyphosphates. The content thereof is generally not more than 25% by weight, preferably not more than 20% by weight, based on the final composition. In some cases, in particular tripolyphosphate, at low levels of up to 10% by weight, based on the final composition, in combination with other builders already shows a synergistic improvement in the secondary wash power. The phosphate is preferably used in an amount of less than 10% by weight, in particular 0% by weight.

Auxiliary builder

A polycarboxylic acid. Useful organic co-builders are, for example, polycarboxylic acids which can be used in the form of their sodium salts of polycarboxylic acids, where polycarboxylic acids are carboxylic acids which bear more than one acid function. Including, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), and derivatives and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

An organic acid. The acid itself may also be used. In addition to its building action, acids generally also have the effect of acidifying components, so that relatively low and mild pH values can be established in the detergent or cleaning composition. Mention may in particular be made of citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and mixtures thereof. Other suitable acidifying agents are known pH regulators such as sodium bicarbonate and sodium bisulfate.

A polymer. Particularly suitable polymeric co-builders are polyacrylates, preferably having molecular weights of from 2000 to 20000 g/mol. Short-chain polyacrylates having a molar mass of 2000 to 10000g/mol, and particularly preferably 3000 to 5000g/mol, are preferred in this group on account of their outstanding solubility. Suitable polymers may also include those which are composed partially or completely of vinyl alcohol units or derivatives thereof.

Other suitable salts of the copolycarbonates are in particular copolymers of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid and maleic acid, which contain from 50 to 90% by weight of acrylic acid and from 50 to 10% by weight of maleic acid, have proven particularly suitable. The relative molecular weight thereof, based on free acid, is generally from 2000 to 70000g/mol, preferably from 20000 to 50000g/mol and in particular from 30000 to 40000 g/mol. The (co) polycarboxylates may be added as an aqueous solution or preferably as a powder. To improve water solubility, the polymers may also contain allylsulfonic acid monomers, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, for example, in EP 0727448B 1.

Biodegradable polymers containing more than two different monomer units are particularly preferred, examples being those in DE 4300772A 1 which contain as monomers salts of acrylic acid and maleic acid, and vinyl alcohol or vinyl alcohol derivatives, or acrylic acid and 2-alkylallyl sulfonates, and sugar derivatives. Other preferred copolymers are those described in german patent applications DE 4303320 a1 and DE 4417734 a1 and preferably comprise acrolein and acrylic acid/acrylate or acrolein and vinyl acetate as monomers.

Likewise, other preferred builders are polymeric aminodicarboxylic acids, salts thereof or precursor materials thereof. Particularly preferred are polyaspartic acids or salts and derivatives thereof, which have a bleach-stabilizing action in addition to the builder properties, as disclosed in German patent application DE 19540086A 1.

Other suitable builders are polyacetals obtained by reacting dialdehydes with polyhydroxycarboxylic acids having from 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in European patent application EP 0280223A 1. Preferred polyacetals are obtained from dialdehydes, such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, and polyhydroxycarboxylic acids, such as gluconic acid and/or glucoheptonic acid.

A carbohydrate. Other suitable organic co-builders are dextrins, such as oligomers or polymers of carbohydrates, which are obtained by partial hydrolysis of starch. The hydrolysis can be carried out by conventional methods, for example acid-catalyzed or enzyme-catalyzed methods. Preference is given to hydrolysates having an average molar mass of from 400 to 500000 g/mol. Preferably a polysaccharide having a Dextrose Equivalent (DE) of from 0.5 to 40, more particularly from 2 to 30, wherein DE is an acceptable measure of the reduction of the polysaccharide compared to glucose having a DE of 100. Maltodextrins with a DE of 3 to 20 and dry glucose syrups with a DE of 20 to 37, as well as so-called yellow and white dextrins with a higher molecular weight of 2000 to 30000g/mol, can be used. Preferred dextrins are described in british patent application 9419091.

Oxidized derivatives of such dextrins relate to the reaction product of the dextrin with an oxidizing agent, which is capable of oxidizing at least the alcohol function of the sugar ring to a carboxylic acid function. Such oxidized dextrins and processes for their preparation are known, for example, from european patent application EP0232202a 1. A product oxidized at C6 of the sugar ring is particularly preferred.

Other suitable co-builders are oxydisuccinates and other derivatives of disuccinates (Disuccinatene), preferably ethylenediamine disuccinate. Preference is given to using ethylenediamine-N, N' -disuccinic acid (EDDS) in the form of its sodium or magnesium salts, the synthesis of which is described, for example, in U.S. Pat. No. 4, 3,158,615. Particularly preferred herein are glycerol disuccinates and glycerol trisuccinates, as described in US 4,524,009. The amount added in the formulation containing zeolite and/or silicate is 3 to 15% by weight.

A lactone. Other organic auxiliary builders which may be used are, for example, acetylated hydroxycarboxylic acids or salts thereof, which may optionally also be present in the form of lactones and which contain at least 4 carbon atoms, at least 1 hydroxyl group and up to 2 acid groups. Such co-builders are described, for example, in international patent application WO 95/20029 a 1.

Bleaching compound, bleaching preparation and bleaching activator

The detergent compositions herein may optionally contain a bleaching formulation or a bleaching composition comprising a bleaching formulation and one or more bleach activators. If present, bleaching agents are generally present at levels of at least about 1% to about 30%, more particularly about 5% to about 20% of the detergent composition, especially for fabric laundering. If included, the bleach activator is typically present at a level of from about 0.1% to about 60%, more preferably from about 0.5% to about 40%, of the bleach composition comprising bleach plus bleach activator.

The bleaching agent used herein may be any bleaching agent suitable for use in detergent compositions for cleaning fabrics, cleaning hard surfaces, or other cleaning applications now known or to be known. These include oxygen bleaches as well as other bleaching agents. Perborate bleaches such as sodium perborate (e.g., monohydrate or tetrahydrate) may be used herein.

Another class of bleaching agents that may be used without limitation includes percarboxylic acid bleaching agents and salts thereof. Suitable examples of such bleaches include magnesium monoperoxyphthalate hexahydrate, magnesium m-chloroperbenzoate, magnesium 4-nonylamino-4-oxoperoxybutyrate and magnesium diperoxydodecanedioate.

Peroxygen bleaches may also be used. Suitable peroxy bleach compounds include sodium carbonate peroxyhydrate and its equivalent, "percarbonate" bleaches, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, and sodium peroxide. Persulfate bleach (e.g.,commercially produced by DuPont).

Preferred percarbonate bleach compositions comprise dry particles having an average particle size in the range of from about 500 to about 1000 microns, no more than about 10% by weight of said particles being less than about 200 microns and no more than about 10% by weight of said particles being greater than about 1250 microns. Optionally, the percarbonate may be coated with silicate, borate or water soluble surfactants. Percarbonate is available from various suppliers.

Mixtures of bleaching agents may also be used.

Peroxygen bleaches, perborates, percarbonates, and the like are preferably used in combination with bleach activators, which result in the in situ generation of peroxyacids corresponding to the bleach activators in aqueous solution (i.e., during the wash). Nonoyloxybenzene sulfonate (NOBS) and Tetraacetylethylenediamine (TAED) activators are typical activators, and mixtures thereof may also be used.

Preferred amido-derived bleach activators include (6-octanoylamino-hexanoyl) oxybenzene-sulfonate, (6-nonanoylamino hexanoyl) oxybenzene-sulfonate, (6-decanoylamino-hexanoyl) oxybenzene-sulfonate and mixtures thereof.

Another class of bleach activators includes the benzoxazines disclosed in US4966723, which is incorporated herein by reference.

Highly preferred lactam activators include benzoyl caprolactam, octanoyl caprolactam, 3,5, 5-trimethylhexanoyl caprolactam, nonanoyl caprolactam, decanoyl caprolactam, undecenoyl caprolactam, benzoyl valerolactam, octanoyl valerolactam, decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactam, 3,5, 5-trimethylhexanoyl valerolactam and mixtures thereof, optionally adsorbed on a solid support, such as acyl caprolactam, preferably benzoyl caprolactam, which is adsorbed into sodium perborate.

Those bleaching agents other than oxygen bleaching agents are also well known in the art and may be used in the present invention. One particularly preferred class of non-oxygen bleaching agents includes photosensitizing bleaching agents such as sulfonated zinc and/or aluminum phthalocyanines. If used, detergent compositions typically contain from about 0.025% to about 1.25% by weight of such bleaching agents, especially zinc phthalocyanine sulfonates.

If desired, the bleaching compound may be catalyzed by a manganese compound. Such manganese-based catalysts are well known in the art and include Mn ^IV ₂(u-O)₃(1,4, 7-trimethyl-1, 4, 7-triazacyclononane)₂(PF₆)₂，Mn^III ₂(u-O)₁(u-OAc)₂(1,4, 7-trimethyl-1, 4, 7-triazacyclononane)₂(ClO₄)₂，Mn^IV ₄(1,4, 7-triazacyclononane)₄(ClO₄)₄，Mn^IIIMn^IV ₄(u-O)₁(u-OAc)₂(1,4, 7-trimethyl-1, 4, 7-triazacyclononane)₂(ClO₄)₃，Mn^IV(1,4, 7-trimethyl-1, 4, 7-triazacyclononane) - (OCH₃)₃(PF₆) And mixtures thereof.

In practice, without limitation, the compositions and methods of the present invention may be adjusted to provide at least about one per million of active bleach catalyst in the aqueous wash solution, preferably from about 0.1ppm to about 700ppm, more preferably from about 1ppm to about 500ppm of catalyst species in the wash solution.

Polymeric soil release agents

Any polymeric soil release agent known to those skilled in the art can be employed in the detergent compositions and methods of the present invention. Polymeric soil release agents are characterized by containing a hydrophilic moiety for hydrophilizing the surface of water-conveying fabrics such as polyester and nylon, and a water-conveying moiety which is deposited on the water-conveying fibers and remains adhered thereto throughout the washing process, thereby serving as a anchor for the hydrophilic moiety. This allows stains treated with the soil release agent to be more easily removed in a subsequent cleaning procedure.

Polymeric soil release agents as used herein include in particular those soil release agents which are provided with (a) one or more nonionic hydrophilic components consisting essentially of: (i) a polyoxyethylene segment having a degree of polymerization of at least 2, or (ii) propylene oxide or a polyoxypropylene segment having a degree of polymerization of 2 to 10, wherein said hydrophilic segment does not comprise any oxypropylene units unless it is linked to the proximal portion of each end by an ether, or (iii) a mixture of oxyethylene units and oxyalkylene units of 1 to 30 oxypropylene units, wherein said mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component is of sufficient size To enhance the hydrophilic properties of the surface of conventional polyester synthetic fibers as measured by deposition of soil release agents on the surface of the fabric, said hydrophilic segments preferably comprise at least about 25% ethylene oxide units and more preferably, especially for those components having from about 20 to 30 propylene oxide units, they contain at least about 50% ethylene oxide units; or (b) one or more hydrophobic components comprising (i) C₃Oxyalkylene terephthalate segments wherein if said hydrophobic component further comprises oxyethylene terephthalate, oxyethylene terephthalate and C are present₃A ratio of oxyalkylene terephthalate units of about 2: 1 or less, (ii) C₄-C₆Alkylene or oxy C₄-C₆(ii) an alkene moiety, or a mixture thereof, (iii) a poly (vinyl ester) moiety, preferably a poly (vinyl acetate) having a degree of polymerisation of at least 2 or (iv) C₁-C₄Alkyl ethers or C₄Hydroxyalkyl ether substituents, or mixtures thereof, wherein said substituents are C₁-C₄Alkyl ethers or C₄A hydroxyalkyl ether cellulose derivative or a mixture thereof, wherein the cellulose derivative is amphoteric or a combination of (a) and (b) such that they have a sufficient amount of C₁-C₄Alkyl ethers and/or C ₄The hydroxyalkyl ether units are deposited onto the surface of conventional polyester synthetic fibers and retain a sufficient amount of hydroxyl groups once they are bonded to the surface of conventional synthetic fibers to enhance the hydrophilic properties of the fiber surface.

Typically, the polyoxyethylene segments of (a) (i) have a degree of polymerization of from about 200, preferably from 3 to about 150, more preferably from 6 to about 100, although higher degrees of polymerization may also be used. Oxygen C suitable for use₄-C₆Alkenyl hydrophobe segments include, but are not limited to, endcaps of polymeric soil release agents.

Polymeric soil release agents useful in the present invention also include cellulose derivatives such as hydroxy ether cellulose polymers, block copolymers of terephthalic acid monoethylene glycol or terephthalic acid monopropylene glycol with polyethylene oxide or polypropylene oxide terephthalate, and the like. Such formulations are commercially available andcomprising hydroxy ethers of cellulose, e.g.(DOW). The cellulosic soil release agents useful in the present invention also include C₁-C₄Alkyl and C₄Hydroxyalkyl cellulose.

Soil release agents characterized by a poly (vinyl ester) hydrophobic segment include poly (vinyl esters), such as C₁-C₆Graft copolymers of vinyl esters, preferably copolymers of poly (vinyl acetate) grafted to a polyalkylene oxide backbone, such as a polyethylene oxide backbone, see 0,219,048, incorporated herein in its entirety. Such soil release agents which are commercially available include Substances of the kind obtainable, for example, from BASFH P-22。

One preferred class of soil release agents are copolymers having random blocks of terephthalic acid monoethylene glycol and polyethylene oxide (PEO) terephthalate. The polymeric soil release agent has a molecular weight of from about 25,000 to about 55,000.

Another preferred polymeric soil release agent is a polyester having ethylene glycol terephthalate repeat units comprising from 10 wt.% to 15 wt.% ethylene glycol terephthalate units and from 90 wt.% to 80 wt.% polyoxyethylene terephthalate units derived from polyoxyethylene glycol having an average molecular weight of 300-5000. Examples of such polymers include those commercially available5126 (manufactured by Dupont) andt (manufactured by ICI).

Yet another preferred polymeric soil release agent is the sulfonated product of a substantially linear ester oligomer having an oligomeric ester backbone of terephthaloyl and oxyalkylene repeat units and terminal moieties covalently attached to the backbone. Such soil release agents are fully described in US4,968,451. Other suitable polymeric soil release agents include terephthalate polyesters in US4,711,730, anionic capped oligoesters in US4,721,580 and block polyester oligomers in US4,702,857, and anionic, particularly sulfoaroyl capped terephthalates in US4,877,896, all of which are incorporated herein by reference in their entirety.

Further preferred soil release agents are oligomers having the following repeating units: terephthaloyl units, sulfoisophthaloyl units, oxyethylene groups and oxy-1, 2-propylene units. These repeating units form the backbone of the oligomer and are preferably capped with a modified isethionate. Particularly preferred soil release agents of this type comprise about one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethylene and oxy-1, 2-propyleneoxy units in a ratio of about 1.7 to about 1.8, and two capping units of sodium 2- (2-hydroxyethoxy) ethanesulfonate. Said soil release agent further comprises from about 0.5 wt% to about 20 wt%, based on the weight of the oligomer, of a crystallization-reducing stabilizer, preferably selected from the group consisting of xylene sulfonate, cumene sulfonate, toluene sulfonate and mixtures thereof.

Soil release agents, if used, are generally used at levels of from about 0.01% to about 10.0%, usually from about 0.1% to about 5%, preferably from about 0.2% to about 3.0% by weight of the detergent compositions herein.

Polymeric dispersants

Polymeric dispersants are advantageously employed in the detergent compositions of the present invention in amounts of from about 0.1 wt% to about 7 wt%, especially in the presence of zeolite and/or layered silicate builders. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, although other dispersants known in the art may also be used. While not wanting to be limited by theory, it is believed that the polymeric dispersant enhances overall detergency builder performance by crystal growth inhibition, particle soil release peptization, and anti-redeposition when used with other builders (including low molecular weight polycarboxylates).

Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing the appropriate unsaturated monomers, preferably in the acid form. Unsaturated monomeric acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The presence of monomeric segments containing non-carboxylic acid groups such as vinyl methyl ether, styrene, ethylene, and the like in the polymeric polycarboxylate is suitable provided that such segments do not constitute more than about 40% by weight.

Particularly suitable polymeric polycarboxylates can be prepared from acrylic acid. These acrylic acid-based polymers used in the present invention are water-soluble salts of polymerized acrylic acid. The average molecular weight of these polymers in acid form is preferably about 2000-10,000, more preferably about 4,000-7,000, and most preferably about 4,000-5,000. The water-soluble salts of these acrylic polymers may include, for example, alkali metal, ammonium and substituted ammonium salts. Such soluble polymers are known materials. The use of such polyacrylates in detergent compositions has been disclosed, for example, in US3,308,067.

Acrylic acid/maleic acid based copolymers may also be used as preferred ingredients for the dispersing/anti-redeposition agent. These materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of these copolymers in acid form is preferably about 2,000-100,000, more preferably about 5,000-75,000, and most preferably about 7,000-65,000. The ratio of acrylate to maleate segments in these copolymers is generally from about 30:1 to about 1:1, more preferably from about 10:1 to 2: 1. The water-soluble salts of these acrylic/maleic copolymers may include, for example, alkali metal, ammonium and substituted ammonium salts. Such water-soluble acrylate/maleate copolymers are known from EP 0193360A 1, which also describes that such polymers contain hydroxypropyl acrylate. Other useful dispersants include maleic/acrylic acid/vinyl alcohol terpolymers, such as the 45/45/10 terpolymer of maleic/acrylic acid/vinyl alcohol.

Another polymeric material that may be added is polyethylene glycol (PEG). PEG can exhibit dispersant properties and can act as a clay soil removal-antiredeposition agent. Typical molecular weights used for these purposes range from about 500 to about 100,000, preferably from about 1,000 to about 50,000, more preferably from about 1,500 to about 10,000.

Polyaspartic and polyglutamic acid dispersants may also be used, particularly in admixture with zeolite builders. The molecular weight (average) of dispersants such as polyaspartic acid is about 10,000.

Foam inhibitor

Conventional suds suppressors can be advantageously added to the composition, especially during automatic washing processes. Suitable suds suppressors include, for example, natural or synthetic soaps containing a significant amount of C₁₈-C₂₄A fatty acid. Non-surface-active types of foam inhibitors are, for example, organopolysiloxanes and mixtures thereof with finely divided, optionally silanized silicon dioxide, and paraffins, waxes, microcrystalline waxes and mixtures thereof with silanized silicon dioxide or distearyldiethylenediamine. Preferably, mixtures of various foam inhibitors are used, for example mixtures of silicones, paraffins or waxes. Preferably, the foam inhibitor, especially a silicone and/or paraffin containing foam inhibitor, is loaded onto a particulate, water soluble or dispersible carrier material. Especially in this case mixtures of paraffin and distearyldiethylenediamine are preferred.

Compounds that reduce or inhibit foam formation may be added to the detergent compositions of the present invention. Suds suppression is particularly important in so-called "high intensity washing processes" and front-loading european style washing machines.

Various materials can be used as foam inhibitors, and foam inhibitors are known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447(John Wiley & Sons, Inc., 1979). One class of foam inhibitors of particular interest includes monocarboxylic fatty acids and their soluble salts. Monocarboxylic fatty acids and their salts useful as suds suppressors generally have hydrocarbon chains having from 10 to about 24 carbon atoms, preferably from 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium, potassium, and lithium salts, as well as ammonium and alkylolammonium salts.

The detergent compositions of the present invention may also contain non-surfactant suds suppressors. These include, for example, high molecular weight hydrocarbons such as paraffins, fatty acid esters (e.g., fatty acid triglycerides), monohydric alcohol esters of fatty acids, aliphatic C₁₈-C₄₀Ketones (e.g., stearyl ketone), and the like. Other suds suppressors include N-alkylated aminotriazines such as tri-to hexa-alkyl melamines (alkylmelamines) or di-to tetraalkyldiamine chlorotriazines formed as the product of cyanuric chloride with 2 to 3 moles of a primary or secondary amine containing 1 to 24 carbon atoms, propylene oxide, monostearyl phosphate esters such as monostearyl alcohol phosphate esters, monostearyl dialkali metal (e.g., sodium, potassium, lithium) phosphate esters, and phosphate esters. Hydrocarbons such as paraffin and halogenated paraffin can be used in liquid form. The liquid hydrocarbon is liquid at room temperature and atmospheric pressure, has a pour point in the range of about-40 ℃ to about 50 ℃, and a minimum boiling point of no less than about 110 ℃ (atmospheric pressure). It is also known to utilize waxy hydrocarbons, preferably having a melting point below about 100 ℃. Hydrocarbon foam inhibitors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having from about 12 to about 70 carbon atoms. The term "paraffin" as used in this section of the foam inhibitor discussion is meant to include mixtures of real paraffin and cyclic hydrocarbons.

Another preferred class of non-surfactant suds suppressors comprises silicone suds suppressors. Included in this category are the use of polyorganosiloxane oils, such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxane with silica gel particles, wherein the polyorganosiloxane is chemisorbed or fused onto the silica gel. Silicone foam inhibitors are well known in the art.

Other silicone foam inhibitors are disclosed in U.S. Pat. No. 3,455,839, incorporated herein in its entirety, which relates to compositions and methods for defoaming aqueous solutions by adding small amounts of polydimethylsiloxane fluids.

Mixtures of siloxanes with silanized silica gels are described, for example, in DE-OS 2124526, which is incorporated herein in its entirety. . Silicone antifoams and foam control agents in granular detergent compositions are disclosed in US 4,652,392.

In preferred silicone suds suppressors for use herein, the solvent of the continuous phase is composed of certain polyethylene glycols or polyethylene-polypropylene glycol copolymers or mixtures thereof (preferred), or polypropylene glycol. The primary silicone suds suppressor is branched/crosslinked, preferably not linear.

The silicone suds suppressors of the present invention preferably comprise polyethylene glycol and polyethylene/polypropylene glycol copolymers having an average molecular weight of less than about 1,000, preferably about 100-800. The polyethylene glycol and polyethylene/polypropylene glycol copolymers used in the present invention have a solubility in water at room temperature of greater than about 2% by weight, preferably greater than about 5% by weight.

Preferred solvents for use in the present invention are polyethylene glycol having an average molecular weight of less than about 1,000, more preferably about 100-800, and most preferably about 200-400, and polyethylene glycol/polypropylene glycol copolymers, preferably PPG200/PEG 300. The weight ratio of polyethylene glycol to polyethylene glycol/polypropylene glycol copolymer is preferably from about 1:1 to 1:10, most preferably from 1:3 to 1: 6.

Preferred silicone suds suppressors for use herein are free of polypropylene glycol, particularly polypropylene glycol having a molecular weight of 4000. They are also preferably free of block copolymers of ethylene oxide and propylene oxide,L101。

other suds suppressors useful herein comprise secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of these alcohols with silicone oils. The secondary alcohol comprises a compound having C₁-C₁₆C of the chain₆-C₁₆An alkyl alcohol. The preferred alcohol is 2-butyloctanol, which is available under the trademark Condea 12 are purchased. Mixtures of secondary alcohols may be trademarked123 from Enichem company. The mixed suds suppressors are typically a 1:5 to 5:1 by weight mixture of alcohol + silicone.

The compositions of the present invention generally contain from 0% to about 5% of a suds suppressor. When used as suds suppressors, the monobasic fatty acids and salts thereof are generally used in amounts up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of a monobasic fatty acid suds suppressor is used. Silicone suds suppressors are generally employed in amounts up to about 2% by weight of the detergent composition, although greater amounts may be employed. The upper limit of the amount can be determined by practice, mainly considering the lowest cost and the effect of the lower amount to effectively control foaming. Preferably, from about 0.01% to about 1% of the silicone foam inhibitor is used, more preferably from about 0.25% to about 0.5%. As used in the present invention. These weight percent values include any silica used in the polyorganosiloxane blend, as well as any additives that may be used. Monostearyl phosphate suds suppressors are generally employed in amounts of from about 0.1% to about 2% by weight of the composition. The hydrocarbon foam inhibitor is generally used in amounts of about 0.01% to about 5.0%, although greater amounts may be used. Alcohol suds suppressors are generally used in amounts of 0.2% to 3% by weight of the finished composition.

Chelating agents

Polyphosphates can be considered as chelating agents or stabilizers, especially for peroxy compounds and enzymes sensitive to heavy metal ions. For example, 1-hydroxyethane-1, 1-diphosphonic acid sodium salt, diethylenetriamine pentamethylenephosphonic acid sodium salt or ethylenediaminetetramethylenephosphonic acid sodium salt are used in amounts of from 0.1 to 5% by weight.

The detergent compositions of the present invention may also optionally contain one or more iron and/or manganese chelating agents. These chelating agents may be selected from the group consisting of amino carboxylates, amino phosphonates, polyfunctionally-substituted aromatic chelating agents and mixtures thereof, all as hereinafter defined. Without being limited by theory, it is believed that the benefits of these materials are due, in part, to the extraordinary ability to remove iron and manganese ions from the wash solution by generating soluble chelates. Some of the detergent builders described above may be used as chelating agents and may provide both functions if such detergent builders are present in sufficient levels.

Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetetraacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetramine hexaacetate, diethylenetriaminepentaacetate, and ethanoldiglycine, alkali metal, ammonium, and substituted ammonium salts thereof, and mixtures thereof.

Amino phosphonates are also suitable for use as chelating agents in the compositions of the present invention when at least low total phosphorus levels are permitted in detergent compositions, including ethylenediamine tetra (methylene phosphonate), nitrilotris (methylene phosphonate) and diethylenetriamine penta (methylene phosphonate) or DEQUEST. Preferably, these amino phosphonates do not contain alkyl or alkenyl groups of 6 carbon atoms or more.

Polyfunctionally substituted aromatic chelating agents are also suitable for use in the compositions of the present invention. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes, such as 1, 2-dihydroxy-3, 5-disulfobenzene.

Preferred biodegradable chelating agents for use in the present invention are ethylenediamine disuccinate ("EDDS"), particularly the [ S, S ] isomer.

These chelants, if used, are typically present in the detergent composition at a level of from about 0.1 wt% to about 10 wt%. More preferably, such compositions, if used, contain from about 0.1% to about 3.0% by weight of the chelating agent.

Clay soil removal/antiredeposition agent

The detergent compositions of the present invention can also optionally contain water-soluble ethoxylated amines having clay soil removal and anti-redeposition properties. Granular detergent compositions containing these compounds generally contain from about 0.01% to about 10.0% by weight of a water-soluble ethoxylated amine; liquid detergent compositions typically contain from about 0.01% to about 5%.

The most preferred clay soil removal and anti-redeposition agent is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US 4,597,898. Another preferred class of clay soil removal-antiredeposition agents are the cationic compounds disclosed in EP 111,965, the ethoxylated amine polymers disclosed in EP 111,984a1, the zwitterionic polymers disclosed in EP 112,592a1, and the amine oxides disclosed in US 4,548,744. Another preferred class of antiredeposition agents includes carboxymethyl cellulose (CMC) materials. Such materials are well known in the art.

Browning inhibitors

The browning inhibitor has the task of keeping the contaminants detached from the fibers suspended in the cleaning liquid and thus avoiding re-adsorption of the contaminants. For this purpose, mostly organic natural water-soluble sols, such as (co) polycarboxylic acids, sizes, salts of gelatin, ether carboxylic acids or ether sulfonates of starch or cellulose, or salts of acid sulfates of cellulose or starch, are suitable. Also suitable for this purpose are water-soluble polyamides containing acidic groups. In addition, soluble starch preparations and the like, such as hydrolyzed starch, aldehyde starch and the like, can be used as the above-mentioned starch products. Polyvinylpyrrolidone may also be used. Preferred cellulose ethers are, however, such as carboxymethylcellulose (sodium salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, and polyvinylpyrrolidone, used in amounts of from 0.1 to 5% by weight, based on the composition.

Fluorescent whitening agents and UV absorbers

Any fluorescent whitening agent or other brightening or whitening agent known in the art can generally be incorporated into the detergent compositions of the present invention in an amount of from about 0.05% to about 1.2% by weight. Commercially available optical brighteners which may be used in the present invention may be classified in subgroups including, but not limited to, stilbene, pyrazoline, coumarin, carboxylic acid, methanecyanine, dibenzothiophene-5, 5-dioxide, azoles, derivatives of 5-and 6-membered heterocycles, and other various agents.

Preferred whitening agents include VeronaA series of whitening agents. Other disclosed whitening agents include:UNPA, Tinopal CBS and Tinopal 5BM from Ciba-Geigy; articCC and Artic White CWD from Hilton-Davis; 2- (4-styryl-phenyl) -2H-naphthol [1,2-d]Triazoles; 4,4' -bis- (1,2, 3-triazol-2-yl) -stilbene; 4,4' -bis (styryl) biphenyls; and aminocoumarins. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin, 1, 2-bis (benzimidazol-2-yl) ethene, 1, 3-diphenyl-pyrazolines, 2, 5-bis (benzoxazol-2-yl) thiophene, 2-styryl-naphtho [1,2-d]Oxazole and 2- (stilbene-4-yl) -2H-naphtho [1,2-d ]A triazole. Anionic brighteners may be preferred for use in the compositions of the present invention.

The compositions may contain, for example, derivatives of diaminostilbene disulfonic acid and alkali metal salts thereof as optical brighteners. Suitable optical brighteners are, for example, 4 '-bis (2-anilino-4-morpholinyl-1, 3, 5-triazin-6-amino) stilbene-2, 2' -disulfonic acid or compounds of similar structure which carry diethanolamino, methylamino, phenylamino or 2-methoxyethylamino groups instead of morpholinyl groups. In addition, substituted biphenylstyryl brighteners may be present, for example the alkali metal salts of 4,4' -bis (2-sulfostyryl) -biphenyl, 4' -bis (4-chloro-3-sulfostyryl) -biphenyl or 4- (4-chlorostyryl) -4' - (2-sulfostyryl) -biphenyl. Mixtures of the above optical brighteners may also be used.

In addition, UV absorbers may be added. UV absorbers are compounds with excellent absorption properties for ultraviolet radiation, which as UV stabilizers can also improve the photostability of pigments and dyes used in textile fibers and protect the skin of the wearer of the fiber product by preventing UV radiation from penetrating through the fiber waves. Generally highly effective non-radiative inerting compounds are derivatives of benzophenones substituted by hydroxy and/or alkoxy groups, in particular in the 2-and/or 4-position. Also suitable are substituted benzotriazoles, acrylates substituted in the 3-position by phenyl and optionally in the 2-position by cyano (cinnamic acid derivatives), salicylates, organic Ni complexes, and natural substances such as umbelliferone and also bulk urocanic acid. In a preferred embodiment the UV absorber absorbs UV-a and UV-B radiation and possibly UV-C radiation and re-emits light of blue wavelength, from which additionally an optical brightening effect is obtained. Preferred UV absorbers contain triazine derivatives, such as hydroxyaryl-1, 3, 5-triazine, sulfonated 1,3, 5-triazine, o-hydroxyphenyl-benzotriazoles and 2-aryl-2H-benzotriazoles, as well as bis (anilinotriazinyl-amino) stilbene disulfonic acid and its derivatives. Ultraviolet absorbing dyes such as titanium dioxide may also be used as UV absorbers.

Dye transfer inhibitors

The detergent compositions of the present invention may also contain one or more materials effective for preventing the transfer of dyes from one fabric to another during the laundering process. Typically the dye transfer inhibiting agents include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanines, peroxidases, and mixtures thereof. These agents, if used, are generally present in an amount of from about 0.01% to about 10%, preferably from about 0.01% to about 5%, and more preferably from about 0.05% to about 2% by weight of the composition.

More specifically, polyamine N-oxide polymers that are preferably used in the present invention are described in US 6,491,728, which is incorporated herein in its entirety.

Any polymer backbone can be used so long as the amine oxide polymer formed is water soluble and has dye transfer inhibiting properties. Examples of suitable polymeric backbones are polyethylenes, polyalkylenes, polyesters, polyethers, polyamides, polyimides, polyacrylates and mixtures thereof. These polymers include random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide. Amine N-oxide polymers typically have a ratio of amine to amine N-oxide of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by suitable copolymerization or a suitable degree of N-oxidation. Polyamine oxides can be obtained in almost any degree of polymerization. The average molecular weight is generally 500-1000000; more preferably 1000-; most preferably 5000-. A preferred class of substances may be referred to as "PVNO".

The most preferred polyamine N-oxide for use in the detergent compositions of the present invention is poly (4-vinylpyridine-N-oxide) having an average molecular weight of about 50000 and an amine to amine N-oxide ratio of about 1: 4.

Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (known as "PVPVI") are also preferred for use in the present invention. The average molecular weight of PVPVPVI is preferably 5000-. The PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone in the range of from 1:1 to 0.2:1, more preferably from 0.8:1 to 0.3:1, most preferably from 0.6:1 to 0.4: 1. These copolymers may be linear or branched.

The compositions of the present invention may also employ polyvinylpyrrolidone ("PVP") having an average molecular weight of from about 5000 to about 400000, preferably from about 5000 to about 200000, more preferably from about 5000 to about 50000. PVP is known to those skilled in the detergent art. Compositions containing PVP may also contain polyethylene glycol ("PEG") having an average molecular weight of from about 500 to about 100000, preferably from about 1000 to about 10000. Preferably, the ratio of PEG to PVP, on a ppm basis, provided in the wash solution is from about 2:1 to about 50:1, more preferably from about 3:1 to about 10: 1.

The detergent compositions of the present invention may also optionally contain from about 0.005% to 5% by weight of certain hydrophilic optical brighteners which provide dye transfer inhibition. If used, the compositions of the present invention preferably contain from about 0.01% to 1% by weight of such optical brighteners.

A preferred whitening agent is 4,4' -bis [ (4-anilino-6- (N-2-di-hydroxyethyl) -s-triazin-2-yl) amino]-2,2' -stilbenedisulfonic acid and disodium salt. This particular class of whitening agents is known under the trade nameSold by Ciba-Geigy. Tinopal-UNPA-GX is a hydrophilic optical brightener preferably used in the detergent compositions of the present invention.

Another preferred brightener is 4,4' -bis [ (4-anilino-6- (N-2-hydroxy)ethyl-N-methylamino) -s-triazin-2-yl) amino]Disodium salt of 2,2' -stilbenedisulfonic acid. This particular class of whitening agents is known under the trade name TinopalSold by Ciba-Geigy.

Another preferred brightener is 4,4' -bis [ (4-anilino-6-morpholino-s-triazin-2-yl) amino]-2,2' -stilbenedisulfonic acid, sodium salt. This particular class of whitening agents is known under the trade name TinopalSold by Ciba-Geigy.

The particular fluorescent whitening agents selected for use in the present invention provide particularly effective dye transfer inhibiting properties when used in combination with the polymeric dye transfer inhibiting agents selected above. The combination of such selected polymeric materials (e.g. PVNO and/or PVPVI) with such selected optical brighteners (e.g. Tinopal UNPA-GX, Tinopal 5BM-GX and/or Tinopal AMS-GX) provides significantly better inhibition of dye transfer in aqueous wash solutions than either of the two detergent composition components used alone. Without being limited by theory, it is believed that the mode of action of such whitening agents is: because of their high affinity for fabrics in the wash solution, they deposit relatively quickly on these fabrics. The extent to which the brightener deposits on the fabric in the wash solution is defined by a parameter known as the "exhaustion coefficient". The exhaustion coefficient generally refers to the ratio of a) the brightener species deposited on the fabric to b) the initial brightener concentration in the aqueous wash solution. Brighteners with a relatively high exhaustion coefficient are most suitable in the context of this type of technology for inhibiting dye transfer.

Of course, it will also be appreciated that other types of conventional optical brighteners from these compounds may optionally be used in the compositions of the present invention to provide conventional fabric "whitening" benefits, but in fact have no dye transfer inhibiting effect. Such applications are conventional and well known in detergent formulation.

Thickening agent

Combination ofThe compositions may also contain conventional thickeners and anti-deposition compositions as well as viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and derivatives thereof, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, polyamine derivatives such as quaternized and/or ethoxylated hexamethylenediamine and mixtures thereof. Preferred compositions have a viscosity of less than 10,000 mPas, using a Brookfield viscometer at 20 ℃ for 50min^-1Measured at shear rate.

Inorganic salt

Other suitable ingredients of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; alkali metal carbonates and amorphous silicates, mainly Na, are used in particular₂O:SiO₂Sodium silicate in a molar ratio of 1:1 to 1:4.5, preferably 1:2 to 1: 3.5. Preferred compositions contain alkali metal salts, builders and/or co-builders, preferably sodium carbonate, zeolite, crystalline layered sodium silicate and/or trisodium citrate, anhydrous material in an amount of from 0.5 to 70% by weight, preferably from 0.5 to 50% by weight, in particular from 0.5 to 30% by weight.

Fragrances and colorants

The composition may contain other typical detergent and cleaning composition ingredients such as perfumes and/or colorants, preferably leaving no or only no significant coloring of any colorant on the washed fibers. The total amount of added colorants is preferably less than 1% by weight, preferably less than 0.1% by weight, based on the composition. The composition may also contain a white dye such as TiO₂。

Capsule

As described below, the perfume is applied to the fibres by means of capsules. Generally, they are encapsulated by a solid covering material, preferably selected from the group consisting of starch, degraded or chemically or physically modified starches (in particular dextrins and maltodextrins), gelatin, gum arabic, agar-agar, ghatti gum, gellan gum, modified and unmodified celluloses, Pullulan (Pullulan), Curdlan (Curdlan), carrageenan, alginic acid, alginates, pectin, inulin, xanthan gum and mixtures of two or more of said substances.

The solid encapsulating material is preferably gelatin (in particular porcine, bovine, chicken and/or fish gelatin and mixtures thereof, preferably comprising at least one gelatin having a bloom value of greater than or equal to 200, preferably a bloom value of greater than or equal to 240), maltodextrin (preferably obtained from corn, wheat, tapioca or potato, preferably a maltodextrin having a DE value of 10 to 20), modified cellulose (e.g. cellulose ether), alginate (e.g. sodium alginate), carrageenan (e.g. beta-, iota-, lambda-and/or kappa-carrageenan), gum arabic, carrageenan and/or agar. The use of gelatin is preferred, in particular because of its good availability at different bloom values. Particularly preferred, especially for oral administration, are seamless gelatin or alginate capsules, the covering of which dissolves very rapidly in the mouth or breaks upon chewing. The preparation can be carried out in EP 0389700A 1, US 4,251,195, US 6,214,376, WO 2003055587 or WO 2004050069A 1.

The capsules may also be in the form of microcapsules. The term "microcapsules" is understood to mean spherical aggregates having a diameter of about 0.0001 to about 5mm, which contain at least one solid or liquid core surrounded by at least one continuous shell. In particular, it is a finely divided liquid or solid phase encapsulated by a film-forming polymer, which is deposited on the material to be encapsulated after emulsification and coagulation or interfacial polymerization. In another method, the liquid active ingredient is absorbed in a matrix ("microsponge"), which may additionally be coated with a film-forming polymer as microparticles. Very small capsules, also known as nanocapsules, can be dried like a powder. In addition to mononuclear microcapsules, polynuclear polymers, also known as microspheres, contain two or more cores distributed in a continuous coating material. The single-or multi-core microcapsules may be surrounded by additional second and third membranes. The membrane may be constructed of natural, semi-synthetic or synthetic materials. Natural membrane materials are, for example, gum arabic, agar, agarose, maltodextrin, alginic acid or salts thereof, e.g. sodium or calcium alginate, fats and fatty acids, cetyl alcohol, collagen, chitosan, lecithin, gelatin, albumin, shellac, polysaccharides, such as starch or dextran, polypeptides, protein hydrolysates, sucrose and waxes. Semi-synthetic film materials include chemically modified celluloses, especially cellulose esters and cellulose ethers, such as cellulose acetate, ethyl cellulose, hydroxypropyl methylcellulose and carboxymethyl cellulose, and starch derivatives, especially starch ethers and starch esters. The synthetic membrane material is a polymer such as polyacrylate, polyamide, polyvinyl alcohol or polyvinyl pyrrolidone.

Examples of known microcapsules are the following commercial products (film materials in parentheses): hallcrest microcapsules (gelatin, gum arabic), Coletica Thalaspheres (marine collagen), Lipotec Millicapsell (alginic acid, agar), Induchem Unispheres (lactose, microcrystalline cellulose, hydroxypropyl methylcellulose), Unicerin C30 (lactose, microcrystalline cellulose, hydroxypropyl methylcellulose), Kobo glycerospheres (modified starches, fatty acid esters, phospholipids), Softspheres (modified agar), and Kuhs Probiol Nanospheres (phospholipids).

Usually, when using formulations containing microcapsules, the active ingredient is released from the microcapsules by mechanical, thermal, chemical or enzymatic destruction of the film. Although the prior art has a wide range of possibilities for the encapsulation of active substances, the process of obtaining a shell by coacervation, precipitation or polycondensation of anionic and cationic polymers has been well suited for the formation of stable capsules. In particular, a preferred method for encapsulating an active ingredient according to the invention is characterized in that it comprises the following steps:

(a) preparing a matrix from a gel forming agent, a cationic polymer and an active ingredient;

(b) optionally dispersing the matrix in an oil phase; and

(c) Treating the dispersed matrix with an aqueous solution of an anionic polymer and optionally removing the same phase in the process.

Of course, the anionic and cationic polymers in steps (a) and (c) may be exchanged.

In the context of the present invention, preferred gel formers are substances which are capable of forming a gel in aqueous solution at temperatures above 40 ℃. Typical examples of such gel formers are heteropolysaccharides and proteins. The preferred thermal gelling heteropolysaccharide is agarose, which is obtainable from red algae in the form of agar, even with up to 30% by weight of non-gel forming agar gel. The major components of agarose are linear polysaccharides of galactose and 3, 6-anhydro-L-galactose, with alternating 1, 3-and 1, 4-glycosidic linkages. The heteropolysaccharide preferably has a molecular weight of 110,000 to 160,000 and is odorless and tasteless. Suitable alternatives are pectin, xanthan (including xanthan) and mixtures thereof. Other preferred types are those which still form gels in 1 wt.% aqueous solution which do not melt below 80 ℃ and re-solidify above 40 ℃. Examples from thermal gelling proteins are various gelatins.

Preferred anionic polymers suitable for this purpose include alginates. Alginic acid is a mixture of a carboxyl group-containing polysaccharide with the following idealized monomer units:

The average molecular weight of the alginic acid or alginate is in the range of 150,000 to 250,000. Alginates and their fully and partially neutralized products are understood to be, in particular, alkali metal salts, preferably sodium alginate ("algin") and also ammonium and alkaline earth metal salts. Particular preference is given to mixed alginates, such as sodium/magnesium or sodium/calcium alginate. However, in alternative embodiments of the invention, carboxymethyl cellulose and anionic chitosan derivatives, such as carboxylation products and especially succinylation products, are also suitable for this purpose.

Chitosan is a biopolymer belonging to hydrocolloids and represents a preferred cationic polymer. Chemically, they are partially deacetylated chitins, varying in molecular weight, containing the following idealized monomer units:

chitosan is a cationic biopolymer under these conditions, in contrast to most hydrocolloids, which are negatively charged at biological pH values. Positively charged chitosan is capable of interacting with oppositely charged surfaces and is therefore useful in cosmetic hair care and body care products as well as pharmaceutical formulations.

In a preferred embodiment of the invention, an aqueous solution of 1 to 10% by weight, preferably 2 to 5% by weight, of a gel former, preferably agar, is generally prepared and heated under reflux. Adding a second aqueous solution containing a cationic polymer, preferably chitosan, in an amount of 0.1 to 2% by weight, preferably 0.25 to 0.5% by weight, and an active ingredient in an amount of 0.1 to 25, preferably 0.25 to 10% by weight, to boiling heat, preferably at 80 to 100 ℃; this mixture is called a matrix. Thus, the microcapsules may also comprise from 0.1 to 25% by weight of the active ingredient, based on the weight of the capsule. If desired, water-insoluble ingredients, such as inorganic pigments, may also be added at this stage to adjust the viscosity, usually in the form of a water or water/alcohol dispersion. Furthermore, it is useful to add emulsifiers and/or solubilizers to the matrix in order to emulsify or disperse the active ingredient. After preparation from the gel former, cationic polymer and active ingredient, the matrix is optionally very finely dispersed in the oil phase using intense shear to produce small particles during subsequent encapsulation. It has proven particularly advantageous in this connection to heat the substrate to a temperature of from 40 to 60 ℃ while cooling the oil phase to from 10 to 20 ℃. True encapsulation, i.e. the contacting of the cationic polymer with the anionic polymer in the matrix to form a film, takes place in the third step. For this purpose, it is advisable to wash the matrix dispersed in the oil phase with an aqueous solution of an anionic polymer, preferably alginate, at a temperature of 40 to 100, preferably 50 to 60 ℃, at a level of 0.1 to 3, preferably 0.25 to 0.5% by weight, while removing the oil phase (if present). The resulting aqueous formulations typically have a microcapsule content of 1 to 10% by weight. In some cases it may be advantageous for the polymer solution to contain other ingredients, such as emulsifiers or preservatives. After filtration, microcapsules with an average diameter of preferably 1-3mm are obtained. It is recommended that the capsules be sieved to ensure a uniform size distribution. The microcapsules so obtained may have any shape within the limits associated with production, but are preferably substantially spherical.

Examples

Example 1

Preferred fragrances for long-lasting performance

Example 2

Preferred fragrances for heat-activated properties

Particularly preferred are fragrances which exhibit:

(i) a Boiling Point (BP) of about 180 to about 250 ℃; and/or

(ii) A LogP value of about 1.5 to about 2.5; and/or

(iii) A diffusion coefficient of about 7.5 to about 8.5.

More preferred are perfumes exhibiting:

(i) a Boiling Point (BP) of about 250 to about 280 ℃; and/or

(ii) A LogP value of about 1.8 to about 2.3; and/or

(iii) A diffusion coefficient of about 7.8 to about 8.2.