阅读说明：本技术 一种臭氧短序漂白桉木板皮浆的方法 (Method for bleaching eucalyptus board skin pulp by ozone in short sequence ) 是由 李军 朱忆魁 万兴 于 2021-09-17 设计创作，主要内容包括：本发明提供了一种臭氧短序漂白桉木板皮浆的方法,具体包括如下步骤：步骤一、将桉木板皮浆与硫酸进行混合；步骤二、在混合完成后将混合后的液体在一定温度下反应一段时间；步骤三、将步骤二得到的浆液通入臭氧一段时间；步骤四、将步骤三中得到的产物加入过氧化氢进行漂白,得到桉木板皮漂白浆。该方法节能环保、生产效率高。(The invention provides a method for bleaching eucalyptus board leather pulp by ozone in a short sequence, which specifically comprises the following steps: step one, mixing eucalyptus board leather pulp with sulfuric acid; step two, after the mixing is finished, reacting the mixed liquid at a certain temperature for a period of time; step three, introducing ozone into the slurry obtained in the step two for a period of time; and step four, adding hydrogen peroxide into the product obtained in the step three for bleaching to obtain the eucalyptus board bark bleached pulp. The method is energy-saving and environment-friendly, and has high production efficiency.)

1. A method for bleaching eucalyptus board bark pulp by ozone in a short sequence is characterized by comprising the following steps:

step one, mixing eucalyptus board leather pulp with sulfuric acid;

step two, after the mixing is finished, reacting the mixed liquid at a certain temperature for a period of time;

step three, introducing ozone into the slurry obtained in the step two for a period of time;

and step four, adding hydrogen peroxide into the product obtained in the step three for bleaching to obtain the eucalyptus board bark bleached pulp.

2. The method of claim 1, wherein the eucalyptus wood veneer pulp is subjected to a pretreatment before being mixed with the sulfuric acid, the pretreatment comprising the steps of:

step 1.1: soaking eucalyptus board bark pulp for defibering;

step 1.2: spin-drying the defibered eucalyptus board skin pulp, wherein the dryness is 35-40%.

3. The method of claim 1, wherein in step one, during the mixing, the moisture is adjusted to 10% and the sulfuric acid concentration is 2 mol/L.

4. The method as claimed in claim 1, wherein in the second step, the mixed liquid is put into a reaction kettle, the reaction kettle is put into a water bath kettle, and the temperature of the water bath is controlled to be 60 +/-0.5 ℃ for 30 min.

5. The method as claimed in claim 1, wherein the amount used in step three is 1% wt, the ozone concentration is 90mg/L, and the pH of the slurry is 2.

6. The method of claim 5, wherein during the step three, if the ozone concentration is outside the predetermined range, the introduction of ozone into the reaction vessel is stopped until the ozone concentration stabilizes within the predetermined range.

7. The method of claim 1, wherein before performing step four, the slurry in step three is subjected to the following steps:

step a: washing the serous fluid obtained in the third step to be neutral;

step b: drying the product obtained in the step a until the dryness is 35-40%;

step c: adjusting the water content of the product obtained in the step b to 10%;

step d: the product of step c was adjusted to pH 11 by the addition of sodium hydroxide.

8. The process of claim 1, wherein in step four, the hydrogen peroxide is used in an amount of 3% wt and the temperature is 25 ℃.

Technical Field

The invention relates to the technical field of papermaking technology and comprehensive utilization of wastes, in particular to a method for bleaching eucalyptus board bark pulp by ozone in a short sequence.

Background

The paper making industry is an important raw material industry closely related to national economy and social development, is related to various aspects of national economy, culture, production, national defense and the like, and occupies an important position in national economy [1 ]. The 2020 annual report of the Chinese paper industry shows that about 2500 paper and paperboard production enterprises exist in the whole country in 2020, and the total production of paper and paperboard in the whole country reaches 11260 ten thousand tons, which is increased by 4.06 percent compared with 2019. The consumption of paper and paperboard in China is as high as 11827 ten thousand tons, which is improved by 10.49 percent compared with 2019. With the continuous development of science and technology, the pulping and papermaking industry in China has been well developed in recent years, and the appearance of the whole papermaking industry is also changed greatly. However, with the continuous change of domestic and foreign environments, the trade policies of China, the United states and other countries in Europe and America are continuously changed, the environmental protection control strength of China is continuously increased, the import of solid wastes in China is limited, and the papermaking industry is facing a plurality of problems and challenges.

The traditional CEH three-stage bleaching wastewater has large discharge amount and contains a large amount of toxic and harmful substances such as AOX and the like, and the substances not only cause severe damage to the environment, but also cause unbalancing harm to human self papermaking. In recent years, with the coming of a series of national environmental protection policies, higher requirements are also made on the paper making industry, and the traditional chlorine-containing bleaching can not meet the requirements of new standards in both wastewater discharge and wastewater pollution load, so that the traditional CEH bleaching mode is abandoned for a long time, and the traditional bleaching modes are replaced by clean bleaching technologies such as element-free chlorine bleaching and total chlorine-free bleaching.

For this reason, the applicant has gradually developed a total chlorine-free bleaching, i.e., TCF, based on ECF bleaching, which is based on an oxygen bleaching agent and does not use any chlorine bleaching agent, in order to eliminate the influence of chlorine on the environment. Because no chlorine-containing substance is used in the bleaching process, the influence of harmful substances such as AOX on the environment is fundamentally solved, the generated bleaching wastewater can be recycled, and high-quality paper pulp can be manufactured by using chlorine-free bleaching agents.

Disclosure of Invention

The invention mainly aims to provide

In order to achieve the above purposes, the technical scheme adopted by the invention is as follows: a method for bleaching eucalyptus board bark pulp by ozone in a short sequence is characterized by comprising the following steps:

step one, mixing eucalyptus board leather pulp with sulfuric acid;

step two, after the mixing is finished, reacting the mixed liquid at a certain temperature for a period of time;

step three, introducing ozone into the slurry obtained in the step two for a period of time;

and step four, adding hydrogen peroxide into the product obtained in the step three for bleaching to obtain the eucalyptus board bark bleached pulp.

Preferably, the eucalyptus wood veneer pulp is subjected to a pretreatment before being mixed with the sulfuric acid, the pretreatment comprising the steps of:

step 1.1: soaking eucalyptus board bark pulp for defibering;

step 1.2: spin-drying the defibered eucalyptus board skin pulp, wherein the dryness is 35-40%.

Preferably, in step one, during the mixing, the moisture is adjusted to 10% and the sulfuric acid concentration is 2 mol/L.

Preferably, in the second step, the mixed liquid is put into a reaction kettle, the reaction kettle is put into a water bath kettle, the water bath temperature is controlled at 60 +/-0.5 ℃, and the time is 30 min.

Preferably, in step three, the dosage is 1% wt, the ozone concentration is 90mg/L, and the pH of the slurry is 2.

Preferably, during the step three, if the ozone concentration exceeds the predetermined range, the supply of ozone to the reaction vessel is stopped until the ozone concentration stabilizes within the predetermined range.

Preferably, before performing step four, the slurry in step three needs to be performed with the following steps:

step a: washing the serous fluid obtained in the third step to be neutral;

step b: drying the product obtained in the step a until the dryness is 35-40%;

step c: adjusting the water content of the product obtained in the step b to 10%;

step d: the product of step c was adjusted to pH 11 by the addition of sodium hydroxide.

Preferably, in step four, hydrogen peroxide is used in an amount of 3% wt at a temperature of 25 ℃.

1) The preparation method of the invention utilizes the eucalyptus board skin as the waste to prepare the pulp, adopts the short-time bleaching process, achieves the aim of totally chlorine-free bleaching, and reduces the pollution treatment cost; the adopted ozone meets the requirement of environmental protection, and the dosage of chemicals is further reduced;

2) according to the method, the eucalyptus board leather pulp is used as a raw material, the ozone and hydrogen peroxide combined short-sequence bleaching process is adopted for the first time, the pulp obtained by bleaching can meet the requirements of paper whiteness and performance in production, compared with the existing common bleaching mode, the number of bleaching stages in the short-sequence bleaching mode is small, the bleaching time is short, the production efficiency can be improved to a great extent, and the consumption of chemicals is low, so that the production cost can be reduced, and the economic benefit can be improved.

Drawings

FIG. 1 is a flow chart of a method according to the present invention;

FIG. 2a is a 1000 times magnified map of the surface morphology of bleached eucalyptus planks;

figure 2b is a 3000 times magnified map of the surface morphology of the fiber after bleaching of the eucalyptus plank skin.

Detailed Description

The following description is presented to disclose the invention so as to enable any person skilled in the art to practice the invention. The preferred embodiments in the following description are given by way of example only, and other obvious variations will occur to those skilled in the art.

Step 1: taking unbleached sulfate eucalyptus board bark pulp as a raw material, and soaking and defibering the raw material, wherein the concentration of the eucalyptus board bark pulp is 10%;

and step 3: spin-drying the defibered eucalyptus board pulp by using a flat centrifuge, wherein the dryness is 35-40%;

and 4, step 4: mixing the eucalyptus board bark pulp obtained in the step 3 with sulfuric acid, and adjusting the water content to 10% and the concentration of the sulfuric acid to be 2 mol/L;

and 5: putting the mixed eucalyptus board skin slurry into a water bath kettle, and reacting for 30 min;

step 6: transferring the eucalyptus board pulp obtained in the step 5 into a stirring reaction kettle, and introducing ozone, wherein the dosage of the ozone is 1% by weight, and the concentration of the ozone is 90 mg/L;

and 7: washing the eucalyptus board skin pulp obtained in the step 6 with water, and spin-drying the pulp until the dryness is 35-40%;

and 8: adjusting the water content of the eucalyptus board pulp obtained in the step 7 to 10%, and adding 2mol/L sodium hydroxide to adjust the pH value to 11;

and step 9: and (3) adding hydrogen peroxide into the alkaline eucalyptus board bark pulp obtained in the step (8), wherein the using amount of the hydrogen peroxide is 3 wt%, and reacting for 110min at 25 ℃ to obtain the bleached eucalyptus board bark pulp.

In step 5, the temperature of the water bath is controlled at 60 +/-0.5 ℃.

In step 6, the concentration of the eucalyptus board bark pulp in the reaction kettle is 10 +/-1%, the pH value is 2, and the temperature is room temperature. And the ozone concentration should be maintained at 90 plus or minus 1mg/L, if the ozone concentration exceeds the range, the ozone is stopped to be introduced into the reaction kettle, and the ozone is continuously introduced into the reaction kettle after the ozone concentration is stable, so as to continue the reaction.

The concentration of the eucalyptus board bark pulp in the step 8 is 10%.

The properties of the pulp before and after bleaching and the fibers were analyzed to obtain tables 1 and 2.

TABLE 1 properties of eucalyptus planks before and after bleaching

TABLE 2 fiber analysis before and after bleaching of eucalyptus board bark bleached pulp

As can be seen from Table 1, for the same freeness (40. + -.2) the number of pulping revolutions required for the bleached pulp is less, which may be thatBecause the fiber is broomed to a certain degree in the bleaching process, and becomes soft and easy to pulp. In addition, the physical properties of the paper made of the paper pulp after the ozone treatment are not seriously reduced compared with the raw material pulp, and the paper is finally subjected to H₂O₂The physical properties of the paper obtained after the supplementary bleaching are as follows: a tensile index of 59.45N m/g and a burst index of 3.71Kpa m²(iv)/g, tear index 5.34 mN. m²And/g, the physical property can meet the requirement of QB/T1678-2017 standard on bleached sulfate hardwood pulp qualified products.

Table 2 lists a summary of other data for the fibers. The average fiber length after the ozone treatment was reduced by 10 μm, H, relative to the raw material slurry₂O₂The average length of the fibers after bleaching is not greatly different from that after ozone treatment, and the average width of the fibers of the three kinds of pulp is not greatly different. This indicates that the ozone delignification stage has a certain destructive effect on the length of the pulp fibers and H₂O₂Bleaching damage is small but the overall effect on fiber width is not very large. In addition, the fibrillation degree and the fine fiber content of the pulp after the ozone delignification are increased compared with those of the raw pulp, because the ozone delignification plays a chemical beating role similar to beating on the fiber, and the fiber can be slightly fibrillated.

The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.