阅读说明：本技术 一种光热自修复碳纳米管增强环氧耐磨涂层及其制备方法 (Photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating and preparation method thereof ) 是由 宋浩杰 李松 李永 贾晓华 杨进 王思哲 于 2020-12-23 设计创作，主要内容包括：本发明公开一种光热自修复碳纳米管增强环氧耐磨涂层的制备方法,包括步骤：1)按质量份数为1～10份的CNTs、50～200份的Tris-HCl缓冲溶液、5～80份的多巴胺盐酸盐混合,经超声、搅拌、离心、冷冻干燥后得到PDA/CNTs粉末；2)取质量份数为1～10份的PDA/CNTs粉末、1～30份的氟聚合物、5～100份的乙醇和5～150份的乙酸乙酯超声处理后得到填料混合溶液；3)按质量比1∶1～12∶1取热固性树脂和固化剂添加到所述步骤2的填料混合溶液中,搅拌、匀浆后喷涂在预处理后的金属基材上,在50-180℃下固化1-20h后得到光热自修复碳纳米管增强环氧耐磨涂层；该涂层能够在光照条件下远距离触发热修复,具有快速、精确、可循环修复大尺度损伤的优点,该方法制备工艺简单,可实现大面积制备,所用原料环保安全无毒。(The invention discloses a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the following steps: 1) mixing 1-10 parts of CNTs, 50-200 parts of Tris-HCl buffer solution and 5-80 parts of dopamine hydrochloride according to the mass parts, and performing ultrasonic treatment, stirring, centrifugation and freeze drying to obtain PDA/CNTs powder; 2) performing ultrasonic treatment on 1-10 parts by mass of PDA/CNTs powder, 1-30 parts by mass of a fluoropolymer, 5-100 parts by mass of ethanol and 5-150 parts by mass of ethyl acetate to obtain a filler mixed solution; 3) adding thermosetting resin and a curing agent into the filler mixed solution obtained in the step (2) according to the mass ratio of 1: 1-12: 1, stirring, homogenizing, spraying on a pretreated metal base material, and curing at 50-180 ℃ for 1-20h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating; the coating can trigger thermal repair in a long distance under the illumination condition, has the advantages of rapidness, accuracy and capability of repairing large-scale damage in a circulating manner, and the preparation method is simple in preparation process, can realize large-area preparation, and is environment-friendly, safe and nontoxic in used raw materials.)

1. A preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating is characterized by comprising the following steps: the method comprises the following steps:

step 1: mixing 1-10 parts of CNTs, 50-200 parts of Tris-HCl buffer solution and 5-80 parts of dopamine hydrochloride according to the mass parts, and performing ultrasonic treatment, stirring, centrifugation and freeze drying to obtain PDA/CNTs powder;

step 2: mixing 1-10 parts by mass of PDA/CNTs powder, 1-30 parts by mass of fluoropolymer, 5-100 parts by mass of ethanol and 5-150 parts by mass of ethyl acetate, and performing ultrasonic treatment to obtain a filler mixed solution;

and step 3: the mass ratio of (1-12): and 1, adding thermosetting resin and a curing agent into the filler mixed solution obtained in the step 2, stirring, homogenizing, spraying on the pretreated metal base material, and curing at 50-180 ℃ for 1-20h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

2. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: and in the step 2, a cell ultrasonic crusher is adopted to carry out ultrasonic treatment for 5-30min at room temperature.

3. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: and in the step 1, a magnetic stirrer is adopted to stir at room temperature for 5-30 min.

4. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: in the step 1, centrifugation is carried out at a centrifugation rate of 5000-.

5. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: the freeze drying time in the step 1 is 12-36 h.

6. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: and in the step 3, stirring for 5-60min by using a magnetic stirrer.

7. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: and in the step 3, a homogenizer is adopted for homogenizing treatment for 5-60 min.

8. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 1, wherein the method comprises the following steps: the pretreatment of the metal base material in the step 3 comprises the following steps: sanding with sand paper, ultrasonically cleaning with mixed solution of ethanol and acetone, and drying.

9. The method for preparing the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating as claimed in claim 8, wherein the method comprises the following steps: the mesh number of the sand paper is 500-1200 meshes.

10. A photothermal self-healing carbon nanotube-reinforced epoxy abrasion-resistant coating prepared according to the method of any one of claims 1-9.

Technical Field

The invention belongs to the field of composite material preparation, relates to a carbon nano tube coating, and particularly relates to a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating and a preparation method thereof.

Background

With the development of science and technology, the coating is widely applied in the fields of aerospace, ocean protection, energy devices, building materials, electronic equipment and the like. The coating comprises a heat insulation coating on the outer layer of the spacecraft, an anticorrosive coating on the surface of a ship, a wind and sand impact resistant coating on a wind power generation blade, a self-cleaning coating of an outer wall of a building, an encapsulation coating of electronic equipment and the like.

When the coating coated on the surface of the substrate is used, the coating is usually damaged and cracked by the factors of environmental temperature, humidity, pH value or artificial external force, so that the service life of the coating is shortened. The damage of the coating can reduce the protective effect of the coating on the matrix and the adhesive force of the coating without timely repairing, so that the protective effect of the coating is invalid, and the damage of the matrix causes economic loss or personnel injury. At present, the damaged coating is repaired by a manual repairing or coating replacing mode, and the repairing process is complicated and the manufacturing cost is high.

With the continuous development of coating materials, people prepare self-repairing coatings based on the natural self-repairing phenomenon under the guidance of bionics. The self-repairing coatings are classified into exogenous self-repairing coatings and endogenous self-repairing coatings according to repairing mechanisms. The principle of the exogenous self-repairing coating is that a catalyst inclusion or a repairing agent is stored in a container and is filled in a matrix in advance, and when the matrix is damaged by environmental temperature, humidity, pH value or artificial external force in the using process, the catalyst inclusion is broken or the repairing agent is released from the loaded container, so that the self-repairing process is achieved. The principle of the endogenous self-repairing coating is that the self-repairing process is realized by the physicochemical properties of the matrix through self phase change, reversible dynamic bonds, hydrogen bonds, non-covalent chemical bonds and a chain entanglement mechanism.

However, both exogenous self-healing coatings and endogenous self-healing coatings require external energy input or stimulation triggering means to start the self-healing process. At present, the common triggering means is that a heat source is utilized to heat a substrate, and the substrate is heated to cause self-repairing, but the traditional heating mode can only cause self-repairing within a short distance range, and the coating structure outside the damaged area of the substrate can be damaged in the heating process, so that the waste and economic loss of the coating material are caused.

With the further development of coating materials, novel self-repairing coatings which generate heat by illumination are widely applied. The principle of the novel self-repairing coating generating heat by illumination is that a light source is used for triggering a substrate to be heated remotely, and the self-repairing process is initiated after the substrate is heated. The photo-thermal triggering self-repairing coating has no strict requirement on the coating substrate, can be repaired no matter whether the coating substrate is a covalent bond or a non-covalent bond, and has extremely important significance on the repair of the coating substrate in special environments such as underwater or vacuum and the like. The photo-thermal triggering self-repairing coating can also realize local high-precision self-repairing of the coating by adjusting the illumination position and the size of a light spot, and avoid thermal damage and side effects of a light source on the intact area of the coating; and by adjusting the wavelength and the intensity condition of the light source, the maximum utilization of the photo-thermal effect is realized, and meanwhile, the coating can be directly repaired by utilizing the solar light source.

Compositions science and technology, 2016, 133: 165-172 journal discloses a self-repairing polyurethane coating by photo-thermal effect, which is a coating that scientists Peng adds 0.04% of gold nanoparticles in the polyurethane coating, then the gold nanoparticles generate a large amount of heat under laser irradiation to melt resin and flow to a damaged part, and the resin is recrystallized after cooling to repair surface damage, thereby finally achieving the purpose of recovering the surface state and mechanical property.

The Chinese patent document CN 107057326A discloses a photoresponse shape self-repairing conforming material, polydopamine with excellent photothermal effect is compounded in a polymer material matrix with shape memory self-repairing performance, and the repair is realized by a light source illumination mode from visible light to near-infrared light wave band. The photoresponse shape self-repairing meets the condition that the material generates cracks or damages in the using process, and the self-repairing is realized in an illumination mode; if the damage of large deformation occurs, the damaged surfaces are mutually contacted for repairing through the shape memory function. The temperature required for repair and shape memory functions can be realized by introducing polydopamine and generating photothermal effect.

The ACS Nano 2019, 13, 8124-8134 journal states that scientist Fan hybridizes with waterborne elastic Polyurethane (PU) through ionic silver nanoparticles (AgNP) @ MXene nanosheets, and the coating has excellent photothermal conversion performance by means of combination of the plasma property of AgNP and the photothermal effect and the thermal conductivity of 2D MXene nanosheets, so that even if a low-power visible-infrared light source is used, the temperature can be remarkably increased to 108.4-113.6 ℃ after mixed light is irradiated for 5 minutes, and the mechanical damage of the composite coating can be rapidly repaired by the increase of the temperature.

In summary, noble metals with high thermal conductivity lead to increased costs and more complex preparation; while materials such as polyurethane and shape memory polymers are held together by relatively weak interactions to achieve high fluidity to promote the healing process, making self-healing coatings that tend to be soft, lacking mechanical strength and long-term durability. And most self-repairing coatings of polyurethane and shape memory polymers can only be limited to repairing small-size damages such as surface cracks of the coatings and the like, and cannot meet practical requirements.

Disclosure of Invention

The invention aims to provide a photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating and a preparation method thereof.

In order to achieve the purpose, the invention adopts the technical scheme that:

a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating comprises the following steps:

step 1: mixing 1-10 parts of CNTs, 50-200 parts of Tris-HCl buffer solution and 5-80 parts of dopamine hydrochloride according to the mass parts, and performing ultrasonic treatment, stirring, centrifugation and freeze drying to obtain PDA/CNTs powder;

step 2: mixing 1-10 parts by mass of PDA/CNTs powder, 1-30 parts by mass of fluoropolymer, 5-100 parts by mass of ethanol and 5-150 parts by mass of ethyl acetate, and performing ultrasonic treatment to obtain a filler mixed solution;

and step 3: the mass ratio of (1-12): and 1, adding thermosetting resin and a curing agent into the filler mixed solution obtained in the step 2, stirring, homogenizing, spraying on the pretreated metal base material, and curing at 50-180 ℃ for 1-20h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

Further, in the step 1, a cell ultrasonic crusher is adopted to carry out ultrasonic treatment for 5-30min at room temperature.

Further, in the step 1, a magnetic stirrer is adopted to stir at room temperature for 5-30 min.

Further, the centrifugation speed in the step 1 is 5000-10000r/min, and the centrifugation time is 5-30 min.

Further, the freeze-drying time in the step 1 is 12-36 h.

Further, stirring for 5-60min by using a magnetic stirrer in the step 3.

Further, a homogenizer is adopted for homogenizing treatment for 5-60min in the step 3.

Further, the pretreatment of the metal base material in the step 3 includes the steps of: sanding with sand paper, ultrasonically cleaning with mixed solution of ethanol and acetone, and drying.

Furthermore, the number of the sand paper meshes is 500-1200 meshes.

The photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating prepared by the preparation method.

Compared with the prior art, the invention has the beneficial effects that:

1) the wear-resistant photo-thermal self-repairing coating is prepared by adding the modified CNTs and the fluoropolymer into the thermosetting resin, the fluoropolymer is used as a solid lubricant and can play a role in lubricating in the friction process, the CNTs can enter a groove of a friction contact surface in the friction process and serve as a microscopic bearing, a physical isolation effect is played between friction pairs, sliding friction is converted into rolling friction, and the tribological performance of the coating is improved through the synergistic effect of the CNTs and the fluoropolymer. The damaged coating is irradiated at a certain intensity, and the CNTs heat conduction network is subjected to photo-thermal conversion rapidly, so that the low-melting-point fluoropolymer is subjected to phase change, the self-repairing effect is achieved, the high-quality self-repairing performance with good wear resistance is realized, and large-area and large-scale damage repair can be realized.

2) The preparation process is simple, the traditional heating self-repairing coating system can only cause self-repairing in a short distance range, and the heating process can also damage the coating structure outside the damaged area of the material, thereby causing energy waste and economic loss. The photo-thermal self-repairing coating obtained by the invention utilizes a light source to remotely trigger a self-repairing process, realizes local high-precision self-repairing of the coating by adjusting the illumination position and the size of a light spot, avoids thermal damage and side effect on the intact area of the coating, and improves the local repairing precision.

3) The raw materials used in the invention are environment-friendly, safe and nontoxic, are easy to realize industrialization, and have good application prospects.

Drawings

FIG. 1 is an optical image of a coating prepared according to the present invention;

FIG. 2 is a diagram of a coated optical mirror made in accordance with the present invention;

FIG. 3 is a scanning electron micrograph of a coating made according to the present invention;

FIG. 4 is a graph of the friction curve of a coating prepared according to the present invention under a load of 300g and a rotation speed of 300 rpm/min;

FIG. 5 is a photograph of the surface temperature of the coating before heating for testing the photothermal properties of the coating prepared in accordance with the present invention;

FIG. 6 is a photograph of the surface temperature of the coating after heating for 30min in the photothermal performance test of the coating prepared by the present invention;

FIG. 7 is a photograph of a coating prepared in accordance with the present invention at the onset of photothermal repair;

FIG. 8 is a photograph of a coating prepared in accordance with the present invention at the end of photothermal repair.

Detailed Description

The present invention will be described in further detail with reference to the following examples, which are not intended to limit the invention thereto.

Example 1

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 800-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under the power of 60w, and then drying in an oven at the temperature of 60 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 1 part of CNTs into 50 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 5min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 5 parts of dopamine hydrochloride, carrying out stirring treatment for 5min at room temperature by using a magnetic stirrer, centrifuging for 5min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 18h to obtain PDA/CNTs powder.

Step 2: 1 part of PDA/CNTs powder and 10 parts of fluoropolymer are added into a mixed solution of ethanol (10mL) and ethyl acetate (10mL), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 50w to obtain a filler mixed solution.

And step 3: adding 50 parts of epoxy resin and 50 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 5min at the speed of 200r/min by using a magnetic stirrer, then homogenizing for 5min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at 120 ℃ for 3h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in figure 1, the coating prepared by the preparation method has a flat and smooth surface, does not have defects such as air holes, needle holes, bulges and the like, has strong bonding force with a metal substrate, can resist the peeling of an adhesive tape, and shows that the coating has a good protection effect on the metal substrate.

Example 2

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 1000-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under the power of 60w, and then drying in an oven at 70 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 5 parts of CNTs into 100 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 10min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 10 parts of dopamine hydrochloride, carrying out stirring treatment for 15min at room temperature by using a magnetic stirrer, centrifuging for 10min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 20h to obtain PDA/CNTs powder.

Step 2: 3 parts of PDA/CNTs powder and 30 parts of fluoropolymer are added into a mixed solution of ethanol (10ml) and ethyl acetate (25ml), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 70w to obtain a filler mixed solution.

And step 3: adding 60 parts of epoxy resin and 40 parts of curing agent into the filler mixed solution in the step 2, stirring for 10min at the speed of 300r/min by using a magnetic stirrer, then homogenizing for 10min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating on the sprayed metal base material at the temperature of 150 ℃ for 1h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in FIG. 2, the microscopic morphology analysis of the coating prepared by the preparation method shows that the modified CNTs and the fluoropolymer are uniformly dispersed in the epoxy resin, which provides material guarantee for the wear resistance and photo-thermal self-repair of the coating.

Example 3

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 1000-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under 80w power, and then drying in an oven at 80 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 3 parts of CNTs into 120 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 15min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 15 parts of dopamine hydrochloride, carrying out stirring treatment for 25min at room temperature by using a magnetic stirrer, centrifuging for 15min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 18h to obtain PDA/CNTs powder.

Step 2: 5 parts of PDA/CNTs powder and 25 parts of fluoropolymer are added into a mixed solution of ethanol (10ml) and ethyl acetate (35ml), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 60w to obtain a filler mixed solution.

And step 3: adding 75 parts of epoxy resin and 25 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 25min at the speed of 800r/min by using a magnetic stirrer, then homogenizing for 25min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating on the sprayed metal base material at 160 ℃ for 1h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in FIG. 3, when the coating prepared by the preparation method is analyzed by a scanning electron microscope, the modified CNTs are uniformly dispersed in the epoxy resin to form a compact heat-conducting network, so that the material guarantee is provided for the wear resistance and the photo-thermal self-repair of the coating.

Example 4

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by 900-mesh abrasive paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under 70w power, and then drying in an oven at 75 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 5 parts of CNTs into 150 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 20min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 20 parts of dopamine hydrochloride, carrying out stirring treatment for 35min at room temperature by using a magnetic stirrer, centrifuging for 20min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 20h to obtain PDA/CNTs powder.

Step 2: 5 parts of PDA/CNTs powder and 15 parts of fluoropolymer are added into a mixed solution of ethanol (15ml) and ethyl acetate (20ml), and ultrasonic treatment is carried out for 0.5h at 80w of power to obtain a filler mixed solution.

And step 3: adding 70 parts of epoxy resin and 30 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 35min at the speed of 600r/min by using a magnetic stirrer, then homogenizing for 35min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at the temperature of 140 ℃ for 2h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in FIG. 4, the coating prepared by the above preparation method is tested for tribological performance, and the coating has good wear resistance as can be seen from the friction curve. The friction coefficient of the coating is still stable and always kept at about 0.07 after a friction test for 30min, which shows that the modified CNTs and the fluoropolymer play roles in reducing and resisting wear in the friction process.

Example 5

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 1000-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under 50w power, and then drying in an oven at 65 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 8 parts of CNTs into 100 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 25min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 15 parts of dopamine hydrochloride, carrying out stirring treatment for 45min at room temperature by using a magnetic stirrer, centrifuging for 25min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 21h to obtain PDA/CNTs powder.

Step 2: 6 parts of PDA/CNTs powder and 20 parts of fluoropolymer are added into a mixed solution of ethanol (20ml) and ethyl acetate (45ml), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 50w to obtain a filler mixed solution.

And step 3: adding 80 parts of epoxy resin and 20 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 45min at the speed of 500r/min by using a magnetic stirrer, then homogenizing for 45min at the speed of 7000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at 130 ℃ for 3h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in FIGS. 5 and 6, the photo-thermal performance test of the coating prepared by the preparation method shows that the surface temperature of the coating rises to 121.3 ℃ after the coating is irradiated for 30min under the condition that the simulated illumination intensity is 3 solar intensities, which shows that the prepared coating has good photo-thermal conversion performance and provides strong evidence for photo-thermal self-repair.

Example 6

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 1000-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under 50w power, and then drying in an oven at 80 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 10 parts of CNTs into 180 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 30min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 60 parts of dopamine hydrochloride, carrying out stirring treatment for 60min at room temperature by using a magnetic stirrer, centrifuging for 30min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 30h to obtain PDA/CNTs powder.

Step 2: 10 parts of PDA/CNTs powder and 30 parts of fluoropolymer were added to a mixture of ethanol (30ml) and ethyl acetate (40ml), and the mixture was sonicated at 50w power for 0.5h to obtain a filler mixture solution.

And step 3: adding 85 parts of epoxy resin and 15 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 60min at the speed of 500r/min by using a magnetic stirrer, then homogenizing for 60min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at the temperature of 150 ℃ for 2h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

As shown in fig. 7 and 8, when the coating prepared by the above preparation method is subjected to photo-thermal repair, it can be seen that under the condition that the simulated illumination intensity is 3 solar intensities, after illumination is carried out for 30 minutes, the wear scar on the surface of the coating disappears, and the surface recovers flat and smooth, which indicates that the prepared coating has a good photo-thermal self-repairing function.

Example 7

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by 500-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under the power of 60w, and then drying in an oven at the temperature of 60 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 1 part of CNTs into 200 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 5min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 80 parts of dopamine hydrochloride, carrying out stirring treatment for 5min at room temperature by using a magnetic stirrer, centrifuging for 5min at the centrifugal rate of 5000-10000r/min, and carrying out freeze drying for 12h to obtain PDA/CNTs powder.

Step 2: 1 part of PDA/CNTs powder and 10 parts of fluoropolymer are added into a mixed solution of 5 parts of ethanol (10mL) and ethyl acetate (150mL), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 50w to obtain a filler mixed solution.

And step 3: adding 50 parts of epoxy resin and 50 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 5min at the speed of 200r/min by using a magnetic stirrer, then homogenizing for 5min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at the temperature of 50 ℃ for 20h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

Example 8

The invention provides a preparation method of a photo-thermal self-repairing carbon nano tube reinforced epoxy wear-resistant coating, which comprises the steps of firstly pretreating a metal base material, namely polishing the metal base material to be smooth and clean by using 1200-mesh sand paper, then adding a mixed solution of ethanol and acetone, ultrasonically cleaning surface stains for 1h under the power of 60w, and then drying in an oven at the temperature of 60 ℃ for 1h for later use.

The preparation process comprises the following steps:

step 1: adding 1 part of CNTs into 200 parts of Tris-HCl buffer solution, carrying out ultrasonic treatment for 5min at room temperature by using a cell ultrasonic crusher to uniformly disperse the CNTs, then adding 80 parts of dopamine hydrochloride, carrying out stirring treatment for 5min at room temperature by using a magnetic stirrer, carrying out centrifugation for 5min at a centrifugation rate of 5000-10000r/min, and carrying out centrifugation for 5min and freeze drying for 36h to obtain PDA/CNTs powder.

Step 2: 1 part of PDA/CNTs powder and 1 part of fluoropolymer are added into a mixed solution of 5 parts of ethanol (10mL) and ethyl acetate (10mL), and the mixture is subjected to ultrasonic treatment for 0.5h at the power of 50w to obtain a filler mixed solution.

And step 3: adding 240 parts of epoxy resin and 20 parts of curing agent into the filler mixed solution obtained in the step 2, stirring for 5min at the speed of 200r/min by using a magnetic stirrer, then homogenizing for 5min at the speed of 8000r/min by using a homogenizer, spraying the mixture on the pretreated metal base material, and curing the coating sprayed on the metal base material at 180 ℃ for 20h to obtain the photo-thermal self-repairing carbon nanotube reinforced epoxy wear-resistant coating.

The present invention is described in detail with reference to the above embodiments, and those skilled in the art will understand that: modifications and equivalents may be made to the embodiments of the invention without departing from the spirit and scope of the invention, which is to be covered by the claims.