阅读说明：本技术 一种化纤织物柔软处理剂 (Chemical fiber fabric softening treatment agent ) 是由 杨坡 于 2019-11-08 设计创作，主要内容包括：本发明涉及纺织柔软剂,具体涉及一种化纤织物柔软处理剂,该化纤织物柔软处理剂,其组分按质量百分比由如下组分组成：改性有机硅乳液5％～10％、水性蜡乳液10％～30％、改性氨基硅油为2％～8％、季铵盐表面活性剂为1％～8％、有机酸为0.1％～0.5％、非离子乳化剂5％～15％、植物精油为0.1％～0.5％,余量为去离子水；制备方法如下：在可变速混合器中按上述配比先加入改性有机硅乳液、改性氨基硅油和季铵盐表面活性剂搅拌均匀,然后再按配比加入水性蜡乳液和非离子乳化剂搅拌,最后按配比缓慢加入有机酸和去离子水,搅拌均匀分装。(The invention relates to a textile softener, in particular to a chemical fiber fabric softening treatment agent, which comprises the following components in percentage by mass: 5-10% of modified organic silicon emulsion, 10-30% of water-based wax emulsion, 2-8% of modified amino silicone oil, 1-8% of quaternary ammonium salt surfactant, 0.1-0.5% of organic acid, 5-15% of nonionic emulsifier, 0.1-0.5% of plant essential oil and the balance of deionized water; the preparation method comprises the following steps: adding the modified organic silicon emulsion, the modified amino silicone oil and the quaternary ammonium surfactant into a variable-speed mixer according to the proportion, uniformly stirring, then adding the aqueous wax emulsion and the nonionic emulsifier according to the proportion, stirring, finally slowly adding the organic acid and the deionized water according to the proportion, uniformly stirring, and subpackaging.)

1. The chemical fiber fabric softening treatment agent comprises the following components in percentage by mass: 5-10% of modified organic silicon emulsion, 10-30% of water-based wax emulsion, 2-8% of modified amino silicone oil, 1-8% of quaternary ammonium salt surfactant, 0.1-0.5% of organic acid, 5-15% of nonionic emulsifier, 0.1-0.5% of plant essential oil and the balance of deionized water.

2. The chemical fiber fabric softening agent of claim 1, wherein the modified silicone emulsion comprises one or both of a silicon fluorine polymer and an amino hydrocarbon-based modified silicone oil.

3. The chemical fiber fabric softening treatment agent according to claim 1, wherein the modified silicone emulsion comprises a silicon fluorine polymer and amino alkyl modified silicone oil, and the mass ratio of the silicon fluorine polymer to the amino alkyl modified silicone oil is 1: 2-4.

4. The chemical fiber fabric softening agent according to claim 1, wherein the aqueous wax emulsion is an aqueous carnauba wax emulsion, an aqueous beeswax emulsion or an aqueous spermaceti wax emulsion.

5. The chemical fiber fabric softening treatment agent as claimed in claim 1, wherein the quaternary ammonium salt surfactant is di-hydrogenated tallow dimethyl ammonium chloride.

6. The chemical fiber fabric softening treatment agent according to claim 1, wherein the organic acid is one or more of acetic acid, citric acid, malic acid, glycolic acid and terephthalic acid.

7. The chemical fiber fabric softening treatment agent as claimed in claim 1, wherein the nonionic emulsifier is isomeric alcohol polyoxyethylene ether or fatty alcohol polyoxyethylene ether.

8. The chemical fiber fabric softening treatment agent according to claim 1, wherein the plant essential oil comprises one or more of blumea oil, brandy oil and patchouli oil.

9. The preparation method of the chemical fiber fabric softening agent in claim 1, which comprises the following steps: adding the modified organic silicon emulsion, the modified amino silicone oil and the quaternary ammonium surfactant into a variable-speed mixer according to the proportion, uniformly stirring, then adding the aqueous wax emulsion and the nonionic emulsifier according to the proportion, stirring, finally slowly adding the organic acid and the deionized water according to the proportion, uniformly stirring, and subpackaging.

Technical Field

The invention relates to a textile softening agent, in particular to a chemical fiber fabric softening treatment agent.

Background

Chemical fiber fabric refers to fabric produced from fibers obtained by chemical synthesis. Chemical fibers are used as artificial high molecular polymers, and the functionality of the chemical fibers can be designed in advance in the production process, for example, an antibacterial agent is added to enable the chemical fibers to have an antibacterial function; the addition of the mineral micro powder enables the fiber to have a low radiation function or a far infrared radiation function, and compared with the modification of natural fiber, the fiber is easier and more economical, and the effect is more obvious.

In addition to the new functions that can be conveniently imparted to chemical fibers in design and production, the characteristics and features of the high polymer that constitutes chemical fibers themselves also have functional factors. For example, the macromolecular structure of the acrylic fiber is very stable and has the capability of resisting ultraviolet radiation, and the acrylic fiber is dyed by cation, so that the acrylic fiber is bright in color and extremely high in light fastness, and therefore, the functionality and the practicability of the acrylic fiber fabric are fully exerted when people use the acrylic fiber fabric as a sun-shading product. Similarly, the abrasion resistance of nylon makes it widely used in sportswear, and the high strength of para-aramid makes it used in bullet-proof clothing.

In the aspect of garment materials, one of the important requirements for chemical fiber fabrics is 'simulation'. Therefore, the external style of natural fiber fabric also becomes the basic requirement of chemical fiber fabric, so the selection of softener is very important.

The fabric softener has been developed for more than half a century now, has a long history in the application of chemical fiber fabrics, and plays a great role in reducing the friction force and the thread breakage rate of the yarn surface of the chemical fiber fabrics.

The chemical fiber fabric softening agent is generally oily at present, is absorbed to yarns through an oil groove in the rewinding stage, and is in a variety from initial white oil to the current simethicone and the current popular silicon wax. However, when these chemical fabrics coated with the oil softening agent are used to sew white or light-colored clothes, silicon spots are easily formed, which affects the appearance and value of the clothes.

Disclosure of Invention

The invention aims to solve the technical problems and provide a chemical fiber fabric softening treatment agent which has good adsorption compatibility, has no influence on color and fastness and reduces the generation rate of silicon spots. In order to achieve the purpose, the technical scheme adopted by the invention is as follows:

the invention provides a chemical fiber fabric softening treatment agent which comprises the following components in percentage by mass: 5-10% of modified organic silicon emulsion, 10-30% of water-based wax emulsion, 2-8% of modified amino silicone oil, 1-8% of quaternary ammonium salt surfactant, 0.1-0.5% of organic acid, 5-15% of nonionic emulsifier, 0.1-0.5% of plant essential oil and the balance of deionized water.

Preferably, in the chemical fiber fabric softening agent provided by the invention, the modified silicone emulsion comprises one or two of a silicon fluorine polymer and amino hydrocarbon-based modified silicone oil.

Preferably, in the chemical fiber fabric softening treatment agent provided by the invention, the modified organic silicon emulsion comprises a silicon fluorine polymer and amino alkyl modified silicone oil, and the mass ratio of the silicon fluorine polymer to the amino alkyl modified silicone oil is 1: 2-4.

Preferably, in the chemical fiber fabric softening treatment agent provided by the invention, the aqueous wax emulsion is aqueous carnauba wax emulsion, aqueous beeswax emulsion or aqueous spermaceti wax emulsion.

Preferably, in the chemical fiber fabric softening treatment agent provided by the invention, the quaternary ammonium salt surfactant is di-hydrogenated tallow dimethyl ammonium chloride.

Preferably, in the chemical fiber fabric softening treatment agent provided by the invention, the organic acid is one or more of acetic acid, citric acid, malic acid, glycolic acid and terephthalic acid.

Preferably, in the chemical fiber fabric softening treatment agent provided by the invention, the nonionic emulsifier is isomeric alcohol polyoxyethylene ether or fatty alcohol polyoxyethylene ether.

Preferably, in the chemical fiber fabric softening agent provided by the invention, the plant essential oil comprises one or more of argyi leaf oil, brandy flower oil and patchouli oil.

Further, the invention also provides a preparation method of the chemical fiber fabric softening treatment agent, which comprises the following steps: adding the modified organic silicon emulsion, the modified amino silicone oil and the quaternary ammonium surfactant into a variable-speed mixer according to the proportion, uniformly stirring, then adding the aqueous wax emulsion and the nonionic emulsifier according to the proportion, stirring, finally slowly adding the organic acid and the deionized water according to the proportion, uniformly stirring, and subpackaging.

Compared with the prior art, the chemical fiber fabric softening treatment agent provided by the invention has the advantages that the modified organic silicon emulsion, the water-based wax emulsion and the modified amino silicone oil can effectively reduce the friction force on the surface of the yarn and endow the fabric with soft and smooth hand feeling; the quaternary ammonium salt surfactant component endows the fabric with good antistatic property; the plant essential oil can obviously improve the hand feeling of the yarn, remove the scratchiness of the fabric, improve the softness of the yarn, improve the air permeability and eliminate the wax feeling on the surface of the washed fabric.

In addition, the chemical fiber fabric softening treatment agent has the advantages of excellent water solubility, good quality stability, strong compatibility, easy emulsification, direct application to dye vat, low yellowing degree of fabric and no silicon spots.

Detailed Description

The present invention is described in detail below with reference to specific examples, which are intended to illustrate the present invention and not to limit the scope of the present invention.

Example 1

The chemical fiber fabric softening treatment agent provided by the invention comprises the following components in percentage by mass: 5% of silicon fluorine polymer, 10% of water-based carnauba wax emulsion, 2% of modified amino silicone oil, 1% of di-hydrogenated tallow dimethyl ammonium chloride, 0.1% of acetic acid, 5% of isomeric alcohol polyoxyethylene ether, 0.1% of argyi leaf oil and the balance of deionized water.

Adding the silicon-fluorine polymer, the modified amino silicone oil and the di-hydrogenated tallow dimethyl ammonium chloride into a variable-speed mixer according to the proportion, uniformly stirring, then adding the aqueous carnauba wax emulsion, the isomeric alcohol polyoxyethylene ether and the blumea oil according to the proportion, stirring, finally slowly adding the acetic acid and the deionized water according to the proportion, uniformly stirring and subpackaging.

Example 2

The invention relates to a chemical fiber fabric softening treatment agent, which comprises the following components in percentage by mass: 7% of amino-hydrocarbon-based modified silicone oil, 20% of aqueous beeswax emulsion, 5% of modified amino silicone oil, 58% of di-hydrogenated tallow dimethyl ammonium chloride, 0.3% of citric acid, 10% of fatty alcohol-polyoxyethylene ether, 0.3% of brandy flower oil and the balance of deionized water.

Adding amino-hydrocarbon modified silicone oil, modified amino-silicone oil and di-hydrogenated tallow dimethyl ammonium chloride into a variable-speed mixer according to the proportion, uniformly stirring, then adding aqueous beeswax emulsion, fatty alcohol-polyoxyethylene ether and brandy flower oil according to the proportion, stirring, finally slowly adding citric acid and deionized water according to the proportion, uniformly stirring, and subpackaging.

Example 3

The invention relates to a chemical fiber fabric softening treatment agent, which comprises the following components in percentage by mass: 4% of silicon fluorine polymer, 6% of amino-hydrocarbon modified silicone oil, 30% of aqueous carnauba wax emulsion, 8% of modified amino silicone oil, 8% of di-hydrogenated tallow dimethyl ammonium chloride, 0.5% of malic acid, 15% of fatty alcohol-polyoxyethylene ether, 0.5% of patchouli oil and the balance of deionized water.

Adding the silicon-fluorine polymer, the amino-hydrocarbon modified silicone oil, the modified amino silicone oil and the di-hydrogenated tallow dimethyl ammonium chloride into a variable-speed mixer according to the proportion, uniformly stirring, then adding the water-based carnauba wax emulsion, the fatty alcohol-polyoxyethylene ether and the agastache rugosus oil according to the proportion, stirring, finally slowly adding the malic acid and the deionized water according to the proportion, uniformly stirring and subpackaging.

The physical properties of the softening treatment agents for chemical fiber fabrics prepared according to the three examples are summarized in table 1:

TABLE 1 summary of physical Properties of chemical fiber Fabric softening treatment

Performance of	Test value
		Appearance of the product	Clear or slightly turbid viscous liquids
Viscosity (25 ℃ C.)	1000～5000C.S.T
		Specific gravity (25 ℃ C.)	0.990g/mL
Solid content	＜80％
		Ammonia value (in ammonia)	2000ppm

The chemical fiber fabric softening treatment agent prepared in the embodiments 1-3 has excellent quality stability, the treated fabric has soft, smooth and fluffy hand feeling, the yellowing effect is low, the hydrophilicity is excellent, certain low surface friction and antistatic force are provided, the thread breakage rate is low in the sewing process, and oil spots cannot occur.

While the preferred embodiments of the present invention have been described in detail, it will be understood by those skilled in the art that the invention is not limited thereto, and that various changes and modifications may be made without departing from the spirit of the invention, and the scope of the appended claims is to be accorded the full scope of the invention.