阅读说明：本技术 用于生产含氧化合物的转移加氢甲酰化 (Transfer hydroformylation for producing oxygenates ) 是由 A·卡彭特 A·维尔萨姆 L·玛藤斯 于 2019-08-20 设计创作，主要内容包括：本公开内容提供由烯烃形成含氧化合物的方法,其包括醛作为合成气的甲酰基来源替代的加氢甲酰化。在至少一种实施方案中,加氢甲酰化方法在低温下和在环境压力下或接近环境压力进行用于将烯烃转化为醛,从而降低副产物的形成,例如通过原料的骨架异构化或双键；或通过形成的醛和醇的进一步转化。在至少一种实施方案中,使用气态烯属产物(例如乙烯)代替张紧的烯烃(例如降冰片烯)改进控制转移加氢甲酰化反应中的平衡。(The present disclosure provides a process for forming oxygenates from olefins comprising hydroformylation with aldehyde as a formyl source replacement for syngas. In at least one embodiment, the hydroformylation process is conducted at low temperatures and at or near ambient pressure for the conversion of olefins to aldehydes, thereby reducing the formation of by-products, such as by skeletal isomerization or double bonds of the feedstock; or by further conversion of the aldehyde and alcohol formed. In at least one embodiment, the use of a gaseous olefinic product (e.g., ethylene) in place of a strained olefin (e.g., norbornene) improves the equilibrium in a controlled transfer hydroformylation reaction.)