阅读说明：本技术 水性环氧涂料及制备方法 (Water-based epoxy coating and preparation method thereof ) 是由 王其军 王向阳 于 2020-12-10 设计创作，主要内容包括：本发明涉及涂料技术领域,公开了水性环氧涂料,该环氧涂料包括A相组合物和B相组合物,其中：A相组合物按重量份组分为：水性环氧树脂30-40份、聚酰胺树脂15-25份、填料5-12份、消泡剂1-3份、流平剂0.5-1份、离子发生剂3-5份、异氰酸脂1-4份、抗磨剂3-8份、增韧剂2-6份；B相组合物按重量组分为：水性环氧固化剂10-20份、去离子水20-30份和活性稀释剂5-15份。该涂料在应用过程中,产生负氧离子,对环境进行改善,对人体有益,而且抗磨剂的调配,可以增强涂料的抗拉伸强度以及涂膜硬度,提高涂料的耐磨性,同时增韧剂和异氰酸酯的加入,可以改善涂料粘接能力,也能降低潮气渗透性,增加涂料的抗水性能,同时对环境的危害性低。(The invention relates to the technical field of coatings, and discloses a water-based epoxy coating, which comprises a phase A composition and a phase B composition, wherein: the A phase composition comprises the following components in parts by weight: 30-40 parts of water-based epoxy resin, 15-25 parts of polyamide resin, 5-12 parts of filler, 1-3 parts of defoaming agent, 0.5-1 part of flatting agent, 3-5 parts of ion generating agent, 1-4 parts of isocyanate, 3-8 parts of antiwear agent and 2-6 parts of toughening agent; the B phase composition comprises the following components in parts by weight: 10-20 parts of waterborne epoxy curing agent, 20-30 parts of deionized water and 5-15 parts of reactive diluent. In the application process, the coating generates negative oxygen ions, improves the environment and is beneficial to a human body, the anti-wear agent is prepared, the tensile strength and the film hardness of the coating can be enhanced, the wear resistance of the coating is improved, meanwhile, the toughening agent and the isocyanate are added, the bonding capability of the coating can be improved, the moisture permeability can be reduced, the water resistance of the coating is improved, and the harm to the environment is low.)

1. An aqueous epoxy coating, characterized in that the epoxy coating comprises a phase a composition and a phase B composition, wherein:

the A phase composition comprises the following components in parts by weight: 30-40 parts of water-based epoxy resin, 15-25 parts of polyamide resin, 5-12 parts of filler, 1-3 parts of defoaming agent, 0.5-1 part of flatting agent, 3-5 parts of ion generating agent, 1-4 parts of isocyanate, 3-8 parts of antiwear agent and 2-6 parts of toughening agent;

the B phase composition comprises the following components in parts by weight: 10-20 parts of waterborne epoxy curing agent, 20-30 parts of deionized water and 5-15 parts of reactive diluent.

2. The water-based epoxy coating as claimed in claim 1, wherein the ion generator comprises the following components in parts by weight: 10-15 parts of shell powder, 15-20 parts of anion powder, 5-10 parts of nano zinc oxide, 3-8 parts of nano silicon powder and the balance of water.

3. The water-based epoxy coating according to claim 2, wherein the ion generator is prepared by:

a1, drying shell powder, anion powder and nano silicon powder, sieving with a 300-mesh sieve, adding into a mixing tank, and stirring uniformly to obtain mixed powder;

a2, putting the mixed powder and nano zinc oxide into a stirring tank, adding a certain amount of water, and uniformly stirring for 25-40min at the temperature of 30-50 ℃, wherein the stirring speed is as follows: 1500 and 2000r/min, and the ion generating agent can be prepared after uniform mixing.

4. The water-based epoxy coating of claim 1, wherein the antiwear agent comprises the following components in parts by weight: 1-5 parts of silica sol solution, 3-8 parts of silicate, 5-15 parts of silicon dioxide, 4-10 parts of aluminum silicate P8202-5 parts of aluminum oxide and the balance of deionized water.

5. The water-based epoxy coating of claim 4, wherein the antiwear agent is prepared by the following steps:

b1, grinding the silicate into powder, sieving the powder by a 300-mesh sieve, then sequentially putting the powder, silicon dioxide, aluminum silicate P820 and aluminum oxide into a reaction tank, sealing the reaction tank at the constant temperature of 30-50 ℃ and carrying out mixing reaction to obtain mixed powder;

and B2, mixing the obtained mixed powder and the silica sol solution in a stirring tank, adding a certain amount of deionized water, and uniformly stirring at the temperature of 20-35 ℃ for 10-25min to obtain the antiwear agent.

6. The waterborne epoxy coating of claim 1, wherein the filler comprises, in parts by weight: 3-8 parts of glass fiber, 1-5 parts of quartz powder, 2-6 parts of magnetic powder, 1-3 parts of graphite powder, 3-5 parts of talcum powder, 2-4 parts of iron powder and 0.5-1.5 parts of modified zinc phosphate;

the preparation method of the filler comprises the following steps: adding glass fiber, quartz powder, magnetic powder, graphite powder, talcum powder, iron powder and modified zinc phosphate into a mixing tank in sequence, uniformly mixing for 30-50min at the temperature of 20-40 ℃ and the rotating speed of 1500-2000r/min, and obtaining the filler after uniform mixing.

7. The waterborne epoxy coating of claim 1, wherein the flexibilizing agent is dibutyl phthalate or dioctyl phthalate.

8. The waterborne epoxy coating and the preparation method thereof according to claim 1, wherein the reactive diluent is one or more of diglycidyl ether, polyglycidyl ether, propylene oxide butyl ether, propylene oxide phenyl ether, propylene oxide ethyl ether and propylene oxide tri-propyl ether.

9. The waterborne epoxy coating of claim 1, wherein the defoamer is a silicone defoamer and the leveling agent is a fluorocarbon leveling agent.

10. The water-based epoxy paint and the preparation method thereof according to any one of claims 1 to 9, characterized in that the preparation method of the water-based epoxy paint comprises the following steps:

s1, adding the water-based epoxy resin and the polyamide resin into a reaction tank, reacting at the temperature of 60-80 ℃, adding a certain amount of isocyanate and a toughening agent, and uniformly mixing and reacting for 15-20min to obtain a mixed solution A;

s2, fully mixing the ion generating agent and the antiwear agent with the mixed solution A, cooling to 40-50 ℃, adding a certain amount of defoaming agent and leveling agent, and fully reacting for 20-30min to obtain the phase A composition;

s3, adding the waterborne epoxy curing agent and the reactive diluent into a stirring tank, adding a certain amount of deionized water, and fully mixing for 10-20min to obtain a B-phase composition;

and S4, mixing the phase A composition and the phase B composition according to the weight part ratio of 5:1-10:1, and uniformly mixing to obtain the water-based epoxy coating.

Technical Field

The invention relates to the technical field of coatings, in particular to a water-based epoxy coating and a preparation method thereof.

Background

The water-based epoxy coating is a coating taking water as a solvent or a dispersion medium, and comprises a water-soluble epoxy coating and a water emulsion coating, wherein the water-soluble coating is often also called an electrophoretic coating, namely, resin is dissolved in water to form a uniform colloidal solution, and if the resin ions have electric charges, colloidal particles can be subjected to discharge deposition on the surface of a workpiece through electrophoresis under the action of direct current.

However, the permeability and the wear resistance of the existing water tank epoxy coating are not perfect enough in the using process, the service life of the coating is easily influenced, bubbles are easily generated in the coating in the long-time using process, the quality of the coating is influenced, and although the existing coating is gradually improved to the environment-friendly green environment, certain harm can be caused to the environment in the using process. Accordingly, one skilled in the art provides a waterborne epoxy coating and a preparation method thereof to solve the problems set forth in the background art.

Disclosure of Invention

The invention aims to provide a water-based epoxy coating and a preparation method thereof, so as to solve the problems in the background technology.

In order to achieve the purpose, the invention provides the following technical scheme: an aqueous epoxy coating comprising a phase a composition and a phase B composition, wherein:

the A phase composition comprises the following components in parts by weight: 30-40 parts of water-based epoxy resin, 15-25 parts of polyamide resin, 5-12 parts of filler, 1-3 parts of defoaming agent, 0.5-1 part of flatting agent, 3-5 parts of ion generating agent, 1-4 parts of isocyanate, 3-8 parts of antiwear agent and 2-6 parts of toughening agent;

the B phase composition comprises the following components in parts by weight: 10-20 parts of waterborne epoxy curing agent, 20-30 parts of deionized water and 5-15 parts of reactive diluent.

As a further scheme of the invention: the ion generating agent comprises the following components in parts by weight: 10-15 parts of shell powder, 15-20 parts of anion powder, 5-10 parts of nano zinc oxide, 3-8 parts of nano silicon powder and the balance of water.

As a still further scheme of the invention: the preparation method of the ion generating agent comprises the following steps:

a1, drying shell powder, anion powder and nano silicon powder, sieving with a 300-mesh sieve, adding into a mixing tank, and stirring uniformly to obtain mixed powder;

a2, putting the mixed powder and nano zinc oxide into a stirring tank, adding a certain amount of water, and uniformly stirring for 25-40min at the temperature of 30-50 ℃, wherein the stirring speed is as follows: 1500 and 2000r/min, and the ion generating agent can be prepared after uniform mixing.

As a still further scheme of the invention: the antiwear agent comprises the following components in parts by weight: 1-5 parts of silica sol solution, 3-8 parts of silicate, 5-15 parts of silicon dioxide, 4-10 parts of aluminum silicate P8202-5 parts of aluminum oxide and the balance of deionized water.

As a still further scheme of the invention: the preparation method of the antiwear agent comprises the following steps:

b1, grinding the silicate into powder, sieving the powder by a 300-mesh sieve, then sequentially putting the powder, silicon dioxide, aluminum silicate P820 and aluminum oxide into a reaction tank, sealing the reaction tank at the constant temperature of 30-50 ℃ and carrying out mixing reaction to obtain mixed powder;

and B2, mixing the obtained mixed powder and the silica sol solution in a stirring tank, adding a certain amount of deionized water, and uniformly stirring at the temperature of 20-35 ℃ for 10-25min to obtain the antiwear agent.

As a still further scheme of the invention: the filler comprises the following components in parts by weight: 3-8 parts of glass fiber, 1-5 parts of quartz powder, 2-6 parts of magnetic powder, 1-3 parts of graphite powder, 3-5 parts of talcum powder, 2-4 parts of iron powder and 0.5-1.5 parts of modified zinc phosphate;

the preparation method of the filler comprises the following steps: adding glass fiber, quartz powder, magnetic powder, graphite powder, talcum powder, iron powder and modified zinc phosphate into a mixing tank in sequence, uniformly mixing for 30-50min at the temperature of 20-40 ℃ and the rotating speed of 1500-2000r/min, and obtaining the filler after uniform mixing.

As a still further scheme of the invention: the toughening agent is dibutyl phthalate or dioctyl phthalate.

As a still further scheme of the invention: the reactive diluent is one or more of diglycidyl ether, polyglycidyl ether, propylene oxide butyl ether, propylene oxide phenyl ether, propylene oxide ethyl ether and propylene oxide propyl ether.

As a still further scheme of the invention: the defoaming agent is a polysiloxane defoaming agent, and the flatting agent is a fluorocarbon flatting agent.

As a still further scheme of the invention: the preparation method of the water-based epoxy coating comprises the following steps:

s1, adding the water-based epoxy resin and the polyamide resin into a reaction tank, reacting at the temperature of 60-80 ℃, adding a certain amount of isocyanate and a toughening agent, and uniformly mixing and reacting for 15-20min to obtain a mixed solution A;

s2, fully mixing the ion generating agent and the antiwear agent with the mixed solution A, cooling to 40-50 ℃, adding a certain amount of defoaming agent and leveling agent, and fully reacting for 20-30min to obtain the phase A composition;

s3, adding the waterborne epoxy curing agent and the reactive diluent into a stirring tank, adding a certain amount of deionized water, and fully mixing for 10-20min to obtain a B-phase composition;

and S4, mixing the phase A composition and the phase B composition according to the weight part ratio of 5:1-10:1, and uniformly mixing to obtain the water-based epoxy coating.

Compared with the prior art, the invention has the beneficial effects that: the invention relates to a water-based epoxy coating and a preparation method thereof, wherein in the practical operation, the A-phase composition and the B-phase composition are prepared according to a certain proportion to prepare the water-based epoxy coating, and the added ion generating agent can generate negative oxygen ions in the application process of the coating to improve the environment, thereby improving the environmental quality and being beneficial to human bodies.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The invention relates to a water-based epoxy coating and a preparation method thereof, wherein the preparation method of the water-based epoxy coating comprises the following steps:

s1, adding the water-based epoxy resin and the polyamide resin into a reaction tank, reacting at the temperature of 60-80 ℃, adding a certain amount of isocyanate and a toughening agent, and uniformly mixing and reacting for 15-20min to obtain a mixed solution A;

s2, fully mixing the ion generating agent and the antiwear agent with the mixed solution A, cooling to 40-50 ℃, adding a certain amount of defoaming agent and leveling agent, and fully reacting for 20-30min to obtain the phase A composition;

s3, adding the waterborne epoxy curing agent and the reactive diluent into a stirring tank, adding a certain amount of deionized water, and fully mixing for 10-20min to obtain a B-phase composition;

s4, mixing the composition of the phase A and the composition of the phase B according to the weight ratio of 5:1-10:1, and uniformly mixing to obtain the water-based epoxy coating;

wherein the reactive diluent is one or more of diglycidyl ether, polyglycidyl ether, propylene oxide butyl ether, propylene oxide phenyl ether, propylene oxide ethyl ether and propylene oxide propyl ether;

the toughening agent is dibutyl phthalate or dioctyl phthalate, the defoaming agent is polysiloxane defoaming agent, and the flatting agent is fluorocarbon flatting agent;

further, the preparation method of the ion generating agent comprises the following steps:

a1, drying shell powder, anion powder and nano silicon powder, sieving with a 300-mesh sieve, adding into a mixing tank, and stirring uniformly to obtain mixed powder;

a2, putting the mixed powder and nano zinc oxide into a stirring tank, adding a certain amount of water, and uniformly stirring for 25-40min at the temperature of 30-50 ℃, wherein the stirring speed is as follows: 1500-;

still further, the preparation method of the antiwear agent comprises the following steps:

b1, grinding the silicate into powder, sieving the powder by a 300-mesh sieve, then sequentially putting the powder, silicon dioxide, aluminum silicate P820 and aluminum oxide into a reaction tank, sealing the reaction tank at the constant temperature of 30-50 ℃ and carrying out mixing reaction to obtain mixed powder;

b2, mixing the obtained mixed powder and the silica sol solution in a stirring tank, adding a certain amount of deionized water, and uniformly stirring at the temperature of 20-35 ℃ for 10-25min to obtain the antiwear agent;

still further, the preparation method of the filler comprises the following steps: adding glass fiber, quartz powder, magnetic powder, graphite powder, talcum powder, iron powder and modified zinc phosphate into a mixing tank in sequence, uniformly mixing for 30-50min at the temperature of 20-40 ℃ and the rotating speed of 1500-2000r/min, and obtaining the filler after uniform mixing.

Example 1

An aqueous epoxy coating comprising a phase a composition and a phase B composition, wherein:

the A phase composition comprises the following components in parts by weight: 30 parts of water-based epoxy resin, 15 parts of polyamide resin, 5 parts of filler, 1 part of defoaming agent, 0.5 part of flatting agent, 3 parts of ion generating agent, 1 part of isocyanate, 3 parts of antiwear agent and 2 parts of toughening agent;

the B phase composition comprises the following components in parts by weight: 10 parts of waterborne epoxy curing agent, 20 parts of deionized water and 5 parts of reactive diluent;

the ion generating agent comprises the following components in parts by weight: 10 parts of shell powder, 15 parts of anion powder, 5 parts of nano zinc oxide, 3 parts of nano silicon powder and the balance of water;

the antiwear agent comprises the following components in parts by weight: 1 part of silica sol solution, 3 parts of silicate, 5 parts of silicon dioxide, 8202 parts of aluminum silicate P, 4 parts of aluminum oxide and the balance of deionized water;

the filler comprises the following components in parts by weight: 3 parts of glass fiber, 1 part of quartz powder, 2 parts of magnetic powder, 1 part of graphite powder, 3 parts of talcum powder, 2 parts of iron powder and 0.5 part of modified zinc phosphate;

the aqueous epoxy coating of the embodiment is prepared by mixing the composition of the phase A and the composition of the phase B according to the weight part ratio of 5: 1.

Example 2

An aqueous epoxy coating comprising a phase a composition and a phase B composition, wherein:

the A phase composition comprises the following components in parts by weight: 40 parts of water-based epoxy resin, 25 parts of polyamide resin, 12 parts of filler, 3 parts of defoaming agent, 1 part of flatting agent, 5 parts of ion generator, 4 parts of isocyanate, 8 parts of antiwear agent and 6 parts of toughening agent;

the B phase composition comprises the following components in parts by weight: 20 parts of waterborne epoxy curing agent, 30 parts of deionized water and 15 parts of reactive diluent;

the ion generating agent comprises the following components in parts by weight: 15 parts of shell powder, 20 parts of anion powder, 10 parts of nano zinc oxide, 8 parts of nano silicon powder and the balance of water;

the antiwear agent comprises the following components in parts by weight: 5 parts of silica sol solution, 8 parts of silicate, 15 parts of silicon dioxide, 8205 parts of aluminum silicate P, 10 parts of aluminum oxide and the balance of deionized water;

the filler comprises the following components in parts by weight: 8 parts of glass fiber, 5 parts of quartz powder, 6 parts of magnetic powder, 3 parts of graphite powder, 5 parts of talcum powder, 4 parts of iron powder and 1.5 parts of modified zinc phosphate;

the aqueous epoxy coating of the embodiment is prepared by mixing the composition of the phase A and the composition of the phase B according to the weight part ratio of 10: 1.

Example 3

An aqueous epoxy coating comprising a phase a composition and a phase B composition, wherein:

the A phase composition comprises the following components in parts by weight: 35 parts of water-based epoxy resin, 20 parts of polyamide resin, 10 parts of filler, 2 parts of defoaming agent, 0.8 part of flatting agent, 4 parts of ion generator, 3 parts of isocyanate, 5 parts of antiwear agent and 4 parts of toughening agent;

the B phase composition comprises the following components in parts by weight: 15 parts of waterborne epoxy curing agent, 25 parts of deionized water and 8 parts of reactive diluent;

the ion generating agent comprises the following components in parts by weight: 12 parts of shell powder, 18 parts of anion powder, 7 parts of nano zinc oxide, 5 parts of nano silicon powder and the balance of water;

the antiwear agent comprises the following components in parts by weight: 3 parts of silica sol solution, 6 parts of silicate, 10 parts of silicon dioxide, 8204 parts of aluminum silicate P, 8 parts of aluminum oxide and the balance of deionized water;

the filler comprises the following components in parts by weight: 6 parts of glass fiber, 3 parts of quartz powder, 4 parts of magnetic powder, 2 parts of graphite powder, 4 parts of talcum powder, 3 parts of iron powder and 1 part of modified zinc phosphate;

the aqueous epoxy coating of the embodiment is prepared by mixing the composition of the phase A and the composition of the phase B according to the weight part ratio of 7: 1.

Comparative example 1

Adopts the water-based epoxy coating in the existing market and the preparation method thereof.

Experiment one

The coatings prepared in examples 1 to 3 and comparative example 1 were subjected to performance tests, specifically, water resistance GB 5209 and acid and alkali resistance GB 9274, and the test results were as follows:

the coating prepared by the invention has excellent water resistance, acid resistance and alkali resistance, and compared with the traditional coating, the coating has more excellent performance and longer service life;

experiment two

Secondly, the coatings prepared in examples 1 to 3 and comparative example 1 are tested for hardness, wear resistance and negative ion release amount, and the test results are as follows:

the test mode is as follows: taking one part of each of the coatings prepared in examples 1-3 and comparative example 1, taking four sealing chambers of 100 square meters at room temperature of 25 ℃, respectively coating four parts of the coatings in the four sealing chambers, and detecting the quantity of negative ions released in the four sealing chambers within 12 hours and 24 hours;

as can be seen from the table above, compared with the existing coating, the coating provided by the invention has the advantages of high wear resistance, good hardness, and good release amount of negative ions in the using process, so that the green environmental protection property of the coating is improved, and the coating also brings benefits to human bodies.

It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.

Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.