Easy-to-clean anti-counterfeit label

文档序号:87965 发布日期:2021-10-08 浏览:48次 中文

阅读说明:本技术 一种易清理的防伪标签 (Easy-to-clean anti-counterfeit label ) 是由 李长顺 单浩然 彭胜 王心愉 阮飞 吴航 于 2021-05-26 设计创作,主要内容包括:本发明公开了一种易清理的防伪标签,包括从下至上依次设置的离型层、压敏胶层、防伪文字层、热收缩膜层和温变油墨层,所述温变油墨层包括由从下至上依次设置的油墨印刷层、光变油墨层和耐磨光油层组成,所述防伪文字层包括由从下至上依次设置的文字印刷层、介质膜层和硅油层组成。本防伪标签具有多种防伪手段,且易于清理。(The invention discloses an easy-to-clean anti-counterfeit label, which comprises a release layer, a pressure-sensitive adhesive layer, an anti-counterfeit character layer, a heat shrinkable film layer and a temperature-change ink layer which are sequentially arranged from bottom to top, wherein the temperature-change ink layer comprises an ink printing layer, a light-change ink layer and a polishing-resistant oil layer which are sequentially arranged from bottom to top, and the anti-counterfeit character layer comprises a character printing layer, a medium film layer and a silicon oil layer which are sequentially arranged from bottom to top. The anti-counterfeiting label has multiple anti-counterfeiting means and is easy to clean.)

1. The utility model provides an easy-to-clean's antifalsification label, its characterized in that includes from supreme release layer (50), pressure sensitive adhesive layer (40), anti-fake characters layer (30), thermal contraction membrane layer (20) and the temperature change printing ink layer (10) that set gradually down, temperature change printing ink layer (10) include by from supreme printing ink layer (13), the light that sets gradually becomes printing ink layer (12) and wear-resisting gloss oil layer (11) of following constitute, anti-fake characters layer (30) include by follow supreme characters printing layer (33), medium rete (32) and the silicon oil layer (31) that set gradually down and constitute.

2. An easy-to-clean security label according to claim 1, wherein the thickness of the burnish-resistant oil layer (11) is 0.5-10 μm, the transmittance of the burnish-resistant oil layer (11) is 50-100%, the level of the burnish-resistant oil layer (11) is CS-10, 500g, 50-300cycles, the burnish-resistant oil layer (11) comprises 10-70 parts of acrylate diluent, 20-50 parts of acrylate oligomer and 1-10 parts of photoinitiator, the functionality of the acrylate diluent is 2-4, the acrylate diluent comprises one or more of TMPTA, TPGDA and DPGDAPETA, preferably TPGDA, the acrylate oligomer comprises one or more of EA, FA, PUA, PEA and AA, preferably EA, and the photoinitiator comprises 184, 907, One or more of TPO, 1173 and ITX, preferably 184.

3. The easy-to-clean anti-counterfeiting label according to claim 1, wherein the thickness of the optically variable ink layer (12) is 1-15 μm, the temperature-change temperature range of the optically variable ink layer (12) is 30-120 ℃, the base color of the optically variable ink layer (12) is colorless, the color after temperature change is red, the color after temperature change is irreversible, the optically variable ink layer (12) comprises 10-70 parts of acrylate diluent, 20-50 parts of acrylate oligomer, 1-10 parts of photoinitiator and 1-10 parts of temperature-change ink, the functionality of the acrylate diluent is 2-4, the acrylate diluent comprises one or more of TMPTA, TPGDA and DPGDAPETA, preferably TPGDA, and the acrylate oligomer comprises EA, FA, PUA, One or more of PEA and AA, preferably EA, and photoinitiator comprising one or more of 184, 907, TPO, 1173, and ITX, preferably 184, and temperature sensitive ink comprising one or more of methyl violet based ink, phenolic compound based ink, acid clay based ink, azo pigment based ink, aryl methane based ink, and capsule based ink.

4. An easy-to-clean anti-counterfeit label according to claim 1, characterized in that the thickness of the ink printed layer (13) is 1-15 μm, and the ink printed layer (13) is printed with patterns or characters.

5. An easy-to-clean security label as claimed in claim 1, wherein the thickness of the heat-shrinkable film layer (20) is 25-125 μm, the color of the heat-shrinkable film layer (20) is preferably white, the shrinkage of the heat-shrinkable film layer (20) is: in the MD direction: 0-10% and TD direction: 0 to 80%, shrinkage temperature interval of the heat shrinkable film layer (20): the material of the heat shrinkable film layer (20) is one of PET, PVC, PE and POF at 40-120 ℃, and the PET type heat shrinkable film is preferred.

6. An easy-to-clean anti-counterfeit label according to claim 1, characterized in that the thickness of the silicone oil layer (31) is 1-10 μm, and the release force of the silicone oil layer (31) is 50-200 g.

7. An easy-to-clean anti-counterfeit label according to claim 1, wherein the thickness of the dielectric film layer (32) is 1-15 μm, and the abrasion resistance level of the dielectric film layer (32) is: CS-10, 500g and 50-300cycles, the medium film layer (32) comprises 10-70 parts of acrylate diluent, 20-50 parts of acrylate oligomer and 1-10 parts of photoinitiator, the acrylate diluent has the functionality of 2-4, the acrylate diluent comprises one or more of TMPTA, TPGDA and DPGDAPETA, preferably TPGDA, the acrylate oligomer comprises one or more of EA, FA, PUA, PEA and AA, preferably EA, and the photoinitiator comprises one or more of 184, 907, TPO, 1173 and ITX, preferably 184.

8. The easy-to-clean anti-counterfeit label according to claim 1, wherein the thickness of the text printing layer (33) is 1-10 μm, and the printed content of the text printing layer (33) is text or pattern.

9. An easy-to-clean security label according to claim 1, wherein the thickness of the pressure sensitive adhesive layer (40) is 20-200 μm, the 180 ° peel force of the pressure sensitive adhesive layer (40) is 10-30N/25mm, the tensile strength of the pressure sensitive adhesive layer (40) is 5-12MPa, the elongation at break of the pressure sensitive adhesive layer (40) is 500-1500%, the pressure sensitive adhesive layer (40) comprises 10-50 parts of thermoplastic elastomer, 20-80 parts of solvent and 2-20 parts of tackifying resin, the thermoplastic elastomer comprises one or more of thermoplastic polyurethane elastomers TPU, SBS, ESBS and SIS, preferably SBS elastomer particles, the solvent can be one or more of ethyl acetate, butyl acetate, toluene, cyclohexanone and DMF, the tackifying resin comprises one or more of rosin, terpene resin, C5, C9 and wingtack 76, preferably wingtack 76.

10. An easy-to-clean security label according to claim 1, characterized in that the thickness of the release layer (50) is 50-200 μm, preferably 75 μm release paper.

Technical Field

The invention relates to the technical field of anti-counterfeit labels, in particular to an easy-to-clean anti-counterfeit label.

Background

The label is used for displaying important information of the article. The label material has a structure comprising a face material, an adhesive and a base paper. The face stock carries important information about the product by printing or printing techniques. The adhesive is used as an important tie for connecting the surface material and the attached object.

The label material has wide application, and can be applied to daily chemical products, product packages, electronic products and automobiles. The label with a special function can play a role in displaying important information of a product and has some anti-counterfeiting functions, so that the functions of tracing, counterfeiting prevention, copying prevention, uncovering prevention, tampering prevention and the like are achieved.

At present, a plurality of anti-counterfeiting technologies are available, and the anti-counterfeiting technology is mainly realized on a label from the following aspects: special materials, special ink technology, information technology, VOID printing technology, anti-counterfeiting patterns and the like are adopted. The special material comprises a laser film, a fragile film, a nuclear pore film and the like. The security pattern includes: flower, lace, relief, latent image, micro-scale, etc. The information technology comprises the following steps: FIRD, two-dimensional code, three-dimensional code, algorithm technology, etc. The special ink technology comprises the following steps: light-variable ink, temperature-variable ink, fluorescent ink, color-variable ink at different angles and the like. Different anti-counterfeiting technologies have different application scenes and different use costs.

In order to guarantee the legitimate rights and interests of consumers, counterfeit commodities are attacked, and some anti-counterfeit labels are often stuck on electronic products. The prior anti-counterfeiting label mostly adopts pressure-sensitive adhesive to connect surface materials, and then a plurality of anti-counterfeiting technologies are manufactured on the surface materials. Because the glass transition temperature of the pressure-sensitive adhesive is lower, after heating, the high molecular chain segment of the pressure-sensitive adhesive becomes soft and slides, so that the viscosity of the pressure-sensitive adhesive is rapidly reduced. Therefore, if a lawless person exists, the anti-counterfeit label can be transferred and replaced by adopting a hot air blowing mode of a blower.

The common anti-counterfeit label is easy to remove by adopting a heating mode. To improve the resistance to removal, the pressure-sensitive adhesive thickness may be increased to raise the glass transition temperature of the pressure-sensitive adhesive, which may increase the difficulty of removal, but the label may be removed by heating for a time sufficient to remove the label.

Under a high-temperature state, the molecular chain of the pressure-sensitive adhesive slides and degrades, so that the cohesion of the pressure-sensitive adhesive is reduced, adhesive residues can be easily generated on an attached object, and the adhesive residues are difficult to clean, and therefore the anti-counterfeiting label easy to clean is provided.

Disclosure of Invention

The invention aims to solve the defects in the prior art and provides an easy-to-clean anti-counterfeit label.

In order to achieve the purpose, the invention adopts the following technical scheme:

the utility model provides an easy antifalsification label of clearing up, includes from supreme release layer, pressure sensitive adhesive layer, anti-fake characters layer, thermal contraction membrane layer and the temperature change printing ink layer that sets gradually down, the temperature change printing ink layer includes by from supreme printing ink printing layer, the light change printing ink layer that sets gradually and resistant polishing oil layer constitution down, anti-fake characters layer includes by from supreme characters printing layer, medium rete and the silicon oil layer that sets gradually down and constitutes.

Preferably, the thickness of the polishing-resistant oil layer is 0.5-10 μm, the transmittance of the polishing-resistant oil layer is 50-100%, the abrasion resistance level of the polishing-resistant oil layer is CS-10, 500g, 50-300cycles, the polishing-resistant oil layer comprises 10-70 parts of acrylate diluent, 20-50 parts of acrylate oligomer and 1-10 parts of photoinitiator, the functionality of the acrylate diluent is 2-4, the acrylate diluent comprises one or more of TMPTA, TPGDA and DPGDAPETA, preferably TPGDA, the acrylate oligomer comprises one or more of EA, FA, PUA, PEA and AA, preferably EA, and the photoinitiator comprises one or more of 184, 907, TPO, 1173 and ITX, preferably 184.

Preferably, the thickness of the optically variable ink layer is 1 to 15 μm, the temperature-change temperature range of the optically variable ink layer is 30 to 120 ℃, the basic color of the optically variable ink layer is colorless, the color becomes red after temperature change, and the color of the optically variable ink layer is irreversible after color change, wherein the optically variable ink layer is usually presented in a character form, such as: "has failed", etc., said optically variable ink layer comprising 10-70 parts of an acrylate diluent, 20-50 parts of an acrylate oligomer, 1-10 parts of a photoinitiator, and 1-10 parts of a temperature change ink, the acrylate diluent having a functionality of 2-4, said acrylate diluent comprising one or more mixtures of TMPTA, TPGDA, and DPGDAPETA, preferably TPGDA, said acrylate oligomer comprising one or more mixtures of EA, FA, PUA, PEA, and AA, preferably EA, said photoinitiator comprising one or more mixtures of 184, 907, TPO, 1173, and ITX, preferably 184, said temperature change ink comprising one or more mixtures of methyl violet inks, phenolic compounds inks, acid clay inks, azo pigment inks, aryl methane inks, and capsule inks.

Preferably, the thickness of the ink printing layer is 1-15 μm, and the ink printing layer is printed with patterns or characters.

Preferably, the thickness of the heat shrinkable film layer is 25 to 125 μm, the color of the heat shrinkable film layer is preferably white, and the shrinkage of the heat shrinkable film layer is: in the MD direction: 0-10% and TD direction: 0-80%, shrinkage temperature interval of heat shrinkable film layer: the material of the heat shrinkable film layer is one of PET, PVC, PE and POF at 40-120 ℃, and the PET type heat shrinkable film is preferred.

Preferably, the thickness of the silicon oil layer is 1-10 μm, and the release force of the silicon oil layer is 50-200 g.

Preferably, the thickness of the dielectric film layer is 1-15 μm, and the wear resistance level of the dielectric film layer is: CS-10, 500g and 50-300cycles, the medium film layer comprises 10-70 parts of acrylate diluent, 20-50 parts of acrylate oligomer and 1-10 parts of photoinitiator, the functionality of the acrylate diluent is 2-4, the acrylate diluent comprises one or more of TMPTA, TPGDA and DPGDAPETA, preferably TPGDA, the acrylate oligomer comprises one or more of EA, FA, PUA, PEA and AA, preferably EA, and the photoinitiator comprises one or more of 184, 907, TPO, 1173 and ITX, preferably 184.

Preferably, the thickness of the character printing layer is 1-10 μm, and the printing content of the character printing layer is characters or patterns.

Preferably, the thickness of the pressure-sensitive adhesive layer is 20-200 μm, the 180 DEG peeling force of the pressure-sensitive adhesive layer is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer is 5-12MPa, the elongation at break of the pressure-sensitive adhesive layer is 500-1500%, the pressure-sensitive adhesive layer comprises 10-50 parts of thermoplastic elastomer, 20-80 parts of solvent and 2-20 parts of tackifying resin, the thermoplastic elastomer comprises one or more of thermoplastic polyurethane elastomer TPU, SBS, ESBS and SIS, preferably SBS elastomer particles, the solvent can adopt one or more of ethyl acetate, butyl acetate, toluene, cyclohexanone and DMF, and the tackifying resin comprises one or more of rosin, terpene resin, C5, C9 and wingtack 76, preferably wingtack 76.

Preferably, the thickness of the release layer is 50-200 μm, preferably 75 μm.

The anti-counterfeiting label has multiple anti-counterfeiting means and is easy to clean.

Drawings

Fig. 1 is a schematic structural diagram of an easy-to-clean anti-counterfeit label according to the present invention.

In the figure: 10 temperature change ink layer, 11 polishing-resistant oil layer, 12 light change ink layer, 13 ink printing layer, 20 heat shrinkage film layer, 30 anti-counterfeiting character layer, 31 silicon oil layer, 32 dielectric film layer, 33 character printing layer, 40 pressure sensitive adhesive layer and 50 release layer.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.

Example one

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

Example two

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 2, the color-changing temperature of the capsule type color-changing ink 2 is 70 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

EXAMPLE III

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 80 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 60 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 2, the color-changing temperature of the capsule type color-changing ink 2 is 70 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

Example four

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 90 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

EXAMPLE five

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 4 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

EXAMPLE six

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 150 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 1200 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

EXAMPLE seven

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 100 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 700 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

Example eight

Referring to fig. 1, an easy-to-clean anti-counterfeit label comprises a release layer 50, a pressure-sensitive adhesive layer 40, an anti-counterfeit character layer 30, a heat shrinkable film layer 20 and a temperature-sensitive ink layer 10, which are sequentially arranged from bottom to top, wherein the heat shrinkable film layer 20 is a white PET heat shrinkable film layer with a thickness of 50 μm, and the shrinkage rate of the heat shrinkable film layer 20 is as follows: in the MD direction: 0% and TD direction: 70 percent, the initial shrinkage temperature of the heat shrinkable film layer 20 is 70 ℃, the thickness of the pressure-sensitive adhesive layer 40 is 150 mu m, the 180-degree peeling force of the pressure-sensitive adhesive layer 40 is 10-30N/25mm, the tensile strength of the pressure-sensitive adhesive layer 40 is 8MPa, the elongation at break of the pressure-sensitive adhesive layer 40 is 700 percent, the pressure-sensitive adhesive layer 40 comprises 40 parts of thermoplastic elastomer SBS, 50 parts of butyl acetate and 10 parts of tackifying resin wingtack 76, the release layer 50 is 75 mu m release paper, the temperature-variable ink layer 10 comprises an ink printing layer 13, an optically variable ink layer 12 and an abrasion-resistant gloss oil layer 11 which are sequentially arranged from bottom to top, the thickness of the abrasion-resistant gloss oil layer 11 is 2 mu m, the transmittance of the abrasion-resistant gloss oil layer 11 is 50-100 percent, the abrasion resistance level of the abrasion-resistant gloss oil layer 11 is CS-10, 500g and 50-300cycles, the abrasion-resistant gloss oil layer 11 comprises 60 parts of acrylate diluent TPGDA, TPGDA and TPA, 35 parts of acrylate oligomer EA and 5 parts of photoinitiator 184, wherein the thickness of the optically variable ink layer 12 is 1 μm, the basic color of the optically variable ink layer 12 is colorless, the color is red after temperature change, and the color of the optically variable ink layer 12 is irreversible after color change, wherein the optically variable ink layer 12 is usually represented in a character form, such as: the anti-counterfeiting ink comprises an optical variable ink layer 12 and a non-optical variable ink layer 30, wherein the optical variable ink layer 12 comprises 60 parts of acrylate diluent TPGDA, 32 parts of acrylate oligomer EA, 5 parts of photoinitiator 184 and 3 parts of capsule type color-changing ink 1, the color-changing temperature of the capsule type color-changing ink 1 is 90 ℃, the thickness of the ink printing layer 13 is 1 mu m, patterns or characters are printed on the ink printing layer 13, the anti-counterfeiting character layer 30 comprises a character printing layer 33, a medium film layer 32 and a silicon oil layer 31 which are sequentially arranged from bottom to top, the thickness of the silicon oil layer 31 is 2 mu m, the release force of the silicon oil layer 31 is 100g, the thickness of the medium film layer 32 is 2 mu m, and the wear resistance level of the medium film layer 32 is as follows: CS-10, 500g and 50-300cycles, the medium film layer 32 comprises 60 parts of acrylate diluent TPGDA, 35 parts of acrylate oligomer EA and 5 parts of 184, the thickness of the character printing layer 33 is 1 mu m, and the printing content of the character printing layer 33 is characters or patterns.

The anti-counterfeit label provided by the first embodiment to the eighth embodiment has a plurality of anti-counterfeit means and is easy to clean.

In the description of the present application, it should be further noted that, unless otherwise explicitly stated or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may include, for example, a fixed connection, a detachable connection, an integral connection, a mechanical connection, an electrical connection, a direct connection, a connection through an intermediate medium, and a connection between two elements. The specific meaning of the above terms in the present application can be understood by those of ordinary skill in the art according to specific circumstances.

The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

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