二氨基缩醛和二氨基缩酮的盐及它们的合成及它们向二氨基缩醛和二氨基缩酮的转化

文档序号:883666 发布日期:2021-03-19 浏览:8次 >En<

阅读说明:本技术 二氨基缩醛和二氨基缩酮的盐及它们的合成及它们向二氨基缩醛和二氨基缩酮的转化 (Salts of diamino acetals and diamino ketals, their synthesis and their conversion to diamino acetals and diamino ketals ) 是由 S.科辛斯基 S.J.帕斯汀 U.巴特 于 2019-01-07 设计创作,主要内容包括:本申请部分涉及由下列式(1)的结构表示的新型盐及其制备方法:其中R~(1a)选自:氢、任选取代的烷基(例如,未取代的C-(1-6)烷基,例如,-CH-3);R~(1b)为任选取代的烷基(例如,未取代的C-(1-6)烷基,例如,-CH-3);R~2和R~3的每一种情况独立地选自:氢、任选取代的烷基、任选取代的环烷基、和任选取代的芳基;R~2和R~3可以彼此组合以形成任选取代的环烷基;各m和n独立地为1至20的整数(例如,m和n独立地为1至5的整数);且各和独立地为抗衡离子(例如,和各自独立地为选自以下的抗衡离子:氯离子、溴离子、氟离子、碘离子、醋酸根、羧酸根、硫酸氢根、硝酸根和苯酚根、以及磺酸根,例如,氯离子)。(The present application relates, in part, to novel salts represented by the structure of the following formula (1) and methods of making the same: wherein R is 1a Selected from: hydrogen, optionally substituted alkyl (e.g. unsubstituted C) 1‑6 Alkyl radicals, e.g., -CH 3 );R 1b Is optionally substituted alkyl (e.g., unsubstituted C) 1‑6 Alkyl radicals, e.g., -CH 3 );R 2 And R 3 Each instance of (a) is independently selected from: hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, and optionally substitutedA substituted aryl group; r 2 And R 3 May be combined with each other to form optionally substituted cycloalkyl; each m and n is independently an integer from 1 to 20 (e.g., m and n are independently an integer from 1 to 5); and each is And independently, a counter ion (e.g., and each independently a counterion selected from: chloride, bromide, fluoride, iodide, acetate, carboxylate, bisulfate, nitrate and phenolate, and sulfonate, e.g., chloride).)

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