阅读说明：本技术 过滤介质和制造这种过滤介质的方法 (Filter media and method of making same ) 是由 O·施陶登迈尔 H·沙赫特 A·霍林斯沃思 T·戈格斯 A·科洛 R·库尔策 A·格赖纳 于 2020-04-08 设计创作，主要内容包括：本发明涉及一种过滤介质和一种用于制造这种过滤介质的方法。所述过滤介质(1)用于过滤空气流,且具有带有大量双组分纤维的无纺织物。根据本发明,所述无纺织物构造成单层纤维复合材料(2),所述纤维复合材料具有由双组分纤维组成的第一结构(3.1)和由连续的双组分纤维组成的第二结构(3.2),通过用第二结构铺放覆盖第一结构,使第二结构(3.2)嵌入第一结构(3.1)。第一结构与第二结构的包覆的纤维一起形成一种非常稳定的单层的材料,这种材料在具有良好的过滤效果同时具有出人意料的高刚度、非常高的透气性和高容尘量。(The present invention relates to a filter medium and a method for manufacturing such a filter medium. The filter medium (1) is used for filtering an air flow and has a nonwoven fabric with a plurality of bicomponent fibers. According to the invention, the nonwoven is designed as a single-layer fiber composite (2) having a first structure (3.1) consisting of bicomponent fibers and a second structure (3.2) consisting of continuous bicomponent fibers, the second structure (3.2) being embedded in the first structure (3.1) by laying the second structure over the first structure. The first structure together with the coated fibres of the second structure form a very stable single-layer material having an unexpectedly high stiffness, a very high air permeability and a high dust holding capacity while having a good filtering effect.)

1. Filter medium (1) for filtering an air flow, comprising a nonwoven fabric comprising a plurality of bicomponent fibres, characterized in that the nonwoven fabric is configured as a single-layer fibre composite (2) having a first structure (3.1) consisting of bicomponent fibres and a second structure (3.2) consisting of continuous bicomponent fibres, the second structure (3.2) being embedded in the first structure (3.1).

2. Filter medium according to claim 1, wherein the bicomponent fibers consist of at least two polymer components and the at least two polymer components of the bicomponent fibers differ in their melting points by at least 15 degrees and in particular have a sheath/core fiber structure or a side-by-side fiber structure.

3. Filter medium according to claim 1 or 2, wherein the polymer species of the low melting polymer component of the bicomponent fibres of the first (3.1) and second (3.2) structures are the same.

4. Filter medium according to one of the preceding claims, wherein the bicomponent fibres of the first (3.1) and second (3.2) structures have different fibre diameters.

5. Filter media according to one of the preceding claims, wherein the polymer component consists of a polyolefin.

6. Filter medium according to one of the preceding claims, wherein the bicomponent fibers of the first structure (3.1) are embodied as staple fibers, spun bond non-woven filaments, melt blown filaments.

7. Filter medium according to one of the preceding claims, wherein the first structure (3.1) is cured thermally, mechanically or chemically.

8. Filter medium according to one of the preceding claims, wherein the first structure (3.1) consists of at least 30% by weight, in particular at least 50% by weight, of bicomponent fibres.

9. Filter medium according to one of the preceding claims, wherein the first structure (3.1) is equipped with electret functionality, antimicrobial arrangement and/or coloration.

10. Filter medium according to one of the preceding claims, wherein the first structure (3.1) has 20 to 150g/m²In particular from 40 to 80g/m²The areal density of (c).

11. Method for manufacturing a filter medium (1) according to one of the preceding claims, having the steps of:

a) -manufacturing a first structure (3.1);

b) feeding a first structure (3.1) into a spunbonding apparatus;

c) laying down a covering first structure (3.1) with a second structure (3.2);

d) curing the fibre composite (2).

12. Method for manufacturing a filter medium according to claim 11, wherein in step d) the fibre composite (2) is pressed and/or thermally bonded and/or thermally calibrated and/or post-treated.

13. The method for manufacturing a filter medium according to claim 11 or 12, wherein in step c) the second structure (3.2) is laid over one or both sides of the first structure (3.1).

14. Filter element (4) with a filter medium according to one of claims 1 to 10, in particular in pleated form, in particular for a filter cassette.

15. Use of a filter element (4) according to claim 14 as a particle filter for filtering air.

Technical Field

The invention relates to a filter medium with a nonwoven fabric according to the preamble of claim 1 and a method for producing such a filter medium according to claim 11.

Background

Pleated, i.e. folded, filter media are widely known for use in many filter elements and for enlarging the filter surface. In order to obtain pleatable and therefore inherently rigid, fold-shape-retaining media, and to obtain corresponding filtration properties, the material is usually arranged in multiple layers. The support layer for the synthetic fiber-based material is usually a very stable spunbonded nonwoven or staple fiber nonwoven which consists of PES fibers or polyolefin fibers. In some configurations, the fibers used may be present as a bicomponent fiber structure. Thermally bonded bicomponent structures typically have a higher stiffness than homopolymer fibers. The support layer consists of relatively coarse spunbond or staple fibers and has mainly a load-bearing function or a reinforcing/pleating function, while the separation of fine particles is achieved by microfibers applied to the support layer. The microfiber layer itself has no load bearing capacity and does not have sufficient strength.

The microfiber layer is additionally partially protected with a cover laminated over the microfiber layer. Microfibers include, for example, polypropylene or polycarbonate polymers. Depending on the type of polymer used and the process, the microfibers are also typically subjected to an electrostatic charge.

That is, the conventional filter material for the aforementioned use is composed of a rigid spunbonded nonwoven fabric layer having coarse fibers, which is manufactured in a spunbond process, and a fine microfiber layer, which is manufactured in a melt blown process. The two layers are connected to each other, for example, by means of ultrasonic calendering. Such structures and processes are known, for example, from WO 2010/049052 or EP 1208959B 1. Alternatively, the layers are also laminated, for example by hot melt or glue spraying. In addition to combinations of carrier structures, which are realized, for example, by means of spunbonded nonwovens with microfibers, composites composed of staple fibers together with carrier structures are also known. Such a composite material with short fibers is very suitable for achieving a high dust holding capacity of the filter and thus a long service life. Here, use is frequently made of triboelectrically charged fibers which are laminated to the carrier due to their limited nonwoven strength or insufficient rigidity. Such lamination is usually effected, for example, by means of ultrasound, needling or by means of adhesion by means of hot melt adhesives. All these embodiments have in common that the laminate is composed of at least two different layers with different fibers/different fiber diameters. In practice, such composite materials constantly lead to disturbances in the process during the pleating, i.e. folding, of the filter material, since the two layers can become detached from one another or become hooked during pleating. In filter elements, it is often observed that the layers separate, which can lead to the formation of "pockets" or small creases in the composite matrix. The pockets or folds have a negative effect on the pressure loss of the filter cartridge in which the filter medium is installed, due to disturbances in the through-flow.

Disclosure of Invention

It is an object of the present invention to provide a filter medium which combines good stability, processability and dust holding capacity and which at least partly obviates the disadvantages of the prior art. Another object is to specify a method for manufacturing such a filter medium.

The filter medium requires high rigidity, and thus can be easily pleated on an industrial scale even if it has wrinkles. It is advantageous for the pressure loss of the filter medium that the material is thin. In the case of a medium which is as thin as possible, the pleat spacing can be reduced, in order thereby to reduce the pressure loss of the filter element. At the same time, it is advantageous to achieve the highest possible dust holding capacity in the filter box by adjusting the material thickness, the air permeability and the nonwoven fabric construction with similar pressure losses in the filter box. A high dust holding capacity means a long service life. At the same time, it is desirable to use as little areal density or filter medium mass as possible in order to save costs.

This object is achieved by a filter medium having the features of claim 1.

According to the invention, it has been found to be advantageous to provide a filter medium made of a nonwoven fabric having a single layer, in which all fibers are connected to one another, i.e. a fiber composite is formed.

The filter medium according to the invention is used for filtering an air flow and has a nonwoven with a plurality of bicomponent fibers. According to the invention, the nonwoven is designed as a single-layer fiber composite having a first structure consisting of bicomponent fibers and a second structure consisting of continuous bicomponent fibers, wherein the second structure is embedded in the first structure by laying down a cover (bespinnen) of the first structure with the second structure.

The first structure forms together with the coated (afspanen) fibres of the second structure a very stable single-layer material with an unexpectedly high stiffness, very high air permeability and high dust holding capacity at the same time as a good filtering effect.

In a particularly advantageous and therefore preferred development of the filter medium according to the invention, the bicomponent fibers consist of at least two polymer components whose melting points differ by at least 15 degrees and in particular have a sheath/core fiber structure (cover-core) or a double-sided side-by-side fiber structure. The preferred polymer for the core and sheath (or side-by-side) fiber structure is polypropylene, although polyester may also be used, particularly in the core of the fiber. The ratio of the two components of the core and sheath (or side-by-side) fibrous structure may vary between 9:1 and 1:1, preferably between 8:2 and 7: 3. Here, the minor ingredients are the components having lower melting points.

It is particularly advantageous if the polymer component of the bicomponent fibres consists of a polyolefin, for example of polypropylene (PP). It has been recognized that it is advantageous that the polymer type of the low-melting polymer component of the first and second structures of bicomponent fibers be the same to ensure material consistency, that is, the low-melting polymer component of the first and second structures of bicomponent fibers are the same type of polymer.

In the filter medium according to the invention, the bicomponent fibers of the first structure can be designed as staple fibers, as filaments of a spunbonded nonwoven, as a combination of these techniques, and can be formed, if necessary, together with meltblown filaments.

It is particularly preferred that the first structure is cured thermally, mechanically or chemically.

The first structure is a planar fiber structure made of synthetic fibers, which can be cured thermally, mechanically or by means of a binder. The nonwoven fabric of the first structure can be manufactured in different well-known methods or a combination of different methods: spunbonded nonwoven, meltblown nonwoven, composite materials of spunbonded nonwoven and meltblown nonwoven, dry-laid nonwoven made of staple fibers, wet nonwoven made of staple fibers, combinations of carrier materials and nanofibers or corresponding combinations of different technologies. These different nonwoven fabric manufacturing methods are well known to those skilled in the art and therefore will not be described. In particular, multilayer nonwoven structures comprising coarse fibers (> 1dtex) and finer fibers (for example microfibers of < 1dtex) are also conceivable here as first structures.

To achieve a gradient structure of the filter media, the bicomponent fibers of the first and second structures may have different fiber diameters.

It has been recognized that it is advantageous for at least 30% by weight, in particular at least 50% by weight, of the first structure to consist of bicomponent fibres (by weight% is meant weight percent).

In a development of the filter medium, the first structure is equipped with electret functionality, antimicrobial arrangement and/or coloring. Fibers made of polypropylene, for example, can be subjected to electrostatic charges particularly well. This can be done, for example, by corona charging. Other methods of introducing static charge are also contemplated.

The first structure of the filter media can have a thickness of 20 to 150g/m²In particular from 40 to 80g/m²The areal density of (c).

The continuous spunbonded nonwoven fibers applied to the pre-laid nonwoven are predominantly made of bicomponent fibers. These fibers are composed of at least two polymer components. The fibers may be a sheath/core fiber structure or a side-by-side fiber structure. Preferred polymers for the core and sheath (or side-by-side) fiber structure are comprised of the polyolefin family. Polyolefin refers to polymers made from olefins. Common but non-limiting examples of such polymers include polypropylene, polyethylene, or copolymers thereof.

In one embodiment, however, PES may also be used in the core of the fibers. The two polymers used for the core and the sheath (optionally side by side) differ in their melting points by at least 15 ℃. The ratio of the two core and sheath components (or side-by-side components) may vary between 9:1 and 1:1, preferably between 8:2 and 7: 3. The minor component is a lower melting component. The continuous spunbonded nonwoven fibers or filaments have an areal density of 15 to 150g/m²Preferably 40 to 80g/m²。

If the pre-laid nonwoven is configured asymmetrically in its composition, the application of continuous spunbond fibers to different sides of the pre-laid nonwoven can be provided according to the desired properties.

The invention also relates to a method for producing a filter medium as described above, having the following steps:

a) manufacturing a first structure;

b) supplying the first structure to a spunbonding apparatus;

c) laying down a second structure over the first structure to achieve a single layer fiber composite;

d) the fiber composite is cured.

In a development of the method, the fiber composite material can be pressed and/or thermally bonded and/or thermally calibrated and/or post-treated in step d).

In other words: a nonwoven fabric comprising bicomponent fibers is supplied to a spunbond apparatus. The supplied nonwoven is covered with a continuous spunbond nonwoven fiber deposit, which is likewise formed as bicomponent fibers. Next, this fiber composite is pressed, thermally bonded or thermally calibrated, and if necessary post-processed. Newly spun applied continuous spunbond nonwoven fibers or flowing polymers readily penetrate into the supplied nonwoven layer during thermal curing. Surprisingly, a very tight fiber-fiber connection is obtained and a single-layer fiber composite is achieved after heat treatment. By the good penetration of the coating polymer, a very compact, highly rigid, thin single-layer nonwoven with a comparatively open fiber structure can easily be produced, which can furthermore be composed of different fiber types and fiber diameters. It is achieved here that a gradient nonwoven structure of the fiber composite can be realized in a simple manner.

In the production of the filter medium, the second structure can be laid down over one or both sides of the first structure in step c).

The invention further relates to a filter element, preferably folded, having a filter medium as described above, in particular for a filter cassette. The filter medium according to the invention and the filter element produced therefrom can be used primarily in the field of air filtration, in particular for vehicle interiors, for air conditioning systems, for air filtration of interiors or all types of spaces in buildings by means of stationary and/or mobile filter devices, for filter elements in vacuum cleaners, trains or agricultural machines, and for air filtration in technical processes such as gas turbines, painting systems or food processing, to name a few.

The invention also relates to the use of such a filter element as a particle filter. The filter medium according to the invention is a particle filter medium and can be used here as a pure particle filter or can be used in combination with other filter media, for example adsorption media, as a component of a filter element. To enlarge the filtration area, the filter medium may be pleated, i.e. the filter medium is folded.

For the adsorbent material, the adsorbent layer may be attached to the outflow side, or the reverse order may be used. With this configuration, not only the particles but also unpleasant odors can be adsorbed.

In this context, the adsorption layer can have activated carbon particles. The filter medium may have an adsorption layer made of activated carbon, zeolite or ion exchanger or a mixture thereof. Thus, harmful gases, such as hydrocarbons, SO, can be adsorbed₂、NO_xAldehyde, ammonia, VOC or similar gas.

The activated carbon particles are preferably bonded to the single-layer material according to the invention using a hot melt adhesive of the same material. The areal density of the adsorbent layer may be 50 to 500g/m²And the thickness thereof may be 0.7 to 3.0 mm. The filter medium with the single-layer material and the adsorption layer according to the invention can be used in particular in the folded state as a combined filter for adsorbing particles and harmful gases.

The described invention and the described advantageous refinements of the invention can also be combined with one another to form advantageous refinements of the invention, if this is technically feasible.

With regard to further advantages and structurally and functionally advantageous embodiments of the invention, reference is made to the dependent claims and to the description of the exemplary embodiments with reference to the drawings. Examples

The following materials are used as possible examples of single-layer filter media according to the invention, either as a pure particle filter or as a combined filter in combination with one or more adsorption devices:

Drawings

The present invention is explained in detail with reference to the accompanying drawings.

Wherein:

FIG. 1 is a cross-sectional view of a filter media according to the prior art;

FIG. 2 is a cross-sectional view of a filter media according to the present invention;

fig. 3 shows a filter element.

example A: supply of 65g/m as a first structure to a spunbond apparatus²Of 100% of 28 μm PP bicomponent fibres (core melting point: 166 ℃ C.; sheath melting point: 145 ℃ C.) and having a thickness of 1.09mm (DIN EN ISO 9073-210 cm)²，12.5cN/cm²)、6390l/m²s permeability (test equipment Textest 300020 cm)²DIN ISO 9073-15 at 200 Pa), low bending stiffness (ISO2493, Fa. Frank, model 58565, 20X 100mm), 0.15Nmm in longitudinal direction and 0.16Nmm in transverse direction, and 8g/m as a second structure (B2)²Is laid down covered with 100% continuous PP bicomponent fibers. The core melting point of the fiber was 166 ℃ and the sheath melting point was 145 ℃. The fibers had a fiber titer of 30 μm.

After the calibration of the composite material consisting of the first and second structures, it is cured by means of hot air, again thermally calibrated to a target thickness and electrostatically charged by means of corona.

Analogously to the above test, at 138g/m²100% PP bicomponent fibers as a spunbond nonwoven fabric was used as a reference. This fiber with a titre of 30 μm was calibrated, cured with the aid of hot air, calibrated again to the target thickness and electrostatically charged with the aid of a corona. The operation of such a spunbonded nonwoven on a device corresponds to the operation according to an embodiment of the invention.

As shown in table 1, a single layer fiber composite having significantly improved stiffness, strength and air permeability was achieved by the present invention at the same areal density.

TABLE 1

The nonwoven fabric according to the invention of reference nonwoven fabric and example a was processed into a filter element and subjected to filtration measurements. In both cases, the dimensions of the filter element were 182X 254 mm.

The folded filter material had a crease height of 35 mm. The filter element comprises 51 double folds with a 5mm pitch. Is provided with 0.51m²The filtration area of (a). The pressure loss between the inflow side and the outflow side of the filter element was tested at different volume flow rates according to DIN 71460.

The filter element was additionally loaded with test dust AC coarse according to DIN 71460 part 1 and the amount of dust absorbed was determined with an increase in pressure loss of 200 Pa. The amount of dust stored is a measure of the service life of the filter, and larger amounts are preferred. The classification efficiency was determined by means of AC fine according to DIN 71460 part 1. In the filter element according to the invention, a measurement of the supplied nonwoven fabric a is carried out on the inflow side and a flow of the spin-applied fiber layer B is carried out. In both cases, a significantly higher dust holding capacity is obtained with a similar pressure loss between the inflow side and the outflow side of the filter cartridge, with similar separation properties (see table 2).

TABLE 2