阅读说明：本技术 一种固化添加剂及其制备方法及其应用 (Curing additive, preparation method and application thereof ) 是由 王秀英 李泰炯 于 2019-03-18 设计创作，主要内容包括：本发明公开一种固化添加剂及其制备方法及其应用,所述固化添加剂的组分包括培养液,硫酸钾,柠檬酸,氯化镁,氯化钠,氯化钙和碳酸钾,其中所述培养液的组分包括氯化钴,酒石酸,氯化铵,碳酸钾和硼砂。本发明固化用添加固化添加剂能够配合水泥有效固化土壤或者含有土壤的工业废料和建筑废料,相较于传统水泥固化法,本发明固化添加剂具有固化强度高的特点,不仅可作为一般混凝土替代物,而且本发明固化添加剂还能有效利用固化反应中产生的多余氢氧化钙,降低对土壤和水的污染。(The invention discloses a curing additive and a preparation method and application thereof. Compared with the traditional cement curing method, the curing additive has the characteristic of high curing strength, can be used as a substitute for common concrete, and can also effectively utilize redundant calcium hydroxide generated in a curing reaction to reduce pollution to soil and water.)

1. A solidification additive, wherein the components of the solidification additive comprise a culture solution, potassium sulfate, citric acid, magnesium chloride, sodium chloride, calcium chloride and potassium carbonate, and wherein the components of the culture solution comprise cobalt chloride and ammonium chloride.

2. The curing additive of claim 1, comprising the following components in weight percent:

0.2-5% of culture solution;

23-27% of potassium sulfate;

1-5% of citric acid;

15-30% of magnesium chloride;

20-30% of sodium chloride;

15-30% of calcium chloride.

3. The curing additive of claim 2, comprising the following components in weight percent:

0.3-2.5% of culture solution;

23-27% of potassium sulfate;

1-5% of citric acid;

15-30% of magnesium chloride;

20-30% of sodium chloride;

15-30% of calcium chloride.

4. The curing additive as claimed in claim 3, wherein the culture fluid comprises the following components in percentage by weight:

1-10% of cobalt chloride;

1-5% of ammonium chloride;

the balance being water.

5. A method of preparing a curing additive as claimed in any one of claims 1 to 4, comprising the steps of:

a. mixing cobalt chloride, ammonium chloride and water in proportion to prepare a culture solution;

b. and c, adding potassium sulfate, citric acid, magnesium chloride, sodium chloride and calcium chloride into the culture solution prepared in the step a, mixing, and drying for 1-6 hours to prepare the powdery solidification additive.

6. Use of a curing additive according to any one of claims 1 to 4 in combination with cement to effect curing of industrial and construction waste to produce a construction material.

7. The use of the curing additive as claimed in claim 6, wherein the industrial or construction waste is a soil-containing industrial or construction waste, wherein the industrial or construction waste contains a soil specific gravity of 10 to 90%.

8. Use of a curing additive according to any one of claims 1 to 4 in road construction in combination with cement to effect soil curing.

9. The use of the curing additive as claimed in any one of claims 1 to 4, wherein the curing additive is used for desert curing to realize desert ecological restoration.

10. Use of a curing additive according to any one of claims 1 to 4 in the manufacture of artificial fish reefs for the construction of marine ranches.

Technical Field

The invention relates to the field of curing materials, in particular to a curing additive, a preparation method and application thereof.

Background

Concrete is generally formed by mixing cement, sand and crushed stone (or gravel) with water. Such concrete is mainly used as a building structural material or a paving material, etc. The use of a large amount of cement causes serious pollution to the environment, substances polluting soil and water sources are generated along with the interaction of components in the cement, for example, various hydrates are generated due to hydration reaction, redundant calcium hydroxide overflows to pollute the surrounding soil and water, the existing cement cannot meet certain high-strength construction requirements, and if the basic amount of cement cannot meet the strength requirement, the freezing effect in winter can be reduced to the maximum extent by increasing the cement consumption, and the deficiency of the strength is made up. However, excessive cement causes the above-mentioned environmental pollution problem.

Accordingly, the prior art is subject to further development and advancement.

Disclosure of Invention

Aiming at the technical problems, the embodiment of the invention provides a curing additive, a preparation method and an application thereof, aiming at solving the problems of low curing strength and environmental pollution in the use process of cement.

The technical scheme of the invention is as follows:

a solidifying additive, wherein the components of the solidifying additive comprise a culture solution, potassium sulfate, citric acid, magnesium chloride, sodium chloride and calcium chloride, and the components of the culture solution comprise cobalt chloride and ammonium chloride.

The curing additive comprises the following components in percentage by weight:

0.2-5% of culture solution;

23-27% of potassium sulfate;

1-5% of citric acid;

15-30% of magnesium chloride;

20-30% of sodium chloride;

15-30% of calcium chloride.

The curing additive comprises the following components in percentage by weight:

0.3-2.5% of culture solution;

23-27% of potassium sulfate;

1-5% of citric acid;

15-30% of magnesium chloride;

20-30% of sodium chloride;

15-30% of calcium chloride.

The curing additive comprises the following components in percentage by weight:

1-10% of cobalt chloride;

1-5% of ammonium chloride;

the balance being water.

A method of preparing a curing additive as described above, comprising the steps of:

a. mixing cobalt chloride, ammonium chloride and water in proportion to prepare a culture solution;

b. and (b) adding potassium sulfate, citric acid, magnesium chloride, sodium chloride and calcium chloride into the culture solution prepared in the step a, mixing, and drying for 1-6 hours to prepare the powdery curing additive.

The invention provides application of the curing additive, wherein the curing additive is applied to the preparation of building materials by matching with cement to cure industrial waste and building waste.

The application of the curing additive is that the industrial waste or the construction waste is the industrial waste or the construction waste containing soil, wherein the specific gravity of the industrial waste or the construction waste containing soil is 10-90%; the curing additive accounts for 0.1-0.5% of the proportion of the industrial waste or the construction waste containing the soil.

The invention provides application of the curing additive, wherein the curing additive is applied to be matched with cement to realize soil curing for road construction.

The invention provides an application of the curing additive, wherein the curing additive is applied to desert curing to realize desert ecological restoration.

The invention provides the use of a curing additive as described above, wherein the curing additive is used in the processing of artificial fish reefs to build a marine ranch.

Advantageous effects

The invention provides a curing additive and a preparation method and application thereof, the curing additive can be matched with cement to effectively cure soil or industrial waste and construction waste containing soil, compared with the traditional cement curing method, the curing additive has the characteristic of high curing strength, not only can be used as a substitute of common concrete, but also can effectively utilize redundant calcium hydroxide generated in the curing reaction to reduce the pollution to soil and water.

Drawings

FIG. 1 is a graph of performance test results for samples of the present example.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items. In addition, the technical features involved in the different embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.

The curing additive of the invention comprises the following components: culture solution, potassium sulfate, citric acid, magnesium chloride, sodium chloride and calcium chloride. Wherein the culture solution contains cobalt chloride and ammonium chloride.

The curing additive is applied to curing molding based on industrial waste or construction waste as a concrete raw material. Wherein the industrial waste or the construction waste is an industrial waste or a construction waste containing soil.