阅读说明：本技术 一种皮革漂白工艺 (Leather bleaching process ) 是由 黄茂英 于 2021-09-15 设计创作，主要内容包括：本发明公开了一种皮革漂白工艺,属于漂白领域,一种皮革漂白工艺,通过扩孔的预处理,使皮革上孔隙得到扩张,在进行漂白时,有效加速双氧水漂白液向内的渗透速度,同时配合压液磁板的设置,通过控制其向上移动,使皮革被挤压在两个压液磁板之间,在挤压力作用下,压液磁板内吸附的双氧水漂白液快速外溢呈喷射状喷射在皮革表面,在不断重复压液磁板的上下移动过程中,双氧水漂白液不断朝向皮革表面喷射,相较于现有技术中的自然渗透,显著加快双氧水漂白液朝向皮革内的渗透速度,提高漂白均匀性以及漂白效率。(The invention discloses a leather bleaching process, which belongs to the field of bleaching, and the leather bleaching process is characterized in that pores on leather are expanded through reaming pretreatment, the inward permeation speed of hydrogen peroxide bleaching solution is effectively accelerated during bleaching, the upward movement of the hydrogen peroxide bleaching solution is controlled by matching with the arrangement of hydraulic magnetic plates, the leather is extruded between the two hydraulic magnetic plates, the hydrogen peroxide bleaching solution adsorbed in the hydraulic magnetic plates rapidly overflows and is sprayed on the surface of the leather in a spraying manner under the action of extrusion force, and the hydrogen peroxide bleaching solution is sprayed towards the surface of the leather in the process of continuously repeating the upward and downward movement of the hydraulic magnetic plates.)

1. A leather bleaching process is characterized in that: the method comprises the following steps:

s1, performing reaming pretreatment on the leather, then enabling the end part of the leather to penetrate through a plurality of traction rollers and two hydraulic magnetic plates which are symmetrical to each other, connecting the end part of the leather with a traction device, and injecting hydrogen peroxide bleaching liquid into a bleaching box;

s2, controlling the hydraulic magnetic plates below to move upwards through the lifting assembly until the leather is extruded between the two hydraulic magnetic plates, and quickly overflowing the hydrogen peroxide bleaching solution adsorbed in the hydraulic magnetic plates to be sprayed on the surface of the leather in a spraying manner under the action of extrusion force so as to accelerate the permeation of the hydrogen peroxide bleaching solution into the leather;

s3, controlling the lower hydraulic magnetic plates to move downwards through the lifting assembly to separate the two hydraulic magnetic plates from each other, recovering the deformation of the end parts close to each other to absorb hydrogen peroxide bleaching liquid, and repeatedly controlling the lower hydraulic magnetic plates to move up and down to enable the hydrogen peroxide bleaching liquid to be continuously sprayed towards the surface of the leather;

and S4, after a period of time, drawing the bleached partial leather out of the bleaching box through a drawing device, rinsing for multiple times after the bleaching of all the leather is finished, and then drying to finish the bleaching of the leather.

2. A process for bleaching leather according to claim 1, characterized in that: the temperature of the hydrogen peroxide bleaching solution is 60-85 ℃, and the interval between the rising and the falling of the lifting component is 10-30 s.

3. A process for bleaching leather according to claim 1, characterized in that: the pre-treatment of the underreaming comprises the following steps:

s11, firstly, soaking the leather in warm water for 15-30min, then taking out the leather and draining the floating water on the surface of the leather;

and S12, continuously and repeatedly cooling and heating the leather, so that the volume of water in the leather is continuously changed under the temperature change, and the hole expansion of the leather surface gap is realized.

4. A leather bleaching process according to claim 3, wherein: the temperature change range in the temperature reduction and temperature rise treatment in the step S12 is 4-25 ℃, the treatment time lasts for 20-30min, and the temperature change from high to low is completed 1-2 times per minute.

5. A process for bleaching leather according to claim 1, characterized in that: the hydraulic magnetic plate comprises a positioning plate (1) and a liquid changing flat bag (3) fixedly connected to one end, close to one end of the two positioning plates (1), a magnetic plate (4) is fixedly connected to the joint of the liquid changing flat bag (3) and the positioning plates (1), and a plurality of silica gel balls (5) are fixedly connected to the outer surface, away from the magnetic plate (4), of the liquid changing flat bag (3).

6. A leather bleaching process according to claim 5, wherein: silica gel ball (5) internal fixation inlays and has the magnetic core, the magnetic core is mutually exclusive with magnetic plate (4), and a plurality of silica gel balls (5) on two hydraulic pressure magnetic plates attract each other.

7. A leather bleaching process according to claim 6, wherein: the liquid-changing flat bag (3) is of an elastic structure, and the end part of the liquid-changing flat bag (3) connected with the silica gel ball (5) is of a porous structure.

8. A leather bleaching process according to claim 5, wherein: change long post of liquid (6) of a plurality of evenly distributed of liquid flat bag (3) inner wall fixedly connected with, change long post of liquid (6) including pressing change end (61) and fixed connection play liquid dish (62) on changing liquid flat bag (3), and go out liquid dish (62) towards leather one side, go out liquid dish (62) and press to change and be connected with the inside lining release link between the end (61) interior top.

9. A process of bleaching leather according to claim 8, wherein: the inside lining release link includes two longitudinal register poles (7) and fixed connection four-way cage on longitudinal register pole (7), four-way cage includes a plurality of fixed connection respectively at two longitudinal register pole (7) tip and presses node marble (8) and a plurality of connection of changing between two vertical adjacent node marbles (8) of changing end (61) inner wall and change strip (9).

10. A process of bleaching leather according to claim 9, wherein: press and become strip (9) and make for high elasticity high tenacity material, press to become end (61) and be elastic seal structure, go out liquid dish (62) and be porous structure.

Technical Field

The invention relates to the field of bleaching, and particularly relates to a leather bleaching process.

Background

The leather is animal skin which is obtained by physical and chemical processing such as unhairing, tanning and the like and is denatured and non-perishable. The leather is formed by tightly weaving natural protein fibers in a three-dimensional space, and the surface of the leather is provided with a special grain surface layer which has natural grains and luster and comfortable hand feeling.

Compared with cloth, the leather has higher density and thicker thickness, and hydrogen peroxide bleaching solution is difficult to rapidly permeate when being bleached, so that the bleaching efficiency is low, and meanwhile, the condition of uneven bleaching is easily caused.

Disclosure of Invention

1. Technical problem to be solved

Aiming at the problems in the prior art, the invention aims to provide a leather bleaching process, pores on leather are expanded through reaming pretreatment, the inward permeation speed of hydrogen peroxide bleaching liquid is effectively accelerated during bleaching, the leather is extruded between two hydraulic magnetic plates by controlling the upward movement of the hydraulic magnetic plates in cooperation with the arrangement of the hydraulic magnetic plates, the hydrogen peroxide bleaching liquid adsorbed in the hydraulic magnetic plates rapidly overflows and is sprayed on the surface of the leather in a spraying manner under the action of extrusion force, and the hydrogen peroxide bleaching liquid is sprayed towards the surface of the leather in the process of continuously repeating the upward and downward movement of the hydraulic magnetic plates.

2. Technical scheme

In order to solve the above problems, the present invention adopts the following technical solutions.

A leather bleaching process comprising the steps of:

s1, performing reaming pretreatment on the leather, then enabling the end part of the leather to penetrate through a plurality of traction rollers and two hydraulic magnetic plates which are symmetrical to each other, connecting the end part of the leather with a traction device, and injecting hydrogen peroxide bleaching liquid into a bleaching box;

s2, controlling the hydraulic magnetic plates below to move upwards through the lifting assembly until the leather is extruded between the two hydraulic magnetic plates, and quickly overflowing the hydrogen peroxide bleaching solution adsorbed in the hydraulic magnetic plates to be sprayed on the surface of the leather in a spraying manner under the action of extrusion force so as to accelerate the permeation of the hydrogen peroxide bleaching solution into the leather;

s3, controlling the lower hydraulic magnetic plates to move downwards through the lifting assembly to separate the two hydraulic magnetic plates from each other, recovering the deformation of the end parts close to each other to absorb hydrogen peroxide bleaching liquid, and repeatedly controlling the lower hydraulic magnetic plates to move up and down to enable the hydrogen peroxide bleaching liquid to be continuously sprayed towards the surface of the leather;

and S4, after a period of time, drawing the bleached partial leather out of the bleaching box through a drawing device, rinsing for multiple times after the bleaching of all the leather is finished, and then drying to finish the bleaching of the leather.

Furthermore, the temperature of the hydrogen peroxide bleaching liquid is 60-85 ℃, the interval between the rising and the falling of the lifting assembly is 10-30s, so that the frequency of spraying the hydrogen peroxide bleaching liquid towards the leather is high, and the bleaching efficiency and uniformity are better.

Further, the pre-treatment of the reaming comprises the following steps:

s11, firstly, soaking the leather in warm water for 15-30min, then taking out the leather and draining the floating water on the surface of the leather;

and S12, continuously and repeatedly cooling and heating the leather, so that the volume of water in the leather is continuously changed under the temperature change, and the hole expansion of the leather surface gap is realized.

Furthermore, the temperature change range in the temperature reduction and temperature rise treatment in the step S12 is 4-25 ℃, the temperature is above 4 ℃ according to the distance of expansion with heat and contraction with cold due to the particularity of water, and the temperature is between 0-4 ℃ in contrast, under the temperature change of 4-25 ℃, leather is not easy to harden, become brittle and crack due to too low temperature, meanwhile, water in the leather is not easy to evaporate rapidly due to too high temperature, the treatment time lasts for 20-30min, and the temperature change from high to low is completed for 1-2 times per minute.

Further, the hydraulic magnetic plate comprises a positioning plate and a liquid changing flat bag fixedly connected to one end, close to one end of each of the two positioning plates, of the liquid changing flat bag, the magnetic plate is fixedly connected to the joint of the liquid changing flat bag and the positioning plate, a plurality of silica gel balls are fixedly connected to the outer surface of the liquid changing flat bag, away from the magnetic plate, the positioning plate on the hydraulic magnetic plate above is fixedly connected with the inner wall of the bleaching box, and the positioning plate below is connected with the lifting assembly.

Further, silica gel ball internal fixation inlays and has the magnetic core, the magnetic core repels with the magnetic slab, when two pressure liquid magnetic slabs keep away from, lose behind the mutual extrusion force, a plurality of silica gel balls are repelled by the magnetic slab, thereby trade the liquid flat bag with higher speed and resume deformation, make its inside can be fast in the deformation in-process that resumes adsorbs hydrogen peroxide solution bleaching liquid, and a plurality of silica gel balls inter attraction on two pressure liquid magnetic slabs, when a plurality of silica gel balls are close to each other, adsorb each other, produce comparatively inseparable clamping action to the leather between the two, remove about controlling the leather through draw gear control this moment, can produce better extrusion friction effect to the leather surface, make hydrogen peroxide solution bleaching liquid's infiltration rate and homogeneity better.

Furthermore, the liquid change flat bag is of an elastic structure, so that after the liquid change flat bag is stressed, the liquid change flat bag can recover deformation after force is removed, and the end part of the liquid change flat bag connected with the silica gel ball is of a porous structure, so that hydrogen peroxide bleaching liquid can move inside and outside the liquid change flat bag before and after deformation.

Further, trade a plurality of evenly distributed's of liquid flat bag inner wall fixedly connected with long post of trading, trade the long post of liquid and including pressing variable end and fixed connection play liquid dish on trading the liquid flat bag, and go out liquid dish towards leather one side, go out the liquid dish and press to be connected with the inside lining release link between the tip in the variable end, when two pressure liquid magnetic plates extrude each other, hydrogen peroxide solution bleaching liquid in a plurality of long posts of trading is restrainted the form and sprays fast and go out, and its penetrating power and impact force are stronger, make the osmotic action to in the leather better, make the bleaching homogeneity better.

Further, the inside lining release link includes two longitudinal register poles and the four-way cage of fixed connection on longitudinal register pole, the four-way cage includes a plurality of fixed connection respectively at two longitudinal register pole tip and presses the node marble of variable end inner wall and a plurality of pressure of connecting between two vertical adjacent node marbles and becomes the strip, the inside lining release link is used for the supplementary speed of changing liquid long post deformation and recovering with higher speed, makes in the unit interval, presses the injection number of times that liquid magnetic sheet can go on the leather surface to be higher, and then is showing and accelerates bleaching efficiency.

Furthermore, press the strip to become for high elasticity high tenacity material makes, press the end to become for elastic seal structure, it is porous structure to go out the liquid dish.

3. Advantageous effects

Compared with the prior art, the invention has the advantages that:

(1) this scheme passes through reaming's preliminary treatment, make the hole obtain the expansion on the leather, when bleaching, the inside infiltration rate of hydrogen peroxide solution bleaching liquid is effectively quickened, cooperate the setting of pressure liquid magnetic plate simultaneously, through controlling its rebound, make the leather extruded between two pressure liquid magnetic plates, under the extrusion force effect, the hydrogen peroxide solution bleaching liquid of absorption in the pressure liquid magnetic plate overflows fast and is the injection form and spray on the leather surface, at the reciprocating in-process of continuous repetition pressure liquid magnetic plate, hydrogen peroxide solution bleaching liquid is constantly sprayed towards the leather surface, compare in the natural infiltration among the prior art, show the infiltration rate of accelerating hydrogen peroxide solution bleaching liquid in towards the leather, improve bleaching homogeneity and bleaching efficiency.

(2) Silica gel ball internal fixation inlays and has the magnetic core, the magnetic core repels with the magnetic slab each other, when two hydraulic pressure magnetic slabs keep away from, lose mutual extrusion force after, a plurality of silica gel balls are repelled by the magnetic slab, thereby trade the liquid flat bag with higher speed and resume deformation, make its inside can be fast in resuming the deformation in-process and adsorb hydrogen peroxide bleach solution, and a plurality of silica gel balls inter attraction on two hydraulic pressure magnetic slabs, when a plurality of silica gel balls are close to each other, mutual adsorption, produce comparatively inseparable clamping action to the leather between the two, remove about controlling the leather through draw gear this moment, can produce better extrusion friction effect to the leather surface, make hydrogen peroxide bleach solution's permeation rate and homogeneity better.

(3) The liquid-changing flat bag is of an elastic structure, so that deformation can be recovered after force is applied and the end part of the liquid-changing flat bag connected with the silica gel ball is of a porous structure, so that hydrogen peroxide bleaching liquid can move inside and outside the liquid-changing flat bag before and after deformation.

(4) Trade liquid flat bag inner wall fixedly connected with a plurality of evenly distributed's long post of trading, trade the long post of liquid including pressing to change end and fixed connection the play liquid dish on trading the liquid flat bag, and go out the liquid dish towards leather one side, it is connected with the inside lining release link with pressing between the end in the change end to go out the liquid dish, when two pressure liquid magnetic plates extrude each other, hydrogen peroxide solution bleaching liquid in a plurality of long posts of trading is restrainted form and sprays fast and go out, its penetrating power and impact force are stronger, it is better to make the osmotic action in the leather, it is better to make the bleaching homogeneity.

(5) The inside lining release link includes two longitudinal register poles and the four-way cage of fixed connection on longitudinal register pole, the four-way cage includes a plurality of respectively fixed connection at two longitudinal register pole tip and presses the node marble of variable end inner wall and a plurality of pressure of connecting between two vertical adjacent node marbles and becomes the strip, the inside lining release link is used for supplementary speed of changing liquid long post deformation recovery with higher speed, make in the unit interval, the injection number of times that the pressure liquid magnetic sheet can go on the leather surface is higher, and then show and accelerate bleaching efficiency.

Drawings

FIG. 1 is a schematic front view of a bleaching box according to the present invention;

FIG. 2 is a schematic view of the process of pre-treating leather according to the present invention;

FIG. 3 is a schematic view of the structure of two hydraulic-magnetic plates of the present invention pressed against each other;

FIG. 4 is a schematic structural view of a part of a hydraulic magnetic plate according to the present invention when hydrogen peroxide bleaching solution is sprayed onto leather;

FIG. 5 is a schematic structural view of a part of the two hydraulic magnetic plates after separation for absorbing hydrogen peroxide bleaching solution;

FIG. 6 is a schematic structural view of an end portion of a hydraulic fluid magnetic plate in embodiment 2 of the present invention;

FIG. 7 is a schematic three-dimensional structure of a liquid-changing long column according to the present invention;

FIG. 8 is a schematic structural view of a cross section of a liquid exchange long column according to the present invention;

fig. 9 is a schematic structural view of the inner hydrogen peroxide bleaching solution sprayed in a bundle shape after the liquid-changing long column is stressed.

The reference numbers in the figures illustrate:

1 locating plate, 3 liquid change flat sacs, 4 magnetic plates, 5 silica gel balls, 6 liquid change long columns, 61 pressure change ends, 62 liquid outlet discs, 7 longitudinal locating rods, 8 node marble balls and 9 pressure change bars.

Detailed Description

The drawings in the embodiments of the invention will be combined; the technical scheme in the embodiment of the invention is clearly and completely described; obviously; the described embodiments are only some of the embodiments of the invention; but not all embodiments, are based on the embodiments of the invention; all other embodiments obtained by a person skilled in the art without making any inventive step; all fall within the scope of protection of the present invention.

In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "top/bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus should not be construed as limiting the present invention. Furthermore, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.

In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "sleeved/connected," "connected," and the like are to be construed broadly, e.g., "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.

Example 1:

referring to fig. 1, wherein a represents leather, b represents a bleaching tank, c represents a lift assembly, d represents a pull roll, a leather bleaching process comprising the steps of:

s1, performing reaming pretreatment on the leather, then enabling the end part of the leather to penetrate through a plurality of traction rollers and two hydraulic magnetic plates which are symmetrical to each other, connecting the end part of the leather with a traction device, and injecting hydrogen peroxide bleaching liquid into a bleaching box;

referring to fig. 2, the pre-treatment of reaming includes the following steps:

s11, firstly, soaking the leather in warm water for 15-30min, then taking out the leather and draining the floating water on the surface of the leather;

s12, continuously and repeatedly carrying out cooling and heating treatment on the leather, so that the volume of water in the leather is continuously changed under the temperature change, and the hole expansion of the leather surface gap is realized;

s2, as shown in figure 4, the hydraulic magnetic plates below the lifting assembly are controlled to move upwards until the leather is extruded between the two hydraulic magnetic plates, and under the action of the extrusion force, the hydrogen peroxide bleaching solution adsorbed in the hydraulic magnetic plates quickly overflows and is sprayed on the surface of the leather in a spraying manner, so that the permeation of the hydrogen peroxide bleaching solution into the leather is accelerated;

s3, as shown in figure 5, the hydraulic magnetic plates below are controlled to move downwards through the lifting assembly, so that the two hydraulic magnetic plates are separated from each other, the end parts close to each other recover deformation to absorb hydrogen peroxide bleaching liquid, and the up-and-down movement of the hydraulic magnetic plates below is controlled repeatedly, so that the hydrogen peroxide bleaching liquid is sprayed towards the surface of the leather continuously;

and S4, after a period of time, drawing the bleached partial leather out of the bleaching box through a drawing device, rinsing for multiple times after the bleaching of all the leather is finished, and then drying to finish the bleaching of the leather.

The temperature of the hydrogen peroxide bleaching liquid is 60-85 ℃, the interval between the rising and the falling of the lifting component is 10-30S, the frequency of spraying the hydrogen peroxide bleaching liquid towards the leather is higher, the bleaching efficiency and the uniformity are better, the temperature change range in the temperature reduction and temperature rise treatment in the step S12 is 4-25 ℃, the temperature is above 4 ℃ according with the distance of expansion with heat and contraction with cold due to the particularity of water, the temperature is opposite to the temperature of 0-4 ℃, under the temperature change of 4-25 ℃, the leather is not easy to harden and become brittle and crack due to too low temperature, meanwhile, the water in the leather is not easy to evaporate rapidly due to too high temperature, the treatment time lasts for 20-30min, and the temperature change from high to low is completed for 1-2 times per minute.

Referring to fig. 3, the hydraulic magnetic plate comprises a positioning plate 1, a liquid-changing flat bag 3 fixedly connected to one end of the two positioning plates 1 close to each other, the liquid-changing flat bag 3 is of an elastic structure, so that after being stressed, the liquid-changing flat bag can recover deformation after force is removed, the end part of the liquid-changing flat bag 3 connected with a silica gel ball 5 is of a porous structure, so that hydrogen peroxide bleaching liquid can move inside and outside the liquid-changing flat bag 3 before and after deformation, a magnetic plate 4 is fixedly connected to the joint of the liquid-changing flat bag 3 and the positioning plate 1, a plurality of silica gel balls 5 are fixedly connected to the outer surface of the liquid-changing flat bag 3 away from the magnetic plate 4, the positioning plate 1 on the upper hydraulic magnetic plate is fixedly connected with the inner wall of the bleaching box, the positioning plate 1 on the lower side is connected with a lifting assembly, a magnetic core is fixedly embedded in the silica gel ball 5 and is repelled from the magnetic plate 4, when the two hydraulic magnetic plates are away from each other, the silica gel balls 5 are repelled by the magnetic plate 4 after mutual extrusion force is lost, thereby change liquid flat bag 3 with higher speed and resume deformation, make its inside can be fast recovering deformation in-process and adsorb hydrogen peroxide solution bleaching liquid, and a plurality of silica gel balls 5 inter attraction on two hydraulic pressure magnetic plates, when a plurality of silica gel balls 5 are close to each other, adsorb each other, produce comparatively inseparable clamping action to the leather between the two, remove about controlling the leather through draw gear this moment, can produce better extrusion friction effect to the leather surface, make hydrogen peroxide solution bleaching liquid's permeation rate and homogeneity better.

Through underreamed preliminary treatment, make the hole obtain the expansion on the leather, when bleaching, the inside infiltration rate of hydrogen peroxide solution bleaching liquid is effectively quickened, cooperate the setting of hydraulic magnetic plate simultaneously, through controlling its rebound, make the leather extruded between two hydraulic magnetic plates, under the extrusion force effect, the hydrogen peroxide solution bleaching liquid of absorption in the hydraulic magnetic plate overflows fast and is the form of spraying and spray on the leather surface, at the reciprocating in-process of continuous repetition hydraulic magnetic plate, hydrogen peroxide solution bleaching liquid constantly sprays towards the leather surface, compare in the natural infiltration among the prior art, show the infiltration rate of accelerating hydrogen peroxide solution bleaching liquid in towards the leather, improve bleaching homogeneity and bleaching efficiency.

Example 2:

referring to fig. 6-7, the inner wall of the liquid-changing flat bag 3 is fixedly connected with a plurality of liquid-changing long columns 6 which are uniformly distributed, each liquid-changing long column 6 comprises a pressing end 61 and a liquid outlet disc 62 fixedly connected to the liquid-changing flat bag 3, the pressing end 61 is an elastic sealing structure, the liquid outlet disc 62 is of a porous structure, the liquid outlet disc 62 faces one side of the leather, a lining reset rod is connected between the liquid outlet disc 62 and the top end of the pressing end 61, when the two liquid-changing long columns 6 are mutually extruded, hydrogen peroxide bleaching liquid in the liquid-changing long columns 6 is rapidly sprayed in a bundle shape, the penetrating power and the impact force are stronger, the penetrating action into the leather is better, the bleaching uniformity is better, and as shown in fig. 8, the lining reset rod comprises two longitudinal positioning rods 7 and a four-way cage fixedly connected to the longitudinal positioning rods 7, the four-way cage comprises a plurality of node bouncing balls 8 respectively fixedly connected to the end portions of the two longitudinal positioning rods 7 and the inner wall of the pressing end 61, and a plurality of two node bouncing balls 8 which are longitudinally adjacent Pressing between 9, pressing and changing 9 and making for high elasticity high tenacity material, like fig. 9, the inside lining release link is used for assisting the speed of changing liquid long column 6 deformation and recovering with higher speed, makes in the unit interval, and the injection number of times that the hydraulic pressure magnetic sheet can go on to the leather surface is higher, and then is showing and accelerate bleaching efficiency, after the atress, the four-way cage is vertically extrudeed, after losing pressure, its quick recovery deformation to thereby it resets and adsorbs hydrogen peroxide solution bleaching liquid fast to drive and change liquid long column 6.

In the embodiment, the liquid-changing long column 6 and the inner lining reset rod are additionally arranged, and the rest parts are consistent with the embodiment 1.

The above; but are merely preferred embodiments of the invention; the scope of the invention is not limited thereto; any person skilled in the art is within the technical scope of the present disclosure; the technical scheme and the improved concept of the invention are equally replaced or changed; are intended to be covered by the scope of the present invention.