烷烃到烯烃的氧化
阅读说明:本技术 烷烃到烯烃的氧化 (Oxidation of alkanes to alkenes ) 是由 R·A·佩里亚纳 B·G·哈士古驰 M·M·孔尼克 于 2018-05-25 设计创作,主要内容包括:本发明提供了一种将烷烃转化为烯烃的方法。该方法包括(a)在包含含氧酸和任选地一种或多种选自不可氧化的液体、盐添加剂、路易斯酸和水的添加剂的液体介质中使烷烃与(i)包含氧化形式的主族元素的氧化性亲电试剂接触,或与(ii)氧化剂和还原形式的氧化性亲电试剂接触,以提供氧化的中间体和还原形式的氧化性亲电试剂;(b)任选地将氧化的中间体和还原形式的氧化性亲电试剂分离;和(c)对氧化的中间体进行消除反应以提供烯烃和含氧酸。(The present invention provides a process for converting alkanes to alkenes. The method comprises (a) contacting an alkane with (i) an oxidizing electrophile comprising a main group element in an oxidized form, or with (ii) an oxidizing agent and a reduced form of the oxidizing electrophile, in a liquid medium comprising an oxoacid and optionally one or more additives selected from the group consisting of non-oxidizable liquids, salt additives, lewis acids, and water, to provide an oxidized intermediate and a reduced form of the oxidizing electrophile; (b) optionally separating the oxidized intermediate from the reduced form of the oxidizing electrophile; and (c) subjecting the oxidized intermediate to an elimination reaction to provide the olefin and the oxoacid.)
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