Ferrate oxidant composite spray-melting filter element and preparation thereof

文档序号:1495548 发布日期:2020-02-07 浏览:16次 中文

阅读说明:本技术 一种高铁酸盐氧化剂复合喷熔滤芯及其制备 (Ferrate oxidant composite spray-melting filter element and preparation thereof ) 是由 谷建辉 陈庆磊 任容科 郭璞 徐俊召 于 2019-10-24 设计创作,主要内容包括:本发明提供一种高铁酸盐氧化剂复合喷熔滤芯,滤芯采用复合材料制成,包括热塑性聚合物和高铁酸盐,按重量比例为1:(0.5-1);热塑性聚合物在110-150℃熔融,加入高铁酸盐,物料混合均匀后,经过喷丝、牵引、接受成形而制成的管状滤芯。本发明针对有机物污染浓度超标(排放标准)不多的排水而提供一种高铁酸盐氧化剂复合喷熔滤芯,将强氧化剂高铁酸盐复合到滤芯的基础丝状结构中,过滤中与水中的有机物进行氧化反应,从而除去有机物,失效后滤芯可以拆除更新。这种方法使用方便,适用于一般超标的废水及浓水。这种高铁酸盐氧化剂复合喷熔滤芯,可以装填到保安过滤器中使用,更换方便,去除COD的效率高,非常适用于一般超标的废水及浓水。(The invention provides a ferrate oxidant composite spray-melting filter element, which is made of composite materials and comprises a thermoplastic polymer and ferrate according to the weight ratio of 1 (0.5-1); the thermoplastic polymer is melted at the temperature of 110-150 ℃, ferrate is added, and the materials are uniformly mixed, and then the tubular filter element is prepared by spinning, drawing and receiving formation. The invention provides a ferrate and oxidant composite spray-melting filter element aiming at drainage with the organic matter pollution concentration exceeding the standard (emission standard), which is characterized in that ferrate, a strong oxidant, is compounded into a basic filamentous structure of the filter element, and is subjected to oxidation reaction with organic matters in water during filtration, so that the organic matters are removed, and the filter element can be detached and updated after failure. The method is convenient to use and is suitable for general overproof waste water and concentrated water. The ferrate oxidant composite spray-melting filter element can be filled into a cartridge filter for use, is convenient to replace, has high COD removal efficiency, and is very suitable for waste water and concentrated water which generally exceed the standard.)

1. A ferrate oxidant composite spray-melting filter element is characterized in that: the filter element is made of composite materials, wherein the composite materials comprise thermoplastic polymers and ferrate according to the weight ratio of 1 (0.5-1).

2. The ferrate-oxidant composite spray-melt filter element of claim 1, wherein: the ferrate is one of potassium ferrate and sodium ferrate.

3. The ferrate-oxidant composite spray-melt filter element of claim 1, wherein: the thermoplastic polymer adopts one of EMA (ethylene-methyl acrylate copolymer) and EVA (ethylene-vinyl acetate copolymer).

4. The ferrate-oxidant composite spray-melt filter element of claim 1, wherein: the ferrate is powder with 100-160 meshes.

5. The ferrate-oxidant composite spray-melt filter element of claim 1, wherein: the filtering precision of the filter element is 200 mu m.

6. A ferrate-oxidant complex spray-fused filter element according to any one of claims 1 to 5, prepared by: melting the thermoplastic polymer at 110-150 ℃, adding ferrate, stirring and mixing, and after the materials are uniform, performing spinning, drawing and shaping through a filter element production line to prepare the tubular filter element.

Technical Field

The technical field relates to the field of industrial water treatment and wastewater treatment, in particular to a ferrate oxidant composite spray-melting filter element.

Background

Along with the development of social economy, the high-efficiency cyclic utilization of water and the high standard requirement of wastewater discharge in industrial production lead the water treatment technology to develop towards the recovery of high-efficiency water and wastewater, the process foundation is that the water is concentrated, fresh water is recovered, and concentrated water is discharged, so another problem is caused, namely, the concentration of organic pollutants in the discharged concentrated water is increased, biological treatment cannot be carried out due to the high salt content of the concentrated water, evaporative crystallization can effectively solve the problem, but the high investment and operation cost limit the common use of the technology, other physical and chemical methods are mostly selected for treatment at present, such as strong oxidant oxidation, fenton, electrochemical fenton, photocatalysis, wet oxidation and the like, which are methods frequently selected for high-difficulty organic wastewater, but for the wastewater with the excessive organic pollution concentration (discharge standard), the above methods are uneconomical and expensive to invest in and operate.

Disclosure of Invention

The invention aims to provide a ferrate and oxidant composite spray-melting filter element, which is characterized in that ferrate as a strong oxidant is compounded into a basic filamentous structure of the filter element, and is subjected to oxidation reaction with organic matters in water during filtering, so that the organic matters are removed, and the filter element can be detached and updated after failure, is convenient to use, and is suitable for general overproof waste water and concentrated water. The filter element is simple to manufacture, the raw materials are easy to obtain, the finished product is safe and convenient to store and transport, and the use is simple and reliable.

In order to achieve the purpose, the invention adopts the following technical scheme:

a ferrate and oxidant composite spray-melting filter element is prepared from composite material including thermoplastic polymer and ferrate in a weight ratio of 1 (0.5-1).

The ferrate is one of potassium ferrate and sodium ferrate, and the ferrate is powder solid with 100 meshes and 160 meshes.

The thermoplastic polymer is one of EMA (ethylene-methyl acrylate copolymer) and EVA (ethylene-vinyl acetate copolymer).

The filtering precision of the filter element is 200 mu m.

Melting the thermoplastic polymer at 110-150 ℃, adding ferrate, stirring and mixing, and after the materials are uniform, performing spinning, drawing and shaping through a filter element production line to prepare the tubular filter element.

The invention has the beneficial effects that: the invention provides a ferrate and oxidant composite spray-melting filter element aiming at drainage with the organic matter pollution concentration exceeding the standard (emission standard), which is characterized in that ferrate, a strong oxidant, is compounded into a basic filamentous structure of the filter element, and is subjected to oxidation reaction with organic matters in water during filtration, so that the organic matters are removed, and the filter element can be detached and updated after failure. The method is convenient to use and is suitable for general overproof waste water and concentrated water. The ferrate oxidant composite spray-melting filter element can be filled into a cartridge filter for use, is convenient to replace, has high COD removal efficiency, and is very suitable for waste water and concentrated water which generally exceed the standard.

Detailed Description

A ferrate oxidant composite spray-melting filter element is characterized in that: the filter element is made of composite materials, and the raw materials of the filter element comprise thermoplastic polymers and ferrate according to the weight ratio of 1 (0.5-1).

The ferrate is one of potassium ferrate and sodium ferrate, and the ferrate is powder solid with 100 meshes and 160 meshes.

The thermoplastic polymer is one of EMA (ethylene-methyl acrylate copolymer) and EVA (ethylene-vinyl acetate copolymer).

The filtering precision of the filter element is 200 mu m.

Melting the thermoplastic polymer at 110-150 ℃, adding ferrate, stirring and mixing, and after the materials are uniform, performing spinning, drawing and shaping through a filter element production line to prepare the tubular filter element.

The present invention will be further described with reference to the following embodiments.

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