阅读说明：本技术 一种功能陶瓷体及其制备方法与应用 (A kind of function ceramics body and the preparation method and application thereof ) 是由 卜钿杰 于 2019-07-25 设计创作，主要内容包括：本发明涉及一种功能陶瓷体,功能陶瓷体的内部稳定地保存有功能性分子颗粒,功能性分子颗粒包括第一功能性有机分子颗粒和第二功能性有机份子颗粒；功能陶瓷体的内部具有正电位微孔,第一功能性有机分子颗粒和第二功能性有机分子颗粒至少部分的处于正电位位置；第一有机分子颗粒为小分子有机分子颗粒,第二有机分子颗粒为大分子有机分子颗粒。本发明通过将大分子有机分子颗粒和小分子有机分子颗粒稳定地复合进陶瓷基材内,形成结构稳定、性能优越的功能陶瓷体,克服单一释放一种功能物质的缺点,且有机分子颗粒的释放速度和扩散效果更好。(The present invention relates to a kind of function ceramics body, functional molecular particle is preserved to the internal stability of function ceramics body, functional molecular particle includes the first functional organic molecules particle and second functional organic one's share of expenses for a joint undertaking particle；The inside of function ceramics body has positive potential micropore, and the first functional organic molecules particle and the second functional organic molecules particle are at least part of in positive potential position；First organic molecule particle is small organic molecule particle, and the second organic molecule particle is macromolecular organic molecule particle.The present invention passes through macromolecular organic molecule particle and small organic molecule is particle stabilizedly compound into ceramic base material, form the function ceramics body of stable structure, superior performance, overcome a kind of single the shortcomings that discharging functional mass, and the rate of release of organic molecule particle and diffusion effect are more preferable.)

1. a kind of function ceramics body, which is characterized in that preserve functional molecular to the internal stability of the function ceramics body Grain, the functional molecular particle include the first functional organic molecules particle and second functional organic one's share of expenses for a joint undertaking particle；

The inside of the function ceramics body has positive potential micropore, the first functional organic molecules particle and second function Energy property organic molecule particle is at least part of to be in the micro well locations；

Wherein, the first functional organic molecules particle is small organic molecule particle, and described second is organic point functional Sub- particle is macromolecular organic molecule particle.

2. function ceramics body according to claim 1, it is characterised in that: every cubic metre of function ceramics body is steadily protected The mass ratio for depositing the first functional organic molecules particle and the second functional organic molecules particle is 0.21-4.88.

3. function ceramics body according to claim 2, it is characterised in that: the first functional organic molecules particle is function Energy property vitamin particles, the second functional organic molecules particle are functional protein particle.

4. function ceramics body according to claim 3, it is characterised in that: every cubic metre of function ceramics body is steadily protected The mass ratio for depositing the first functional organic molecules particle and the second functional organic molecules particle is 0.68-3.1.

5. function ceramics body according to claim 4, it is characterised in that: every cubic metre of functional vitamin particle Quality is 16-78g, and the quality of the functional protein particle is 16-78g.

6. according to function ceramics body as claimed in claim 3 to 5, it is characterised in that: the functional molecular particle is by described First functional organic molecules particle and second functional organic one's share of expenses for a joint undertaking particle composition.

7. according to any function ceramics body of claim 3-6, it is characterised in that: first functional organic molecules Grain and the second organic molecule particle can be released from the inside of the function ceramics body under the driving of anion, and its The speed released and the negative ion amount are positively correlated.

8. function ceramics body according to claim 7, it is characterised in that: when the negative ion amount is in 300-2000W ion/ m²When, the functional vitamin particle releases to be sustained, in an amount of from 0.5-3.2mg/h*m², and the functional protein Particle releases to be sustained, in an amount of from 0.3-2.5mg/h*m²。

9. a kind of preparation method of function ceramics body, the preparation method are used to prepare as described in any one of claims 1-8 Function ceramics body, comprising the following steps:

(1) material containing the functional molecular particle is mixed with cellulose powder, foaming agent and plastotype agent, in Muffle furnace In toasted, obtain the powder body material containing the functional molecular particle；

(2) powder body material is dissolved in the double solvents containing alcohol and acetone, being sufficiently stirred makes the powder body material It is uniformly distributed in the double solvents, forms mixed solution；

(3) ceramic matrix is immersed in the mixed solution, external pressurized to 1.2-2 standard atmospheric pressure, continues 20-24h；

(4) the aging 1-2h in 40-55 DEG C of oven of the ceramic matrix after pressurizeing will be submerged, is obtained containing the functional molecular particle Function ceramics body.

10. a kind of hair drier, including machine shell, heating wire, fan and anion generator, the anion generator with Ceramic body is equipped between the air outlet of the machine shell, it is characterised in that: the ceramic body is any described in claim 1-8 Function ceramics body；The anion generator generates anion and blows over the function ceramics body under the driving of the fan At least surface portion, to drive the intracorporal functional molecular particle of the function ceramics to release.

Technical field

The present invention relates to technical field of functional ceramics, in particular to a kind of function ceramics body and the preparation method and application thereof.

Background technique

Hair dryer is composed of one group of resistance wire and one high revolving speed small fan, is provided not by motor speed With the outlet air of intensity, temperature is usually to be powered to generating heat according to heater, heats outlet air.Hair dryer is widely used in the dry of hair Dry and shaping, but also make local desiccation, heating and physical therapy for laboratory, psyciotherapy room and industrial production, art designing etc. and be used. The heater of hair dryer is usually resistance wire in the prior art, but there are frequent operations to be easily damaged using Resistant heating, The not high problem of electric conversion rate.With the continuous improvement of people's quality of life, produces add ceramic be used as in the prior art Hot cell or ceramic body structure are fixed in hair dryer, to discharge far infrared or anion etc., but in the prior art The function for the ceramic body that hair dryer uses is more single, is not able to satisfy the growing diversified demand of people.

Function ceramics refers to the material that its non-mechanical property is mainly utilized in application, such as electricity, magnetic, light, heat, chemistry, life Object etc. usually merges a kind of substance in the prior art, therefore function ceramics body h substance is single, although realizing a variety of Substance fusion enters ceramic body, but (for example multiple larger molecular organics or multiple small molecules have the release between its many kinds of substance The fusion of machine object enters ceramic body) it is easy to cause many kinds of substance to interfere with each other, finally influence mutual rate of release and diffusion effect.

Summary of the invention

It is an object of the invention to overcome the deficiencies of existing technologies, a kind of stable structure, h substance multiplicity are provided and released Put better function ceramics body of effect and the preparation method and application thereof.

First aspect present invention provides a kind of function ceramics body, saves to the internal stability of the function ceramics body active Energy property molecule particles, the functional molecular particle include the first functional organic molecules particle and second functional organic one's share of expenses for a joint undertaking Particle；

The inside of the function ceramics body has positive potential micropore, the first functional organic molecules particle and described the Two functional organic molecules particles are at least part of to be in the micro well locations；

Wherein, the first functional organic molecules particle is small organic molecule particle, second organic molecule Particle is macromolecular organic molecule particle.

The present invention passes through macromolecular organic molecule particle and small organic molecule is particle stabilizedly compound into ceramic base In material, the function ceramics body of stable structure, superior performance is formed, overcomes a kind of single the shortcomings that discharging functional mass, and it compares The rate of release and diffusion effect of much molecule particles compounds or more small molecule particle composites are more preferable.

Further, every cubic metre of function ceramics body steadily save the first functional organic molecules particle with The mass ratio of second functional organic molecules particle is 0.21-4.88.

Further, the first functional organic molecules particle is functional vitamin particle, and described second is functional Organic molecule particle is functional protein particle.

Further, every cubic metre of function ceramics body steadily save the first functional organic molecules particle with The mass ratio of second functional organic molecules particle is 0.68-3.1.

Further, the quality of every cubic metre of functional vitamin particle is 16-78g, the functional protein The quality of grain is 16-78g.

Further, the functional molecular particle is by the first functional organic molecules particle and second function Property organic one's share of expenses for a joint undertaking particle composition.

Further, the first functional organic molecules particle and the second organic molecule particle can be in anions It is released from the inside of the function ceramics body under driving, and its speed released is positively correlated with the negative ion amount.

Further, when the negative ion amount is in 300-2000W ion/m²When, the functional vitamin particle is released It is out sustained release, in an amount of from 0.5-3.2mg/h*m², and the functional protein particle release for sustained release, in an amount of from 0.3- 2.5mg/h*m²。

Second aspect of the present invention, provides a kind of preparation method of function ceramics body, and the preparation method is used to prepare as above The function ceramics body, comprising the following steps:

(1) material containing the functional molecular particle is mixed with cellulose powder, foaming agent and plastotype agent, in horse It is not toasted in furnace, obtains the powder body material containing the functional molecular particle；

(2) powder body material is dissolved in the double solvents containing alcohol and acetone, being sufficiently stirred makes the powder Material is uniformly distributed in the double solvents, forms mixed solution；

(3) ceramic matrix is immersed in the mixed solution, external pressurized to 1.2-2 standard atmospheric pressure, continues 20- 24h；

(4) the aging 1-2h in 40-55 DEG C of oven of the ceramic matrix after pressurizeing will be submerged, is obtained containing the functional molecular The function ceramics body of particle.

Third aspect present invention provides a kind of hair drier, including machine shell, heating wire, fan and anion generator, Ceramic body is equipped between the anion generator and the air outlet of the machine shell, it is characterised in that: the ceramic body is Function ceramics body as described above；The anion generator generates anion and blows over the function under the driving of the fan At least surface portion of energy ceramic body, to drive the intracorporal functional molecular particle of the function ceramics to release.

The present invention at least has the advantages that by by macromolecular organic molecule particle and small organic molecule Grain is steadily compound to form the function ceramics body of stable structure, superior performance into ceramic base material, overcomes and single discharges a kind of function Can substance the shortcomings that, and it is than much molecule particles compounds or the rate of release and diffusion effect of more small molecule particle composites More preferably；The function ceramics body is applied in hair dryer, by the driving effect of anion in hair dryer, by functional vitamin or Functional protein is derived from ceramic excited inside, be discharged into air, act on user after realize more diversified health care Effect, and its realize more evenly, more linear rate of release and burst size, the use feeling of user it is more preferable.

Detailed description of the invention

Fig. 1 is the surface texture schematic diagram of function ceramics body of the present invention；

Fig. 2 is the preparation embodiment flow diagram of function ceramics body of the present invention；

Specific embodiment

Technical solution of the present invention is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation Example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill Personnel's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.

In the description of the present invention, it should be noted that term " center ", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" be based on the orientation or positional relationship shown in the drawings, merely to Convenient for description the present invention and simplify description, rather than the device or element of indication or suggestion meaning must have a particular orientation, It is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.In addition, term " first ", " second ", " third " is used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance.

In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected；It can To be mechanical connection, it is also possible to be electrically connected；It can be directly connected, can also can be indirectly connected through an intermediary Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood at this with concrete condition Concrete meaning in invention.

Referring to Fig. 1, for a kind of internal structure signal of function ceramics body of the present invention, the internal stability of the function ceramics body Functional molecular particle is preserved on ground, and the functional molecular particle includes the first functional organic molecules particle and the second function The organic one's share of expenses for a joint undertaking particle of property；The first organic molecule particle is small organic molecule particle, the second organic molecule particle For macromolecular organic molecule particle.Preferably, the functional molecular particle is by the first organic molecule particle and described Two organic molecule particles composition.By the way that macromolecular organic molecule particle and small organic molecule is particle stabilizedly compound into pottery In porcelain substrate, the function ceramics body of stable structure, superior performance is formed, a kind of single the shortcomings that discharging functional mass is overcome, and It is more preferable than the rate of release and diffusion effect of much molecule particles compounds or more small molecule particle composites.

As shown in Figure 1, the inside of the function ceramics body has micropore 1, which is in positive potential, this is because selection The structure of function ceramics composition make it with spontaneous polarization effect, macro manifestations are that surrounding is deposited there are electrostatic field and always It is not being influenced and is being disappeared by the external world, can be hydroxide ion and hydrogen ion by the water decomposition of surrounding, hydrogen ion obtains micro- electricity What stream provided electronically forms hydrogen, then the surface of micropore then loses electronics or with obvious discrete trend in function ceramics body, So that the micropore of function ceramics body is in positive potential.So, the first functional organic molecules particle and second function Property organic molecule particle is in positive potential position and is then in positive potential position.Therefore, the first functional organic molecules particle Being in positive potential position with the second functional organic molecules particle can be under the driving of anion from the function ceramics body It is released in inside.

Preferably, every cubic metre of function ceramics body contains the first functional organic molecules particle and the second functionality and has The mass ratio of machine molecule particles is 0.21-4.88.When its ratio is too low or excessively high, the functional effect of corresponding function molecule is influenced Release.However this is only one of influence factor, at least, when the first functional organic molecules are organic point functional relative to second When sub- granular mass is excessively high, small molecule organic granular easily forms reuniting effect, this aspect shadow on macromolecular organic granular surface The release to particle and diffusion effect are rung, the realization of itself function of macromolecular organic granular is on the other hand also influenced.Therefore, The mass ratio of one functional organic molecules particle and the second functional organic molecules particle is more preferably 0.68-3.1 (such as functionality Vitamin particles and functional protein particle).

Preferably, the first organic molecule particle is functional vitamin particle, and the second organic molecule particle is Functional protein particle, functional vitamin and functional protein, which are released, generates beneficial effect to human body.Further, preferably often The quality of cubic meter functional vitamin particle is 16-78g, and the quality of functional protein particle is 16-78g, such quality Rate of release and the release that the first organic molecule particle and the second organic molecule particle can be made to have more evenly, more linear are set Amount.Preferably, the functional vitamin is vitamin C, and the functional protein is collagen.

The functional vitamin particle and the functional protein particle can be under the drivings of anion from the function It is released in the inside of ceramic body, the functional vitamin particle and functional protein particle is released from function ceramics body, To realize health-care effect.The composition of the functional vitamin, the functional protein and the two is from the function ceramics The speed released in body is related to the quality of composition unit area of functional vitamin, functional protein and the two, if The quality of the composition of the functional vitamin of unit area, functional protein and the two is too low, anion can not drive its from It is released inside functionality ceramic body, if the matter of the composition of the functional vitamin of unit area, functional protein and the two Measure it is excessively high, may result in anion directly functional vitamin, functional protein and the two composition save location Nearby directly neutralize.

Preferably, when negative ion amount is in a certain range, the functional vitamin particle, the functional protein particle The speed released from the function ceramics body and the negative ion amount are positively correlated.When the negative ion amount is in 300-2000W ion/m²When, the functional vitamin particle releases to be sustained, in an amount of from 0.5-3.2mg/h*m².When the negative ion amount In 300-2000W ion/m²When, the functional protein particle releases to be sustained, in an amount of from 0.3-2.5mg/h*m², this is slow The amount of releasing is that ensure that the functional effect that functional vitamin particle and functional protein release not will cause waste again.

The invention further relates to a kind of hair driers, including machine shell, heating wire, fan and anion generator, described The function ceramics body is equipped between anion generator and the air outlet of the machine shell；The anion generator generates big Anion is measured, the anion blows over the surface of the function ceramics body under the driving of the fan, and drives the function The intracorporal functional vitamin of ceramics, functional protein release.

Set experimental condition are as follows: when the negative ion amount is in 300-2000W ion/m²When, every square meter Victoria C and every square meter glue The sustained release amount of former albumen is as shown in the table:

Referring to attached drawing 2, by taking functional vitamin particle and functional protein particle as an example, illustrate function ceramics body of the present invention Preparation method step:

(1) material (such as seaweed, fruits and vegetables) of the functional vitamin particle will be contained and containing the functional egg The material (such as skin or squama of aquatic livestock) of white particle, mixes, cellulose powder with cellulose powder, foaming agent and plastotype agent For methylcellulose or hydroxyethyl cellulose, foaming agent is lauroyl chloride or lauryl amine, and plastotype agent is citrate, in Muffle furnace In toasted, obtain the powder body material containing functional vitamin and functional protein；

(2) powder body material is dissolved in the double solvents containing alcohol and acetone, being sufficiently stirred makes the powder Material is uniformly distributed in the double solvents, forms mixed solution；

(3) ceramic matrix is immersed in mixed solution, external pressurized to 1.2-2 standard atmospheric pressure, continues 20-24h；

(4) the aging 1-2h in 40-55 DEG C of oven of the ceramic matrix after pressurizeing will be submerged again, is obtained containing the functional dimension The function ceramics body of raw crude granule and the functional protein particle.

Just using functional vitamin particle in the function ceramics body of preparation method production and functional protein particle Potential distribution is more evenly, more advantageous for the sustained release of functional vitamin particle and functional protein particle.

More than, function pottery is formed by stablizing to be compound in ceramic body macromolecular organic granular and small molecule organic granular Porcelain body, which is applied in hair dryer, by the driving effect of anion in hair dryer, by functional vitamin or Functional protein is derived from ceramic excited inside, be discharged into air, act on user after realize more diversified health care Effect, and its realize more evenly, more linear rate of release and burst size, the use feeling of user it is more preferable.

The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention, It should be equivalent substitute mode, be included within the scope of the present invention.