阅读说明：本技术 一种促进白酒陈化的陶瓷材料及其制备方法 (Ceramic material for promoting aging of white spirit and preparation method thereof ) 是由 袁勇 袁航 于 2021-08-05 设计创作，主要内容包括：本发明公开了一种促进白酒陈化的陶瓷材料,由按质量份计的下列组分制成：氧化锆5-60份、氧化锰3-15份、氧化镉2-20份、氧化铁10-50份、紫砂土20-90份、氧化锌3-20份、纳米氧化锆2-80份、纳米二氧化钛10-80份、氧化钴2-20份；按质量配比称取原料,加适量水配制成浆料,然后陈化,练泥得到泥料；将泥料加入挤出成型装置中挤出成型,采用多孔蜂窝挤出模具挤出,然后切割得到多孔坯体,或者直接挤出柱状坯体,然后通过打孔模具在柱状坯体上打孔得到多孔坯体；将多孔坯体烧制成多孔陶瓷。本发明利用尖晶石类矿物结构产生远红外射线,远红外效应加快白酒陈化,而且可以吸附白酒的辛辣味、涩味,改善香型和口感。(The invention discloses a ceramic material for promoting white spirit aging, which is prepared from the following components in parts by mass: 5-60 parts of zirconium oxide, 3-15 parts of manganese oxide, 2-20 parts of cadmium oxide, 10-50 parts of iron oxide, 20-90 parts of purple clay, 3-20 parts of zinc oxide, 2-80 parts of nano zirconium oxide, 10-80 parts of nano titanium dioxide and 2-20 parts of cobalt oxide; weighing raw materials according to the mass ratio, adding a proper amount of water to prepare slurry, then aging, and pugging to obtain pug; adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous green body, or directly extruding a columnar green body, and then punching the columnar green body by using a punching die to obtain the porous green body; and firing the porous body into porous ceramic. The invention utilizes spinel mineral structure to generate far infrared ray, the far infrared effect accelerates the aging of the white spirit, and the invention can absorb the pungency and astringency of the white spirit, and improve the fragrance and taste.)

1. The ceramic material for promoting the aging of the white spirit is characterized by being prepared from the following components in parts by mass: 5-60 parts of zirconium oxide, 3-15 parts of manganese oxide, 2-20 parts of cadmium oxide, 10-50 parts of iron oxide and 20-90 parts of purple clay.

2. The ceramic material for promoting aging of white spirit according to claim 1, further comprising: 3-20 parts of zinc oxide, 2-80 parts of nano zirconia, 10-80 parts of nano titanium dioxide and 2-20 parts of cobalt oxide.

3. A method for preparing a ceramic material for promoting white spirit aging according to claim 1 or 2, which is characterized by comprising the following steps:

step one, weighing raw materials according to a mass ratio, adding a proper amount of water to prepare slurry, then aging, and pugging to obtain pug;

adding the pug into extrusion molding for extrusion molding, extruding by adopting a porous honeycomb extrusion die, cutting to obtain a porous green body, or directly extruding a columnar green body, and then punching the columnar green body by using a punching die to obtain the porous green body;

and step three, firing the porous blank into porous ceramic.

4. A method for promoting white spirit aging is characterized in that excited porous ceramic is added into a white spirit aging tank, and white spirit is added for aging in a sealed mode.

5. A method for promoting yellow wine aging is characterized in that excited porous ceramic is added into a yellow wine aging tank, and white spirit is added for aging in a sealed manner.

6. A method for promoting vinegar aging is characterized in that excited porous ceramic is added into a vinegar aging tank, and vinegar is added for aging in a sealed manner.

Technical Field

The invention belongs to the technical field of functional ceramics, and particularly relates to a ceramic material for promoting white spirit aging and a preparation method thereof.

Background

China is a big country for liquor consumption, and the liquor needs to be aged after being brewed, so that the ageing time and the taste of the liquor are greatly different, and the price of the liquor in different years is also greatly different. How to shorten the aging time of the white spirit and improve the taste is the research direction of the continuous efforts of the white spirit industry. The ceramic is commonly used as a container for aging the white spirit, does not influence the quality of the white spirit, and is beneficial to keeping the taste of the white spirit.

The ceramic catalyst is a functional ceramic widely applied in the chemical industry, but the report of using the ceramic catalyst as a white spirit aging promoting material is not seen yet. The ceramic has different components and characteristics, and the aging of the white spirit can be influenced by the characteristics of the ceramic catalyst due to the reasonable design of the ceramic formula.

Disclosure of Invention

The invention aims to provide a ceramic material for promoting white spirit aging and a preparation method thereof, wherein the porous ceramic is prepared and added into the white spirit to promote white spirit aging, shorten aging time and improve the taste of the white spirit.

The invention is realized by the following technical scheme: a ceramic material for promoting white spirit aging is prepared from the following components in parts by mass: 5-60 parts of zirconium oxide, 3-15 parts of manganese oxide, 2-20 parts of cadmium oxide, 10-50 parts of iron oxide and 20-90 parts of purple clay.

Further preferably, the method further comprises: 3-20 parts of zinc oxide, 2-80 parts of nano zirconia, 10-80 parts of nano titanium dioxide and 2-20 parts of cobalt oxide.

A preparation method of a ceramic material for promoting white spirit aging comprises the following steps:

step one, weighing raw materials according to a mass ratio, adding a proper amount of water to prepare slurry, then aging, and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, cutting to obtain a porous green body, or directly extruding a columnar green body, and then punching the columnar green body by using a punching die to obtain the porous green body;

and step three, firing the porous blank into porous ceramic.

The invention also provides a method for promoting the aging of the white spirit, which is to add the excited porous ceramic into a white spirit aging tank, add the white spirit, seal and age the mixture.

The invention also provides a method for promoting the aging of the yellow wine, which is to add the excited porous ceramic into a yellow wine aging tank, add the white wine and seal the mixture for aging.

The invention also provides a method for promoting vinegar aging, which is characterized in that activated porous ceramic is added into a vinegar aging tank, and vinegar is added for aging in a sealed manner.

The invention has the beneficial effects that: the ceramic formula is reasonably designed to prepare porous ceramic which is used as a catalyst, a spinel mineral structure is utilized to generate far infrared rays, the ageing of white spirit is accelerated by the far infrared effect, and the porous ceramic can absorb the pungency and the astringency of the white spirit. The white spirit aged by the porous ceramic has obviously increased ether content and improved fragrance and taste.

Detailed Description

The present invention is described below with reference to examples, and it should be understood that the examples described herein are only for illustrating and explaining the present invention and are not intended to limit the present invention.

Example 1

Step one, weighing the following raw materials in parts by mass: 5 parts of zirconium oxide, 15 parts of manganese oxide, 5 parts of cadmium oxide, 60 parts of iron oxide, 60 parts of purple sandy soil, 17 parts of zinc oxide, 8 parts of nano zirconium oxide, 10 parts of nano titanium dioxide and 20 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank; (ii) a

And step three, firing the porous blank into porous ceramic.

Example 2

Step one, weighing the following raw materials in parts by mass: 10 parts of zirconium oxide, 10 parts of manganese oxide, 15 parts of cadmium oxide, 50 parts of iron oxide, 55 parts of purple clay, 20 parts of zinc oxide, 5 parts of nano zirconium oxide, 20 parts of nano titanium dioxide and 15 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 3

Step one, weighing the following raw materials in parts by mass: 15 parts of zirconium oxide, 13 parts of manganese oxide, 2 parts of cadmium oxide, 55 parts of ferric oxide, 50 parts of purple sandy soil, 20 parts of zinc oxide, 5 parts of nano zirconium oxide, 30 parts of nano titanium dioxide and 10 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 4

Step one, weighing the following raw materials in parts by mass: 20 parts of zirconium oxide, 10 parts of manganese oxide, 15 parts of cadmium oxide, 40 parts of ferric oxide, 45 parts of purple clay, 10 parts of zinc oxide, 5 parts of nano zirconium oxide, 40 parts of nano titanium dioxide and 15 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 5

Step one, weighing the following raw materials in parts by mass: 25 parts of zirconium oxide, 10 parts of manganese oxide, 10 parts of cadmium oxide, 40 parts of ferric oxide, 35 parts of purple clay, 10 parts of zinc oxide, 5 parts of nano zirconium oxide, 50 parts of nano titanium dioxide and 15 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 6

Step one, weighing the following raw materials in parts by mass: preparing slurry by adding a proper amount of water into 35 parts of zirconium oxide, 9 parts of manganese oxide, 11 parts of cadmium oxide, 30 parts of iron oxide, 43 parts of purple sandy soil, 11 parts of zinc oxide, 5 parts of nano zirconium oxide, 45 parts of nano titanium dioxide and 11 parts of cobalt oxide, aging, and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 7

Step one, weighing the following raw materials in parts by mass: : preparing slurry by adding a proper amount of water into 35 parts of zirconium oxide, 9 parts of manganese oxide, 11 parts of cadmium oxide, 30 parts of iron oxide, 43 parts of purple sandy soil, 11 parts of zinc oxide, 5 parts of nano zirconium oxide, 45 parts of nano titanium dioxide and 11 parts of cobalt oxide, aging, and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, directly extruding a columnar blank, and then punching the columnar blank through a punching die to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 8

Step one, weighing the following raw materials in parts by mass: 45 parts of zirconium oxide, 5 parts of manganese oxide, 20 parts of cadmium oxide, 15 parts of iron oxide, 30 parts of purple clay, 10 parts of zinc oxide, 5 parts of nano zirconium oxide, 60 parts of nano titanium dioxide and 10 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 9

Step one, weighing the following raw materials in parts by mass: 50 parts of zirconium oxide, 5 parts of manganese oxide, 10 parts of cadmium oxide, 20 parts of ferric oxide, 25 parts of purple clay, 7 parts of zinc oxide, 5 parts of nano zirconium oxide, 70 parts of nano titanium dioxide and 8 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 10

Step one, weighing the following raw materials in parts by mass: 55 parts of zirconium oxide, 8 parts of manganese oxide, 10 parts of cadmium oxide, 12 parts of ferric oxide, 27 parts of purple clay, 3 parts of zinc oxide, 5 parts of nano zirconium oxide, 75 parts of nano titanium dioxide and 5 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 11

Step one, weighing the following raw materials in parts by mass: 60 parts of zirconium oxide, 3 parts of manganese oxide, 12 parts of cadmium oxide, 10 parts of iron oxide, 20 parts of purple clay, 11 parts of zinc oxide, 2 parts of nano zirconium oxide, 80 parts of nano titanium dioxide and 2 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 12

Step one, weighing the following raw materials in parts by mass: 60 parts of zirconium oxide, 3 parts of manganese oxide, 12 parts of cadmium oxide, 10 parts of iron oxide and 20 parts of purple clay, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 13

Step one, weighing the following raw materials in parts by mass: 45 parts of zirconium oxide, 5 parts of manganese oxide, 20 parts of cadmium oxide, 15 parts of iron oxide and 30 parts of purple clay are added with a proper amount of water to prepare slurry, and then the slurry is aged and pugged to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 14

Step one, weighing the following raw materials in parts by mass: adding a proper amount of water into 35 parts of zirconium oxide, 9 parts of manganese oxide, 11 parts of cadmium oxide, 30 parts of ferric oxide and 43 parts of purple sandy soil to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

Example 15

Step one, weighing the following raw materials in parts by mass: 5 parts of zirconium oxide, 15 parts of manganese oxide, 5 parts of cadmium oxide, 60 parts of iron oxide, 60 parts of purple sandy soil, 17 parts of zinc oxide, 8 parts of nano zirconium oxide, 10 parts of nano titanium dioxide and 20 parts of cobalt oxide, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank; (ii) a

And step three, firing the porous blank into porous ceramic.

Example 16

Step one, weighing the following raw materials in parts by mass: 15 parts of zirconium oxide, 13 parts of manganese oxide, 2 parts of cadmium oxide, 55 parts of iron oxide and 50 parts of purple sandy soil, adding a proper amount of water to prepare slurry, and then aging and pugging to obtain pug;

adding the pug into an extrusion molding device for extrusion molding, extruding by adopting a porous honeycomb extrusion die, and then cutting to obtain a porous blank;

and step three, firing the porous blank into porous ceramic.

A white spirit aging experiment was performed using the porous ceramics obtained in examples 1 to 16, using a white spirit aging tank to which 100g of the porous ceramics was added per kg of white spirit for 4 months, and the results are shown in the following table:

item	Mouthfeel before aging	Taste after aging
			Blank sample	Poor astringent taste	Poor astringent taste
Example 1	Poor astringent taste	Mellow, soft and soft
			Example 2	Poor astringent taste	Delicate fragrance
Example 3	Poor astringent taste	Mellow, soft and soft
			Example 4	Poor astringent taste	Obvious old fragrance
Example 5	Poor astringent taste	Strong cellar fragrance
			Example 5	Poor astringent taste	Lingering aftertaste
Example 6	Poor astringent taste	Mellow and full
			Example 7	Poor astringent taste	Endless afternoon
Example 8	Poor astringent taste	The old fragrance is outstanding
			Example 9	Poor astringent taste	Full of fragrance
Example 10	Poor astringent taste	Plump and mellow
			Example 11	Poor astringent taste	Soft and soft at the entrance
Example 12	Poor astringent taste	Clean and cool
			Example 13	Poor astringent taste	Soft and smooth sponge
Example 14	Poor astringent taste	Alcohol without strong effect
			Example 15	Poor astringent taste	Soft and mellow
Example 16	Poor astringent taste	A poor astringent feeling, good

As can be seen from the above table, the mouthfeel is basically unchanged within 4 months without using porous ceramic catalyst. The spinel mineral structures of zirconium oxide, manganese oxide, cadmium oxide, iron oxide and the like are utilized to generate far infrared rays, the ageing of the white spirit is accelerated by the far infrared effect, the generation of ether can be accelerated, the ether content is increased, and the hot and astringent taste of the white spirit can be adsorbed by the porous ceramic; the effect is better when zinc oxide, nano zirconia, nano titanium dioxide and cobalt oxide are added.

The invention adopts far infrared porous ceramics, accelerates the aging of the fungus of the white spirit by excitation, and accelerates the generation of ether in the white spirit by the action of aging bacteria. The spicy and astringent tastes in the wine are greatly reduced within one week by utilizing the adsorption effect of the porous ceramic, so that the taste of the wine is excellent. Under the action of infrared rays, the wine aging effect is better within four months, and the aim of quickly aging the wine is further fulfilled.

The porous ceramic can also be used for aging yellow wine and vinegar in the same action mode.

Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.