阅读说明：本技术 一类高Q×f镓酸盐石榴石结构微波介质陶瓷材料及其制备方法 (High Q x f gallate garnet structure microwave dielectric ceramic material and preparation method thereof ) 是由 杨利 杨小燕 匡小军 于 2021-09-22 设计创作，主要内容包括：本发明公开一种相对介电常数ε在15～17之间,品质因子与谐振频率乘积(Q×f)在80,000～95,000GHz之间,谐振频率温度系数(τ-(f))在-30～-28ppm/℃之间的新型镓酸盐石榴石微波介质陶瓷及其制备方法,属于微波介质陶瓷制备技术领域,其化学组成为Ca-(3)TiMGa-(3)O-(12)(M＝Nb,Ta)。本发明公开的镓酸盐石榴石结构微波介质陶瓷化学组成及制备工艺简单,可应用于介质谐振器、微波集成电路基片等微波器件的制造。(The invention discloses a dielectric ceramic material with a relative dielectric constant epsilon of 15-17, a product (Qxf) of a quality factor and a resonance frequency of 80,000-95,000 GHz, and a temperature coefficient (tau) of the resonance frequency f ) A novel gallate garnet microwave dielectric ceramic between-30 to-28 ppm/DEG C and a preparation method thereof, belonging to the technical field of microwave dielectric ceramic preparation, wherein the chemical composition of the gallate garnet microwave dielectric ceramic is Ca 3 TiMGa 3 O 12 (M ═ Nb, Ta). The gallate garnet structure microwave dielectric ceramic disclosed by the invention has simple chemical composition and preparation process, and can be applied to the manufacture of microwave devices such as dielectric resonators, microwave integrated circuit substrates and the like.)

1. the invention discloses a relative epsilon_rA dielectric constant of 15-17, a product of quality factor and resonant frequency (Qxf) of 80,000-95,000 GHz, and a temperature coefficient of resonant frequency (τ)_f) A novel gallate garnet structure microwave dielectric ceramic between-30 to-28 ppm/DEG C and a preparation method thereof, belonging to the technical field of microwave dielectric ceramic preparation, wherein the chemical composition is Ca₃TiMGa₃O₁₂(M＝Nb,Ta)。

2. The microwave dielectric ceramic of claim 1 prepared by the steps of:

(1) mixing CaCO₃(99％)，TiO₂(99％)，Nb₂O₅(99.99％)，Ta₂O₅(99.99％)，Ga₂O₃(99.99%) dried powder as Ca₃TiMGa₃O₁₂Weighing and batching the chemical formula (M ═ Nb, Ta);

(2) mixing the raw materials in the step (1), wet-type hand-grinding for 1-2 hours, drying the mixture, and then adding Ca into the mixture₃TiNbGa₃O₁₂Presintering at 1100 deg.C for 8 hr to obtain Ca powder₃TiTaGa₃O₁₂Presintering for 8 hours at 1200 ℃ in an atmosphere;

(3) pressing the powder obtained in step (2) to form Ca₃TiNbGa₃O₁₂Sintering at 1210 deg.C for 8 hr to obtain Ca powder₃TiTaGa₃O₁₂Sintering at 1360 deg.C for 8 hr.

Technical Field

The invention relates to a dielectric ceramic material of microwave components such as a dielectric substrate, a resonator, a waveguide loop and the like used at microwave frequency and a preparation method thereof.

Background

With the rapid development of modern communications such as 5G communications technology, communications network technology and satellite communications, the demands for miniaturization, low loss, low cost and high stability of modern communications technology materials are further increased. The microwave dielectric ceramic is used as a core component of modern communication technology, and is widely applied to microwave communication systems such as mobile communication, satellite communication, global satellite positioning system, Bluetooth equipment, wireless local area network and the like as microwave electronic components such as a dielectric resonator/filter, a dielectric antenna, a dielectric guided wave loop and the like due to excellent dielectric constant, high quality factor and low resonant frequency temperature coefficientIn the middle, the design and the discovery of a novel microwave dielectric ceramic material with excellent microwave dielectric property are the key points of the development of modern communication technology. The commercial application of microwave dielectric ceramics requires that it has low relative dielectric constant, high quality factor, near-zero temperature coefficient of resonance frequency, and in addition, the manufacturing cost and sintering temperature of the ceramics are important factors to be considered. In recent years, many studies have found that rare earth gallate garnet ceramics exhibit excellent microwave dielectric properties, such as Sm₃Ga₅O₁₂The dielectric constant of the material is 12.3, Q x f is 192173GHz, and the temperature coefficient of resonance frequency is-19.2. Albeit Sm₃Ga₅O₁₂The ceramic has excellent comprehensive microwave dielectric property, but has no obvious advantages in synthesis temperature and preparation cost. In addition, the natural mineral Ca₃SnSbFe₃O₁₂、Ca₃SnSbAl₃O₁₂The finding shows that the octahedral central position in the garnet structure can also be filled by the four-and pentavalent positive ions together. In view of the above-mentioned discovery of natural minerals, and Nb⁵⁺ And Ta⁵⁺ All have Sb⁵⁺ Similar ionic radius, with Ti⁴⁺ Also has a structure of a metal oxide with Sn⁴⁺ Close ionic radius, thereby exploring the acquisition of novel, relatively inexpensive to prepare, Ti⁴⁺And M⁵⁺The microwave dielectric ceramic with the gallate garnet structure with the octahedral center occupied by (M ═ Nb, Ta) has feasibility.

Disclosure of Invention

The invention aims to provide a novel high Q x f gallate garnet structure microwave dielectric ceramic material and a preparation method thereof.

The invention relates to a high Q x f gallate garnet structure microwave dielectric ceramic material which comprises the following chemical components: ca₃TiMGa₃O₁₂Where M ═ Nb, Ta.

The high Q x f gallate garnet structure microwave dielectric ceramic is prepared by the following steps:

(1) mixing CaCO₃(99％)，TiO₂(99％)，Nb₂O₅(99.99％)，Ta₂O₅(99.99％)，Ga₂O₃(99.99%) dried powder as Ca₃TiMGa₃O₁₂Weighing and batching the chemical formula (M ═ Nb, Ta);

(2) mixing the raw materials in the step (1), wet-type hand-grinding for 1-2 hours, drying the raw materials by using absolute ethyl alcohol, and presintering the raw materials for 8 hours at 1280 ℃ in an atmosphere;

(3) pressing the powder obtained in step (2) to form Ca₃TiNbGa₃O₁₂Sintering at 1210 deg.C for 8 hr to obtain Ca powder₃TiTaGa₃O₁₂Sintering at 1360 deg.C for 8 hr.

The invention prepares high Q x f microwave dielectric ceramic Ca₃TiMGa₃O₁₂(M ═ Nb, Ta), simple in preparation process, and low in relative dielectric constant (15)<ε_r<17) And good quality factor (80000 GHz)<Q×f<95000GHz), a temperature coefficient of resonance frequency of-30.00 ppm/DEG C<τ_f<The temperature is-27.00 ppm/DEG C, and the application requirement of the low dielectric constant type dielectric substrate communication electronic component can be met.

Drawings

FIG. 1 is an X-ray diffraction pattern of 2 examples of the present invention

Detailed Description

Table 1 shows 2 specific examples of the invention and their microwave dielectric properties. The preparation method was as described above, and phase analysis was performed on the sintered ceramic sample by the powder X-ray diffraction method, and fig. 1 is an X-ray diffraction pattern of examples 1 and 2, showing that a single garnet structure phase was formed. The dielectric properties of the microwaves were evaluated by the cylindrical dielectric resonator method.

The present invention is by no means limited to the above embodiments. The composition, the upper limit and the lower limit of the sintering temperature and the range value can realize the invention, and the embodiments are not listed.

The invention can be widely used for manufacturing microwave devices such as various dielectric substrates, resonators/filters and the like, and can meet the technical requirements of systems such as mobile communication, satellite communication, global satellite positioning systems, Bluetooth equipment, wireless local area networks and the like.

Table 1: