阅读说明：本技术 一种危险废物处置回转窑用高致密刚玉莫来石砖 (High-density corundum mullite brick for hazardous waste disposal rotary kiln ) 是由 夏文斌 高长贺 占华生 马淑龙 卫迎锋 蔡斌利 于 2020-12-07 设计创作，主要内容包括：一种危险废物处置回转窑用高致密刚玉莫来石砖,属于耐火材料技术领域。刚玉莫来石砖按重量百分比各组份为：粒径≤5mm的电熔白刚玉,质量百分比为65～80％；粒径≤4mm的红柱石,质量百分比为10～20％；粒径≤0.004mm氧化铝微粉,质量百分比为5～15％；结合剂：质量百分比为1～5％。烧成温度1450～1650℃,在温度最高点恒温4～10小时,总的烧成时间在60～120小时。优点在于,适用于各种规格危险废弃物处置用回转窑,抗侵蚀、抗渗透、热震稳定性好、高温耐磨性优良,使用寿命可达到6个月以上,烧制成的高致密刚玉莫来石砖工艺简单性能优良。(A high-density corundum mullite brick for a rotary kiln for hazardous waste disposal belongs to the technical field of refractory materials. The corundum-mullite brick comprises the following components in percentage by weight: the mass percentage of the fused white corundum with the grain diameter less than or equal to 5mm is 65-80%; andalusite with the particle size of less than or equal to 4mm, wherein the mass percentage is 10-20%; alumina micropowder with the particle size of less than or equal to 0.004mm, and the mass percent of the alumina micropowder is 5-15%; binding agent: the mass percentage is 1-5%. The firing temperature is 1450-1650 ℃, the temperature is kept constant at the highest point for 4-10 hours, and the total firing time is 60-120 hours. The method has the advantages that the method is suitable for rotary kilns for treating dangerous wastes of various specifications, has the advantages of erosion resistance, permeation resistance, good thermal shock stability, excellent high-temperature wear resistance, service life of more than 6 months, and simple process and excellent performance of the sintered high-density corundum mullite brick.)

1. A high-density corundum mullite brick for a rotary kiln for hazardous waste disposal is characterized by comprising the following components in percentage by weight: electric melting white corundum with grain diameter less than or equal to 5 mm: wherein Al is₂O₃More than or equal to 98 percent, and the mass percent is 65-80 percent; andalusite with the particle size not greater than 4 mm: wherein Al is₂O₃Not less than 55 percent, and 10 to 20 percent by mass; alumina micro powder with the particle size less than or equal to 0.004 mm: wherein Al is₂O₃More than or equal to 99 percent, and the mass percent is 5-15 percent; binding agent: the mass percentage is 1-5%.

2. The corundum mullite brick of claim 1, wherein the binding agent is one or more of water glass, aluminum dihydrogen phosphate and lignin.

3. The corundum mullite brick according to claim 1, wherein the preparation method of the corundum mullite brick comprises the following specific steps and parameters:

1) preparing materials: the fused white corundum is less than or equal to 5mm and 65-80%, the andalusite is less than or equal to 4mm and 10-20%, the alumina micropowder is 5-15%, and the bonding agent is 1-5%;

2) mixing: firstly pouring the fused white corundum and andalusite into a mixer for dry mixing for 3-5 minutes, then pouring the bonding agent, mixing for 3-5 minutes, finally pouring the alumina micropowder, and mixing for 10-15 minutes to form a wet material;

3) molding: pressing and molding the mixed wet material for 1-24 hours, wherein the tonnage of a molding press is more than or equal to 400 tons;

4) and (3) drying: drying in a drying kiln for more than 24 hours, wherein the temperature of a drying entrance is 30-70 ℃, and the highest drying temperature is controlled at 110-150 ℃;

5) and (3) firing: and (3) firing in a high-temperature tunnel kiln or a shuttle kiln, wherein the firing temperature is 1450-1650 ℃, the constant temperature is kept at the highest temperature for 4-10 hours, and the total firing time is 60-120 hours.

Technical Field

The invention belongs to the technical field of refractory materials, and particularly relates to a high-density corundum mullite brick for a hazardous waste disposal rotary kiln.

Background

In recent years, with the massive construction of hazardous waste treatment projects in China, the lining of a rotary kiln of main incineration equipment mainly uses refractory bricks, the types of treated materials are complex, the requirements on refractory materials are strict, and the service life of the refractory bricks becomes a key for increasing benefits in hazardous waste treatment operation management. But the comprehensive performances of erosion resistance, penetration resistance, thermal shock resistance and high-temperature wear resistance of the currently used refractory bricks are influenced by the selection of raw materials and the production process.

Disclosure of Invention

The invention aims to provide a high-density corundum mullite brick for a rotary kiln for hazardous waste disposal, which solves the problem of poor comprehensive performance of the conventional corundum mullite brick. The high-density corundum-mullite brick with excellent comprehensive performance of erosion resistance, penetration resistance, thermal shock resistance and high-temperature wear resistance is manufactured.

A high-density corundum-mullite brick for a rotary kiln for hazardous waste disposal comprises the following components in percentage by weight: electric melting white corundum with grain diameter less than or equal to 5 mm: wherein Al is₂O₃More than or equal to 98 percent, and the mass percent is 65-80 percent; andalusite with the particle size not greater than 4 mm: wherein Al is₂O₃Not less than 55 percent, and 10 to 20 percent by mass; alumina micro powder with the particle size less than or equal to 0.004 mm: wherein Al is₂O₃More than or equal to 99 percent, and the mass percent is 5-15 percent; binding agent: the mass percentage is 1-5%.

The binding agent is one or more of water glass, aluminum dihydrogen phosphate, lignin and the like.

The preparation method of the high-density corundum mullite brick comprises the following specific steps and parameters:

1. preparing materials: the fused white corundum is less than or equal to 5mm and 65-80%, the andalusite is less than or equal to 4mm and 10-20%, the alumina micropowder is 5-15%, and the bonding agent is 1-5%;

2. mixing: firstly pouring the fused white corundum and andalusite into a mixer for dry mixing for 3-5 minutes, then pouring the bonding agent, mixing for 3-5 minutes, finally pouring the alumina micropowder, and mixing for 10-15 minutes to form a wet material;

3) molding: pressing and molding the mixed wet material for 1-24 hours, wherein the tonnage of a molding press is more than or equal to 400 tons (the larger the pressure is, the better the pressure is);

4) and (3) drying: drying for more than 24 hours in a drying kiln (the longer the drying time is, the better), controlling the temperature of a drying inlet to be 30-70 ℃ and the highest drying temperature to be 110-150 ℃.

5) And (3) firing: and (3) firing in a high-temperature tunnel kiln or a shuttle kiln, wherein the firing temperature is 1450-1650 ℃, the constant temperature is kept at the highest temperature for 4-10 hours, and the total firing time is 60-120 hours.

The invention has the advantages of suitability for rotary kilns for treating hazardous wastes of various specifications, corrosion resistance, permeation resistance, good thermal shock stability, excellent high-temperature wear resistance, service life of more than 6 months and very positive effect on improving the running rate of the rotary kilns for treating the hazardous wastes. The fired high-density corundum-mullite brick has simple process and excellent performance.

Detailed Description

Example 1

A high-density corundum-mullite brick for a rotary kiln for hazardous waste disposal comprises the following components in percentage by weight:

the raw materials are mixed according to the required proportion, pug is prepared in a mixing roll, the pug is formed under the pressure of more than or equal to 400 tons, and the formed green brick is fired in a tunnel kiln or a shuttle kiln at the temperature of 1450 and 1650 ℃.

Example 2

A high-density corundum-mullite brick for a rotary kiln for hazardous waste disposal comprises the following components in percentage by weight:

the raw materials are mixed according to the required proportion, pug is prepared in a mixing roll, the pug is formed under the pressure of more than or equal to 400 tons, and the formed green brick is fired in a tunnel kiln or a shuttle kiln at the temperature of 1450 and 1650 ℃.