阅读说明：本技术 一种高发射率隔热复合型耐火涂料 (High-emissivity heat-insulation composite refractory coating ) 是由 刘鹏程 张伟 王刚 王曲 于 2021-01-13 设计创作，主要内容包括：本发明属于高温节能保温技术领域,具体涉及一种高发射率隔热复合型耐火涂料。涉及的一种高发射率隔热复合型耐火涂料的原料组成及以质量份为：堇青石细粉10-30份、氧化铝细粉10-35份、氧化锆细粉20-40份、空心陶瓷微珠10-30份、玻璃微珠10-25份；复合型耐火涂料的原料组成的总质量为100份,每100份所述的原料中添加有30-50份结合剂、20-40份溶剂,以及0.1-0.2份的增稠剂和0.03-0.05份的促烧剂。本发明按照原料的质量分数称量混合均匀得到复合型保温涂料,该涂料具有1300℃耐高温、低的热导率以及高红外辐射率等性能,并且涂层与基体结合牢固、抗热震性较好的优点。(The invention belongs to the technical field of high-temperature energy-saving heat preservation, and particularly relates to a high-emissivity heat-insulating composite refractory coating. The high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by mass: 10-30 parts of cordierite fine powder, 10-35 parts of alumina fine powder, 20-40 parts of zirconia fine powder, 10-30 parts of hollow ceramic microspheres and 10-25 parts of glass microspheres; the composite fire-resistant coating comprises 100 parts of raw materials by mass, and each 100 parts of raw materials are added with 30-50 parts of bonding agent, 20-40 parts of solvent, 0.1-0.2 part of thickening agent and 0.03-0.05 part of burning promoter. The composite heat-insulating coating is obtained by weighing and uniformly mixing the raw materials according to the mass fraction, and has the advantages of high temperature resistance at 1300 ℃, low thermal conductivity, high infrared radiance and the like, firm bonding between the coating and the matrix, and good thermal shock resistance.)

1. The high-emissivity heat-insulation composite refractory coating is characterized in that: the composite fire-resistant coating comprises the following raw materials in parts by mass: 10-30 parts of cordierite fine powder, 10-35 parts of alumina fine powder, 20-40 parts of zirconia fine powder, 10-30 parts of hollow ceramic microspheres and 10-25 parts of glass microspheres; the composite fire-resistant coating comprises 100 parts of raw materials by mass, and each 100 parts of raw materials are added with 30-50 parts of bonding agent, 20-40 parts of solvent, 0.1-0.2 part of thickening agent and 0.03-0.05 part of burning promoter.

2. The high-emissivity heat-insulating composite fire-resistant coating according to claim 1, wherein: 20 parts of cordierite fine powder, 20 parts of alumina fine powder, 30 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres and 15 parts of glass microspheres, and 40 parts of a binding agent, 30 parts of a solvent, 0.1 part of a thickening agent and 0.03 part of a burning accelerator are added.

3. The high-emissivity heat-insulating composite fire-resistant coating according to claim 1, wherein: the binding agent is one of aluminum dihydrogen phosphate or silica sol.

4. The high-emissivity heat-insulating composite fire-resistant coating according to claim 3, wherein: the density of the used aluminum dihydrogen phosphate is 1.5g/ml at 25 ℃, and the pH value is about 1.4; SiO in the silica sol₂The content of (B) is 30-35%, and the pH value is 9-9.5.

5. The high-emissivity heat-insulating composite fire-resistant coating according to claim 1, wherein: the thickening agent is one of carboxymethyl cellulose or hydroxyethyl cellulose.

6. The high-emissivity heat-insulating composite fire-resistant coating according to claim 1, wherein: the burning accelerator is one of borosilicate glass powder or potassium feldspar powder.

7. The high-emissivity heat-insulating composite fire-resistant coating according to claim 1, wherein: the particle sizes of the fine cordierite powder, the fine alumina powder and the fine zirconia powder are all less than or equal to 0.076mm, and the average particle sizes of the hollow ceramic microspheres and the glass microspheres are 0-0.2 mm.

Technical Field

The invention belongs to the technical field of high-temperature energy-saving heat preservation, and particularly relates to a high-emissivity heat-insulating composite refractory coating.

Background

With the rapid development of national economy, the problems of energy shortage and dissipation are increasingly highlighted, the development concepts of energy conservation and low carbon are deeply concentrated, the state successively develops the policies of energy conservation and emission reduction, and the energy conservation becomes a hot point of social attention. The energy consumption of the high-temperature industry accounts for about 25-40% of the national energy consumption, the average heat efficiency of the most important industrial kilns is less than 40% and is 10-20% lower than that of developed industrial countries, and therefore energy is greatly wasted, and therefore the heat-insulation and heat-preservation high-emissivity coating is produced at the same time, and the purposes of energy conservation and emission reduction can be effectively achieved in different modes.

The main action mechanism of the heat insulation coating is to improve the porosity, reduce the heat conduction and prevent the heat convection, and the heat insulation coating is applied to the outer walls of high-temperature pipelines and furnace walls and can effectively prevent the heat from dissipating. The infrared ceramic material can be divided into high, medium and low emission ceramic materials according to the emissivity, the emissivity ranges are respectively more than 0.8, 0.5-0.8 and less than 0.8, the high emissivity coating has the action mechanism that a coating with high emissivity is prepared by utilizing a material with high emissivity, and the coating is used in a kiln to improve the radiation capability of the inner wall of the kiln so as to achieve the purposes of reducing energy dissipation and improving the temperature of the kiln. So far, the two coatings show better performance and energy-saving expectation in practical use, however, a single thermal insulation coating can not isolate the diffusion of heat to a greater extent, and if the barrier type and high-emissivity radiation coating are fused together, the thermal insulation performance can be greatly improved. As early as 60 years in the last century, radiation heat-preservation composite coatings have appeared and are mainly utilized in the field of buildingsSo as to reduce the internal temperature, and then gradually popularize the technology in other fields, thereby saving a large amount of energy in industrial application. There are foreign companies researching TiO₂、Fe₂O₃The mica powder, the talcum powder and the like are used as the pigment and the filler and the heat insulation filler to prepare the water-based acrylic acid-based heat insulation paint, and the paint has higher reflectivity. But the coating has lower use temperature, cannot be well applied to the kiln liner, and can be stably used for a long time. In addition, there is a patent "high emissivity thermal insulation coating" (patent application No. 201910596986.6) which is a high emissivity thermal insulation coating combining a thermal insulation coating and a high emissivity coating, and is mainly formed by combining the high emissivity of a doped lanthanum aluminate coating and the thermal insulation performance of a zirconia hollow sphere coating. However, the method has the problems of complicated construction and raw material preparation, high cost, difficulty in popularization and application in actual production and the like.

Therefore, if a single coating which is prepared simply by using cheap raw materials and has the characteristics of heat preservation and high radiation can be realized, the method has important significance for reducing the cost and improving the energy conservation of the industrial kiln.

Disclosure of Invention

The invention aims to provide a high-emissivity heat-insulating composite refractory coating aiming at the problems of high cost and complex process of the coating.

The purpose of the invention is realized by the following technical scheme:

the composite refractory coating with high emissivity comprises the following raw materials in parts by mass: 10-30 parts of cordierite fine powder, 10-35 parts of alumina fine powder, 20-40 parts of zirconia fine powder, 10-30 parts of hollow ceramic microspheres and 10-25 parts of glass microspheres; the composite fire-resistant coating comprises 100 parts of raw materials by mass, and each 100 parts of raw materials are added with 30-50 parts of bonding agent, 20-40 parts of solvent, 0.1-0.2 part of thickening agent and 0.03-0.05 part of burning promoter.

Further, the composite fire-resistant coating comprises the following raw materials in parts by mass: 20 parts of cordierite fine powder, 20 parts of alumina fine powder, 30 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres and 15 parts of glass microspheres, and 40 parts of a binding agent, 30 parts of a solvent, 0.1 part of a thickening agent and 0.03 part of a burning accelerator are added.

The binding agent is one of aluminum dihydrogen phosphate or silica sol.

The density of the used aluminum dihydrogen phosphate is 1.5g/ml at 25 ℃, and the pH value is about 1.4; SiO in the silica sol₂The content of (B) is 30-35%, and the pH value is 9-9.5.

The thickening agent is one of carboxymethyl cellulose or hydroxyethyl cellulose.

The burning accelerator is one of borosilicate glass powder or potassium feldspar powder.

The particle sizes of the fine cordierite powder, the fine alumina powder and the fine zirconia powder are all less than or equal to 0.076mm, and the average particle sizes of the hollow ceramic microspheres and the glass microspheres are 0-0.2 mm.

According to the high-emissivity heat-insulation composite refractory coating provided by the invention, the cordierite and zirconia materials have high infrared radiation characteristics, and in addition, common hollow ceramic beads and glass beads are added to reduce the volume density of the materials and increase the porosity so as to reduce the heat conductivity of the coating and achieve the purposes of energy conservation and heat insulation; the aluminum dihydrogen phosphate binding agent used for the coating has strong binding capacity and better high-temperature resistance, and ensures that the coating can be stably used under the high-temperature condition. The composition of the refractory coating can be uniformly mixed by weight parts of materials to obtain refractory slurry, and then the refractory slurry is sprayed or brushed on the surfaces of working linings of kilns such as tunnel kilns and roller kilns, so that sintering and the kilns are tightly combined in use, the infrared emissivity in the kilns is improved, heat loss is reduced, and the purpose of energy conservation is achieved. The fire-resistant coating has the beneficial effects that:

1. stable in use at high temperature. The refractory coating disclosed by the invention can bear high-temperature calcination at about 1300 ℃, and can not deform or melt. The zirconia and cordierite raw materials used by the coating have high emissivity, and the emissivity can be kept at a high level for a long time. The coating has good use stability.

2. Convenient operation, economy and environmental protection. The coating is of a single-layer structure, the characteristics of high emissivity and geothermal conductivity are guaranteed, the coating is simple to prepare, the raw material cost is low, and the purposes of economy, practicability, energy conservation and environmental protection are met.

Detailed Description

The invention is further described below in conjunction with the specific embodiments.

Example 1: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 20 parts of cordierite fine powder, 20 parts of alumina fine powder, 30 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 30 parts of aluminum dihydrogen phosphate and 40 parts of deionized water. 0.1 part of carboxymethyl cellulose thickener and 0.03 part of borosilicate glass powder burning accelerator are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 2: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 20 parts of cordierite fine powder, 20 parts of alumina fine powder, 25 parts of zirconia fine powder, 20 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 35 parts of (20 +20+25+10+15 is less than 100) aluminum dihydrogen phosphate and 35 parts of deionized water. 0.1 part of carboxymethyl cellulose thickener and 0.05 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 3: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 25 parts of cordierite fine powder, 20 parts of alumina fine powder, 25 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 40 parts of aluminum dihydrogen phosphate and 30 parts of deionized water. In addition, 0.2 part of hydroxyethyl cellulose thickener and 0.04 part of borosilicate glass powder burning accelerator are added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 4: high-emissivity heat-insulating composite refractory coating and raw materials thereofComprises the following components in parts by weight: 30 parts of cordierite fine powder, 20 parts of alumina fine powder, 20 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 30 parts of silica sol and 40 parts of deionized water. 0.1 part of hydroxyethyl cellulose thickener and 0.03 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 5: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 20 parts of cordierite fine powder, 25 parts of alumina fine powder, 25 parts of zirconia fine powder, 20 parts of hollow ceramic microspheres, 10 parts of glass microspheres, 40 parts of aluminum dihydrogen phosphate and 30 parts of deionized water. 0.1 part of carboxymethyl cellulose thickener and 0.05 part of borosilicate glass powder burning accelerator are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 6: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 25 parts of cordierite fine powder, 20 parts of alumina fine powder, 20 parts of zirconia fine powder, 20 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 30 parts of silica sol and 40 parts of deionized water. 0.2 part of carboxymethyl cellulose thickener and 0.05 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 7: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 30 parts of cordierite fine powder, 20 parts of alumina fine powder, 20 parts of zirconia fine powder, 20 parts of hollow ceramic microspheres, 10 parts of glass microspheres, 40 parts of silica sol and 30 parts of deionized water. 0.15 part of hydroxyethyl cellulose thickener and 0.04 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, and has good high-temperature radiation performanceThermal insulation performance, infrared emissivity of above 0.8, and thermal conductivity of 0.5 W.m at 1000 deg.C^-1·K^-1Left and right.

Example 8: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 15 parts of cordierite fine powder, 20 parts of alumina fine powder, 35 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 45 parts of silica sol and 25 parts of deionized water. 0.15 part of carboxymethyl cellulose thickener and 0.03 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 9: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 10 parts of cordierite fine powder, 25 parts of alumina fine powder, 35 parts of zirconia fine powder, 15 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 40 parts of aluminum dihydrogen phosphate and 30 parts of deionized water. 0.2 part of hydroxyethyl cellulose thickener and 0.03 part of potassium feldspar powder burning promoter are additionally added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.

Example 10: a high-emissivity heat-insulation composite refractory coating comprises the following raw materials in parts by weight: 15 parts of cordierite fine powder, 20 parts of alumina fine powder, 30 parts of zirconia fine powder, 20 parts of hollow ceramic microspheres, 15 parts of glass microspheres, 45 parts of silica sol and 25 parts of deionized water. In addition, 0.1 part of carboxymethyl cellulose thickener and 0.04 part of borosilicate glass powder burning accelerator are added. The coating can be stably used at about 1300 ℃, has good high-temperature radiation and heat preservation performance, can keep the infrared emissivity above 0.8, and has the heat conductivity coefficient of 0.5 W.m at 1000 DEG C^-1·K^-1Left and right.