阅读说明：本技术 一种高低温无机颜料结合花纸及其制备方法及应用 (High-low temperature inorganic pigment combined stained paper and preparation method and application thereof ) 是由 刘钢 李志和 于 2020-05-23 设计创作，主要内容包括：本发明涉及陶瓷花纸工艺领域,具体涉及一种高低温无机颜料结合花纸及其制备方法与应用。所述花纸通过采用高温无机颜料和低温无机颜料按照花纸图案印刷获得；所述高温无机颜料各原料的重量份数为：氧化锌20-25份,长石30-40份,色料35-40份,升温剂10-20份；所述低温无极颜料各原料的重量分数为：氧化锌20-25份,长石30-40份,色料35-40份,降温剂10-20份。该花纸应用到陶瓷制品时,画面轮廓部位或者指定部位有色彩错位的立体感觉,使产品更加丰富多彩,图案光鲜,立体感强烈,图案及色彩变化范围大,艺术效果好,且应用到陶瓷制品时,其表面釉质具有良好的耐磨性和耐污性能。(The invention relates to the technical field of ceramic stained paper, in particular to high-low temperature inorganic pigment combined stained paper and a preparation method and application thereof. The stained paper is obtained by printing high-temperature inorganic pigment and low-temperature inorganic pigment according to a stained paper pattern; the high-temperature inorganic pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of heating agent; the low-temperature electrodeless pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of cooling agent. When the stained paper is applied to ceramic products, the picture outline part or the designated part has a three-dimensional sense of color dislocation, so that the product is more colorful, the pattern is bright and fresh, the three-dimensional sense is strong, the pattern and color change range is large, the artistic effect is good, and when the stained paper is applied to the ceramic products, the enamel on the surface of the ceramic products has good wear resistance and stain resistance.)

1. The high-low temperature inorganic pigment combined stained paper is characterized in that the stained paper is obtained by printing high-temperature inorganic pigment and low-temperature inorganic pigment according to a stained paper pattern;

the high-temperature inorganic pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of heating agent;

the low-temperature electrodeless pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of cooling agent.

2. The high and low temperature inorganic pigment combined stained paper according to claim 1, characterized in that the temperature raising agent is any one or two of alumina and silica.

3. The high and low temperature inorganic pigment combined stained paper according to claim 1, characterized in that the temperature reducing agent is any one or combination of calcium carbonate, strontium carbonate and borax.

4. The high and low temperature inorganic pigment combined stained paper according to claim 1, wherein the temperature raising agent and the temperature lowering agent are 10-20% of the high temperature inorganic pigment and the low temperature inorganic pigment.

5. The preparation method of the high-low temperature inorganic pigment combined stained paper is characterized by comprising the following steps:

determining a high-temperature inorganic pigment printing area and a low-temperature inorganic pigment printing area according to the stained paper pattern;

mixing zinc oxide, feldspar, a pigment and a heating agent, calcining, cooling, ball-milling, drying and sieving to obtain a high-temperature inorganic pigment, and mixing the high-temperature inorganic pigment with ink-regulating oil to obtain a high-temperature inorganic printing pigment;

mixing zinc oxide, feldspar, a pigment and a cooling agent, calcining, cooling, ball-milling, drying and sieving to obtain a low-inorganic pigment, and mixing the low-inorganic pigment with ink-regulating oil to obtain a low-temperature inorganic printing pigment;

printing the low-temperature inorganic printing pigment on the pattern base paper by adopting a screen printing mode and drying, and repeating the printing and drying process of the low-temperature inorganic pigment until the printing of the low-temperature inorganic pigment printing area is finished to obtain the low-temperature inorganic pigment stained paper;

and printing the high-temperature inorganic printing pigment on the low-temperature inorganic pigment stained paper by adopting a screen printing mode, drying, repeating the high-temperature inorganic pigment printing and drying process until the high-temperature inorganic pigment printing area is printed, and printing and drying by adopting the seal oil to obtain the high-temperature and low-temperature inorganic pigment combined stained paper.

6. The preparation method of the high and low temperature inorganic pigment combined stained paper according to claim 5, wherein the drying process comprises the following process parameters:

temperature: 30-38 ℃, relative humidity: 50-70%, duration: 50-70 min.

7. The preparation method of the high and low temperature inorganic pigment combined stained paper according to claim 5, wherein the mass ratio of the high temperature inorganic pigment to the low temperature inorganic pigment to the varnish is 10: 5-7.

8. The use of any of the high and low temperature inorganic pigment-bonded decals on ceramic decals as defined in claims 1-4 wherein the post-decal firing temperature is 760-780 ℃.

Technical Field

The invention relates to the technical field of ceramic stained paper, in particular to high-low temperature inorganic pigment combined stained paper and a preparation method and application thereof.

Background

The ceramic stained paper is formed by blending the ornamentation, the color and the modeling into the ceramic to form the industrial art and ceramic products. The stained paper is pasted on the surface of the porcelain, the porcelain is formed into various multi-colored patterns through high-temperature roasting, the method is a common use method for ceramic surface decoration, and is widely applied to the production of daily ceramics and furnishing art porcelain.

Ceramic stained paper is generally printed by using pigments with various colors, and the ceramic stained paper can be classified into high-temperature stained paper and low-temperature stained paper according to the barbecue temperature in the market at present due to the different barbecue temperatures. With the strong desire and pursuit of the aesthetic level of ceramic products by modern people, the common ceramic decal paper can not meet the requirements of customers.

Disclosure of Invention

Aiming at the defects in the prior art, the invention provides a high-low temperature inorganic pigment combined stained paper, which is obtained by printing high-temperature inorganic pigment and low-temperature inorganic pigment according to a stained paper pattern;

the high-temperature inorganic pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of heating agent;

the low-temperature electrodeless pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of cooling agent.

The invention also provides a preparation method of the high-low temperature inorganic pigment combined stained paper, which specifically comprises the following steps:

determining a high-temperature inorganic pigment printing area and a low-temperature inorganic pigment printing area according to the stained paper pattern;

mixing zinc oxide, feldspar, a pigment and a heating agent, calcining, cooling, ball-milling, drying and sieving to obtain a high-temperature inorganic pigment, and mixing the high-temperature inorganic pigment with ink-regulating oil to obtain a high-temperature inorganic printing pigment;

mixing zinc oxide, feldspar, a pigment and a cooling agent, calcining, cooling, ball-milling, drying and sieving to obtain a low-inorganic pigment, and mixing the low-inorganic pigment with ink-regulating oil to obtain a low-temperature inorganic printing pigment;

printing the low-temperature inorganic printing pigment on the pattern base paper by adopting a screen printing mode and drying, and repeating the printing and drying process of the low-temperature inorganic pigment until the printing of the low-temperature inorganic pigment printing area is finished to obtain the low-temperature inorganic pigment stained paper;

and printing the high-temperature inorganic printing pigment on the low-temperature inorganic pigment stained paper by adopting a screen printing mode, drying, repeating the high-temperature inorganic pigment printing and drying process until the high-temperature inorganic pigment printing area is printed, and printing and drying by adopting the seal oil to obtain the high-temperature and low-temperature inorganic pigment combined stained paper.

Has the advantages that:

when the high-low temperature inorganic pigment is applied to ceramic products in combination with stained paper, the outline part or the designated part of the picture has a three-dimensional sense of color dislocation, so that the product is more colorful, the pattern is bright and fresh, the three-dimensional sense is strong, the pattern and the color change range are large, the artistic effect is good, and when the high-low temperature inorganic pigment is applied to the ceramic products, the surface enamel of the ceramic products has good wear resistance and stain resistance.

Detailed Description

In order to clearly illustrate the technical content of the present invention, the detailed description is given in conjunction with specific examples, and it is obvious that the examples are only the preferred embodiments of the technical solution, and other technical solutions which can be obviously derived by those skilled in the art from the technical content disclosed still belong to the protection scope of the present invention.

The invention provides a high-low temperature inorganic pigment combined stained paper, which is obtained by printing high-temperature inorganic pigment and low-temperature inorganic pigment according to a stained paper pattern; the high-temperature inorganic pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of heating agent; the low-temperature electrodeless pigment comprises the following raw materials in parts by weight: 20-25 parts of zinc oxide, 30-40 parts of feldspar, 35-40 parts of pigment and 10-20 parts of cooling agent.

Further, the temperature raising agent is any one or a combination of two of alumina and silicon dioxide; the cooling agent is any one or combination of calcium carbonate, strontium carbonate and borax. The percentage content of the temperature raising agent and the temperature reducing agent in the high-temperature inorganic pigment and the low-temperature inorganic pigment is 10-20%.

The invention also provides a preparation method of the high-low temperature inorganic pigment combined stained paper, which specifically comprises the following steps: determining a high-temperature inorganic pigment printing area and a low-temperature inorganic pigment printing area according to the stained paper pattern; mixing zinc oxide, feldspar, a pigment and a heating agent, calcining, cooling, ball-milling, drying and sieving to obtain a high-temperature inorganic pigment, and mixing the high-temperature inorganic pigment with ink-regulating oil to obtain a high-temperature inorganic printing pigment; mixing zinc oxide, feldspar, a pigment and a cooling agent, calcining, cooling, ball-milling, drying and sieving to obtain a low-inorganic pigment, and mixing the low-inorganic pigment with ink-regulating oil to obtain a low-temperature inorganic printing pigment; printing the low-temperature inorganic printing pigment on the pattern base paper by adopting a screen printing mode and drying, and repeating the printing and drying process of the low-temperature inorganic pigment until the printing of the low-temperature inorganic pigment printing area is finished to obtain the low-temperature inorganic pigment stained paper; and printing the high-temperature inorganic printing pigment on the low-temperature inorganic pigment stained paper by adopting a screen printing mode, drying, repeating the high-temperature inorganic pigment printing and drying process until the high-temperature inorganic pigment printing area is printed, and printing and drying by adopting the seal oil to obtain the high-temperature and low-temperature inorganic pigment combined stained paper.

Further, the process parameters of the drying process are as follows: temperature: 30-38 ℃, relative humidity: 50-70%, duration: 50-70 min; the mass ratio of the high-temperature inorganic pigment to the low-temperature inorganic pigment to the varnish is 10: 5-7.

The application also provides the application of the high-low temperature inorganic pigment combined with the stained paper on the ceramic applique, and the baking temperature after the applique is 760-780 ℃.

The present invention is specifically illustrated by the following specific examples: