阅读说明：本技术 一种胶合板用胶黏剂及其胶合生产工艺 (Adhesive for plywood and gluing production process thereof ) 是由 卢俊 叶润露 迟正林 彭冲 黎健冰 康彦辉 于 2021-07-01 设计创作，主要内容包括：本申请实施例公开了一种胶合板用胶黏剂及其胶合生产工艺,为卷材,包括主体层,所述主体层为热熔胶膜,该种胶合板用胶黏剂还包括覆于所述主体层之上的功能层,所述功能层为防霉剂膜。通过将主体层与功能层以机械形式复合,故而能够在单板的热压胶合过程之中同时完成防霉的处理,在一定程度上简化了制造步骤、缩短了制造周期；与此同时,功能层在其上、下与单板结合处具有相对较高的防霉剂浓度,在一定程度上能够实现胶层的防霉。(The embodiment of the application discloses gluing agent for plywood and veneer production technology thereof, is the coiled material, including the main part layer, the main part layer is hot melt adhesive membrane, this gluing agent for plywood still including cover in functional layer on the main part layer, the functional layer is the mould proof agent membrane. The main body layer and the functional layer are compounded in a mechanical form, so that the mould-proof treatment can be simultaneously completed in the hot-press gluing process of the veneer, the manufacturing steps are simplified to a certain extent, and the manufacturing period is shortened; meanwhile, the functional layer has relatively high concentration of the mildew preventive at the joints of the upper part and the lower part of the functional layer and the veneer, and the mildew prevention of the glue layer can be realized to a certain extent.)

1. The utility model provides an adhesive for plywood, is the coiled material, includes main part layer (100), main part layer (100) are hot melt adhesive film, its characterized in that, this adhesive for plywood still including cover in functional layer (200) on main part layer (100), functional layer (200) are the mould inhibitor membrane.

2. The adhesive for plywood according to claim 1, wherein said functional layer (200) is formed by curtain coating or roll coating a micro emulsion type mildewcide on said main layer (100) and curing, and a thickness of said functional layer (200) is 0.050mm to 0.100 mm.

3. The adhesive for plywood according to claim 1, wherein said main body layer (100) has first penetration holes (110), said first penetration holes (110) are arranged in an array, and the diameter of said first penetration holes (110) is 0.005 mm-0.015 mm.

4. The adhesive for plywood of claim 3, wherein said functional layer (200) has second penetration holes (210) formed therein, and said second penetration holes (210) are arranged in a staggered manner with respect to said first penetration holes (110).

5. The adhesive for plywood of claim 4, wherein the second penetration hole (210) has a pore diameter of 0.010mm to 0.030 mm.

6. The adhesive for plywood according to claim 1 or 3 or 4 or 5, wherein said body layer (100) and said functional layer (200) are compounded by normal temperature rolling; and the functional layer (200) comprises the following components in percentage by weight: 2.5-5% of main component, 12.5-15% of styrene-acrylic resin, 0.25-0.33% of dispersing agent, 0.08-0.25% of defoaming agent, 0.16-0.42% of flatting agent, 7.33-10% of film-forming assistant and the balance of water; the main component is an aqueous organic mildew-proof medicament.

7. The adhesive for plywood of claim 6, wherein said functional layer (200) has a thickness of 0.030mm to 0.200 mm.

8. The gluing production process by using the adhesive for plywood as claimed in claim 1, which is characterized by sequentially comprising the following stages in the production sequence:

a slow release stage;

a hot pressing stage, wherein the temperature is 130-140 ℃, the contact pressure is 1.0-2.5 MPa, and the treatment time is 3-10 min;

in the cooling stage, the pressure is kept and naturally reduced to below 50 ℃;

cold pressing stage, normal temperature, contact pressure of 0.8 MPa-1.5 MPa, and treatment time of 3 min-10 min.

9. The gluing production process of claim 8, wherein the slow release stage comprises a no-pressure slow release stage and a pressure slow release stage; in the pressure-free slow release stage, the treatment temperature is normal temperature to 60 ℃, the environmental humidity is 90% RH to 95% RH, and the treatment time is 45min to 60 min; in the pressure slow release stage, the treatment temperature is 70-90 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.2-0.5 MPa, and the treatment time is 3-20 min.

10. The gluing production process according to claim 8, further comprising a veneer treatment step, wherein the veneer treatment step comprises the following stages in sequence of production:

a veneer drying stage, wherein the veneer is dried to 1% -4%;

and in the stage of veneer surface wet treatment, the veneer surface is wetted by roller coating or spraying, and the water consumption for veneer surface wet treatment is 35 to 45 grams per square meter.

Technical Field

The invention relates to the technical field of adhesives, in particular to an adhesive for producing and manufacturing a plywood, and also relates to a gluing production process of the adhesive.

Background

The plywood used for furniture in some occasions, such as kitchens, toilets, balconies and the like, has relatively high requirements on waterproof performance and mildew resistance of the plywood used for manufacturing the plywood.

In order to improve the waterproof performance of the plywood, means of modifying and improving adhesives are mostly utilized in the prior art. For example, in chinese patent CN110643312A, "a method for preparing an environment-friendly phenolic adhesive", a formaldehyde aqueous solution and an alkaline solution are used to modify a phenolic adhesive, so as to obtain a modified phenolic adhesive with good anti-boiling performance and low formaldehyde emission.

In order to improve the mildew resistance of the plywood, the means of impregnating and soaking the veneer with the aqueous mildew preventive are mostly utilized in the prior art. For example, CN108839144A, "a method for preparing a flame-retardant and mildew-proof plywood", is to dip a veneer with a mildew-proof solution for about 6 to 8 hours, and then dry the dipped veneer.

In summary, in the prior art, waterproof and mildewproof modification of veneers for manufacturing plywood are two relatively independent steps, and working hours consumed by mildewproof treatment are relatively long, so that the plywood has two disadvantages, one of which is complex in manufacturing step and relatively long in manufacturing period, and the other of which still has mildewing in use due to the adhesive.

Disclosure of Invention

The first technical object of the present invention is to overcome the above technical problems, thereby providing an adhesive for plywood, which has a composite structure, and can complete the mildew-proof treatment during the hot-press gluing process of the veneer by mechanically compounding the main body layer and the functional layer, thereby simplifying the manufacturing steps of the waterproof and mildew-proof plywood to a certain extent and shortening the manufacturing period; meanwhile, the functional layer has relatively high concentration of the mildew preventive at the joints of the upper part and the lower part of the functional layer and the veneer, and the mildew prevention of the glue layer can be realized to a certain extent. The second technical purpose of the invention is to provide a gluing production process of the adhesive for plywood.

In order to achieve the first technical object, an embodiment of the present invention provides an adhesive for plywood, which is a coiled material and includes a main body layer, wherein the main body layer is a hot-melt adhesive film, the adhesive for plywood further includes a functional layer coated on the main body layer, and the functional layer is a mildew preventive film.

By means of the structure, the main body layer and the functional layer are compounded in a mechanical mode, so that the mildew-proof treatment can be completed simultaneously in the hot-pressing gluing process of the veneer, the manufacturing steps of the waterproof and mildew-proof plywood are simplified to a certain extent, the manufacturing period is shortened, and the mildew prevention of the glue layer can be realized. Specifically, in the process of hot melting, bonding and curing the main body layer, the functional layer can release the mildew-proof medicament by means of moisture in the veneer and hot pressing treatment, and the mildew-proof medicament permeates into the veneer, and the film-shaped hot melt adhesive has relatively good waterproof performance, so that the mildew-proof treatment of the veneer can be completed in the gluing step, the manufacturing steps of the waterproof and mildew-proof plywood are simplified to a certain extent, and the manufacturing period is shortened. Moreover, the mildew-proof medicament permeates from the main body layer to the veneer layer, so that the joint of the veneer layer and the main body layer has relatively high concentration of the mildew-proof medicament, and the mildew prevention of the adhesive layer is realized to a certain extent.

Preferably, the functional layer is formed by coating or rolling the microemulsion-type mildew inhibitor on the main layer and fixing, and the thickness of the functional layer is 0.050 mm-0.100 mm.

In the technical scheme, by limiting the thickness of the functional layer, the mildew-proof agent in the functional layer can be enabled to basically permeate into the wood channel of the veneer on the premise of ensuring the impregnation amount of the mildew-proof agent, so that the influence of excessive residue of the functional layer on the bonding strength of the main body layer is avoided. Meanwhile, the thickness of the functional layer should not be too thin, which affects the leveling of the microemulsion-type mildewcide on the main layer, and causes the thickness of the functional layer to be uneven.

Preferably, the main body layer is provided with first permeation holes, the first permeation holes are arranged in an array, and the pore diameter of the first permeation holes is 0.005 mm-0.015 mm.

In this technical scheme, through the setting of first infiltration hole, the mould proof medicament that is arranged in the functional layer on the main part layer can pass first infiltration hole and fill wherein to realize mould proof to the glue film that the main part layer hot melt solidification formed.

Preferably, the functional layer has second penetration holes thereon, and the second penetration holes are staggered with the first penetration holes.

In this technical scheme, through the setting of second infiltration hole, the main part layer that is located between functional layer and the veneer gluing face can pass functional layer and veneer gluing face bonding through second infiltration hole after the melting to avoid the functional layer to the influence of bonding strength to a certain extent.

Preferably, the second penetration hole has a pore diameter of 0.010mm to 0.030 mm.

Preferably, the main body layer and the functional layer are compounded by rolling at normal temperature; and the functional layer comprises the following components by weight: 2.5-5% of main component, 12.5-15% of styrene-acrylic resin, 0.25-0.33% of dispersing agent, 0.08-0.25% of defoaming agent, 0.16-0.42% of flatting agent, 7.33-10% of film-forming assistant and the balance of water; the main component is a mildew-proof medicament.

Preferably, the functional layer has a thickness of 0.030mm to 0.200 mm.

In the technical scheme, by limiting the thickness of the functional layer, the mildew-proof agent in the functional layer can be enabled to basically permeate into the wood channel of the veneer on the premise of ensuring the impregnation amount of the mildew-proof agent, so that the influence of excessive residue of the functional layer on the bonding strength of the main body layer is avoided.

In order to achieve the second technical object, an embodiment of the present invention provides a gluing production process using the adhesive for plywood, which sequentially comprises the following steps in order of production:

a slow release stage;

a hot pressing stage, wherein the temperature is 130-140 ℃, the contact pressure is 1.0-2.5 MPa, and the treatment time is 3-10 min;

in the cooling stage, the pressure is kept and naturally reduced to below 50 ℃;

cold pressing stage, normal temperature, contact pressure of 0.8 MPa-1.5 MPa, and treatment time of 3 min-10 min.

By means of the method, in the slow release stage, the mildew-proof medicament in the film-shaped functional layer is released by means of moisture in the veneer, and the mildew-proof medicament is promoted to be impregnated into the veneer by means of concentration difference in the wood channel, so that in the slow release stage, the release and impregnation of the mildew-proof medicament in the functional layer are partially completed. In the hot pressing stage, the adhesive in the main body layer is melted and solidified to form an adhesive layer for bonding the two veneer layers; the high temperature required by hot pressing provides a temperature difference for the impregnation of the mildew preventive agent to serve as impregnation power; part of the adhesive permeates to the surface of the veneer to form the glue nail, and meanwhile, the previous impregnation of the mildew-proof medicament in the wood channel of the veneer and the permeation of the adhesive are mutually promoted, so that the gluing performance of the adhesive can be improved to a certain extent. In the cooling stage, the mildew preventive is further permeated, and the distribution of the mildew preventive in the veneer is perfected. In the cold pressing stage, the distribution of the mildew-proof agent in the thickness direction of the veneer is further optimized through the normal-temperature and pressure curing regulation for a period of time.

Preferably, the slow release stage comprises a pressure-free slow release stage and a pressure slow release stage; in the pressure-free slow release stage, the treatment temperature is normal temperature to 60 ℃, the environmental humidity is 90% RH to 95% RH, and the treatment time is 45min to 60 min; in the pressure slow release stage, the treatment temperature is 70-90 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.2-0.5 MPa, and the treatment time is 3-20 min.

In the technical scheme, the slow release stage is divided into two sub-stages. Particularly, in the pressure-free slow release stage, the film-shaped functional layer is liquefied in the moisture contained in the veneer layer to release the mildew-proof medicament in the veneer layer; in the pressure slow release stage, along with the increase of the temperature, the release of the mildew preventive is promoted, and simultaneously, the free water in the veneer wood channel is heated, so that the power of dissolving the mildew preventive in the free water is used as the osmotic power of the mildew preventive, and the slow release and the osmosis are promoted in a mechanical mode by assisting the pressure.

Preferably, the method further comprises a step of veneer processing, and in the step of veneer processing, the method sequentially comprises the following steps according to the production sequence:

a veneer drying stage, wherein the veneer is dried to 1% -4%;

and in the stage of veneer surface wet treatment, the veneer surface is wetted by roller coating or spraying, and the water consumption for veneer surface wet treatment is 35 to 45 grams per square meter.

In the technical scheme, the mildew preventive agent in the functional layer can be dissolved relatively more efficiently by means of the moisture on the surface of the veneer. Meanwhile, by means of the high temperature in the pressure slow-release stage or the hot-pressing stage and the relatively low moisture content of the veneer, the moisture on the surface of the veneer can relatively quickly permeate into the wood channel of the veneer along with the mildew-proof agent. On the other hand, during the temperature rise process in the hot pressing stage, the water of the coating amount can be basically permeated, and the bonding strength is prevented from being influenced by the water accumulated on the surface of the veneer.

Preferably, the thickness of the single plate is 0.6mm to 2.5 mm.

In summary, compared with the prior art, the invention has the beneficial effects that: the manufacturing steps can be simplified to a certain extent, the manufacturing period is shortened, and the mould prevention of the glue layer can be realized to a certain extent.

Drawings

In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below, it is obvious that the drawings in the following description are only some embodiments of the present application, and for those skilled in the art, other drawings can be obtained according to the drawings without inventive exercise.

FIG. 1 is a schematic structural view of an adhesive for plywood in example 1 of the present invention;

FIG. 2 is a schematic view of a wet treatment method in a wet treatment stage of a veneer surface according to embodiment 2 of the present invention;

FIG. 3 is a schematic view of a wet treatment method in a wet treatment stage of a veneer surface according to embodiment 3 of the present invention;

FIG. 4 is a schematic structural view of an adhesive for plywood in example 4 of the present invention;

FIG. 5 is a schematic view of a combination of a main layer and a functional layer according to example 5 of the present invention;

FIG. 6 is a schematic structural diagram of the bulk layer 100 according to embodiment 8 of the present invention;

fig. 7 is a schematic structural view of a functional layer 200 according to embodiment 9 of the present invention;

fig. 8 is a schematic view of a method for perforating the first and second penetration holes according to examples 8 and 9 of the present invention.

In the figure: 100-main body layer, 200-functional layer, 300-mesh belt conveyor, 400-atomized water spray head, 500-air curtain, 610-redirection roller, 620-compression roller group, 700-high pressure perforator, 900-veneer, 110-first penetration hole and 120-second penetration hole.

Detailed Description

In order to make those skilled in the art better understand the technical solutions in the present application, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.

Example 1: referring to fig. 1, the adhesive for plywood is a roll material, and includes a main body layer 100 and a functional layer 200 coated on the main body layer 100. In this embodiment, functional layer 200 overlies one surface of body layer 100, while in other embodiments functional layer 200 may overlie both surfaces of body layer 100.

The main layer 100 is any one of hot melt adhesive films without a substrate in the prior art, and preferably, the main layer 100 is an EVA adhesive film without a substrate or a PA adhesive film without a substrate. Such as a substrate-free type EVA adhesive film.

The functional layer 200 is a mold inhibitor film. Specifically, the functional layer 200 is formed by curtain coating or roll coating a micro emulsion type mildewcide (e.g., isothiazolinone micro emulsion) on the unwound body layer 100, followed by curing through a low temperature heat tunnel, e.g., 60 to 70 ℃ infrared light and heat tunnel, for a transit time of 25 to 90 seconds. In view of production efficiency, controllability of film thickness, and the like, it is preferable that the functional layer 200 is applied to the main layer 100 by roll coating. The thickness of the main layer 100 is 0.120mm, and the thickness of the functional layer 200 is 0.070mm to 0.100mm, and in this embodiment, the thickness is 0.090 mm.

The thickness of the veneer 900 bonded by the embodiment is 1.6mm, and the rotary-cut fast-growing poplar veneer has the water content of 16-20%. The gluing process of the adhesive for the plywood sequentially comprises the following stages according to the production sequence:

s1, in a slow release stage,

s1-1, a pressure-free slow release stage, wherein the treatment temperature is 58 +/-2 ℃, the environmental humidity is 90-95% RH, and the treatment time is 58-60 min;

s1-2, in a pressure slow release stage, the treatment temperature is 70 +/-2 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.2-0.3 MPa, and the treatment time is 18-20 min;

s2, hot pressing at 132 +/-2 ℃, under the contact pressure of 1.0-1.1 MPa, for 9-10 min;

s3, in a cooling stage, keeping the pressure and naturally cooling to below 50 ℃;

s4, cold pressing at normal temperature, wherein the contact pressure is 0.8-0.9 MPa, and the treatment time is 9-10 min.

Example 2: example 2 differs from example 1 in that the functional layer 200 has a thickness of 0.080 mm. The veneer 900 bonded in this example is 2.0mm thick, and is rotary cut fast growing poplar veneer. The adhesive for the plywood needs to treat the veneer before gluing and bonding, and in the step of treating the veneer, the adhesive sequentially comprises the following stages according to the production sequence:

s1, a veneer drying stage, namely drying a veneer 900 to the moisture content of 1% -2% by hot-press drying;

s2, in the stage of veneer surface wet treatment, two surfaces of the veneer 900 are wetted by spraying, and the water consumption for the veneer surface wet treatment is 43 g/square meter to 45 g/square meter (single-side consumption).

Wet treatment method in the veneer surface wet treatment stage referring to fig. 2, a veneer 900 is placed on an mesh belt conveyor 300 and fed, a group of atomized water spray heads 400 is positioned above the mesh belt conveyor 300 and sprays atomized water upward or obliquely upward at an angle of not less than 45 °, and a group of air curtains 500 are positioned at least 0.5m above the atomized water spray heads 400; another group of atomizing water nozzles 400 is located below the mesh belt conveyor 300 and sprays atomizing water downward or obliquely downward at an angle of not less than 45 °, and another group of air curtains 500 is located at least 0.5m below the atomizing water nozzles 400. The air flow direction of the two air curtains 500 faces the mesh belt conveyor 300, and the air flow speed is 0.2-0.5 m/s.

The gluing process of the adhesive for the plywood sequentially comprises the following stages according to the production sequence:

s1, in a slow release stage,

s1-1, a pressure-free slow release stage, wherein the treatment temperature is 58 +/-2 ℃, the environmental humidity is 90-95% RH, and the treatment time is 58-60 min;

s1-2, in a pressure slow release stage, the treatment temperature is 70 +/-2 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.2-0.3 MPa, and the treatment time is 18-20 min;

s2, hot pressing at 135 +/-2 ℃, under the contact pressure of 1.3-1.5 MPa, for 7-8 min;

s3, in a cooling stage, keeping the pressure and naturally cooling to below 50 ℃;

s4, cold pressing at normal temperature, wherein the contact pressure is 1.0-1.2 MPa, and the treatment time is 7-8 min.

Example 3: example 3 differs from example 1 in that the functional layer 200 has a thickness of 0.080 mm. The veneer 900 bonded in this example is 2.0mm thick, and is rotary cut fast growing poplar veneer. The adhesive for plywood of this embodiment needs to treat the veneer 900 before gluing and bonding, and in the step of veneer treatment, the following stages are included in order according to the production sequence:

s1, single-board drying, namely drying a single board 900 to the moisture content of 1% -2% by single-side hot-pressing drying, wherein the heating surface is a surface A, the other surface of the single board 900 is a surface B, the average moisture content of the surface A side is 1%, and the average moisture content of the surface B side is 2%;

s2, in the stage of veneer surface wet treatment, the side B of the veneer 900 is wetted by roller coating or spraying, and the water consumption for the veneer surface wet treatment is 43 grams per square meter to 45 grams per square meter.

Wet treatment method in the veneer surface wet treatment stage referring to fig. 3, a veneer 900 is placed on an mesh belt conveyor 300 and fed with the side of face B facing upward, a group of atomized water spray heads 400 is positioned above the mesh belt conveyor 300 and sprays atomized water upward or obliquely upward at an angle of not less than 45 °, an air curtain 500 is positioned at least 0.5m above the atomized water spray heads 400 and the air flow direction is toward the mesh belt conveyor 300, and the air flow velocity is 0.2 to 0.5 m/s.

The gluing process of the adhesive for the plywood sequentially comprises the following stages according to the production sequence:

s1, in a slow release stage,

s1-1, a pressure-free slow release stage, wherein the treatment temperature is 58 +/-2 ℃, the environmental humidity is 90-95% RH, and the treatment time is 58-60 min;

s1-2, in a pressure slow release stage, the treatment temperature is 70 +/-2 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.2-0.3 MPa, and the treatment time is 18-20 min;

s2, hot pressing at 135 +/-2 ℃, under the contact pressure of 1.3-1.5 MPa, for 7-8 min;

s3, in a cooling stage, keeping the pressure and naturally cooling to below 50 ℃;

s4, cold pressing at normal temperature, wherein the contact pressure is 1.0-1.2 MPa, and the treatment time is 7-8 min.

Example 4: example 4 is different from example 2 in that, referring to fig. 4, a functional layer 200 is coated on both surfaces of a main body layer 100, and the functional layer 200 has a thickness of 0.060 mm.

Example 5: example 5 differs from example 1 in that the functional layer 200 comprises the following components by weight: 2.5-2.7% of main component, 12.5-12.8% of styrene-acrylic resin, 0.25-0.28% of dispersing agent, 0.08-0.10% of defoaming agent, 0.16-0.19% of flatting agent, 7.33-7.50% of film-forming assistant and the balance of water; the main component is a microemulsion type mildew-proof medicament. The functional layer 200 with the thickness of 0.180 mm-0.200 mm is prepared from the above component materials, and the preparation method can be a reaction kettle type extrusion film forming mode in the prior art, and the functional layer is rolled and stored. The bulk layer 100 is then combined with the functional layer 200 by normal temperature and pressureless rolling, in the manner shown in fig. 5. Specifically, the main body layer 100 and the functional layer 200 are respectively rolled, and the two layers enter the roller group 620 to complete the pressing under the redirection of the redirection roller 610, and finally are rolled again.

The veneer 900 bonded in this example is 2.5mm thick and is rotary cut fast growing poplar veneer. The adhesive for plywood of this embodiment needs to treat the veneer 900 before gluing and bonding, and in the step of veneer treatment, the following stages are included in order according to the production sequence:

s1, single-board drying, namely drying a single board 900 to the moisture content of 1% -3% by single-side hot-pressing drying, wherein the heating surface is a surface A, the other surface of the single board 900 is a surface B, the average moisture content of the surface A side is 1%, and the average moisture content of the surface B side is 3%;

s2, in the veneer surface wet treatment stage, the side B of the veneer 900 is wetted by roller coating or spraying, and the water consumption for the veneer surface wet treatment is 40 to 42 grams per square meter.

The wet treatment method in the wet treatment stage of the veneer surface is described with reference to example 3.

The gluing process of the adhesive for the plywood sequentially comprises the following stages according to the production sequence:

s1, in a slow release stage,

s1-1, a pressure-free slow release stage, wherein the treatment temperature is 55 +/-2 ℃, the environmental humidity is 90-95% RH, and the treatment time is 50-55 min;

s1-2, in a pressure slow release stage, the treatment temperature is 85 +/-2 ℃, the environmental humidity is 80-85% RH, the contact pressure is 0.4-0.5 MPa, and the treatment time is 16-18 min;

s2, hot pressing at 132 +/-2 ℃, under the contact pressure of 2.3-2.5 MPa, for 5-6 min;

s3, in a cooling stage, keeping the pressure and naturally cooling to below 50 ℃;

s4, cold pressing at normal temperature, wherein the contact pressure is 1.3MPa to 1.5MPa, and the treatment time is 5min to 6 min.

Example 6: example 6 differs from example 5 in that the functional layer 200 comprises the following components by weight: 3.0-3.2% of main component, 14.0-14.2% of styrene-acrylic resin, 0.32-0.33% of dispersing agent, 0.14-0.17% of defoaming agent, 0.20-0.21% of flatting agent, 9.0-9.2% of film-forming assistant and the balance of water; the main component is a microemulsion type mildew-proof medicament.

In the drying stage of the single plate, single-side hot-pressing drying is carried out to dry the single plate 900 until the water content is 2% -4%, the average water content of the side A is 2%, and the average water content of the side B is 4%; the water consumption for the surface wet treatment of the veneer is 37 g/square meter to 40 g/square meter.

And in the pressure-free slow release stage, the treatment temperature is 40 +/-2 ℃, the environmental humidity is 90-92% RH, and the treatment time is 60 min.

And in the pressure slow release stage, the treatment temperature is 68 +/-2 ℃, the ambient humidity is 80-82% RH, the contact pressure is 0.4-0.5 MPa, and the treatment time is 20 min.

Example 7: example 7 is different from example 5 in that the functional layer 200 is coated on both surfaces of the body layer 100, and the thickness of the functional layer 200 is 0.030mm to 0.040 mm. The functional layer 200 comprises the following components by weight: 4.8-5% of main component, 14.9-15% of styrene-acrylic resin, 0.31-0.33% of dispersing agent, 0.23-0.25% of defoaming agent, 0.40-0.42% of flatting agent, 9.9-10% of film-forming assistant and the balance of water; the main component is a microemulsion type mildew-proof medicament.

The veneer 900 bonded in this example is 0.6mm thick, and is rotary cut fast growing poplar veneer. The adhesive for plywood of this embodiment needs to treat the veneer 900 before gluing and bonding, and in the step of veneer treatment, the following stages are included in order according to the production sequence:

s1, a veneer drying stage, namely drying a veneer 900 to the moisture content of 3% -4% by hot-press drying;

s2, in the stage of veneer surface wet treatment, two surfaces of the veneer 900 are wetted by spraying, and the water consumption for the veneer surface wet treatment is 35 g/square meter to 37 g/square meter (single-side consumption).

The wet treatment method in the wet treatment stage of the veneer surface is described with reference to example 2.

The gluing process of the adhesive for the plywood sequentially comprises the following stages according to the production sequence:

s1, in a slow release stage,

s1-1, a pressure-free slow release stage, wherein the treatment temperature is 40 +/-2 ℃, the environmental humidity is 90-92% RH, and the treatment time is 45-50 min;

s1-2, in a pressure slow release stage, the treatment temperature is 70 +/-2 ℃, the environmental humidity is 80-82% RH, the contact pressure is 0.2-0.3 MPa, and the treatment time is 5-7 min;

s2, hot pressing at 132 +/-2 ℃, under the contact pressure of 1.0-1.2 MPa, for 3-4 min;

s3, in a cooling stage, keeping the pressure and naturally cooling to below 50 ℃;

s4, cold pressing at normal temperature, wherein the contact pressure is 0.8 MPa-1.0 MPa, and the treatment time is 3 min-4 min.

Example 8: example 8 is different from example 7 in that, referring to fig. 6, the main body layer 100 has first penetration holes 110, the first penetration holes 110 are arranged in an array, the first penetration holes 110 have a hole diameter of 0.005mm to 0.080mm, and a distance between adjacent first penetration holes 110 is 0.015mm to 0.024 mm.

Example 9: example 9 is different from example 7 in that the first penetration holes 110 have a hole diameter of 0.012mm to 0.015mm and a space between adjacent first penetration holes 110 is 0.036mm to 0.045 mm.

Referring to fig. 7, the functional layer 200 has second penetration holes 210, the second penetration holes 210 are arranged in a staggered manner with respect to the first penetration holes 110, and the second penetration holes 210 have a hole diameter of 0.010mm to 0.012 mm.

The first and second penetration holes 110 and 210 of examples 8 and 9 are perforated by any of the methods of the prior art using high voltage electrical breakdown. Referring to fig. 8, the roll of the main body layer 100 and the roll of the two functional layers 200 are respectively placed on a roll, before the direction-changing roll 610, a high-pressure perforation instrument is arranged below the three films, and then the three films enter the roll set 620 to complete the pressing and the rolling under the direction-changing of the direction-changing roll 610, and finally the three films are wound again.

Example 10: example 10 is different from example 9 in that the pore diameter of the second penetration hole 210 is 0.028mm to 0.030 mm.

Product properties of multi-ply veneers (11 plies, 16.2mm thick) manufactured using the adhesive for veneers of the present application and the gluing method thereof of examples 1 to 10 are shown in table 1. The control group 1 is a common 11-layer multilayer plywood sold in the market, the control group 2 is a 11-layer multilayer plywood prepared by impregnating and modifying a single-board mildew preventive agent sold in the market, and the control group 3 is a 11-layer multilayer plywood prepared by using a non-base material type EVA adhesive film as an adhesive sold in the market.

In particular, wherein:

(1) the cold-hot cycle test is carried out for 4 times at 80 ℃ and-20 ℃;

(2) the moisture resistance test comprises placing in boiling water bath for 2h, cooling in 20 deg.C water bath for 1h, placing in 70 deg.C water bath for 16h, and testing internal bonding strength;

(3) the mildew-proof performance is executed by reference to GB/T18261-2013 test method for the control efficiency of the mildew-proof agent on wood mildew and discoloring bacteria and LY/T2230-2013 evaluation for the mildew-proof performance of the artificial board.

Table 1. adhesive for plywood and product performance parameter table of multilayer plywood manufactured by using adhesive and gluing method

The foregoing description is for the purpose of illustration and is not for the purpose of limitation. Many embodiments and many applications other than the examples provided will be apparent to those of skill in the art upon reading the above description. The scope of the present teachings should, therefore, be determined not with reference to the above description, but should instead be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled. The disclosures of all articles and references, including patent applications and publications, are hereby incorporated by reference for all purposes. The omission in the foregoing claims of any aspect of subject matter that is disclosed herein is not intended to forego the subject matter and should not be construed as an admission that the applicant does not consider such subject matter to be part of the disclosed subject matter.