阅读说明：本技术 一种蓝皮霉斑重油脂重退斑方法 (Blue skin mildew spot heavy grease heavy spot-removing method ) 是由 雷丙南 林汉彬 陈启明 杨俊昇 于 2019-12-03 设计创作，主要内容包括：本发明公开了一种蓝皮霉斑重油脂重退斑方法,包括下列步骤：将带有霉斑和/或重油脂的蓝皮作为皮坯,将皮坯、水、脱脂剂、纯碱加入转鼓中,转动50～70min；将丁酮加入转鼓中,继续转动80～100min,排液；然后进行一次洗水,排液；将水、脱脂剂、高锰酸钾加入转鼓中,转动35～45min；将焦亚硫酸钠、草酸加入转鼓中,继续转动55～68min,排液；然后进行二次洗水,排液；将水、脱脂剂、高锰酸钾加入转鼓中,转动35～45min；将焦亚硫酸钠、草酸加入转鼓中,继续转动55～65min,排液；然后进行三次洗水,干净后排液。本发明的方法具有良好的退斑效果,能够有效保证成品革的色泽均匀性。(The invention discloses a heavy grease heavy despeckle method for blue dermatomycosis, which comprises the following steps: taking blue leather with mildew and/or heavy grease as a leather blank, adding the leather blank, water, a degreasing agent and soda ash into a rotary drum, and rotating for 50-70 min; adding butanone into the rotary drum, continuously rotating for 80-100 min, and discharging liquid; then, carrying out primary washing and draining; adding water, a degreasing agent and potassium permanganate into a rotary drum, and rotating for 35-45 min; adding sodium pyrosulfite and oxalic acid into the rotary drum, continuously rotating for 55-68 min, and discharging liquid; then, carrying out secondary washing and draining; adding water, a degreasing agent and potassium permanganate into a rotary drum, and rotating for 35-45 min; adding sodium pyrosulfite and oxalic acid into the rotary drum, continuously rotating for 55-65 min, and discharging liquid; and then washing for three times, and draining after cleaning. The method has good spot-removing effect and can effectively ensure the color uniformity of finished leather.)

1. A blue dermatomycosis heavy grease heavy spot-removing method is characterized by comprising the following steps:

s1, taking blue leather with mildew stains and/or heavy grease as a leather blank, adding the leather blank into a rotary drum, adding 180-220% of water, 0.4-0.6% of degreasing agent and 0.4-0.6% of soda ash into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 50-70 min;

s2, adding 1.6-2.4% of butanone into the rotary drum according to the mass percent of the leather blank, continuously rotating for 80-100 min, discharging liquid, and checking the leather blank treatment condition;

s3, washing the leather blank treated in the step S2 with water for the first time, and discharging liquid;

s4, adding 95-105% of water, 0.25-0.35% of degreasing agent and 0.4-0.6% of potassium permanganate into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 35-45 min;

s5, adding 1.3-1.6% of sodium metabisulfite and 0.9-1.1% of oxalic acid into the rotary drum according to the mass percentage of the leather blank, and discharging liquid after continuously rotating for 55-68 min;

s6, performing secondary water washing on the leather blank processed in the step S5, and discharging liquid;

s7, adding 95-105% of water, 0.16-0.24% of degreasing agent and 0.44-0.56% of potassium permanganate into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 35-45 min;

s8, adding 1.3-1.6% of sodium metabisulfite and 0.92-1.07% of oxalic acid into the rotary drum according to the mass percentage of the leather blank, continuously rotating for 55-65 min, discharging liquid, and checking the leather blank treatment condition;

and S9, washing the leather blank processed in the step S8 for three times, and draining after cleaning.

2. The method for regressing blue dermatome plaque heavy oil and fat according to claim 1, wherein in step S1, blue skin with the plaque and/or heavy oil and fat is used as the skin blank, the skin blank is added into the rotating drum, and 200% of water, 0.5% of degreasing agent and 0.5% of soda ash are added into the rotating drum according to the mass percentage of the skin blank, the water temperature is controlled at 45 ℃, and the rotating drum rotates for 60 min.

3. The method for removing the blue dermatomyces macula heavy grease again according to claim 1, characterized in that in step S2, according to the mass percent of the dermatomyces, 2% butanone is added into the rotary drum, the liquid is discharged after the rotary drum rotates for 90min, and the processing condition of the dermatomyces is checked.

4. The method for regressing the blue dermatome plaque heavy oil and fat according to claim 1, wherein in step S4, 100% of water, 0.3% of degreasing agent and 0.5% of potassium permanganate are added into the rotary drum according to the mass percentage of the leather blank, the water temperature is controlled at 45 ℃, and the rotary drum is rotated for 40 min.

5. The method for regressing the heavy grease of blue dermatome according to claim 1, wherein in step S5, 1.5% sodium metabisulfite and 1% oxalic acid are added into the rotary drum according to the mass percentage of the leather blank, and the liquid is discharged after the rotary drum is rotated for 60 min.

6. The method for regressing the blue dermatome plaque heavy oil and fat according to claim 1, wherein in step S7, 100% of water, 0.2% of degreasing agent and 0.5% of potassium permanganate are added into the rotary drum according to the mass percentage of the leather blank, the water temperature is controlled at 45 ℃, and the rotary drum is rotated for 40 min.

7. The method for retreating the blue dermatomyces macula heavy grease heavy macula, according to the claim 1, characterized in that in step S8, according to the mass percent of the dermatomyces, 1.5% sodium metabisulfite, 1% oxalic acid are added into the rotary drum, and the liquid is discharged after continuing rotating for 60min, and the processing condition of the dermatomyces is checked.

8. The method for removing the heavy grease and the heavy grease of the blue dermatome according to claim 1, wherein in step S3, the primary washing water is: according to the mass percentage of the leather blank, 300% of water is added into the rotary drum, the water temperature is controlled to be 26-28 ℃, and liquid is discharged after the rotary drum rotates for 10 min.

9. The method for removing the heavy grease and the heavy grease of the blue dermatome according to claim 1, wherein in the step S6, the secondary washing water is: according to the mass percentage of the leather blank, 300% of water is added into the rotary drum, the water temperature is controlled to be 26-28 ℃, and liquid is discharged after the rotary drum rotates for 10 min.

10. The method for removing the heavy grease and the heavy grease of the blue dermatome according to claim 1, wherein in the step S9, the three times of washing water are as follows: firstly, adding 300% of water into a rotary drum according to the mass percentage of a blank, controlling the water temperature to be 26-28 ℃, and discharging liquid after rotating for 10 min; and then adding 200% of water into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 26-28 ℃, and discharging the liquid after rotating for 10 min.

Technical Field

The invention relates to the technical field of leather, in particular to a blue dermatomycosis heavy grease spot retreating method.

Background

The skin which is removed after the animals are slaughtered is generally called fur. The fur is easy to rot, and is generally salted by salt to form the salt-wet fur for preventing the fur from rotting, falling down, rotting pores and rotting surfaces. The salt-wet skin can be preserved for 3-5 months. Both skins and wet salt skins are collectively referred to as hides.

Hides are typically referred to as wet blue hides (blue hides) because of the blue color and moisture associated with degreasing, dehairing and chrome tanning of the hides with lime, alkali sulfide, chlorine, nitric acid and chromium powders, etc. The wet blue leather, also called as cooked leather, is generally split and is a semi-finished product in the leather processing process.

Because the wet blue leather is stored for too long time and the wet blue leather is not ripe, the blue leather mildews and generates serious mildew spots and oil spots, the mildew spots and the oil spots of the wet blue leather and natural grease must be removed firstly in the leather making process so as to ensure the quality of the final finished leather.

However, the currently used methods of despeckle still have the following problems:

1. the spot-removing effect is poor, if the blue leather is processed into color leather, the problem of uneven color can occur, even if the blue leather is dyed with black color, the original shape of the finished leather can be completely exposed after the finished leather is exposed to sunlight;

2. the treatment agent and other chemical raw materials used in the process steps are not friendly to the environment and human bodies, and cause secondary pollution;

3. the process steps are complex, the operation is inconvenient, the cost is high, and the popularization and the application are not facilitated.

Disclosure of Invention

Based on the situation, the invention aims to provide a method for removing blue dermatomycosis heavy grease spot, which can effectively solve the problems.

In order to solve the technical problems, the technical scheme provided by the invention is as follows:

a method for removing blue dermatomycosis heavy grease heavy stain comprises the following steps:

s1, taking blue leather with mildew stains and/or heavy grease as a leather blank, adding the leather blank into a rotary drum, adding 180-220% of water, 0.4-0.6% of degreasing agent and 0.4-0.6% of soda ash into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 50-70 min;

s2, adding 1.6-2.4% of butanone into the rotary drum according to the mass percent of the leather blank, continuously rotating for 80-100 min, discharging liquid, and checking the leather blank treatment condition;

s3, washing the leather blank treated in the step S2 with water for the first time, and discharging liquid;

s4, adding 95-105% of water, 0.25-0.35% of degreasing agent and 0.4-0.6% of potassium permanganate into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 35-45 min;

s5, adding 1.3-1.6% of sodium metabisulfite and 0.9-1.1% of oxalic acid into the rotary drum according to the mass percentage of the leather blank, and discharging liquid after continuously rotating for 55-68 min;

s6, performing secondary water washing on the leather blank processed in the step S5, and discharging liquid;

s7, adding 95-105% of water, 0.16-0.24% of degreasing agent and 0.44-0.56% of potassium permanganate into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 42-48 ℃, and rotating for 35-45 min;

s8, adding 1.3-1.6% of sodium metabisulfite and 0.92-1.07% of oxalic acid into the rotary drum according to the mass percentage of the leather blank, continuously rotating for 55-65 min, discharging liquid, and checking the leather blank treatment condition;

and S9, washing the leather blank processed in the step S8 for three times, and draining after cleaning.

Preferably, in step S1, the blue leather with mildew and/or heavy grease is used as a leather blank, the leather blank is added into a rotary drum, and 200% of water, 0.5% of degreasing agent and 0.5% of soda ash are added into the rotary drum according to the mass percentage of the leather blank, the water temperature is controlled at 45 ℃, and the rotary drum is rotated for 60 min.

Preferably, in step S2, 2% of butanone is added into the rotary drum according to the mass percentage of the leather blank, the liquid is discharged after the rotary drum continuously rotates for 90min, and the leather blank processing condition is checked;

preferably, in step S4, 100% of water, 0.3% of degreasing agent and 0.5% of potassium permanganate are added into the rotating drum according to the mass percentage of the leather blank, the water temperature is controlled at 45 ℃, and the rotating drum is rotated for 40 min.

Preferably, in step S5, 1.5% of sodium metabisulfite and 1% of oxalic acid are added into the rotary drum according to the mass percentage of the blank, and the rotary drum is rotated for 60min to discharge liquid.

Preferably, in step S7, 100% of water, 0.2% of degreasing agent and 0.5% of potassium permanganate are added into the rotating drum according to the mass percentage of the leather blank, the water temperature is controlled at 45 ℃, and the rotating drum rotates for 40 min.

Preferably, in step S8, 1.5% of sodium metabisulfite and 1% of oxalic acid are added into the rotary drum according to the mass percentage of the blank, and the blank is discharged after rotating for 60min, and the blank treatment condition is checked.

Preferably, in step S3, the primary washing water is: adding 300% of water into a rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 26-28 ℃, and discharging liquid after rotating for 10 min; in step S6, the secondary washing water is: according to the mass percentage of the leather blank, 300% of water is added into the rotary drum, the water temperature is controlled to be 26-28 ℃, and liquid is discharged after the rotary drum rotates for 10 min.

Preferably, in step S9, the third washing water is: firstly, adding 300% of water into a rotary drum according to the mass percentage of a blank, controlling the water temperature to be 26-28 ℃, and discharging liquid after rotating for 10 min; and then adding 200% of water into the rotary drum according to the mass percentage of the leather blank, controlling the water temperature to be 26-28 ℃, and discharging the liquid after rotating for 10 min.

The blue leather obtained by the blue leather mildew heavy grease heavy stain removing method can be directly used for the subsequent leather manufacturing and processing steps and can be processed into finished leather products such as color leather and the like at the later stage.

Compared with the prior art, the invention has the following advantages and beneficial effects:

the heavy grease heavy stain removing method for blue dermatomyces has the advantages that the order of the steps of the stain removing process (method) is reasonably controlled, the process condition parameters of the steps are strictly controlled (the control of the process condition parameters is the key for obtaining good stain removing effect, and the good stain removing effect can be ensured only if the process condition parameters are controlled within a proper range), so that the method has good stain removing effect, can effectively ensure that the blue leather is processed into finished leather such as color leather at the later stage, and the finished leather has uniform color.

The leather blank is firstly degreased for the first time by performing saponification and emulsification twice in water through the degreasing agent and the soda ash, so that the degreasing effect is good; removing the redundant degreasing agent by butanone; then, degreasing the leather blank for the second time by using a degreasing agent, and performing primary fading treatment on the leather blank by using potassium permanganate; then carrying out primary neutralization treatment on potassium permanganate through sodium metabisulfite and oxalic acid; then, degreasing the leather blank for the third time by using a degreasing agent, and performing secondary fading treatment on the leather blank by using potassium permanganate; then, the potassium permanganate is subjected to secondary neutralization treatment by sodium metabisulfite and oxalic acid.

The heavy grease heavy stain removing method for blue dermatomyces has the advantages that the order of the steps of the stain removing process (method) is reasonably controlled, the process condition parameters of the steps are strictly controlled (the control of the process condition parameters is the key for obtaining good stain removing effect, and the good stain removing effect can be ensured only if the process condition parameters are controlled within a proper range), so that the method has good stain removing effect, can effectively ensure that the blue leather is processed into finished leather such as color leather at the later stage, and the finished leather has uniform color.

The treatment agent and other chemical raw materials used in the process steps of the method for removing the blue dermatomycosis heavy grease are all water-soluble, are friendly to the environment and human body, and effectively avoid secondary pollution.

The method for removing the blue dermatomycosis heavy grease spot has the advantages of simple process steps, convenience in operation, capability of saving the production cost and good popularization and application prospects.

Detailed Description

In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.

The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.