阅读说明：本技术 一种无机密封材料及其在点火电嘴上的应用方法 (Inorganic sealing material and application method thereof on ignition nozzle ) 是由 万思明 乌凯 党腾华 于 2019-10-30 设计创作，主要内容包括：本申请属于火电嘴密封技术领域,涉及一种无机密封材料及其在点火电嘴上的应用方法。该方法包括装配半导体块(1)、中心电极(6),并用螺母固定到壳体(5)上；将由所述无机密封材料形成的第一份胶粒装填至所述腔体内；将中心绝缘体(4)装填至所述腔体内,加热并压紧；将由所述无机密封材料形成的第二份胶粒装填至所述腔体内；将后端绝缘体(8)装填至所述腔体内,加热并压紧。通过该方法提高了点火电嘴高温下质量稳定性,提高了点火电嘴的使用寿命。(The application belongs to the technical field of ignition nozzle sealing, and relates to an inorganic sealing material and an application method thereof on an ignition nozzle. The method comprises assembling a semiconductor block (1), a center electrode (6) and fixing to a case (5) with a nut; filling a first portion of colloidal particles formed from the inorganic sealing material into the cavity; filling a central insulator (4) into the cavity, heating and pressing; filling a second portion of colloidal particles formed from the inorganic sealing material into the cavity; and filling a rear end insulator (8) into the cavity, heating and pressing. By the method, the quality stability of the ignition electric nozzle at high temperature is improved, and the service life of the ignition electric nozzle is prolonged.)

1. An inorganic sealing material, comprising:

independently calcining silicon dioxide, aluminum oxide, calcium oxide, boron trioxide, magnesium oxide and sodium oxide at a first temperature, ball-milling and sieving; and then mixing, and calcining the mixture at a second temperature, ball-milling and sieving to form the inorganic sealing material, wherein the first temperature is 850-950 ℃, and the second temperature is 1250-1350 ℃.

2. A method of applying an inorganic sealing material to an ignition nozzle, wherein the ignition nozzle comprises a housing (5) and a center electrode assembly (6) disposed in the housing (5), and a cavity between the housing (5) and the center electrode assembly (6) comprises a semiconductor block (1), a center insulator (4), and a rear insulator (8) in this order from front to rear, and the inorganic sealing material is used for sealing according to claim 1, wherein the method comprises:

step S1, assembling the semiconductor block (1) and the center electrode (6) and fixing the semiconductor block and the center electrode to the shell (5) by using a nut;

step S2, filling a first part of colloidal particles formed by the inorganic sealing material into the cavity;

step S3, filling a central insulator (4) into the cavity and pressing the central insulator;

step S4, filling a second part of colloidal particles formed by the inorganic sealing material into the cavity;

and step S5, filling the rear-end insulator (8) into the cavity and pressing.

3. The method of applying the inorganic sealing material to an ignition nozzle as set forth in claim 2, wherein the inorganic sealing material is sintered at 1200 ℃ for 30min and then crushed to form the first part of the colloidal particles in step S2.

4. The method of claim 3 wherein said first portion of colloidal particles have a size of no greater than 1.5 mm.

5. The method of applying an inorganic sealing material to an ignition nozzle as set forth in claim 2, wherein the step S3 further comprises heating the ignition nozzle at a position where the first portion of the colloidal particles are filled.

6. The method of applying an inorganic sealing material to an ignition tip according to claim 5, wherein the ignition tip is heated by an induction coil.

7. The method of applying an inorganic sealing material to an ignition nozzle as set forth in claim 2, wherein step S3 is followed by further comprising performing a hermetic seal test on the ignition nozzle.

8. The method of applying an inorganic sealing material to an ignition nozzle as set forth in claim 2, wherein the step S4 further comprises heating the ignition nozzle at a position where the second portion of the colloidal particles are filled.

9. The method of applying an inorganic sealing material to an ignition nozzle as set forth in claim 2, wherein step S4 is followed by further comprising performing a hermetic seal test on the ignition nozzle.

Technical Field

The application belongs to the technical field of ignition nozzle sealing, and particularly relates to an inorganic sealing material and an application method thereof on an ignition nozzle.

Background

The ignition electric nozzle is an important accessory of an aircraft engine, more than ten ignition electric nozzles are sealed by sealing materials, and the type of ignition electric nozzle has the characteristics of large volume, relatively more parts, simple process method and suitability for mass production; the defects are that the fluctuation of heat sealing parameters is large when an induction coil is used for heating, and the product consistency can be different.

The biggest defect of prior art is that, when the part of filling sealing material appears the hole or is loose when, the sealed integrative structure of the inside gluey of ignition nozzle suffers destruction, and ignition nozzle is long-term work under engine high temperature, vibration environment, causes gas leakage scheduling problem easily.

Through analysis, the biggest defect of the existing ignition nozzle is that the sealing material does not fully play a role in fixing and sealing at high temperature. The main reasons are as follows: the dosage of the sealing material is small, and because the temperature of the discharge end of the ignition nozzle is high, the sealing length can be ensured to meet the requirement of the length of a high-temperature area of the ignition nozzle by a sufficient amount; the heat preservation time at high temperature is short when the sealing material is subjected to heat sealing. The short holding time makes the sealing material not fully fill the gaps around the semiconductor block and the pores around the special nut after melting, and the short holding time also makes the sealing material not fully vitrified. The sealing material and two ends of the sealing material are firstly loosened in the working process due to the reasons, and the whole glue sealing structure of the ignition nozzle is loosened along with the prolonging of the working time, so that the air leakage of the ignition nozzle is finally caused.

Disclosure of Invention

In order to solve at least one of the above technical problems, the present application provides an inorganic sealing material, and also provides an application of the inorganic sealing material to an ignition nozzle.

The present application provides, in a first aspect, an inorganic sealing material comprising:

independently calcining silicon dioxide, aluminum oxide, calcium oxide, boron trioxide, magnesium oxide and sodium oxide at a first temperature, ball-milling and sieving; and then mixing, and calcining the mixture at a second temperature, ball-milling and sieving to form the inorganic sealing material, wherein the first temperature is 850-950 ℃, and the second temperature is 1250-1350 ℃.

A second aspect of the present application provides a method of applying an inorganic sealing material to an ignition nozzle, the ignition nozzle comprising a housing and a center electrode assembly disposed in the housing, a cavity between the housing and the center electrode assembly comprising a semiconductor block, a center insulator and a rear insulator in that order from front to rear, the inorganic sealing material of claim 1 being used for sealing, the method comprising:

step S1, assembling the semiconductor block, the center electrode, and fixing to the case with a nut;

step S2, filling a first part of colloidal particles formed by the inorganic sealing material into the cavity;

step S3, filling a central insulator into the cavity and pressing the central insulator;

step S4, filling a second part of colloidal particles formed by the inorganic sealing material into the cavity;

and step S5, filling the rear-end insulator into the cavity and compressing the rear-end insulator.

Preferably, in step S2, the first colloidal particles are formed by crushing after sintering the inorganic sealing material at 1200 ℃ for 30 min.

Preferably, the size of the first portion of the billet is not greater than 1.5 mm.

Preferably, the step S3 further includes heating the position of the ignition nozzle where the first portion of the rubber particles are filled.

Preferably, the ignition torch is heated by an induction coil.

Preferably, step S3 is followed by further detecting the airtightness of the ignition nozzle.

Preferably, the step S4 further includes heating the position of the ignition nozzle where the second portion of the rubber particles are filled.

Preferably, step S4 is followed by further detecting the airtightness of the ignition nozzle.

The invention solves the problem of air leakage after the ignition electric nozzle works for a long time by improving the application method of the inorganic sealing material G8909 on the ignition electric nozzle, and prolongs the service life of the ignition electric nozzle.

Drawings

Fig. 1 is a schematic view of an ignition torch according to an embodiment of the present application.

Fig. 2 is a flow chart of an ignition torch assembly according to an embodiment of the present application.

1-semiconductor block; 2-inorganic sealing material G8909; 3-a screw cap; 4-a central insulator; 5-a shell; 6-a central electrode assembly; 7-inorganic sealing material G8909; 8-a back-end insulator; b is the boundary of twice G8909.

Detailed Description

In order to make the implementation objects, technical solutions and advantages of the present application clearer, the technical solutions in the embodiments of the present application will be described in more detail below with reference to the accompanying drawings in the embodiments of the present application. In the drawings, the same or similar reference numerals denote the same or similar elements or elements having the same or similar functions throughout. The described embodiments are some, but not all embodiments of the present application. The embodiments described below with reference to the drawings are exemplary and intended to be used for explaining the present application, and should not be construed as limiting the present application. All other embodiments obtained by a person of ordinary skill in the art without any inventive work based on the embodiments in the present application are within the scope of protection of the present application. Embodiments of the present application will be described in detail below with reference to the drawings.

The method for applying the inorganic sealing material of the present invention to the ignition tip, as shown in fig. 1, for example, comprises an inorganic sealing material 1 of a semiconductor block, a special nut 3, a center insulator 4, a case 5, a center electrode assembly 6, an inorganic sealing material 7, and a rear end insulator 8, wherein the inorganic sealing material G89092 is disposed at a position 1 and the inorganic sealing material G89097 is disposed at a position 7, the inorganic sealing material G89092 and the inorganic sealing material G89097 are subjected to heat sealing twice, the inorganic sealing material G8909 is subjected to sintering treatment before the heat sealing, and the amounts of the inorganic sealing materials G89092 and G89097 and the heat sealing parameters are adjusted.

Fig. 2 shows a flow chart of the application of the inorganic sealing material on the ignition nozzle, which mainly comprises the following steps:

1. the semiconductor block 1 is fitted over the center electrode assembly 6, tightened with the special nut 3, and the center electrode assembly 6 and the special nut 3 are spot welded together after tightening. The above components are then loaded into the housing 5.

2. Sintering the inorganic sealing material G8909 at 1200 ℃ in an electric furnace in an oxidizing atmosphere, preserving the heat for 30min, cutting off the power, and naturally cooling to room temperature. Crushing the sintered material block into small colloidal particles with the particle size not larger than 1.5mm, and taking out impurities in the small colloidal particles;

3. 1G of the colloidal particles of the inorganic sealing material G89092 was charged into the case 5 and pressed with a swage bar, and then charged into the insulator 4. Heating with induction coil, heating current 4A, and maintaining for 2min30 s.

4. The ignition electric nozzle is tested to be airtight under the air pressure of 0.43 MPa.

5. 0.6G of the colloidal particles of the inorganic sealing material G89097 was charged into the case 5 and pressed with a swage bar, and then charged into the insulator 8. Heating with induction coil, heating current 4A, and maintaining for 2min30 s.

6. And testing the ignition electric nozzle to be airtight under the air pressure of 0.43MPa, testing the minimum discharge voltage and the like, and performing the next procedure after the ignition electric nozzle is qualified.

The invention provides an application method of inorganic sealing material on the ignition electric nozzle, and the produced ignition electric nozzle has good comprehensive performance, no air leakage under the air pressure of 0.43MPa, qualified performance of discharge voltage and the like, and good appearance. The workability is good, and the qualification rate of the product is high. Especially, the quality stability of the ignition electric nozzle at high temperature is improved, and the service life of the ignition electric nozzle is prolonged.

The inorganic sealing materials G89092 and G89097 are the same material, and are prepared by calcining a plurality of oxides such as silicon dioxide, aluminum oxide, calcium oxide, diboron trioxide, magnesium oxide, sodium oxide and the like (keeping the temperature of the silicon dioxide at 900 ℃ for 2h, keeping the temperature of the aluminum oxide at 1450 ℃ for 2h), ball-milling, sieving, mixing according to the proportion (the silicon dioxide: the aluminum oxide: the calcium oxide: the diboron trioxide: the magnesium oxide: the sodium oxide: 55: 14: 16: 9: 4: 2), calcining (keeping the temperature at 1300 ℃ for 3h), ball-milling for 36h, sieving with a 250-mesh sieve, and drying. The sealing temperature is 1150 ℃, the long-term use temperature can reach 1000 ℃, the consumption of the material is increased when the ignition nozzle is in heat sealing, the heat preservation time at high temperature is properly prolonged when in heat sealing, the material achieves the optimal sintering effect, the requirement of high temperature resistance of the ignition nozzle in an engine can be met, and the ignition nozzle can always keep good air tightness in the working process.

The insulator 4 and the insulator 8 of the present invention are both 95% alumina ceramic materials, and the insulator 4 and the insulator 8 function to position, insulate, and compress the inorganic sealing materials G89092 and G89097 in the ignition nozzle. The insulator 4 and the insulator 8 are bonded by the inorganic sealing materials G89092 and G89097, so that the inside of the ignition nozzle is formed into an insulating and air-tight whole.

The semiconductor 1 of the present invention is a sintered body of a silicon carbide ceramic material, and is a key material of an ignition tip capable of discharging at a low voltage.

The shell 5 is made of GH3044 high-temperature alloy, and the ignition nozzle is used for forming the appearance of the ignition nozzle and fixing internal components of the ignition nozzle. The housing 5 also functions as an electrode of the ignition torch.

The material of the central electrode 6 is 4J29 sealing alloy, which is the other electrode of the ignition nozzle.

According to the invention, the powder material during the heat sealing of the inorganic sealing material G89092 in the original process is sintered and crushed into colloidal particles smaller than 1.5mm, the dosage of the inorganic sealing material G89092 is increased from 0.5G to 1G, and the retention time under 4A during the heat sealing is prolonged from 1min30s to 2min30s, so that on one hand, the vitrification effect of the inorganic sealing material G89092 is optimal, the inorganic sealing material G89092 can permeate into each gap, the defect of the heat sealing position is avoided, the sealing length of the inorganic sealing material G89092 is prolonged, and the reliability of the air tightness of the ignition electric nozzle in a high-temperature environment is enhanced.

The invention eliminates the original DM308 sealant 7 and replaces the original DM308 sealant with an inorganic sealing material G89097. The cementing temperature of the DM308 sealant 7 is 850 ℃, the long-term use temperature is 600 ℃, and the DM308 sealant 7 can lose effectiveness under the condition of slight abnormal temperature rise. Therefore, the reliability of the ignition nozzle is obviously improved by replacing the ignition nozzle with the inorganic sealing material G89097 which has higher temperature resistance.

After a comparison test at high temperature in a factory, the processed ignition electric nozzle sample piece is superior to the ignition electric nozzle before improvement.

The application method of the inorganic sealing material G8909 on the ignition nozzle is characterized in that the powder material during the heat sealing of the inorganic sealing material G89092 is changed into colloidal particles with the particle size less than 1.5mm, which is beneficial to increasing the weight of the inorganic sealing material G89092 in unit volume and reducing the defects after heat sealing.

The application method of the inorganic sealing material G89092 on the ignition nozzle is characterized in that the using amount of the inorganic sealing material G89092 is set to be 1G, and the holding time under 4A during heat sealing is set to be 2min30s, so that on one hand, the vitrification effect of the inorganic sealing material G89092 is optimal, the inorganic sealing material G89092 can permeate into gaps, the defects of the heat sealing position are avoided, meanwhile, the sealing length of the inorganic sealing material G89092 is prolonged, and the reliability of the air tightness of the ignition nozzle in a high-temperature environment is enhanced.

The application method of the inorganic sealing material G8909 on the ignition nozzle is characterized in that the original DM308 sealant 7 is eliminated and replaced by the inorganic sealing material G89097. The cementing temperature of the DM308 sealant 7 is 850 ℃, the long-term use temperature is 600 ℃, and the DM308 sealant 7 can fail under the condition of slight abnormal temperature rise. Therefore, the reliability of the ignition nozzle is obviously improved by replacing the ignition nozzle with the inorganic sealing material G89097 which has higher temperature resistance.

The above description is only for the specific embodiments of the present application, but the scope of the present application is not limited thereto, and any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present application should be covered within the scope of the present application. Therefore, the protection scope of the present application shall be subject to the protection scope of the claims.