阅读说明：本技术 一种用于铝板生产用脱脂液 (Degreasing fluid for aluminum plate production ) 是由 俞金发 朱良科 林士兵 于 2021-07-26 设计创作，主要内容包括：本发明涉及金属表面处理技术领域,尤其涉及一种用于铝板生产用脱脂液及其制备方法。所述脱脂液由强碱、椰油酰基甲基牛磺酸钠、直链烷基磺酸钠、缓蚀剂、乳化剂、螯合剂、表面活性剂、去离子水组成。本发明所提供的脱脂液渗透性强,脱脂时间短,脱脂率高,室温25℃下也能快速有效清除属表面的油污。本发明采用的原料不含磷元素,无毒,环保,对环境的污染程度小,使用安全方便。(The invention relates to the technical field of metal surface treatment, in particular to degreasing fluid for aluminum plate production and a preparation method thereof. The degreasing solution consists of strong alkali, sodium cocoyl methyl taurate, linear alkyl sodium sulfonate, a corrosion inhibitor, an emulsifier, a chelating agent, a surfactant and deionized water. The degreasing fluid provided by the invention has strong permeability, short degreasing time and high degreasing rate, and can quickly and effectively remove oil stains on the surface at room temperature of 25 ℃. The raw materials adopted by the invention do not contain phosphorus element, are nontoxic and environment-friendly, have small pollution degree to the environment and are safe and convenient to use.)

1. The degreasing fluid for producing the aluminum plate is characterized by comprising the following raw materials in parts by weight: 4-6 parts of sodium hydroxide, 10-20 parts of sodium cocoyl methyl taurate, 6-10 parts of sodium dodecyl sulfate, 10-20 parts of sodium metasilicate pentahydrate, 1-3 parts of sodium pyrophosphate, 1-5 parts of sodium tetrapolyphosphate, 2-6 parts of tetrasodium EDTA, 2-6 parts of sodium gluconate, 15-25 parts of isomeric tridecanol polyoxyethylene ether and 75-90 parts of deionized water.

2. The degreasing fluid of claim 1, wherein the strong base comprises one or a combination of two or more of sodium hydroxide, magnesium hydroxide, and potassium hydroxide.

3. The degreasing fluid of claim 1, wherein the linear alkyl sodium sulfonate is sodium dodecyl sulfonate.

4. The degreasing fluid of claim 1, wherein the corrosion inhibitor is sodium metasilicate pentahydrate.

5. The degreasing fluid as claimed in claim 1, wherein the emulsifier comprises one or more of sodium pyrophosphate, potassium pyrophosphate, sodium tripolyphosphate, potassium tripolyphosphate, sodium tetrapolyphosphate, sodium metaphosphate, potassium metaphosphate, sodium trimetaphosphate, potassium polymetaphosphate and sodium hexametaphosphate.

6. The degreasing fluid as claimed in claim 1, wherein the emulsifier is a combination of sodium pyrophosphate and sodium tetrapolyphosphate.

7. The degreasing fluid of claim 1, wherein the chelating agent comprises one or more of sodium gluconate, disodium EDTA, tetrasodium EDTA, monoethanolamine, diethanolamine, and triethanolamine.

8. The degreasing fluid as claimed in claim 1, wherein the surfactant comprises one or more of polyoxyethylene octyl phenol ether, fatty alcohol polyoxyethylene ether, octyl phenol polyoxyethylene ether, nonyl phenol polyoxyethylene ether, and fatty acid polyoxyethylene ester.

9. A method for preparing the degreasing fluid for aluminum plate production as recited in claims 1-8, wherein the method comprises the following steps:

(1) sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 30-35 rpm for 10-20 min to obtain a mixture A.

(2) And (2) adding sodium cocoyl methyl taurate, sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring at a stirring speed of 30-35 rpm for 25-30 min to obtain a mixture B.

(3) And (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 25-30 rpm for 10-20 min to obtain the sodium hydroxide.

Technical Field

The invention relates to the technical field of metal surface treatment, in particular to degreasing fluid for aluminum plate production and a preparation method thereof.

Background

In the surface treatment and processing of metal workpieces, many oil and fat auxiliaries such as petroleum derivatives (mineral oil), animal oil and fat, vegetable oil and fat, and the like are used, such as rust preventive oil, cutting oil, punching oil, cooling liquid, lubricating oil, and the like. These grease-based auxiliaries are important for protecting workpieces and equipment from rusting, corrosion, and the like. At the same time, however, when the workpieces and materials are to be made into final products, the grease-based auxiliary agents must be removed from the surfaces of the workpieces, which may affect other processes and even cause serious product scrap. Therefore, how to effectively remove oil from the surface of a workpiece is a common problem faced by almost all manufacturing industries.

In the oxidation treatment process of the aluminum plate, grease impurities on the metal surface need to be removed by using degreasing fluid, and the quality of the degreasing fluid is directly related to the effect of the subsequent surface treatment of the aluminum alloy, so that improvement and research on the degreasing fluid are necessary and critical, but the degreasing fluid with good degreasing effect is still lacked in the current market

Based on the situation, the invention provides degreasing fluid for aluminum plate production and a preparation method thereof, which can effectively solve the problems.

Disclosure of Invention

The invention aims to provide degreasing fluid for aluminum plate production and a preparation method thereof.

In order to achieve the purpose, the invention provides degreasing fluid for producing an aluminum plate, which consists of strong alkali, sodium cocoyl methyl taurate, linear alkyl sodium sulfonate, a corrosion inhibitor, an emulsifier, a chelating agent, a surfactant and deionized water.

Preferably, the strong base comprises one or a combination of more than two of sodium hydroxide, magnesium hydroxide and potassium hydroxide.

Preferably, the linear alkyl sodium sulfonate is sodium dodecyl sulfonate.

Preferably, the corrosion inhibitor is sodium metasilicate pentahydrate.

Preferably, the emulsifier comprises one or more of sodium pyrophosphate, potassium pyrophosphate, sodium tripolyphosphate, potassium tripolyphosphate, sodium tetrapolyphosphate, sodium metaphosphate, potassium metaphosphate, sodium trimetaphosphate, potassium polymetaphosphate and sodium hexametaphosphate.

Preferably, the emulsifier is a combination of sodium pyrophosphate and sodium tetrapolyphosphate.

The chelating agent comprises one or more of sodium gluconate, disodium EDTA, tetrasodium EDTA, monoethanolamine, diethanolamine and triethanolamine.

Preferably, the chelating agent is a combination of tetrasodium EDTA and sodium gluconate.

Preferably, the surfactant comprises one or a combination of more than two of polyoxyethylene octyl phenol ether, fatty alcohol polyoxyethylene ether, octyl phenol polyoxyethylene ether, nonylphenol polyoxyethylene ether and fatty acid polyoxyethylene ester.

Preferably, the fatty alcohol-polyoxyethylene ether comprises one or a combination of more than two of isooctanol polyoxyethylene ether, lauryl alcohol polyoxyethylene ether and isomeric alcohol polyoxyethylene ether.

Preferably, the isomeric alcohol polyoxyethylene ether is isomeric tridecanol polyoxyethylene ether.

Preferably, the degreasing fluid consists of the following raw materials in parts by weight: 4-6 parts of sodium hydroxide, 10-20 parts of sodium cocoyl methyl taurate, 6-10 parts of sodium dodecyl sulfate, 10-20 parts of sodium metasilicate pentahydrate, 1-3 parts of sodium pyrophosphate, 1-5 parts of sodium tetrapolyphosphate, 2-6 parts of tetrasodium EDTA, 2-6 parts of sodium gluconate, 15-25 parts of isomeric tridecanol polyoxyethylene ether and 75-90 parts of deionized water.

Preferably, the degreasing fluid consists of the following raw materials in parts by weight: 4 parts of sodium hydroxide, 10 parts of sodium cocoyl methyl taurate, 6 parts of sodium dodecyl sulfate, 10 parts of sodium metasilicate pentahydrate, 1 part of sodium pyrophosphate, 1 part of sodium tetrapolyphosphate, 2 parts of EDTA tetrasodium, 2 parts of sodium gluconate, 15 parts of isomeric tridecanol polyoxyethylene ether and 75 parts of deionized water.

Preferably, the degreasing fluid consists of the following raw materials in parts by weight: 6 parts of sodium hydroxide, 20 parts of sodium cocoyl methyl taurate, 10 parts of sodium dodecyl sulfate, 20 parts of sodium metasilicate pentahydrate, 3 parts of sodium pyrophosphate, 5 parts of sodium tetrapolyphosphate, 6 parts of EDTA tetrasodium, 6 parts of sodium gluconate, 25 parts of isomeric tridecanol polyoxyethylene ether and 90 parts of deionized water.

The invention also provides a preparation method of the degreasing fluid for producing the aluminum plate, which comprises the following steps:

(1) sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 30-35 rpm for 10-20 min to obtain a mixture A;

(2) adding sodium cocoyl methyl taurate, sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring at a stirring speed of 30-35 rpm for 25-30 min to obtain a mixture B;

(3) and (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 25-30 rpm for 10-20 min to obtain the sodium hydroxide.

Compared with the prior art, the invention has the following beneficial effects:

1. the degreasing fluid provided by the invention has strong permeability, short degreasing time and high degreasing rate, and can quickly and effectively remove oil stains on the surface at room temperature of 25 ℃.

2. The raw materials adopted by the invention do not contain phosphorus element, are nontoxic and environment-friendly, have small pollution degree to the environment and are safe and convenient to use.

3. The raw materials of the invention are sufficient in China and proper in price, so that the large-scale production of the invention is not limited by too high cost; meanwhile, the preparation method is simple, the total production cost is low, and the industrial large-scale production is facilitated.

Detailed Description

Example 1

The specific raw materials were weighed as in table 1, and the preparation steps were as follows:

(1) sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 30rpm for 20min to obtain a mixture A;

(2) adding sodium cocoyl methyl taurate, sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring for 30min at a stirring speed of 30rpm to obtain a mixture B;

(3) and (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 25rpm for 20min to obtain the compound.

Example 2

The specific raw materials were weighed as in table 1, and the preparation steps were as follows:

(1) sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 35rpm for 10min to obtain a mixture A;

(2) adding sodium cocoyl methyl taurate, sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring at a stirring speed of 35rpm for 25min to obtain a mixture B;

(3) and (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 30rpm for 10min to obtain the compound.

Example 3

The specific raw materials were weighed as in table 1, and the preparation steps were as follows:

(1) sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 30rpm for 20min to obtain a mixture A;

(2) adding sodium cocoyl methyl taurate, sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring for 30min at a stirring speed of 30rpm to obtain a mixture B;

(3) and (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 30rpm for 10min to obtain the compound.

Comparative example 1

(1) Sequentially adding water, sodium metasilicate pentahydrate, sodium pyrophosphate, sodium tetrapolyphosphate, EDTA tetrasodium and sodium gluconate into a stirring device, and mixing and stirring at a stirring speed of 30rpm for 20min to obtain a mixture A;

(2) adding sodium dodecyl sulfate and isomeric tridecanol polyoxyethylene ether into the mixture A obtained in the step (1), and mixing and stirring for 30min at a stirring speed of 30rpm to obtain a mixture B;

(3) and (3) adding sodium hydroxide into the mixture B obtained in the step (2), and mixing and stirring at a stirring speed of 30rpm for 10min to obtain the compound.

TABLE 1

Kind of material	Example 1	Example 2	Example 3	Comparative example 1
					Sodium hydroxide	4	5	6	6
Sodium cocoyl methyl taurate	10	15	20	/
					Sodium dodecyl sulfate	6	8	10	10
Sodium metasilicate pentahydrate	10	15	20	20
					Pyrophosphoric acid sodium salt	1	2	3	3
Tetrapolyphosphoric acid sodium salt	1	3	5	5
					Tetrasodium EDTA	2	4	6	6
Sodium gluconate	2	4	6	6
					Isomeric tridecanol polyoxyethylene ether	15	20	25	25
Deionized water	75	80	90	110

Example 4 degreasing effect test

The copper plate, the aluminum plate and the zinc plate are respectively cut into 10 multiplied by 20 to be used as sample pieces, after weighing is carried out to obtain M1, the sample pieces are immersed into lubricating oil to be oiled, and after standing for 3min, the weight of the oiled sample piece is weighed to be M2. Heating the degreasing solution to 55 ℃, soaking the degreased sample pieces into the degreasing solutions of examples 1-3 and comparative example 1 for 1, 3 and 5min respectively, draining, weighing the sample pieces, wherein the weight of each sample piece is M3, M4 and M5, the degreasing rate is (M2-Mn)/(M2-M1), and n is 3, 4 and 5. The test results are shown in Table 2.

And taking the degreasing fluids of the examples 1-3 and the comparative example 1, preserving the heat at 25 ℃ for 10-20 min, and degreasing the aluminum plate, wherein the test results are shown in Table 3.

TABLE 2 degreasing effect test results (55 deg.C)

TABLE 3 degreasing effect test results (25 deg.C)

	Example 1	Example 2	Example 3	Comparative example 1
					Defatting rate at 1 min%	70％	68％	69％	46％
Defatting rate at 3 min%	82％	80％	81％	58％
					Defatting rate at 5 min%	97％	95％	96％	70％

The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. It is not intended to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the above teaching. The exemplary embodiments were chosen and described in order to explain certain principles of the invention and its practical application to enable one skilled in the art to make and use various exemplary embodiments of the invention and various alternatives and modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the claims and their equivalents.