阅读说明：本技术 作为穿刺元件的夹带矿物的塑料配制品 (Mineral-entrained plastic formulations as piercing elements ) 是由 R·基柏乐 A·艾尔特兹奇德 于 2018-05-02 设计创作，主要内容包括：披露了穿刺元件以及使用其的方法。根据所披露的概念的穿刺元件包括切割边缘或尖部,并且由负载矿物的聚合物组成。所述负载矿物的聚合物中的矿物包含活性剂,例如干燥剂。任选地,所述穿刺元件用于刺穿包装的盖(例如箔密封件)。(Lancing elements and methods of using the same are disclosed. The piercing element according to the disclosed concept includes a cutting edge or tip and is composed of a mineral-laden polymer. The mineral in the mineral-loaded polymer comprises an active agent, such as a desiccant. Optionally, the piercing element is used to pierce a lid (e.g., a foil seal) of the package.)

1. A method for dispensing a product from a package, the method comprising the steps of:

a. Providing a package having a base and a sidewall extending therefrom, the base and sidewall defining an interior of the package, the package further having an opening to the interior and having a lid that seals the opening when the package is in a sealed position to enclose a product therein, the package further comprising a piercing element disposed in the interior, the piercing element having a cutting edge or tip that faces the lid, wherein the piercing element is comprised of a mineral-laden polymer comprising a monolithic material formed of at least a base polymer and a mineral-containing active agent;

b. Inserting the package into a dispensing apparatus; and

c. Activating the dispensing device such that pressure is exerted on the lid in a direction perpendicular to the cutting edge or the tip until the cutting edge or the tip pierces or separates at least part of the lid, thereby transitioning the package from the sealed position to a dispensing position in which the product is dispensed through the opening.

2. The method of claim 1, wherein the monolithic material comprises a channeling agent.

3. The method of claim 1 or 2, wherein the active agent is a desiccant, optionally a molecular sieve or silica gel.

4. The method of any preceding claim, wherein the mineral-loaded polymer has a mineral loading level of up to 50% by weight of the monolith.

5. The method of any preceding claim, wherein the mineral-loaded polymer has a mineral loading level of from 20% to 50%, optionally from 30% to 50%, by weight of the monolith.

6. The method of claim 5, wherein the active agent is a desiccant that absorbs moisture from the interior of the package in order to maintain a desired quality of the product.

7. a method as claimed in any preceding claim, wherein the product is a powder.

8. a method as claimed in any preceding claim, wherein the lid is secured around the opening by heat sealing when in the sealed position.

9. The method of any preceding claim, wherein the lid comprises one or more layers selected from the group consisting of: paper, cardboard, plastic, and foil.

10. A method as claimed in any preceding claim, wherein the cover is flexible and has a thickness of from 0.01mm to 1.00mm, optionally from 0.01mm to 0.50 mm.

11. A package having a base and a sidewall extending therefrom, the base and sidewall defining an interior of the package, the package further having an opening to the interior and having a lid that seals the opening when the package is in a sealed position, the package further comprising a piercing element disposed in the interior, the piercing element having a cutting edge or tip toward the lid, wherein the piercing element is comprised of a mineral-loaded polymer comprising a monolithic material formed of at least a base polymer and a mineral-containing active agent, the package configured for insertion into a dispensing apparatus such that when the dispensing apparatus exerts sufficient pressure on the lid in a direction perpendicular to the cutting edge or tip, the cutting edge or tip is configured to pierce or separate at least a portion of the lid, thereby transitioning the package from the sealed position to a dispensing position in which the product enclosed within the interior can be dispensed through the opening.

12. The package of claim 11, wherein the active agent is a desiccant, optionally a molecular sieve or silica gel.

13. The package of claim 11 or 12, wherein the mineral-loaded polymer has a mineral loading level of up to 50%, optionally from 20% to 50%, optionally from 30% to 50%, by weight of the monolith.

14. The package of any one of claims 11 to 13, wherein the active agent is a desiccant that absorbs moisture from the interior of the package in order to maintain a desired quality of the product enclosed within the interior.

15. The package of claim 14, wherein the product is a powder.

16. The package of any one of claims 11 to 15, wherein said lid comprises one or more layers selected from the group consisting of: paper, cardboard, plastic, and foil.

17. A package according to any of claims 11 to 16 wherein the lid is flexible and has a thickness of from 0.01 to 1.00mm, optionally from 0.01 to 0.50 mm.

18. A piercing element having a cutting edge or tip, wherein the piercing element is comprised of a mineral-laden polymer comprising a monolithic material formed from at least a base polymer and a mineral-containing active agent.

19. The lancing element of claim 18, wherein the active agent is a desiccant, optionally a molecular sieve or silica gel.

20. The piercing element of claim 18 or 19, wherein the mineral-loaded polymer has a mineral loading level of up to 50%, optionally from 20% to 50%, optionally from 30% to 50%, by weight of the monolith.

21. A lancing element according to any one of claims 18 to 20, wherein if the lancing element has a tip, the tip has a diameter or cross-sectional width of less than 1.0mm, optionally less than 0.75mm, optionally from 0.01mm to 0.75mm, optionally from 0.03mm to 0.5 mm.

22. A lancing element according to any one of claims 18 to 20, wherein if said lancing element has a cutting edge, said cutting edge has a width of less than 1.0mm, optionally less than 0.75mm, optionally from 0.01mm to 0.75mm, optionally from 0.03mm to 0.5 mm.

23. The piercing element of any of claims 18 to 22, wherein the piercing element is configured to pierce a 40 micron thick aluminum foil cover without rupture upon application of sufficient pressure.

24. Use of a piercing element according to any of claims 18 to 23 for piercing a cap, optionally sealing a cap of a package.

1. Field of the invention

The present invention generally relates to desiccant entrained plastic formulations. More particularly, the invention relates to the use of such formulations as piercing elements in product packaging, for example for piercing foils, paper, cardboard or plastic films or layers.

2. Description of the related Art

There are many items that are preferably stored, transported and/or used in an environment that must be controlled and/or regulated. For example, in the field of moisture control, containers and/or packages having the ability to absorb excess moisture trapped in the container and/or package have been considered desirable. Control of moisture, oxygen, ethylene, and other gaseous substances may be desirable in medical, electronic, and food packaging applications.

Conventionally, desiccants, oxygen absorbers, and other active agents have been used in raw form (e.g., as loose particulates contained in a sachet or canister within a package) to control the internal environment of the package. For many applications, it is undesirable to have such loosely stored actives. To address this problem, the assignee of the present application has developed active entrained polymers containing active agents, wherein such polymers can be extruded and/or molded into desired forms, such as container liners, stoppers, films, pellets, and other such structures. Optionally, such active entrapment polymers may include channeling agents, such as polyethylene glycol (PEG), that form channels between the surface and the interior of the entrapment polymer to transport selected materials (e.g., moisture) to the entrapment active agent (e.g., a desiccant to absorb the moisture). The entrained polymer may be a two-phase formulation (i.e., comprising the base polymer and the active agent, without channeling agent) or a three-phase formulation (i.e., comprising the base polymer, the active agent, and the channeling agent). Entrained polymers are described, for example, in U.S. patent nos. 5,911,937, 6,080,350, 6,124,006, 6,130,263, 6,194,079, 6,214,255, 6,486,231, 7,005,459, and U.S. patent publication No. 2016/0039955, each of which is incorporated herein by reference as if fully set forth.

Advantageously, the entrained polymer can be molded to form a part having a particular geometry. However, high loading of the desiccant material may render such components brittle. This is because typical desiccant materials are in mineral form, such as silica gel, molecular sieves, and bentonite. The more desiccant, the greater the moisture absorption capacity, but the more brittle the resulting product. Desiccant entrained polymers in the form of discs, liners and films for product packaging, desiccant loadings of 60% to 70% are typical. However, such desiccants typically serve only a drying function, or may provide a defined cavity for storing the product (e.g., a desiccant liner in a diagnostic test strip vial). Due to the fragility of high mineral desiccant loaded components, they are generally not suitable for movably and physically engaging (e.g., piercing) other components because of the risk of cracking.

It is desirable to provide a piercing member that doubles as a desiccant element when the package volume is small, and when it is necessary to manually or automatically pierce the plastic, paper, foil or cardboard film or layer or layers of the package. However, determining the appropriate formulation ratio can be challenging, especially because of the brittleness discussed above.

Thus, there is a need for desiccant entrained polymers that are capable of puncturing seals (e.g., foils) while also providing desiccating action within the enclosed space.

Background

Disclosure of Invention

Thus, in one aspect, the disclosed concept relates to a package piercing element made of a specially formulated desiccant plastic component having a suitable piercing geometry, such as at least one point. The tip should preferably have a sufficient modulus to pierce a standard packaging foil or plastic laminate upon application of a piercing force.

In an optional embodiment, the entire part is made from a formulation containing 30-50% by weight of a desiccant. The drying agent is optionally a molecular sieve. The base polymer is optionally polypropylene or nylon. If used as part of a food-contact surface, the channeling agent may be Ethylene Vinyl Acetate (EVA), or alternatively polyethylene glycol (PEG) or any other channeling agent disclosed in the above-cited patent references. The above-described desiccant loading advantageously provides sufficient moisture absorption for the intended application and does not make the component too brittle to be used as a piercing element.

In an optional embodiment, a portion of the component is made as described above and overmolded onto a rigid metal or plastic component that itself includes a tip for piercing. In this way, the desired rigidity (no brittleness) is provided, facilitating the piercing of the foil or one or more plastic packaging layers.

Optionally, a method of piercing a packaging foil or laminate is provided. The method includes providing a piercing element according to any embodiment disclosed herein and applying a force between the piercing element and one or more packaging layers until the piercing element breaks through the one or more packaging layers.

Drawings

The present invention will hereinafter be described in conjunction with the following drawing figures, wherein like numerals denote like elements, and wherein:

Fig. 1 is a perspective view of a plug formed from an entrained polymer to illustrate the configuration of the entrained polymer.

FIG. 2 is a cross-sectional view taken along line 2-2 of FIG. 1;

FIG. 3 is a cross-sectional view similar to the cross-sectional view of FIG. 2, showing a plug formed from other embodiments of entrained polymers;

Fig. 4 is a schematic illustration of an entrained polymer, wherein the active agent is an absorbing or adsorbing material, such as a desiccant, according to an optional embodiment.

Fig. 5 is a schematic illustration of an optional package according to the disclosed concept, prior to filling the package with product and without a lid.

Fig. 6 is a schematic illustration of the package of fig. 5 filled with a product and including a lid over the opening of the package, thereby providing a sealed position.

Fig. 7 is a schematic illustration of the filled and sealed package of fig. 6 arranged in a dispensing apparatus.

Fig. 8 is a schematic illustration of the packaging and dispensing device of fig. 7, illustrating the operation of dispensing product from the packaging.

Detailed Description

As used herein, the term "active" is defined as capable of acting on, interacting with, or reacting with a selected material (e.g., moisture or oxygen) according to the present invention. Examples of such actions or interactions may include absorption, adsorption, or release of the selected material.

As used herein, the term "active agent" is defined as a material that (1) is immiscible with the base polymer and will not melt, i.e., has a melting point higher than the melting point of the base polymer or channeling agent, when mixed with the base polymer and channeling agent and heated, and (2) acts on, interacts with, or reacts with the selected material. The term "active agent" may include, but is not limited to, materials that absorb, adsorb, or release the one or more selected materials. The active agent according to the invention may be in the form of granules, preferably in the form of minerals, but the invention should not be considered as being limited to particulate active agents in general (unless the corresponding claims recite otherwise).

As used herein, the term "base polymer" is a polymer, optionally having a gas permeability of a selected material, which is substantially lower than, or substantially equal to the gas permeability of the channeling agent. For example, in embodiments where the selected material is moisture, such permeability would be water vapor permeability and the active agent would be a water-absorbing desiccant. The primary function of the base polymer is to provide a structure for the entrained polymer. Suitable base polymers may include thermoplastic polymers, for example, polyolefins such as polypropylene and polyethylene, polyisoprene, polybutadiene, polybutylene, polysiloxane, polycarbonate, polyamide, ethylene-vinyl acetate copolymer, ethylene-methacrylate copolymer, poly (vinyl chloride), polystyrene, polyester, polyanhydride, polyacrylonitrile, polysulfone, polyacrylate, acrylic, polyurethane, and polyacetal, or copolymers or mixtures thereof.

Referring to this comparison of the water vapor transmission rates of the base polymer and the channeling agent, in one embodiment, the channeling agent has a water vapor transmission rate that is at least twice the water vapor transmission rate of the base polymer. In another embodiment, the channeling agent has a water vapor transmission rate that is at least five times greater than the water vapor transmission rate of the base polymer. In another embodiment, the channeling agent has a water vapor transmission rate that is at least ten times greater than the water vapor transmission rate of the base polymer. In yet another embodiment, the channeling agent has a water vapor transmission rate that is at least twenty times greater than the water vapor transmission rate of the base polymer. In yet another embodiment, the channeling agent has a water vapor transmission rate that is at least fifty times greater than the water vapor transmission rate of the base polymer. In yet another embodiment, the channeling agent has a water vapor transmission rate that is at least one hundred times the water vapor transmission rate of the base polymer.

As used herein, the term "channeling agent" or "channeling agents" is defined as a material that is immiscible with the base polymer and has an affinity to transport gas phase species at a faster rate than the base polymer. Optionally, the channeling agent is capable of forming a channel through the entrained polymer when the entrained polymer is formed by mixing the channeling agent with the base polymer. Optionally, such channels are capable of transporting a selected material through the entrained polymer at a faster rate than in the base polymer alone.

As used herein, the term "channel" or "interconnecting channel" is defined as a channel formed by a channeling agent that passes through the base polymer and may be interconnected with one another.

As used herein, the term "entrained polymer" is defined as a monolithic material formed at least from a base polymer with an active agent and optionally also a channeling agent entrained or distributed throughout. Entrained polymers thus include two-phase polymers and three-phase polymers. A "mineral-loaded polymer" or "mineral-loaded entrained polymer" is a type of entrained polymer in which the active agent is in the form of a mineral, for example, mineral particles such as molecular sieves or silica gels.

As used herein, the terms "monolithic," "monolithic structure," or "bulk composition" are defined as a composition or material that is not composed of two or more discrete macroscopic layers or portions. Thus, "monolithic composition" does not include multilayer composites.

As used herein, the term "phase" is defined as a portion or component of an overall structure or composition that is uniformly distributed throughout to impart its overall characteristics to the structure or composition.

As used herein, the term "selected material" is defined as a material that is acted upon by, or interacts or reacts with, an active agent and is capable of being transported through a passageway that entrains a polymer. For example, in embodiments where a desiccant is used as the active agent, the selected material may be moisture or a gas that may be absorbed by the desiccant. In embodiments where a release material is used as the active agent, the selected material may be an agent that is released by the release material, such as moisture, a fragrance, or an antimicrobial agent. In embodiments where an adsorbent material is used as the active agent, the selected material may be certain volatile organic compounds and the adsorbent material may be activated carbon.

As used herein, the term "three-phase" is defined as an overall composition or structure comprising three or more phases. An example of a three-phase composition according to the invention would be an entrained polymer formed from a base polymer, an active agent, and a channeling agent. Optionally, the three-phase composition or structure may comprise additional phases, e.g., colorants.

Fig. 1-4 illustrate an exemplary entrained polymer 10 that may be useful in accordance with aspects of the disclosed concept. The entrained polymers 10 each include a base polymer 25, a channeling agent 35, and an active agent 30. As shown, the channeling agent 35 forms interconnected channels 45 through the entrained polymer 10. At least some active agent 30 is contained in these channels 45 such that the channels 45 communicate between the active agent 30 and the exterior of the entrained polymer 10 through channel openings 48 formed at the exterior surface of the entrained polymer 25. The active agent 30 can be, for example, any of a variety of absorbing, adsorbing, or releasing materials, as described in further detail below. Although channeling agents (e.g., 35) are preferred, the present invention broadly encompasses entrained polymers that optionally do not contain channeling agents.

Suitable channeling agents may include: polyglycols such as polyethylene glycol (PEG), ethylene vinyl alcohol (EVOH), polyvinyl alcohol (PVOH), glycerol polyamines, polyurethanes, and polycarboxylic acids including polyacrylic acid or polymethacrylic acid. Alternatively, the channeling agent 35 may be, for example, a water-insoluble polymer such as a propylene oxide polymer-monobutyl ether, such as Polyglykol B01/240, manufactured by CLARIANT corporation. In other embodiments, the channeling agent may be a propylene oxide polymer monobutyl ether, such as Polyglykol B01/20, manufactured by Clariant, a propylene oxide polymer, such as Polyglykol D01/240, manufactured by Clariant, ethylene vinyl acetate, nylon 6, nylon 66, or any combination of the foregoing.

suitable active agents according to the present invention include absorbent materials, such as dry compounds. Fig. 4 illustrates an embodiment of an entrained polymer 10 according to the disclosed concept in which the active agent 30 is an absorbing or adsorbing material, such as a desiccant. These arrows indicate the path of the selected material (e.g., moisture or gas) from the exterior of the entrained polymer 10, through the channel 45, to the particles of the active agent 30 (which absorb or adsorb the selected material).

If the active agent is a desiccant, any suitable desiccant for a given application may be used. Typically, for many applications, physical absorption desiccants are preferred. These may include molecular sieves, silica gels, clays, and starches. Alternatively, the desiccant may be a chemical compound that forms an aqueous crystal or a compound that reacts with water to form a new compound. Optionally, in any embodiment, the desiccant is a mineral.

Optionally, in any embodiment, the active agent can be an oxygen scavenger.

suitable absorbent materials may also include: (1) metals and alloys such as, but not limited to, nickel, copper, aluminum, silicon, solder, silver, gold; (2) metal-plated particles such as silver-plated copper, silver-plated nickel, silver-plated glass beads; (3) inorganic substances, e.g. BaTiO₃、SrTiO₃、SiO₂、Al₂O₃、ZnO、TiO₂、MnO、CuO、Sb₂O₃WC, fused silica, fumed silica, amorphous fused silica, sol-gel titanates, mixed titanates, ion exchange resins, lithium-containing ceramics, hollow glass beads; (4) carbon-based materials such as carbon, activated carbon, carbon black, ketchem black, diamond powder; (5) elastomers such as polybutadiene, polysiloxane, and semimetals, ceramics; and (6) other fillers and pigments.

In another example, the absorbent material may be a carbon dioxide scavenger, such as calcium oxide. In the presence of moisture and carbon dioxide, calcium oxide is converted to calcium carbonate. Thus, calcium oxide can be used as an absorbent material in applications where absorption of carbon dioxide is desired. Such applications include the preservation of fresh foods (e.g., fruits and vegetables) that release carbon dioxide.

Other suitable active agents according to the present invention include release materials. Such materials may include any suitable material that will release the selected material from the release material. The selected material released from the release material may be in the form of a solid, gel, liquid, or gas. These substances can perform a variety of functions including: acting as a source of fragrance, flavor, or perfume; supplying a biologically active ingredient such as an insecticide, pest repellent, antimicrobial, bait, aromatic drug, etc.; providing a humidified or dried material; delivering air-borne active chemicals, such as corrosion inhibitors; a ripening agent and an odor-producing agent.

Suitable biocides for use as release materials in the entrained polymers of the present invention may include, but are not limited to, insecticides, herbicides, nematicides, fungicides, rodenticides, and/or mixtures thereof. In addition to biocides, the coverings of the invention may also release nutrients, plant growth regulators, pheromones, defoliants and/or mixtures thereof.

Quaternary ammonium compounds may also be used as release materials according to the present invention. Such compounds not only act as surfactants, but also impart sterile properties to the surface of the entrained polymer or establish conditions for reducing the number of microbial organisms, some of which may be pathogenic. Many other antimicrobial agents, such as benzalkonium chloride and related types of compounds such as hexachlorophene, may also be used as release agents according to the present invention. Other antimicrobial agents, such as chlorine dioxide releasing agents, may be used.

it is believed that the higher the concentration of active agent in the mixture, the greater will be the absorption, adsorption or release capacity (as the case may be) of the final composition. However, too high a concentration of active agent, particularly in the form of mineral particles, can result in the entrained polymer being brittle after solidification. In addition, the high mineral loading of the entrained polymer can make the molten mixture of active agent, base polymer, and channeling agent more difficult to thermoform, extrude, or injection mold. Thus, the applicants have found that when considering the friability of the mineral-laden entrained polymer, the mineral loading percentage (by weight) of the entrained polymer should preferably be that which is absolutely required only for its active function (e.g. moisture absorption). In one embodiment, the mineral active loading level may be in the range of from 20% to 50%, preferably 30% to 50% by weight relative to the total weight of entrained polymer. Optionally, if used, the channeling agent may be provided in a range of 2% to 10% by weight. Optionally, the base polymer may range from 50% to 80% by weight of the total composition. Optionally, a colorant is added, for example, at about 2% by weight of the total composition.

Referring to fig. 1, an insert 20 constructed of an entrained polymer is illustrated that may be used in accordance with optional aspects of the disclosed concept. The insert 20 is in the form of a plug 55. It should be understood that the plug 55 is merely representative of an optional configuration of the entrained polymer component, and that the entrained polymer may be formed into different configurations and shapes, such as piercing elements, as discussed below.

Referring to fig. 2, a cross-sectional view of a plug 55 is shown that has been constructed from an entrained polymer 10 comprising a base polymer 25 that has been homogeneously blended with an active agent 30 and a hydrophilizing agent or channeling agent 35. In the illustration of fig. 2, the entrained polymer has solidified such that interconnected channels 45 are formed throughout the entrained polymer 10 to establish channels throughout the solidified plug 55. As can be understood from both fig. 1 and 2, these channels terminate at the channel opening 48 at the outer surface of the plug 55.

Fig. 3 illustrates an embodiment of a plug 55 similar in construction and composition to the plug 55 of fig. 2, wherein the interconnecting channels 45 are very thin compared to those of fig. 2. This may be due to the use of a dimerizing agent (i.e., plasticizer) in conjunction with a channeling agent 35. The dimerizing agent may enhance the compatibility between base polymer 25 and channeling agent 35. This enhanced compatibility is facilitated by the reduced blend viscosity, which may facilitate more thorough blending of the base polymer 25 and channeling agent 35, which may resist combination into a homogeneous solution under normal conditions. Upon solidification of the entrained polymer 10 to which the dimerizing agent is added, the interconnected passages 45 formed therethrough have a greater dispersion and less porosity, thereby establishing a greater density of interconnected passages throughout the plug 55.

The interconnecting channels 45, such as those disclosed herein, facilitate the transport of desired materials (such as moisture, gas, or odor) through the base polymer 25, which generally resists penetration by such materials, thus acting as a barrier thereto. For this reason, the base polymer 25 itself acts as a barrier substance in which the active agent 30 may be entrained. The interconnecting channels 45 formed by the channeling agent 35 provide a path for the desired material to move through the entrained polymer 10. Without these interconnecting channels 45, it is believed that a relatively small amount of the desired material is transported to or from the active agent 30 through the base polymer 25. Where the desired material is transferred to the active agent 30, it may be absorbed by the active agent 30, such as in embodiments where the active agent 30 is an active agent such as a desiccant or an oxygen absorber. Where it is desired that the material be delivered from the active agent 30, it can be released from the active agent 30, such as in embodiments where the active agent 30 is a releasing material (e.g., a fragrance or gas releasing material).

Referring now to fig. 5 and 6, an optional embodiment of a package 110 in accordance with the disclosed concepts is shown. Fig. 5 shows the package 110 before being filled with product and sealed. Fig. 6 shows the package 110 in a sealed position.

The package 110 has a base 112 and sidewalls 114 extending therefrom that define an interior 118 of the package 110. Before being sealed, the package 110 includes an opening 116 to an interior 118. As shown in fig. 6, when in the sealed position, the package 110 includes a lid 120 that encloses a product 126 stored within the interior 118. Optionally, in any embodiment, the product 126 is a powder, such as a moisture sensitive powder. A lid is optionally secured around the perimeter of opening 116, optionally by heat sealing 122. The heat seal 122 (if used) may be applied by an induction sealing method, as will be familiar to the skilled artisan.

The package 110 further includes a piercing element 130 disposed within the interior 118. The piercing element 130 includes a cutting edge or tip 132 facing the cover 120. The cutting edge or tip 132 is optionally adjacent to the lid 120 or even in contact with the lid 120 when the package 110 is in the sealed position. The piercing element 130, which optionally includes a cutting edge or tip 132, is composed of a mineral-loaded polymer comprising a monolithic material formed of at least a base polymer and a mineral-containing active agent, as described herein.

Optionally, in any embodiment, the monolithic material comprises a channeling agent. Optionally, in any embodiment, the active agent in the monolith is a desiccant, such as a molecular sieve or silica gel. Optionally, in any embodiment, the mineral-loaded polymer has a mineral loading level of up to 50%, optionally from 20% to 50%, optionally from 30% to 50%, by weight of the monolith. Optionally, in any embodiment, the active agent is a desiccant that absorbs moisture from the interior 118 of the package 110 to maintain the desired qualities of the product 126, such as to extend the freshness of the product and/or (in the case of a powder) to prevent caking or agglomeration of the product. Optionally, in any embodiment, the lid 120 comprises one or more layers, which may comprise paper, cardboard, plastic, foil, or a combination of the foregoing. Optionally, in any embodiment, the cover is flexible and has a thickness of from 0.01mm to 1.00mm, optionally from 0.01mm to 0.40 mm.

referring now to fig. 7 and 8, an optional dispensing apparatus 124 is shown that may be used in accordance with the method for dispensing product 126 from package 110. According to such methods, the package 110 is inserted into a dispensing apparatus 124. The dispensing device 124 may be activated to transition the package 110 from the sealed position to the dispensing position to dispense the product 126 from the package 110.

In an optional method, when the package 110 is inserted into the dispensing device 124 and the dispensing device 124 is activated, pressure will be applied to the lid 120 in a direction perpendicular to the cutting edge or tip 132. Optionally, this may be accomplished by the pressure member 128 pressing upwardly on the lid 120 and/or forcing the package 110 downwardly such that the pressure member 128 exerts a force on the lid 120. In any event, the aforementioned pressure exerted on the lid 120 in a direction perpendicular to the cutting edge or tip 132 causes the cutting edge or tip 132 to pierce the lid 120 or separate a portion of the lid 120 from the package 110. This in turn transitions the package 110 from the sealed position to a dispensing position in which the product 126 is dispensed through the opening 116.

Optionally, product 126 is dispensed into a container 134 below package 110 and filled with liquid 136. Optionally, product 126 is mixed with liquid 136 to form a solution.

Optionally, in any embodiment, the base polymer is polypropylene, e.g., S-1005P.

Optionally, in any embodiment, the disclosed concept relates generally to a piercing element (e.g., 130) having a cutting edge or tip (e.g., 132), wherein the piercing element (optionally the entire piercing element, preferably including the cutting edge or tip) is comprised of a mineral-laden polymer comprising a monolithic material formed of at least a base polymer and a mineral-containing active agent. The disclosed concept is not limited to the use of piercing elements in packages (e.g., 110), although this is currently the preferred application.

Optionally, in any embodiment, the active agent in the piercing element is a desiccant, such as a molecular sieve or silica gel. Optionally, in any embodiment of the piercing element, the mineral-loaded polymer has a mineral loading level of up to 50%, optionally from 20% to 50%, optionally from 30% to 50%, by weight of the monolith. Optionally, in any embodiment of the piercing element, if the piercing element has a tip (i.e., a point, etc.), the tip has a diameter or cross-sectional width of less than 1.0mm, optionally less than 0.75mm, optionally from 0.01mm to 0.75mm, optionally from 0.03mm to 0.5 mm. Optionally, in any embodiment of the piercing element, if the piercing element has a cutting edge (i.e., a blade), the cutting edge has a width of less than 1.0mm, optionally less than 0.75mm, optionally from 0.01mm to 0.75mm, optionally from 0.03mm to 0.5 mm. Optionally, in any embodiment, the piercing element is configured to pierce a 40 micron thick aluminum foil cover without rupture upon application of sufficient pressure. Optionally, the disclosed concept relates to the use of any embodiment of a piercing element as disclosed herein to pierce a cap, optionally a cap (e.g., 120) of a package (e.g., 110).

While the invention has been described in detail and with reference to specific examples thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.