Pearlescent interference color combination product and preparation method thereof, stained paper and one-time color firing process
阅读说明：本技术 珠光干涉彩组合产品及其制备方法、花纸与一次彩烧工艺 (Pearlescent interference color combination product and preparation method thereof, stained paper and one-time color firing process ) 是由 孟瑞飞 刘权耀 于 2021-08-31 设计创作，主要内容包括：本发明涉及装饰工艺技术领域,特别是涉及一种珠光干涉彩组合产品及其制备方法、花纸与一次彩烧工艺。本发明通过选用合适的第一助熔剂,并将其与无机色料和第一调墨油按照一定比例复配,制成用于珠光干涉彩装饰的底衬,该底衬具备良好的流动性,同时具备较快的干燥速度,并且对待加工的坯体具备良好的附着性,烧制过程不易龟裂；通过选用合适的第二助熔剂,并将其与珠光颜料和第二调墨油按照一定比例复配,制成珠光干涉彩材料,具备优良的珠光效果,对底衬具有较好的附着性。烧制过程中,底衬材料与珠光干涉彩材料不会发生熔融反应,因此,将二者搭配使用,通过一次烧制即可完成珠光干涉彩陶瓷或玻璃制品的制备,大大简化了生产工艺。(The invention relates to the technical field of decoration processes, in particular to a pearlescent interference color combined product and a preparation method thereof, stained paper and a one-time color burning process. The proper first fluxing agent is selected and compounded with the inorganic pigment and the first varnish according to a certain proportion to prepare the bottom lining for pearlescent interference color decoration, the bottom lining has good fluidity and higher drying speed, and has good adhesiveness to a blank to be processed, and the blank is not easy to crack in the firing process; the appropriate second fluxing agent is selected and compounded with the pearlescent pigment and the second varnish according to a certain proportion to prepare the pearlescent interference color material, which has excellent pearlescent effect and better adhesiveness to the bottom lining. In the firing process, the bottom lining material and the pearlescent interference color material do not generate melting reaction, so the bottom lining material and the pearlescent interference color material are matched for use, and the preparation of the pearlescent interference color ceramic or glass product can be finished by firing once, thereby greatly simplifying the production process.)
1. A pearlescent interference color combination product for ceramic or glass decoration is characterized by comprising an inorganic substrate material and a pearlescent interference color material which are respectively packaged, wherein the pearlescent interference color combination product comprises the following components in parts by mass,
the inorganic substrate material comprises:
30-50 parts of an inorganic pigment;
50-70 parts of a first fluxing agent;
60-80 parts of first ink mixing oil;
the pearlescent interference color material comprises:
20-50 parts of pearlescent pigment;
50-80 parts of a second fluxing agent;
100-150 parts of second ink adjusting oil;
the inorganic pigment and the pearlescent pigment are used for ceramic decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 750-850 ℃, and the first fluxing agent and/or the second fluxing agent are boron fluxing agents;
the inorganic pigment and the pearlescent pigment are used for glass decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 550-650 ℃, and the first fluxing agent and the second fluxing agent are respectively and independently selected from at least one of a lead fluxing agent and a lithium fluxing agent.
2. The pearlescent interference color combination of claim 1 wherein the viscosity of the first varnish and/or the second varnish at 25 ± 0.1 ℃ is from 350 mPa-s to 550 mPa-s.
3. The pearlescent interference color combination of claim 1 wherein the distance between the color of the inorganic colorant and the color of the pearlescent pigment on the hue circle is 60 degrees or more.
4. The pearlescent interference color combination according to any one of claims 1-3 wherein the average particle size of the particles in the inorganic backing material is 2-5 μm; the average grain diameter of the particles in the pearlescent interference color material is 10-20 μm.
5. The method for preparing the pearlescent interference color combination product according to any one of claims 1-4, characterized by comprising the following steps:
preparing materials according to preset conditions, physically and uniformly mixing the raw materials of the inorganic substrate material, and physically and uniformly mixing the raw materials of the pearlescent interference color material.
6. The preparation method according to claim 5, wherein the step of physically and uniformly mixing the raw materials of the inorganic substrate material comprises the following steps: firstly, physically and uniformly mixing the inorganic pigment and the first fluxing agent, and then adding the first varnish for physical and uniform mixing;
the method for physically and uniformly mixing the raw materials of the pearlescent interference color material comprises the following steps: and firstly, physically and uniformly mixing the pearlescent pigment and the second fluxing agent, and then, adding the second varnish for physically and uniformly mixing.
7. The stained paper for decal transfer is characterized by comprising a printing paper layer, an inorganic bottom lining layer and a pearlescent interference color layer which are sequentially arranged; the inorganic substrate layer is formed by curing the inorganic substrate material in the pearlescent interference color combination product of any claim 1 to 4, and the pearlescent interference color layer is formed by curing the pearlescent interference color material in the pearlescent interference color combination product of any claim 1 to 4.
8. The method of making a decal for decal transfer according to claim 7, comprising the steps of:
applying the inorganic substrate material to printing paper, and airing; and then applying the pearlescent interference color material to the dried inorganic substrate material layer, and drying.
9. The preparation method of the pearlescent interference color ceramic is characterized by comprising the following steps:
the decal paper as claimed in claim 7 is pasted on a ceramic white base by a decal process, and is fired at 750-850 ℃ after being put into a kiln.
10. The preparation method of the pearlescent interference colored glass is characterized by comprising the following steps:
the decal paper as claimed in claim 7 is pasted on a glass blank by a decal process, and fired at 550 ℃ to 650 ℃ after being put into a kiln.
Technical Field
The invention relates to the technical field of decoration processes, in particular to a pearlescent interference color combined product and a preparation method thereof, stained paper and a one-time color burning process.
Background
The ceramic has a history of thousands of years, and is one of the great contributions of China to human civilization. In recent years, with the development of various related technologies, the mass production of ceramics enters a rapid development stage and keeps a high growth rate; however, in general, the production of the traditional ceramics belongs to labor-intensive industries, and has the disadvantages of complex production process, more procedures, high production cost, low input-output ratio and the like. Furthermore, with the improvement of living standard of substances, people increasingly pursue aesthetic feelings, and the traditional ceramic styles are not enough to meet the market demands, so that various novel ceramic products come into play.
The pearlescent pigment has certain metal luster, can generate the soft luster of natural pearls, can show soft and dazzling luster through multi-level reflection when being irradiated by a light source, and is widely applied to decoration in many fields, such as decoration of ceramics. The pearlescent decoration of ceramics can be roughly divided into two types, one is common pearlescent decoration, and the other is pearlescent interference color decoration, wherein the pearlescent pigment is directly applied to the ceramics, and the other one needs to prefabricate a colored bottom liner with larger color difference with the pigment on the ceramics, and then the pearlescent pigment is applied to realize the effect of presenting different color tones from different angles. The traditional pearlescent interference color decoration can be finished only by adding one-time kiln firing, firing a layer of bottom lining on the ceramic in advance, then coating pearlescent pigment and then performing the second kiln firing, but the secondary firing is time-consuming and labor-consuming, and the quality of the ceramic product is influenced by the condition of artificial inaccurate registration; of course, pearlescent pigments with larger color difference with the ceramic can be directly adopted, and no prefabricated substrate is needed, but the application scene is obviously greatly limited, and the method has no universality.
Disclosure of Invention
Therefore, there is a need for a pearlescent interference color combination product and a preparation method thereof, stained paper and a one-time color firing process, which can realize pearlescent interference color decoration of products such as ceramics or glass only by one-time firing, have no additional requirements on the color of the ceramics or glass blank, and have the advantages of simple and efficient process, good universality, high yield and the like.
In one aspect of the present invention, there is provided a pearlescent interference color composition product for ceramic or glass decoration, which comprises separately packaged inorganic substrate material and pearlescent interference color material, in parts by mass,
the inorganic substrate material comprises:
30-50 parts of an inorganic pigment;
50-70 parts of a first fluxing agent;
60-80 parts of first ink mixing oil;
the pearlescent interference color material comprises:
20-50 parts of pearlescent pigment;
50-80 parts of a second fluxing agent;
100-150 parts of second ink adjusting oil;
the inorganic pigment and the pearlescent pigment are used for ceramic decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 750-850 ℃, and the first fluxing agent and/or the second fluxing agent are/is respectively and independently selected from boron fluxing agents;
the inorganic pigment and the pearlescent pigment are used for glass decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 550-650 ℃, and the first fluxing agent and the second fluxing agent are respectively and independently selected from at least one of a lead fluxing agent and a lithium fluxing agent.
The proper first fluxing agent is selected and compounded with the inorganic pigment and the first varnish according to a certain proportion to prepare the bottom lining for pearlescent interference color decoration, the bottom lining has good fluidity and is easy to print, the drying speed is high, the ceramic blank or glass blank to be processed has good adhesiveness, and the firing process is not easy to crack; the appropriate second fluxing agent is selected and compounded with the pearlescent pigment and the second varnish according to a certain proportion to prepare the pearlescent interference color material, and the pearlescent interference color material has excellent pearlescent effect and good adhesiveness to the bottom lining. In the firing process, the bottom lining material prepared according to the formula of the invention and the pearlescent interference color material do not generate melting reaction, so the bottom lining material and the pearlescent interference color material are matched for use, and the preparation of the pearlescent interference color ceramic or glass product can be finished by firing once, thereby greatly simplifying the production process, reducing the production cost and avoiding the ghost image phenomenon which is possibly generated when the artificial nesting is fired twice.
In some embodiments, the viscosity of the first varnish and/or the second varnish is from 350mPa · s to 550mPa · s at 25 ± 0.1 ℃.
In some embodiments, the color of the inorganic colorant is greater than or equal to 60 degrees from the color of the pearlescent pigment on the hue circle.
In some embodiments, the particles in the inorganic primary backing material have an average particle size of 2 μm to 5 μm; the average grain diameter of the particles in the pearlescent interference color material is 10-20 μm.
In another aspect of the present invention, a method for preparing the pearlescent interference color composition product comprises the following steps:
preparing materials according to preset conditions, physically and uniformly mixing the raw materials of the inorganic substrate material, and physically and uniformly mixing the raw materials of the pearlescent interference color material.
In some embodiments, the step of physically blending the raw materials of the inorganic substrate material comprises: firstly, physically and uniformly mixing the inorganic pigment and the first fluxing agent, and then adding the first varnish for physical and uniform mixing;
the method for physically and uniformly mixing the raw materials of the pearlescent interference color material comprises the following steps: and firstly, physically and uniformly mixing the pearlescent pigment and the second fluxing agent, and then, adding the second varnish for physically and uniformly mixing.
In another aspect of the invention, the invention also provides a decal paper for decal transfer, which comprises a printing paper layer, an inorganic bottom lining layer and a pearlescent interference color layer which are arranged in sequence; the inorganic bottom lining layer is formed by solidifying the inorganic bottom lining material in the pearlescent interference color combined product, and the pearlescent interference color layer is formed by solidifying the pearlescent interference color material in the pearlescent interference color combined product
The invention also provides a preparation method of the stained paper for decal transfer, which comprises the following steps:
applying the inorganic substrate material to printing paper, and airing; and then applying the pearlescent interference color material to the dried inorganic substrate material layer, and drying.
Meanwhile, the invention also provides a preparation method of the pearlescent interference color ceramic, which comprises the following steps:
the stained paper is stuck on a ceramic white base by a decal process, and is fired at 750-850 ℃ after being put into a kiln.
The invention also provides a preparation method of the pearlescent interference colored glass, which comprises the following steps:
the stained paper is pasted on a glass blank through a decal process, and is fired at 550-650 ℃ after being put into a kiln.
Detailed Description
In order that the invention may be more fully understood, reference will now be made to the accompanying examples. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In the description of the invention, "a plurality" means at least two, e.g., two, three, etc., unless explicitly specified otherwise. In the description of the present invention, "a plurality" means at least one, e.g., one, two, etc., unless specifically limited otherwise.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
In the present invention, the technical features described in the open type include a closed technical solution composed of the listed features, and also include an open technical solution including the listed features.
In the present invention, the numerical intervals are regarded as continuous, and include the minimum and maximum values of the range and each value between the minimum and maximum values, unless otherwise specified. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range-describing features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein.
The percentage contents referred to in the present invention mean, unless otherwise specified, mass percentages for solid-liquid mixing and solid-solid mixing, and mass percentages for liquid-liquid mixing.
The percentage concentrations referred to in the present invention refer to the final concentrations unless otherwise specified. The final concentration refers to the ratio of the additive component in the system to which the component is added.
The temperature parameter in the present invention is not particularly limited, and may be a constant temperature treatment or a treatment within a certain temperature range. The constant temperature process allows the temperature to fluctuate within the accuracy of the instrument control.
In one aspect of the present invention, there is provided a pearlescent interference color composition product for ceramic or glass decoration, which comprises separately packaged inorganic substrate material and pearlescent interference color material, in parts by mass,
the inorganic substrate material comprises:
30-50 parts of an inorganic pigment;
50-70 parts of a first fluxing agent;
60-80 parts of first ink mixing oil;
the pearlescent interference color material comprises:
20-50 parts of pearlescent pigment;
50-80 parts of a second fluxing agent;
100-150 parts of second ink adjusting oil;
when the inorganic pigment and the pearlescent pigment are used for ceramic decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 750-850 ℃, and the first fluxing agent and/or the second fluxing agent are boron fluxing agents;
when the inorganic pigment and the pearlescent pigment are used for glass decoration, the color development temperature range of the inorganic pigment and the pearlescent pigment is 550-650 ℃, and the first fluxing agent and the second fluxing agent are respectively and independently selected from at least one of a lead fluxing agent and a lithium fluxing agent.
Alternatively, the inorganic coloring material having a color temperature range of 750 to 850 ℃ may be, for example, 20C920 (black), R20984 (red), 20987 (yellow), 211 (blue); the pearlescent pigment having a color temperature range of 750 to 850 ℃ may be, for example, 1045R4 (grape violet), 1045R5 (blue), 1045R6 (blue violet), KC231 (light green), KC221 (light blue), or KC201 (gold).
Alternatively, the inorganic coloring material having a color temperature range of 550 to 650 ℃ may be 1713 (black), 10P150 (yellow) or 30C591 (blue), for example; the pearlescent pigment having a color development temperature range of 550 to 650 ℃ may be, for example, 1045R8 (yellow green), 1045R5 (blue), KC223 (purple) or KC201 (gold).
The traditional pearlescent interference color decoration is usually processed by adopting a twice firing method, namely, the substrate is fired firstly, and then the pearlescent color is fired, so that the method is time-consuming and labor-consuming, the ghost phenomenon is easily caused by manual inaccurate registration, and the yield is low. The main reasons for the traditional technology adopting twice firing processing are as follows: in order to ensure the adhesion of the substrate to the substrate, the substrate material needs to have better fusibility to the substrate, but better fusibility to the substrate often means the ablation property to the pearlescent pigment, so in the conventional technology, if the substrate is coated, the pearlescent pigment is directly coated after drying, and then the substrate material and the pearlescent pigment are fired in a kiln, the substrate material and the pearlescent pigment are subjected to a melting reaction, so that the pearlescent pigment is damaged, and the pearlescent effect is difficult to present. Therefore, it is desirable to pre-fire the substrate to avoid as much as possible of the melting reaction between the substrate material and the pearlescent pigment.
The bottom lining for pearlescent interference color decoration is prepared by selecting a proper first fluxing agent and compounding the first fluxing agent, the inorganic pigment and the first varnish according to a certain proportion, and the bottom lining not only has a matched thermal expansion coefficient with a ceramic or glass substrate, thereby avoiding the cracking phenomenon in the firing process, but also has good adhesive force to the substrate, good fluidity, easy printing and faster drying speed; the appropriate second fluxing agent is selected and compounded with the pearlescent pigment and the second varnish according to a certain proportion to prepare the pearlescent interference color material, and the pearlescent interference color material has excellent pearlescent effect and good adhesiveness to the bottom lining. In the firing process, the bottom lining material and the pearlescent interference color material prepared according to the formula of the invention do not have melting reaction, the contradiction between the adhesive force and the decorative effect is well balanced, the bottom lining material and the pearlescent interference color material are matched for use, and the preparation of the pearlescent interference color ceramic or glass product can be completed by firing once, so that the production process is greatly simplified, compared with the traditional secondary color firing process, the total time consumption is 5-6 days on average, the total time consumption of the invention can be completed by only 3-3.5 days, the production cost is effectively reduced, and the ghost phenomenon which is possibly generated when the secondary firing is carried out for artificial positioning is avoided.
Preferably, the amount of the organic solvent is, in parts by mass,
the inorganic substrate material comprises:
30-40 parts of an inorganic pigment;
60-70 parts of a first fluxing agent;
68-72 parts of first ink mixing oil;
the pearlescent interference color material comprises:
30-40 parts of pearlescent pigment;
60-70 parts of a second fluxing agent;
110-130 parts of second ink adjusting oil;
when used for ceramic decoration, the first fluxing agent and the second fluxing agent are respectively and independently selected from one or more of F50 fluxing agent, F52 fluxing agent and F60 fluxing agent;
when used for glass decoration, the first and second fluxing agents are each independently selected from at least one of the #48 and 33005 fluxing agents.
Further preferably, the water-soluble polymer is a copolymer of, by mass,
the inorganic substrate material comprises:
35 parts of an inorganic pigment;
65 parts of a first fluxing agent;
70 parts of first varnish;
the pearlescent interference color material comprises:
40 parts of pearlescent pigment;
60 parts of a second fluxing agent;
120 parts of second ink adjusting oil;
when used for ceramic decoration, the first and/or second fluxing agents are the F50 fluxing agents; the fluxing agent can ensure that the ceramic has better coloring effect and interference effect and better hand feeling;
when used for glass decoration, the first and/or second fluxing agent is a #48 fluxing agent; the fluxing agent can ensure that the glass has better coloring effect and interference effect and better hand feeling.
Preferably, the first fluxing agent is the same as the second fluxing agent. The same fluxing agent is selected, so that the thermal expansion coefficients of the inorganic substrate material and the pearlescent interference color material are matched, cracking in the firing process is avoided, and a layer formed by the inorganic substrate material and the pearlescent interference color material has better bonding degree.
Preferably, the first varnish is the same as the second varnish. The same varnish is selected, so that the particles of all the raw materials can be distributed more uniformly, and a better interference effect is achieved.
In some embodiments, the viscosity of the first varnish and/or the second varnish is from 350mPa · s to 550mPa · s at 25 ± 0.1 ℃. The viscosity of the varnish is set within a proper range, so that the inorganic substrate material and the pearlescent interference color material have good fluidity and are easy to print, and can be dried quickly.
In some embodiments, the color of the inorganic colorant is greater than or equal to 60 degrees from the color of the pearlescent pigment on the hue circle. The colors of the inorganic pigment and the pearlescent pigment can show better interference effect when having certain color difference.
In some embodiments, the particles in the inorganic backing material have an average particle size of 2 μm to 5 μm; the average grain diameter of the particles in the pearlescent interference color material is 10-20 μm. Preferably, the average particle size of the particles in the inorganic substrate material is 3-4 μm; the average particle size of the particles in the pearlescent interference color material is 15-18 microns, the particle size of the particles in the inorganic substrate material and the pearlescent interference color material is controlled, the flowability of a combined product can be further improved, the printing operability is improved, the finally formed pearlescent interference color decorative layer is softer and more uniform in gloss, and the particle size matching of the two materials can ensure that the mixed material is more compact and has better hand feeling.
In another aspect of the present invention, a method for preparing the pearlescent interference color composition product comprises the following steps:
preparing materials according to preset conditions, physically and uniformly mixing the raw materials of the inorganic substrate material, and physically and uniformly mixing the raw materials of the pearlescent interference color material.
In some embodiments, the step of physically blending the raw materials of the inorganic substrate material comprises: firstly, physically and uniformly mixing the inorganic pigment and the first fluxing agent, and then adding the first ink mixing oil for physical and uniform mixing;
the method for physically and uniformly mixing the raw materials of the pearlescent interference color material comprises the following steps: and firstly, physically and uniformly mixing the pearlescent pigment and the second fluxing agent, and then, adding the second varnish for physically and uniformly mixing.
In some embodiments, the physical blending is by ball milling or sand milling.
In some embodiments, the ball milled or sanded feedstock is screened to provide a more concentrated and more uniform particle size distribution in the feedstock.
In another aspect of the invention, the invention also provides a decal paper for decal transfer, which comprises a printing paper layer, an inorganic bottom lining layer and a pearlescent interference color layer which are arranged in sequence; the inorganic bottom lining layer is formed by solidifying the inorganic bottom lining material in the pearlescent interference color combined product, and the pearlescent interference color layer is formed by solidifying the pearlescent interference color material in the pearlescent interference color combined product
The invention also provides a preparation method of the stained paper for decal transfer, which comprises the following steps:
applying the inorganic substrate material on printing paper, and airing; and then coating the pearlescent interference color material on the dried inorganic substrate material layer, and drying.
In some embodiments, the inorganic backing material and/or pearlescent interference color material is applied by printing.
In some embodiments, after the pearlescent interference color material is dried and cured, a cover coat oil is applied to the layer of the pearlescent interference color material.
Meanwhile, the invention also provides a preparation method of the pearlescent interference color ceramic, which comprises the following steps:
the stained paper is stuck on a ceramic white base by a decal process, and is fired at 750-850 ℃ after being put into a kiln. Preferably, the firing is carried out at 780 ℃ to 820 ℃ after the raw materials are put into the kiln. Further preferably, the firing is carried out at 800 ℃ after the charging into the kiln.
The invention also provides a preparation method of the pearlescent interference colored glass, which comprises the following steps:
the stained paper is pasted on a glass blank through a decal process, and is fired at 550-650 ℃ after being put into a kiln. Preferably, the firing is carried out at 580 to 620 ℃ after the charging into the kiln. Further preferably, the firing is carried out at 600 ℃ after the introduction into the kiln.
The present invention will be described in further detail with reference to specific examples and comparative examples. It is understood that the following examples are more specific to the apparatus and materials used, and in other embodiments, the apparatus and materials may not be limited thereto, and may not be limited to physical blending using a high speed blender, for example.
The manufacturer information and the brand of each reagent adopted in the invention are as follows:
example 1
Weighing 70g of 20C920 black inorganic pigment and 130g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 70g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 80g of 1045R4 grape purple pearl powder (interference color) and 120g of F50 fluxing agent, performing mixed grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 120g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 2
Weighing 64g of 20C920 black inorganic pigment and 132g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 98g of the component A and 72g of M9001 varnish, and rolling and uniformly mixing and grinding the component A and the varnish by a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 80g of 1045R4 grape purple pearl powder (interference color) and 120g of F50 fluxing agent, performing mixed grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 120g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 3
Weighing 70g of 20C920 black inorganic pigment and 130g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 70g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 60g of 1045R4 grape purple pearl powder (interference color) and 140g of F50 fluxing agent, performing mixed grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 110g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 4
Weighing 100g of 20C920 black inorganic pigment and 100g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 80g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 80g of 1045R4 grape purple pearl powder (interference color) and 120g of F50 fluxing agent, performing mixed grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 120g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 5
Weighing 70g of 20C920 black inorganic pigment and 130g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 70g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 1045R4 grape purple pearl powder (interference color) 100g and F50 fluxing agent 100g, mixing and grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 140g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 6
Weighing 70g of 20C920 black inorganic pigment and 130g of F50 fluxing agent, mixing and grinding for 50 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 70g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 3 mu M;
weighing 80g of 1045R4 grape purple pearl powder (interference color) and 120g of F50 fluxing agent, performing mixed grinding for 30 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 120g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 16 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 750 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 7
Weighing 70g of 20C920 black inorganic pigment and 130g of F50 fluxing agent, mixing and grinding for 60 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain a component A for later use; taking 100g of the component A and 70g of M9001 varnish, and rolling and uniformly mixing and grinding the components in a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 2 mu M;
weighing 80g of 1045R4 grape purple pearl powder (interference color) and 120g of F50 fluxing agent, performing mixed grinding for 20 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 120g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 20 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference color paper is pasted on a ceramic white base by a decal process, and is placed in a kiln for color firing at the temperature of 800 ℃ to obtain the grape purple interference color decorative ceramic product.
Example 8
Weighing 1713 g of black inorganic pigment and 120g of #48 fluxing agent, mixing and grinding for 40 seconds in a high-speed mixer at the rotating speed of 1500RPM, discharging and sieving to obtain component A for later use; taking 100g of the component A and 60g of M9001 varnish, and rolling and uniformly mixing and grinding the component A and the varnish by a three-roller machine to obtain an inorganic bottom lining material with the average particle size of 5 mu M;
weighing 1045R8 yellow-green pearl powder (interference color) 40g and F50 fluxing agent 160g, mixing and grinding for 40 seconds in a high-speed mixer at the rotating speed of 1200RPM, discharging and sieving to obtain a component B for later use; taking 100g of the component B and 100g of M9001 varnish, and rolling and uniformly mixing and grinding the mixture in a three-roller machine to obtain a pearlescent interference color material with the average particle size of 10 mu M;
fixing the screen plate with the patterns dried in advance on an automatic printing machine, loading an inorganic substrate material, performing printing to obtain substrate stained paper with certain patterns, and drying; fixing the dried bottom liner stained paper on an automatic printing machine, installing a pearlescent interference color material, and performing register printing on the bottom liner printed stained paper, wherein the register is accurate in the printing process and no double image appears; airing the stained paper printed with the pearlescent interference color, and then printing S503Y seal oil to obtain the pearlescent interference colored paper for decal transfer;
the pearlescent interference colored paper is pasted on a glass blank by a decal process, and is placed in a kiln for color burning at the temperature of 600 ℃ to obtain a yellow-green interference colored decorative glass product.
Comparative example 1
Substantially in accordance with example 1, except that in the inorganic backing material: the amount of the 20C920 black inorganic colorant was 40g, and the amount of the F50 flux was 160 g.
Comparative example 2
Substantially in accordance with example 1, except that in the inorganic backing material: the amount of the 20C920 black inorganic coloring material was 120g, and the amount of the F50 flux was 80 g.
Comparative example 3
The same as example 1 except that 90g of the M9001 varnish was used as the inorganic base material.
Comparative example 4
In substantial agreement with example 1, except that in the pearlescent interference color material: 1045R4 grape purple pearl powder (interference color) in 20g, F50 flux in 180 g.
Comparative example 5
In substantial agreement with example 1, except that in the pearlescent interference color material: 1045R4 grape purple pearl powder (interference color) in an amount of 120g, and F50 flux in an amount of 80 g.
Comparative example 6
The difference from the above example 1 is that 90g of the M9001 varnish was used as the pearlescent interference color material.
Comparative example 7
Substantially the same as in example 1 except that the average particle size in the pearlescent interference color material is 5 μm.
Comparative example 8
Substantially as in example 1, except that the firing temperature was 700 ℃.
Comparative example 9
Substantially as in example 7, except that the color firing temperature was 700 ℃.
And (3) performance testing:
(1) and (3) testing the adhesive force:
the test is carried out in two ways, and the test standard is as follows: a) nail scraping is not peeled off; b) white paper wipes do not develop bright color and dirty color.
If both tests meet the standard, the adhesive force is considered to be good, if one test does not meet the standard, the adhesive force is considered to be medium, and if both tests do not meet the standard, the adhesive force is considered to be poor.
(2) Judging coloring effect and interference effect:
visual observation (at least three-person observation, taking an average value), wherein the brighter the color is, the higher the coloring effect score is; the stronger the metallic texture, the better the reflection effect, and the higher the interference effect score.
(3) Judging hand feeling:
the tactile sensation (the average value is taken by at least three people for observation) is more exquisite and smooth in hand feeling, marks are not easy to leave after the tactile sensation is touched, and the hand feeling score is higher.
Note: the coloring effect, interference effect and hand feeling fullness are all 10 points.
Adhesion force
Color effect score
Score of interference effect
Hand feeling score
Example 1
Good taste
9.9
10.0
9.8
Example 2
Good taste
10.0
9.2
9.5
Example 3
Good taste
9.5
10.0
10.0
Example 4
Good taste
8.2
9.3
9.4
Example 5
Good taste
8.1
8.9
9.1
Example 6
Good taste
8.7
8.4
9.2
Example 7
Good taste
9.0
8.2
8.8
Example 8
Good taste
7.7
8.8
9.0
Comparative example 1
Good taste
7.3
3.4
8.5
Comparative example 2
Difference (D)
8.5
8.9
3.9
Comparative example 3
Good taste
8.2
9.0
9.6
Comparative example 4
Good taste
3.6
4.2
9.2
Comparative example 5
Medium and high grade
8.9
5.2
7.8
Comparative example 6
Difference (D)
7.3
2.8
3.4
Comparative example 7
Good taste
9.5
5.0
9.5
Comparative example 8
Difference (D)
4.8
5.4
9.1
Comparative example 9
Good taste
3.1
4.7
8.2
From the above table, the ceramic product and the glass product prepared by the embodiments of the invention can be finished by only one-time firing process, and on the premise, the ceramic product and the glass product have good adhesive force, good coloring effect and interference effect, and high yield; can bear certain external force without peeling, and has deep coloring and soft and uniform pearl effect. Compared with the example 1 with all the parameters in the optimal range, the inorganic pigment in the example 2 is slightly less in dosage, the first fluxing agent is slightly more in dosage, the interference effect is slightly reduced, and the hand feeling is also slightly reduced; the pearlescent pigment in the embodiment 3 is slightly less in dosage, the second fluxing agent is slightly more in dosage, the hand feeling is finer and finer, but the degree of coloration is slightly reduced; in example 4, the amount of the inorganic coloring material was slightly larger, the amount of the first flux was slightly smaller, and the amount of the first varnish was slightly larger, and although the interference effect was better, the darker ground color had a certain effect on the coloring effect of the light pearlescent color; the pearlescent pigment in the embodiment 5 is used in a little amount, the second fluxing agent is used in a little amount, the second varnish is used in a much amount, although the pearlescent effect is better, the adhesion is slightly inferior to that in the embodiment 1; the firing temperature of example 6 is slightly lower, and both the coloring effect and the interference effect are affected to some extent; the inorganic coloring material and pearlescent pigment of example 7 have a slightly poor particle size matching, so that the interference effect is slightly weak and the hand is somewhat deteriorated.
Compared with the example 1, the comparative example 1 greatly influences the interference effect and also influences the coloring effect to a certain extent due to the excessively low use amount of the inorganic pigment; comparative example 2 the first fluxing agent used in an excessively low amount resulted in poor adhesion, significant flaking and staining during testing, and poor hand feel; in comparative example 3, the first varnish amount is too large, the drying time is too long, the coloring effect and the interference effect are affected to a certain extent, and the production efficiency is reduced; in comparative example 4, the pearlescent pigment is used in an excessively small amount, the coloring effect is poor, and the interference effect is also greatly influenced; comparative example 5 the second flux used in too little, not only the adhesion was reduced to some extent, but also the interference effect was significantly affected, and the hand was also poor; in comparative example 6, the second varnish amount was too small, resulting in poor fluidity, difficulty in uniform printing, a large reduction in interference effect, insufficient uniformity of coloring effect, and a large influence on hand feeling; in comparative example 7, the average particle size is too small, and refraction and reflection of light deviate from preset, so that the interference effect is poor; comparative example 8 the firing temperature was too low and the substrate and pearlescent color did not develop completely, resulting in poor coloring and interference effects, poor adhesion, flaking and significant color smudge; the firing temperature of comparative example 9 is too high compared to example 7, resulting in slight softening deformation of the glass gob and a lightening of the substrate color, greatly affecting the coloring and interference effects.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the patent of the invention is subject to the appended claims, and the description can be used for explaining the contents of the claims.
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