阅读说明：本技术 一种低温金属清洗剂及其在金属工件上的应用 (Low-temperature metal cleaning agent and application thereof to metal workpiece ) 是由 车家云 于 2021-08-12 设计创作，主要内容包括：本发明涉及工业清洗剂技术领域,且公开了一种低温金属清洗剂及其在金属工件上的应用,包括无水偏硅酸钠,0.8％～2％；葡萄糖酸钠,5％～8％；氢氧化钠,10％～15％；H5768缓蚀剂,2％～4％；硼酸三乙醇胺酯,1％～3％；PAA,1％～3％；WP172,5％～8％；RPE2520,2％～4％；由纳米氧化铁均衡分散在聚噻吩中形成的浓度为5％的混合清洗催化剂,5％～8％；余量为去离子水；本发明所制得的低温金属清洗剂使污染物在激光能量和混合清洗催化剂的共同作用下,通过物理或化学反应克服与金属工件的结合力并脱离,污染物吸收激光能量后瞬时温度急剧升高至超过熔点或沸点,进而分解或气化并从表面消失,其各项质量指标均优于JB/T4323.2-1999标准要求；不仅实现了彻底清除污染物的技术效果,而且不含有机硅消泡剂。(The invention relates to the technical field of industrial cleaning agents, and discloses a low-temperature metal cleaning agent and application thereof on a metal workpiece, wherein the low-temperature metal cleaning agent comprises 0.8-2% of anhydrous sodium metasilicate; 5 to 8 percent of sodium gluconate; 10 to 15 percent of sodium hydroxide; h5768 corrosion inhibitor, 2% -4%; 1-3% of triethanolamine borate; 1% -3% of PAA; WP172, 5% -8%; RPE2520, 2% -4%; 5 to 8 percent of mixed cleaning catalyst with the concentration of 5 percent is formed by evenly dispersing nano iron oxide in polythiophene; the balance of deionized water; the low-temperature metal cleaning agent prepared by the invention enables the pollutants to overcome the bonding force with the metal workpiece and be separated from the metal workpiece through physical or chemical reaction under the combined action of laser energy and a mixed cleaning catalyst, and the instantaneous temperature of the pollutants is sharply increased to exceed the melting point or the boiling point after the pollutants absorb the laser energy, so that the pollutants are decomposed or gasified and disappear from the surface, and all quality indexes of the pollutants are superior to JB/T4323.2-1999 standard requirements; not only the technical effect of thoroughly removing pollutants is realized, but also the organic silicon defoaming agent is not contained.)

1. The low-temperature metal cleaning agent is characterized by comprising 0.8 to 2 percent of anhydrous sodium metasilicate; 5 to 8 percent of sodium gluconate; 10 to 15 percent of sodium hydroxide; h5768 corrosion inhibitor, 2% -4%; 1-3% of triethanolamine borate; 1% -3% of PAA; WP172, 5% -8%; RPE2520, 2% -4%; 5 to 8 percent of mixed cleaning catalyst with the concentration of 5 percent is formed by evenly dispersing nano iron oxide in polythiophene; the balance being deionized water.

2. The low-temperature metal cleaner as claimed in claim 1, wherein the nano iron oxide has an average particle size of 50nm or less.

3. The low-temperature metal cleaning agent as claimed in claim 2, wherein the cleaning agent comprises the following raw materials in parts by mass: anhydrous sodium metasilicate, 1%; 6% of sodium gluconate; 12% of sodium hydroxide; h5768 corrosion inhibitor, 3%; triethanolamine borate, 2%; PAA, 2%; WP172, 7%; RPE2520, 3%; 6 percent of mixed cleaning catalyst with the concentration of 5 percent formed by evenly dispersing ferric oxide with the average grain diameter of less than or equal to 30nm in polythiophene; the balance being deionized water.

4. The application of the low-temperature metal cleaner on the metal workpiece is characterized by comprising the following steps: soaking the metal contaminated test piece in a cleaning solution; irradiating a metal contaminated test piece by pulse laser, ultrasonically cleaning the metal contaminated test piece in a ZQ25-12TJR ultrasonic cleaner at 45 ℃ and 1kHz, and then washing the metal contaminated test piece by deionized water.

Technical Field

The invention relates to the technical field of industrial cleaning agents, in particular to a low-temperature metal cleaning agent and application thereof to a metal workpiece.

Background

After the metal workpiece is machined, the surface of the metal workpiece can carry dirt, such as various cutting fluids, guide rail oil and the like, if the metal workpiece is not cleaned, the smooth operation of a machining process is influenced, the corrosion of the metal surface is caused and accelerated, and the machining quality and the service life of a product are influenced. In addition, the cleaning process is not required to be performed before the finish of plating, phosphating (silanization) glazing, painting, and the like, and in the maintenance and repair of mechanical equipment. The selection of the cleaning process and the quality of the cleaning effect not only relate to the major problems of safety, energy, environmental protection and the like, but also directly influence the performance and the quality of the product, so the cleaning process becomes an indispensable important link in the modern industrial production.

The metal cleaning agent has two types of water-based type and solvent type. The water-based metal cleaning agent has a series of advantages of replacing oil with water, saving energy, protecting environment, not harming the health of operators, being nonflammable, having low cost and the like, thereby being developed rapidly. However, the water-based metal cleaning agent is easy to foam and remain, and a large amount of surfactant is taken away by the foam overflowing in severe cases, so that the service life of the cleaning agent is shortened. Therefore, a low-foaming rust-preventive metal cleaner has been a hot point of research in industrial cleaning. Because the nonionic surfactant in the low-foam metal cleaning agent can realize no foam at a certain temperature (cloud point), the common low-foam metal cleaning agent generally needs to be at a higher temperature to ensure that no foam enters the cleaning agent along with oil stains, and foam is increased, so that the low-foam metal cleaning agent is difficult to use at a low temperature (normal temperature in winter). Although the organic silicon defoaming agent can temporarily and quickly defoam, due to poor compounding property, a large amount of solubilizer is needed during product preparation, the cost is increased, and a cleaning solution is easy to separate out and even blocks a spray head; in addition, silicone defoamers contain a large amount of emulsifiers, which can cause more foam after the silicone is wrapped by the cleaning solution during cleaning. Furthermore, silicone defoamers have a negative effect on the detergency of the product. Therefore, the water-based metal cleaner which does not contain an organic silicon defoaming agent, is suitable for low-foaming, high-efficiency and antirust water-based metal cleaners at low temperature is urgently needed.

Disclosure of Invention

Technical problem to be solved

Aiming at the defects of the prior art, the invention provides a low-temperature metal cleaning agent and application thereof on a metal workpiece, so as to solve the technical problem that the existing organic silicon defoaming agent contains a large amount of emulsifying agents, and causes more foams after cleaning liquid wraps organic silicon in cleaning.

(II) technical scheme

In order to achieve the purpose, the invention provides the following technical scheme:

a low-temperature metal cleaner comprises 0.8 to 2 percent of anhydrous sodium metasilicate; 5 to 8 percent of sodium gluconate; 10 to 15 percent of sodium hydroxide; h5768 corrosion inhibitor, 2% -4%; 1-3% of triethanolamine borate; 1% -3% of PAA; WP172, 5% -8%; RPE2520, 2% -4%; 5 to 8 percent of mixed cleaning catalyst with the concentration of 5 percent is formed by evenly dispersing nano iron oxide in polythiophene; the balance being deionized water.

Furthermore, the average grain diameter of the nano ferric oxide is less than or equal to 50 nm.

Further, the cleaning agent comprises the following raw materials in parts by mass: anhydrous sodium metasilicate, 1%; 6% of sodium gluconate; 12% of sodium hydroxide; h5768 corrosion inhibitor, 3%; triethanolamine borate, 2%; PAA, 2%; WP172, 7%; RPE2520, 3%; 6 percent of mixed cleaning catalyst with the concentration of 5 percent formed by evenly dispersing ferric oxide with the average grain diameter of less than or equal to 30nm in polythiophene; the balance being deionized water.

The application of the low-temperature metal cleaner on the metal workpiece comprises the following steps: soaking the metal contaminated test piece in a cleaning solution; irradiating a metal contaminated test piece by pulse laser, ultrasonically cleaning the metal contaminated test piece in a ZQ25-12TJR ultrasonic cleaner at 45 ℃ and 1kHz, and then washing the metal contaminated test piece by deionized water.

(III) advantageous technical effects

Compared with the prior art, the invention has the following beneficial technical effects:

the mixed cleaning catalyst formed by uniformly dispersing the nano iron oxide in the polythiophene is doped in the cleaning formula, when a metal workpiece is cleaned, under the combined action of laser energy and the mixed cleaning catalyst, the binding force of pollutants with the metal workpiece is overcome through physical or chemical reaction and the pollutants are separated, and the instantaneous temperature of the pollutants is sharply increased to exceed the melting point or the boiling point after the pollutants absorb the laser energy, so that the pollutants are decomposed or gasified and disappear from the surface; tests show that all quality indexes of the low-temperature metal cleaning agent prepared by the invention are superior to JB/T4323.2-1999 standard requirements; not only the technical effect of thoroughly removing pollutants is realized, but also the organic silicon defoaming agent is not contained.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The first embodiment is as follows:

the low-temperature metal cleaning agent comprises the following raw materials in parts by mass: anhydrous sodium metasilicate, 0.8%; 5% of sodium gluconate; 10% of sodium hydroxide; h5768 corrosion inhibitor, 2%; 1% of triethanolamine borate; PAA, 1%; WP172, 5%; RPE2520, 2%; 5 percent of mixed cleaning catalyst with the concentration formed by evenly dispersing ferric oxide with the average grain diameter less than or equal to 50nm in polythiophene; the balance of deionized water;

the application method on the metal workpiece comprises the following steps: soaking the metal contaminated test piece in a cleaning solution for 1 h; irradiating the metal contaminated test piece by pulse laser for 10min, ultrasonically cleaning the metal contaminated test piece in an ultrasonic cleaner ZQ25-12TJR at 45 ℃ and 1kHz for 10min, and then washing the metal contaminated test piece by deionized water; the specific parameters of the pulse laser are as follows: center wavelength of 1064nm, maximum single pulse energy of 10.0mJ, pulse frequency of 30kHz, average power of 120W, spot diameter of 0.36mm, maximum scanning rate of 10000 mm/s, and beam quality M²＝11.2；

Example two:

the low-temperature metal cleaning agent comprises the following raw materials in parts by mass: anhydrous sodium metasilicate, 1%; 6% of sodium gluconate; 12% of sodium hydroxide; h5768 corrosion inhibitor, 3%; triethanolamine borate, 2%; PAA, 2%; WP172, 7%; RPE2520, 3%; 6 percent of mixed cleaning catalyst with the concentration of 5 percent formed by evenly dispersing ferric oxide with the average grain diameter of less than or equal to 30nm in polythiophene; the balance of deionized water;

the application method on the metal workpiece comprises the following steps: soaking the metal contaminated test piece in a cleaning solution for 1 h; irradiating metal contaminated test piece with pulsed laser for 15min, and ultrasonically cleaning in ZQ25-12TJR ultrasonic cleaner at 45 deg.C and 1kHz for 15minThen, washing with deionized water; the specific parameters of the pulse laser are as follows: center wavelength of 1064nm, maximum single pulse energy of 10.0mJ, pulse frequency of 50kHz, average power of 150W, spot diameter of 0.36mm, maximum scanning rate of 10000 mm/s, and beam quality M²＝11.2；

Example three:

the low-temperature metal cleaning agent comprises the following raw materials in parts by mass: anhydrous sodium metasilicate, 2%; 8% of sodium gluconate; 15% of sodium hydroxide; h5768 corrosion inhibitor, 4%; triethanolamine borate, 3%; PAA, 3%; WP172, 8%; RPE2520, 4%; 8 percent of mixed cleaning catalyst with the concentration of 3 percent formed by evenly dispersing ferric oxide with the average grain diameter less than or equal to 10nm in polythiophene; the balance of deionized water;

the application method on the metal workpiece comprises the following steps: soaking the metal contaminated test piece in a cleaning solution for 1 h; irradiating a metal contaminated test piece by pulse laser for 8min, ultrasonically cleaning the metal contaminated test piece in an ultrasonic cleaner ZQ25-12TJR at 45 ℃ and 1kHz for 8min, and then washing the metal contaminated test piece by deionized water; the specific parameters of the pulse laser are as follows: center wavelength of 1064nm, maximum single pulse energy of 10.0mJ, pulse frequency of 30kHz, average power of 200W, spot diameter of 0.36mm, maximum scanning rate of 10000 mm/s, and beam quality M²＝11.2；

And (3) performance testing:

according to JB/4323.2-1999 Water-based Metal cleaner test method, dirty test pieces of HT300, A3.20 steel and No. 45 steel are made of the above oil stains, and cleaning, rinsing and rust prevention tests are carried out on the dirty test pieces for 5min at 3 ℃ with the use concentration of the cleaner being 5%, and the cleaning rate is calculated and the rust prevention performance is inspected according to JB/4323.2-1999 Water-based Metal cleaner test method;

the detection result is as follows:

the first embodiment is as follows: the cleaning rate is 99.2 percent, and the corrosion amount is 0.2 mg;

example two: the cleaning rate is 99.6 percent, and the corrosion amount is 0.3 mg;

example three: the cleaning rate is 99.5 percent, and the corrosion amount is 0.2 mg;

the test result shows that all quality indexes of the low-temperature metal cleaning agent prepared by the invention are superior to the JB/T4323.2-1999 standard requirement.

Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.