阅读说明：本技术 一种燃料制备装置及其应用 (Fuel preparation device and application thereof ) 是由 黄浩东 杨嵩 林蒙 于 2021-09-15 设计创作，主要内容包括：本发明公开了一种燃料制备装置及其应用,所述燃料制备装置包括反应器,所述反应器包括电化学氧泵和多孔载体,所述多孔载体与外设燃料原料流连通,所述燃料原料流中的原料在多孔载体中反应生成氧气和燃料,所述电化学氧泵用于将所述氧气抽离所述多孔载体。本发明通过电化学氧泵快速电离热化学还原阶段产生的氧气,同时可以通过调节输入电化学氧泵的功率,实现高效并节能地除氧。本发明的热源可以是电能,核能/工业余热,或者是新能源,具有很大的应用空间。(The invention discloses a fuel preparation device and application thereof, wherein the fuel preparation device comprises a reactor, the reactor comprises an electrochemical oxygen pump and a porous carrier, the porous carrier is communicated with an external fuel feeding stream, raw materials in the fuel feeding stream react in the porous carrier to generate oxygen and fuel, and the electrochemical oxygen pump is used for pumping the oxygen away from the porous carrier. The electrochemical oxygen pump is used for quickly ionizing oxygen generated in the thermochemical reduction stage, and simultaneously, the oxygen can be efficiently removed in an energy-saving manner by adjusting the power input into the electrochemical oxygen pump. The heat source of the invention can be electric energy, nuclear energy/industrial waste heat or new energy, and has a large application space.)

1. A fuel preparation apparatus comprising a reactor, said reactor comprising an electrochemical oxygen pump and a porous support, said porous support being in communication with an external fuel feed stream, feedstock in said fuel feed stream reacting in the porous support to produce oxygen and fuel, said electrochemical oxygen pump being adapted to pump said oxygen away from said porous support.

2. A fuel preparation device according to claim 1, characterized in that: the electrochemical oxygen pump comprises an oxygen pump cathode, an electrolyte layer and an oxygen pump anode, wherein the electrolyte layer is positioned between the oxygen pump cathode and the oxygen pump anode, and the porous carrier is adjacent to the oxygen pump cathode.

3. A fuel preparation device according to claim 1, characterized in that: the reactor comprises a cavity type reactor, a tubular reactor or a columnar reactor; preferably, the shape of the cavity type reactor is at least one of cylindrical, conical or square; preferably, the tubular reactor has a shape of at least one of a cylindrical tube, a conical tube, or a square tube.

4. A fuel preparation device according to claim 1, characterized in that: the reactor comprises a direct reactor or an indirect reactor; preferably, the direct reactor comprises the electrochemical oxygen pump, a porous carrier, a cavity and a light-transmitting plate which are sequentially arranged, the porous carrier is positioned between the electrochemical oxygen pump and the cavity, and the light-transmitting plate is positioned on one side of the cavity, which is far away from the porous carrier;

preferably, the direct reactor is a cavity, the electrochemical oxygen pump and the light-transmitting plate form an outer layer of the direct reactor, and the cavity is formed between the porous carrier and the light-transmitting plate;

or the direct reactor is in a cavity layer type, heat-insulating layers are arranged on two sides of the electrochemical oxygen pump, the heat-insulating layers are respectively adjacent to two ends of the porous carrier and two ends of the light-transmitting plate, and the cavities are formed among the porous carrier, the light-transmitting plate and the heat-insulating layers;

or the direct reactor is tubular, the interior of the direct reactor is hollow and is communicated with the outside to form an air channel, and the direct reactor sequentially comprises the air channel, the electrochemical oxygen pump, the porous carrier, the cavity and the light-transmitting plate from inside to outside;

preferably, the light-transmitting plate is a glass plate.

5. A fuel preparation device according to claim 4, characterized in that: the indirect reactor comprises the electrochemical oxygen pump, a porous carrier and a heat exchange part which are sequentially arranged, wherein the porous carrier is positioned between the electrochemical oxygen pump and the heat exchange part; preferably, the heat exchanging part includes at least one of a heat transfer layer or a heat exchanger; preferably, the heat exchanging part comprises a heat transfer layer and a heat exchanger, wherein the heat transfer layer is positioned between the porous carrier and the heat exchanger;

preferably, the indirect reactor is in a cavity shape, the electrochemical oxygen pump is positioned at the outer side of the indirect reactor, and a cavity communicated with the air is formed at one side of the heat transfer layer, which is far away from the porous carrier;

or the indirect reactor is tubular, the interior of the indirect reactor is hollow and is communicated with the outside to form an air channel, and the indirect reactor sequentially comprises the air channel, a heat transfer layer, a porous carrier and an electrochemical oxygen pump from inside to outside;

or the indirect reactor is tubular, the interior of the indirect reactor is hollow and is communicated with the outside to form an air channel, and the indirect reactor sequentially comprises the air channel, the electrochemical oxygen pump, the porous carrier and the heat transfer layer from inside to outside.

6. A fuel preparation device according to claim 1, characterized in that: the fuel preparation device also comprises a heat supply device, and the heat supply device is used for supplying heat energy to the reactor; preferably, the heat supply device comprises a solar heat supply device, a nuclear energy waste heat supply device, an industrial waste heat supply device or an electric energy heat supply device; preferably, the heat supply device comprises a concentrated photo-thermal device, a laser device, a nuclear power/industrial waste heat device or a battery.

7. A fuel preparation device according to claim 4, characterized in that: the fuel preparation facilities still includes heating device, when the reactor is direct reactor, heating device is at least one among spotlight light heat device or the laser device, spotlight light heat device or laser device's light passes the light-passing board shine in on the porous carrier.

8. A fuel preparation device according to claim 5, characterized in that: the fuel preparation device also comprises a heat supply device, when the reactor is an indirect reactor, the heat supply device is adjacent to the heat transfer layer, and the heat of the heat supply device is transmitted to the porous carrier through the heat transfer layer.

9. Use of a fuel production apparatus according to any one of claims 1 to 8 in thermochemical fuel production.

10. A method of producing fuel by means of a fuel production plant according to any one of claims 1 to 8, comprising the steps of: introducing a fuel feed stream into a porous support, reacting said fuel feed stream to form oxygen and fuel, starting an electrochemical oxygen pump to pump off oxygen formed from the fuel feed stream, and collecting said fuel produced.

Technical Field

The invention relates to the technical field of thermochemical fuels, in particular to a fuel preparation device and application thereof.

Background

Based on thermochemical reduction of H in order to reduce the emission of carbon dioxide₂O/CO₂Preparation H₂The technology of/CO fuels is receiving increasing social attention. Thermochemical reduction of H₂O/CO₂Preparation H₂In the technical process of the/CO fuel, oxygen removal technology is particularly important. The conventional thermochemical reaction apparatus generally removes oxygen by a purge gas method or a vacuum pump method, however, the purge gas causes thermochemical reaction at high temperatureThe apparatus generates a large amount of heat loss (generally 5-30%), while the vacuum pump has an excessively low electrical efficiency (generally 5-40%) under a high vacuum (10-0.01 Pa absolute), and thus the energy conversion rate of the conventional thermochemical reaction apparatus is excessively low.

Disclosure of Invention

The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides a fuel preparation device which has the characteristic of high energy conversion rate.

The invention also provides an application of the fuel preparation device.

The invention also provides a method for preparing fuel by the fuel preparation device.

In a first aspect of the invention, a fuel preparation apparatus is provided, comprising a reactor, the reactor comprising an electrochemical oxygen pump and a porous carrier, the porous carrier being in communication with an external fuel feed stream, the feedstock in the fuel feed stream reacting in the porous carrier to produce oxygen and fuel, the electrochemical oxygen pump being configured to pump the oxygen away from the porous carrier.

The fuel preparation device provided by the embodiment of the invention has at least the following beneficial effects:

the working process of the invention mainly comprises the following steps: the oxide of the reactor is reduced at high temperature (300-3000 ℃) to release oxygen and become a reduction state for reducing H₂O/CO₂Generating H₂a/CO fuel. Through the electrochemistry oxygen pump, the oxygen that the oxide produced in the ionization reactor accelerates oxide to the degree and the speed of reduction state conversion, specifically is: under the drive of electric energy, the cathode of the electrochemical oxygen pump ionizes oxygen to generate oxygen ions, the oxygen ions are transported to the anode, and electrons are lost to obtain oxygen.

Oxygen generated in the thermochemical reduction stage is quickly ionized by the electrochemical oxygen pump, and meanwhile, the power of the electrochemical oxygen pump can be adjusted in real time according to the rate of oxygen generated by oxides, namely, the oxygen can be efficiently removed in an energy-saving manner by adjusting the power input into the electrochemical oxygen pump, and the electrochemical oxygen pump is high in energy conversion rate and system efficiency. In addition, the input power and the oxygen pumping amount of the electrochemical oxygen pump can be kept consistent, and the electric efficiency is high. The electrochemical oxygen pump has fast dynamic response, the control variable of the electrochemical oxygen pump is voltage, and the real-time regulation and control of oxygen partial pressure can be realized by regulating and controlling the current in the reduction reaction process: under the condition that other conditions are not changed, the current can instantaneously respond along with the voltage, and the change of the current is reflected by the reduction rate of oxygen molecules on the cathode, so that the change of the voltage can quickly change the reduction rate of the oxygen on the cathode, thereby achieving the quick regulation and control of the oxygen concentration in the porous carrier, namely, the working condition can be regulated in real time, and the oxygen partial pressure in the porous carrier can be regulated and controlled according to the requirement.

The heat source used in the high-temperature reduction process can be electric energy, nuclear energy/industrial waste heat or new energy, and the electric energy of the electrochemical oxygen pump can be provided by a power grid and a power generation device (a photovoltaic power generation device or a thermoelectric power generation piece), so that the high-temperature reduction method has larger application space and market prospect.

Meanwhile, in the existing mechanical vacuum pump oxygen removal technology: the vacuum pump requires that the whole reactor is in a low-pressure state in the reduction process, so that the whole reactor needs to have good air tightness and high processing technology requirement. Compared with a mechanical vacuum pump deoxygenation technology, the method provided by the invention only needs to have good air tightness in the reactor, namely, the porous carrier and the electrochemical oxygen pump have good air tightness, so that the processing difficulty is reduced.

In some embodiments of the invention, the electrochemical oxygen pump comprises at least one of a cell or a stack.

In some embodiments of the invention, the electrochemical oxygen pump comprises an oxygen pump cathode, an electrolyte layer, an oxygen pump anode, the electrolyte layer being between the oxygen pump cathode and the oxygen pump anode, the porous support being adjacent to the oxygen pump cathode.

The porous carrier is adjacent to the oxygen pump cathode, namely the porous carrier and the oxygen pump cathode can be attached or a gap is formed between the porous carrier and the oxygen pump cathode.

In some preferred embodiments of the invention, a side of the oxygen pump cathode facing away from the electrolyte layer is provided with a first current collector.

According to the above embodiment, the first current collector serves to collect current, facilitating the flow of electrons between the porous support and the oxygen pump cathode. Generally, the first current collector is provided with holes as oxygen transfer passages.

In some preferred embodiments of the invention, a side of the oxygen pump anode facing away from the electrolyte layer is provided with a second current collector.

According to the above embodiment, the second current collector is used to collect the current, facilitating the flow of electrons on the anode of the oxygen pump and thus facilitating the flow of O₂And (4) precipitating. Generally, the second current collector is provided with holes as oxygen transfer passages.

In some more preferred embodiments of the present invention, the material of the first current collector and the second current collector is metal.

In some more preferred embodiments of the present invention, the material of the first current collector and the second current collector is at least one of silver or gold.

In some embodiments of the invention, the porous support is a porous media oxide.

In some preferred embodiments of the invention, the electrochemical oxygen pump is spaced from the porous media oxide by 0 to 2 cm.

In some preferred embodiments of the invention, the porous medium oxide is at least one of a metal oxide or a halide.

In some more preferred embodiments of the invention, the metal oxide comprises at least one of ceria or zinc oxide.

In some more preferred embodiments of the invention, the metal oxide comprises doped ceria.

In some more preferred embodiments of the invention, the porous media oxide has a porosity of 0.3 to 0.99.

In some embodiments of the invention, the reactor comprises a cavity reactor, a tubular reactor, or a column reactor.

In some preferred embodiments of the present invention, the shape of the chamber reactor is at least one of cylindrical, conical, or square.

The shape of the cavity type reactor is square, which means that the shape of the cavity type reactor is cuboid or cube.

In some preferred embodiments of the present invention, the tubular reactor is at least one of a cylindrical tube, a conical tube, or a square tube in shape.

The square pipe means that the shape of the tubular reactor is cuboid or cube, and the inside of the tubular reactor is hollow and communicated with the outside.

In some embodiments of the invention, the reactor comprises a direct reactor or an indirect reactor.

By the above embodiments, the reactor is classified into a direct type reactor or an indirect type reactor according to the form of heating the porous support (e.g., porous medium oxide); wherein, the direct reactor mainly adopts solar energy, laser and other light heat sources, and the light can irradiate on the porous carrier (such as porous medium oxide) to heat the porous carrier (such as porous medium oxide); the indirect reactor refers to a heat exchange part (such as a heat transfer layer) of the reactor, which is heated by a heat source, and the heat is transferred to a porous carrier (such as a porous medium oxide) through the heat exchange part.

In some preferred embodiments of the present invention, the direct reactor comprises the electrochemical oxygen pump, a porous carrier, a cavity and a light-transmitting plate, which are sequentially arranged, wherein the porous carrier is located between the electrochemical oxygen pump and the cavity, and the light-transmitting plate is located on a side of the cavity facing away from the porous carrier.

With the above embodiment, the heat source mainly used in the direct reactor is a light heat source such as solar energy and laser, and light can pass through the light-transmitting plate (e.g., glass plate) and irradiate on the porous carrier (porous medium oxide) to heat the porous carrier (porous medium oxide).

In some more preferred embodiments of the present invention, the direct reactor is a chamber, the electrochemical oxygen pump and the light-transmitting plate form an outer layer of the direct reactor, and the cavity is formed between the porous support and the light-transmitting plate;

or the direct reactor is in a cavity layer type, heat-insulating layers are arranged on two sides of the electrochemical oxygen pump, the heat-insulating layers are respectively adjacent to two ends of the porous carrier and two ends of the light-transmitting plate, and the cavities are formed among the porous carrier, the light-transmitting plate and the heat-insulating layers;

or the direct type reactor is the tubulose, the inside cavity of direct type reactor just forms air passage with external intercommunication, the direct type reactor is by interior and outer air passage, electrochemistry oxygen pump, porous carrier, cavity and light-passing board of including in proper order.

In some more preferred embodiments of the invention, the light-transmitting plate is a glass plate.

In some more preferred embodiments of the present invention, the material of the glass plate may be quartz glass or sapphire having high light transmittance and high temperature resistance.

In some more preferred embodiments of the present invention, the glass sheet has a light transmittance of 50% to 100%, and the glass sheet can withstand a temperature of 500-3000 ℃.

In some more preferred embodiments of the present invention, the material of the insulating layer is a high temperature resistant material and has a thermal conductivity of less than 1W/(m · K).

In some more preferred embodiments of the present invention, the material of the insulating layer is alumina.

In some preferred embodiments of the present invention, the indirect-type reactor includes the electrochemical oxygen pump, a porous support and a heat exchanging part, which are sequentially disposed, the porous support being located between the electrochemical oxygen pump and the heat exchanging part.

Through the above embodiment, the indirect reactor means that the heat source heats the heat exchange part first, and then the heat is transferred to the porous carrier (porous medium oxide) through the heat exchange part.

In some more preferred embodiments of the present invention, the heat exchanging portion includes at least one of a heat transfer layer or a heat exchanger.

In some more preferred embodiments of the present invention, the heat exchange portion includes a heat transfer layer and a heat exchanger, the heat transfer layer being located between the porous support and the heat exchanger.

It should be noted that, the heat provided to the porous carrier is a heat supply device, when the heat supply device is a nuclear power/industrial wastewater heat supply device, the heat needs to be transferred to the heat transfer layer through the heat exchanger, and finally the porous carrier (porous medium oxide) is heated, and when the heat exchanger has good sealing performance, the heat transfer layer can be omitted to reduce heat transfer resistance.

When the heat supply device is a sunlight or laser heat supply device, the heat exchanger is not needed, and the light directly heats the heat transfer layer.

In some more preferred embodiments of the present invention, the indirect reactor is in a cavity shape, the electrochemical oxygen pump is located outside the indirect reactor, and a side of the heat transfer layer away from the porous support forms a cavity communicated with air;

or the indirect reactor is tubular, the interior of the indirect reactor is hollow and is communicated with the outside to form an air channel, and the indirect reactor sequentially comprises the air channel, a heat transfer layer, a porous carrier and an electrochemical oxygen pump from inside to outside;

or the indirect reactor is tubular, the interior of the indirect reactor is hollow and is communicated with the outside to form an air channel, and the indirect reactor sequentially comprises the air channel, the electrochemical oxygen pump, the porous carrier and the heat transfer layer from inside to outside.

In some embodiments of the invention, the fuel preparation apparatus further comprises a heat supply apparatus for providing thermal energy to the reactor.

In some preferred embodiments of the present invention, the heating device includes a solar heating device, a nuclear waste heat heating device, an industrial waste heat heating device, or an electric energy heating device.

Through the implementation mode, solar energy, nuclear power/industrial waste heat and the like are used as heat sources, so that energy conservation and emission reduction are facilitated, and carbon emission is reduced.

In some more preferred embodiments of the present invention, the heat supply device comprises a concentrated photothermal device, a laser device, a nuclear/industrial waste heat device, or a battery.

In some more preferred embodiments of the present invention, the concentrated photo-thermal power generation apparatus includes at least one of a tower type power generation system or a dish type power generation system.

In some more preferred embodiments of the invention, the concentrated photothermal power device comprises a solar concentrator comprising at least one of a solar revolved parabolic dish concentrator or a solar tower heliostat field concentrator.

In some embodiments of the present invention, when the reactor is a direct reactor, the heat supply device is at least one of a concentrated photo-thermal device or a laser device, and light of the concentrated photo-thermal device or the laser device passes through the light-transmitting plate and irradiates the porous support.

Through the above embodiment, the main working process includes:

step 1), a heat supply device (such as solar energy/laser) irradiates a porous carrier (porous medium oxide) through a light-transmitting plate (such as a glass plate), and the porous carrier absorbs light energy and converts the light energy into heat energy;

step 2) under the condition of high temperature, the oxide in the porous carrier is subjected to reduction reaction to release oxygen;

step 3), transferring the oxygen generated on the porous carrier to the cathode of the electrochemical oxygen pump, ionizing to generate oxygen ions, and oxidizing the oxygen ions at the anode of the electrochemical oxygen pump to form oxygen;

because the oxygen released from the porous carrier can be ionized in time, the reduction reaction rate is accelerated. When the reaction in step 2) reaches equilibrium, H is introduced into the porous carrier₂O/CO₂Chemically reacting with the reduced porous carrier to form H₂a/CO fuel.

In some embodiments of the present invention, the fuel preparation apparatus further comprises a heat supply apparatus, and when the reactor is an indirect-type reactor, the heat supply apparatus is adjacent to the heat transfer layer, and heat of the heat supply apparatus is transferred to the porous support through the heat transfer layer.

Through the embodiment, compared with a direct reactor, the indirect reactor is mainly different in the heating mode of the porous carrier (porous medium oxide), when a heating device is nuclear power/industrial wastewater, heat needs to be transferred to the heat transfer layer through the heat exchanger, and finally the porous carrier (porous medium oxide) is heated, and when the heat exchanger is good in sealing performance, the heat transfer layer can be omitted, so that heat transfer resistance is reduced.

When the heating device is sunlight or laser, the heat exchanger is not needed, and the light directly heats the heat transfer layer.

In some preferred embodiments of the present invention, the material of the heat transfer layer is a high thermal conductivity and high temperature resistant material.

In some more preferred embodiments of the present invention, the thermal conductivity of the material of the heat transfer layer is greater than 5W/m/K, and the temperature that can be tolerated is 500-3000 ℃.

In some more preferred embodiments of the present invention, the material of the heat transfer layer is at least one of metal or ceramic.

In some embodiments of the invention, the fuel preparation apparatus further comprises a power supply electrically connected to the electrochemical oxygen pump.

Through the above embodiment, the working process of the present invention mainly includes:

step 1) heating apparatus (e.g.: a concentrated photo-thermal device or laser, etc.) to provide a suitable operating temperature (high temperature) for the porous support of the reactor;

step 2), at high temperature, the oxide of the porous carrier is subjected to reduction reaction to generate oxygen and transmit the oxygen to the anode of the electrochemical oxygen pump;

and 3) the power supply device provides electric energy for the electrochemical oxygen pump, the cathode can timely convert oxygen generated on the ionized porous carrier into oxygen ions by adjusting the power of the electrochemical oxygen pump, and the oxygen ions are transferred from the cathode to the anode of the electrochemical oxygen pump and subjected to oxidation reaction to be converted into oxygen under the action of electromigration.

Because the oxygen generated on the porous carrier can be ionized in time, the reaction is favorably carried out towards the direction of generating a reducing substance;

when the reaction of step 2) is in equilibrium, feeding H into the reactor₂O/CO₂The reducing substance generated in the step 2) and the introduced H₂O/CO₂Reaction takes place to produce H₂/CO；

The current collectors (the first current collector and the second current collector) can be additionally arranged outside the cathode and the anode of the electrochemical oxygen pump so as to be connected with a power supply device.

In some preferred embodiments of the invention, the power supply means comprises an electrical grid, a battery or a power generation means.

In some more preferred embodiments of the present invention, the power generation device includes at least one of a photovoltaic power generation device or a thermoelectric generation sheet.

In some more preferred embodiments of the invention, the cell comprises a photovoltaic cell.

Through the embodiment, the electrochemical oxygen pump is driven by the photovoltaic cell, and two poles of the photovoltaic cell are respectively connected with the anode of the oxygen pump and the cathode of the oxygen pump through leads, so that the solar energy driven electrochemical oxygen pump is clean and energy-saving.

In some more preferred embodiments of the present invention, the reactor is a direct reactor, the heat supply device is a concentrated photothermal device, and the power supply device is a photovoltaic cell.

Through the above embodiment, the concentrated photo-thermal device provides a high-temperature environment for the reactor by concentrating sunlight (the porous carrier absorbs light energy and converts the light energy into heat energy), and the oxide in the porous carrier undergoes a high-temperature reduction reaction to release oxygen. Meanwhile, the photovoltaic cell supplies power to drive the electrochemical oxygen pump, oxygen is ionized at the cathode of the electrochemical oxygen pump to generate oxygen ions, and the oxygen ions are oxidized at the anode of the electrochemical oxygen pump to become oxygen. The heat energy of the high-temperature reduction reaction and the electric energy for driving the electrochemical oxygen pump are both from solar energy, namely the thermochemical reaction device realizes 100% solar energy driving, and is energy-saving and environment-friendly.

In a second aspect of the invention, the use of the above-described fuel production apparatus for thermochemical fuel production is proposed.

In a third aspect of the present invention, a method for preparing fuel by the above fuel preparation apparatus is provided, comprising the steps of: introducing a fuel feed stream into a porous support, reacting said fuel feed stream to form oxygen and fuel, starting an electrochemical oxygen pump to pump off oxygen formed from the fuel feed stream, and collecting said fuel produced.

Drawings

The invention is further described with reference to the following figures and examples, in which:

FIG. 1 is a schematic diagram of the operation of a fuel preparation apparatus according to an embodiment of the present invention;

FIG. 2 is a sectional view showing a schematic configuration of a reactor part of a direct fuel production apparatus of a chamber type in example 1 of the present invention;

FIG. 3 is a sectional view showing a schematic configuration of a reactor part of a cavity layer type direct fuel production apparatus in example 2 of the present invention;

FIG. 4 is a sectional view showing a schematic configuration of a reactor part of a tubular direct fuel production apparatus in example 3 of the present invention;

FIG. 5 is a sectional view showing a schematic configuration of a reactor part of a cavity-type indirect fuel production apparatus in example 4 of this invention;

FIG. 6 is a sectional view showing a schematic configuration of a reactor part of an indirect fuel production apparatus of tube-in-tube type in example 5 of the present invention;

FIG. 7 is a sectional view showing a schematic configuration of a reactor part of an indirect fuel production apparatus of the pipe-out type according to example 6 of the present invention;

FIG. 8 is a schematic view showing the operation of a direct reactor in example 7 of the present invention;

FIG. 9 is a schematic view showing the operation of an indirect reactor in example 8 of the present invention.

Reference numerals: A. a heating device; D. a power supply device; 1. an electrochemical oxygen pump; 11. an oxygen pump cathode; 12. an electrolyte layer; 13. an oxygen pump anode; 14. a current collector; 141. a first current collector; 142. a second current collector; 2. a porous dielectric oxide layer; 3. a glass plate; 4. a cavity; 5. a heat-insulating layer; 6. a heat transfer layer; 7. a heat exchanger.

Detailed Description

Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the accompanying drawings are illustrative only for the purpose of explaining the present invention, and are not to be construed as limiting the present invention.

In the description of the present invention, it should be understood that the orientation or positional relationship referred to in the description of the orientation, such as the upper, lower, front, rear, left, right, etc., is based on the orientation or positional relationship shown in the drawings, and is only for convenience of description and simplification of description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and thus, should not be construed as limiting the present invention.

In the description of the present invention, the meaning of a plurality is one or more, the meaning of a plurality is two or more, and the above, below, exceeding, etc. are understood as excluding the present numbers, and the above, below, within, etc. are understood as including the present numbers. If the first and second are described for the purpose of distinguishing technical features, they are not to be understood as indicating or implying relative importance or implicitly indicating the number of technical features indicated or implicitly indicating the precedence of the technical features indicated.

In the description of the present invention, unless otherwise explicitly limited, terms such as arrangement, installation, connection and the like should be understood in a broad sense, and those skilled in the art can reasonably determine the specific meanings of the above terms in the present invention in combination with the specific contents of the technical solutions.

In the description of the present invention, reference to the description of the terms "one embodiment," "some embodiments," "an illustrative embodiment," "an example," "a specific example," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.

In the embodiment of the invention, the porous carrier is a porous medium oxide layer, and the light-transmitting plate is a glass plate.

Example 1

A fuel preparation device is a cavity type direct fuel preparation device, the cross section of a reactor part is shown in figure 2 and is square, the fuel preparation device comprises an electrochemical oxygen pump 1, a porous medium oxide layer 2, a cavity 4 and a glass plate 3 which are sequentially arranged, the porous medium oxide layer 2 is positioned between the electrochemical oxygen pump 1 and the cavity 4, the porous medium oxide layer 2 is attached to an oxygen pump cathode 11 of the electrochemical oxygen pump 1, the glass plate 3 is positioned on one side of the cavity 4, which is deviated from the porous medium oxide layer 2, the electrochemical oxygen pump 1 and the glass plate 3 form an outer layer of the cavity type direct fuel preparation device, and the cavity 4 is formed between the porous medium oxide layer 2 and the glass plate 3. Wherein, the composition of the porous medium oxide layer 2 comprises cerium dioxide, and the porosity of the porous medium oxide layer is 0.3.

The cavity type direct fuel preparation device further comprises a heat supply device (a light-focusing photo-thermal device, not shown in the figure) and a photovoltaic cell (not shown in the figure), the photovoltaic cell is electrically connected with the electrochemical oxygen pump 1, and light rays of the light-focusing photo-thermal device penetrate through the glass plate 3 and irradiate on the porous medium oxide layer 2.

Example 2

The utility model provides a fuel preparation facilities, be cavity layer type direct fuel preparation facilities, the sectional view of reactor part is as shown in figure 3, it is square, including setting gradually electrochemistry oxygen pump 1, porous medium oxide layer 2, cavity 4, glass board 3, porous medium oxide layer 2 is located between electrochemistry oxygen pump 1 and the cavity 4, porous medium oxide layer 2 laminates with electrochemistry oxygen pump 1's oxygen pump negative pole 11 mutually, electrochemistry oxygen pump 1's both sides set up heat preservation 5, heat preservation 5 respectively with porous medium oxide layer 2 both ends, glass board 3 both ends are adjacent, porous medium oxide layer 2, form cavity 4 between glass board 3 and the heat preservation 5.

And a heating device and a power supply device are also included, and the structures and the connection relations with other components of the heating device and the power supply device are the same as those of the embodiment 1, and are not shown in the figure.

Example 3

A fuel preparation device is a tubular direct fuel preparation device, a cross section of a reactor part is shown in figure 4 and is tubular, specifically hollow and cylindrical, the fuel preparation device comprises an electrochemical oxygen pump 1, a porous medium oxide layer 2, a cavity 4 and a glass plate 3 which are sequentially arranged, the porous medium oxide layer 2 is positioned between the electrochemical oxygen pump 1 and the cavity 4, the porous medium oxide layer 2 is attached to an oxygen pump cathode 11 of the electrochemical oxygen pump 1, the interior of the reactor is hollow and is communicated with the outside to form an air channel, and the reactor sequentially comprises the air channel, the electrochemical oxygen pump 1, the porous medium oxide layer 2, the cavity 4 and the glass plate 3 from inside to outside.

And a heating device and a power supply device are also included, and the structures and the connection relations with other components of the heating device and the power supply device are the same as those of the embodiment 1, and are not shown in the figure.

Example 4

A fuel preparation device is a cavity type indirect fuel preparation device, the cross section of a reactor part is shown as figure 5, the reactor part is square, and comprises an electrochemical oxygen pump 1, a porous medium oxide layer 2 and a heat transfer layer 6 which are sequentially arranged, the porous medium oxide layer 2 is positioned between the electrochemical oxygen pump 1 and the heat transfer layer 6, the electrochemical oxygen pump 1 is positioned at the outer side of the reactor, and a cavity 4 communicated with air is formed at one side of the heat transfer layer 6, which is far away from the porous medium oxide layer 2.

The cavity type indirect fuel preparation device further comprises a heat supply device (an industrial waste heat supply device, not shown in the figure) and a photovoltaic cell (not shown in the figure), the photovoltaic cell is electrically connected with the electrochemical oxygen pump 1, and heat of the industrial waste heat supply device is transmitted to the porous medium oxide layer 2 through the heat transfer layer 6.

Example 5

A fuel preparation device is an in-tube indirect fuel preparation device, the cross section of a reactor part is shown in figure 6 and is tubular, the fuel preparation device comprises an electrochemical oxygen pump 1, a porous medium oxide layer 2 and a heat transfer layer 6 which are sequentially arranged, the porous medium oxide layer 2 is positioned between the electrochemical oxygen pump 1 and the heat transfer layer 6, the interior of the reactor is hollow and is communicated with the outside to form an air channel, and the reactor sequentially comprises the air channel, the electrochemical oxygen pump 1, the porous medium oxide layer 2 and the heat transfer layer 6 from inside to outside.

And a heating device and a power supply device are also included, and the structures and the connection relations with other components of the heating device and the power supply device are the same as those of the embodiment 4, and are not shown in the figure.

Example 6

A fuel preparation device is an external indirect fuel preparation device, the cross section of a reactor part is shown in figure 7 and is tubular, the fuel preparation device comprises an electrochemical oxygen pump 1, a porous medium oxide layer 2 and a heat transfer layer 6 which are sequentially arranged, the porous medium oxide layer 2 is positioned between the electrochemical oxygen pump 1 and the heat transfer layer 6, the interior of the reactor is hollow and is communicated with the outside to form an air channel, and the reactor sequentially comprises the air channel, the heat transfer layer 6, the porous medium oxide layer 2 and the electrochemical oxygen pump 1 from inside to outside.

And a heating device and a power supply device are also included, and the structures and the connection relations with other components of the heating device and the power supply device are the same as those of the embodiment 4, and are not shown in the figure.

Example 7

A fuel preparation apparatus, a cross-sectional view of a reactor part is shown in fig. 8, which is different from example 3 in that: one side of the oxygen pump cathode 11 of the electrochemical oxygen pump 1 departing from the electrolyte layer 12 is provided with a first current collector 141, and one side of the oxygen pump anode 13 of the electrochemical oxygen pump 1 departing from the electrolyte layer 12 is provided with a second current collector 142.

The working process mainly comprises the following steps:

step 1), light rays emitted by a heat supply device (a light-condensing photo-thermal device) irradiate a porous medium oxide layer through a glass plate, and the porous medium oxide layer absorbs light energy and converts the light energy into heat energy;

step 2) under the condition of high temperature, the oxide in the porous medium oxide layer is subjected to reduction reaction to release oxygen;

step 3), transferring the oxygen generated on the porous medium oxide layer to the cathode of an oxygen pump of the electrochemical oxygen pump, ionizing to generate oxygen ions, and oxidizing the oxygen ions at the anode of the electrochemical oxygen pump to form oxygen;

oxygen released from the porous medium oxide layer can be ionized in time, so that the reduction reaction rate is accelerated. When the reaction in the step 2) reaches the equilibrium, introducing H into the porous medium oxide layer₂O/CO₂Chemically reacting with the reduced porous dielectric oxide layer to form H₂a/CO fuel.

Example 8

A fuel production apparatus, a cross-sectional view of a reactor part is shown in fig. 9, which is different from example 5 in that: the side of the heat transfer layer 6 facing away from the porous medium oxide layer 2 is provided with a heat exchanger 7.

The working process mainly comprises the following steps:

step 1), a heat supply device (an industrial waste heat supply device) transfers heat to a heat transfer layer 6 through a heat exchanger 7, and the porous medium oxide layer is heated through heat transfer of the heat transfer layer 6;

step 2) under the condition of high temperature, the oxide in the porous medium oxide layer is subjected to reduction reaction to release oxygen;

step 3), transferring the oxygen generated on the porous medium oxide layer to the cathode of an oxygen pump of the electrochemical oxygen pump, ionizing to generate oxygen ions, and oxidizing the oxygen ions at the anode of the electrochemical oxygen pump to form oxygen;

oxygen released from the porous medium oxide layer can be ionized in time, so that the reduction reaction rate is accelerated. When the reaction in the step 2) reaches the equilibrium, introducing H into the porous medium oxide layer₂O/CO₂Chemically reacting with the reduced porous dielectric oxide layer to form H₂a/CO fuel.

The structures and the mutual connection modes of the heating device (a solar heating device, a nuclear energy waste heat heating device, an industrial waste heat heating device or an electric energy heating device) and the power supply device (such as a photovoltaic cell and a concentrating photo-thermal power generation device) in the application are common in the market and are the prior art, so that the understanding of the actual protection scope of the invention by the technical personnel in the field is not influenced even though the detailed description is omitted.

The embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge of those skilled in the art without departing from the gist of the present invention. Furthermore, the embodiments of the present invention and the features of the embodiments may be combined with each other without conflict.